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MTBE technology

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  • People, Skills, Equipment.

    Saipem S.p.A.Via Martiri di Cefalonia, 67 - 20097 San Donato Milanese, Milan - ItalyTel. +39.02.520.1 - Fax +39.02.520.44415

    saipem.com - A subsidiary of Eni S.p.A.

    PETROCHEMICALSENGINEERING AND CONSTRUCTIONPROJECT REFERENCES

    06.201

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  • PETROCHEMICALS

  • 3

    INDEX

    SAIPEM TODAY 4

    SAIPEM ENGINEERING & CONSTRUCTION 6

    PETROCHEMICALS 8 TECHNOLOGY ACCESS 10

    COMMERCIAL EXPERIENCE 12

    FOCUS ON POLYMERS 18

    A CONTINUING COMMITMENT 22

    PETROCHEMICAL PROJECT REFERENCES 24

  • 5 4

    SAIPEMTODAYSAIPEM TODAY IS A WORLD LEADER IN THE GLOBAL SUPPLYOF ENGINEERING, PROCUREMENT, PROJECT MANAGEMENT, CONSTRUCTION AND DRILLING SERVICES WITH DISTINCTIVE CAPABILITIES IN THE DESIGN AND EXECUTION OF LARGE-SCALE OFFSHORE AND ONSHORE PROJECTS.

    Saipem has a strong bias towards oiland gas frontiers, namely activitiesin harsh and remote areas, in deep waters as well as in extremely cold and hot environments, applying significanttechnological competences in manydiverse fields such as gas monetizationand heavy oil exploitation.

    Saipem is organized in two BusinessUnits: Engineering & Constructionand Drilling.

  • SAIPEMENGINEERING & CONSTRUCTIONFOLLOWING AN AGGRESSIVE GROWTH STRATEGY, WHICH INCLUDED IN THE LAST DECADE THE ACQUISITION OF MANY CONSTRUCTION, TECHNOLOGY AND ENGINEERING COMPANIES, MOST PROMINENTLY OF SNAMPROGETTI, BOUYGUES OFFSHORE, SOFRESID AND MOSS MARITIME, SAIPEM HAS BECOME ONE OF THE WORLD LARGESTAND MOST COMPLETE ENGINEERING AND CONSTRUCTION COMPANIESIN THE GLOBAL OIL AND GAS MARKETS, ONSHORE AND OFFSHORE.

    Ever since its initial steps in the fiftiesas the construction division of Snam,the pipeline company of the Eni Groupin Italy, Saipem has pursueda systematic growth strategy, basedon the development of internal assets,expertise and skilled resources, as wellas on the acquisition of other playerswith their own asset bases, such asMicoperi in late eighties, and manyothers.

    In the last decade, Saipem hascontinued its growth by acquiringBouygues Offshore and Sofresid inFrance, Moss Maritime in Norway, IDPEin India and Snamprogetti in Italy,and by carrying out a multibillioninvestment program into the expansionof its offshore construction and drillingfleets. Since the year 2000, Saipemsmarket capitalization has grown morethan sixfold and its revenues tenfold.(*)

    The organizational integration ofthis considerable asset base, namelythe network of engineering centres,fabrication and support yards in severalcontinents as well as the offshoreconstruction fleet, has been completedgradually over the years - most recentlywith the creation of a unified BusinessUnit Engineering & Construction,an entity with over 30,000 employees(excluding corporate and BU Drillingstaff) from over 100 nationalities,with over 60 permanent establishments

    and numerous project executioncentres around the globe, and withyearly revenues exceeding 10 billion E/y;all held together by outstanding projectmanagement skills.

    Through the involvement of our globalEP(I)C hubs in Milan, Rome and Fano(Italy), Paris (France) and Chennai(India), which operate in connectionwith a growing number of medium sizeand smaller regional enginveeringand project execution centresemploying altogether over 7,000engineers, Saipem balances highproject execution quality with acompetitive cost and - most importantly- with a major emphasis on localknow-how and content.

    This well-integrated multicenterapproach provides a consistent designand robust execution philosophyon all our projects worldwide.Top priority is provided throughoutto all HSEQ aspects.

    Saipem therefore offers a completerange of project definitionand execution services, offshoreand onshore, particularly forthe complex mega-projects requiredby the market today: from feasibilityand conceptual studies to complexintegrated solutions combining design,engineering, procurement, fieldconstruction, fabrication and offshore

    installation; also revamps, upgradings,maintenance, decommissionings,reclamations and decontaminations.

    Saipem today operates in virtually everyworld market, often in remote locationswith harsh environmental conditionsand challenging logistics, leveragingon its proven experience across themost significant product lines in theoil and gas production onshore,offshore, in deepwater; gas and oiltransportation via offshore and onshorepipeline systems; midstream, refining,chemicals, power generation from fossilas well as from renewable sources;environmental industries, maritimeworks and infrastructure.

    This new series, therefore, outlinesSaipems integrated referencesin engineering and constructionmarkets offshore and onshore,according to individual businessand technology lines.

    7 6

  • 9 8

    PETROCHEMICALSOVER 40 YEARS OF EXPERIENCEIN THE DESIGN AND CONSTRUCTIONOF PETROCHEMICAL PLANTS.

    The roots of Saipems involvement in petrochemicals as an Engineering and Construction Main Contractor date back to the early 60s, when Snamprogetti started its initial experiences at Enis chemical site in Gela, in Sicily, Italy. Subsequently, during the 60s, the commitment towards this line of business evolved and accompanied the rapid growth of other Enis sites in Italy (Ravenna, Porto Torres). During the 70s and after, Snamprogetti engaged in a

    continuous and rapidly growing involvement as an EPC General Contractor in many petrochemical projects worldwide.

    The scope of work performed by Saipem today typically covers the full range from conceptual studies and Basic/FEED packages, up to designing and building complete projects on an EPC basis, including start-up and commissioning.

    SAIPEM REFERENCES IN PETROCHEMICALS (*)

    (*) References ranging from sole-services to full-scope EPC contracts. Ethylene Plant at Gela Petrochemical Complex, Caltanissetta, Italy, 1960.

    OLEFINSEthylene, Propylene, High Purity Isobutene, Butene-1, Butadiene 40

    POLYMERS AND ELASTOMERSPolyethylene, Polypropylene, Elastomers & Rubbers, ABS 57

    BASE INTERMEDIATE CHEMICALSEO/EG, VCM, EB, Styrene, LAB, ALPHA ALCOHOLS 34

    HIGH OCTANE PRODUCTS FOR GASOLINE BLENDING MTBE, ETBE, TAME, Iso-Octane, Iso-Octene 33

  • 11 10

    Some of them are proprietary (today under the trademark SnamprogettiTM), the other ones are procured from the major global licensors through frame and/or project agreements, depending on end-user preferences or on predating agreements between Saipem and the technology licensors.

    Snamprogettitm

    proprietary technologieS:

    Etherification(MTBE,ETBE,TAME, TAEE)Butene-1PolymerizationGrade recoveryHighPurityIsobuteneviaMTBE crackingIsobutene Dimerization/Hydrogenation (Iso-Octene and Iso-Octane)ParaffinsDehydrogenation

    the following licenSorS* provide their technologieS to Saipem, through frame and collaborative agreementS:

    BASF BayerCDTECHDowChemicalsIFPJacobsEngineeringLummusTechnologiesPolimeriEuropa

    ShellInternationalResearchSolutia(Monsanto)UNIVATIONUOP

    *(In alphabetic order)

    TECHNOLOGY ACCESSSAIPEM DESIGNS AND BUILDSPETROCHEMICAL PLANTS BASED ON A WIDE RANGE OF FIRST CLASS TECHNOLOGIES.

  • 13 12

    olefins and diolefins (ethylene, propylene, high-purity isobutene, butene-1, butadiene);

    polymers and elastomers(LDPE,HDPE,LLDPE,PP,PVC,PBR,SBR,PS,ABS);

    high octane compounds forgasolineblending(MTBE,ETBE,TAME,TAEE,Iso-Octane,Iso-Octene); base intermediate chemicals(ethyleneoxide,ethyleneglycol,VCM,ethylbenzene,styrene);

    intermediate products for detergents(LAB,alpha-alcohols).

    During the recent years, Saipem has designed and built the following major projects:

    rio polimeroS gaSchemical complex (BRAzIL)520,000 T/y ETHyLEnE PLAnT (LuMMuS TECHnOLOGy) COMBInEd wITH2 x 270,000 T/y HdPE/LLdPE SwInG PLAnTS (unIVATIOn TECHnOLOGy).EPC/LSTK COnTRACT PERfORMEd By SAIPEM In A 50/50 JV ASSOCIATIOn.In OPERATIOn SInCE 2005.

    COMMERCIAL EXPERIENCETO DATE, SAIPEM HAS DESIGNED MORETHAN 160 PETROCHEMICAL PLANTSAND INTEGRATED COMPLEXES WORLDWIDEIN THE FOLLOWING FIELDS:

  • 15 14

    SuperoctanoS (VEnEzuELA) MuLTIPuRPOSE PLAnT fOR 500,000 T/y MTBE OR 365,000 T/y ISO-OCTAnE BASEd On SnAMPROGETTITM TECHnOLOGy.EPC/LSTK COnTRACT PERfORMEd By SAIPEM.PLAnT On STREAM In 2010.

    braSkem (BRAzIL)REVAMP Of An ExISTInG THIRd PARTy TECHnOLOGy MTBE PLAnT TO PROduCE 151,500 T/y Of ETBE, nOw uTILIzInG THE nEw SnAMPROGETTITM TECHnOLOGy.COnTRACT: BASIC dESIGn And LICEnSE.In OPERATIOn SInCE 2007.

  • 17 16

    Qatofin (QATAR)450,000 T/y LLdPE POLyETHyLEnE PLAnT: THIS IS THE TwELfTH POLyETHyLEnE LInE dESIGnEd On THE BASIS Of unIVATIOn GAS PHASE PROCESS By SAIPEM In ITS CAPACITy AS AuTHORIzEd COnTRACTOR fOR THE unIPOLTM TECHnOLOGy (SEE fOCuS On POLyMERS). EPC/LSTK COnTRACT PERfORMEd By SAIPEM.PLAnT On STREAM SInCE 2009.

    duShanzi SSbr/SbS plant (CHInA)100,000 T/y SSBR PLuS 80,000 T/y SBS RuBBER PLAnTS BASEdOn POLIMERI EuROPA TECHnOLOGy.LuMP SuM COnTRACT InCLudInG LICEnSE, BASIC/fEEdAnd PROCuREMEnT Of KEy EQuIPMEnT.PLAnT duE On STREAM In 2009.

  • 19 18

    Notably, as shown, since 1996 the success in the polyethylene sector has been boosted by the agreement signed between Snamprogetti and UNIVATIONTechnologies.

    In fact, since then Snamprogetti (now Saipem)isoneoftheAuthorizedContractorsfortheUNIPOLTM

    Polyethylene Technology (Gas-phase HDPE/LLDPE).

    This co-operation is aimed at implementing a shared commitment betweentheLicensorandtheContractor for the creation of value through innovative design.

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