hazardous material transportation q - 2
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Contents
1. Introduction to hazardous cargo transportation
2. Safety of Personnel, Vessel and Environment
. Security precautions Prior loading, during loading and !hile cargo is on"oard
#. Preparation for $oading of %angerous cargo
&. 'eporting re(uirements for carriage of )azardous cargo
*. I+% code
-. %ocumentation for %angerous cargo
. /uestion papers
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Introduction to transportation of hazardous cargo:
Any material being transported by any form which is capable of causing harm
to Humans or the environment is considered to be Hazardous cargo and to be
treated with extreme caution.
The carriage of hazardous goods by any mode of transport is to be considered
a high risk activity. The above operation not only exposes the personnel
involved in its transportation to the severe conseuences of harmful material
exposure! it has also the danger of starting a catastrophic chain of events
leading to human disaster is very real. This factor is only aggravated by the
various political and economical scenarios where the very material which
helped the civilization progress to such high levels of sophistication might see
the very end or at the least! the beginning of such an end. It is in this light this
course has to be approached and not as a legal reuirement or a general
transportation awareness course.
Transportation of hazardous cargo between places of origin of cargo to its
final destination is multimodal and the level of security! "afety and emergency
preparedness has to be the same in all the modes by #and! sea or Air. In this
regards the presence of very large amount of cargo on board a vessel with
various classes of cargo placed in closed proximity is by far the most complex
sector of the hazardous cargo transportation. The limited and isolated
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uantities of cargo where each trailer or rail carrier will carry is much limited
in its variety and uantity than what will be carried on board $argo vessel like
a container or a %ulk carrier.
The &ersonnel involved in the transportation of hazardous cargo at every stage
have to be fully aware of the nature of the operation and risks associated with
any lapses. The results of an accident involving chemicals in large scale can
be catastrophic and the human suffering from such an incident can leave
lasting impression on the future of humanity. The damage to environment from
any such incidence can be permanent and irreversible apart from the
prolonged operations to contain the fallout of such accidents.
I would not want to dwell too much on such doomsday scenarios but rather
concentrate on the ways to prevent any such undesired incidence.
It would suffice my interests to introduce this course as that which prepares
all shipboard personnel dealing with hazardous cargo to fully understand the
hazards associated with the type of cargo being handled by them and be in a
position where they are able to respond uickly and efficiently to any
emergencies arising while the cargo is in their care to prevent any damage to
the people! environment! 'essel or cargo.
It is imperative that the seafarer is fully trained in the emergency procedures !
well aware of all the hazards he is likely to face! has in his immediate disposal
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all information pertaining to the cargo involved! has immediate access to
additional information pertaining to the relevant cargo and
#egally the transportation of hazardous cargo is regulated by the I() and the
convention that enforces this is the ")#A" $H*'II + $arriage of dangerous goods
by sea along with (A,&)# Annex II + $arriage of -oxious liuid substances in
bulk (ainly Tankers/! Annex III + $arriage of harmful substances in packaged
form $ontainers/. Together these form the legal frame work under which
hazardous cargoes are carried on board vessels. The guidelines for the carriage
of harmful substance is available from the following sources:
The I(01 $)02 + International (aritime 0angerous goods code $ontainers/
The %$ code + $ode for the carriage of %ulk cargoes on bulk carriers.
(erchant shipping notice (1- 34 + "pecial reuirements for the carriage of
0angerous goods 0ocument of compliance for the carriage of 0angerous
goods/
Together these conventions and associated codes provide complete
1uidance on the safe carriage of Hazardous cargo
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"afety of &ersonnel! 'essel and 2nvironment
The transportation of hazardous goods is an important component of world
economy and well being and can not be dispensed with. Hence the only
alternative available to us is their safe handling and safe transport. This
brings us to the human element involved in the transportation as a whole! be it
during production! storage! transportation or finally its safe usage
The most effective way to prevent any incidents associated with handling of
Hazardous cargo is to ensure that at every stage the human element involved
in the operation is fully aware of the -ature of the $argo and hazards
associated with it. 5nowledge in itself will not be of help in times of
emergency or an incidence. This can be achieved by ensuring that an effective
system is in place and adeuate training of personnel is carried out so as to
enable them follow the above system effectively.
"afety concerns during the handling and transportation of Hazardous cargo:
Any transportation of hazardous cargo involves or is associated with a number
of safety hazardous which are listed below.
6ire + "elf heating! 2xplosive! Highly reactive
$hemical exposure + $hemically very active and could react with other cargo
or elements leading to explosion and or substantial damage to life7property7
2nvironment "evere marine pollutant/
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$orrosive + Has corrosive effect when it comes in contact with other
substances.
Toxicity + $ould prove to be toxic when in physical contact or inhaled or
ingested.
,adio active materials: These can cause serious mutation in bio cells causing
chronic disease on even very minute duration of exposure.
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"ecurity precautions and proced ures &rior loading! during loading and
wh ile cargo is onboard
The nature of cargo being handled is such that if stringent security measures
are not applied it could have serious conseuences especially if certain
cargoes were to be available to antisocial elements even in very limited
uantities. 2xplosives and chemicals can cause massive destruction even in
small uantities if their usage is professionally engineered and timed. 2ven in
amateur hands they could turn out to be very lethal causing loss of
lives7damage to environment. These are weapons in the hands of any one who
wants to cause harm. A ship loaded with explosives 7 $hemicals can be
considered to be a floating bomb and would be a very lucrative target to any
one wanting to cause destruction in a huge level.
The above summarizes the utmost security procedures to be in place for
carriage of hazardous cargo.
The ships security plan has to address the security aspect to prevent misuse...
&rocedures are to be in place to ensure there is strict access control available
at the point of entry in to the vessel.
-o access is to be available to cargo other than personnel designated by the
master.
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,egular monitoring of sensitive cargo is to be carried out while being loaded!
during transit and when being discharged.
0epending on the nature of cargo being handled it might be necessary to vary
the security level to ensure maximum security.
,egular security drills are to be carried out ensure crew are well trained to
report and respond to any security incidence.
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$hapter + 4 (01 code
All substances classified as marine pollutants7 hazardous are to be &acked!
#abeled! &lacarded! "egregated! "towed and transported as per I(01 code
$ontents of I(01 code:
')# 8! 9! and "upplement
$lass room exercises for thorough familiarisation.
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$hapter + + 0ocumentation
,efer chapter ;.< of the I(01 code for the complete details of the
0ocumentation reuired transportation of 0angerous goods.
A brief summary of the documents are listed and explained here.
0angerous goods7(arine pollutants note: "hipping note/
The master or the ship operator shall be provided with the dangerous goods
declaration or a marine pollutants declaration could also be a combined
declaration/ prior any cargo is accepted for transportation.
The following information shall be provided on the above declaration:
The proper shipping name of the goods! Their class and division! =- numbers
allocated by the I(01 code! the packaging or packing group! uantity and kind
of packages! total uantity of dangerous goods! &rimary and subsidiary
hazards! the words marine pollutant! details of the declaration as to when it
was prepared! contact details of the person from whom information about the
packed goods will be available.
If the capacity of an aerosol is above 8>>> ml this shall be declared in the
shipping note.
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$ontainer or vehicle packing certificate:
A declaration by the person responsible for stowing the goods in transport
unit.
%ulk cargo documentation:
6ollowing details shall be provided to the (aster7)perator prior loading of bulk
cargo:
?uantity! nature of cargo including any reactivity! Technical name! =- number!
$lassification as per I(01 code! for liuids with flash point below 4> deg their
flash point! contact details of the person from whom information about the
packed goods will be available.
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&reparation and procedures for an 2merg ency involving hazardous
material
@hile utmost care and preparation is reuired for the handling and
transportation of hazardous cargo it can be observed that any amount of such
preparation and procedures can not guarantee the absence of accidents
involving dangerous cargo. The very nature of the cargo combined with the
perils of the sea can always throw a surprise at the well prepared seafarer
while involved in the transportation of the hazardous cargo.
In this regards it is not enough that shipboard personnel are trained for
transportation of hazardous cargo but also they are provided with a system to
assist them in enabling a uick response measures in the event of emergency.
6ollowing points to be taken in to account in ensuring vessels preparedness to
react effectively to an emergency:
2nsure the 0)$ is consulted soon as the cargo plan is received to ensure that
the cargo stowage is as permitted by The 0)$.
2nsure the $argo hold is prepared as reuired for the relevant cargo and in
case of containers ensure any remnants of previous cargo is removed.
Have the dangerous cargo notes available in suitable location for use in
immediate emergency.
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2nsure the cargo stowage and segregation is as per I(01 code part
2nsure the $argo is loaded as per the plan approved by the master7chief officer
in consultation with the shore planner.
2nsure the 6ire fighting system has been regularly tested and maintained in
good working condition.
Additional euipments reuired for fighting chemical spills have to be located
in easily accessible location and are to be regularly checked for their uality
and uantity. To ensure their effectiveness when reuired.
These euipments are to be tried out regularly during drills to ensure that
personnel are familiar with their proper use.
$hemicals reuired to counter the effects of chemicals 2xposure to &oison +
Inhalation! Ingestion etc are to be regularly checked for their validity/
)xygen cylinders and their associated euipment ,esuscitator units/
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Mitsui OSK Lines
HAZMAT FAMILIARIZATION COURSE
QUESTION PAPER ime 1& +ins
Choose the correct answers
1. uidance for Carriage of %angerous goods on "oard containers is availa"le in follo!ing documents
1. S3$4S Ch5VI
2. I+% C3%E
. I6C code#. %ocument of compliance
2. he master of vessel !here dangerous cargo is "eing loaded should "e provided !ith follo!ing
documents
1. +arine pollutant declaration
2. %angerous goods declaration
. %angerous goods note
#. Vehicle pac7ing certificate
. he list of hazardous cargo is availa"le in !hich volume of I+% code
#. Information regarding the emergency procedure for dangerous goods is listed in the follo!ing
Pu"lication
1. I+% code Vol 2
2. I+% code supplement
. 6C code
#. I+% code Vol 1
&. he supplement to I+% code consists of !hat ma8or information9
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*. :hich column to refer to in order to 7no! the E+S and +;4 schedule for a given cargo.
-. :here is the emergency telephone num"er provided !ith regards to a dangerous cargo "eing carried
on "oard
. In simple !ords define Category 4,6,C,% cargo as per I+% code
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12. Indicate rue or ;alse
1. +arine pollutants are indicated "y P
2. Severe +arine pollutants are indicated "y PP
. +arine pollutants are mar7ed "y a triangle containing a fish sym"ol
1. Indicate rue or ;alse
1. $oading of e0plosives can "e made simultaneously !ith 6un7ering
2. $oading of e0plosives should "e indicated "y displaying of 6 flag during day and red light
during night
. Chapter - deals !ith Sto!age and segregation of cargo
#. %3C has an anne0 !hich has description of sto!age of class of cargo and location
1#. :here !ill you refer in the I+% code for CP', 46C and recovery procedures
1&. >ame different type of containers as per chapter - ofI+% code
1*. Can e0plosives "y smothered !ith steam fire e0tinguishing system
1-. Can EE6%@s "e used along !ith Chemical suits !hile fighting a small spillage Afire
1. 4n I+% cargo is mar7ed !ith S5B should it "e 7ept dry or !et
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Mitsui OSK Lines
HAZMAT FAMILIARIZATION COURSE
QUESTION PAPER !" ime 1& +ins
Choose the correct answers
1. uidance for Carriage of %angerous goods on "oard containers is availa"le in follo!ing documents
1. S3$4S Ch5VII
2. I+% C3%E
. I6C code#. %ocument of compliance
&. 4llofa"ove
2. he master of vessel !here dangerous cargo is "eing loaded should "e provided !ith follo!ingdocuments
1. +arine pollutant declaration
2. %angerous goods declaration
. %angerous goods note
#. Vehicle pac7ing certificate
&. 4ll of a"ove
. he list of hazardous cargo is availa"le in !hich volume of I+% code
1. I+% Vol 1
2. I+% Vol 2
. I+% supplement
#. Information regarding the emergency procedure for dangerous goods is listed in the follo!ing
Pu"lication
1. I+% code Vol 2
2. I+% code supplement
. 6C code
#. I+% code Vol 1
&. he supplement to I+% code consists of !hat ma8or information9
0i0
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*. :hich column to refer to in order to 7no! the E+S and +;4 schedule for a given cargo.
-. :here is the emergency telephone num"er provided !ith regards to a dangerous cargo "eing carried
on "oard
. In simple !ords define Category 4, or 6, C or % cargo as per I+% code
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1. Indicate rue or ;alse
1. $oading of e0plosives can@t "e made simultaneously !ith 6un7ering
2. $oading of e0plosives should "e indicated "y displaying of 4 flag during day and
. Chapter - deals !ith Sto!age and segregation of cargo
#. %3C has an anne0 !hich has description of sto!age of class of cargo and location
1#. :here !ill you refer in the I+% code for CP', 46C and recovery proceedures
1&. )o! many different type of containers as per chapter - ofI+% code
1*. Can e0plosives "y smothered !ith steam fire e0tinguishing system
1-. Can EE6%@s "e used along !ith Chemical suits !hile fighting a small spillage Afire
1. 4n I+% cargo is mar7ed !ith S5B should it "e 7ept dry or !et
1