Hazardous Materials TransportationMarch 12, 2008

Truck Bombs Used

1983, U.S. Embassies, Lebanon & Kuwait1983, U.S. Marine Barracks, Lebanon1988, USO Club, Italy1992 and 1993, U.S. Embassy, Peru1993, World Trade Center, New York1995, Federal Building, Oklahoma City1998, U.S. Embassies, Kenya, Tanzania

Algerian charged with transporting explosives

December 17, 2000 Man charged with

transporting explosives32 year old Algerian tried to

smuggle 100 pounds of explosive material and timer across border at Port Angeles, Wa.

Planned to use at LAX on New Years Eve; Seattle’s Space Needle was secondary target

Written Security Plan (Part 172.800 - .804)

Part 107.601, those who offer or transport: RC quantity of class 7 >55 lb. Class 1.1, 1.2, 1.3 >1.06 qt. Poison inhalazion hazard Zone A Bulk shipment of HM in package greater than

3500 gallons (liquid, gas) or 468 cubic ft solid Placarded loads Agent or toxin regulated by CDC

Components of Written Plan (Part 172.802)

Assess transportation security risks and measures to address the risks Personnel security Unauthorized access En route security Plan must be:

In writingAvailable to employeesChanged as conditions change

Profile of Terrorist Act

Target – select and rate value (how much damage, how many dead, media coverage)

Casing – observe operations, schedules, etc. and prepare written plan

Surveillance – physical plant; equipment; written security plan; web site

Rehearsal – limited resources can’t be wasted

Driver Security

Be alert when leaving; criminal surveillance starts within a mile of your origin

Do not discuss your cargo, destination or trip near people you don’t know

Do not park under bridges, overpassesSurvey surroundings before leaving truckMake sure radio or cell phone is working

properlyPerform quick walkaround at every stop If in doubt, call 911

Driver Security (cont.)

Avoid being boxed in; leave room in front and at rear

Keep truck locked at all timesWatch for people following youTeam driving? Leave one person in the

truckPadlock cargo doors; use 5th wheel lockWhen in doubt, call 911

Hazardous Materials Regulations (HMR)

Regulated by US DOT 49 CFR §100-180

Enforced by Pipeline and Hazardous Materials Safety Administration (PHMSA)

Regulations apply to: Shippers, handlers, transporters,

packaging manufacturers, testers, etc.

All modes (highway, air, rail, water) Domestic transportation of hazmat

Registration Part 107 Subpart G

Applicability

Exceptions

General requirements

Fees

Recordkeeping

Training §172.700 Applies to all hazmat employees Trained before they perform hazmat function and

must be tested Training shall include:

General awareness Function-specific Safety – self-protection/emergency response Security Modal-specific (highway, rail, air, etc.)

Recurrent training – every three (3) years Recordkeeping required

Record of Training§172.704(d)

Record must include: Hazmat employee’s name Most recent completion

date Description, copy or location

of training materials Name and address of trainer Certification of training and

testing

General Requirements§171.2

Responsibility

No person shall offer or accept a hazardous material for transportation in commerce...unless it’s legal!

HMR per 49 CFR Part 107 – Program Procedures

Part 171 – General Information, Definitions

Part 172 – Hazmat Table, Appendices A & B, Markings, Labels, Shipping Papers, Placards, Training, Emergency Information, and Security

Part 173 – Shipper’s Requirements

Part 177 – Carriage by Public Highway

Part 178 – Specifications for Packages

Part 180 – Cargo Tank Inspections

Definitions & Abbreviations§171.8

Hazardous Material Hazard Class Packing Group Bulk and Non-bulk Performance-oriented Packaging

(POP) Combination Packaging

Definitions & Abbreviations§171.8

Limited Quantity Consumer Commodity Hazardous Substance Marine Pollutant Hazmat Employee Person

Bulk Package

Liquids - Maximum capacity over 119 gallons

Solids - Maximum net capacity over 882 pounds and maximum capacity over 119 gallons

Gases - Water weight capacity over 1,000 pounds

IBC (Tote)

Composite IBCs

Flexible IBC

Cargo Tank

Tank Car

Steel Drum (Pail)

Plastic Jerrican (Pail)

Plastic Drum

Steel Drum

Hazard Classes & DivisionsCLASS 1EXPLOSIVES1.1, 1.2, 1.3, 1.4, 1.5, 1.6

CLASS 2GASES2.1 (FLAMMABLE)2.2 (NONFLAMMABLE)2.3 (POISON)

CLASS 3FLAMMABLE LIQUID

CLASS 4FLAMMABLE SOLIDS4.1 (FLAMMABLE SOLIDS)4.2 (SPONTANEOUSLY COMBUSTIBLE)4.3 (DANGEROUS WHEN

WET)

CLASS 5OXIDIZING SUBSTANCESOXIDIZING SUBSTANCES5.1 (OXIDIZER)5.1 (OXIDIZER)5.2 (ORGANIC PEROXIDES)5.2 (ORGANIC PEROXIDES)

CLASS 6CLASS 6POISONSPOISONS6.1 (POISON)6.1 (POISON)6.2 (INFECTIOUS)6.2 (INFECTIOUS)

CLASS 7RADIOACTIVERADIOACTIVE

CLASS 8CLASS 8CORROSIVESCORROSIVES

CLASS 9CLASS 9MISCELLANEOUSMISCELLANEOUS

Combination Package

Consumer Commodity

DOT Hazmat Definition 49 CFRA substance or material that is capable of posing anunreasonable risk when transported in commerce.This term includes:

Substances (RQ)

Wastes

Marine pollutants

Elevated temperature

Packing Groups (PG)

PG I - Great danger

PG II – Medium danger

PG III – Minor danger

Hazardous MaterialsShipping Procedure

Classify materialClassify material Select packagingSelect packaging Communicate hazardCommunicate hazard

Shipping papersShipping papers Markings/labelsMarkings/labels PlacardsPlacards

Provide emergency response Provide emergency response information and phone numberinformation and phone number

Load and segregate on vehicleLoad and segregate on vehicle

Classify materialClassify material Select packagingSelect packaging Communicate hazardCommunicate hazard

Shipping papersShipping papers Markings/labelsMarkings/labels PlacardsPlacards

Provide emergency response Provide emergency response information and phone numberinformation and phone number

Load and segregate on vehicleLoad and segregate on vehicle

Determining Hazard Classification

Definition starts in Part 171.8; then follow instructions

Origin of information = Material Safety Data Sheet (MSDS)

UN Marking

4G/Y1.4/S/98USA/+BB1053

Performance-oriented Packaging (POP)

POP Packaging Marking (Combination Packaging)

un

4G/Y15/S/97USA/+AJOUnited

NationsSymbol

PackagingIdentification

Code

PGPerformance

Level

Gross Weight

Solids/Inner Packaging

Year of Manufacture

Country of Authorization

Manufacturer ID

General Packaging Requirements §173.24

Bulk and non-bulk

New and reconditioned

Specification andnon-specification packaging

Must survive the transportation:

Must NOT leak

Withstand impact

No release of gases

Additional Requirements §173.24(a)

Inner closures upright

Reduce friction

Secure andcushioning

No nails, staplesprotruding interior

Withstand vibration

HMTHAZMATTABLE

Appendix A Appendix B

Appendix A-EPA Hazardous Substances

o Technical and chemical nameso RQ per package; see definitions for mixtures & solutions

Appendix B-Marine Pollutantso Technical and chemical nameso “PP” for severe marine pollutanto > 1% for SMP, 10% for other than SMP

Hazardous Substance

Listed on “Appendix A” Is in a quantity in one (1) package

equal to or more than the RQ When in a mixture:

Equals or exceeds the concentrations corresponding to the material’s RQ as shown in PPM table(i.e., 1# RQ = 20 ppm)

Hazardous SubstancesAppendix A to §172.101Table 1 – Hazardous Substances other than Radionuclides

Hazardous Substances Reportable Quantity (RQ)Pounds (Kilograms)

AcenaphtheneAcetic AcidAcetoneAldrinCupric tartrateD001

100 (45.4)5000 (2270)5000 (2270)

1 (0.454)100 (45.4)100 (45.4)

5000 (2270)5000 (2270)AcetoneAcetone

Marine Pollutant(Listed on Appendix B)

Is a marine pollutant if in a 10% or 1% solution ormixture?

Marine PollutantsS.M.P.

Carbofuran………..

Carbon tetrabromide

Carbophenothion

Carbon tetrachloride

Cartap hydrochlorideChlordane

………..………..

PP...…..………..PP...…..

Marine PollutantsAppendix B to §172.101

Shipping Papers§172.200

Each person who offers a hazardous material for transportation shall describe it in the prescribed manner.

Basic Description§172.202

Proper shipping name (Column #2)

Hazard class or division (Column #3)

ID number (Column #4) Packing group (Column

#5)

Acetone, 3, UN1090, PG II Total quantity

No. of Description of articles Hazard I.D. Packing Weight Class Labels packages Class Number Group

HM

This is t certify that the above-named materials are properly classified, described, packaged, marked and labeled and are in proper condition for transportation according to the applicable regulations of the Department of Transportation. Per________________________________________

Emergency Telephone Number:_______________________

STRAIGHT BILL OF LADINGCarrier_____________ SCAC._________ Carrier’s No.______

6/17/05

AcetoneX 3 UN1090 II

Joe Shipper800-Cal-Help

55 gal

General Entries§172.201 Contents (hazardous and non-

hazardous shipments)

Descriptions legible and printed (manually or mechanically) in English

No unauthorized codes or abbreviations

Package description

Contents§172.201(a)(1)(i-iii)

Hazmat and non-hazmat can go on thesame shipping paper if:

Hazmat listed first; or

Contrasting color; or

Identified with “X” or “RQ” in hazmat column.

No. of Description of articles Hazard I.D. Packing Weight Class Labels packages Class Number Group

HM

This is to certify that the above-named materials are properly classified, described, packaged, marked and labeled and are in proper condition for transportation according to the applicable regulations of the Department of Transportation. Per________________________________________

Emergency Telephone Number:_______________________

STRAIGHT BILL OF LADINGCarrier_____________ SCAC._________ Carrier’s No.______

6/17/05

Acetone 3 UN1090 II 15 gal.X

Joe Shipper800-Cal-Help

Acetic acid solution 8 UN2790 II 55 gal.X

Paper towels 30 lbs.

Optional Sequence§172.202(b)

UN2789, Acetic acid, glacial, 8(3), PG II

Hazardous Waste Manifest Information *EPA form 8700-22 Generator EPA ID # and

state # Five (5) digit manifest # generators:

Name Address Phone #

Transporter name, federal ID # and state ID #

Treatment, storage and disposal facility: Name Address EPA ID # State ID # Phone #

Shipper’s Certification§172.204

Who Each person who offers

Exceptions Cargo tank supplied by carrier Private carriage Return of empty tank car

Signatures Legibly signed by employee/agent of

shipper Signed manually or mechanically

Signatures

Non-bulk Package Marking and Labeling

Marking Non-bulk§172.301

Shipper shall MARK with: Proper shipping name ID number Technical name (if needed) Consignee’s or consignor’s name

and address Exemption (DOT-E)?ACETONE UN1090

TO:

Large Quantities of Hazmat inNon-bulk Packages §172.301(a)(3)

Loaded at one (1) facility 8,820 pounds (4,000 kg) or more All hazmat has same proper shipping

name and ID number Transport vehicle/freight container

contains no other materials; hazmat or not

Transport vehicle/freight container must be

marked with ID number on both sides and

each end

1993

Marking Requirements§172.304

Durable and in EnglishPrinted or affixedColor to contrast with backgroundLocated away from other markings

ACETONE UN1090

ORM-D Mark§172.316

Marking Hazardous Waste Containers

Must affix WASTE MARKER on drums:

EPA ID number Accumulation start

date Proper shipping

name UN/NA ID number EPA waste code Generator’s name

and address

Additional non-bulk markings?

§172.313 – Poison w/SP notation Mark with “Inhalation Hazard”

§172.322 – Marine pollutant via water Mark with “Marine Pollutant”

§172.324 – Hazardous substance Mark with name of substance and

“RQ”

Marking Bulk Packages§172.302 Identification number marking:

Each side & each end >1000 gals Two (2) opposing sides =< 1000 gals

How (§172.332): Orange panel White square-on-point

• Materials not needing placards Placards

1993 1993

Cargo Tank Marking

Additional Markings – Bulk

§172.313 – Poisonous Mark “Inhalation Hazard” on two (2) opposing

sides

§172.322 – Marine Pollutant Mark “Marine Pollutant”

• Two (2) sides/ends if less than 1,000 gallons• Four (4) sides if 1,000 gallons or more

§172.325 – Elevated Temperature Mark “HOT” on two (2) opposing sides

§172.326 – Portable Tanks Shipping name on two (2) opposing sides Name of owner Identification number (if not visible)

Marking Bulk§172.302

Exemption packagings: Mark with “DOT-E” & number

1203DOT-E 151

Labeling§172.400 Shipper’s responsibility

Label each non-bulk package

Label each bulk package or portable tank unless placarded

Label each overpack, freight container or unit load device of less than 18 cubic meters (640 cubic feet)

Placement of Labels§172.406

Printed on or affixed to

Same surface as the proper shipping name and ID

Multiple labels within6” of each other

Contrast with background

AcetoneUN1090

Additional Requirements§172.402

Display of class number: Primary hazard First code listed in

Column #6 of HMT Display in lower

corner Subsidiary hazards Second code(s) listed

in Column #6 of HMT Display of class

number optional (until 10/01/05)

Emergency Response Information §172.602

Info needed, seven (7) items Presented on:

Shipping paper MSDS ERG

Maintenance of information: Carriers just like shipping

papers Facility operators just

like MSDS Telephone Number

(§172.604): On shipping paper Staffed while in transit

Must be included with all applicable shipments!

Carriage by HighwayPart 177

Driver training Shipping paper

review, accessibility, and retention

Loading, unloading, and securement

Segregation

Loading & Unloading §177.834*Carriers and Shippers (§173.30) are both responsible Secure all packages Segregate No smoking Keep fire away Set brake Prevent relative motion

between containers Vehicle attendance

Example of Proper Securement

1.61.51.3 1.4 2 4 5

7

5

1

Class

2

3

4

6

8

876431.11.2

1.3

1.4

1.5

1.6

2.1

2.2

2.3

2.3

POISONOUS GASZONE A

POISONOUS GASZONE B

3

4.1

4.2

4.3

5.1

5.2

6.1

7

8

EXPLOSIVES

EXPLOSIVES

EXPLOSIVES

VERY INSENSITIVEEXPLOSIVES

EXTRE INSENSITIVEEXPLOSIVESFLAMMABLEGASNONFLAMMABLEGAS

FLAMMABLELIQUIDFLAMMABLESOLIDSPONTANEOUSLYCOMBUSTIBLE

DANGEROUS WHEN WET

OXIDIZERS

ORGANICPEROXIDE

POISONOUS LIQUIDS PGI ZONE A

RADIOACTIVEMATERIALS

CORROSIVELIQUIDS

***** ***** ***** **

*** *****

0 0 0 0 0 0 0

0000

1.11.2

00 0 0 0 0 0 0 0 0

000

00000

0

0

0

0

000

0 0 0 0 0

00

0

X X X X X X X X X X X X XXXXXXXXXXX

X X X X X X X X X XX X X

X XXX

XXXXXXXXX

X

X

XXXXX

XXX

XXXXXXXXXXXXX X X X

XXXXXXXX X

XXXXX

XXXXX

X X X X X X X X

X

X

HAZARDOUS MATERIALS LOAD AND SEGREGATION CHART

Placards Not Required§172.500(b)

Infectious substances

ORM-D

Limited quantities

Small quantities

Combustibles non-bulk

Placarding§172.500

Shipper/carrier are both responsible Placards must be offered to

transporter by shipper per §172.506 Must be maintained by transporter

upon departure

Prohibited/PermissivePlacarding §172.502

Material offered/transported must be hazmat

Placard displayed represents hazard Conforms with requirements Any sign/device that could be

confused for placard as of 10/1/01

General Requirements§172.504

Must placard each: Bulk load Freight containers going

marine shipment Unit load device going

by air Transport vehicle with

IBC/totes on board Railcar

Containing any quantity!

Placards – 1,001 Pound Exception §172.504(c)

Transport vehicles or freight containers:

Containing less than 1,001 pounds aggregate gross weight of Table 2 non-bulk items:

Excepted from placarding

Dangerous Placard§172.504(b) Transport vehicle, freight container,

etc., containing non-bulk packages of: Two (2) or more items from Table

2 may use “Dangerous” Unless:

2,205 pounds (1,000 kg) or more of one (1) category is loaded at one (1) location

Effective 10/1/98North America only

Visibility and Display§172.516 Four (4) are required Visible from direction it faces Securely attached Clear of ladders, doors, tarps, etc. No dirt or water directed onto from wheels Displayed horizontally Maintained by carrier Contrast to background Holders not to obscure

Hazmat Incidents§171.15

Carriers, an immediate notice is required if: A person is killed A person requires

hospitalization Estimated damage exceeds

$50,000

As a result of transporting (loading, unloading temporary storage of) hazmat/hazardous waste.

Report To:800-424-8802

(NATIONAL RESPONSE CENTER)

General Hazmat Exceptions Part 173

Small Quantities§173.4

Agriculture§173.5

Materials of Trade §173.6

Hazardous MaterialsCargo Tanks

Must have manufacturer’s specification plate

Must have these inspections: External visual – every year Internal visual – every 5 years Leakage – every year Pressure – every 5 years Thickness – every 2 years

Hazardous MaterialsCargo Tanks

Over 1,000 gallons requires CDL endorsement

Load has higher center of gravity; more prone to rollover

Surge may occur (movement of liquid within the tank)

Outage may occur (expansion of product due to temperature change)

Hazardous MaterialShipping Procedure

Identify/classify material Select/verify packaging Communicate hazard

Shipping papers Markings Labels Placards

Properly load Safely transport

THANK YOU !

John Backowski602-850-6002

jbackowski@aztrucking.com

John Backowski602-850-6002

jbackowski@aztrucking.com