final analytical report

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYRegion 3 Environmental Science Center

Analytical Services & Quality Assurance Branch701 Mapes Road

Fort Meade, Maryland 20755-5350

Final Analytical Report

Site Name

Sample Collection Date(s).,

eontact...., ........

Report Date

Project #..., .„..,„,.

Work Orders.,......,..;... ;..„..;

Consolidated Pharmaceuticals

06/19/07 11:20-06/19/07 13:25

Greg Ham

09/06/07 16:54

DAS R32769

0706024

Analyses included in this report:

Alcohols by EPA 8015DIgnitability by 1010VOCs based on EPA 5030B/8260B

Conosiviry by limited SW846Percent Water by SW846 9001

Approved for Release.

illative 0706024 FINAL 090607165' of 29

AR100089




Site Name: Consolidated Pharmaceuticals Project #: DAS R32769

Report Narrative

Ignitability by Method 1010

Sample 0706024-05. Tank 110, was not analysed due to the concern that the high concentration of HC1 or other acid woulddamage the Pensky-Martens apparatus.

Samples from tanks 101 and 113 (0706024-04 and 0706024-06, respectively) ignited at the first application of the flame and mayactually have a lower flash point.

Corrosivity and % water

Samples from station locations Tank 109 and Tank 110 were qualified with a I qualifier since the matrix of the sample is mostlikely interfering with the reaction that takes place in the percent water test. The values are expected to be lower.

Volatile Organic Analyses (VOC)

VOC testing was performed as screening to identify the high concentration organic constituents in two samples, Tank 113 andTank 117. Sample results are flagged J, estimated, because the samples were analyzed outside the 14 day recommended holdingtime and one sample, 0706024-06, Tank 113, was subsampled from ajar with headspace. This caused greater uncertainty in thecalculation of the final concentration, such as sample 0706024-06, Tank 113, with compounds totaling greater than 100%. Thissample was observed to be primarily acetone. The samples were analyzed at very high dilutions which did not allow for theexamination for tentatively identified compounds.

0706024 FINAL 09 06 07 1654

of29

AR100090





ANALYTICAL REPORT FOR SAMPLES

Station ID

SSTank

Tank 109

Tank 117

Tank 101

Tank 110

Tank 113

Laboratory H)

0706024-01

0706024-02

0706024-03

0706024-04

0706024-05

0706024-06

Matrix

Waste

Waste water

Wastewater

Waste

Waste

Waste

Date Sampled

06/19/07 13:25

06/19/0711:25

06/19/0711:50

06/19/0711:20

06/19/0711:35

06/19/0711:45

Date Received

06/26/07 13:00

06/26/07 13:00

06/26/07 13:00

07/03/07 09:48

07/03/07 09:48

07/03/07 09:48

0706024 FINAL 09 06 07 1654 of29AR100091

^B*IV,<y *j» •UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 3 Environmental Science CenterAnalytical Services & Quality Assurance Branch

701 MapesRoadFort Meade, Maryland 20755-5350


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LABORATORY COPY

0706024 FINAL 09 06 07 1654 of29AR100092


Analytical Services & Quality Assurance Branch701 MapesRoad


Site Name: Consolidated Pharmaceuticals Project #: DASR32769

US£PA Contract Ufeor̂ wy Program

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3'1418182i3-062607-0001- L AftflRATORY TflPYfc^^WV^IVrt I \ff\ I V»Vfr I

0706024 FINAL 09 06 07 1654 of29

AR100093





Lab ID: 0706024-01

Batch: BG73101

Sample Type: Waste

Station ID: SS Tank

Date Collected: 06/19/2007

Wet Chemistry

Targets

Analyte

Result Analyte

% by Volume Qualifiers

Quantitation

Limit Dilution Prepared Analyzed Method/SOP#

Percent Water 14 1 07/31/07

Classical Chemistry Parameters

Targets

08/01/07 13:50 EPA 9001

Analyte

Result Analyte

pH Units Qualifiers

Quantitation


PH

Ignitability

12.0 K 1 07/31/07

Physical Parameters by APHA/ASTM/EPA Methods

Targets

08/01/07 13:50 SDWA 846

Analyte

Result

°C

Analyte

Qualifiers

Quantitation

Limit Dilution Prepared Analyzed MethodVSOP*

No Flash. 07/06/07 07/06/07 12:20 ASTM D-93

0706024 FINAL 09 06 07 1654

of 29AR100094

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 3 Environmental Science Center

Analytical Services & Quality Assurance Branch701MapesRoad


Site Name: Consolidated Pharmaceuticals Project#: DAS R32769

Lab ID: 0706024-02

Batch: BG73101

Sample Type: Wastewater

Station ID: Tank 109


Wet Chemistry

Targets

Anatyte

Result Analyte


QuantitarJon


Percent Water 100 ] 1 07/31/07


Targets

08/01/07 13:50 EPA 9001

Analyte

Result Analyte

pH Units Qualifiers

Quantitation

Limit Dilution Prepared Analyzed Method/SOPfl

pH 6.9 K 1 07/31/07

Physical Parameters by AFHA/ASTM/EPA Methods

Targets

08/01/07 13:50 SDWA 846

Analyte

Result Analyte

°C Qualifiers

Quantitation

Limit Dilution Prepared Analyzed Method/SOPff

Ignitability No Flash. 1 07/06/07 07/06/07 12:30 ASTM D-93

0706024 FINAL 09 06 07 1654 of29AR100095


Analytical Services & Quality Assurance Branch701MapesRoad



Lab ID: 0706024-03

Batch: BG71906


Analyte

Methanol

Ethanol

1-Propanol

1-Butanol

2-Butanol

Analyte

Percent Water

Result

mg/kg

U

U

U

U

U

Result

% by Volume

71

Analyte

Qualifiers

U

U

U

U

U

Analyte

Qualifiers

Alcohols

Targets

Quantitation

Limit

200

200

200

200

200

Wet ChemistryTargets

Quantitation

Limit



Dilution

,

1

1

1

1

Dilution

I

Prepared

07/19/07

07/19/07

07/19/07

07/19/07

07/19/07

Prepared

07/31/07

Analyzed

07/19/0720:08

07/19/07 20:08

07/19/0720:08

07/19/07 20:08

07/19/0720:08

Analyzed

08/01/07 13:50

Method/SOP#

EPA8015D/R3QA203

EPA8015D/R3QA203

EPA 8015D/R3QA203

EPA8015D/R3QA203

EPA8015D/R3QA203

Method/SOP#

EPA 9001


Analyte

pH

Result

pH Units

5.1

Analyte

Qualifiers

K

Targets

Quantitation

Limit Dilution

1

Prepared

07/31/07

Analyzed

08/01/07 13:50

Method/SOPS

SDWA 846

Volatile Organic Compounds

Analyte

Acetone

Benzene

Bromobenzene

Bromochloromethane

Bromodichloromethane

Bromoform

Bromomethane

2-Butanone

sec-Butylbenzene

tert-Butylbenzene

n-Butylbenzene

Result

ug/L

177000000

U

U

U

U

U

U

UU

U

U

Analyte

Qualifiers

J

J

J

J

J

J

J

J

J

J

J

Targets

Quantitation

Limit

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

Dilution

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

Prepared

08/27/07

OX/27/01

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

Analyzed

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

Method/SOPff

R3QA210

R3QA2IO

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

0706024 FINAL 09 06 07 1654 of 29

AR100096

:^D^UNITED STATES ENVIRONMENTAL PROTECTION AGENCY


701 MapesRoadFort Meade, Maryland 20755-5350

Site Name: Consolidated Pharmaceuticals Project* DASR32769

Lab ID: 0706024-03

Batch: BI70402



Targets (Continued)

Analyte

Carbon disulfide

Carbon Tetrachloride

Chlorobenzene

Chlorodibromomethane

Chloroethane

Chloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

Cyclohexane

1 ,2-Dibromo-3-chloropropane

1 ,2-Dibromoethane (EDB)

Dibromomethane

1 ,2-Dichlorobenzene



Dichlorodifluoromethane

1,1-Dichloroethane

1,2-Dichloroethane

1,1-Dichloroethene

cis- 1 ,2-Dichloroethene

trans- 1 ,2-Dichloroethene

1 ,2-Dichloropropane


2,2-Dichloropropane

1,1-Dichloropropene

cis- 1 ,3-Dichloropropene

trans- 1 ,3-Dichloropropene

Ethylbenzene

Freon 113

Hexachlorobutadiene

2-Hexanone

.Isopropylbenzene

p-Isopropyltoluene

Result

ug/L

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

13

U

U

Analyte

Qualifiers

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

Quantitation

Limit

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

Dilution

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000



Prepared

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

osm/OT08/27/07

08/27/07

Analyzed Method/SOPtf

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/0716:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16.52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

OS/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/0716:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/17/07 16-.52

08/27/07 16:52

08/27/07 16:52

0706024 FINAL

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210 v

R3QA2IO

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA2AQ

R3QA210

R3QA210

090607 1654 of 29

AR100097


Analytical Services & Quality Assurance Branch

701 Mapes RoadFort Meade, Maryland 20755-5350


Lab ID:

Batch:

Sample Type:

0706024-03

BI70402

Wastewater




Targets (Continued)

Analyte

Methyl Acetate

Methylcyclohexane

Methyl-tert-butyl ether

Methylene Chloride

4-Methyl-2-pentanone

Naphthalenen-Propylbenzene

Styrene

1 , 1 ,2,2-Tetrachloroethane

1,1,1 ,2-Tetrachloroethane

Tetrachloroethene

Toluene

1 ,2,3-Trichlorobenzene


1,1,1-Trichloroethane

1 , 1 ,2-Trichloroethane

Trichloroethene

Trichlorofluoromethane

1 ,2,3-Trichloropropane

1 ,2,4-Trimethylbenzene


Vinyl acetate

Vinyl chloride

m-Xylene/p-Xylene

o-Xylene

Result

ug/L

U

U

U

17900000

U

U

U

U

U

U

U

U

U

U

U

U

U

U

UU

U

U

U

U

U

Analyte

Qualifiers

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

Quantitation

Limit

5000000

5000000

5000000

5000000

5000000

5000000

5000000

10000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

5000000

10000000

10000000

Dilution

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

1000000

Prepared

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

. 08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

Analyzed

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

08/27/07 16:52

OS/27101 16:52

08/27/07 16:52

08/27/07 16:52

OS/21/01 16:52

08/27/07 16:52

08/27/07 16:52

OS/21/01 16:52

OS/21/01 16:52

OS/21/01 16:52

OS/21/01 16:52

OS/21/01 16:52

08/27/07 16:52

08/27/07 16:52

OS/21/01 16:52

OS/21/01 16:52

08/27/07 16:52

08/27/07 16:52

OS/21/01 16:52

Memod/SOPtf

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA2IO

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

Surrogates

Analyte

Surrogate: 4-Bromofluorobenzene

Surrogate: 1 ,2-Dichloroethane-d4

Surrogate: Toluene-d8

Result

ug/L

20.03

18.36

19.91

Analyte

Qualifiers %Recovery

100 %

92%100 %

%Recovery

Limits

86-115

76-114

88-110

Prepared

08/27/07

08/27/07

08/27/07

Analyzed

08/27/07 16:52

OS/21/01 16:52

08/27/07 16:52

Method/SOP#

R3QA210

R3QA210

R3QA210

0706024 FINAL 090607 1654 of 29

AR100098





Lab ID: 0706024-03

Batch: BG70506





Targets

Analyte

Ignitability

Result

°C

20.2

Analyte

Qualifiers

Quantitation

Limit Dilution

1

Prepared

07/06/07

Analyzed

\07/06/07 12:45

Method/SOP#

ASTM D-93

0706024 FINAL 09 06 07 1654

of29AR100099





Lab ID: 0706024-04

Batch: BG73101

Sample Type: Waste



Wet Chemistry

Targets

Analyte

Result Analyte


Quantitation


Percent Water 38 1 07/31/07


Targets

08/01/07 13:50 EPA 9001

Analyte

Result Analyte

pH Units Qualifiers

Quantitation


3.8 1 07/31/07 08/01/07 13:50 SDWA 846


Targets

Analyte

Result Analyte

°C Qualifiers

Quantitation


Ignitability 19.2 1 07/06/07 07/06/07 13:21 ASTM D-93

0706024 FINAL 09 06 07 1654 of 29AR100100





Lab ID: 0706024-05

Batch: BG73101

Sample Type: Waste



Wet Chemistry

Targets

Analyte

Result Analyte


Quantitation


Percent Water 100 I 1 07/31/07


Targets

08/01/07 13:50 EPA 9001

Analyte

Result Analyte

pH Units Qualifiers

Quantitation

Limit Dilution Prepared Analyzed Method/SOPtf

pH -0.3 1 07/31/07 08/01/07 13:50 SDWA 846

0706024 FINAL 09 06 07 1654 of 29

AR100101





Lab ID: 0706024-06

Batch: BG73101

Sample Type: Waste

Wet Chemistry

Targets

Analyte

Percent Water

Result

% by Volume

9.5

Analyte

Qualifiers

Quantitation

Limit Dilution

1



Prepared

07/31/07

Analyzed

08/01/07 13:50

Method/SOPff

EPA 9001


Analyte

PH

Result

pH Units

6.7

Analyte

Qualifiers

K

Targets

Quantitation

Limit Dilution

1

Prepared

07/31/07

Analyzed

08/01/07 13:50

Method/SOP#

SDWA 846


Analyte

Acetone

Benzene

Bromobenzene

Bromochloromethane


Bromoform

Bromomethane

2-Butanone

sec-Butylbenzene

tert-Butylbenzene

n-Butylbenzene

Carbon disulfide


Chlorobenzene


Chloroethane

Chloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

Cyclohexane

Result

ug/L

i/52qooqooouuuuuuuuuuuuuuuuuuuu

Analyte

Qualifiers

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

J

Targets

Quantitation

Limit

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

100000000

Dilution

2E+07

2E+07

2E+07

2E+07

2E+07

2E-K17

2E+07

2E+07

2E+07

2E+07

2E+07

2E-KJ7

2E+07

2E+07

2E+07

2E-KJ7

2E+07

2E+07

2E+07

2E-KJ7

2E+07

Prepared

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

Analyzed

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/0716:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

Method/SOP#

R3QA210

R3QA210

R3QA210

R3QA210

R3QA2IO

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA2IO

R3QA210

R3QA210

R3QA210 _

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

0706024 FINAL 09 06 07 1654

of 29AR100102





Lab ID: 0706024-06

Batch: BI70402

Sample Type: Waste


Targets (Continued)

Analyte

l,2-Dibromo-3-chloropropane

1,2-Dibromoethane (EDB)

Dibromomethane





1 , 1 -Dichloroe thane

1,2-Dichloroe thane

1 , 1 -Dichloroe thene

cis- 1 ,2-Dichloroethene




2,2-Dichloropropane

1 , 1 -Dichloropropene



EthylbenzeneFreon 113

Hexachlorobutadiene

2-Hexanone

Isopropylbenzene

p-Isopropyltoluene

Methyl Acetate

Methylcyclohexane


Mcthylcne Chloride


Naphthalene

n-Propylbenzene

Styrene


1 , 1 , 1 ,2-Tetrachloroethane

Tetrachloroethene

Result Analyte

ug/L Qualifiers

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U J

U JU J

U J

U J

U J

U J

U J

U J

U J19800,000 J

U J

U J

U J

U JU J

U J

U J

Quandtation

Limit

100000000

100000000100000000

100000000

100000000100000000100000000100000000100000000

100000000

100000000

100000000

100000000

1000000001 00000000

100000000100000000

100000000

100000000100000000

100000000100000000100000000

100000000

100000000100000000100000000100000000100000000

100000000

100000000200000000100000000100000000

100000000

Dilution

2E+07

2E+07

2E+07

2E+07

2E+07

2E407

2E407

2E+07

2E+07

2E407

2E+07

2E+07

2E407

2E+07

2E+07

2E+07

2E+07

2E+07

2E407

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E-K17

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E-K17



Prepared

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

Analyzed

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

0706024

Method/SOPfl

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

FINAL 09 06 07 1654

of 29AR100103





Lab ID: 0706024-06

Batch: BI70402

Sample Type: Waste


Targets (Continued)

Analyte

Toluene



1 , 1 , 1 -Trichloroethane

1 , 1 ,2-TricWoroethane

Trichloroethene


1 ,2,3-Trichloropropane



Vinyl acetate

Vinyl chloride

m-Xylene/p-Xylene

o-Xylene

Analyte


Surrogate: 1, 2-Dichloroethane-d4


Result

ug/L

U

U

U

U

U

U

U

U

U

U

U

U

U

U

Result

ug/L

19.65

18.31

20.01

Analyte Quantitadon

Qualifiers Limit

J 100000000

J 100000000

J 100000000J 100000000J 100000000

J 100000000J 100000000

J 100000000J 100000000

J 100000000

J 100000000

J 100000000

J 200000000

J 200000000

Surrogates

Analyte

Qualifiers %Recovery

98%

92%

100 %

Dilution

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E+07

2E407

2E+07

2E407

2E-HH

2E+07

2E-K17

2E+07

%Recovery

Limits

86-115

76-114

88-110

Physical Parameters by APHA/ASTM/EPA

Analyte

Ignitability

Result

°C

20.2

Targets

Analyte Quandtation

Qualifiers Limit Dilution

1



Prepared

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

08/27/07

Prepared

08/27/07

OS/27/07

OS/27/07

Methods

Prepared

07/06/07

Analyzed

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

08/27/07 16:03

Analyzed

OS/27/07 16:03

OS/27/07 16:03

OS/27/07 16:03

Analyzed

07/06/07 13:28

Method/SOP#

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA210

R3QA2IO

R3QA210

R3QA210

R3QA2IO

R3QA210

R3QA210

Method/SOP#

R3QA210

R3QA210

R3QA2IO

Method/SOPff

ASTM D-93

0706024 FINAL 09 06 07 1654 of 29AR100104





Lab ID: 0706024-03 Station ID: Tank 117

Sample Type: Wastewater Date Collected: 06/19/2007

Tentatively Identified Compound (TIC) Report

Result Analyte Retention Analyzed Method/SOP#

CAS Number Compound ug/L Qualifiers Time

0706024 FINAL 09 06 07 1654

of 29AR100105





Lab ID: 0706024-06 Station ID: Tank 113

Sample Type: Waste Date Collected: 06/19/2007

Tentatively Identified Compound (TIC) Report

Result Analyte Retention Analyzed Method/SOP#

CAS Number Compound ug/L Qualifiers Time

0706024 FINAL 09 06 07 1654 of 29AR100106





QCDataAlcohols - Quality Control

Analvte Result

Quantitation

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPDRPD

Limit Notes

Batch BG71906 - Alcohols

Blank (BG71906-BLK1)

Methanol

Ethanol

1-Propanol

1-Butanol

2-Butanol

U

U

uuu

Prepared: 07/19/07 17:18 Analyzed: 07/19/07 19:19200 ing/kg

200

200

200

200

U

U

U

U

U

0706024 FINAL 09 06 07 1654

of 29AR100107

"%





QC DataAlcohols - Quality Control

AnaJvte Result

QuanbtatioD

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

Limit Notes


LCS (BG71906-BS1) Prepared: 07/19/07 17:18 Analyzed: 07/19/07 19:35

Mcthanol

Ethanol

1-Propanol

l-Butanol

2-Butanol

1060

1070

1070

1000

1030

200 mg/kg 1000.0

200 " 1000.0

200 " 1000.0

200 " 1000.0

200 " 1000.0

106 70-130

107 70-130

107 70-130

100 70-130

103 70-130

0706024 FINAL 090607 1654

of 29AR100108






Analvte Result

Quantitation

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPDRPD

Limit Notes


LCS(BG71906-BS2) Prepared: 07/19/07 17:18 Analyzed: 07/19/07 19:52

Methanol

Ethanol

1-Propanol

1-Butanol

2-Butanol

236

243

241

211

176

200

200

200

200

200

mg/kg11

"11

»

200.00

200.00

200.00

200.00

200.00

118

122

120

105

88

70-130

70-130

70-130

70-130

70-130 J

0706024 FINAL 09 06 07 1654 of 29AR100109


Region 3 Environmental Science Center


701 Mapes Road



QC Data

Alcohols - Quality Control

Analvte Result

QuantitadonLimit Units

SpikeLevel

SourceResult

%REC%REC Limits RPD

RPDLimit Notes


Matrii Spike (BG71906-MS1) Source: 0706024-03 Prepared: 07/19/07 17.18 Analyzed: 07/19/07 20:24

Methanol

Ethanol

1-Propanol

1-Butanol

2-Butanol

6980

2200

670

896

763

192 mg/kg

192

192

192

192

961.54

961.54

961.54

961.54

961.54

U

U

U

U

U

726

229

70

93

79

70-130

70-130

70-130

70-130

70-130

A

A

0706024 FINAL 09 06 07 1654 of 29

AR100110



701 MapesRoad



QC Data

Alcohols - Quality Control

QuantitationAnalvte Result Limit Units

SpikeLevel

SourceResult %REC

%RECLimits RPD

RPDLimit Notes


Matrix Spike Dup (BG71906-MSD1)

Methanol

Ethanol

1 -Propanol

l-Butanol

2-Butanol

Source:

5280

1780

630

852

755

0706024-03

189 mg/kg

189

189

189

189

Prepared

943.40

943.40

943.40

943.40

943.40

07/19/0717

U

U

U

U

U

1 8 Analyzed: 07/1 9/07 20:40

559

188

67

90

80

70-130

70-130

70-130

70-130

70-130

26

20

4

3

0.9

25

25

25

25

25

A

A

A

0706024 FINAL 09 06 07 1654 of 29AR100111






Analvte Result

Quandtadon

Limit Units

Spike

Level

Source

Result %REC

%REC

Limits RPD

RPD

Limit Notes

QC DataClassical Chemistry Parameters - Quality Control

Analvte

Quantitadon

Result Limit Units

Spike Source %REC

Level Result %REC Limits RPD

RPD

Limit Notes

Batch BG73101 - NO PREP

Duplicate (BG73101-DUP1) Source: 0706024-03 Prepared: 07/31/07 11:02 Analyzed: 08/01/07 13:50

PH

Reference (BG73101-SRM1)

5.0 pH Units 5.1 0.7 200

Prepared: 07/31/07 11:02 Analyzed: 08/01/07 13:50

pH 6.4 pH Units 6.6000 98 90-110

0706024 FINAL 09 06 07 1654 of 29

AR100112





QC DataVolatile Organic Compounds - Quality Control

QuanutationAnalvte Result Limit

Spike Source %REC RPDUnits Level Result %REC Limits RPD Limit Notes

Batch BI70402 - VOC Purge and Trap

Blank (BI70402-BLK1)

Acetone

Benzene

Bromobenzene

3romochloromethane


3Fomofbrm

Bromometnane

2-Butanone

sec-Butylbenzene

tert- Buty Ibenzene

n-Butylbenzcne

Darbon disulfide


[?hloro benzene

^hlorodibromomethane

^hloroemane

Dhloroform

Chloromethane

2-Chlorotoluene

4-Chlorotoluene

lyclohexane



Dibromomethane



,4-Dichlorobenzenc

3ichlorodifluoromethane

1 , 1 -Dichloroethane

1 ,2-Dichloroethane

1,1-Dichloroethene

cis-l,2-Dichloroethene



,3-DichIoropropane

2,2-Dichloropropane

1,1-Dichloropropene


trans-l,3-Dichloropropene

^thylbenzene

Freon 113

HexachlorobuUdiene

2-Hexanone

Isopropylbenzene

)-lsopropyltoluene

0.7

U

U

U

U

U

0.2

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

UU

UU

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.05.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

Prepared: 08/27/07 09:00 Analyzed: 08/27/07 12:47

ug/L J11

"

••

"

"

J••11

11

11

11

••

""

"11

»

••11

11

"11

"

"11

"

"

"11

"

"

"11

11

11

11

11

"11

11

"

"

"

0706024 FINAL 09 06 07 1654 of 29AR100113






Quanutation Spike Source %REC RPDAnalvte Result Limit Units Level Result %REC Limits RPD Limit Notes


Blank (BI70402-BLK1)

Methyl Acetate

^lethylcyclohexane


Methylene Chloride


Naphthalene

a-Propylbenzene

Styrene


,1,1 ,2-Tetrachloroethane

retrachloroethene

Toluene


,2,4-Trichlorobenzene

,1,1 -Trichloroethane

, 1 ,2-Trichloroethane

~richloroethene

rrichlorofluorom ethane

,2,3-Trichloropropane

,2,4-Trimethylbenzene


Vinyl acetate

Vinyl chloride

n-Xylene/p-Xylene

>Xylene

Surrogate: 4-Bromo/luorobenzene

Surrogate: 1 ,2-Dichloroethane-d4


U

U

U

U

U

U

U

U

UU

UU

U

U

UU

U

U

U

U

U

U

U

U

U

19.56

17.62

19.86

Prepared: 08/27/07 09:00 Analyzed: 08/27/07 1 2:47

5.0 ug/L

5.0

5.0

5.0

5.0

5.0

5.0

10.0

5.0 "

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

10.0

10.0

20.000 98 86-115

20.000 88 76-114

20.000 99 88-110

0706024 FINAL 09 06 07 1654 of 29AR100114






Quantitation

Analvte Result Limit Units

Spike

LevelSource

Result %R£C

%REC RPD

Limits RPD Limit Notes


LCS(BI70402-BS1)Acetone

3enzene

Bromobenzene

3romochloromethane

3romodichloromethane

3romofbrm

3romomethane

2-Butanone

sec-Butylbenzene

lert-Butylbenzene

n-Bulylbcnzcne

Carbon disulfide


^hlorobenzene


Chloroethane

2-Chloroethylvinyl ether

Chloroform

Uhloromethane

2-Chlorotoluene

1-Chlorotoluene

Cyclohexane



Dibromomethane



1 ,4-DicbJorobenzene


1 , 1 -Dichloroethane

1 ,2-Dichloroethane

1 , 1 -Dichloroethene

cis-1 ,2-Dichloroethene




2,2-Dichloropropane

1 , 1 -Dichloropropene

cis-1 ,3-DichJoropropene


Zthylbenzene

Freon 113

Hexachlorobutadiene

2-Hexanone

sopropylbenzene

U

21.65

21.06

21.71

20.25

20.53

24.65

U

21.62

20.97

21.04

U

22.41

21.46

20.32

20.96

U

20.99

20.88

20.21

20.52

U

18.87

20.92

21.12

20.35

20.76

21.19

23.32

21.20

20.78

21.43

20.93

21.02

21.19

20.80

19.84

22.05

21.34

20.47

21.19

U

19.68

U

20.12

5.0 ug/L

5.0

5.0

5.0

5.0

5.0 .

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.05.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

Prepared:

20.00020.00020.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

08/22/07 09:00 Analyzed: 08/22/07 12:55

108105109101103123

108105105

112

107

102

105

105

104

101

103

94

105106

102

104

106

117

106

104

107

105

105

106

104

99

110

107

102

106

98

101

80-120

80-120

80-120

80-120

80-120

80-120

80-120 A

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

0706024 FINAL 09 06 07 1654 of 29AR100115






QuantitationAnalvte Result Limit

SpikeUnits Level

SourceResult %REC

%REC RPDLimits RPD Limit Notes


LCS(BI70402-BS1)

p-Isopropyltoluene

Methyl Acetate

^ethylcyclohexane

Methyl-ten-butyl ether

Methylene Chloride


Naphthalene

n-Propylbenzene

Styrene


,1,1 ,2-Tetrachloroethane

retrachloroethene

Toluene


,2,4-Trichlorobenzene

,1,1 -Trichloroethane

, 1 ,2-Trichloroethane

frichloroethene


,2,3-Trichloropropane



Vinyl acetate

Vinyl chloride

n-Xylene/p-Xylene

>Xylene


Surrogate: ],2-Dichloroethane-d4

Surrogate: Toluene-dS

20.86

U

U

U

20.36

U

21.44

20.64

20.41

21.48

20.79

22.21

21.63

20.86

21.11

21.84

21.35

22.30

21.17

20.71

21.33

20.92

U

25.50

41.93

20.21

20.04

19.25

19.75

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

10.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

5.0

10.0

10.0

Prepared:

ug/L 20.00011

11

11

20.000"

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000

20.000"

20.000

40.000

20.000

20.000

20.000

20.000

08/22/07 09:00 Analyzed: 08/22/07 12:55

104

102

107103102107104

111

108

104

106

109

107

112

106

104

107

105

128

105

101

10096

99

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120 '

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120 A

80-120

80-120

86-115

76-114

88-110

0706024 FINAL 09 06 07 1654

of 29AR100116

::^°^r-ffi-.:sUNITED STATES ENVIRONMENTAL PROTECTION AGENCY

Region 3 Environmental Science Center 'Analytical Services & Quality Assurance Branch

701MapesRoadFort Meade, Maryland 20755-5350

Mi, VI


J

I

A

_NF

Notes and Definitions

Analyte included in the analysis, but not detected at or above the quantitation limit.

The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than thereported value.

The identification of the analyte is acceptable; the reported value is an estimate.

An interference exists which masks the true response. See report narrative for explanation.

Quality control value is outside acceptance limits.

No Flash.

NR Not Reported

RPD Relative Percent Difference

U Analyte included in the analysis, but not detected at or above the quantitation limit.

Quantitation Limit: The lowest concentration of an analyte that can be reliably measured within specified limits of precision and accuracy for aspecific laboratory analytical method and that takes into account analytical adjustments made during sample preparation and analysis.

SOLID SAMPLE RESULTS - REPORTING PROTOCOL: Solid samples where % Solids (percent dry wt at 105 degrees C) hasbeen performed, are analyzed wet and converted to a dry weight result for reporting purposes. This is routine for organics and mostinorganic analyses. When metals and mercury analyses are requested, solid samples are routinely analyzed and reported on a dryweight basis. Solid samples for metals/mercury are prepared for analysis by an initial drying at 60 degree C and homogenizationbefore digestion. Oil-type samples will be analyzed and reported on a wet weight basis for all analyses because of the nature of thesample. Any exceptions to the protocol will be noted with a qualifier

0706024 FINAL 09 06 07 1654

of 29AR100117

final analytical report

Documents