chetan ad materials
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ADVANCE MATERIALS USAGE & ITS BENEFITSIN
ULTRA SUPER CRITICAL TECHNOLOGYAPPLICATION IN
COAL BASED POWER PLANTS
GROUP No:10
Chetan Patil (12126008)
Vivek Deshmukh (12126009)
Sitikantha Das (12126028)IIT ,KANPUR
Submitted to:
Prof . Anish Upadhyaya
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In the 21st Century, the world facing the critical
challenge of providing abundant, cheap electricity
to meet the needs of a growing global population &
economy .
Technical constraints in traditional technology
from material POV .
Need of advance materials .
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Heat absorption in differentstages in super critical boilers
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Advance alloy used presently inUSC
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ALLOWABLE STRESS AS FUNCTION OF TEMPERATURE FOR ALLADVANCE ALLOYS
Actual stresses at several steam pressures The nickel-based alloys Inconel
740, Haynes 230,Inconel 625, Inconel 617, and HR 120 have much higher
temperature capability, in decreasing order as listed compared to austenitic
steels, followed by the ferritic steels.
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Scope of advance material
usage
Evaluation includes
Mechanical properties
Steam-side oxidation
Fireside corrosion
Weldability
Fabricability
Review of applicable design codes and standards
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Creep strength:
100,000 hr rupture life for Nickel
based tubing and plates .
CCA 617 shows improved strength
compared to ordinary 617
Inconel 740 shows heat to heat
and heat treatment variations.
Heat B has 100Mpa 100000 Hrrupture life at temperature 760 C
which meets the aggressive
strength requirements .
MECHANICAL PROPERTIES
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All of the austenitic and Ni-
based materials tested formed a
dense layer of chromium oxide
that will result in low oxidation
rates at this temperature &enhanced tube life .
Among the diffusion coatings
tested, SiCr and FeCr coatings
perform much better than AlCr
coatings.
STEAM SIDE OXIDATION PREVENTION
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The testing involved the
corrosive environmentsrepresentative of different coal
types depending on the coarse
& constituents (moisture
%,sulphur% & ash %)
Corrosion behaviour is a
function of Cr level, with
corrosion decreasing rapidly as
the chromium level increased
to 22-27%.
Diffusion coatings of Cr and
Cr-Si displayed better
corrosion resistance than Al-Cr
and were comparable to weld
Fire side corrosion Resistance
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Preliminary results indicate that submerged arc welding
(SAW), a high deposition rate process favoured by boilermanufacturers for thick sections, might not be feasible for Ni-
based materials;
Tests on Haynes 230 and Inconel 740 have beenunsuccessful.
Hot wire gas tungsten arc welding tests conducted on 2-
inch thick Inconel 740 plates using a 25% Helium/75% Argon
shielding gas and matching filler wire gives encouraging
results.
An orbital gas-tungsten arc welding (GTAW) process has
been qualified for Super 304H
WELDABILITY PERFORMANCE OF ADVANCE ALLOYS
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Fabrication capabilities with alloys of interest for an USC steam boiler
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FERRITIC STEEL OR AUSTENITIC STEEL TUBES AFTER 1YEARS OF USAGE
NICKEL ALLOY STEEL TUBES AFTER 1 YEARS OF USAGE
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Efficiency improvement of pulverized coal-
fired power plants by as much as 9 %(from
35% to 45%)
Reduction of CO2 emissions by about 22%
compared to current subcritical steam
power plants & by increasing the operating
temperature and pressure to 760C(1400F) and 35 Mpa.
Less fuel consumption, Less Operation &
maintenance cost
BENEFITS
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References
www.asminternational.org
www.netl.doe.gov/publications/factsheets/project/proj463.pdf
www.fwc.com/publications/tech_papers/files/TP_CCS_07_04.pdf
asminternational.org/portal/site/csc/Details/?vgnextoid...
www.power.alstom.com
http://www.asminternational.org/http://www.netl.doe.gov/publications/factsheets/project/proj463.pdfhttp://www.netl.doe.gov/publications/factsheets/project/proj463.pdfhttp://www.fwc.com/publications/tech_papers/files/TP_CCS_07_04.pdfhttp://www.fwc.com/publications/tech_papers/files/TP_CCS_07_04.pdfhttp://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.power.alstom.com/http://www.power.alstom.com/http://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.asminternational.org/portal/site/csc/Details/?vgnextoidhttp://www.fwc.com/publications/tech_papers/files/TP_CCS_07_04.pdfhttp://www.fwc.com/publications/tech_papers/files/TP_CCS_07_04.pdfhttp://www.netl.doe.gov/publications/factsheets/project/proj463.pdfhttp://www.netl.doe.gov/publications/factsheets/project/proj463.pdfhttp://www.asminternational.org/ -
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