the chemistry of petrol diesel
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THE CHEMISTRY OF PETROL & DIESELThere's a lot behind the fuel we put in our cars – in this graphic, we take a look at the differences between diesel, leaded petrol, and unleaded petrol.
LEADED UNLEADED DIESEL
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PETROL & DIESEL – THE DIFFERENCE
DIESEL
PETROL
250 – 300 ˚C
35 – 200 ˚C
OCTANE RATINGS & KNOCKING
HOW ENGINES WORK LEADED & UNLEADED PETROL
Petrol and diesel are both obtained by fractional distillation of crude oil. However, they differ in their
composition. Diesel is a fraction of crude oil that is removed at a higher boiling point, and contains a larger amount of energy per litre, meaning more
miles can be covered with the same volume of fuel.
Knocking occurs when fuel's combustion doesn't occur in sync with the engine cycle. This causes lower engine efficiency and engine damage. Octane ratings gauge how well fuel avoids this problem, with higher values indicating less knocking. Isooctane (100) and
n-heptane (0) are used as references.
n-HEPTANE ISOOCTANE
OCTANE RATING: 0 OCTANE RATING: 100
Pb
Compounds can be added to petrol to boost its octane rating. Tetraethyl lead was one of these, but is now banned in most countries as it releases toxic
lead fumes. Alternative anti-knocking agents used in unleaded petrol include methyl tertiary-butyl ether
(MTBE), ethanol, benzene, and toluene.
OCH3
TETRAETHYL LEAD MTBE BENZENE
10-15 CARBONS
5-12 CARBONS
36.9 MJPER LITRE
33.7 MJPER LITRE
INTAKE1
COMPRESSION2
COMBUSTION3
EXHAUST4
AIR, FUEL INJECTED (PETROL ENGINES)
FUEL INJECTED (DIESEL ENGINES)
HIGHER COMPRESSION WITH DIESEL
WASTE GASES FROM COMBUSTION
1
SPARK PLUG(petrol engine only)
AIR IN
FUEL IN(petrol only)
2 3 4
FUEL IN(diesel)