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Stochastic Thermodynamics 1. Prelude & Brief History of Fluctuation theorems 2. Thermodynamics & Jarzynski/Crooks FT 3. Experiments & Applications 4. Stochastic thermodynamics & FTs 5. Detailed balance & Fluctuation-dissipation theorem 6. Information thermodynamics 7. Summary $ Outlook Nonequilibrium statistical physics & active matter systems IOP, CAS, Beijing (Aug. 11-13, 2016) Hyunggyu Park

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Stochastic Thermodynamics

1. Prelude & Brief History of Fluctuation theorems

2. Thermodynamics & Jarzynski/Crooks FT

3. Experiments & Applications

4. Stochastic thermodynamics & FTs

5. Detailed balance & Fluctuation-dissipation theorem

6. Information thermodynamics

7. Summary $ Outlook

Nonequilibrium statistical physics & active matter systems IOP, CAS, Beijing (Aug. 11-13, 2016)

Hyunggyu Park 박 형 규 朴 炯 奎

Summary of Part I

Jarzynski equality

Crooks relation

: time-reverse path

Stochastic thermodynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Microscopic deterministic dynamics

Macroscopic thermodynamics

Stochastic dynamics

Stochastic thermodynamics

Equilibrium

Stochastic thermodynamics

Equilibrium

Stochastic thermodynamics

state space

Equilibrium

Stochastic thermodynamics

state space

Equilibrium

Stochastic thermodynamics

state space

Equilibrium

Stochastic thermodynamics

state space

Equilibrium

Stochastic thermodynamics

state space

Equilibrium

Stochastic thermodynamics

state space

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

state space

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Equilibrium Nonequilibrium Process

Stochastic thermodynamics

trajectory

System

Langevin (stochastic) dynamics

Langevin (stochastic) dynamics

Langevin (stochastic) dynamics

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Langevin (stochastic) dynamics

state space

trajectory

System

Stochastic process, Irreversibility & Total entropy production

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Stochastic process, Irreversibility & Total entropy productionstate space

trajectory

time-rev

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

System

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Total entropy production and its components

Probability theory viewpoint

on Fluctuation theorems

Seifert, PRL 95, 040602 (2005) Esposito/VdBroeck, PRL 104, 090601 (2010)

Fluctuation theorems System

Fluctuation theorems

Integral fluctuation theorems

System

Fluctuation theorems

Fluctuation theorems

Integral fluctuation theorems

Fluctuation theorems

Integral fluctuation theorems

Fluctuation theorems

Integral fluctuation theorems

Thermodynamic 2nd laws

Fluctuation theorems

Integral fluctuation theorems

Detailed fluctuation theorems

Thermodynamic 2nd laws

Fluctuation theorems

Integral fluctuation theorems

Detailed fluctuation theorems

Thermodynamic 2nd laws

Probability theory

Probability theory

• Consider two normalized PDF’s :

Probability theory

• Consider two normalized PDF’s : state space

trajectory

Probability theory

• Consider two normalized PDF’s : state space

trajectory

Probability theory

• Consider two normalized PDF’s : state space

trajectory

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Integral fluctuation theorem

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Integral fluctuation theorem

(exact for any finite-time trajectory)

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Integral fluctuation theorem

(exact for any finite-time trajectory)

Probability theory

• Consider two normalized PDF’s : state space

trajectory

• Define “relative entropy”

Integral fluctuation theorem

(exact for any finite-time trajectory)

Probability theory

• Consider the mapping :

Probability theory

• Consider the mapping :

• Require

Probability theory

• Consider the mapping :

• Require reverse path

Probability theory

• Consider the mapping :

• Require reverse path

Probability theory

• Consider the mapping :

• Require reverse path

Probability theory

• Consider the mapping :

• Require reverse path

Probability theory

• Consider the mapping :

• Require

Detailed fluctuation theorem

reverse path

Probability theory

• Consider the mapping :

• Require

Detailed fluctuation theorem

reverse path

(exact for any finite t)

Probability theory

• Consider the mapping :

• Require

Detailed fluctuation theorem

reverse path

(exact for any finite t)

Probability theory

• Consider the mapping :

• Require

Detailed fluctuation theorem

reverse path

(exact for any finite t)

Probability theory

• Consider the mapping :

• Require

Detailed fluctuation theorem

reverse path

(exact for any finite t)

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

Dynamic processes & Path probability ratio

: time-reverse path

Dynamic processes & Path probability ratio

: time-reverse path

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics

Markovian jump dynamics s R

Markovian jump dynamics s R

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Reservoir entropy change Schnakenberg/Hinrichsen/Park

Langevin dynamics

Langevin dynamics

Langevin dynamics

Langevin dynamics

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Discretization scheme for a path integral

Langevin dynamics

Langevin dynamics

Langevin dynamics

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Langevin dynamics

: time-reverse path

Fluctuation theorems

Fluctuation theorems

reverse path

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathIrreversibility (total entropy production)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathWork free-energy relation (dissipated work)

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed

Fluctuation theorems

reverse pathHouse-keeping & Excess entropy production

NEQ steady state (NESS) for fixed