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7/23/2019 ppt fosfor

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PHOSPHOR and NITROGEN


2/25

History of Phosphorus

Hannig Brand(1690 in Hamburg,

Grmany!

"isti##ing t$ urint$roug$ t$%ro&ss of

'a%oration

ftr 'a%ori)s *0bu&+ts of atrurin, $ r&nt#yfound t$ itms

s$ ants

Eosphoros whichmeans ' light

bearer '

Eosphoros wichmean that has

the light

"is&o'rr

St%

-atin.unani

The ancientname for the

planet Venuswhen looking

Sunrise

The ancientname for the

planet Venuswhen looking

Sunrise

because of itsuniqueness

that is glowingin the dark

because of itsuniqueness

that is glowingin the dark


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bundan& of Phosphorus

T$ #mnt %$os%$orus is n'r found in frStat, b&aus &ruising bund# to o/ygn is#arg

0.1%of

theEarth

's

crust

Thereare

appro

imatel!"00

million

metric tons

ofphosp

hateon

Earth.

P$os%$orus &om%ounds found in natur,

among ot$rs #ot of Apatite &ontaining 2a3(PO4! 5 n/t &ontains #im, 2a2#5,and 2a5

Apatitemay b found in t$Pro'in&s of &$, Nort$ Su#asi,East Nusa Tnggara, and 7a'aPhosphorite(calcium phosphate)is found in t$ bons of t$mamma#


4/25

bundan& of Phosphorus

#hosphorus is the main foodstu$s used b!all organisms for growth and source ofenerg!.

#hosphorusin sea water

rganiccompounds

Sugarphosphate

and theoidation&ukloeprote

in andphosphorprotein

inorganiccompounds

rtofosfat

#olifosfat

norganicphosphate

compounds in seawater in (eneralbe in the form of

ions )rtho*phosphoric acid)+,#-* where

the 10% as aphosphate ionand /0% in the

form of +#-".#hosphate is an

importantelement in theformation of

proteins and help

the process ofcell metabolism


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Pro%rtis of %$os%$orusChemical Physical

E#&tron &on8guration :N;3s5 3%3

2o#our#ss

Priod * So#id

tomi& numbr 1*

E#mnt Non

"nsity 1,@53 gA&m3 ##otro%s B$it

5,34 gA&m3 Rd

5,609 gA&m3 ?#a&+


6/25

P$os%$orus

C%$os%$orus is ssntia# for #if, as %art of t$ %$os%$at grou%, it is a &om%onnt of "N, RN andTP (adnosin tri%$os%$at!, and t$ %$os%$o#i%ids t$at form a## # mmbransC%$os%$orus /ists in s'ra# form (a##otro%s! t$at /$ibit stri+ing#y diDrnt %ro%rtisT$ tomost &ommon a##otro%s ar $it %$os%$orus and rd %$os%$orus


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?n8t of P$os%$orus


8/25

"angr of P$os%$orus

To/i& for $it %$os%$orus

&ut in$a#ation /%osur $as

rsu#td in rs%iratory tra&tirritation and &utg$ing in $umans

O'r P$os%$orus in body is

dangrous, D&td osto%orosis,bro+n +idny

In$a#ation if sniD t$ $it

%$or%$orus


9/25

History of nitrogn

Nitrogn dis&o'rd by S&ottis$ %$ysi&ian"ani# Rut$rfordin 1==5, $o &a##d itnoxious air. In t$ sam tim, Nitrogn

a#so studid by 2ar# Bi#$#m S&$#,Hnry 2a'ndis$, and7os%$ Prist#yNitrogn is inrt, so ntoin -a'oisir &a##it is m%$iti& air from t$ Gr+ord

JKLM azotost$ man is #if#ss ndt$at ord &$angd to ot$r #anguag
http://wiki/Daniel_Rutherfordhttp://wiki/Carl_Wilhelm_Scheelehttp://wiki/Henry_Cavendishhttp://wiki/Joseph_Priestleyhttp://wiki/Inerthttp://wiki/Antoine_Lavoisierhttp://smb//en.wiktionary.org/wiki/mephitic_airhttp://wiki/Greek_languagehttp://wiki/Greek_languagehttp://smb//en.wiktionary.org/wiki/mephitic_airhttp://wiki/Antoine_Lavoisierhttp://wiki/Inerthttp://wiki/Joseph_Priestleyhttp://wiki/Henry_Cavendishhttp://wiki/Carl_Wilhelm_Scheelehttp://wiki/Daniel_Rutherford


10/25

Nitrogn &om%ounds +non sin&


11/25

in t$ art$s atmos%$r =@Q$i# on t$ surfa& of t$ &rust is on#y33QNitrogn &om%ounds ar a#so 'ryabundant in natur, in t$ form of o/id,

nitrits, nitrats or ot$r #mnts in t$form of sa#t

Nitrat and nitrit ar 'ry so#ub# inatr, so t$y ar a#so abundant in t$atrs Nitrogn &om%ounds found innatur among NaNO3, usua##y usd as afrti#i)r


12/25

2$mi&a# and P$ysi&a# Pro%rtis ofNitrogn


13/25

Electronic Confguration

ma+ing t$ir #&troni& &on8guration /tra stab#, b&aus#&troni& &on8guration of t$s #mnts is ns5n%3 T$ s

orbita# in t$s #mnts is &om%#t#y 8##d and % orbita#s ar$a#fF8##d

Atomic and Ionic adii

2o'a#nt and ioni& (in a %arti&u#ar stat! radii in&ras in si)don t$ grou%

Ionisation EnthalpyIonisation nt$a#%y d&rass don t$ grou% du to gradua#in&ras in atomi& si)

Physical Properties


14/25

Benevit of Nitrogen

Nitrogen fertilizer

Medicine

Zat pewarna

Eksplosive Coagulation of food product

Preserving of reprodution cell (sperm and ovum)

Storage iological sample !ave a role "n growt# of plants vegetatif

$iving olour at plants

%engt#ening plants age


15/25

"angr of Nitrogn


16/25

2ara mm%ro#$ N5

1 NH42# NaNO5 Na2# NH4NO5it$ &a#or N5 5H5O

5 4NH3 32a(O!5 5N5 6NH4?r

3 @NH3 3?r5 N5 6NH4?r

4 5NaN3 it$ su$u 300 2 3N5 5Na


17/25

P$osfor is t$ #'nt$ most abudant#mnt in t$ art$s &rust

bout 60Q of bons and tt$ ar

2a3(PO4!5 or :3(2a3(PO4!5!2a5; T$ nui& a&ids ar mad u% of

%o#ystr&$ains of %$os%$at and sugarit$ organi& bas

P$os%$orus in t$ form of TP and "P isim%ortan&s for t$ %rodu&tion of nrgyin#s


18/25

Ra&ti'ity

Nitrogn is r#ati'#y unra&ti',$i&$ is $y it $as a&&umu#atd insu&$ #arg amounts in t$

atmos%$r B$it %$os%$orus &at&$s 8r $n

/%osd to air, burning to form

P4O10 Rd %$os%orus is stab#in airtm%ratur, t$oug$ it ra&ts on$ating


19/25


20/25

Nitrogn 8/ation

2yanamid %ro&ss

2a25 N5 11002 2aN2N 2

2aN2N *H5O 2a2O3 5NH4OH HabrF?os&$ %ro&ss

N5 3H5 U 5NH3 $at

Its or+ on $ig$ tm%ratur


21/25

Ra&tion it$ Ha#ids

1 Tri$a#ids

## t$ %ossib# tri$a#ids ofN,P,s,Sb, and ?i ar +non

V 3W VW3 it$ W ,2#,?r,I

Nitrogn &om%ounds art$ #aststab#

N3 is stab#, N2#3 is /%#osi'


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T$ tri$a#id ty%i&a##y $ydro#ys rad#y it$atr, but t$ %rodu&ts d%nding on t$#mnt

N2#3 4H5O NH4OH 3HO2#P2#3 3H5O H3PO4 3H2#

s2#3 H5O SbO(! 32#F 5H

Sb2#3 H5O SbO 32#F 5H

?i2#3 H5O ?iO 32#F 5H T$y a#so ra&t it$NH3

P2#3 6NH3 P(NH5!3 3NH42#


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5 Pnta$a#ids

Nitrogn is unab# to form%nta$a#ids b&aus t$ s&onds$## &ontains a ma/imumof ig$t#&trons T$ subsXunt #mnts$a' suitab# d orbita# and form

%nta$a#ids T$ mo#&u#s $a' a trigona#

bi%yramid s$a%


24/25

O/ids of Nitrogn

ormu#a O/idationNumbr

Nam

N5O I Nitrous O/id

NO II Nitri& O/id

N5O3 III Nitrogn SsXuio/idNO5, N5O4 IY Nitrogn "io/id, "initrogn

Ttro/id

N5O* Y "initrogn Pnto/id

NO3, N5O6

(Yry unstab#!

YI Nitrogn Trio/id, "initrogn

H/o/id


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!ormula "#idation $umber

P4O6 III

P4O= III and Y

P4O@ III and Y

P4O9 III and YP4O10 Y

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