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BIOREMEDIATION The NEW Waste Management. The NEW Waste Management. LANDFILL & INDUSTRIAL SERVICES LANDFILL & INDUSTRIAL SERVICES Off-Site Bioremediation for Contaminated Soils www.wm.com n-site remediation of soils and media contaminated with petrochemicals, pesticides, explosives or hazardous organics can be an expensive and time-consuming process. There are also serious legal and regulatory issues to consider when decontaminating soils on location, issues that can jeopardize the viability of a construction or re-development project. Waste Management, North America’s leading solid waste services company, has developed a collection of innovative off-site remediation technologies to help companies deal effectively with contaminated soils. These bioremediation services include: TOSS SM (Two-Step Static System) for the off-site treatment of soils contaminated with explosives Bio-In-A-Box SM for the off-site decontamination of all types of contaminated soils in drums or in bulk The BioSite SM System for the off-site remediation of petrochemical-contaminated soils THE BENEFITS OF OFF-SITE BIOREMEDIATION Regardless of the technique used, off-site bioremediation by Waste Management offers numerous advantages over on-site treatment, windrow composting or incineration. These include: Lower costs compared to treating the soil at the original site or at an intermediate location An environmentally friendly process Controlled access to fully equipped, insured and permitted waste sites Stabilization of heavy metals (if any) prior to landfilling Waste Management’s comprehensive indemnification package Remediation backed by the knowledge, experience and financial resources of North America’s leading solid waste services company Off-site bioremediation services may be accessed from most North American locations via Waste Management’s WasteByRail program. For more information on WasteByRail services, visit www.wastebyrail.com. SPECIALLY LICENSED FACILITIES Bioremediation is conducted in specially licensed facilities situated at Waste Management landfills throughout North America. All are specifically designed, licensed and operated to provide waste generators and remediation companies with a responsive program for the expeditious removal, treatment and disposal of hazardous and non-hazardous industrial waste. (Not all facilities are licensed to accept RCRA waste.) TOSS SM TWO-STEP STATIC SYSTEM* TOSS SM is a two-stage solid phase bioremediation technology that involves both anaerobic and aerobic treatment stages. In the first stage, explosives-contaminated soil is combined with a carbon source, an inoculum, vitamins and water to achieve anaerobic conditions. The resulting mixture is formed into a static pile or placed in a bermed construction or box to facilitate the chemical reduction of nitroaromatic and nitramine explosives. In the second stage, the anaerobically treated soil is combined with yard waste compost and built into an aerated biopile. The biopile may be aerated by forced air conveyed through perforated piping buried within the pile or by turning the pile with a compost turner. Previous testing of TOSS SM has demonstrated TNT removal efficiencies of >99%. * U.S. PATENT #6,066,722 BIO-IN-A-BOX SM Bio-In-A-Box SM is a Waste Management process for remediating petrochemical-contaminated soils in quantities of 1,000 cubic yards or less. In this process, the contaminated soil is moistened, mixed with nutrients and custom-grown microorganisms and then placed in enclosed containers called “solid phase bio-reactors” for incubation. These containers may or may not be linked to aeration and vacuum pipes, depending on the contaminants being processed. In just a few weeks, the decontaminated soil will be ready for landfill disposal or reintroduction into the environment. THE BIOSITE SM SYSTEM The BioSite SM System is Waste Management’s proprietary system for the large-scale bioremediation of soils contaminated with petrochemicals including, but not limited to: Acetone • Alcohols Benzene • Ethylbenzene Toluene • Xylene Methyl Ethyl Ketone Methyl Isobutyl Ketone (MEK) (MIBK) Petroleum hydrocarbons Two- and three-ring PAHs. The BioSite SM System can also handle other contaminants, including: Aliphatic chlorinated hydrocarbons (e.g., Trichloroethylene) Spent molecular sieve from packing towers Chemical manufacturing wastes Pesticides Regulated compounds including Underlying Hazardous Constituents (UHC) are screened prior to acceptance. Soils co-contaminated with metals may be accepted depending on their concentration. Using the Daramend® bioremediation process licensed from Adventus Remediation Technologies, Inc., BioSite SM works by forming the contaminated soil into earthen biopiles around vented pipes that circulate air through the mixture. Specially cultivated hydrocarbon degrading microorganisms and a blend of inorganic nutrients are then introduced to the pile. A synthetic cover is placed over the biopile and, within a few months, the contaminants are safely and naturally broken down into less-toxic compounds. Once treated, the material may be landfilled, treated for metals, reused or returned to the customer in accordance with regulatory requirements. DDT contaminated soils may be treated using the Xenorem® bioremediation process licensed from AstraZeneca. In addition, Waste Management employs two patented processes for the rapid remediation of contaminated soils: Daramend®: Designed to accelerate the bioremediation of soils or sediments containing high concentrations of creosote, PCPs, PAHs, heavy oils and petroleum hydrocarbons, this product, licensed from Adventus Remediation Technologies, Inc., utilizes matrix-specific solid-phase organic amendments to create aquatic microsites where native microorganisms can grow, contact contaminants and degrade them. Daramend® products are matrix-specific solid-phase organic particles that are manufactured from natural botanical materials. Xenorem®: Developed by the biotech firm AstraZeneca, Xenorem® combines organic compounds derived from wood pulp, straw and animal manure to rapidly and naturally break down chlorinated pesticides, such as DDT, from contaminated soils. By carefully controlling the temperature and oxygen level of the combined waste, Waste Management technicians can degrade pesticides in contaminated soils while producing less harmful byproducts. Bioremediation O Conducted under controlled conditions, BioSite SM bioremediation uses a combination of chemicals and microorganisms to naturally break down hazardous materials into non-hazardous substances that can be recycled or buried in conventional landfills. Treating contaminated soils on-site at bioremediation facilities is ultimately less expensive and more environmentally friendly. To find out if off-site bioremediation is right for you, contact your local Waste Management Landfill and Industrial Services sales representative. From everyday collection to environmental protection, look to the NEW Waste Management.

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BIO

REM

EDIA

TIO

N

The NEW Waste Management.The NEW Waste Management.

LANDFILL &INDUSTRIAL

SERVICES

LANDFILL &INDUSTRIAL

SERVICES

Off-Site Bioremediation for Contaminated Soils

www.wm.com

n-site remediation of soils and media contaminated with petrochemicals, pesticides,

explosives or hazardous organics can be an expensive andtime-consuming process. There are also serious legal andregulatory issues to consider when decontaminating soilson location, issues that can jeopardize the viability of aconstruction or re-development project.

Waste Management, North America’s leading solidwaste services company, has developed a collection of innovative off-site remediation technologies to helpcompanies deal effectively with contaminated soils.These bioremediation services include:

• TOSSSM (Two-Step Static System) for the off-sitetreatment of soils contaminated with explosives

• Bio-In-A-BoxSM for the off-site decontamination of all types of contaminated soils in drums or in bulk

• The BioSiteSM System for the off-site remediationof petrochemical-contaminated soils

THE BENEFITS OF OFF-SITE BIOREMEDIATION

Regardless of the technique used, off-site bioremediationby Waste Management offers numerous advantages overon-site treatment, windrow composting or incineration.These include:

• Lower costs compared to treating the soil at the original site or at an intermediate location

• An environmentally friendly process

• Controlled access to fully equipped, insured and permitted waste sites

• Stabilization of heavy metals (if any) prior to landfilling

• Waste Management’s comprehensive indemnification package

• Remediation backed by the knowledge, experience and financial resources of NorthAmerica’s leading solid waste services company

• Off-site bioremediation services may be accessedfrom most North American locations via WasteManagement’s WasteByRail program. For moreinformation on WasteByRail services, visitwww.wastebyrail.com.

SPECIALLY LICENSED FACILITIES

Bioremediation is conducted in specially licensed facilitiessituated at Waste Management landfills throughout NorthAmerica. All are specifically designed, licensed and operatedto provide waste generators and remediation companieswith a responsive program for the expeditious removal,treatment and disposal of hazardous and non-hazardousindustrial waste. (Not all facilities are licensed to acceptRCRA waste.)

TOSSSM TWO-STEP STATIC SYSTEM*

TOSSSM is a two-stage solid phase bioremediation technologythat involves both anaerobic and aerobic treatment stages.In the first stage, explosives-contaminated soil is combinedwith a carbon source, an inoculum, vitamins and water toachieve anaerobic conditions. The resulting mixture isformed into a static pile or placed in a bermed constructionor box to facilitate the chemical reduction of nitroaromaticand nitramine explosives.

In the second stage, the anaerobically treated soil is combinedwith yard waste compost and built into an aerated biopile.The biopile may be aerated by forced air conveyed throughperforated piping buried within the pile or by turning thepile with a compost turner. Previous testing of TOSSSM hasdemonstrated TNT removal efficiencies of >99%.* U.S. PATENT #6,066,722

BIO-IN-A-BOXSM

Bio-In-A-BoxSM is a Waste Management process for remediatingpetrochemical-contaminated soils in quantities of 1,000cubic yards or less. In this process, the contaminated soilis moistened, mixed with nutrients and custom-grownmicroorganisms and then placed in enclosed containerscalled “solid phase bio-reactors” for incubation. These containers may or may not be linked to aeration and vacuumpipes, depending on the contaminants being processed. In just a few weeks, the decontaminated soil will be readyfor landfill disposal or reintroduction into the environment.

THE BIOSITESM SYSTEM

The BioSiteSM System is Waste Management’s proprietary system for the large-scale bioremediation ofsoils contaminated with petrochemicals including, butnot limited to:

• Acetone • Alcohols

• Benzene • Ethylbenzene

• Toluene • Xylene

• Methyl Ethyl Ketone • Methyl Isobutyl Ketone (MEK) (MIBK)

• Petroleum hydrocarbons • Two- and three-ring PAHs.

The BioSiteSM System can also handle other contaminants, including:

• Aliphatic chlorinated hydrocarbons (e.g., Trichloroethylene)

• Spent molecular sieve from packing towers

• Chemical manufacturing wastes

• Pesticides

Regulated compounds including Underlying HazardousConstituents (UHC) are screened prior to acceptance. Soilsco-contaminated with metals may be accepted dependingon their concentration.

Using the Daramend® bioremediation process licensed fromAdventus Remediation Technologies, Inc., BioSiteSM works byforming the contaminated soil into earthen biopiles aroundvented pipes that circulate air through the mixture.Specially cultivated hydrocarbon degrading microorganismsand a blend of inorganic nutrients are then introduced tothe pile. A synthetic cover is placed over the biopile and, within a few months, the contaminants are safely and naturally broken down into less-toxic compounds. Oncetreated, the material may be landfilled, treated for metals,reused or returned to the customer in accordance with regulatory requirements.

DDT contaminated soils may be treated using the Xenorem®bioremediation process licensed from AstraZeneca.

In addition, Waste Management employs two patentedprocesses for the rapid remediation of contaminated soils:

• Daramend®: Designed to accelerate the bioremediation of soils or sediments containinghigh concentrations of creosote, PCPs, PAHs,heavy oils and petroleum hydrocarbons, thisproduct, licensed from Adventus RemediationTechnologies, Inc., utilizes matrix-specific solid-phase organic amendments to create aquatic microsites where native microorganismscan grow, contact contaminants and degradethem. Daramend® products are matrix-specificsolid-phase organic particles that are manufactured from natural botanical materials.

• Xenorem®: Developed by the biotech firmAstraZeneca, Xenorem® combines organic compounds derived from wood pulp, straw andanimal manure to rapidly and naturally breakdown chlorinated pesticides, such as DDT, fromcontaminated soils. By carefully controlling thetemperature and oxygen level of the combinedwaste, Waste Management technicians candegrade pesticides in contaminated soils whileproducing less harmful byproducts.

Bioremediation

O

Conducted under controlled conditions, BioSiteSM

bioremediation uses a combination of chemicals andmicroorganisms to naturally break down hazardous materials into non-hazardous substances that can be recycled or buried in conventional landfills.

Treating contaminated soils on-site at bioremediation facilitiesis ultimately less expensive and more environmentally friendly.

To find out if off-site bioremediation is right for you, contact your local Waste Management Landfill and IndustrialServices sales representative.

From everyday collection to environmental protection, look to the NEW Waste Management.

The NEW Waste Management.

Soil is unloaded at a staging area adjacent to the pile. Materials are fingerprinted and inspected for any foreign matter collected during the excavation process.

Loader places soil onto pile.

A blend of special chemicals and organisms is added.

A synthetic cover is applied to control emissions and humidity.

Perforated pressure piping adds air to the pile.

Perforated vacuum piping removes air from the pile.

Recirculated air is periodically monitored to determine the rate of treatment.

The demister (knock out drum) collects the condensate.

The blower assembly circulates air through the perforated pipe aeration system.

Instruments monitor the pressure and temperature of the pile core.

BioSiteSM System is a safe, cost-effective method for remediatingthe contaminated soils in quantities of 1000 yards or more. Afterbeing placed in a ventilated biopile, soil is treated with a blend of selected chemicals and microorganisms that naturally break the toxins down into less harmful compounds. After treatment,treated soils can be safely landfilled or taken off-site for other uses.

Bioremediation