“the future of munitions batteries” workshop...• tabs v4 was demonstrated at spring review –...

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Joint DoD/DOE Munitions Program UNCLASSIFIED UNCLASSIFIED TCG-V: Power Systems Technology 1 “The Future of Munitions Batteries” Workshop Army Research Laboratory (ARL) 7 December 2016 Anthony Pergolizzi (ARDEC) -- TCG-V Chair [email protected], 973-724-2361 DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

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Page 1: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V: Power Systems Technology

1

“The Future of Munitions Batteries”Workshop

Army Research Laboratory (ARL)7 December 2016

Anthony Pergolizzi (ARDEC) -- TCG-V [email protected], 973-724-2361

DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 2: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Mission,Vision & Goals

• Mission:– Foster S&T Investments In Munition Power

Sources• Vision:

– Develop the Next Generation of Power Sources– Develop Computational Models To Predict

Performance Of Power Sources• Goals

– Support Development of Advanced Munitions and Weapon Systems.

2DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 3: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Projects

Project Name Lab Potential/Planned CustomersThermal Battery Performance Models

Sandia DoD Laboratories, Thermal Battery Industrial Base, DoD Prime Contractors

Thin Film Thermal Battery Sandia Thermal Battery Industrial Base, DoD Prime Contractors, DoDLaboratories

3DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 4: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Impact• TCG-V Modeling Provides Significant Cost Savings

– Thermal Battery Designs Can Be Quickly Evaluated – Eliminates Iterative Design Process– Expands Our Understanding Of How Thermal Batteries Work

• Thin Film Battery Development – Potential In Medium & Small Size Munitions– Conformal Shape Does Not Require Central Design Space – Improved Production Process – Improved Performance

• Faster Rise Times • Higher Power & Energy Densities

Thermal Battery Modeling & Thin

Film Development

Affordable -- Advances Technology --

Improves Performance -- Supports Fragile

Industrial Base4

DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 5: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Accomplishments

• SNL:– Thermal Battery Modeling Effort

• High Temp Friction Measurements Were Obtained To Feed Model• An Apparatus Was Built To Measure Permeability Of Battery Materials

– Data Collected Will be Used To Feed Coupled Physics Models• A Coupled Thermal Electo-Mechanical Single Cell Model Was Demonstrated• Thermal, Electrochemical and Two Phase Porous Flow Physics

– Models Coupled and Demonstrated• TABS v4 Was Demonstrated At Spring Review

– Thin Film Conformal Battery• Successfully Coated and Produced Thin Film Cathode

– Overcame Early Lamination and Adhesion Issue• Successfully Produced Thin Film Separator

5DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 6: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Transitions

• SNL:– Thermal Battery Modeling Effort

• TABS v4 Was Transitioned To DoD– 6-7 Active Licenses Tri-Service Applicability– Early Attempts To Transition To Industrial Base Unsuccessful

» Small Cost For Training & Support Remains Underfunded» TCG-V Will Continue To Work With Industry Partners

– Thin Film Battery Conformal Battery• Transitions Planned To Industry Either As Full Battery or Components• DoD Transitions Planned

6DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 7: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Accomplishment / Transition / Collaboration Highlights

7

Li

Li3Fe2S4

e-

e-

K+Li+ Cl-

e-

(+)

FeS2

(-)Stainless Steel

Stainless Steel

Fe/KClO4Heat Pellet

MgO Matrix

e-

Li(Si)Anode

FeS2 + EB + Li2OCathode

Cl-

Cl-Cl- Li+K+

Amps

e-

e-

• Thermal Battery Modeling• High Level of Support• Reduces Development Cost• Good Transition History

• Thin Film Conformal Battery• Potential To Reduce Space Claim• Supports Smaller Munitions• Leverages TCG-X & JFTP• Break-Through Technology

• Currently Limited To Pressed Pellet

TCG-V• Re-Visit Un-Confined DoD / DOE Needs• Align Future Modeling Needs w/User Goals

DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 8: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-VTechnical Gap Survey

8

• Small DoD Munition Power Sources Required• Thermal or Liquid Reserve

• Active Batteries Which Have 20+ Years Shelf Life• May Not Be Feasible For Significant Time

• Energy Harvestors• Lowest Level Of Interest• Used By All Services• May Be Too Application Specific

DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 9: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-VTechnical Gap Survey

9

Ordinal Rank Order

1) Full Battery Multi-Physics Design Model2) Experimental Model Validation3) Battery Material Property Discovery11) Models For Liquid Reserve Batteries6) Modeling Batteries Under Environmental Stresses4) TABS Uncertainty Qualification / Component Margin Studies7) Incorporate Thin Film Batteries Into TABS Model9) Models For Battery Ageing5) Three Dimensional Battery Models12) Models For Primary of Seconday Batteries (Actives, Lithium Ion etc)8) Next Generation GUI (Impoved User Interface)10) Abnormal Environmental Modeling (Accidental Fires, etc)

DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 10: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Technical Gap Survey Observations & Questions

• Modeling Ranks Closely Spaced• Variations Due To Process Or Actual Ranked Weight?• Is This The Correct Order?• How Would DOE Rank?• Improved User Interface Scored Low

– Poor User Interface Directly Linked To Transitions and Use– Is It That Users Are Happy With Interface As Is?

• How Does Each Task Weigh To LOE and Cost?

10DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 11: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

TCG-V Technical Gap Survey Addition Items To Study

• Aging models for Thermal Batteries and components.• Alternative Thermal Battery header designs.• Aging models and studies for COTS (or novel) super-

capacitors and components• Non-destructive surveillance of Reserve Batteries (thermal

or liquid)• Include newer materials in models

11DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.

Page 12: “The Future of Munitions Batteries” Workshop...• TABS v4 Was Demonstrated At Spring Review – Thin Film Conformal Battery • Successfully Coated and Produced Thin Film Cathode

Joint DoD/DOE Munitions Program

UNCLASSIFIED

UNCLASSIFIED

Questions?

12DISTRIBUTION A: Approved for Public Release. Distribution is unlimited.