Air Pollution

• Americans release some 147 million metric tons of air pollution (not including CO2 or wind-blown soil) each year.

Air Pollution

• Even so, air quality in the US and in most industrial nations is better today then it was 20 years.

• Air quality in the developing world, however, is significantly worse.

• Primary pollutants - pollutants released in hazardous form

• Secondary pollutants - become hazardous after reactions in the atmosphere. – Photochemical oxidants - are compounds

formed with solar energy– Acids/Acid rain

• Conventional or “criteria” pollutants - – Carbon Monoxide– Lead– Nitrogen oxides – Ozone – Particulate Matter– Sulfur Dioxide – Volatile organic compounds

CARBON MONOXIDE (CO)• Carbon monoxide (CO) is a colorless, odorless and

poisonous gas produced by incomplete burning of carbon in fuels. When CO enters the bloodstream, it reduces the delivery of oxygen to the body's organs and tissues. Exposure to elevated CO levels can cause impairment of visual perception, manual dexterity, learning ability and performance of complex tasks.

• 77% of the nationwide CO emissions are from transportation sources. The largest emissions contribution comes from highway motor vehicles. Other major CO sources are wood-burning stoves, incinerators and industrial sources.

Lead (Pb)

• Lead (Pb) is a widely used metal that, once released to the environment, can contaminate air, food, water, or soil. Exposures to even small amounts of lead over a long time can accumulate to reach harmful levels. Harmful effects may therefore develop gradually without warning. Short-term exposure to high levels of lead may also cause harm. Lead can adversely affect the nervous, reproductive, digestive, cardiovascular blood-forming systems, and the kidney. In men, adverse reproductive effects include reduced sperm count and abnormal sperm.

Lead (Pb)• In women, adverse reproductive effects include

reduced fertility, still-birth, or miscarriage. Children are a sensitive population as they absorb lead more readily and their developing nervous system puts them at increased risk for lead-related harm, including learning disabilities.

• Lead gasoline additives, non-ferrous smelters, and battery plants are the most significant contributors to Pb emissions into the atmosphere. In 1993 transportation sources contributed 33% of the annual emissions, down substantially from 81% in 1985.

Lead (Pb)

• Total Pb emissions from all sources dropped from 20,100 tons in 1985 to 4,900 tons in 1993. The decrease in Pb emissions from cars and trucks shifting to lead-free gasoline accounts for essentially all of this decline.

Nitrogen oxides (NOx)

Nitrogen oxides (NOx) include various nitrogen compounds like nitrogen dioxide (NO2) and nitric oxide (NO). These compounds play an important role in the atmospheric reactions that create Tropospheric ozone (O3) and acid rain.

Individually, they may affect ecosystems, both on

land and in water.

NOx forms when fuels are burned at high temperatures. The two major vehicles and stationary combustion sources such as electric utility and industrial boilers.

Nitrogen dioxide (NO2)

• Nitrogen dioxide (NO2) is a brownish, highly reactive gas that is present in all urban atmospheres. NO2 can irritate the lungs, cause bronchitis and pneumonia, and lower resistance to respiratory infections.

• The major mechanism for the formation of NO2 in the atmosphere is the oxidation of nitric oxide (NO), which is produced by most combustion processes.

Ozone (O3)• Ozone (O3) is the major component of smog.

Although O3 in the upper atmosphere is beneficial because it shields the earth from the sun's harmful ultraviolet radiation, high concentrations of O3 at ground level are a major health and environmental concern. The reactivity of O3 causes health problems because it damages lung tissue, reduces lung function and sensitizes the lungs to other irritants. Scientific evidence indicates that ambient levels of O3 not only affect people with impaired respiratory systems, such as asthmatics, but healthy adults and children as well.

Ozone (O3)• Exposure to O3 for several hours at relatively low

concentrations has been found to significantly reduce lung function and induce respiratory inflammation in normal, healthy people during exercise.

• O3 is not usually emitted directly but is formed through complex chemical reactions in the atmosphere. Precursor compounds like volatile organic compounds (VOC) and oxides of nitrogen (NOx) react to form O3 in the presence of sunlight. These reactions are stimulated by ultraviolet radiation and temperature, so peak O3 levels typically occur during the warmer times of the day and year.

Particulate matter (PM)• Particulate matter (PM) is a mixture of particles

that can adversely effect human health, damage materials and form atmospheric haze that degrades visibility. PM is usually divided up into different classes based on size, ranging from total suspended matter (TSP) to PM-10 (particles less than 10 microns in aerodynamic diameter) to PM-2.5 (particles less than 2.5 microns). In general, the smallest particles pose the highest human health risks. PM exposure can affect breathing, aggravate existing respiratory and cardiovascular disease, alter the body's defense systems against foreign materials, and damage lung tissue, contributing to cancer and premature death.

Particulate matter (PM)• Individuals with chronic obstructive pulmonary or

cardiovascular disease, asthmatics, the elderly and children are most sensitive to the effects of PM.

• Particulate matter (PM) includes dust, dirt, soot, smoke and liquid droplets directly emitted into the air by sources such as factories, power plants, cars, construction activity, fires and natural windblown dust. Particles formed in the atmosphere by condensation or the transformation of emitted gases such as SO2 and VOCs are also considered particulate matter.

SULFUR DIOXIDE (SO2)

• SULFUR DIOXIDE (SO2) High concentrations of sulfur dioxide (SO2) affect breathing and may aggravate existing respiratory and cardiovascular disease. Sensitive populations include asthmatics, individuals with bronchitis or emphysema, children and the elderly. SO2 is also a primary contributor to acid rain, which causes acidification of lakes and streams and can damage trees, crops, historic buildings and statues. In addition, sulfur compounds in the air contribute to visibility impairment in large parts of the country. This is especially noticeable in national parks.

SULFUR DIOXIDE (SO2)

• Sulfur dioxide (SO2) is released primarily from burning fuels that contains sulfur (like coal, oil and diesel fuel). Stationary sources such as coal- and oil-fired power plants, steel mills, refineries, pulp and paper mills, and nonferrous smelters are the largest releasers.

Volatile organic compounds (VOC)

• Volatile organic compounds (VOC) are defined by the Clean Air Act as chemicals that participate in forming ozone (O3). Ozone is a respiratory toxicant. The class of VOCs includes many specific chemicals which may also cause adverse health effects in their own right (such as cancer or reproductive toxicity).

Volatile organic compounds (VOC)

• VOCs are emitted from diverse sources, including automobiles, chemical manufacturing facilities, drycleaners, paint shops and other commercial and residential sources that use solvent and paint. VOC emissions form O3 through complex chemical reactions with oxides of nitrogen (NOx) in the presence of sunlight.

Air quality standards (NAAQS)

9-34

red indicates entire county is in nonattainment pink indicates that part of the county is in nonattainment

http://www.scorecard.org/community/index.tcl?zip_code=14221&fips_county_code=36029

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Pollution emission reductions

9-24

Other Pollutants

• The EPA also monitors several thousand other chemicals in the atmosphere that are not “critical” pollutants. – mercury, benzene, vinyl chloride, PCBs …– Smoking

Indoor Air Pollution

• Concentration of pollutants in homes, in some cases, is much higher than outdoors, and can even reach levels that would be considered illegal in the workplace. – chloroform, benzene, C-tet, – Molds and other biohazards

Long range transport and effect

• The atmosphere acts as transport for air pollutants circulating them far from their points of origin and concentrating them in certain areas.

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Air currents over north poleFigure 9.20

9-28

Country Sulfur Sulfur Exported to Emitted Sweden (1992)

Belgium 156 18Denmark 122 100Finland 97 37France 604 30Germany 2275 302Ireland 80 4Netherlands 89 13Norway 20 18Poland 1420 160Sweden 51 ---United Kingdom 1782 183

total received 865

Battery AcidStomach Acid Lemon Juice

Acid Rain pH < 5.6

DistilledWater

NaturalRain 5.6

Baking Soda

Ammonia

Orange Juice 4.2

Natural Water is Slightly Acidic

Acid HydrolysisMost common - CARBONIC ACID (H2CO3)

formed by water reacting with carbon dioxide forms where water is in contact with the atmosphere,

in the root zones of plants where carbon dioxideis released into the soil, and where bacteria in

the soil is decomposing organic material

Also found are Nitric Acid, Humic Acid and Sulfuric Acid

Acid Hydrolysis

CARBONIC ACID (H2CO3)

H2O + CO2 H2CO3 H2CO3 H + HCO3 (bicarbonate)

H + HCO3 + CaCO3 Ca + 2HCO3

+

_+

_

+ + _

Ex. Weathering of calcite - the main component of limestone

Soluble ions affected by dissolution

•Limestone and marble contain calcite and are soluble in acidic water

•Marble tombstones and carvings are particularly susceptible to chemical weathering by hydrolysis followed by dissolution.

Modern replacementfrom 1980s

Original marble from 1807The Capitol Building

Sulfuric Acid

• H2S + 2O2 ==> 2H+ + SO4 - (sulfuric acid)

Sulfur dioxide reacts with water vapor to form sulfuric acid

Second only to smoking as a cause of air-pollution related health damage.

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

U.S. acid precipitation mapFigure 9.25

9-32 Source: National Atmospheric Deposition Program/National Trends Network http://nadp.sws.uiuc.edu.

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Ozone destruction

9-29

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Ozone holeFigure 9.22

9-30 Source: Goddard Space Flight Center, NASA.

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Chlorofluorocarbon productionFigure 9.23

9-31 Source: Data from Sebastian Oberthur, Production and Consumption of Ozone-Depleting Substances, 1986-1995 (Deutsche Gesellschaft for Technische Zusammenarbeit, Bonn Germany, 1997, p. 30).

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Photochemical oxidants -

9-27

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Emission-control system (car)Figure 9.28

9-33

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

U.S. air pollution trendsFigure 9.29

9-35 Source: Data from Environmental Protection Agency.

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Principal pollutants (slide 1 of 2)

9-25

Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Principal pollutants (slide 2 of 2)Table 9.5 continued

9-26