pesticide residue monitoring at finnish customs 2013-2014 carola ranta, pekka ravio finnish customs...
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Pesticide Residue Monitoring at Finnish Customs 2013-2014
Carola Ranta, Pekka Ravio
Finnish Customs Laboratory
11th NPRW/Carola Ranta, Pekka Ravio
Contents
• Introduction
• Methods
• Results
• Non-compliant products
11th NPRW/Carola Ranta, Pekka Ravio
Finnish Customs Laboratory
• Main research areas- Foodstuffs - Consumer goods- Customs technical- Ilicit import
• National Reference Laboratory (pesticides)- Fruit and Vegetables- Cereals- Single Residue Methods
11th NPRW/Carola Ranta, Pekka Ravio
LC-MS/MS methods
Method Compounds Accreditation
Multiresidue 210 X
Chlormequat and mepiquat 2 X
Phenoxy herbicides 14 -
Glyphosate, AMPA and glufosinate ammonium
3 -
Ethephon, perchlorate and chlorate
3 -
Fenbutatin oxide 1 -
BAC and DDAC 5 -
Screening with Orbitrap -
11th NPRW/Carola Ranta, Pekka Ravio
GC-methods
Method Compounds Accreditation
Multiresidue 110 X
Chlorothalonil 1 -
Dithiocarbamates as CS2
1 X
DRS screening -
Phosphine 1 -
Bromide 1 X
11th NPRW/Carola Ranta, Pekka Ravio
Sampling plan 2015Product Amount
Fresh fruit 430 Also 30 BAC and DDAC
Berries 50
Orange juice 15 EU programme
Nuts and almonds 40 Also fumigants
Vegetables Fresh
Green + herbsFrozen herbs
Beans, Lentils Dried fungus
48050503010
Also 30 BAC and DDACChlorate and perchlorate
Nicotine
Vegetable products 20
Herbal teas 30
Soups etc. containing spices 20
Herbal spices 30
Teas 70
Cereals 70 20 rice
Infant foodCereal based
Vegetable based1010
Total 1415
11th NPRW/Carola Ranta, Pekka Ravio
Analyzed samples 2013-2014
OK Rejected Remarked
5 %4 %
11th NPRW/Carola Ranta, Pekka Ravio
Pesticide residues 2002-2014
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
0
500
1000
1500
2000
2500
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
8.0
9.0
Analyzed lots
Non-compliant lots, %
11th NPRW/Carola Ranta, Pekka Ravio
Pesticides analyzed/detected
20042005
20062007
20082009
20102011
20122013
0
50
100
150
200
250
300
350
199213
230251 259 264
295310 311 311
95
114116
137163 168 179 180
161 153
Pesticides analyzed
Pesticides detected
Year
Am
ount
of p
estic
ides
11th NPRW/Carola Ranta, Pekka Ravio
Pesticides exceeding the MRLs
Carben
dazim
and b
enom
yl
Aceta
mip
rid
Dimet
hoate
and O
met
hoate
Triazo
phos
Anthra
quinone
Dodine
Imid
aclo
prid
Profe
nofos
Chlorp
yrifo
s
2-Phen
yl p
henol
Acephat
e 0
5
10
15
20
25
11th NPRW/Carola Ranta, Pekka Ravio
New compounds
Pesticide Number of Findings
Found in products such as
Country
Fluopicolide FUPI 25 Cucumber, Tomatoes, Spinach Spain, Holland, Italy
Bixafen FUBX 1 Proficiency test Denmark
Fluxapyroxad FUFX 1 Proficiency test Denmark
Prosulfocarb MHPS 2 Varsiselleri, Frozen dill Great Britain, Sweden
Pyridalyl INPD 2 Chili peppers, Aubergine Holland
Triflumizole FUTF 1 Cucumber Holland
Etoxazole ACET 1 Strawberry Spain
Novaluron INNO 1 Apple Argentina
Forchlorfenuron MHFC 0 - -
Clomazone MHKL 0 - -
1-Naphtylacetamide MHNP 0 - -
Proquinazid FUPQ 0 - -
11th NPRW/Carola Ranta, Pekka Ravio
Pumpkin seeds from China
• Isofenphos methyl 0,076 mg/kg
• Not approved pesticide
• Partly distributed= > withdrawn from the markets
11th NPRW/Carola Ranta, Pekka Ravio
Chili peppers from Spain
• Methiocarb 0,71-1,3 mg/kg
• MRL 0,2 mg/kg
• 344-630 % above ARfD
11th NPRW/Carola Ranta, Pekka Ravio
RASFF notifications in 2014
Product Country of origin
Pesticide (mg/kg) MRL(mg/kg)
1 Dried chili peppers Mexico Anthraquinone 0,99 Not Approved
2 Aubergine Thailand Dimethoate 0,13 0,02
3 Rucola Kenya Bifenthrin 11 2
4 Pumpkin seeds China MalathionIsofenphos-methyl
0,0490,076 Not Approved
5 Organic Apples Argentina Chlorate 0,31
6 Organic dried dandelium
Spain TriadimenolPhorate
0,580,13 Not Approved
7 Herbal tea USA Anthraquinone 0,087 Not Approved
8 Kale Spain Pirimicarb 2 0,1
11th NPRW/Carola Ranta, Pekka Ravio
Thank you!