p2x göttingen 2019 · rapsmethylester (biodiesel) ome1 d. deutsch, d. oestreich, l. lautenschütz,...
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![Page 1: P2X Göttingen 2019 · Rapsmethylester (Biodiesel) OME1 D. Deutsch, D. Oestreich, L. Lautenschütz, P. Haltenort, U. Arnold, J. Sauer ChemieIngenieurTechnik 2017, 89, 486–489. OME(1;](https://reader031.vdocuments.site/reader031/viewer/2022013011/6077907089bbe5791a6a1983/html5/thumbnails/1.jpg)
INTEGRATED ENERGY
Rüdiger-A. Eichel
IEK-9: Fundamental Electrochemistry Chair of Energy Conversion & StorageInsGtute of Energy and Climate Research InsGtute of Physical ChemistryForschungszentrum Jülich RWTH Aachen UniversityGermany
11. GöPnger Energietagung ∣ Paulinerkirche, 8. 5. 2019
Power-to-X as Key Enabling Technology & Industrial Implementa=on Aspects
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KOPERNIKUS FLAGSHIP-PROJECT“Power-to-X: Exploration, Validation and Implementation of P2X Concepts”
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 2
funding:
Consor$um:
17 Research Ins$tutes26 Partners from Industry
3 Civil Society Organiza$ons➞ 64 Working Groups
Budget:
38.3 M€ (1st funding period of 3 years)8.3 M€ (contribu$on from Industry)
Funding term:
10 y in total (of three periods)
Coordina$on:
AcademiaIndustrySocio-economics
Rüdiger-A. Eichel, IEK-9
Walter Leitner, ITMC
Kurt Wagemann
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EXCELLENCE INITIATIVE OF THE GERMAN FEDERAL AND STATE GOVERNMENTS
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
Cluster of Excellence (2012 – 2018)
Tailor-Made Fuels from Biomass (TMFB)Cluster of Excellence (2019 – 2025)
The Fuel Science Center (FSC)
funding:
Adaptive Conversion Systems for Renewable Energy and Carbon Sources
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DAS RHEINISCHE ZUKUNFTSREVIER
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TRANSFORMATION TOWARDS SUSTAINABILITY
Status-Quo – ‚Energiewende’ is mainly a TransformaGon of the Energy Sector
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 5
AGEE-Stat 2017
Proportion of Renewable Energies in Germany
in the sectors: Electricity, Heat and Transport
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TRANSFORMATION TOWARDS SUSTAINABILITY
Global Warming and Greenhouse-Gas Emissions
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 6
Source: Dezentrale Solarstromspeicher für die Energiewende, Berliner WissenschaGs-Verlag, (2015)
Previous development
Climate path
Tem
pera
ture
cha
nge
in �
C
Global warming by Anthropogenic Greenhouse Gases:
§ Up to 5�in 2100 without Mitigation Measures
332,2
166,8
126,4
65,2
136,6
CO2-Emissions [Mt CO2-equiv.]
Energy
Traffic & Transportation
Manufacturing Industries and Construction
Agriculture
Other SectorsSource: Umweltbundesamt; Na$onales
Treibhausgasinventar 04/2018
Temperature Change [°C]
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POWER-TO-X & INTEGRATED ENERGYTransi6on of Key Sectors towards Sustainability
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 7
Today: Petro-Chemical Value Chains Future: P2X for Integrated Energy
Fossil Resources
Gas CoalOil
Renewable Resources
CO2
DSM DSM
De-Carbonization De-Fossiliza6on
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Utilization
Valo
riza
+on
Storage‘INTEGRATED ENERGY’ SCENARIOPower-to-X as Key enabling Technology
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 8
Energy Sector
Mobility Sector
Chemistry Sector
Renewables
Fuel storage
Ba?ery storage
§ Reduction of Industrial Carbon Footprint
§ Sustainable Value Generation
Electrolysis
Fuel cell
Gas Sector
gas storageCo-electrolysis
Power-to-Gas
Power-to-Chemicals Power-to-Fuels
Power-to-Power
Feedstock
WasteBio
CO2
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Storage / Usage / Valoriza0on
CIRCULAR-ECONOMY SCENARIOPower-to-X as Key Enabling Technology
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 9
Circular Economy(Feedstock Defossiliza$on)
Integrated Energy(‘Sektorenkopplung‘)
Renewables
Electro-cataly0c Synthesis
Bulk Chemicals
Waste & Emissions
Hydro-carbons
‘Circular’ Fuels
Specialty Chemicals
Co-Electrolysis(H2O / CO2 / N2)
§ Chemical Produc$on using Renewables with CO2 from Emissions and (Waste) Water as Feedstock
§ Closed Carbon Loops
(Waste) Water
Air / Exhaust
Biomass
Electricity
H2O
CO2 (N2)
!"
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‘POWER-TO-GAS‘Transi1on of the Energy Sector (‘Energiewende’)
Objectives for Chemical Energy Storage:§ Intermittent Energy Supply & Consumption§ Long-term (seasonal) Energy Storage by Chemicals§ Reliable Energy Supply with Renewables
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry page 10
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H2-Vector(Cavern Storage)
POWER-TO-GAS-TO-POWERRound Trip Efficiency
Ins-tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 11
! "#"=%&
−(&
%
Re-electrification(GuD, Gas Turbine)
Storage(Gas Grid)
Chem. conversion(Methanation)
El.chem. conversion(H2O-Electrolysis)
High poten-al of improvement:Efficient Electrolyzer Cells
High poten-al of improvement:Efficient Fuel Cells
CH4-Vector(Grid Storage)
Power generation(Renewables)
el.
H2
CH4
CH4
* ≈ 65 − 80% * ≈ 80 − 85% * ≈ 85 − 95% * ≈ 35 − 55%100%H2O CO2
Re-electrificaJon(Fuel Cell)
Storage(Cavern)
El.chem. conversion(H2O-Electrolysis)
Power generaJon(Renewables)
el.
H2 H2
* ≈ 65 − 80% * ≈ 85 − 95% * ≈ 65 − 80%100%H2O
! "#"=(&
−34
%
Preis pro Tonne() H2 wird aus Methan hergestellt
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‘POWER-TO-FUELS’Transition of the Traffic & Transportation Sector (‘Verkehrswende’)
ObjecDves for Synfuels:§ Reduced CO2- & NOx-emissions
Ins4tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry page 12
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SYNFUELS
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 13
SynFuelsPrimary ProductsSyngas
Diesel
CO/H2Syngas
Fischer-Tropsch-ProductsCXHY, CXHYOH
Kerosin
Flüssiggas (LPG)
Methan (SNG)
MethanolCH3OH DME / OME
Benzin
Herstellung flüssiger KraSstoffe:– SyntheVsches Kerosin und Diesel über das Fischer-Tropsch-Verfahren– OYobenzin über die ProdukVon von syntheVsches Methanol mit anschließendem Methanol-to-Gasoline(MTG)-Verfahren– Oxymethylenether (OMEx) als Dieselersatz
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ENERGY DENSITY OF SYNFUELS
range, power
...R
ußem
issi
onen
(Sch
war
zrau
chza
hl) /
-
0.0
0.2
0.4
0.6
0.8
1.0
Stickoxidemissionen (NOx) / g/kWh0.00 0.25 0.50 0.75 1.00 1.25 1.50
EN590 Diesel Fischer-Tropsch Diesel Rapsmethylester (Biodiesel) OME1
D. Deutsch, D. Oestreich, L. Lautenschütz, P. Haltenort, U. Arnold, J. SauerChemie Ingenieur Technik 2017, 89, 486–489.
OMEx (1; 3 < x < 6)
Synfuel Emissions (Oxymethylene ether, OME)
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry Seite 14
Energy Storage CapaciPes
volumetric energy density [Wh/L]
spec
ific
ener
gy d
ensi
ty[W
h/kg
]
liquid fuelsgaseous fuels
baVeries
100008000600040002000
100
1 k
10 k
lead-acid
lithium-ion
CNG*(20 Mpa)high-pressure
hydrogen (35Mpa)
low-pressurehydrogen
ethanol
gasoline
bio-dieseldiesel
*CompressedNatural Gas
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FILLING STATION INFRASTRUCTURE (GERMANY)
Hydrogen Filling Station Infrastructure (future)Petrol Filling StaDon Infrastructure (exis+ng)
www.aral.de www.linde.com
Exis+ng infrastructure:§ 14.510 petrol filling sta+ons (2017)§ Capital cost per sta+on: ≈ 2.5 M€
Existing infrastructure:§ 17 hydrogen filling stations (2014)§ Capital cost per station: ≈ 1.0 – 2.5 M€
planned infrastructure (2023):§ 400 hydrogen filling stations (invest ≈ 400 – 1000 M€)
Nutzung bestehende
Tankstellen und -
InfrastrukturBeibehaltung bestehender
Konzepte
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‘POWER-TO-CHEMICALS’CO2 as Chemical Feedstock (‘Chemiewende’)
ObjecFves for CO2 as Chemical Feedstock:§ Chemical Produc/on using CO2, Water and Renewables
§ CO2 (and Biomass) as sole Carbon Source for Chemical Industry
Ins/tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry page 16
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VALORIZATION ... VALUE CHAINSShort History of Time – towards Power-to-Chemicals
Tagebau Hambach, RWE
Kohlechemie Petrochemie
Leuna Chemie BP
Golf von Mexico, Shell
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POWER-TO-CHEMICALSSustainable Value Chain – ‚green‘ syngas chemistry
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 18S. Foit, I.C. Vinke, L.G.J. de Haart, R.-A. Eichel, Angew. Chem. Int. Ed. 56 (2017) 5402 – 5411
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‘INTEGRATED ENERGY’ SCENARIOSPower-to-X as Key enabling Technology
ObjecDves for ‘Integrated Energy’ Scenarios (‘Sektorkopplung’):§ Reduc&on of GHG emissions by input of renewables into the sectors Chemical Industry, Heat, Traffic & Transporta&on
§ CO2-conversion as chemical Storage Op&on
Ins&tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry page 19
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‘INTEGRATED ENERGY’ SCENARIOAvailability of Renewables – Case Study ‚Synfuels‘
1 TWh (@ 550 MW rated power)
➞ ca. 40.000 t annual synfuel production
0.242 TWh (@ 60 MW rated power)
➞ ca. 10.000 t annual synfuel produc@on
‚Worldscale‘-Facility Alpha Ventus(45 km north Borkum)
‚Worldscale‘-Facility Topaz Solar Farm(California, USA)
Foto: NASA Foto: Deutsche Offshore-Testfeld und Infrastruktur GmbH & Co. KG Oldenburg
Assumption: 25 TWh ≡ 1 Mio. t trad. fuel
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‘INTEGRATED ENERGY’ SCENARIOAvailability of CO2 as Feedstock
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 21
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‘INTEGRATED ENERGY’ SCENARIOAvailability of Renewable Power
Institute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 22
Courtesy of DLR
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?
OFF-GRID SCENARIOSDecentralized or Autonomous Technologies
Ins$tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
page 23
➞ Scalability (‘Terawatt Challenge’) ➞ Versatility (Fuels, Chemicals, …)
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ACKNOWLEDGEMENTS
page 24
funding:
Ins+tute of Energy and Climate Research IEK-9: Fundamental Electrochemistry
Team High-Temperature P2X:
§ Dr. Lambertus G.J. de Haart§ Dr. Isaak C. Vinke§ Dr. Kevin Schiemann§ Dr. Vibhu Vaibhav
§ M.Sc. Severin Foit§ M.Sc. Lucy DiMrich§ M.Sc. Markus Nohl§ M.Sc. Kevin Schiemann§ M.Sc. Trutz Theuer§ et al.
Team Low-Temperature P2X:
§ Prof. Josef Granwehr§ Dr. Hans Kungl§ Dr. Hermann Tempel§ Dr. Peter Jakes§ Dr. Steffen Merz
§ Dr. Peter P.M. Schleker§ M.Sc. Jörg Ackermann§ M.Sc. Sven Jovanovic§ M.Sc. Ansgar Kretzschmar§ M.Sc. Emmanouil Verou+s§ M.Sc. Heeyong Park§ et al.