micromachining and nanoprocessing of gan/si for ghz

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Micromachining and nanoprocessing of GaN/Si for GHz acoustic resonators and UV photodetecting applications A. Müller, G. Konstantinidis, D. Neculoiu A. Dinescu, M. Dragoman, Alina Cismaru IMT Bucharest, 32B, Erou Iancu Nicolae Street, 077190 Bucharest, Romania, FORTH-IESL-MRG Heraklion, PO Box 1527, Crete, Greece [email protected]

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Page 1: Micromachining and nanoprocessing of GaN/Si for GHz

Micromachining and nanoprocessing of GaN/Si for GHz acoustic resonators and UV

photodetecting applications

A. Müller, G. Konstantinidis, D. NeculoiuA.Dinescu, M. Dragoman, Alina Cismaru

IMT Bucharest, 32B, Erou Iancu Nicolae Street, 077190 Bucharest, Romania,

FORTH-IESL-MRG Heraklion, PO Box 1527, Crete, Greece

[email protected]

Page 2: Micromachining and nanoprocessing of GaN/Si for GHz

OUTLINE

•Introduction

•GaN/Si FBAR resonators

•GaN/Si SAW resonators

•UV photodetectors on thin GaN membranes

•Conclusions

Page 3: Micromachining and nanoprocessing of GaN/Si for GHz

The most common WBG materials are SiC, GaN and AlNWBG materials exhibit unique physical properties like:

► high breakdown field► high electron saturation velocity ► high sound velocity► strong piezoelectric effects► high power capabilities ► high temperature environment

GaN and AlN present pronounced piezoelectric properties.

All these properties make them very attractive for microwave and millimeter wave applications and also for creating a new generation of sensing devices capable of working in harsh environments at temperatures higher than 600 °C.

Page 4: Micromachining and nanoprocessing of GaN/Si for GHz

►►Surface Acoustic Wave (SAW)Surface Acoustic Wave (SAW) and and ►►Film Bulk Acoustic Resonators (FBAR)Film Bulk Acoustic Resonators (FBAR)

have a major interest in the fabrication of radio frequency (RF)

1.1. filters for mobile and satellite communication systems, filters for mobile and satellite communication systems, 2.2. various forms of data transmission (WLAN). various forms of data transmission (WLAN).

- Most SAW resonators used in the actual mobile communicationsystems are manufactured on quartz, lithium tantalite or lithium niobate. - Classical technologies for FBAR resonators are based on ZnO

sputtered layers.

It becomes very difficult to achieve low-loss and sharp-cut off filters working at frequencies higher then 2 GHz

using the classical SAW and FBAR technologies

Page 5: Micromachining and nanoprocessing of GaN/Si for GHz

Because

►The cellular phone is evolving from a third generation (3G) system to a fourth generation (4G) system. The radio frequency of 4G systems is expected to be within the high-frequency range from 3 to 6 GHz.

► Using MEMS micromachining techniques and nanolithography,applied to WGB materials it is possible to obtain devices with low losses, and high operating frequency

► Also is important the possibility of monolithic or hybrid integration with other circuit elements (e.g. HEMT transistors), because these materials (GaN, AlN) can be grown or deposed on semiconductor wafers (high resistivity GaAs or silicon)

Sensors based on SAW and FBAR structures have the sensitivity ~f2

Page 6: Micromachining and nanoprocessing of GaN/Si for GHz

1.1. The The subsub--micron micron thicknessthickness of the of the GaNGaN or or AlNAlNmembrane in membrane in FBARFBAR devices can increase their devices can increase their operating frequencyoperating frequency

2.2. The use of The use of nanolithographynanolithography (fingers and (fingers and interdigitsinterdigits100100––300 nm wide),300 nm wide), to fabricate the interdigitated to fabricate the interdigitated transducer (IDT) of the transducer (IDT) of the SAWSAW structures will resulting structures will resulting an increasing of operating frequencyan increasing of operating frequency

3.3. Micromachining for Micromachining for GaNGaN/Si and the use of /Si and the use of nanolithographynanolithography for the MSM interdigitated for the MSM interdigitated structure can improve structure can improve UV UV photodetectorphotodetectorperformances and permits backperformances and permits back--side illuminationside illumination

WBG semiconductor technologies

Page 7: Micromachining and nanoprocessing of GaN/Si for GHz

AlN/Si GaN/Si•Deposition by magnetron sputtering

•Sound velocity 9000 m/s

•Coupling coefficient 6%

•Band gap 6.3 eV

•Deposition by MBE and MOCVD

•Sound velocity 7000 m/s

•Coupling coefficient 2%

•Nanolithography a big challenge

•Monolithic integration with HEMT transistors is possible

•Band gap 3.4 eV for UV photodetection

Page 8: Micromachining and nanoprocessing of GaN/Si for GHz

Surface Acoustic Wave ResonatorFBAR-Film Bulk Acoustic Resonator

NANOTECHNOLOGY AND NANOPROCESSINGNANOTECHNOLOGY AND NANOPROCESSING

vs ~ km/s; d, w ~nm, fr ~ GHz

Page 9: Micromachining and nanoprocessing of GaN/Si for GHz

GaN membrane supported series connection of two FBAR structures (test structures)

We develop for the first timea FBAR structure on a thin membrane!

increasing drasticaly the resonance frequency !

The GaN on silicon structure grown by MOCVD (Azzuro Ltd. Magdeburg)

A. Muller, D. Neculoiu, D. Vasilache, D. Dascalu, G. Konstantinidis, A. Kosopoulos, A. Adikimenakis, A. Georgakilas, K. Mutamba, C. Sydlo, H.L. Hartnagel, A. Dadgar, “GaN micromachinedFBAR structures for microwave applications”,

SuperlaticesSuperlatices & Microstructures& Microstructures, 40, 2006, pp , 40, 2006, pp 426426--431431

IMT- Bucharest-FORTH Heraklion –TU Darmstadt 2006

2.2 μm thin membrane

fr = 1,3 GHz

Page 10: Micromachining and nanoprocessing of GaN/Si for GHz

6.3 GHz resonance on a GaN FBAR obtained by micromachining of GaN/Si (1)

-540nm540nm {340 nm (GaN) +200nm (buffer)} thin membrane supported FBAR structure based on GaN micromachining -50nm thin Mo metallization GaN/Si wafers from NTT AT Japan

IMT and FORTH IMT and FORTH July 2008July 2008

Top view with top and bottom illumination

28 29 30 31 32 33 34 35 36 37100

101

102

103

104

15.5 16.0 16.5 17.0 17.5 18.0 18.5

0

20

40

60

80

100

FWHM=0.3803o

(0002)

I (a.

u.)

ω scan [o]

GaNBuffer

GaN(0002)

I [

cps]

2θ [o]

GaNSi(111)

Maximum deflection 2.7μm

White Light Interferometer

XRD

Cross section

Page 11: Micromachining and nanoprocessing of GaN/Si for GHz

6.3 GHz resonance on a GaN FBAR obtained by micromachining of GaN/Si (2)

IMT and FORTH July 2008

A. Müller, D. Neculoiu, G. Konstantinidis et al. “6.3 GHz Film Bulk Acoustic Resonator Structures Based on a Gallium Nitride/Silicon Thin Membrane”

IEEE Electron Devices Letters , IEEE Electron Devices Letters , volvol 30, no 8,30, no 8, August 2009, pp 799August 2009, pp 799--801801

5.8 6.3 6.8 7.3 7.4Frequency (GHz)

FBAR_GaN

100

120

140

160

180

IZI

6.219 GHz103.7 Ohm

6.306 GHz175.63 Ohm

Qsp= fsp/(f2-f1), where fsp is the resonance frequency (series or parallel), f1 and f2 are the frequencies at which the magnitude of the input impedance is ½ from its resonance (anti-resonance) value

fr=6.3 GHz

540 nm thin membrane

(VNA) Vector Network Analyzer characterization in

microwaves

Qp=1130

Page 12: Micromachining and nanoprocessing of GaN/Si for GHz

Last results• It is under test a run processed in Dec 2009•• 350nm350nm {200 nm (GaN) +150nm (buffer)} thin membrane supported

FBAR structure based on GaN micromachining ,

• 50nm thin metallization (top) and 120nm bottom

S parameter of the FBAR series connection structure

Resistance and conductance of the FBAR series connection structure

(Preliminary results)

fr= 9 GHz

350 nm thin membrane

Page 13: Micromachining and nanoprocessing of GaN/Si for GHz

SAW devicesSAW devices for GHz applications with nanolithographicnanolithographic IDTsIDTsResults obtained on AlN ( IMT-FORTH-NIMP)

D. Neculoiu, A. Müller, G. Deligeorgis, A. Dinescu, A. Stavrinidis, D. Vasilache, A. Cismaru, G. E. Stan and G. Konstantinidis,“AlN on silicon based Surface Acoustic Wave resonators operating at 5 GHz”

Electron. Electron. LettLett. 45, 1196 (2009). 45, 1196 (2009) Best previous result obtained before was a SAW on AlN (but on diamond not on silicon) operating at 4.5 GHz [P. Kirsch et al. Appl Phys. Lett.88, 223504, 2006]

Fingers and Fingers and interdigitsinterdigits250 nm wide250 nm wide

4.6 4.8 5 5.2 5.4frequency, GHz

-70

-65

-60

-55

-50

-45

-40

S21

, dB

Best results up on Best results up on AlNAlN,,

First results on First results on AlN/SiAlN/Si !!

Results 2009Results 2009Resonance > Resonance > 5GHz !!5GHz !!

Page 14: Micromachining and nanoprocessing of GaN/Si for GHz

SAW resonators on SAW resonators on GaN/SiGaN/Si with fingers and with fingers and interdigitsinterdigits 250 nm250 nm wide (up) wide (up) and and 150nm 150nm widewide (down) (down) patterned in IMTpatterned in IMT on the new on the new

““EE--LineLine”” equipment from equipment from RaithRaith (electron beam (electron beam lithography)lithography)

GaN SAW structures manufactured using nanolithography

250nm

150nm 150nm

GaN

150nm

February 2009

Page 15: Micromachining and nanoprocessing of GaN/Si for GHz

Recent results SAW on GaN/Si -1(IMT – FORTH 23 Dec 2009)

5.8 6.3 6.8 7.3 7.4Frequency (GHz)

SAW_GAN_150 nm

-41

-40.5

-40

-39.5

-39

-38.5

-38

S21

Para

met

er [d

B]

7.062 GHz-40.612 dB

GaN SAW structures with fingers and interdigits 150 nm wideresonating at a frequency 7 GHz

unpublished

Page 16: Micromachining and nanoprocessing of GaN/Si for GHz

3.2 3.6 4 4.4 4.8Frequency (GHz)

SAW_300 nm

-70

-60

-50

-40

-30

S21

para

met

er [d

B]

3.93 GHz-67.49 dB

GaN SAW structure with fingers and interdigits 300 nm300 nm wide resonating at a frequency close to 4 GHz

Recent results SAW on GaN/Si -1(IMT – FORTH 23 Dec 2009)

unpublished

Page 17: Micromachining and nanoprocessing of GaN/Si for GHz

UV photodetectors have an important commercial and scientific interest for:

• engine control • astronomy• lithography aligners• solar UV monitoring• space-to-space communications,• detection of missiles

Most of these applications fit in the optical spectrum range 200–370 nm covered by nitrides, in particular by GaN and AlGaN compounds.

Most used photo detectors devices are based on metal-semiconductor metal (MSM) interdigitated structures due to their simplicity

UV photodetectors

Page 18: Micromachining and nanoprocessing of GaN/Si for GHz

The main The main ideeaideea was to manufacture was to manufacture

a UV a UV photodetectorphotodetector on a membraneon a membranePotential advantages:

1. reduction of losses,

2. increased responsivity,

3. possibilty of back-side illumination

2.2 µm thin GaNmembrane

1 μm wide digit and interdigit

A.A. MMüüllerller, G. , G. KonstantinidisKonstantinidis, M. Dragoman, D. , M. Dragoman, D. NeculoiuNeculoiu, A. , A. KostopoulosKostopoulos, , M.AndroulidakiM.Androulidaki, M. , M. KayambakiKayambaki and D. and D. VasilacheVasilache „„GaNGaN membrane metalmembrane metal––semiconductorsemiconductor––metal ultraviolet metal ultraviolet photodetectorphotodetector””

APPLIED OPTICS, Vol. 47, No. 10, 2008, pp 1453APPLIED OPTICS, Vol. 47, No. 10, 2008, pp 1453--14561456

MSM GaN membrane test structure for UV detection (first run 2007)

Page 19: Micromachining and nanoprocessing of GaN/Si for GHz

Membrane technology+ Nanolithography

780 nm (0.28 buffer+0.5 GaN) thin membrane

500 nm wide finger/ interdigit detector structure

Semitransparent Schottkymetallization 5/10nm Ni/Au

SEM photo (left)and detail (right) for the 0.5 µm wide finger/ interdigitdetector structure manufactured on a 0.78 µm thin GaN membrane

300 320 340 360 380 400

0

50

100

150

200

250

2.5V 5V 6V 10V 15V

R(A

/W)

λ(nm)

#1

Responsivity vs wavelength for the 0.5µm finger / interdigit for two UV detector structures-

manufactured on 0.78µm thin GaN membrane

A.MullerA.Muller , G. , G. KonstantinidisKonstantinidis , M. Dragoman , D. , M. Dragoman , D. NeculoiuNeculoiu , , A. A. DinescuDinescu , M. , M. AndroulidakiAndroulidaki , M. , M. KayambakiKayambaki, A. , A. StavrinidisStavrinidis, D. , D. VasilacheVasilache, C. , C. BuiculescuBuiculescu, I. , I. PetriniPetrini, A. , A. KostopoulosKostopoulos, D. , D. DascaluDascalu,, “GaN membrane-supported UV photodetectors manufactured using nanolithographic processes”

Microelectronics Journal, Microelectronics Journal, 40 (2009), pp. 31940 (2009), pp. 319--321321

Higher responsivity !

Very low dark current !

MSM GaN membrane test structure for UV detection (second run 2008)

Page 20: Micromachining and nanoprocessing of GaN/Si for GHz

100nm

200nm 500nm

RECENT resuts (IMT-FORTH Dec 2009)characterization in progress

••Excellent Excellent yeldyeld! for ! for GaNGaN where where nanonano processing is very difficultprocessing is very difficult

••Structures with fingers and Structures with fingers and intedigitsintedigits 100nm, 200nm, 500nm 100nm, 200nm, 500nm succefullysuccefully achieved due to a achieved due to a very reliable very reliable nanonano--lithographic lithographic process ( Eprocess ( E--Line equipment)Line equipment)

NANOLITHOGRAPHY AT IMT

100nm

5/10nm Ni/Au

Page 21: Micromachining and nanoprocessing of GaN/Si for GHz

CONCLUSIONS •First FBAR structures on GaN/Si have been developed a suspended technology based on very thin ( up to 350nm) self sustainable membranes has been developed having a resonance at 6.3 GHz (with Q>1100) and more, has been obtained.

• Nanolithographic process was successfully developed on GaN/Si. IDTs with fingers and interdigits 150nm and 250nm wide have been obtained with an yield of about 70-75%. SAW structures resonating at frequencies in the 5-7 GHz have been obtained for the first time on GaN.

•A new type of UV photodetector structure, based on micromachining and nanoprocessing of GaN/Si has been developed, for the first time. The new structure has low dark current, very high responsivity and offers the possibility of back-side illumination.

Page 22: Micromachining and nanoprocessing of GaN/Si for GHz

Thank you for your attention !

AcnowledgementsThe author agnowledge:

The EC support under the FP 6 AMICOM project and the FP7 MIMOMEMS and MEMS 4 MMIC projects.

ANCS for the support under the MIMFOMEMS and GIGASABAR PNII projects