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Page 1: Main Menu Boyle’s Problems Main Menu

Gas Laws used in Chemistry

Ms. Ciceraro

Page 2: Main Menu Boyle’s Problems Main Menu

Chemistry The Gas

LawsThe following PowerPoint

presentation will explore, explain, and elaborate on three of the Gas

Laws. By engaging in exercise problems Charles’, Boyle’s and the

Ideal Gas Law will be evaluated.

Page 3: Main Menu Boyle’s Problems Main Menu

Let’s take a look at some of the Gas Laws:

Boyle’s Law

Charles’ Law

Ideal Gas Law

Page 4: Main Menu Boyle’s Problems Main Menu

Boyle’s LawExplanation

FormulaPictureVideo

ProblemsExcel

Main Menu

Page 5: Main Menu Boyle’s Problems Main Menu

Boyle’s LawExplanation: The volume of a gas at a given temperature varies inversely with

the applied pressure.

As the pressure increases the volume decreases.

Main Menu

Page 6: Main Menu Boyle’s Problems Main Menu

Boyle’s LawFormula:

PIVI= PFVF

Where: PI= Initial Pressure VI= Initial Volume PF= Final Pressure VF= Final Volume

Main Menu

Page 7: Main Menu Boyle’s Problems Main Menu

Boyle’s Law

A picture is worth a thousand words…

Main Menu

Page 8: Main Menu Boyle’s Problems Main Menu

Boyle’s Law

What is this Boyle’s Law thing all about??

Boyle’s Law Video

Main Menu

Page 9: Main Menu Boyle’s Problems Main Menu

Problem 1

Problem 2

Problem 3

Problem 4

Problem 5

Problem 6

Problem 7

Problem 8

Problem 9

Problem 10

Boyle’s Law

Main Menu

Page 10: Main Menu Boyle’s Problems Main Menu

Problem 1:

A final volume of air occupies 0.50 L and it has a final

pressure of 3 atm. If your initial volume is 0.250 L, what is your initial pressure in atm?

a. 60.0 atm

b. 0.6 atm

c. 6.0 atm

Boyle’s LawMain Menu

Boyle’s Problems

Page 11: Main Menu Boyle’s Problems Main Menu

Problem 2:

A final volume of air occupies 0.50 L and it has a final

pressure of 3 atm. What is your initial volume is, if your initial pressure is 1.5 atm?

a. 1.0 L

b. 10.10L

c. 0.10 L

Boyle’s Law

Boyle’s Problems

Main Menu

Page 12: Main Menu Boyle’s Problems Main Menu

Problem 3:

A final volume of air occupies 0.50 L. If your initial volume is 1.00 L, and your initial pressure is 4.75 atm, what is your pressure final?

a. 9.5 atm

b. 0.95 atm

c. 95.0 atm

Boyle’s Law

Boyle’s Problems

Main Menu

Page 13: Main Menu Boyle’s Problems Main Menu

Problem 4:

What is the final volume if you have a final pressure of 3 atm, your initial volume is 1.50 L, and your initial pressure is 17 atm?

a. 8.5L

b. 0.85 L

c. 85.0 L

Boyle’s LawMain Menu

Boyle’s Problems

Page 14: Main Menu Boyle’s Problems Main Menu

Problem 5:

A final volume of air occupies 0.50 L and it has a final

pressure of 3 atm. If your initial volume is 1.75 L, what is your

initial pressure in atm?

a. 1.00 atm

b. 0.86 atm

c. 0.92 atm

Boyle’s LawMain Menu

Boyle’s Problems

Page 15: Main Menu Boyle’s Problems Main Menu

Problem 6:

What is the final volume of air if it initially occupies 0.50 L and 3 atm and your final pressure is

2.00 atm.

a. 14.00 atm

b. 7.50 atm

c. 0.75 atm

Boyle’s LawMain Menu

Boyle’s Problems

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Problem 7:

What is the final pressure of air if it initially occupies 0.50L and a pressure of 3atm and your final volume is 2.75 L, what is your

final pressure in atm?

a. 0.55 atm

b. 5.20 atm

c. 1.5 atm

Boyle’s LawMain Menu

Boyle’s Problems

Page 17: Main Menu Boyle’s Problems Main Menu

Problem 8:

What is the initial volume if you have a final volume of air occupying 0.50 L and a

pressure of 3 atm, and your initial pressure is 4.50atm?

a. 3.00 L

b. 2.36 L

c. 0.33 L

Boyle’s Law

Boyle’s Problems

Main Menu

Page 18: Main Menu Boyle’s Problems Main Menu

Problem 9:

What is the initial pressure if air occupies at the end 0.50 L and it

5 atm. If your initial volume is 6.00 L?

a. 0.42 atm

b. 4.20 atm

c. 42.0 atm

Boyle’s Law

Boyle’s Problems

Main Menu

Page 19: Main Menu Boyle’s Problems Main Menu

Problem 10:

What is the final volume of air if it initially occupies 0.32 L and

7.25 atm and in the end has a pressure is 9.80 atm?

a. 2.36 L

b. 23.6 L

c. 0.24 L

Boyle’s Law

Boyle’s Problems

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Page 20: Main Menu Boyle’s Problems Main Menu

Charles’ LawExplanation

FormulaPictureVideo

ProblemsExcel

Main Menu

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Charles’ LawExplanation:The volume occupied by any sample of

gas at a constant pressure is directly proportional to the absolute temperature.

As the temperature increases the volume increases.

Main MenuCharles’ Law

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Charles’ LawFormula:

VI/TI= VF/TF

Where:

VI= Initial Volume TI= Initial Temperature

VF= Final Volume TF= Final Temperature

Main MenuCharles’ Law

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Charles’ Law

A picture is worth a thousand words…

Main MenuCharles’ Law

Page 24: Main Menu Boyle’s Problems Main Menu

Charles’ Law

What is this Charles’ Law thing all about??

Charles’ Law Video

Main MenuCharles’ Law

Page 25: Main Menu Boyle’s Problems Main Menu

Problem 1

Problem 2

Problem 3

Problem 4

Problem 5

Problem 6

Problem 7

Problem 8

Problem 9

Problem 10

Charles’ Law

Main MenuCharles’ Law

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Problem 1:

What is the initial volume of oxygen that can be obtained from a

particular tank at 1.0 atm and that has a final volume and

temperature of 305 K and 1.52 L (including the volume remaining

in the tank). With an initial temperature of 273.89 K.

Charles’ Law

A) 1.36 L

B) 1.24 L

C) 1.14 L

Main Menu

Charles’ Law Charles’ Problems

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Problem 2:

What is the initial temperature of oxygen that can be obtained from a particular tank at 1.73 atm and

that has a final volume and temperature of 305 K and 1.52 L (including the volume remaining

in the tank). With an initial volume of 73.89 L.

Charles’ Law

A) 1.4827 K

B) 148.27 K

C) 14826.61 K

Main Menu

Charles’ Law Charles’ Problems

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Problem 3:

What is the final volume of oxygen that can be obtained from a

particular tank at 3.86 atm and that had a inital volume and

temperature of 325 K and 3.58 L (including the volume remaining

in the tank). With an final temperature of 273.89 K.

Charles’ Law

A) 1.337 L

B) 3.017 L

C) 1.627 L

Main Menu

Charles’ Law Charles’ Problems

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Problem 4:

What is the final temperature of oxygen that can be obtained from a particular tank at 4.37 atm and its initial temperature and volume

are 305 K and 1.52 L (including the volume remaining in the tank)

and its final volume is 3.28L.

Charles’ Law

A) 658.16K

B) 65.816 K

C) 6.5816 K

Main Menu

Charles’ Law Charles’ Problems

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Problem 5:

What is the initial volume of oxygen that can be obtained from a

particular tank at 1.0 atm and its final temperature and volume are 423.86 K is 13.21 L (including the volume remaining in the tank) and the initial temperature was 257.49

K?

Charles’ Law

A) 8.02 K

B) 80.2 K

C) 0.802K

Main Menu

Charles’ Law Charles’ Problems

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Problem 6:

What is the initial temperature. If the final temperature and

volume of oxygen that can be obtained from a particular tank at 1.0 atm and 285 K is 5.23 L

(including the volume remaining in the tank), and the initial volume had been 4.73 L.

Charles’ Law

A) 2.57 L

B) 257.75 L

C) 25.75 L

Main Menu

Charles’ Law Charles’ Problems

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Problem 7:

The total volume of oxygen that can be obtained from a particular tank at 1.0 atm and 305 K is 1.52 L (including the volume remaining in the tank). What would be this volume of oxygen if the temperature had been 358.40 K.

Charles’ Law

A) 1.59 L

B) 1.29 L

C) 1.32 L

Main Menu

Charles’ Law Charles’ Problems

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Problem 8:

The total volume of oxygen that can be obtained from a particular tank at 1.0 atm and 305 K is 1.52 L (including the volume remaining in the tank). What would be this volume of oxygen if the temperature had been 361.52 K.

Charles’ Law

A) 1.33 L

B) 1.48 L

C) 1.28 L

Main Menu

Charles’ Law Charles’ Problems

Page 34: Main Menu Boyle’s Problems Main Menu

Problem 9:

The total volume of oxygen that can be obtained from a particular tank at 1.0 atm and 305 K is 1.52 L (including the volume remaining in the tank). What would be this volume of oxygen if the temperature had been 365.17 K.

Charles’ Law

A) 1.27 L

B) 1.14 L

C) 1.60 L

Main Menu

Charles’ Law Charles’ Problems

Page 35: Main Menu Boyle’s Problems Main Menu

Problem 10:

The total volume of oxygen that can be obtained from a particular tank at 1.0 atm and 305 K is 1.52 L (including the volume remaining in the tank). What would be this volume of oxygen if the temperature had been 373.15 K.

A) 1.29 L

B) 1.33 L

C) 1.24 L

Charles’ Law

Charles’ Law Charles’ Problems

Main Menu

Page 36: Main Menu Boyle’s Problems Main Menu

Ideal Gas LawExplanation

FormulaPictureVideo

ProblemsExcel

Back to Main Menu

Page 37: Main Menu Boyle’s Problems Main Menu

Ideal Gas LawExplanation:The ideal gas law is the combination of not only

Charles’ and Boyle’s laws but also of Avogadro’s law.

As long as you know 3 out of the 5 variables- and R (universal gas constant) is always constant you can algebraically manipulating the ideal gas law formula you can see the different relationships between Temperature, Volume, Pressure, and amount of moles.

Ideal Gas Law Main Menu

Page 38: Main Menu Boyle’s Problems Main Menu

Ideal Gas LawFormula:

PV= nRTWhere:

P= Pressure V= Volume T= Temperature n= moles

R= Gas Constant 8.314 J/k*mol

R= Gas Constant 0.0821 (L*atm)/(mol*K)

R= Gas Constant 8.314 (Pa*m3)/(k*mol)

Main MenuIdeal Gas Law

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Ideal Gas Law

A picture is worth a thousand words…

Main MenuIdeal Gas Law

Page 40: Main Menu Boyle’s Problems Main Menu

Ideal Gas Law

What is this Ideal Gas Law thing all about??

Ideal Gas Law Video

Main MenuIdeal Gas Law

Page 41: Main Menu Boyle’s Problems Main Menu

Problem 1

Problem 2

Problem 3

Problem 4

Problem 5

Problem 6

Problem 7

Problem 8

Problem 9

Problem 10

Ideal Gas Law

Main MenuIdeal Gas Law

Page 42: Main Menu Boyle’s Problems Main Menu

Problem 1:

A balloon contains 0.76 moles of He. He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

i) 0.70124 L

ii) 0.7124 L

iii) 0.7612 L

Ideal Gas Problems

Main Menu

Ideal Gas Law

Ideal Gas Law

Page 43: Main Menu Boyle’s Problems Main Menu

i) 1.35 atm

ii) 1.27 atm

iii) 1.11 atm

Problem 2:

A balloon contains 1.11 moles of He, He is at 305 K and 25 L. What is the pressure of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

Page 44: Main Menu Boyle’s Problems Main Menu

i) 2.47 moles

ii) 2.67 moles

iii) 2.53 molesProblem 3:

A balloon contains 2.67 liters of He, He is at 305 K and 25 atm. How many moles of the gas are in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

Page 45: Main Menu Boyle’s Problems Main Menu

i) 0.041 (L*atm)/(mol*K)

ii) 0.021 (L*atm)/(mol*K)

iii) 0.039 (L*atm)/(mol*K)Problem 4:

A balloon contains 3.92 moles of He, He is at 305 K, 1.0L and 25 atm. What is the gas constant of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

Page 46: Main Menu Boyle’s Problems Main Menu

i) 20278.28K

ii) 25573.21 K

iii) 24628.43KProblem 5:

A balloon contains 4.58 moles of He, He is at 305 L and 25 atm. What is the temperature of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

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i) 530.48 L

ii) 427.96 L

iii) 503.84 LProblem 6:

A balloon contains 5.23 moles of He, He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

Page 48: Main Menu Boyle’s Problems Main Menu

i) 541.73 L

ii) 637.78 L

iii) 650.17 LProblem 7:

A balloon contains 6.41 moles of He, He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

Page 49: Main Menu Boyle’s Problems Main Menu

i) 795.22 L

ii) 802.37 L

iii) 692.12 LProblem 8:

A balloon contains 7.84 moles of He, He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

Ideal Gas Law

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Ideal Gas Law

i) 824.11 L

ii) 844.92 L

iii) 854.73 LProblem 9:

A balloon contains 8.33 moles of He, He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

Main Menu

Ideal Gas Law Ideal Gas Problems

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Ideal Gas Law

i) 993.47 L

ii) 888.95 L

iii) 986.92 LProblem 10:

A balloon contains 9.73 moles of He, He is at 305 K and 25 atm. What is the volume of the gas in the balloon?

Main Menu

Ideal Gas ProblemsIdeal Gas Law

Page 52: Main Menu Boyle’s Problems Main Menu

Excelling with the Gas LawsClick on the Excel icon and

input your own values. You will be able to see graphs

of the various Gas Law relationships.

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Picture Images:http://www.astronomynotes.com/starsun/idealgas-anim.gifhttp://upload.wikimedia.org/wikipedia/commons/thumb/c/cb/Travel

_problem.svg/350px-Travel_problem.svg.pnghttp://kaffee.50webs.com/Science/images/KTG.PV.constant.nT.gifhttp://www.chemistryland.com/CHM130/Web-PowerPoints/Gases_P

V_nRT.jpghttp://www.ttlearning.com/images/jp_boyle.jpg

References

Page 58: Main Menu Boyle’s Problems Main Menu

Ebbing, Darrell, and Steven Gammon. General Chemsitry 6th Edition. New York: Houghton Mifflin Company, 1999.

References

Page 59: Main Menu Boyle’s Problems Main Menu

WOOHOO! You are correct.

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 60: Main Menu Boyle’s Problems Main Menu

AWESOME!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 61: Main Menu Boyle’s Problems Main Menu

You are a real Gas Law Wizard!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 62: Main Menu Boyle’s Problems Main Menu

Excellent!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 63: Main Menu Boyle’s Problems Main Menu

Super!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 64: Main Menu Boyle’s Problems Main Menu

Way to go!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 65: Main Menu Boyle’s Problems Main Menu

Good Job!Main Menu

Boyle’s ProblemsCharles’ Problems

Ideal Gas Problems

Page 66: Main Menu Boyle’s Problems Main Menu

Correct!

Main MenuIdeal Gas Problems

Charles’ Problems Boyle’s Problems

Page 67: Main Menu Boyle’s Problems Main Menu

Boyle’s Law

Let us look at that calculation again...

PIVI= PFVF

Where:

PI= Initial Pressure VI= Initial Volume

PF= Final Pressure VF= Final Volume

Boyle’s Problems

Main Menu

Page 68: Main Menu Boyle’s Problems Main Menu

Charles’ Law

Let us look at that calculation again...

VI/TI= VF/TF

Where:

VI= Initial Volume TI= Initial Temperature VF= Final Volume TF= Final Temperature

Charles’ Law Charles’ Problems

Main Menu

Page 69: Main Menu Boyle’s Problems Main Menu

Ideal Gas Law

Let us look at that calculation again...

PV= nRTWhere:

P= Pressure V= Volume T= Temperature n= moles R= Gas Constant 8.314 J/k*mol

Ideal Gas Law Ideal Gas Problems

Main Menu