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9621 – Soil Remediation Engineering
Spring 2012
Faculty of Engineering & Applied Science
Lecture 2: Soil Properties and
Groundwater Flow
1
Each discipline defines soil in a different way,
depending on how soil affects it
“In an engineering sense, soil is the relatively loose
agglomerate of mineral and organic materials and
sediments found above the bedrock.”
--- R.D. Holtz and W.D. Kovacs (1981)
2.1 Soil properties
2.1.1 What is soil?
Soils equation
Soil = f (parent material, climate, biota, topography, time)
2
Soil composition
About 50% of the soil solid particles
45% - Minerals
5% - Organic matter
About 50% of soil should be pore space
25% - Air/Pore space
25% - Water
3 Source: Codutoet al., Geotechnical Engineering, 2011
Air
Water
Soil
Soil composition by phase:
s-soil (dry) w-water a-air
v-void (pores filled with water or air)
V is volume
M is mass
4
(1) Soil profile
Soil profile layers of soil are called horizons
Typical profile
A Horizon topsoil
B Horizon subsoil
C Horizon bedrock
A Horizon
B Horizon
C Horizon
2.1.2 Physical characteristics of soil
5
Soil texture the way the soil “feels”
depends on the amount of each size of mineral
particles in the soil
Sand, silt, and clay are names that describe the
size of individual mineral particles in the soil
(2) Soil texture
Sand the largest particles and they fell “gritty”
Silt medium sized, and they feel soft, silky or
“floury”
Clay the smallest sized particles, and they feel
“sticky”
6
Soil texture: Relative size comparison of soil particles
7
Source: Codutoet al., Geotechnical Engineering, 2011
Soil texture triangle represents 12 textural classes
Different
combinations of
coarse and fine
contents produce
different soil
textures
A loam a
mixture of sand,
silt and clay
Soils are more cohesive when they have more fine particles
Clay
Soils are more loose when the have more coarse particles
Sand
8
Source: Codutoet al., Geotechnical Engineering, 2011
Bulk density a measure of soil compaction soil weight
per unit soil volume
To calculate bulk density:
1 cm (so, there is 1 cubic
centimeter of soil)
Sample is made
of solids and
pore spaces 1.33 gms
Volume = 1 cm3
Weight = 1.33 g
Bulk density = WT VT
Bulk density = 1.33
1
Bulk density = 1.33 g/cm3
(3) Soil bulk density (ρd)
9
Bulk density and compaction zones
8 inches
1.43
0 inches
7 inches
9 inches 10 inches
Depth Bulk Density (grams/cm3)
1.90
1.87
1.84
1.80
1.60
Plow layer
Compacted zone
Uncompacted
subsoil
Low BD = high porosity High BD = low porosity
10
(4) Soil moisture content
Soil moisture content the quantity of water
contained in a soil
Volumetric moisture content, θ defined mathematically
as
where
VW = the volume of water
VT = VS + VV = VS + VW + Va = the total volume (that is soil
volume + water volume + air space)
T
w
V
V
11
Gravimetric moisture content, u expressed by mass
(weight) as follows:
where
MW = the mass of water
MS = the mass of soil
s
w
M
Mu
12
Groundwater Soil
Soil at different moisture levels
Pore Space
Water on soil particle surface Pore Spaces are filled with water
13 Source: Codutoet al., Geotechnical Engineering, 2011
(1) Soil pH or Hydrogen-ion activity
Soil pH a measure of the relative amount of H+
ions indicates the acidity or the alkalinity of a
solution (a soil solution) pH meter
pH = -log [H+]
In a soil it is driven by the ionization of soil water
pH scale ranges from 0 to 14
7 is considered neutral
Everything greater than 7 is considered alkaline
(basic)
Everything less than 7 is considered acidic
2.1.3 Chemical characteristics of soil
14
(2) Soil surface charge
Coarse-grained soil such as gravel, sand and silt are
chemically inert
The surface of clay minerals and organic matters
(OM) in soil generally carry electro-negative charges
Clay Particle
- -
- -
- - - - - - - - -
15 Source: Codutoet al., Geotechnical Engineering, 2011
Ionization on edges it is pH-dependent, similar
to charge on OM just as in the case of a weak acid
Isomorphous substitution in clays it is not
affected by pH often referred to as permanent
charges
- Substitution of Al3+ for Si4+ in the tetrahedral
layer of clays
- Substitution of Mg2+ for Al3+ in the octahedral
layer of clay
Sources of charge on clays
16
(3) Cation exchange capacity (CEC)
CEC = quantity of exchangeable cations per unit
weight of soil
The capacity of a soil to adsorb and exchange cations
(positively charge ions, Ca2+, Mg2+, K+, Na+, NH4+ ,
Al[OH]2 +, Al3+, and H+)
CEC due to the net negative charge of soil
colloids (clays and organic matter)
Both ionization and isomorphous substitution impart
CEC to clays
Total CEC of the soil is dependent upon the
amount of these sources and also upon the surface area
of clays exposed
17
With Magnets
-
-
+
-
Unlikes Attract
Likes Repel
In soil
CLAY
NH4+
Ammonium
CLAY
K+
Potassium
CLAY
NO3-
Nitrate
+
-
+ +
18 Source: Codutoet al., Geotechnical Engineering, 2011
Cation exchange the replacement of one
adsorbed cation for another from solution
-
-
-
-
-
-
..Na+
..Na+ [Ca2+]
-
-
-
-
-
-
..Ca2+ [Na+]
[Na+]
Negatively-charged clay
Dissolved in soil solution
+ +
2XNa+ + Ca2+ XCa2+ + 2Na+
19
It is water that exists beneath the earth's surface in
underground streams and aquifers
It is found that underground where part/entire void spaces
between particles of rock and soil, or in crevices and cracks
in rock are filled with water
2.2 Groundwater flow
2.2.1 Introduction
20
(1) Groundwater
Sand and gravel Igneous rocks limestone
Intergranular Crevice Solution
2.2 Groundwater flow
2.2.1 Introduction
Source: Codutoet al., Geotechnical Engineering, 2011
Groundwater an important part of the hydrologic cycle
Some of the water from melting snow/rainfall seeps into the
soil and percolates into the saturated zone to become
groundwater recharge
Eventually, groundwater reappears above the ground into
streams, rivers, marshes, lakes and oceans or as springs and
flowing wells discharge
21
Source: Environment Canada, 1990
22
Groundwater contains 98.7% of the fresh water
resources and is a reserve of good quality water
Percentage of population reliant on
Groundwater in Canada
Groundwater and the
world‘s freshwater supply
Source: Statistics Canada, 1996
Groundwater faces the threat of contamination from waste sites
Properties of subsurface govern both the rate and direction of
groundwater flow
(2) Vertical distribution of groundwater
Groundwater can be characterized according to its vertical
distribution
23
Soil water zone extending from ground surface
down through the major root zone
Vadose zone extending from lower edge of soil
water zone to the upper limit of capillary zone
Capillary zone extending from the water table up
to the limit of capillary rise
Zone of aeration consists of interstices occupied partially
by water and partially by air
Zone of saturation all interstices are filled with water
under hydrostatic pressure
24
Source: Bedient et al., Hydrology and Floodplain Analysis, 2007
25
(3) Aquifer
A formation that contains sufficient saturated permeable
material to yield significant quantities of water to wells and
springs
Type of aquifers
Confined aquifer (artesian aquifer) groundwater is
confined by a relatively impermeable stratum, or
confined unit, and water is under pressure greater than
atmosphere artesian wells or flowing wells
Unconfined aquifer (water table aquifer) an
aquifer in which the water table forms the upper
boundary the water level in a well tapping an
unconfined aquifer will rise only to the level of the water
table within the aquifer
26
Perched aquifer a perched water table, an example
where an unconfined water body sits on top of a clay lens,
separated from the main aquifer formed perched
aquifer
Leaky aquifer upper or lower boundary is semi-
pervious stratum could be confined or unconfined
leaky aquifer
Piezometric surface an imaginary surface coinciding
with the hydrostatic pressure level of the water in the certified
aquifer elevation of the surface at a given point can be
determined by finding water level in a penetrating well
Water table the upper surface of the saturation zone
under atmospheric pressure
27 Source: Bedient et al., Hydrology and Floodplain Analysis, 2007
Water filled porosity θw (or nW) volumetric soil
moisture content
Air filled porosity θg (or θa, na)
Total porosity
28
It is the ratio of voids volume to
the total volume of medium
(1) Porosity (n)
2.2.2 Subsurface hydraulic properties and groundwater
flow
In the zone of areation
aWn
In the zone of saturation porosity is an index of how
much total groundwater can be stored in the void space of
the saturated medium not indicate how much water the
porous medium will yield
Effective porosity (ne) the ratio of the volume of the
void space through which flow can occur to the total
volume less than total porosity n
Specific yield of an aquifer (Sy) the ratio of the
volume of water that drains from saturated material due to
the attraction of gravity to the total volume in most
cases, ne = Sy
Specific retention of an aquifer (Sr) the ratio of
volume of water that is retained against the force of
gravity to the total volume
Total porosity
29
In the zone of saturation
ry SSn
Air
Water
Soil
30
taa VV
VtWW sVVV
tV nVV
sw uMM
tds VM
Soil composition by phase
(2) Hydraulic conductivity (K)
Hydraulic conductivity (or permeability) is defined as
the property of a porous media that permits the
transmission of water through it
K can be obtained through using Darcy’s Law
In 1856, Henri Darcy investigated the flow of water
through beds of permeable sand. The followed figure
shows the experimental set-up for determining head loss
through the sand column
Darcy experimented with different soils and with
different values of L, h1, and h2. The results showed
31
L
hhKA
dL
dhKAQ
21
32 Head loss through a sand column (z = elevation)
Source: Zhang, Engineering Hydrology, 2003
Where, Q = volumetric flow rate or total discharge K = coefficient of permeability or hydraulic conductivity A = cross-sectional area of flow h = hydraulic head; h1 h2 = head loss L = length of flow path; dh/dL = i = hydraulic gradient
KiAL
hhKA
dL
dhKAQ
21
33
Hydraulic conductivity a measure of the
permeability of the porous media or, say, an indication of
an aquifer’s ability to transmit water
Its value usually depends on the size and number of
pores in the soil or aquifer material
It has the dimensions of length/time (L/T) or velocity,
such as cm/sec, ft/day
Source: Bedient et al., Hydrology and Floodplain Analysis, 2007
34
An expression for hydraulic conductivity in terms of
fluid and porous media properties
K = cd2g/
Where
c = a dimensionless constant
d = mean grain diameter
= fluid density
= fluid absolute viscosity
g = gravitational acceleration
The product cd2 is a function only of the porous media
and are functions of the fluid
The intrinsic permeability k is a property of the
medium (soil or rock) only, independent of fluid properties
k = cd2 and K= kg/
(3) Groundwater movement velocity
Darcy’s velocity (v), or discharge velocity an average discharge velocity through the entire cross section of the column v = Q/A = -Kdh/dL = -Ki Seepage velocity (vS) equals to the Darcy velocity divided by effective porosity since the actual flow is limited to the pore space only vS = v /ne = -Ki/ne
Seepage velocity (vS) usually higher than the Darcy’s velocity
35
(4) Transmissivity (T)
Transmissivity a measure of the water amount that
can be transmitted horizontally through a unit width by
the fully saturated thickness of an aquifer under a
hydraulic gradient equal to 1
T = Kb
Where
T = hydraulic conductivity
b = the saturated thickness of an aquifer
36
Example 2-1: Calculate the discharge and seepage velocities
for water flowing through a pipe filled with sand with a
hydraulic conductivity of 1.5 x 10–6 cm/s and a porosity of 0.2.
the hydraulic gradient is 0.01 and the cross-sectional area of
the pipe is 150.0 cm2.
37
2.2.3 Groundwater flow toward a pumping well
(1) Steady flow to a well in a confined aquifer
When a well is pumped, water levels in its
neighborhood are lowered this lowering amount at a
given point defines the drawdown at that point
At the given point in time, the variation of drawdown
with distance from the well describes the drawdown
curve (or cone of depression).
The steady-state flow to a well means the variation
of head occurs only in space and not in time
The steady radial flow to a well fully penetrating a
homogeneous confined aquifer can be expressed as
38
Radial flow to a well penetrating a confined aquifer
)/ln(2
w
w
rr
hhTQ
)/ln(2
12
12
rr
hhTQ
or
Source: Bedient et al., Hydrology and Floodplain Analysis, 2007
39
(2) Steady flow to a well in a unconfined aquifer
The steady radial flow to a well fully penetrating a
homogeneous unconfined aquifer can be expressed as
)/ln( 12
2
1
2
2
rr
hhKQ
Source: Bedient et al., Hydrology and Floodplain Analysis, 2007
40
Example 2-3: A well is drilled through an unconfined aquifer.
Original water table was 50 ft below ground surface and bedrock
was reached at 150 ft below ground surface. After pumping until
equilibrium conditions at 1700 gpm, the water table was lowered
by 10 and 20 ft at observation wells located at 1000 and 100 ft
respectively. Determine hydraulic conductivity.
Example 2-2: a well is constructed to pump water from a
confined aquifer. Two observation wells, OW1 and OW2, are
constructed at distances of 100m and 1000m, respectively. Water
is pumped from the pumping well at a rate of 0.2 m3/min. at
steady state, drawdown s is observed as 2m in OW2 and 8m in
OW1. Determine the hydraulic conductivity K and transmissivity
T if the aquifer is 20 m thickness.