iowa department of natural resources november 20041 ambient monitoring sites (blue dots=cafo sites,...

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November 2004 1 IOWA Department of Natural Resources Ambient Monitoring Ambient Monitoring Sites Sites # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S # S (Blue dots=CAFO sites, yellow dots (Blue dots=CAFO sites, yellow dots =Federal sites) =Federal sites)

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  • Ambient Monitoring Sites

    (Blue dots=CAFO sites, yellow dots =Federal sites)

  • Monitor Types

  • EPAs Air Quality Index

  • AQI Levels over 100 (2004 to date)

  • Realtime Ozone and PM2.5 Data Reported at EPAs AIRNOWhttp://www.epa.gov/airnow

  • Comparison of 2003 Monitored Values to Annual PM2.5 Standard (15 mg/m3 )

  • CAFO Monitoring10 sitesHydrogen sulfide, ammonia, wind speed and directionAt houses neighboring large hog, cattle, dairy and chicken confined animal feeding operations (CAFOs)

  • Clarion CAFO: Ammonia Data

  • Clarion CAFO: Hydrogen Sulfide Data

    to6-30-04Comments

    Raw Data for these graphs was downloaded from AIRS on 8/16/04.

    Data for these graphs was pasted in from V3_04AllButMalQ1-Q2_8-16.xls

    deleted PPV graph base?Replaced PPV graph base?updated X axis max for substance vs time (1 day after last day)updated graph row ranges?

    Belmond Oldyyyy2-8761 is OK

    Clarionyyyy2-8761 is OK

    Goldfieldyyyy2-8761 is OK

    Malcomyyyy2-8761 is OK

    Sioux Centeryyyy2-8761 is OK

    Viking Lakeyyyy2-8761 is OK

    Williamsyyyy2-8761 is OK

    Woodbineyyyy2-8761 is OK

    Stanhope/Hendrixyyyy2-8761 is OK

    IA Falls/Stockdaleyyyy2-8761 is OK

    Sac City/LangbeinyyNo H2S, y2-8761 is OK

    checked all X axes with a timeline, major unit =7, minor unit = auto, alignment = +90Set H2S and NH3 vs Wind Speed X axis to "Auto Scale" Maximum. I did this even though it caused Max of X axis to vary from site to site.Autoscaled max of wind speed in speed verses direction.Took a look at each graph, and for pollutant vs Wind Direction, checked if it matched direction expected from Air Photo.Checked wind speed vs wind direction

    Belmond Oldyyyy 150, then max set by autoscale. But Sioux Center NH3 maxed out at 110 ppb, so I just let it autoscale, rather than set max to 150 and loose resolution.

    John Gering:see Winter/DeCoster Sow 12 as well as Winniger

    Belmond Old-H2SvsTime

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    0.3

    0.3

    0.1

    0.3

    0.4

    0.5

    0.3

    0.3

    0.2

    0.3

    0.2

    0.2

    0.4

    0.5

    0.2

    0.1

    0.1

    0.1

    0.2

    0.3

    0.2

    0.3

    0.3

    0.2

    0.1

    0

    0.1

    0

    0.1

    0

    0.1

    0

    0.1

    0.1

    0.1

    0.1

    0

    0.1

    0

    0.1

    0

    0

    0

    0.1

    0.1

    0.1

    0.1

    0

    0

    0

    0

    2.1

    4.2

    2.6

    2.5

    1.9

    0.3

    0.8

    1.2

    2.2

    2.7

    0.6

    0.5

    0.2

    0.1

    0.4

    0.7

    0.2

    0.1

    0.5

    0.1

    0.1

    0.2

    0.2

    0.6

    0.3

    1.2

    2.3

    1.7

    0.8

    1.9

    1.3

    2.9

    2.6

    2.7

    3.5

    2.7

    1.7

    2

    2.3

    3.4

    2.3

    2.9

    2.8

    0.4

    0.7

    1.4

    0.4

    0.7

    0.3

    0.2

    0

    0

    0

    0

    0.1

    0

    0

    0

    0.1

    0.1

    0.3

    0.3

    0.2

    0.2

    0.3

    0.2

    0.2

    0.3

    0.3

    0.1

    0.2

    0.3

    0.2

    0.1

    0.2

    0.1

    0.3

    0.1

    0.3

    0

    0

    0.1

    0

    0

    0.1

    0.1

    0

    0.1

    0

    0

    0

    0.1

    0.1

    0.2

    1.3

    1.1

    1.3

    1

    0.7

    0.4

    38106.4583333333

    38106.5

    0.1

    0.2

    0.3

    0.8

    1.1

    0.5

    0.4

    0

    0.1

    0

    0.1

    0.1

    0.2

    0.3

    0.1

    0.2

    0.1

    0.1

    0

    0.1

    0.1

    0.1

    0

    0

    0

    0.1

    0.7

    0.4

    0

    0

    0.4

    0.1

    0.3

    1.4

    0.5

    0

    0

    0

    0

    0.4

    3.8

    1

    0.2

    0

    0

    0

    0

    0.1

    0.1

    0

    0

    0.2

    0.5

    0.3

    0.8

    1

    0.4

    0.6

    0.6

    0.6

    1.3

    1.3

    0.8

    0.2

    0.2

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.3

    0.2

    0.6

    0.7

    1.8

    1.2

    0.7

    0.2

    0.1

    0.3

    0.2

    0.2

    0.1

    0.1

    0

    0.2

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.2

    0.2

    0.2

    0.2

    0.1

    0.2

    0.1

    0.2

    0.1

    0.2

    0.4

    1.1

    0.6

    0.9

    1.6

    1.1

    1.4

    1.4

    1.5

    2

    1.8

    1.7

    2.3

    3.4

    2.3

    1

    3.8

    2

    1.6

    1.3

    0.7

    0.5

    0.6

    0.4

    0.3

    0.2

    0.1

    0.2

    0.1

    0.3

    0.1

    0.2

    0

    0

    0

    0

    0.1

    0.3

    0.4

    0.3

    0.4

    0.4

    0.3

    0.4

    0.5

    0.5

    0.5

    0.4

    0.4

    0.7

    0.4

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0.1

    0.2

    0.3

    0.3

    0.7

    0.3

    0.4

    0.4

    0.4

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.2

    0.1

    0.2

    0.1

    0.2

    0.3

    0.2

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.1

    0

    0

    0.3

    0.1

    0.2

    0.1

    0.1

    0.2

    0.1

    0.1

    0.2

    0.1

    0

    0

    0

    0.1

    0.1

    0.2

    0.1

    0.1

    0.1

    0.2

    0.2

    0.6

    2.6

    1.6

    1.4

    0.3

    0.9

    2

    0.2

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.2

    0.2

    0.4

    0.3

    0.5

    0.5

    0.3

    0.2

    0.2

    0.2

    0.1

    0.1

    0.2

    0.1

    0.1

    0.2

    0.1

    0.1

    0

    0.1

    0.1

    0

    0.1

    0.1

    0.2

    0.2

    0.3

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.2

    0.1

    0

    0.1

    0

    0.1

    0.3

    0.7

    0.5

    0.9

    1.3

    1.6

    1

    0.1

    0.1

    0.8

    1.4

    0.1

    0

    0

    0

    1.2

    1.7

    0.4

    38120.25

    38120.2916666667

    38120.3333333333

    0.4

    0.4

    0.5

    0.6

    0.1

    0.4

    0.5

    0.3

    0.6

    0

    0

    0.1

    0

    1.3

    1.2

    1.2

    3.2

    2.5

    2.7

    2.5

    2.5

    2.5

    1.1

    0.9

    1.1

    0.8

    1.1

    0.9

    1

    0.9

    1

    1.1

    1.3

    1.8

    2.4

    3.6

    7.7

    2

    1

    0.3

    0.3

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0.1

    0.1

    0.3

    0.3

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.2

    0.1

    0.1

    0

    0

    0

    0

    0

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.2

    0.2

    0.2

    0.2

    0.1

    0

    0.1

    0.1

    0.2

    0.2

    0.1

    0

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.2

    3.6

    0.3

    2.7

    2.6

    0

    0.1

    0.2

    3

    1

    4.2

    1.7

    0.1

    0.2

    0.1

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0.1

    0.2

    0.1

    0.2

    0.2

    0

    0.1

    0

    0.1

    0.1

    0

    0

    0

    0

    0.1

    0.1

    0

    0.2

    0

    0.1

    0.1

    0.1

    0.1

    0.2

    0.3

    0.4

    0.2

    0.2

    0.2

    0.2

    0.1

    0.2

    0.5

    0.6

    0.2

    1.1

    0.9

    0.7

    0.5

    0.5

    0.4

    0

    0

    0.1

    0

    0

    0

    0

    0.1

    0

    0.2

    0.1

    0

    0.1

    0.1

    0

    0.1

    0

    0.2

    0.1

    0

    0

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0

    0

    0

    0

    0

    0

    0.8

    0

    0

    0.1

    0

    0

    0

    0

    0.2

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0

    0.1

    0.1

    0

    0.1

    0

    0

    0

    0

    0.2

    0.1

    0.1

    0.9

    0.7

    0

    0.1

    0.8

    0.2

    0.2

    0.2

    0.5

    0.5

    0.5

    0.5

    0.8

    0.3

    0.3

    2.2

    2.7

    3.1

    2.2

    1.8

    1

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0

    0

    0.1

    0

    0

    0.1

    0

    0

    0

    0

    0.1

    0.1

    3.3

    1.3

    0.5

    0.5

    0.4

    0.3

    0.5

    0.1

    0.1

    0.2

    1.2

    1.6

    1.1

    0.4

    1

    2.3

    2.1

    1.9

    2.5

    2.3

    2.8

    2.5

    0.5

    0

    0.2

    0.2

    0.2

    0.1

    0.3

    38133.25

    38133.2916666667

    0.1

    0

    0.3

    0.2

    0.2

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.4

    0.4

    0.5

    0.4

    0.5

    0.3

    0.2

    0.4

    0.3

    0.3

    0.4

    0.5

    0.5

    0.4

    0.4

    0.3

    0.6

    1.4

    1.3

    1.5

    0.9

    1

    0.9

    0.3

    0.2

    0.3

    0.3

    0.3

    0.3

    0.4

    0.4

    0.4

    0.4

    0.4

    0.4

    0.5

    0.4

    0.3

    0.2

    0.3

    0.2

    0.3

    0.2

    0.2

    0.3

    0.2

    0.2

    0.3

    0.3

    0.4

    0.4

    0.4

    0.3

    0.5

    0.4

    0.3

    0.3

    0.3

    0.5

    0.3

    0.3

    0.4

    0.4

    0.4

    0.3

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.2

    0.3

    0.3

    0.2

    0.3

    0.2

    0.2

    0.3

    0.2

    0.4

    0.3

    0.3

    0.4

    0.4

    0.3

    0.3

    0.2

    0.2

    0.2

    0.3

    0.2

    0.4

    0.5

    0.3

    0.3

    0.2

    0.3

    0.3

    0.4

    0.4

    0.4

    0.3

    0.4

    0.4

    0.4

    0.3

    0.4

    0.3

    0.2

    0.3

    0.2

    0.2

    0.3

    0.2

    0.3

    0.2

    1

    0.5

    0.4

    0.3

    0.3

    0.3

    0.3

    0.2

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.4

    0.3

    0.2

    0.3

    0.5

    0.9

    0.3

    0.7

    0.8

    0.7

    0.7

    0.6

    0.9

    0.6

    0.3

    0.8

    0.7

    2

    2.2

    2

    1.8

    2

    2.1

    1.8

    1.7

    1.7

    1.4

    0.9

    0.4

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.4

    0.4

    0.4

    0.5

    0.6

    0.4

    0.5

    0.4

    0.9

    3

    0.5

    0.5

    0.4

    0.4

    0.7

    0.3

    0.2

    0.1

    0.2

    0.2

    0.2

    0.3

    0.3

    0.2

    0.2

    0.3

    0.3

    0.3

    0.4

    0.4

    0.4

    0.5

    0.6

    0.7

    0.5

    0.4

    0.3

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.3

    0.2

    0.3

    0.2

    0.2

    0.4

    0.5

    0.4

    0.4

    0.4

    0.5

    0.6

    0.6

    0.6

    0.7

    0.4

    0.2

    0.1

    0.2

    0.2

    0.3

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.4

    0.5

    0.4

    0.6

    0.6

    0.6

    0.3

    0.4

    0.5

    0.5

    0.4

    0.5

    0.4

    0.4

    0.4

    0.3

    0.3

    0.2

    0.2

    0.2

    0.3

    0.3

    0.2

    0.2

    0.3

    0.4

    0.3

    0.5

    0.5

    0.5

    0.5

    0.4

    0.4

    0.5

    0.5

    0.5

    0.4

    0.4

    0.3

    0.3

    0.2

    38145.4583333333

    38145.5

    0.2

    0.3

    0.2

    0.2

    0.3

    0.3

    0.3

    0.3

    0.4

    0.4

    0.5

    0.4

    0.3

    0.3

    0.3

    0.4

    0.5

    0.5

    0.4

    0.4

    0.3

    0.3

    0.3

    0.3

    0.2

    0.4

    0.3

    0.2

    0.2

    0.2

    0.3

    0.3

    0.4

    0.9

    0.6

    0.4

    0.3

    0.3

    0.4

    0.4

    0.4

    0.3

    0.3

    0.2

    0.3

    0.3

    0.3

    0.2

    0.2

    1.7

    2.1

    0.8

    0.3

    0.3

    0.3

    0.3

    0.5

    0.3

    0.4

    0.4

    0.3

    0.3

    0.3

    0.4

    0.3

    0.4

    0.4

    0.4

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.4

    0.4

    0.5

    0.3

    0.4

    0.4

    0.4

    0.4

    0.4

    0.4

    0.3

    1

    0.4

    0.5

    0.3

    0.4

    0.4

    0.4

    0.4

    0.2

    0.3

    0.4

    0.3

    0.4

    1.5

    0.3

    0.2

    0.4

    0.3

    0.4

    0.8

    0.7

    0.5

    0.5

    0.4

    0.7

    1.7

    0.6

    0.5

    0.3

    0.3

    0.2

    0.2

    0.4

    0.2

    0.3

    0.3

    1.2

    0.3

    0.2

    0.3

    0.1

    0.1

    0.1

    0.2

    0.5

    1.2

    2.3

    6

    0.6

    0.4

    0.5

    0.4

    0.3

    0.3

    0.8

    1.1

    1.4

    0.8

    0.3

    0.3

    0.2

    0.3

    0.4

    0.4

    0.4

    0.3

    0.3

    0.5

    0.5

    2.8

    1.3

    1

    0.6

    0.3

    0.5

    0.4

    1

    1.1

    0.6

    0.8

    0.6

    0.8

    1.1

    1

    1.2

    2.2

    0.8

    0.4

    0.4

    0.4

    0.5

    0.5

    0.4

    0.5

    0.5

    0.6

    0.7

    0.6

    0.4

    0.4

    0.4

    0.2

    0.2

    0.3

    0.3

    0.3

    0.3

    0.2

    0.3

    0.3

    0.3

    0.3

    0.4

    0.5

    0.3

    0.5

    0.5

    0.5

    0.4

    0.3

    0.4

    0.5

    0.4

    0.4

    0.4

    0.4

    0.4

    0.5

    0.3

    0.8

    1.4

    0.3

    0.3

    0.4

    0.3

    2.9

    3.3

    2.1

    4.2

    3.8

    4

    3

    3.3

    3.3

    3.8

    2.3

    1.9

    2.2

    2.1

    2.1

    38155.4583333333

    38155.5

    38155.5416666667

    38155.5833333333

    38155.625

    38155.6666666667

    38155.7083333333

    38155.75

    38155.7916666667

    38155.8333333333

    38155.875

    38155.9166666667

    38155.9583333333

    Date

    Concentration (ppb)

    Belmond CAFO: Hydrogen Sulfide vs Time

    Belmond Old-NH3vsTime

    12.6

    14.8

    17

    15.9

    13

    10.8

    10.3

    8.9

    7.7

    11.2

    14.8

    16.4

    18.3

    22.7

    24.2

    24.7

    17.3

    10.5

    8.9

    11.3

    13.3

    13.1

    11.2

    11.4

    11.6

    9

    8.3

    7.7

    7.9

    11.1

    19.1

    20.3

    24.9

    30.1

    26.9

    25.6

    24.4

    25.7

    25.3

    27.2

    22.9

    13.4

    10.8

    21.2

    21.5

    12

    6.9

    4.5

    2.7

    2.3

    0.4

    0.3

    0.1

    0

    0

    0

    0

    0

    2.8

    11

    14.4

    15.7

    14.7

    16.9

    11.8

    9.8

    10.1

    7.8

    5.3

    4.3

    4.3

    4.2

    3

    2.3

    2.3

    2.3

    1.7

    0.5

    0.3

    0.3

    0.3

    0

    0

    0.3

    0.3

    0.3

    0.3

    0.3

    0.2

    0

    0

    0

    0

    0

    0

    0

    0

    1.8

    4.3

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    0

    0

    0.3

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    0

    0

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    9.9

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    33

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    29

    22.6

    20

    19

    16.7

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    18.3

    17.4

    14.2

    12.5

    12.1

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    5.5

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    7.5

    7.5

    6.6

    6.9

    8.5

    10.8

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    8

    7.2

    6.1

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    4.2

    4.2

    4.2

    5.3

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    14.6

    15.2

    11.8

    9.6

    9.6

    11.3

    10.9

    9.6

    11.7

    19.5

    28.4

    31.8

    27.5

    27.5

    22.7

    17.5

    15.5

    14.2

    13.2

    12.2

    9.2

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    6

    4.3

    4

    2.5

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    0

    0

    0

    1.3

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    16.5

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    17

    10.7

    8.1

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    8.2

    8.4

    6.2

    5.6

    5.1

    10.9

    12.7

    10.5

    8.2

    7.4

    6.2

    4.6

    2.8

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    13

    24.8

    21.7

    21

    19.7

    22.7

    16.9

    10

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    2.2

    1.6

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    9.9

    9.8

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    8

    11.6

    15

    38000.3333333333

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    0

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    14.4

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    11.8

    10.2

    9.3

    8.6

    8.4

    11.8

    11.7

    8.5

    8.4

    8.4

    8.1

    8.3

    7.8

    7.4

    7.8

    6.9

    6.4

    5.3

    4.4

    5.4

    8.8

    11.3

    11.8

    11.4

    9.7

    8.2

    8.1

    7.1

    5.9

    5.3

    6.4

    6.4

    6.4

    6.4

    6.4

    6.2

    6.4

    7.2

    6.4

    6.4

    6.3

    6.1

    6.4

    7.8

    6.4

    6.2

    4.5

    6.4

    7.2

    8.4

    9.2

    6

    4.4

    3.2

    2.4

    2.4

    2.4

    1.9

    0

    0

    4

    13.4

    15.9

    12.3

    9.1

    8

    8.9

    8.3

    8.7

    9.2

    7.1

    10.5

    10.3

    8.6

    5.6

    3.1

    5.8

    6.3

    6

    5.5

    7.3

    5.7

    5.2

    3.5

    2.6

    5.3

    6.3

    6.9

    4.6

    3

    7.2

    7.7

    7.2

    7.5

    9.9

    14.1

    11.6

    11.4

    10.2

    4.1

    3.8

    4.4

    2.6

    4

    4.4

    3.9

    4

    4.4

    3.1

    3.9

    4.4

    5.1

    7.5

    10.9

    13.6

    15.3

    13.7

    13.2

    10.3

    8.7

    8.4

    8

    6.8

    6.3

    4.7

    4.4

    4.4

    4.4

    3.7

    2.5

    2.4

    2.4

    1.8

    0.5

    0.4

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    0.4

    0.4

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    14

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    8.7

    8.4

    8.4

    9.3

    11.5

    14.5

    22.1

    19.3

    18

    20.7

    22.6

    31.5

    34.6

    27.3

    18.6

    13.8

    9.3

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    2.4

    1.6

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    0.4

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    0

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    4

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    0

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    0

    0

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    2.2

    2.7

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    3.5

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    5.1

    9.4

    11.7

    11

    10.9

    10.2

    8.2

    6.2

    5.5

    5.1

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    4

    2.4

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    11.6

    8.9

    7.9

    5.6

    4.3

    4.3

    5

    6.3

    6.3

    6.1

    4.3

    1.6

    0.3

    0.3

    2

    3.7

    5

    6.3

    6.2

    4.6

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    4.6

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    4.3

    4.3

    4.3

    4.6

    6.3

    6.3

    6.3

    5.8

    4.3

    4.8

    5.5

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    4.4

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    2.5

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    4

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    6.8

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    5.6

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    3.6

    2.8

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    2.3

    2.3

    2.3

    2.3

    2.3

    2.4

    2.3

    2.7

    3.8

    5.8

    17.2

    19.3

    14.4

    11.5

    9.1

    8.4

    8.6

    7

    5.1

    2.9

    2.2

    0.6

    0.3

    0.3

    0.3

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    2.5

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    3.4

    3.2

    5.4

    9.7

    7.7

    5.6

    4.1

    4.3

    4.4

    4.3

    3.2

    2.3

    0.6

    0.3

    0.3

    0.3

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    4.3

    4.3

    4.3

    3.6

    3.3

    3.8

    4.4

    6.9

    9.4

    13.8

    16.8

    18.5

    14.6

    13.4

    11

    8.5

    7.1

    6.2

    6.3

    9.6

    8.1

    7.4

    7.3

    12.6

    17.5

    17.9

    16.9

    15.8

    14.3

    15.5

    18.1

    23.6

    35.6

    23.3

    17.8

    16.3

    15.6

    12.4

    10.3

    8.7

    6.1

    4.4

    4.3

    4.3

    8.1

    11.4

    14

    19.1

    19.6

    20.5

    16.6

    14.8

    13.8

    12.3

    15.5

    19

    23.8

    39.8

    37.4

    39.4

    36.9

    35.7

    29.7

    21.9

    18.3

    18.3

    20.9

    23.4

    27.1

    22.9

    21.8

    18.6

    17

    18.9

    33.9

    30.1

    24.8

    24.1

    36.6

    115.9

    98.1

    311.8

    99.3

    51.9

    66.4

    105.4

    59.6

    35.7

    26.5

    23.4

    24.6

    25.9

    29

    26.2

    22.6

    20.8

    18.3

    18.3

    18.3

    16.7

    17.2

    18.3

    19.3

    21.8

    29

    24

    19.9

    16.5

    14.4

    12.5

    11.7

    10.3

    10.1

    9.2

    8.3

    8.3

    8.3

    8.3

    8

    8

    7.6

    8.3

    8.3

    9.1

    8.3

    6.3

    6.3

    7.8

    14.3

    19

    16.4

    15.4

    27.2

    57.1

    66.6

    50.9

    23.3

    24.9

    29.4

    35.7

    43.3

    53.8

    58.3

    65.6

    73.5

    60.3

    48

    63

    55

    42.1

    36.8

    30.4

    27.5

    46.9

    57.5

    51.9

    54.6

    58.4

    58.8

    53.1

    29.2

    25.3

    24.3

    21

    17.9

    13.2

    13

    14.9

    18.6

    19.8

    19.8

    18.9

    25.6

    41.6

    37.5

    35.7

    37.7

    36.8

    36.6

    38040.5416666667

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    12

    10.4

    8.9

    8.4

    8.4

    8.4

    8.9

    10.9

    17.2

    45.3

    67.5

    64.5

    37.5

    22.6

    20.6

    20

    16.9

    14

    16.1

    15.9

    14.5

    13.6

    12.5

    12.7

    10.5

    15.6

    25.5

    26.7

    25.1

    24

    24.1

    25.4

    28.6

    30.8

    32.8

    34.2

    34.4

    35.1

    36.8

    37.4

    30.9

    23.7

    18.6

    13.9

    11.6

    10.4

    13.9

    26.4

    24.9

    19.4

    16.6

    15.2

    12.6

    12.9

    12.2

    13.4

    29.2

    42.3

    42.5

    40.1

    37.6

    38.4

    36.1

    33.6

    31.3

    26.9

    21.1

    23.9

    27.1

    29.4

    28.3

    24.1

    23.4

    20.8

    19.3

    18.6

    18.5

    16.4

    14.9

    16.3

    24.2

    27.2

    28.2

    30.4

    31.7

    32.9

    34.9

    35.3

    31.1

    26.1

    20.5

    20.9

    24.3

    27.7

    23

    23.4

    23.7

    24.1

    24.7

    23.8

    20.4

    18.7

    18.4

    18.7

    23.2

    30.1

    33.1

    38.7

    40.7

    41.8

    43.3

    42.3

    38.6

    33.6

    28.5

    27.4

    35.7

    33.1

    29.9

    26.8

    25.1

    26.5

    28.1

    31.4

    29.7

    28.9

    29.3

    32.7

    39.1

    48.9

    47.2

    48.4

    50

    58.2

    64

    49.5

    41.6

    34.4

    29.3

    26

    24.3

    26

    27

    33.2

    36.7

    34.6

    26.6

    27.6

    30.1

    29.3

    36.6

    44.4

    53.2

    54.7

    52.6

    50.7

    56.7

    37.3

    20.5

    18.3

    17.2

    15.7

    14.4

    14.2

    14.4

    14.4

    14.4

    13.4

    13.5

    13.9

    12.4

    11.2

    10.3

    9

    8.4

    7.9

    6.7

    7.2

    7.7

    8.4

    8.4

    8.4

    8.4

    7.4

    7.4

    6.6

    7.2

    6.4

    6.4

    6.2

    6.4

    4.6

    4.8

    5.5

    6.4

    6.8

    7.5

    8.1

    8.3

    8.5

    15.9

    20.6

    15.7

    18.2

    19.2

    19.7

    23.3

    17.8

    14.7

    14.5

    15.3

    15.2

    16.5

    19.1

    21.9

    22.2

    19.5

    18.7

    19

    19.7

    19.8

    18.4

    18.7

    19.5

    20.1

    36.5

    33.5

    22.1

    16.3

    12.4

    11.6

    10.7

    9.3

    8.4

    7.9

    6.8

    6.4

    6.4

    6.4

    6.4

    6.4

    6.4

    5.7

    4.4

    4.4

    4.3

    3.5

    3.8

    4.4

    6.2

    6.5

    6.8

    7.6

    8.4

    8

    6.4

    5.6

    4.7

    4.4

    4.4

    3

    2.4

    2.4

    2.4

    2.6

    4.4

    4.4

    4.4

    4.4

    4.4

    4.4

    4.4

    4.6

    7.8

    8.4

    8.4

    9

    15.4

    67.2

    58.7

    40.4

    35.6

    29.4

    25.7

    19.1

    15.7

    12.8

    12.4

    10.5

    10.4

    9.5

    8.4

    10.4

    10.4

    10.4

    10.3

    10.4

    10.4

    10.4

    10

    7.8

    6.8

    6.4

    6.4

    6.4

    6

    4.4

    4.4

    4.4

    4.4

    3.5

    2.5

    2.4

    2.4

    2.4

    2.4

    2.4

    2.4

    2.4

    1.6

    2.3

    38054.375

    38054.4166666667

    38054.4583333333

    28.4

    27.4

    28.7

    29.3

    23.2

    19.5

    16.1

    12.9

    11.9

    10.4

    9.9

    9

    8.2

    6.4

    6.4

    6.4

    6.4

    6.4

    7.6

    9

    23.1

    27.4

    41.9

    46.2

    40.7

    41.6

    43.5

    40.2

    39.4

    33

    24

    15.8

    14.2

    14.4

    16.1

    18.2

    20.7

    21.3

    22.4

    22

    20.6

    18.2

    17.4

    18

    21.7

    22.4

    23.9

    29.7

    29.7

    22.9

    19.9

    14.7

    9.9

    8.3

    7.2

    10

    8.8

    8.4

    7.2

    8.2

    9.9

    8.7

    7.8

    5.1

    2.4

    1.6

    0.4

    0.4

    0.4

    0.4

    1.5

    2.4

    2.4

    2.4

    2.4

    2.5

    2.4

    2.6

    2.4

    2.4

    2.4

    4.2

    5.9

    6.4

    4.4

    4.4

    4.4

    3.6

    2.4

    3.8

    3.9

    7.6

    12.4

    10.7

    10.4

    10.4

    10.6

    29.6

    39.3

    30.1

    22.6

    21.8

    15.9

    15.6

    17.9

    16.7

    15.7

    16.1

    15

    15.7

    14.6

    14.4

    14.4

    14

    15.2

    15.7

    14.4

    15.5

    17.4

    17.6

    20.2

    29.4

    27

    23.8

    20.7

    16.6

    16.4

    16.4

    18.8

    15.8

    12.4

    13.1

    12.9

    11.3

    10.4

    10.4

    10.4

    10

    8.4

    8.4

    8.4

    9.3

    10.9

    12.4

    11.9

    10.4

    11.7

    10.5

    8.7

    8.2

    6.4

    6.1

    5.5

    4.9

    4.4

    4.4

    4.4

    5.6

    7.3

    8.4

    8

    7.6

    7

    6.5

    6.4

    6.4

    6.4

    6.6

    5.1

    4.4

    4.4

    4.1

    2.4

    2.4

    2.4

    2.4

    2.4

    2.4

    2.4

    2.3

    1.5

    1.4

    0.5

    0.4

    0.4

    2.1

    7.5

    9

    14.6

    15.6

    26.6

    40.8

    28.9

    20.5

    17.8

    16.8

    15.5

    14.2

    13

    10.8

    9.9

    9

    8.4

    7.9

    6.4

    6.7

    8.4

    7.7

    6.9

    6.8

    8.4

    7.9

    11.7

    21.2

    44.8

    46.5

    36.5

    40.6

    45.6

    42.2

    39.5

    37.4

    28.2

    20.2

    17.1

    16.3

    15.6

    15.2

    17

    19.4

    19.7

    20.5

    21.2

    15.7

    13.8

    18.9

    20.4

    23.7

    20.7

    17.5

    14.9

    12.4

    15.6

    24.2

    30.6

    25.8

    19.9

    13.7

    13.9

    15.2

    13.3

    12.4

    10.6

    12.2

    12.2

    13

    17.8

    27.7

    28.4

    27

    26.6

    32.4

    32.6

    30.6

    27.5

    31.2

    39.7

    43.1

    42.6

    40.5

    37.5

    31.4

    34.1

    37.5

    36.9

    37.9

    40.9

    48.5

    45

    35.2

    27.5

    23.1

    22.1

    28.4

    42.9

    40.2

    33.1

    23.6

    21.1

    29.8

    28.5

    28.4

    26.8

    28.8

    19.3

    16.8

    17.3

    15.9

    13

    10.9

    10.3

    8.8

    6.4

    5.3

    4.2

    4.2

    4.2

    8.1

    12.3

    15.8

    20.8

    29.8

    28.7

    28.5

    28.3

    38067.625

    38067.6666666667

    38067.7083333333

    38067.75

    17.4

    13.5

    12.8

    19.3

    20.8

    19.4

    18.3

    15.2

    12.6

    10.7

    10.4

    10.8

    20.3

    25.6

    23.3

    19.7

    17.2

    16.3

    15.6

    14.3

    13.1

    12.3

    12.5

    11.9

    11.7

    12.6

    13.6

    14.3

    15.5

    18

    19.3

    18.3

    16.3

    16

    14.3

    14.3

    23.2

    30.2

    30.8

    38069.4166666667

    35.7

    40.7

    42.4

    42.2

    41.1

    40.3

    39.4

    41.3

    41.8

    40

    35

    31.2

    29.9

    27.4

    27

    25.7

    29.3

    36.9

    37.9

    34.8

    34

    47.2

    61.8

    55.7

    54

    54.9

    62.3

    61.6

    60.2

    59.2

    56.8

    56.9

    52.2

    52.5

    53.4

    50.5

    45.9

    39.7

    43.8

    42.6

    43.6

    38.2

    34.3

    39.2

    42.4

    45.5

    44.2

    44.4

    39.6

    39.4

    39.2

    30.3

    29.4

    37.1

    31.8

    34.2

    38

    40.5

    40.9

    41.2

    30.8

    30.3

    31.6

    32.4

    40.8

    35.2

    29

    27.3

    29.6

    32.4

    34.2

    37.1

    33.3

    28

    28

    29.5

    27.3

    25.9

    21.9

    23.2

    29.9

    38

    37.2

    39.3

    47.9

    48.9

    47.6

    43.5

    39.3

    37.1

    34.5

    31.9

    31

    29.6

    30

    32.3

    31

    32.2

    31.9

    31.1

    31.2

    34

    35.8

    34.6

    33.7

    30.5

    27.4

    26.7

    22.7

    23.4

    19.7

    17.9

    18.6

    16

    11.5

    9

    7.1

    6.2

    6.9

    6.9

    7.7

    11.9

    14.2

    12.5

    14.1

    15

    13.7

    13.1

    11.3

    8.6

    8.7

    9.1

    8.2

    8.2

    8.2

    7.4

    6.2

    4.9

    4.2

    4.2

    8.1

    14.6

    28.3

    30.9

    25.9

    22.8

    20.5

    18

    15

    15.5

    16.2

    14.5

    11.2

    12

    12.6

    11.2

    10.3

    13

    12.9

    10.5

    12.6

    19.1

    16.4

    13.5

    14.3

    14.6

    17.6

    23

    26.4

    24.5

    25.4

    23.7

    19.2

    15.2

    14.1

    13.7

    11.2

    7.7

    6.8

    7.6

    7.5

    10.8

    11.3

    9.2

    9.5

    15.1

    15.6

    18.5

    31.9

    31.3

    33

    23.2

    17.6

    16

    17.9

    19.2

    19.8

    20.3

    18.3

    16.8

    12.4

    10.3

    10.3

    10.2

    9.9

    9.5

    8.5

    8.3

    8.3

    6.9

    6.3

    7.9

    17.6

    23

    18.3

    17.1

    15

    12.2

    14.5

    17.8

    19.2

    19.9

    17.6

    18

    17.6

    17.6

    15.5

    14.3

    14.2

    13.3

    12.3

    12.8

    12.1

    28.5

    29.9

    32.9

    39.5

    38.8

    29.6

    22.2

    19.3

    18.8

    20.1

    21.1

    21.8

    22.1

    22.8

    27.2

    34.4

    32.6

    39.2

    91.1

    75.1

    60.6

    38.9

    75.6

    52.4

    37.5

    34.3

    32.7

    27.7

    25.7

    28.9

    25.9

    21.4

    14.6

    10.9

    38080.5833333333

    38080.625

    38080.6666666667

    38080.7083333333

    24.7

    22.2

    40.5

    34.4

    22.6

    25.2

    20.4

    13.9

    10.7

    8

    7.6

    8.4

    13.8

    25.9

    32.9

    40.2

    31

    25.3

    23.3

    23.9

    26.6

    27.4

    29.3

    30.3

    25.1

    16.4

    14.3

    12.6

    12.4

    12.6

    12.3

    11.5

    12.6

    12.6

    14.4

    13.7

    21.3

    34

    32.5

    22.6

    18

    15.9

    14.9

    15.4

    16

    16.2

    16.4

    16.7

    16.2

    15.2

    15.9

    16.1

    16.5

    15.9

    16.3

    18

    18.7

    20.4

    23.3

    24.3

    27.1

    42.7

    40

    38.5

    35.7

    31

    27.7

    25.6

    24.9

    30.6

    25.4

    22.8

    32.4

    43.3

    60.2

    114

    116.5

    53.3

    27.5

    23

    23.2

    19.9

    16.9

    14.3

    19.2

    36.3

    43.7

    46.8

    41

    52.7

    48.2

    32.4

    27.1

    30.9

    41.6

    60

    64.4

    72.1

    77

    69.5

    67.7

    71.3

    48.4

    43.9

    38.4

    59.8

    72.6

    64.8

    71.6

    66.5

    48.8

    50.5

    45.7

    38.1

    32.5

    31.2

    31.1

    30.1

    45.2

    57

    48.5

    56.9

    69.6

    48.8

    64.7

    56.5

    90.2

    63

    42

    36.1

    26.7

    27.5

    33.4

    35

    28.8

    22

    18.2

    22.5

    28.6

    31

    27.8

    27.2

    25

    24.5

    20

    17.6

    15.4

    14.2

    12.8

    12.3

    11.8

    9.1

    8.3

    9.3

    15.1

    16.8

    21.1

    25.5

    25

    20.8

    22.2

    22.9

    22.1

    21.5

    23.5

    24.9

    23.2

    20.1

    20.4

    24.5

    26.9

    31.1

    25.8

    22.8

    21.8

    32.4

    29.4

    17.4

    28

    38.7

    55

    56.9

    41.4

    33.5

    29.2

    26.4

    23.5

    23.1

    22.3

    22.1

    21

    20.6

    18.8

    16

    13.1

    12.4

    13.5

    13.9

    12.4

    10.6

    10.1

    9.5

    8.3

    6.7

    7.9

    13.3

    14.4

    12.5

    10.3

    11.2

    10.5

    13.7

    16.5

    16.3

    15.7

    15.1

    21.2

    17.2

    15.9

    13.9

    12.4

    10.9

    9.1

    20.8

    24.4

    20

    98.8

    49.7

    48.4

    59.5

    47.1

    36.8

    28.7

    24.1

    21.5

    21.7

    19.9

    20.7

    22.3

    25.3

    145.4

    53.7

    24.3

    31.9

    29.8

    24.7

    21.9

    24.3

    21.1

    20.3

    20.3

    21.1

    27.7

    34.3

    34.6

    31.3

    25.3

    20.1

    18.1

    16.3

    15.9

    16.3

    17.1

    17.4

    18

    17.6

    17.2

    17.9

    19.6

    21.4

    23.7

    24.3

    24.3

    24.9

    25.5

    24.2

    24

    24.3

    25.9

    26.4

    25.8

    22.8

    25.6

    27.3

    25.5

    22.8

    22.6

    23.2

    22.6

    20.5

    18.2

    19.8

    24.2

    26.4

    24.7

    22.4

    21.1

    18

    16.7

    15.9

    24.5

    56.7

    57.5

    52.4

    45.2

    35.2

    38093.5

    38093.5416666667

    38093.5833333333

    38093.625

    32.6

    28.3

    21.9

    17.1

    15.8

    16.6

    20.9

    24.3

    23.7

    22.2

    19.2

    18.1

    18.3

    18.3

    18.1

    20.9

    22.9

    28.9

    28.2

    25.4

    21.9

    24.1

    28.8

    30.8

    32.7

    31.1

    30.3

    29.3

    28.7

    30.2

    34.8

    35.4

    33.5

    34.5

    36.6

    38.3

    39.2

    39.6

    36.9

    34.3

    31.4

    29.5

    29.2

    27.2

    23.9

    21.5

    20.3

    18.6

    16.7

    15.2

    14.2

    13.4

    12.8

    10.5

    9.5

    8.7

    11.3

    12.2

    11.5

    10.3

    9.2

    8

    6.3

    6.3

    14.7

    62.1

    67.3

    46.1

    52.8

    42.2

    35.1

    30.6

    26.8

    20.1

    16.5

    13.1

    9.4

    7.3

    6.4

    5.7

    4.7

    6.3

    6.3

    9

    12

    10.4

    12.2

    16.8

    17.7

    14.5

    10.9

    10.3

    12.4

    12.4

    12.6

    12.8

    12.9

    11.8

    11.4

    11.7

    13.7

    16.4

    16

    23.8

    20.5

    14.9

    11.3

    9

    7.1

    6.4

    8

    10.3

    30.2

    56.8

    46.3

    51.1

    54.9

    57

    53.2

    49.2

    39.2

    33.9

    29.3

    36.9

    25.9

    19.5

    15.1

    12.5

    12.5

    17.6

    15.4

    13.8

    16.4

    16.1

    20.7

    28.7

    26.8

    23.6

    22.9

    19.8

    18.5

    18.1

    16.5

    14.4

    13.4

    13.9

    23

    25.5

    23.9

    19.6

    16

    14.3

    14.3

    25.3

    36

    29.2

    23.9

    20.8

    27.9

    35.7

    32.3

    37.7

    42

    34.8

    25.6

    26

    23

    26.2

    28.3

    34.8

    26.6

    19.1

    15.9

    14.3

    13.8

    12.4

    10.4

    9.6

    8.3

    8.3

    8.4

    8.4

    7.7

    7.6

    9.4

    11.9

    13.5

    13.8

    13.9

    13.1

    12.4

    10.9

    9.7

    8.3

    7.1

    6.3

    6.3

    6.3

    6.4

    5.2

    4.4

    4.4

    4.4

    4.3

    4.3

    2.3

    2.3

    2.3

    2.3

    42.6

    61.4

    40.6

    50.6

    36.1

    38.4

    43.8

    56.1

    47.8

    28.4

    23.1

    20.5

    31.9

    22

    16.8

    13

    13.9

    10.9

    7.8

    6.4

    4.5

    5.1

    13.3

    17.3

    33.3

    40.4

    28.7

    19.1

    20.4

    33.6

    43.5

    47.2

    60.4

    67.7

    47.6

    40.1

    42.6

    117.6

    114.3

    153.9

    160

    62

    45

    70.8

    38.4

    32.5

    27.2

    23.7

    29.5

    27.7

    22.9

    17.5

    13.3

    12.2

    12.2

    13

    14.8

    15

    14.1

    13.5

    16.7

    16.1

    15.2

    15.1

    14.3

    14.1

    12.6

    14.3

    15.9

    19.5

    26.7

    25.6

    20.7

    18

    15.3

    13.7

    12.3

    12

    11.2

    10.1

    8.9

    8.3

    8.3

    8.6

    9.2

    9.2

    8.4

    8.3

    8

    8.3

    8.4

    8.5

    6.1

    4.3

    9.3

    22.5

    29.1

    23.3

    19.1

    38106.5

    38106.5416666667

    38106.5833333333

    38106.625

    30.1

    37.7

    26

    16.8

    13.8

    10.9

    8.5

    7

    6.4

    5.5

    4.5

    4.4

    4.4

    4.4

    2.7

    4

    6.7

    8.4

    8.2

    7.5

    8.2

    8.4

    8.7

    14.4

    18.6

    14.1

    9.3

    9.2

    8.4

    8.4

    29

    34.4

    15.2

    9.9

    8.4

    6.4

    5.6

    18.2

    46.4

    15.5

    6.9

    3.9

    2.9

    6.1

    11.3

    12.9

    15.9

    13.4

    13.1

    22.8

    17.8

    22.7

    48.5

    31.8

    32.7

    65.8

    34.6

    54.4

    85.5

    52.7

    32.2

    26.3

    27.4

    22.7

    18.6

    14.5

    12

    9.8

    7.2

    4.1

    2.4

    2.2

    8

    6.1

    14.8

    11.1

    26.9

    16.6

    24.5

    12.8

    8

    6.1

    4.4

    4.4

    4.4

    3.8

    13.3

    24.4

    22.5

    15.8

    13.1

    12.4

    9.8

    8.4

    7.9

    6.4

    6.4

    6.4

    7.8

    6.7

    8.5

    11.1

    12.5

    14.4

    13.6

    11.6

    9.8

    8.4

    8.3

    6.9

    8.3

    15.2

    29.6

    28.2

    41.1

    33.5

    32.3

    38.5

    38.6

    53.1

    58.7

    62.8

    95.5

    271.4

    263.7

    145.6

    214.5

    84.9

    60

    60.1

    29.3

    16.8

    13.7

    12.3

    15.4

    13.6

    11.7

    17.3

    16.3

    19.2

    18.1

    15.5

    16.6

    15.5

    13.7

    13.4

    14

    15.2

    22.8

    27.3

    28.6

    32.6

    27.1

    25.8

    24.3

    20.6

    19.5

    21.5

    24.6

    28.6

    28.5

    31.9

    23.3

    16.3

    8.3

    6.1

    4.4

    3.1

    3.3

    2.4

    2.4

    2.4

    1.6

    0.5

    0.4

    0.4

    0.4

    0.4

    0.1

    0

    0

    0.4

    1.8

    2.4

    2.9

    2.4

    2.3

    2.4

    2.5

    3

    4.2

    4.4

    4.4

    4.4

    4.4

    4.4

    2.8

    2.4

    2.4

    2.6

    3.7

    4.4

    5.5

    6.4

    7.9

    9.4

    15.9

    27.8

    29.8

    23.7

    22.5

    39.4

    47.5

    53.6

    41.3

    32.7

    28.3

    27.5

    26.7

    24

    20

    19.6

    26.4

    25

    20.8

    22.5

    26.8

    33.9

    33.1

    30.5

    28.1

    26.2

    27.5

    27.2

    29.3

    31.8

    27.8

    23.6

    22.5

    20.8

    18.3

    15.8

    14.6

    13

    12

    10.4

    10.4

    9.6

    9.1

    8.4

    8.6

    10.3

    28.6

    59.4

    71.1

    38.6

    28.5

    68.9

    43.8

    27.7

    23.1

    20.2

    17.9

    15.2

    11.5

    9

    6.4

    4.5

    4.1

    3

    2.6

    2.4

    2.9

    4.1

    4.4

    5.1

    10.4

    19.5

    23.7

    20.9

    20

    21.2

    23.7

    24.6

    20.5

    16.8

    14.9

    13.9

    11.9

    10.2

    8.8

    8.1

    6.4

    6.4

    5.8

    5.9

    7.8

    9.9

    12.7

    14.9

    16.5

    15.6

    15.9

    19.2

    21.6

    19.8

    18

    15.7

    12.5

    8.3

    6.3

    4.9

    11.4

    21.6

    32.9

    33

    23.4

    17.1

    11.7

    8.8

    6.7

    8.1

    7

    4.7

    3.3

    2.5

    0.6

    1.7

    38120.3333333333

    38120.375

    38120.4166666667

    38120.4583333333

    38120.5

    49.9

    27.4

    18.9

    15.9

    14.9

    14.4

    14.4

    13.4

    13.2

    16.2

    23.8

    40.3

    35.7

    48.9

    56

    61.7

    62.7

    64.4

    52.3

    42

    41

    47

    53.5

    106.6

    81.9

    69.6

    68.6

    59.7

    60.3

    65.3

    64.2

    81.7

    379.1

    157.6

    76.1

    60.9

    38

    28

    22.2

    18.2

    19

    26.5

    37.9

    36.4

    32.3

    25.7

    26.2

    25.2

    22.8

    21

    19.1

    17.5

    17.9

    19.9

    19.7

    19.1

    17.3

    16.2

    14.4

    16.8

    19

    19.1

    18.4

    20.5

    21

    32.5

    48.4

    36.2

    28.5

    23.1

    19.7

    18.8

    18.6

    15.2

    12.2

    11.7

    10.9

    10.4

    10.5

    10.9

    10.7

    10.9

    12.4

    15.1

    16.6

    15.6

    14.9

    14.3

    13.3

    13.7

    14.5

    16.2

    16.9

    16.5

    16.1

    15.7

    16.7

    15.6

    13.1

    10

    8

    6.8

    11.2

    20

    17.2

    14.6

    34.3

    180.6

    112.9

    64.6

    35

    24.2

    18.9

    17.1

    21.9

    24

    19.4

    16.5

    13.6

    11.1

    9.9

    8.4

    7.1

    6

    4.4

    3

    2.4

    2.4

    2.4

    2.4

    2.4

    2.4

    4

    9.7

    22.9

    26

    27.5

    29.4

    33.6

    35.9

    32.5

    31.4

    32.9

    30.9

    28.6

    26.9

    24.4

    21.7

    20.7

    20.5

    20.7

    20.1

    21.6

    23.5

    26.2

    25.5

    23.4

    21

    18.6

    16.7

    14.8

    18.1

    31.5

    59.1

    52.5

    46.5

    41.8

    39.9

    34.7

    29.3

    23

    19.7

    17.6

    14.9

    12.8

    12.1

    10.6

    10.4

    10.4

    9.3

    8.5

    8.2

    8.4

    7.6

    6.4

    7.4

    11

    13.4

    14.8

    15.4

    19.4

    24.9

    21.5

    15.4

    17

    18.8

    14.5

    11

    8.1

    6.4

    6.4

    6.4

    7.8

    7.7

    6.2

    4.5

    5.9

    6.8

    8.3

    8.4

    8.8

    17.4

    25

    26

    24.3

    21.2

    18.6

    18

    14.2

    12.1

    12.2

    10.6

    8.9

    7.3

    6.4

    4.5

    4.4

    3.6

    2.4

    2.4

    1.2

    0.4

    0.4

    0.4

    1.5

    5.9

    11.6

    22.2

    13.2

    8.4

    7.6

    13.6

    14.4

    12.8

    8.9

    8.4

    8.9

    12.4

    52.6

    52.2

    47.4

    37.5

    29.4

    22.3

    14.8

    11.8

    10

    8.4

    8.4

    8.3

    13.3

    27.3

    33.6

    31.6

    29.2

    22.2

    17.7

    14.5

    10.2

    9.7

    10.6

    12.9

    11.4

    9.6

    7.7

    6.4

    4.4

    8.1

    32.8

    23.3

    20.4

    22.6

    19.3

    23.8

    21.8

    18.3

    16

    16.1

    21.1

    23

    18.7

    19.3

    36.9

    47.4

    40.6

    50.9

    47.9

    98.4

    80.6

    53.1

    31.2

    21.3

    16.2

    12.8

    12.4

    17.3

    38133.2916666667

    38133.3333333333

    38133.375

    38133.4166666667

    27.2

    21.4

    17.2

    15.3

    14.2

    13.5

    11.9

    10.6

    9.3

    9.2

    14.1

    21.4

    21.5

    22.7

    18.6

    14.7

    11

    7.6

    6

    4.9

    8.6

    14.6

    12.7

    9.9

    8.6

    9.8

    25.7

    45.4

    44.1

    43.8

    44.1

    30.5

    19.1

    14.3

    11.6

    9.6

    8.1

    7

    6.5

    5

    4.6

    4.5

    4.9

    13.4

    19.9

    19.1

    18.9

    22.6

    24.8

    24.6

    25.5

    25.6

    22.9

    17.6

    13.4

    11

    8.7

    7.7

    6.7

    6.5

    5.5

    4.5

    4.5

    6

    11.9

    11.8

    10.5

    9.5

    7.8

    6.8

    7

    8.3

    7.3

    6.5

    7.6

    9

    11.3

    12.7

    10.9

    10.4

    8.8

    8.3

    6.6

    6.4

    5.5

    4.6

    4.6

    4.2

    2.6

    2.5

    2.5

    2.5

    3.9

    5.4

    11.2

    11.6

    10

    8.7

    8.5

    6.5

    6.3

    4.8

    4

    2.5

    2.5

    0.8

    0.6

    0.6

    0.6

    0.3

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    2.5

    2.5

    2.5

    1.7

    0.5

    0.5

    0.5

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    1.3

    7.4

    12.3

    11

    9.7

    14.1

    13.5

    29

    54.6

    47.3

    44.8

    84.7

    100.2

    67.5

    49.8

    40.8

    38.1

    47.4

    33.8

    27

    22.1

    18.8

    13.5

    10.1

    7.6

    5.5

    4.1

    2.5

    1.9

    0.5

    0.5

    0.5

    0.5

    0

    0

    0

    0

    4.6

    16.2

    22

    22.7

    24.5

    21.1

    18.4

    17.7

    18

    21.1

    20.6

    20.1

    17.8

    14.3

    11.7

    9.8

    8.4

    13.7

    33.5

    35.2

    27.5

    22.1

    18.8

    16.7

    21.8

    30.1

    28

    23.2

    25.4

    24.6

    25.3

    25.9

    26.2

    19.5

    20.9

    20.4

    22.8

    21.2

    17.2

    14.5

    13.7

    12.3

    12.4

    12.1

    17.6

    26

    40.2

    42.9

    40.9

    30.8

    22.6

    17.1

    13.4

    10.2

    8.4

    8.1

    6.6

    6.4

    8.1

    6.4

    6.7

    8.4

    8.4

    8.4

    8.4

    8.6

    11.6

    17.6

    14.9

    11.7

    9

    7.4

    6.8

    14.9

    20.5

    24.1

    24.6

    19.9

    21.1

    24.3

    23.6

    20

    19

    17

    16.3

    14.8

    15.2

    20.5

    32.7

    27.9

    26.8

    30.3

    30.7

    27.6

    24.7

    24

    29.5

    34

    30.7

    24.7

    20

    17.9

    38145.5

    38145.5416666667

    38145.5833333333

    38145.625

    49.2

    21.4

    14.2

    11.8

    10

    8.3

    8

    6.4

    6.3

    6.2

    6

    5.8

    5.4

    4.6

    4.3

    4.8

    9.7

    14.4

    15.3

    15.7

    14.2

    13.4

    12.2

    12.2

    16.6

    18.5

    18.4

    15.3

    13

    10.8

    9.2

    8.2

    7.3

    9.2

    12.9

    13.2

    11

    9.1

    7.6

    6.2

    5.6

    4.3

    5.5

    6.2

    6.2

    6.2

    6.2

    6.2

    10.4

    23.1

    22.7

    17.4

    12.8

    10.6

    10.3

    10.3

    10.8

    13

    15.7

    17.8

    18

    18.1

    16.6

    16.2

    15.2

    15.7

    16.5

    24.4

    30.5

    26.9

    19.3

    25.4

    22.8

    15.1

    11.2

    8.7

    7

    6.2

    6.2

    6.1

    4.8

    4.3

    4.3

    4.1

    4.3

    4.3

    6

    8.9

    14

    14.1

    11.4

    9.3

    8.7

    26.9

    30.4

    29.1

    26.2

    22.8

    19.8

    14.6

    10.8

    8.3

    6.5

    6.1

    4.8

    4.4

    4.4

    4.4

    5.1

    7.7

    10.2

    16.4

    29.4

    25.4

    22.9

    22.8

    21.9

    21.2

    23.4

    20

    20.6

    16.8

    13.1

    10.2

    8.8

    9.9

    8.2

    8.4

    7.8

    6.4

    4.8

    4.4

    67.2

    82.7

    48.1

    37.3

    27.8

    20.2

    17.1

    16.9

    14

    29.5

    32.8

    25.7

    21.6

    18.1

    14.8

    11.7

    10.4

    9.9

    10.8

    11.7

    10.5

    8.7

    7.6

    78.5

    44.5

    26.8

    25.5

    31.9

    26

    28.6

    45.8

    43

    34

    34.2

    32.9

    33.9

    47.3

    46

    63.3

    52

    35.2

    26.9

    21.3

    17.8

    18.4

    59.2

    41.8

    26.9

    18.7

    16.9

    18.5

    21.5

    20.4

    24.4

    24.7

    22.8

    22.4

    20.2

    19.5

    18.3

    18

    18.3

    17.5

    15.6

    13.7

    12.6

    12.3

    12.4

    13.4

    14.4

    14

    12.9

    13.2

    13.4

    14.4

    16.3

    22.6

    27.8

    20.7

    16.7

    14.5

    16

    15.6

    12

    8.9

    7.2

    11.7

    13.8

    11.8

    11.8

    36.4

    37.9

    34.4

    41.8

    53.5

    60.2

    56.4

    73.9

    69.7

    57

    52

    76.2

    93.8

    93.7

    68.8

    38155.5416666667

    38155.5833333333

    38155.625

    38155.6666666667

    38155.7083333333

    38155.75

    38155.7916666667

    38155.8333333333

    38155.875

    38155.9166666667

    38155.9583333333

    Date

    Concentration (ppb)

    Belmond CAFO: Ammonia vs Time

    Belmond Old-H2SvsWs

    0.1

    0.2

    0.1

    0.2

    0.1

    0.1

    0.1

    0.1

    0.2

    0.3

    0.2

    0.2

    0.3

    0.2

    0.1

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.1

    0.1

    0.3

    0.3

    0.5

    0.5

    0.3

    0.4

    0.4

    0.4

    0.3

    0.4

    0.3

    0.2

    0.4

    0.3

    0.2

    0.3

    0.6

    0

    0

    0

    0.2

    0.2

    0.1

    0.2

    0.2

    0.4

    0.3

    0.4

    0.7

    0.8

    1.1

    1.1

    0.8

    0.9

    0.6

    0.5

    0.3

    0.1

    0

    0

    0

    0

    0

    0

    0

    0.1

    0.1

    0

    0

    0.2

    0.1

    0

    0.1

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0

    0.2

    0.2

    0.1

    0.3

    1

    0.9

    0.8

    1

    0.7

    0.9

    0.7

    0.5

    1

    0.9

    0.7

    0.6

    0.4

    0.4

    0.2

    0.1

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0.1

    0

    0.1

    0.1

    0.2

    0.1

    0.2

    0.1

    0.2

    0.3

    0.3

    0.3

    0.4

    0.3

    0.3

    0.3

    0.3

    0.4

    0.3

    0.4

    0.3

    0.4

    0.3

    0.4

    0.4

    0.5

    0.4

    0.4

    0.4

    0.3

    0.5

    0.4

    0.4

    0.5

    0.5

    0.4

    0.4

    0.3

    0.4

    0.4

    0.4

    0.3

    0.4

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.1

    0.3

    0.1

    1

    1.1

    0.6

    0.3

    0.3

    0.2

    0.1

    0.2

    0.1

    0.3

    0.2

    0.2

    0.2

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.3

    0.2

    0.2

    0.3

    0.3

    0.3

    0.3

    0.2

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.3

    0.4

    0.6

    0.6

    0.6

    0.5

    0.5

    0.4

    0.4

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.3

    0.2

    0.2

    0.4

    0.3

    0.1

    0.2

    0.2

    0.5

    0.7

    0.5

    0.5

    0.3

    0.2

    0.1

    0.1

    0.1

    0.3

    0.2

    0.1

    0.2

    0.2

    0.3

    0.2

    0.3

    0.2

    0.1

    0.1

    0.1

    0.3

    0.8

    1.6

    1.1

    0.2

    0.4

    0.1

    0.1

    0

    0

    0

    0

    0.2

    0.4

    0.5

    0.2

    0.6

    0.4

    0.5

    0.2

    0.2

    0.2

    0.1

    0.1

    0

    0

    0

    0

    0.1

    0

    0.1

    0.1

    0.1

    0.1

    0

    0.1

    0

    0.1

    19.4

    11.3

    0.1

    0.1

    0.3

    0.2

    0.3

    0.5

    0.7

    0.9

    0.9

    1.3

    0.6

    0.1

    0

    0.2

    0.2

    0.3

    0.3

    0.1

    0.1

    0.3

    0.1

    0.1

    0.2

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.3

    0.3

    0.2

    0.1

    0.2

    0.3

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.2

    0.3

    0.3

    0.3

    0.3

    0.2

    0.3

    0.4

    0.4

    0.6

    0.6

    0.5

    0.6

    0.6

    0.5

    0.6

    0.6

    0.6

    0.5

    0.5

    0.5

    0.9

    0.7

    1.4

    0.4

    0.4

    0.3

    0.6

    1

    0.7

    0.6

    0.5

    0.6

    0.3

    0.4

    0.3

    0.2

    0.3

    0

    0

    0

    0.3

    0.2

    0.3

    0.3

    0.3

    0.4

    0.6

    0.5

    0.6

    0.5

    0.5

    0.3

    0.3

    0.3

    0.4

    0.4

    0.4

    0.4

    0.7

    0.7

    0.6

    0.7

    0.8

    0.7

    0.7

    0.1

    0.2

    0.9

    0.8

    0.9

    0.1

    0.1

    0

    0

    0

    0.1

    0.1

    0.1

    0

    0

    0

    0

    0

    0

    0

    0

    0.1

    0

    0

    0

    0.1

    0.2

    0.1

    0.2

    0.1

    0.1

    0.1

    0.1

    0.1

    0.1

    0.2

    0.1

    0.1

    0.1

    0.1

    0.1

    0

    0

    0

    0.2

    0.2

    0.2

    0.2

    0.3

    0.2

    0.2

    0.2

    0.3

    0.4

    0.3

    0.4

    0.2

    0.1

    0

    0.1

    0.2

    0.1

    0

    0

    0.1

    0

    0.1

    0

    0

    0

    0

    0

    0.1

    0.1

    0.1

    0