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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 1

     Submitted to:

    Whom it may concern

    Pak-Arab Company limited

     Submitted by:

    Muhammad Yousaf

    Internee #: 04 (TSD)

    University of Punjab Lahore.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 2

    Thank you Parco for giving such respect.

    For me Parco stands for

    P for people who are Friendly.

     A for people who are Amazing.

    for people who are respectful.

    C for people who are truly caring.

    O for people who worth’s like ornaments.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 3

    Dedicated to

    The One in Whose Hands My Life Is

    "And Allah has brought you out from the wombs of your mothers while you know

    nothing. And He gave you hearing, sight, and hearts that you might give thanks (to

    Allah)"

    [Quran, 16:78] 

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 4

    Acknowledgement:

    This report is only made possible due to combine efforts of all the members MCR and specially the

    Engineers from Technical Services Department (TSD-MCR) who has given best of their efforts and

    available time to make me things clear.

    I would like to thank Mr. Khalil Ur rehman and my respective mentor Engineer Muhammad Abubakar

    and Imran rasheed the great and kindest of all in the organization and charming personality who

    guided me during my entire internship. I have not seen such a versatile and super kind personality in

    my life.

    Also to the members of HR and TSD department who has provided me the opportunity for internship

    and facilities during stay to the internees. Special thanks to following members.

      Mr. Khalil ur rehman

      Mr. Abubakar

      Mr. Imran Rasheed

      Mr. Zubair ahmad

      Mr. Farooq

      Mr. Ameer Gull

      Mam khalida

      Mr. Usman 

    Finally, I wish to thank my parents and my all Teachers for their support and encouragement

    throughout my study.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 5

    T able Of Contents:  General Training:

      Introduction to PARCO

      Technical Services Department 

      Health Safety and Environment

      Fire Protection Department

      Specific Training:

      Crude distillation unit 100 

      Vacuum distillation unit 110 

      Vis breaking unit 130 

      Gas concentration unit 411 

      Nephta hydro treating unit 200 

      Kero-Merox unit

      LPG-Merox unit 

      Storage tanks 

      Assignments  

      All assignments that were assigned are attached with report.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 6

    General Training:

      Introduction to PARCO & MCR

    Parco

    A Pakistan Abu-Dhabi Joint Venture.

    Corporate Objectives

    To consolidate financial and organizational gains, PARCO purposes the following objectives;

    Professional and progressive corporate outlook

     Aggressive technical thinking and advanced planning

    Reliability of service 

    C onsistency in performance

    Organized and systematic development

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 7

    C OMPANY PROFILE:-  PARCO! Means ENERGY.

    Incorporated in Pakistan in May 1974, as a public limited company, Pak-Arab

    Refinery Limited (PARCO) is a joint venture between the Government of

    Pakistan (GOP) and Abu Dhabi. Its authorized capital is Rs.15 billion and the

    current paid-up capital of PRs. 2.16 billion IS in the process of being raised to

    Rs.II.6 billion by the end of year 2002. 60% of the share capital is held by GOP,

    and 40% by Abu Dhabi Petroleum Investments (ADPI). In the last 25 years, the

    company has expanded a phenomenal 24 times and has achieved an equity

    base of over PRs 12 billion and an asset base exceeding PRs. 92 billion or just

    over US$ 1.5 billion in current dollar terms.

    " An enlightened investment decision in anyone's books!"  

    It was the first AAA credit rated Company by PACRA in the country and

    continues to command that credit worthiness for an unprecedented fifth year-

    running. The Management of the Company is vested in a Board often Directors

    of which GOP appoints six Directors including the Chairman and the Managing

    Director and the remaining four Directors represent ADPI. The Managing

    Director is the Chief Executive of the Company and the Federal Ministry for

    Petroleum and Natural Resources performs an overview role and represents the

    interest of the Government of Pakistan.

    PARCO is truly Energy Company.

    PARCO as an energy company is the fulcrum and key building block in the

    country's strategic oil supply and its logistics. With the synergy of a

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 8

    comprehensive and expanding oil pipeline network, integrated with a significant

    and modem refining capability, PARCO has emerged as the strategic fuel

    supplier to the country. Parco's discrete areas of competitive advantage will

    enable it to achieve excellence in  Energy transportation through pipelineoperations and management, strategic storage, leading edge refining and

    leadership in marketing products through retail and exports.

      PARCO Mid-Country Refinery

    PARCO is actively involved in various facets of Oil Storage, Transportation,

    Refining, Marketing and Export of Energy products. It serves as the lifeline for

    transportation of fuel supplies in the country and represents more than 40% of

    the indigenous refining capacity. It has the most comprehensive cross-country

    oil pipeline and storage network with a 100,000 BPD state-of-the-art refinery

    based on latest leading edge refining technology and processes. Commissioned

    in the year 2000, a full month ahead of schedule and within the approved

    budget of US$ 836 million, the sensibly located ''Mid Country”. 

    Refinery was formally inaugurated in February, 200I by the Chief Executive of

    Pakistan. Besides being the critical inland supplier to the high consumptioncentral and northern areas of Pakistan, PARCO also assists with the balance of

    payments of the country. It helps substitute imports of refined value added oil

    products to the tune of $100 million annually and has additionally earned more

    than US$50 million through exports of quality 90 RON Unleaded Motor Gasoline

    and other products to international buyers. PARCO, through leaderships and

    technical where withal was successful in introducing unleaded motor gasoline in

    the country in June 2001, fully four years ahead of the World Bank

    recommended time frame. Future generations of Pakistanis will be thankful for

    Having been ensured a much healthier environment and improved quality of life

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 9

    With the coming on-stream of the refinery operations, the company has begun

    marketing of its fuel products and LPG. Under a Technical Services and Support

    Agreement (TSSA), SHY of Holland is marketing25% of the LPG production as

    PARCO's brand 'PEARL Gas.' PARCO is also marketing OMY Austria's lubricantsthrough the brand name of 'PEARL Lubes'. PARCO has also entered in to a joint

    venture agreement with Total Final lf of France whereby consumer petroleum

    products are marketed under the co-branding of TOTALPARCO through a rapidly

    emerging national network of retail outlets. Already more than a dozen have

    been commissioned in the Punjab, and over the next decade about 500 stations

    will be dotted across the country.

      Pipeline Network

    The refined petroleum products transport logistics on road and rail and the

    existing pipeline network. The surface transport mode is potentially hazards to

    other traffic, human lives and the environment besides wear and tear of road

    surfaces. PARCO’s pipeline network is a safer and more cost effective

    alternative for both crude and product transportation. With the completion of

    the White Oil Pipeline in about two years, a more comprehensive, safer, cost

    effective, demand responsive and eco-friendly pipeline network will be

    available to meet the country’s growing needs for energy.

      The project facts are summarized below;

    Location Qasba Gujrat / Mahmood Kot

    Project cost US $886 million

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 10

    Main supply and construction contractors JG and Marubeni Corporation

    Japan.

    Completion Period 36 months

    First crude in Pipeline August03, 2000

    First crude at Refinery site August25, 2000

    First product out September04, 2000

      Why PARCO is Mid- Country  Refinery?

    Petroleum product demand in Pakistan has outstripped local production

    Demand in Northern region of Pakistan is more than 60% of Pakistan’s total

    requirement Furnace oil being a viscous product cannot be transported over a

    long distance in pipeline to meet requirements of power plants in the vicinity of

    Mehmood Kot. It is more economical to transport crude oil to Mid-Country

    Refinery & produce products including Furnace oil. Indigenous refining

    capability brings additional security and the desired flexibility of product supply

    with respect to imports.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 11

    PARCO Mid-Country Refinery has a lead of at least 3-4 years on any other

    refinery project in the country giving market positioning benefits and ensuring

    maximum commercial advantage. Parco’s 1,228-Km cross country pipe line is

    already available for crude/product transportations.

      Advantages Of This Location for Refinery;

    Sensible and strategic location from a commercial and national security point of

    view. Server’s major consumption centers catering to a population of 35 million

    with a current /projected significant deficit. Is close to located close to power

    plants with an annual demand of 1 million tons of Furnace oil.

    Parco’s existing infrastructure at Mehmood Kot terminal (TS-2) has been

    optimally integrated into the Refinery resulting in cost saving and improved

    operations. Streamlines the movement of Crude Oil and petroleum products

    thus reducing the burden on country’s rail/road transportation. Is close to

    petroleum demand centers giving advantage for the future growth into bulk

    petrochemicals. Utility supplies have been secured through adjacent power

    plants and there is plenty of water to meet Refinery requirements.

    An Overview to PARCO;

    The refinery complex include onsite process units beside numerous

    offsite/utilities units and other permanent facilities with tanks to store the

    crude oil, intermediate feeds stocks and finished products.

    •   H ealth Safety and Environment

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 12

    Why Health Safety and environment?

    Accidents can take place anywhere around the world. These accidents affect

    profit, company’s reputation and environment. There is no budget assigned to

    these unpredicted incidents. Over the years, numerous oil companies have

    encountered major accidents which resulted loss of billions of dollars and

    loss of many lives. Let’s put some light on some of the major accidents

    hitting oil and gas sector around the world. Some of the disasters are as

    follow

    •   Piper Alpha 1988

     – Explosion, Oil and Gas caught fire on the rig

     – 167 workers killed

     – 1.7 billion pound of property damage

    •   BP Texas Refinery 2005

     – Dangerous gases level emitted

     – 8 warnings given by the government

     – System over pressured, liquid erupted

     – 17 people killed

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 13

     – US $ 1.3 billion

    •   BP’s Deep -water Horizon Oil Spill 2006

     – Wellhead Blowout

     – Fire on Oil Rig

     – 4.9 million barrels of oil spilled in the Gulf of Mexico

     – 11 people killed

     – US $20 billion spent on recovery

    Above given examples tell us about the consequences a company might have to

    suffer in case of an accident. It is evident that there is a dire need of a

    department which can help minimize the chances of an accident, which does

    regular auditing of the safety around the plant area and which can put a strong

    check on the implementation of rules at the refinery area.

    PARCO HSE department policy statement “PARCO is committed to enhance

    customer satisfaction through continual improvement, operational excellence

    and in time delivery of quality products while remaining watchful over the

    safety, health and environmental concerns of its employees, contractors and

    the general public associated with it.”

    Furthermore HSE policy ensures the provision of health and safety of its

    employees and maintains an ecological balance is the responsibility of the

    company. The department is not only concerned for the company’s employees

    and the refinery area, but it is also consistent in protecting the people living

    outside PARCO, minimizing hazards, creating a safe atmosphere to work at.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 14

    In order to guide the employees regarding their safety, HSE conducts regular

    seminars and training sessions so that the employees are prepared to handle

    any kind of challenging situation at the refinery area.

    VISION: We aim to be an organization where individual and collective effort

    achieves outstanding HSE performance, evident for all to see. HSE is treated at

    par with productivity and profitability. HSE policy statement recognizes that the

    provision of health and safety of its employees and maintain an ecological

    balance is the responsibility of the company.

    •   FIRE MANAGEMENT SYSTEM

    Fire is a potential hazard, especially in hydro-carbon industry such as PARCO. It

    is very crucial for these organizations to have Fire Management System in order

    to minimize losses and overcome fire as soon as possible in case of a fire

    accident. A Fire Management System includes;

     – Fire Detection, Prevention and Suppression

     – Emergency Response

     – Fire Fighting

    HSE ensures Fire Prevention system by;

     – Work Permit Procedures; No activity in plant area can be done without getting

    Work permit from the relevant authorities

     – Regular tests and audits of fire equipment

     – Installing lightening arrestors at plant

     – Classification of hazardous areas

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 15

     – Use of intrinsically safe equipment; equipment (might be electronic) which are

    fully covered with insulation and do not pose any threat to a hydro carbon

    refinery area

     – Apart from IS equipment, no electronic device is allowed inside the plant area.

     – No worker can carry lighter or matchsticks inside the plant area.

     –  For smokers, isolated and safe smoking booths are installed at numerous

    points in the plant area.

     – Use of Floating roof tanks for storage purposes. The roof rises and falls with

    the liquid level in the tank.

    •   Fire Detection

    Different kinds of detectors are installed around the plant area to detect release

    of any dangerous hydrocarbon or detect fire at plant are;

     – Smoke Detector

     – Heat Detector

     – Hydrocarbon Detector

     – Infra-Red Flame Detector

    •   Fire suppression

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 16

    Suppression systems use a combination of dry chemicals and/or wet agents to

    suppress equipment fires. Following is a list of Fire Suppression systems and

    equipment used at PARCO;

    •   Fire Extinguishing Methods

    Parco has state of the art equipment to fight a fire with a complete fire brigade

    squad ready 24 hours for firefighting operation. Following is a list of firefighting

    equipment;

     – Fire Brigade Trucks

     – Fire Hoses installed at different spots including storage tanks area

     – A network of water Pipeline (red colored) which covers almost every spot of

    the area and is fully pressurized by 2 Jockey pumps. In case of fire, rest of the 4

    main pumps start within 10 seconds one after the other.

     –  Above mentioned pipeline is used to refill fire brigades, fire suppression

    system, hoses etc.

     – Foam tanks

     – Fire hydrants

     – Fire suits

     – Fire extinguishers

     – Ladders

     – Fire Drills

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 17

    •   Emergency Response

    In MCR, there is a well-established accident response system. Following are the

    vital components of the communication system for emergency at MCR;

     – Manual Call Point

     – Telephone (emergency # 4000 or 11)

     – Radio communication (Motorola)

     – Fire Alarm Panel

    •   Emergency Alarm

    In case of Emergency HSE turns on the master alarm which has a sinusoidal

    sound wave and goes on for about two minutes. As soon as the fire alarm goes

    on, each employee is supposed to rush to the respective assembly point

    assigned for each area at MCR.

    Onsite Process Units and their Capacities

    Unit

    Code Unit Cap(BPSD)

    100 crude distillation 100,000

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 18

    110 Vacuum distillation 42,800

    200 Naphtha hydro treating 25,600

    300 CCR Plat former 16,350

    284 Dieselmax 22,450

    130 Visbreaker 15,560

    801 Kerosene Merox 20,000

    802 LPG Merox 4,500

    411 Gas Concentration 22,050(liquid)

    11,242(Gas/MMSCR)

    810 Amine Treating 7,721(FG/MMSCR)

    9,963(sws)

    820 Sulfur Recovery 115 MTPD

    T ECHNICAL SERVICESDEPARTMENT (TSD)

    Mission Statement:-

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 19

    Support production targets and Meet future challenges in industry, while

    Ensuring trouble free Economical operations in All instances by adopting Best

    practices & Improvements in technology on Sustainable basis.

    Main functions:-

      Support Refinery operation to meet the production targets at optimum

    cost.

      Quality control of intermediate and product streams.

      Troubleshooting and debottleneck studies.

      Turnaround planning and execution of various special activities.

       Advice and assist in technology upgrades, plant modifications and future

     projects.

      Management/coordination of Technical Review for CRs & QRI systems.

      Preparation of Monthly Progress Report of Refinery Performance. 

    The technical services department has three sections:

      Process Engineering Section

      Production Planning & Oil Accounting Section

      Laboratory

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 20

    P rocess Engineering Section:

    The process engineering section is responsible for the trouble shooting,

    monitoring of the Refinery Operation and also to give the technical assistance

    for further improvements.

    The department is directly concerned with the on-site units, which include:

    1.  Crude Distillation Unit

    2.  Vacuum Distillation Unit

    3.  Gas Concentration Unit

    4.  Visbreaker Unit

    5.  Dieselmax Unit

    6.  NHT/CCR/Platformer

    7.  Meroxes

    8.  Amine treating Unit

    9.  Sulfur recovery unit

    10. DHDS

    11. AABU

    12. Storage tanks

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 21

    Laboratory section:The MCR has got well-equipped laboratories some of which are listed as under:

    Diesel Lab:

    Following tests are being carried out in the laboratory:

      Distillation  Flash point

      Pour point

      Specific Gravity

      Viscosity

    Octane Analyzer Room:

    The research octane number of naphtha is tested.

    Water Laboratory:

    The pH, hardness SiO2 content, conductivity etc. of water is tested prior to

    feeding the water to the boiler.

    Ca2+, Mg2+ ions are tested by titration.

    Introducing ammonium molybedate to water checks SiO2 content.

    Respective meters check conductivity and ph.

    Jet Fuel and Gasoline Lab:

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 22

    Flash points are measured using Abel closed cup apparatus. Corrosion tests are

    carried out using copper strips in copper corrosion bath. Jet Fuel Thermal

    Oxidation Stability Test is carried out.

    Gas Chromatography Lab:

    Gas chromatography is carried out for the PONA test (paraffin’s, olefins,

    naphthenic, and aromatics) of the sample of naphtha.

    LPG Lab:

    Weathering tubes are used to measure the evaporation temperature of the LPG.

    95% of LPG should evaporate at not more than 4.4degC.

    Atomic Absorption Lab:

    Trace metals e.g. Li, K, Zn, Na, Fe are detected on basis of absorption using

    spectrophotometer.

    Overall refinery process:-

    The overall refinery process flow sheet diagram,

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 23

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 24

    C rude Distillation Unit(unit 100):

    The crude distillation is design to process 100,000 BPSD of crude. The feed of

    this unit is:

      100% Arabian light crude

      70% upper Zakum and 30% Murban crude oil

    The crude distillation unit consists of the following sections;

      Crude charge and pre-heat section.

      Crude de-salter section.

      Crude charge heater section.

      Crude column and site cut product section.

      The unit functions to separate the crude oil into different cuts: naphtha,

    kerosene, diesel and reduced crude. These cuts are further processed to

    the gas concentration unit, Kero-merox unit and for blending and vacuum

    distillation unit.

    Arabian light, upper zakum and murban crude oil coming from Karachi

    To Mahmood Kot via several kilometers pipe line is coming to the unit

    Crude distillation.

    All the crude contains salt water together with sediment depend upon the area

    from which the crude is produced

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 25

    Salt content is reported as pounds of salt per thousand barrels of oil.

    Old method heating of oil was settling or addition of chemicals before settling.

    But now a day a new method has been introduced named as Electrical desalting.

    It is a two stage process

      Emulsion of crude oil and water ( mixing )

      Demulsification ( breaking)

    Approximately 95% of salt is present in base sediment of crude.

    The emulsion is produced by passing the liquids at high velocity through theorifice or b/w the fixed surfaces.

    This is accomplished by a mixing valve upstream of the electric desalter or by

    injecting the water at the start of exchanger train that proceeds to the desalter

    Greater the pressure drop greater will be mixing.

      Low velocity desalter

    It is used where oil contains 50% of salt in continuous phase of crude oil. Oil

    passing through the distributor and then upward at relatively low velocity

    through electrodes.

    Initial coalescence takes place between the oil water interphase and lower

    electrode and final coalescence takes place where the drops coalesce and

    Becomes large and fall against the upward flow of oil to the bottom with thegravity action.

    The oil interphase is controlled by the interface level controller which bleeds the

    water from bottom of the tank and the clean crude oil from top.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 26

      High velocity desalter

    It is used for stable emulsions and having the same elements as low velocitydesalter. We use high velocity because the emulsion particles can form a chain

    between the electrodes and can cause a short circuit.

    In crude distillation unit low velocity desalter is used.

    From the desalter the heat is then proceed to the fire heaters and gain the

    require heat before entering to the crude distillation unit.

    The temperature of the feed can vary from 315 oC. To 427 oC.

    Then after heating in fire heaters the crude enter in the flash zone of

    fractionation column.

    There are 40 trays into the distillation unit some of the material flashes into

    vapor which rises up to the column.

    Rest of the feed goes down with the trays. Steam from near the 40th tray is

    introduce into the column which goes upward taking with the lighter ands and

    heavier ends collected at the bottom.

    There is accumulative tray between 27

    th

     and 28

    th

     tray from which the diesel isstripped and there is another accumulator tray between the 15th and 16th tray

    from which the kerosene is stripped similarly from between the 4th and 5th 

    accumulator tray the unstabilized naphtha is stripped.

    The overhead vapors are carried out of crude column and pass through the

    condenser where all of the steam and gasoline vapors are condensed into the

    liquid.

    A portion of the liquid is sent to the fractionator as top reflux while rest of netliquid overhead is pumped to the gas concentration process unit.

    And the uncondensed gas from the overhead is sent to the Gas concentration

    unit.

    All products are cooled before being sent to the storage.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 27

    This is accomplished by the use of heat exchange with crude oil feed, air fin

    coolers and trim coolers and also circulating cooling tower water with

    exchangers.

    The lighter products should be cold before send to the storage to reduce vaporlosses in storage tanks but the heavier products not need to be cold as they can

    b use as feed to another unit depending upon the unit inlet temp we can use it.

    A product must never leave with a temperature 100 oC. If there is any

    possibility of it passing through the tank containing water the hot product can

    boil the water and forming the steam which can blow off the roof of tank.

    The block diagram of the crude distillation unit is given as,

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    University of Punjab Lahore.

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      PAK- ARAB REFINERY COMPANY LIMITED

    University of Punjab Lahore.

    PAK-ARAB COMPANY LIMITED Page 29

    V acuum Distillation Unit:To achieve maximum recovery of gas oil from crude we introduce it into the

    vacuum distillation column. The vacuum residue is designed to process the

    atmospheric residue of either Arabian light crude oil or upper zakum and

    murban crude oil blend. The processing capacity of vacuum distillation is 42,800

    BPSD

    The feed of the vacuum distillation unit is

      100% Arabian light Crude residue  70/30% volume blend of Upper Zakum and Murban crude residue

    The unit is composed of the following sections;

      Vacuum charge heater section

      Flash zone section

      Product condensation

      Heat exchangers

    Reduced Crude from the CDU is charged to the VDU through vacuum

    heaters at less pressure. Distillation takes place in the presence of

    vacuum to prevent degradation of reduced crude. Temperature should

    not be so high that cracking does not take place if this happens then it is

    necessary to lower the temperature. Flash zone temperature widely

    depends on the crude source.

    Flash zone section is the section residue of crude oil is flashes at a

    pressure below than the atmospheric usually less than 1 atmospheric

    pressure and at a temperature where gas oil usually not fractionate and

    also the bottom residue will not suffer nay thermal decomposition.

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    The maximum performance or ability to lift the gas oil depends on the

    lowest absolute pressure that can be maintained in flash zone with

    maximum non cracking temperature. The optimum temperature of flash

    zone is 399 oC.

    Vacuum column operates on the principle that boiling point of any

    material is lowered as the pressure id reduced.

    Vacuum residue must be handled very carefully that most of the refinery

    products, the vacuum bottom pump which handle very hot liquid can lose

    its suction. It can be minimized by introducing some cooled vacuum

    bottom to the column bottom and can reduce the tendency to form

    vapor. This problem can also be minimized that vacuum bottom pump’s

    gland should be tightly close so that air cannot be introduce into pump.

    The vapor rising from the flash zone of is the gas oil product and no

    further fractionating is required. All we just need now is to condense

    these vapors as efficiently as possible. This can be done in tube and shell

    condensers but these are inefficient at low pressures and a high pressure

    drop through this condenser will raise the flash zone pressure.

    That’s why the most efficient method is to contact the hot vapors with

    the cooled liquid in heat exchanger.

    In order to reduce the cost of operating the vacuum distillation column

    the VDU is combined with CDU so that as much heat as possible is

    recovered from the hot product streams by heat exchanging with the cold

    crude streams.

    The vacuum gas oils are then routed to Dieselmax unit and the vacuum

    residue is then forward to the Visbreaker unit.

    The block diagram of the vacuum distillation unit is as given,

    The products if the vacuum distillation unit is

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      Light vacuum gas oil ( LVGO )

      Heavy vacuum gas oil ( HVGO )

      Vacuum residue

       M   S

       W   A   S   T   E   G   A   S

       T   O   1   0   0  -   H   1

       S   t  r   i  p  p   i  n  g   S   t  e  a  m

       H   S

       L   S

       T   W   S

       1   1   0  -   E   A   4

       T   W   R

       1   1   0  -   E   2

       9   4   5  -   E   7   2

       8   4  -   E   1   2

       F  u  e   l   O   i   l   T  a  n   k  s

       F  u  e   l   O

       i   l

       C   W   S

       C   W   R

       L   S   L

       S  o  u  r   W  a   t  e  r

      m   3   /   h

       1   1   0  -   E   A   1

       1   1   0  -   E   A   3

       1   1   0  -   V   1

       1   1   0  -   V   1

       1   1   0  -   H

       1

       1   1   0  -   H   1

       M   E   1  -   J   1   A   /   B

       M   E   1  -   J   3   A   /   B

       M   E   1  -   J   2   A   /   B

       M   E   1  -   E   3

       M   E   1  -   E   2

       M   E   1  -   E   1

       F   O   B

       V   G   O   T   A   N   K

       F   O   B   D   O   B

       L   D   O

       V   G   O   T   K

       D   M   A   X

       L   V   G   O

       H   V   G   O

       S   l  o  p   W  a  x

       V  a  c  u  u  m   B  o   t   t  o  m

       V   B   U

       F   O   B

       R   F   O

       1   0   0  -   E   1   9  -   1   7

       1   1   0  -   E   2

       1   1   0  -   E   1

       1   0   0  -   E   1   8  -

       1   5  -   1   3  -   1   1

       C   R   U   D   E

       C   R   U   D   E

       F   E   E   D

       R  e   d  u  c  e   d   C  r  u   d  e

       1   1   0   V   6

       1   1   0   V   6

       1   1   0  -   V   7

       1   1   0  -   V   7

       1   1   0  -   V   2

       1   1   0  -   V   2

       1   1   0   V   3

       1   1   0   V   3

       1   1   0  -   V   4

       1   1   0  -   V   4

       1   1

       0  -   P   4

       1   1   0

      -   P   3

       1   1   0  -   P   2

       1   1   0  -   P   1

       1   1   0  -   P   7

       V   A   C   U   U   M    D

       I   S   T   I   L   L   A   T   I   O   N

       U   N   I   T

       V   A   C   U   U   M    D

       I   S   T   I   L   L   A   T   I   O   N

       U   N   I   T

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    V isbreaker unit:

    The Visbreaker Process Unit is designed to process 15,560 BPSD of vacuum

    residue from the Vacuum Distillation Unit, based on the Crude and Vacuum

    Distillation Units processing 100% Arabian Light crude oil and 70/30 volume

    percent blend of Upper Zakum/Murban crude oils.

    The feed of the Visbreaker unit is,

      Vacuum residue

    The visbreaking unit is the combination fuel gas and fuel oil fired In the presence of

    heat the bottoms are broken to give off gases, naphtha and vacuum bottoms.

    Heating the material to predetermined heater outlet temperatures and rapid

    quenching of furnace outlets facilitates thermal cracking and altered viscosity

    necessary for further processing.

    This unit consists of three heaters for heating purpose. For safety purpose the

    sour water from this section is forward to the amine treating unit.

    The products of the visbreaking unit are,

      Off gases

      Unstabilized naphtha  Visbreaker bottom residue

    The block diagram of Visbreaking unit is,

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    G as concentration unit:-

    The Gas Concentration Process Unit is designed to recover C3/C4 LPG and to

    produce a stabilized naphtha feed to the Naphtha Hydro treating Unit. Gases

    from various process units will be compressed and routed through an

    absorption system to maximize the recovery of LPG.

    The feeds of the gas concentration unit are,

    Feed gases to the Gas Concentration Process Unit are as follows:

    •  Gas from the Net Gas Compressor at the Crude Distillation Unit in case of

    Upper Zakum and Murban blend oil feed.

    •  Gas from the Fractionator Receiver at the Visbreaking Unit.

    •  Gas from the Stripper Receiver at the Diesel max Unit.

    •  Gas from the Flash Fractionator Receiver at the Diesel max Unit.

    •  Gas from the Stripper at the Naphtha Hydro treating Unit.

    The liquid feeds to the Gas Concentration Process Unit are as follows:

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    •  Unstabilized naphtha from the Crude Distillation Unit.

      Unstabilized naphtha from the Fractionator Receiver at the Visbreaking

    Unit.

      Unstabilized naphtha from the Product Fractionator Receiver at theDieselmax Unit.

      Unstabilized naphtha from the Flash Fractionator Receiver at the

    Dieselmax Unit.

      Unstabilized liquid from the Stripper Receiver at the Naphtha Hydro

    treating Unit.

    The operation of gas concentration unit consist of the following three major

    sections

      Compressor section

      Absorption section

      Distillation section

    In the compressor section the gas is pressurize for further use in other two

    sections.  All incoming gas streams except for the Naphtha Hydro treater

    Stripper gas combine and flow into a two stage centrifugal compressor via the

    compressor suction cooler and the compressor suction drum. Mists separated

    and accumulated in the compressor suction drum is manually drained out and

    sent to the CDU.

    Gas from the Naphtha Hydrotreater Stripper combines with the first stage

    discharge which is pressurized from 3.7 kg/cm2G to 8.2 kg/cm2G, and enters the

    second stage of the compressor via the inter stage cooler and the compressor

    inter stage suction drum

    Gas pressurized to 17.1 kg/cm2G mixes with the Stripper overhead vapor, the

    incoming liquid stream, and Primary Absorber bottoms. The combined stream is

    cooled in the high pressure cooler and sent to the high pressure receiver Liquid

    separated and accumulated in the compressor inter stage suction drum is sent

    to the combined stream by the compressor inter stage suction drum pumps.

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    The absorption process consists of passing a cooled liquid of heavier

    components downwards through a column while a gas of lighter components

    travels upwards through the same column. During this process the heaviercomponents of the gas are recovered from the gas by absorption. The degree of

    absorption is controlled by the ratio of liquid flow to gas flow, the degree of

    contact time between the two flows, and the temperature of the heavier liquid

    flow.

    The first column in the absorption process is the primary absorber. In the

    primary absorber, the liquid flow, which is stabilized naphtha coming from the

    debutanizer, enters the column above the first tray. The C3/C4 rich gas stream

    from the high pressure receiver enters the column below the bottom tray. The

    degree of absorption in this column is partly controlled by a reflux stream near

    the middle of the column. This intercooler stream is withdrawn from the draw

    tray No. 16 in the middle of the column and passes through a cooler before

    returning to the column just above the draw tray on flow control. The

    intercooler reflux is returned to the column at approximately the same

    temperature as the stabilized naphtha entering the top of the column. This

    cooling is necessary due to the increase of temperature of the absorbing liquid

    caused by the heat of absorption. This cooling of the liquid stream allows for

    better recovery of the C3/C4 material. The primary absorber rich oil from thebottom of the column returns to the high pressure receiver, where most of the

    light material recovered is pumped with the heavier material to the stripper for

    further processing. The operation of the stripper will be discussed in the

    distillation process section.

    The second column in this process is the sponge absorber. This column is smaller

    in size and filled with packing that allows intimate contact between the liquid

    and gas streams. The overhead of the primary absorber is directed to the

    bottom of the sponge absorber, while the circulating diesel enters the top of the

    column.

    The process principal of the sponge absorber is the same as the primary

    absorber, in that the overhead gas from the primary absorber is intimately

    contacted with a heavier liquid to recover the C3/C4 material that was not

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    absorbed in the primary absorber. The main differences between the primary

    and the sponge absorber are the internals of the column, and the type of lean

    Oil used. Instead of trays like those used in the primary absorber, the sponge

    absorber has a packed section to cause the intimate contact between the down

    flowing liquid and the upward flowing gas. The sponge absorber does not have a

    reflux flow as the primary absorber does, but the sponge absorber has a

    demister blanket installed near the top of the column to aid in the removal of

    liquid from the gas leaving the top of the column. The lean oil used in the

    sponge absorber is circulating diesel from the Crude Unit. After passing down

    the column, the diesel is collected in the bottom of the column where it is

    returned to the Crude Unit as rich oil on level control at the bottom of the

    sponge absorber. Pressure control for the absorption section is placed on the

    lean gas exiting the top of the sponge absorber. The lean gas after passing

    through the pressure control valve is directed to the Amine Treating Process

    Unit and then to the refinery fuel gas system. And the pressure control valve

    maintains a constant pressure on the entire absorption system.

    Liquid hydrocarbon from the high pressure receiver is pumped to the stripper

    where hydrogen sulfide (H2S), ethane and lighter components are stripped out.Feed to the stripper is heated using the total debutanizer bottoms stream in the

    stripper feed exchanger. Stripper charge enters the column above the top tray.

    Stripping action is provided via reboilers at the bottom of the column through

    which heat is supplied from the debutanizer bottoms stream and MP steam. The

    steam flows through the tube side of the stripper reboilers with its condensate

    flow regulated by a flow controller which is reset by the stripper overhead

    vapor rate. The overhead vapor is returned to the high pressure cooler. Bottoms

    material is pressured to the debutanizer on level control.

    The feed to the debutanizer is the stripper bottoms stream. Heat is supplied via

    a reboiler. The heating oil to the reboiler is the circulating diesel from the Crude

    Unit. The diesel is regulated by a flow recording controller. The total flow of

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    debutanizer bottoms is directed to one of the stripper reboilers and to the

    stripper feed exchanger. After exiting the stripper feed exchanger, the

    debutanizer bottoms flow is divided into two flows. The first flow is directed on

    Flow control to the primary absorber as lean oil or sent to the stabilizednaphtha storage tank. The second flow or net production of stabilized naphtha

    is pumped on level control to the Naphtha Hydro treating Unit.

    Overhead vapors (butane, propane and propylene) are condensed by an air

    cooler condenser then collected in the debutanizer receiver a portion of the

    total overhead is pumped back to the column as reflux. The quantity of reflux is

    regulated by a flow recording controller which is reset by the level indicator

    controller on the receiver. The net overhead liquid product is pumped out on

    flow control which is reset by the Tray 10 temperature indicator controller. The

    debutanizer overhead product is pumped to the LPG Merox Unit for sulfur

    removal.

    The debutanizer column pressure is controlled by a pressure recording

    controller on the overhead vapor line which controls the amount of vapor

    directed through the condenser. The pressure differential controller regulates a

    valve in a bypass line around the cooler. This allows a small amount of vapor to

    bypass the condensing system to regulate the surface area available to

    condense the overhead vapor, hence regulating the rate at which the vapor is

    removed from the column.

    The products of the gas concentration unit are,

      LPG

      Stabilized naphtha

      Off gases

    The block diagram of the unit is as,

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    N ephta Hydro TreatingUnit:-

    The unit has the processing capability of 25,400 BPSD. This is a catalytic refining

    process and uses a catalyst and hydrogen stream to decompose the organic

    sulfur, oxygen and nitro compounds.

    The feed of the Nephta hydro treating unit is,

      Naphtha from hydro treating and Dieselmax unit in combine form

      Makeup ammonia from the Plat forming unit

    The unit has major three sections.

      Reactor section

      Stripping section

      Splitter section

    The purpose of the reactor section is to remove the naphtha fractions so that it

    can be used in the plat forming unit for the further processing. There are six

    types of reactions which occur in the reactor section of Nephta hydro treating

    unit.

    Reactions:

      Conversion of organic sulfur compounds to hydrogen sulfide

      Conversion of organic nitrogen compounds to ammonia

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      Conversion of organic oxygen compounds to water

      Saturation of olefins

      Conversion of organic halides to hydrogen halides

     Removal of organo-metallic compounds

    The feed from the Gas concentration unit or from the stabilizer naphtha tanks is

    send to the feed surge drums. Tanks must be gas blanketed so that they can

    prevent the oxygen from stabilized naphtha.

    Even trace amount of olefins can cause the polymerization of olefin and when

    stored for long times it can cause fouling and loss of heat in transfer efficiency.

    From feed surge drum the naphtha feed is pumped and combined with

    hydrogen rich stream from the recycle compressor.

    The feed combines at a point and enters in combined feed exchangers where

    the feed is heated and effluent from reactor 2 is cooled.

    The combined feed leaving the exchanger is all vapor and this combined feed

    leaving the exchanger is heated through the shall side of the reactor no 1

    effluent cooler and flow to charge in the heater where it is heated to required

    temperature.

    And then combined feed enters in the reactor no 1 which is design for down

    flow operation and contain sufficient amount of catalyst to remove

    contaminants. The reactor no 1 removes the sulfur and saturate olefins while

    the second reactor hydrogenates any recombinant sulfur formed in the reactor

    no 1.

    The effluent from reactor no 1 is cooled in effluent cooler and then enter in to

    the second reactor flows through heat exchangers and then into the product

    condenser.

    A water wash injection points are provided in the reactor so that any salt build

    up in the pipes, exchangers can be removed.

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    Then this effluent passes through the product trim condenser at a low enough

    temperature to ensure the complete recovery of naphtha and enters to product

    separator to ensure complete separation of gas, hydro carbon, liquid and water.

    It is also provided with a water boot to collect the water injected for saltremoval then the water is automatically pressured to the water stripper at

    amine treating unit.

    The rich hydrogen gas is provided to the reactors by the recycle compressor.

    This takes suction from the top of separator with the discharge combining with

    the naphtha feed upstream of heat exchangers.

    Recycle compressor suction drum is provided between the separator and

    compressor to remove any condensed liquid in the recycle gas, protecting

    compressor from damage

    Since the process consumes hydrogen, so a hydrogen rich gas stream is brought

    into the unit to make immediately upstream of heat exchanger.

    The liquid hydrocarbon is the sent to the splitter bottom exchanger and the

    Stripper Feed-Bottoms Exchanger, and thus heated material enters the Stripper,

    Stripper Reboiler is provided to supply the required heat input for stripping

    hydrogen sulfide, water, light hydrocarbons and dissolved hydrogen from the

    feed and vapor from 200v2, passes overhead to the Stripper Condenser, and

    Stripper Trim Condenser,, and to the Stripper Receiver. Normally, no netoverhead liquid product is produced, and all of the liquid in the receiver is

    pumped back to the stripper as reflux. A reflux/feed ratio of approximately

    0.25 is sufficient to strip the light ends and water from the tower. The reflux is

    pumped into the stripper on receiver, to increase the amount of reflux; the

    reboiler heat input must be increased to provide more overhead material. The

    net overhead gas leaves the receiver to Gas Concentration Unit or to flare via

    with split range control. Stripper receiver pressure is maintained at 9.4

    kg/cm2g.

    The stripper overhead system is equipped with inhibitor addition facilities to

    prevent corrosion of the process lines and equipment by hydrogen sulfide in the

    overhead vapor. The corrosion inhibitor is pumped directly from a drum,

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    diluted with a small slipstream of reflux, and injected directly into the overhead

    vapor line at the top of the stripper.

    The stripper bottoms material is pumped through heat exchangers and is sent to

    the Splitter.

    The splitter is design to split C5 and C6 components. The light naphtha product

    is mostly a C5 fraction and heavy naphtha is C6 fraction.

    The splitter feed is cooled by the stripper feed material in the splitter feed

    exchangers. Splitter boiler is provided to fulfill the heat requirement for the

    column.

    The overhead vapor is condensed in the splitter trim cooler and liquid collects in

    the splitter receiver.The light naphtha from the top of splitter is cascaded with a temperature

    controller at the top tray of splitter

      Products:

    The light naphtha is sent to tankage and for blending system while the heavy

    naphtha from the bottom of splitter is dent to heat exchanger via pump and

    then send to the plat forming unit.

    The block diagram of the unit is

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    LPG-Merox unit:-This unit has capability of processing 4500 BPSD of Lpg to achieve a sweet

    product with less than 5 wppm mercaptan and less than 20 wppm of total

    sulfur.

    The feed of the LPG Merox unit is C3/C4 from debutanizer receiver at gas

    concentration unit.

    This unit consists of three major sections.

      Pretreatment section  Extraction section

      Caustic regeneration section

    The LPG from the gas concentration unit is fed at bottom tray no 10 of amine

    absorber for counter current liquid- liquid contacting with a 20% (DEA) solution

    from amine treating unit and the lean amine from tray no 1 and at top enters

    and goes downward and contacted with the Lpg coming from bottom

    Lean amine become rich and removes from the bottom of the absorber and is

    returned to the amine treating unit. The LPG is then advanced to prewash vessel

    where it is contacted with 10 degree Baume caustic for the removal of residual

    hydrogen sulfide. LPG for caustic wash is then sent to the filters for extraction

    section. Whereas the spent caustic is sent to effluent treatment plant via spent

    caustic degassing drums.

    LPG from prewash vessel is send to the bottom of extractor. Lean caustic via

    pump is fed at top of extractor. The counter current fashion takes place. The

    rich caustic is removed from the bottom of extractor and returned to causticknockout drum to separate caustic from hydrocarbons stream.

    Then LPG is send to the sand filters which will coalesce and remove any

    entrained caustic.

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    The mercaptan rich caustic from extractor bottom and air injected is introduced

    in oxidizer where it is heated to initiate the mercaptide oxidation reaction. From

    the oxidizer the mixture enters into the disulfide separator where spend air is

    removed from disulfide separator. It leaves from the top of separator and is

    mixed with the fuel gas then it is send to the Sulfur recovery incinerator.

    The disulfide oil is pumped to the tankage and blending system for blending

    with fuel and oil gasoline.

    The block diagram of the unit is as,

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    K ero-Merox unit:-The processing capability of the Kerosene Merox Process Unit is 20,000 BPSD of

    kerosene to achieve a jet fuel product with less than 10 wppm mercaptan and

    less than 1 wppm sodium.

    The feed of the section is kerosene.

    This unit consists on major three sections.

      Pretreatment section

      Sweetening action

      Post treatment section

    The purpose of pretreatment section is to remove naphthenic acid from feed is

    that if these are not removed then sodium naphthenates are formed insweetening reactor which is surfactant and coat the catalyst and block the pores

    of charcoal catalyst support. This is achieved by alkaline electrostatic prewash.

    Mercaptans are directly converted to disulfides in fixed bed reactor system

    which remains in product and there is no reduction in sulfur contents because

    the vapors of disulfides are so low reactant to mercaptan so there presence is

    much less objective.

    Raw crude from CDU is routed directly to electrostatic coalesce prewash atpressure 8.4kg/cm2 and at a temp of 40 Degree. The feed kerosene before

    entering to prewash electrostatic coalescer is mixed with 3 degree Baume

    caustic solution by means of mixing device and pumped by caustic injection

    pump from caustic storage tank.

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    Naphthenic acid in kerosene stream is neutralized by the caustic and the spent

    caustic is settled in the electrostatic coalescer. The reaction takes place is

    RCOOH + NaOH → RCOONA + H2O 

    Then air is compressed by reciprocating compressor and is mixed with kerosene

    discharged from electrostatic coalescer. A small amount of catalyst is activator

    is injected into the kerosene stream after the addition of air. The combined

    stream passes through a bed of Merox catalyst in the reactor flows where the

    mercaptans are oxidized into disulfides.

    The sweetened kerosene from the reactor flows into the caustic settler for

    gravity separation of entrained.

    The treated kerosene from caustic settler into the water wash vessel to remove

    entrained caustic solution and water soluble surfactants.

    Wash water when required is injected by was water pump at the bottom of

    water wash vessel. The waste water is drawn from the bottom of wash water

    vessel.

    The washed kerosene is then introduced into the salt filter and then last step is

    clay filter which serves basically as a final clean-up step to assure a kerosene

    product that is free of solids, color bodies, water and soaps.

    The Salt Filter immediately ahead of the Clay Filter protects the clay from being

    rendered ineffective prematurely by free water.

    The treated kerosene product is run down to Tankage and Blending System at apressure of 3.52 Kg/cm2G and at a temperature of 40 under pressure control.

    The block diagram of the unit is as,

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     S torage tanks:-Storage tanks are containers that hold liquids used for short or long term

    storage. Storage tanks containing organic liquids, in-organic liquids and can be

    found in many industries.

    Industries where storage tanks can be found are petroleum producing andrefining, petrochemical and chemical manufacturing and other industries.

    Storage tanks are available in many shapes and having different types.

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    Fixed roof tanks are common in production facilities to store hydrocarbons with

    vapor pressure close to the atmospheric pressure. Before using it should be

    equipped with pressure vacuum valves and purge with natural gas to eliminate

    air intake into the vapor space. Product evaporate loses can be high especiallywhen crude is added to tank and vapors are expelled through the pressure vent

    valve.

    Floating roof tanks:-

    The floating roof tank has further categorized into,

      External floating roof tank  Internal floating roof tank

      Dome external floating roof tank

    External Floating Roof Tank:-

    A typical external floating roof tank consists of an open-topped cylindrical steel

    shell equipped with a roof that floats on the surface of the stored liquid, rising

    and falling with the liquid level. The floating roof is comprised of a deck, fittings,

    and rim seal system. Floating roof decks are constructed of welded steel plates

    and are of three general types: pan, pontoon, and double deck.

    Although numerous pan-type decks are currently in use, the present trend is

    toward pontoon and double-deck type floating roofs.

    Manufacturers supply various versions of these basic types of floating decks,

    which are tailored to emphasize particular features, such as full liquid contact,

    load-carrying capacity, roof stability, or pontoon arrangement. The liquid

    surface is covered by the floating deck, except in the small annular space

    between the deck and the shell; the deck may contact the liquid or float directly

    above the surface on pontoons.

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    External floating roof tanks are equipped with a rim seal system, which is

    attached to the roof perimeter and contacts the tank wall. The rim seal system

    slides against the tank wall as the roof is raised and lowered. The floating deck

    is also equipped with fittings that penetrate the deck and serve operationalfunctions. The external floating roof design is such that evaporative losses from

    the stored liquid are limited to losses from the rim seal system and deck fittings

    (standing storage loss) and any exposed liquid on the tank walls (withdrawal

    loss).

    Internal Floating Roof Tank:-

    That tank has both, a permanent fixed roof and a floating roof inside. There are

    two basic types of internal floating roof tanks:

    Tanks in which the fixed roof is supported by vertical columns within the tank

    tanks with a self-supporting fixed roof and no internal support columns

    The fixed roof is not necessarily free of openings but does span the entire open

    plan area of the vessel. Fixed roof tanks that have been retrofitted to employ an

    internal floating roof are typically of the first type, while external floating roof

    tanks that have been converted to an internal floating roof tank typically have aself-supporting roof.

    Tanks initially constructed with both a fixed roof and an internal floating roof

    may be of either type. An internal floating roof tank has both a permanently

    affixed roof and a roof that floats inside the tank on the liquid surface (contact

    deck) or is supported on pontoons several inches above the liquid surface

    (noncontact deck). The internal floating roof rises and falls with the liquid level.

    Domed External Floating Roof Tank:-

    Domed external floating roof tanks have the heavier type of deck used in

    external floating roof tanks as well as a fixed roof at the top of the shell like

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    internal floating roof tanks. Domed external floating roof tanks usually result

    from retrofitting an external floating roof tank with a fixed roof.

    As with the internal floating roof tanks, the function of the fixed roof is not to

    act as a vapor barrier, but to block the wind. The type of fixed roof most

    commonly used is a self-supporting aluminum dome roof, which is of bolted

    construction. Like the internal floating roof tanks, these tanks are freely vented

    by circulation vents at the top of the fixed roof. The deck fittings and rim seals,

    however, are basically identical to those on external floating roof tanks.

    T he Parco (MCR) storagetanks:-

    Unit 945:-

    Tank# Service Capacity (m3)

    Tk 945: Crude tanks 44169

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    1,2,34,5,6 

    Tk945: 9,10,11 HOBC product 2390

    Tk945: 12,13,14 Regular gasoline 5650

    Tk945: 15,16,17 JP-1 product 7130

    Tk945: 18,19,20 JP-8 product 2010

    Tk945: 22,23

    24

    Kerosene product 7940

    19860

    Tk945: 21,

    25,26

    Diesel product 19860

    25420

    Tk945: 27,28,29 Fuel oil product 12760

    Tk945: 30,31,32 LPG product 1530

    Tk945: 33,34 Heavy naphtha 5770

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    tanks

    Tk945: 35 VGO intermediate 29730

    Tk945: 37,38 Light naphtha tank 1630

    Tk945: 30,40 Reformate tank 5670

    Tk945: 46 Stabilized naphtha 12927

    Tk945: 52,53 Stabilized naphtha 17457

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     A ssignments

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     Assignment no 1:-

    Bottom up gradation technologies:-

    With the continuous depletion in world oil reserves and increasing demand of

     petroleum products, the refiners are forced to process more and heavier crude

    the cost advantage of heavy crudes over light crudes has incentivized many

    Refineries to process heavier crude, therefore increasing the heavy residue

     produced at a time when fuel oil demand is declining. In order to dovetail both

    the requirement for processing crude oil of deteriorating quality and enhancing

    distillates of improved quality, technological up gradation have been carried out

    at refineries which takes care of processing heavy crudes as well as maximizing

    value added products and stringent product quality requirements.

    Technologies:-

    There are two types of up gradation technologies,

      Thermal cracking technology  Catalytic cracking technology

    Cracking:-

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    Cracking of heavy residue is most commonly used method for up gradation of

    residues. This involves of decomposition of heavy residues by exposure to

    extreme temperatures in the presence or absence of catalysts.

    Thermal cracking:-

    Cracking at elevated temperatures in the absence of catalyst eg: Visbreaking

    delayed coking, Fluid coking etc.

    Catalytic cracking:-

    Cracking in presence of catalyst e.g.: FCC, Hydrocracking, and DCC

    Thermal cracking technology:-

    Thermal cracking process for up gradation of heavy residue has been used since

    long and still it is playing an important role in the modern refinery through up

    gradation of heavy residue and improving the economics of the refinery through

    the production of lighter distillate and other valuable product like low value fuel

    gas and petroleum coke.

    Thermal cracking processes and technologies:-

      Visbreaking  Delayed coking

      Fluid coking

      Flexi coking

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    Visbreaking:

    Visbreaking is essentially a mild thermal cracking operation at mild conditions

    where in long chain molecules in heavy feed stocks are broken into short

    molecules thereby leading to a viscosity reduction of feedstock. A given

    conversion in Visbreaker can b

    cracking: Soaker visbreaking.

    The process conditions are,

      Mild thermal cracking (low severity)

      Mild (470-500oC) heating at 50-200 psig

      Improve the viscosity of fuel oil

      Low conversion (10%) to 4300F

      Residence time1-3 min

      Heated coil or drum

    Delayed coking:-

    Delayed coking process is used to crack heavy oils into more valuable light liquid products with less valuable gas and solid coke as byproducts. Typical delayed

    coking consists of a furnace to preheat the feed, coking drum where the

     fractionation of the product takes place. The process conditions are,

      Operates in semi batch mode

      Moderate (900-960oF) heating at 90 psig

      Soak drums (845-900oF) coke walls

      Coked until drum solid

      Coke (removed hydraulically) 20-40% on feed,  Yield 4300F, 30%

    Fluid Coking:-

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    Fluid coking is non- catalytic fluid bed process where residue is coked by

    spraying into a fluidized bed of hot, fine coke particles. Higher temperature with

    shorter contact time than delayed coking results in increased light and medium

    hydrocarbons with less cake generation. Shorter residence time can yield higherquantities of liquid less coke, but the product has lower value. The process

    conditions are,

      Server (510-520oC) heating at 10 psig

      Oil contact refractory coke Bed fluidized with steam-even heating,

      Higher yield of light ends (

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     Assignment no 2

      What is the advantage of diesel-max unit?

    The diesel-max unit is used to maximize the production of diesel. The Dieselmax

    Process Unit Catalytically desulfurizes and denitrifies vacuum gas oil (VGO)

     feedstock and converts the feedstock to a diesel product, Kerosene, naphtha,

    and light ends including LPG in the presence of hydrogen the hydrogen gas

    which is used as feed in the diesel maxis used for saturation and removes

    oxygenates and other metallic compounds.

    Our requirements are achieved we get overhead gases which is used in further

    units and distillate is pure diesel which is used as blending component for fuel oil

    and also send to storage.

      What types of crudes are being used in the

    Parco MCR?

    There are five types of crude are being used in the refinery. They are as follow.

       Arabian light 51%

      Upper zakum 17%

      Murban crude 17%

      Local crude 7%

      Condensate crude 7%

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     Assignment no 3

    Hydrogen cycle of refinery:-

    The hydrogen gas is producing in the plat forming unit 300 and then routed to

    the net gas three stage compressors where its pressure is increased from 3.1

    kg/cm2 to 95.6 kg/cm2.Then it is routed to the chloride treater where hydrogen chloride is removed

    which can cause catalyst efficiency.

    The production rate of hydrogen in plat forming unit is 29000  Nm3/hr.

    The hydrogen gas is very important in refinery; the hydrogen gas used is due to

    that it removes impurities or gases from crude.

      Hydrogen gas is used to remove

      Sulfur as hydrogen sulfide  Nitrogen as ammonia

      Oxygen as water

      Metals

      Olefins and metal halides

    Consumption:-

    The hydrogen gas consumption in the following units as follow,

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      Naphtha hydro treating unit ( 20Nm3/m3)

      Diesel-max unit (126NM3/m3)

      DHDS unit (30-35Nm3/m3)

     Fuel gas system unit

     Assignment no 4:-

    Blending components for the followings:-

    1. 

    Mogas:-

    The Mogas is produced by blending the following,

      Light naphtha RON 73

      Heavy naphtha RON 44

      Reformate RON 98

    The research octane number of gasoline is 87.7.therefore we mix the abovecomponents in the following percentage

      Light naphtha30%

      Heavy naphtha 8%

      Reformate 62%

     And gasoline is made then it is send to the market.

    2.  Diesel:-

    The blending components of diesel is as follow,

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      Diesel-max residue

      DHDS diesel

      Straight run diesel oil

      Furnace oil:-

    The blending components of furnace oil are as follow,

      Visbreaker bottom residue 70%

      Diesel max residue 30%

    The viscosity of Visbreaker bottom residue is 1500 CST while diesel max bottomresidue has 35 CST. We mix these in proper ratio and get furnace oil. If by mixing

    they do not meet the requirements then we mix it with

      LVGO

      Straight run gas oil

      Kerosene

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    B ibliography:•  Operating manual by JGC corporation for Pak

     Arab refinery Ltd. Mid country refinery

     project, Mahmood Kot, Pakistan

    •  Refinery training manual, vol.1,2,3,4,5 Pak-

     Arab refinery Ltd, Mid country refinery

     project, Mahmood Kot, Pakistan, Shazoo Islam

     printers Multan, Pakistan

    •  WWW.weikipedia.com