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  • 8/20/2019 Iit Model Paper Answer 5

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    Max Marks:36

    KEY SHEET

    Physics :1)   1   2)   3   3)   2   4)   3   5)   3   6)   4   7)   3   8)   2   9)   1   10)   4

    11)   1   12)   1   13)   1   14)   1   15)   1   16)   2   17)   3   18)   4   19)   2   20)   1

    21)   2   22)   2   23)   3   24)   1   25)   3   26)   4   27)   2   28)   3   29)   3   30)   3

    Chemistry :

    31)1   32)3   33)3   34)2   35)2   36)3   37)1   38)1   39)2   40)1

    41)2   42)4   43)1   44)3   45)3   46)1   47)4   48)4   49)2   50)3

    51)1   52)1   53)2   54)3   55)1   56)2   57)3   58)1   59)4   60)2

    Mathematics :

    31)   3   32)   3   33)   1   34)   2   35)   1   36)   4   37)   2   38)   2   39)   2   40)   3

    41)   2   42)   2   43)   2   44)   2   45)   4   46)   3   47)   3   48)   1   49)   2   50)   4

    51)   2   52)   1   53)   1   54)   2   55)   2   56)   1   57)   1   58)   3   59)   1   60)   4

    SOLUTIONS

    PHYSICS:

    1. Conceptual

    2. c

    71 10 LC 

    w = = ;710

    2 f 

     p= ;

    8

    7

    3 102 60

    10l p p

    ´= ´ =

    3. v0 =22 (8.5 0.8)g

    r g   h

    -;  v0 =

    22 (2.5 0.8)gr 

    g   h

    -;   = 17/77

    4.  B

    kT is dimensionless

    [B] = [kT]Also [I] = [AT2]

      [A] = [IT – 2]

    [AB2] = [IK2]5. Process AB and CD are isothermal

    W = nRT f lni

    æ ö÷ç   ÷ç   ÷ç   ÷çè ø

    Dotted lines are isochoric lines as they pass through origin

    f i

    V  is same for both process

    WAB = nRT1

    f lni

    æ ö÷ç   ÷ç   ÷ç   ÷çè ø

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    20.   longest Emin

    for Balmer  longest is for n = 2  3

    for Lyman   longest is for n = 1  2   longest Balmer >  longest Lyman

    21. Conceptual

    22. Force of buoyancy FB = A[x0 + (L – x)w]gWeight W = LA

    sg For equilibrium F

    B= W

    LAsg = A[x

    0+ (L – x)

    w]g   L

    s= x

    0+ (L – x) 

    w

    s=

     x

     L(

    0 –  

    w) + 

     x

     L=

    0

    w s

    w

    r r 

    r r 

    -

    -=

    1000 800

    1000 300

    -

    -=

    2

    7

    23. Least count =1( )main scale

     N ; 0.1 mn =

    1( )

    20

    main scale

    1 Main scale division = 2mm

    24. Since area vector rotates in xy plane, therefore flux is due to by only.

    At any instant   (t) = r2 By

    cos t|E

    ind| = r2 B

    y  sin t

    25. Field will be uniform at the outside and, E =2

    (2 )

    (4 )

    k Q

    a=

    28

    kQ

    a

    26.   4maximum 100 10 0.01 I A A

    gV I G R

    10 0.01 100   R 900 R 

    27.

    The Boolean expression of the given circuit . X A B=

     A B= + (Using De morgan theorem )=A+B (Using Boolean identity)

    This is same as the Boolean expression of OR gate.

    Alternative method

    The truth table of the given circuit is as shown is the table

    A B   A B . A B . X A B=0 0 1 1 1 0

    0 1 1 0 0 1

    1 0 0 1 0 1

    1 1 0 0 0 1

    This is same as that of OR gate .

    28. Conceptual29. Conceptual30. Conceptual

    Chemistry

    31.

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    3

    2 2 2 2

     H 

    CH 

    CH C CH CH CH CH 

    O

    3

    2 2 2 2

     H 

    CH O

    CH C CH CH CH CH  

    |

    |

     

    1

    3

    2 2 2 2

    SN 

    CH O H  

    CH C CH CH C H CH  

    | |

     

    CH3O

    H

    H

    CH2OH

    O

    H H

    CH3

    CH2OH

    -H+

    CH2OH

    CH3

    OH

    32. Conceptual

    33. Conceptual

    34. p – nitrophenol (III) > phenol (I) > p – cresol (II).

    35.22

    2 3 2 3 24 2O

    SiC NaOH Na SiO Na CO H O

    36. Conceptual

    37.

    Cl   THF  Br Mg Cl  Mg Br  ClC

      O M gBr 

    Cl C OH

    O

     H  

    1 mole X

    C

    O

    O

    O

    38. Conceptual

    39. Conceptual

    40. - NO2 is a meta – directing group. As it is also a deactivating group so no chance of 

    introduction of second – Br atom.

    41 2 2 32 6 2 42 2CH O CH CH  

     NaH B H NaB H 

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    42. Conceptual

    43. A is CH3 – CHO, which then undergo aldol condensation to give compound B.

    3 2 3 2

    || |

    .

    | |

     NaOH 

    O OH 

    CH C H CH CHO CH CCH CHO

     H H 

     

    44. Conceptual

    45.1

    1

    100 1

    1 200 4

     X A

     X A= ´

    -1 1

    8 1  A x A x= -

    1 1

    9 A

     x   =

    1 8

    100 2009 9Pm = ´ + ´ = 188.8 Torr46. As same charges are present at nearest position (less stable)

    47.   4 3 3 444CuSO NH Cu NH SO 48.

    1K 2B

    2C2K 

    A Where1

    2

    1

    2

    2 2

    2 0 0

     A B C 

    Finally 0.51

    2 1.53

    0.5 2 0.5 2 0.5 1 2 3.549. Conjugate base is week conjugate acid strong50. Conceptual

    51. Conceptual

    52. 3 cis & 3 trans isomers

    i)

    C C 

    Cl

    3CH 

    H

    3CH ii)

    C C 2

    CH Cl

    H

    3CH 

    H

    iii)

    C C Cl

    H

    2 5C H 

    H

    iv)

    C

    H

    Cl2 3C H 

    3CH 

    C

    H

    Cl

    3CH 

    2 3C H 

    iii

    53. Conceptual

    54. For isobaric process

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    2

    1

    logCPT 

    S nT 

    55.

    2

    0 5

     NaNO HCl

    /

    NH2   2

     N Cl 

    56. Conceptual

    57. Conceptual58. Condensation polymerization

    59. Conceptual

    60. Conceptual

    Mathematics61. R(b c) a bc

    2R sin A bcb c

    sinA2 bc

    Now sin A 1b c

    12 bc

    2

    b c 0 b c sin A 1 0

    A 90 and b = cHence, triangle is right isosceles62. Since and are unit vectors and equally inclined to each other.

    is are equilateral triangle and

    Area of the base

    If is the centroid of the then is a right angled triangle and

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    Volume of the tetrahedron

    63. Let be the required angle, then

    64. Let be the of the line of the common perpendicular (or SD) to the

    two given lines. Then, we have and

    solving, these, we get or

    of SD are

    Also, is a point on first line and is a point on second line, then

    and two lines are said to be skew lines or nonintersecting lines if they do not lie in the same plane.

    65.

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    66.

    1 2 3

    10 3 2 4

    4s s s

    No. of non negative integral solutions of  1 2 3 4s s s is  3 1 24 3 1 6c c

    67. A-event that sum 5 occurs, B-sum 7 occurs

    ,probability that neither a sum 5 or 7 occur

    68. Probability of equal number of W and L is

    69.

     f x kx c

    0 1 1 f c ' 1 f x k 

    1 f x x

    1 1 1

    2 2 2

    1 1 0

    1 1 12

    1 1 1 2

     xdx dx dx

     x x x

    π

    70.  

    2

    2

    2 2 2 2 2 2

    1 1 1 1 1 1 1 1 1

    1 1 1 1 1 5

    1 1 1

    α β α β α β α β α β

    α β α β α β

    71. Let equation of variable circles is   2 2

    1 1 2 3 0 x y x yλ equation of common

    chord of variable circle and given circle is

    1 0 2 3 1 6 0S S x y xλ common chords always pass though point of 

    intersection of 1 – 6x = 0 & x + 2y – 3 = 0.

    72. Let the numbers be 1,2,3,4,....., n and the erased number be x then 1   x n

    Now,

    172 35

    1 17

    n n x

    n

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    1 11

    72 2351 17 1

    7 235

    2 17 2

    7 2352 17 2

    1470 2

    17

    69 70

    n n n nn

    n n

    n n

    n n

    n n

    n or 

    at n = 69 ;

    69 x 7072 35 7

    68 17

     x

     x

    at n = 70 ;   x I 73. We have to de- arrange 5 objects to 6 places

    No. of ways =   44 44 4 9 9 3 2 2 2 1 1 = 256

    74. Let   2 2

    x be the point on ellipse 1

    9 4

     yP   θ  

    Equation of Tangent,cos sin

    13 2

     x yθ θ --------- (1)

    at  2 1 cos 2 1 cos

    3 3,sin sin

     x y T θ θ

    θ θ

    at   12 1 cos 2 1 cos3 3,sin sin x y T θ θ

    θ θ

    1T 

    P   θT 

    3 x

    3 x Circle with 1TT  as diameter,   2 2 1 2 1 2 1 2 1 2 0 x y x x K y y y x x y y

    2 2 5 0 x y yλ

    It passes through  5, 075. Let   201 20 . 2

      r r a b

    r r T C x y kx y  

    20 1 11 20 . 2  ss a b

    S sT C x y kx y

     

    For given condition r – s=1

    and1

    120 .2 20 .2 13

    s s

    s sC C S 

       r=14 a=6

    76. a,b,c are in.G.P 2b ac

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    22 0ax bx c can be written as 

    2

    0ax c

    c x

    a It is common root

    Subsitute  c

     x

    a

    in given equation

    77. Let ABCD be the given rectangle

    and EFGH be the required reactangle

    A = area of EFGH

          2 2 2 2sin cos sin cos

    1 1sin2

    2 2

    b a a b

    ab a b ab a b

    θ θ θ θ

    θ

    78.     6

    24 2 5 4 3. 1 . 6 5 4g x x x x x x x dx

    6

    4 5 6 5 4 3. 6 5 4 x x x x x x dx Put 6 5 4t x x x

    76

    7

    t t dt C  

    7

    6 5 4

    7

     x x xC 

    But it passes through (0,0) 0C 

    731

    7g

    79. Draw the graphs,100

     x y  and y = sinx. By using this graph Find the no. of solutions

    80. Let   3 3 1 f x x x

    Then     1 23 1 f x x Let   1 0 1 f x x and f(1) f( – 1) < 0

    81. Conceptual

    82. f(x) is symmetric about y = x

    Required area =   2

    0

    2x   f x x dx

    π

    =   2

    0

    2 sin sin xd x dx

    π π

    π

    =   32 2 2 2 3K 

    83.2

    1

    2

    1

     xdy

    dx y

    Tangent equation is 2 2 3 31 1 1 1 x x y y x y 2 2 3

    1 1 x x y y a

    Since, it passes through   2 2, x y 2 2 31 2 1 2   1 x x y y a

    and   3 3 31 1   2 x y a

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    3 3 32 2   3 x y a

    By solving (1), (2), (3) we get result

    84. :   ( ) ( )cos sin cos sini i ie e i i ea b g a a b b+ = + + + =

    Let , ,i i ia e b e c ea b g = = = then   a b c+ = . Also 1 1 1a b c

    + = .

    2ab cÞ =   ( ) ( )2i ie ea b g +Þ =   ( )sin sin 2a b g Þ + = .

    85. The given expression is the coefficient of x4

    in

    4C0 (1 + x)

    404 – 

    4C1 (1 + x)

    303+

    4C2 (1 + x)

    202 – 

    4C3 (1 + x)

    101+

    4C4

    i.e. in [(1 + x)101

     – 1]4

    i.e. in (101

    C1x +101

    C2 x2

    + ….. +101

    C101 x101

    )4

    = (101)4

    option (B) is correct.

    86.   ( ){ }2 2, : 4 3 0, , R x y x xy y x y N = - + = ÎLet   x N Î , 2 24. . 3 0 x x x x- + =

    ( ), x x R\ Î   \ R is reflexive .

    we have   ( ) ( )() ()2 2

    3 4 3 1 3 1 9 12 3 0- + = - + = or   ( )3,1   RÎ

    Also   ( )( ) ( )221 4 1 3 3 3 1 12 27 0- + = - + ¹ .

    ( )1,3   R\ Ï ,   R\ is not symmetric.

    Again   ( )9,3   RÎ because

    ( )( ) ( )229 4 9 3 3 3 108 108 0- + = - = .

    and   ( )3,1   RÎ because   ( ) ( )() ()2 2

    3 4 3 1 3 1 12 12 0- + = - =

    and   ( )9,1   RÎ if    ( )( ) ( )22

    9 4 9 1 3 1 0- + =

    if 84-36=0 which is not possible.

    ( )( )9, 3 , 3,1   R\ Î and   ( )9,1   RÏ   R is not transitive\ .

    \ Relation R is reflexive but neither symmetric nor transitive.87. As lines are perpendicular to each other ‘C’ moves on a circle with AB as diameter.

    Now P, mid-point of AB (which is fixed) when joined with C is median.

    Centroid is moving at a constant distance   1

    PA3

    from P.

    Locus is a circle

    A is point of intersection of x + 4y + 2 = 0 and x – y + 1 = 0 i.e.,6 1

    ,5 5

    B is point of intersection of 4x – y + 6 = 0 and x + y + 3 = 0 i.e.,9 6

    ,5 5

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    3 7P ,

    2 10

    therefore locus is2 2

    3 7 17x y

    2 10 50

    88.Let n be even ,    f x   as   x  .

    Let 3 2C i be the centre of the circle 3 2 4 z i . Join the origin to C and let it meet the circlein A and B ( see figure).

    B

    A

    O

    C

    3

    2

    Least value of   z OB

    CB OC   2 24 3 2

    4 13

    Maximum value of  4 13 z OA

    The absolute difference between the maximum and minimum values of   z is 2 13

    89. The inverse of    p qÞ   : is   p qÞ: the contra positive of    p qÞ: is   q pÞ: .

    [Contra positive of    p qÞ is   q pÞ: : ]90. Give that , mean 21= and median 22= .

    we know, mod 3 2e median mean= - .( ) ( )mod e 3 22 2 21 66 42 24Þ = - = - =