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  • 8/20/2019 Iit Model Paper Answer 9

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    Max Marks:360

    KEY SHEET

    PHYSICS

    1 4 2 2 3 2 4 1 5 2 6 3 7 3

    8 3 9 3 10 3 11 2 12 3 13 3 14 3

    15 3 16 3 17 1 18 4 19 1 20 4 21 2

    22 2 23 4 24 2 25 4 26 1 27 1 28 2

    29 2 30 3

    MATHEMATICS

    31 2 32 1 33 2 34 1 35 1 36 4 37 4

    38 1 39 1 40 3 41 2 42 1 43 3 44 1

    45 1 46 2 47 2 48 3 49 1 50 4 51 4

    52 4 53 1 54 1 55 4 56 2 57 1 58 1

    59 4 60 3

    CHEMISTRY

    61 4 62 4 63 2 64 4 65 3 66 4 67 1

    68 4 69 1 70 3 71 3 72 4 73 3 74 3

    75 2 76 4 77 2 78 4 79 3 80 1 81 2

    82 1 83 1 84 4 85 1 86 4 87 4 88 2

    89 3 90 2

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    HINTS &SOLUTIONS

    PHYSICS

    12

    0 0 0

    0

    1 2

    2

     I  I E C or E 

    C ε

    ε

    0 12 8

    2 4

    8.8 10 3 10 E 

    155.5 NC 2 Conceptual

    3 from input signals , we have

    A B OUTPUT nand

    GATE

    0 0 1

    1 0 1

    0 0 1

    1 1 0

    0 0 1

    The output signal is shown at (b)

    4

    A B Y1Y  2Y  Y

    0 0 1 1 1 0

    0 1 1 1 0 1

    1 0 1 0 1 11 1 0 1 1 0

    5

    61 1.5

    4

    t and drift t km

    62

    050cos37  v

     R

    2

    40 ; 20 /  10

    vv m s

    7 conceptual

    8

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    9   30 20 5di di

    l i t vedt dt  

    30 30 2sec; 1di

     L at t i ampdt 

    10 Basic concept of phasor

    11 This error occur in all the instruments which utilizes screw or nut-bolt system

    12 L.C of vernier =M.S.D – V.S.D

    45 4.9 10 0.01m mm L.C. of screw gauge =0.01mm

    13

    Let slope of line AC is 1 &m that of line DB is 2m , then

    2 21 2

    1 1

    ln 2 lnm mnRT nRT  m m

    1

    2

    2T 

    14 The temperature of these objects being identical the cooling rate will depend upon surface area. The

    circular pate has the largest area and hence will cool faster than cube and sphere, Sphere having less

    surface area than a cube will cool at the lower rate

    152

    4 4 0.052 ; 10

    2 10

    S  R cm P Pa

     R 

    16

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    0 3

    tan378 4

    6r m

    20F P h g r  ρ π

    510 10 8000 10 36π 5 71.8 36 10 2 10π

    17 since it is a conductor

    0V  = potential at surface=0

    0 0

    04 4 2

    q Q

    a aπε πε

    2

    Qq

    18  A at surface B C OV V V V V  

    Charge is on the outer surface hence insideV  remains constant

    19 The potential at centre of sphere in which q charge is uniformly distributed throughout the volume is

    0

    1 3

    4 2C 

    qV 

     Rπε

    By symmetry the potential at centre due to half sphere will be half of the complete sphere

    0

    1 3 / 2

    4 2C 

    qV 

     Rπε

    0

    1 3

    4 2 2

    Q qQ

     Rπε

    20 1 2 12

    1 2

    ;

    2

    v v v A A v

    v v

    energy reflected

    1

    9energy incident 

    21

    36 / 1.2

    30

    m sl m

    0.3m

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    22 Conservation of angular momentum2 2 2

    0 '2 2 3

    i f 

    mR mR ml L L   ω ω

     

    2

    0

    2 2

    3'

    3 2

     R

     R l

    ωω

    23 1 2 2 1 2(1 cos )cos 2 cos 2 cos 2 cos 2 E a f t f t a f t a f t f t π π π π π

    2 1 2 1 21 1

    cos 2 cos 2 cos 22 2

     E a f t a f f t a f f t π π π

    This is a complex vibration consists of harmonic vibrations of frequencies   2 1 2 1 2, f f f and f f 

    The highest is   1 2 max. f f So hv T φ

    max 1 2T h f f    φ

    34

    15 15

    19

    6.6 103.6 10 1.2 10 2.35

    1.6 10

    17.45ev

    24 Apply conservation of momentum & energy

    25 Let total sum of number of isotopes at the formation of the planet was 0 N  and currently is N

    0 1 0.22

     X 

     N  N e N 

    λ

    ….(i)

    20 0.82

     y

     N  N e N 

    λ

    …..(ii)

    Dividing equation (ii) by (i) 1 2 4

    t e

      λ λ

    1 2ln 4t λ λ

    9

    ln 2 1 12ln2

    10 2 4t 

    98 10t  years26

    At P,  8 3

    ,d d 

     x D

    For 2nd

    maxim,224

    2 2d 

     x D

    λ λ

    27 0 0 0

    2 2 2

     I I I  B i j k 

     R R R

    µ µ µ

    0 32

     I  B

     R

    µ

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    28 In steady state the capacitor is fully charges and is treated as open circuit, so no current flows

    through branch containing capacitor in steady state, So, the circuit can be redrawn as

    Potential difference across capacitor in steady state

    6 6V V V  (-ve sign signifies that left hand plate is of negative polarity )

    Charge 1 6 6CV C µ

    29 In steady state current through capacitor is zero. For zero deflection  A BV V 

    So, 11

    q IR

    And 1 22

    2 2 1

    q R C  IR

    C R C 

    30   4

    3 2

    02

    4

    T    xU x x dx x Since there is no loss energy , so

    42 2

    1

    13

    4 2

     x x E mv

    4 24 12 0 x x

    2 4 16 48

    2 x

     

    4 8

    6, 22

    2 x

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    MATHEMATICS31 As z,iz 1 are collinear

    1 1

    0 1

    1 1 1 1 1 1

     z z z z

    iz iz i z z i

    [taking – I common from 2 R ]

    1 1 1

    0

    0 0 1

     z z

     z i z i i

    [Using 1 1 3 2 3C C C and C C   ]

    1 1 0 z z i z i z

    0 z z z iz i z z i z z i

    2 1 1 0 z z i z i z

    1 10

    2 2

    i i z z z z

    1 1

    2 21

    i z

     

    Thus , z lies on a circle

    32

    As 1 2 3 , z z z circum centre of    ABC  is 0s z   .Also, centriod of    ABC  is 0s z   . Also

    centroid of    1 2 31

    3G ABCis z z z z . If   H  z denotes the orthocentres of    ABC  , then

    1

    23

    G H S  z z z

    1 2 31 1

    2 03 3

      H  z z z z

    1 2 3 H  z z z z

    33 Let common root be  α , then2 2

    3 1 0 2 1 0 p and qα α α α Multiply the second expression by 3/2 and subtract from the first to obtain

    3 1 1

    2 2 2 3 p q

     p qα α

    Thus,   2

    3 2 3 2 3 0 p p q p q

    34 2 12n n na a a

     / 20

    2cos 2 4 cos 2 cos 2 2

    1 cos 2

    n x nx n xdx

     x

    π  

     / 2

    0

    2 cos 2 2 0n x dxπ

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    35 30 4 27C  

    36 conceptual

    37 We have

    5 0 0 1 0 0

    0 1 0 0 1 00 10 2 5 0 0 1

     x

     AB x x

    1/ 5 x

    38

    1

    1 0

    1

    a a

    b b

    c c

    Applying 2 2 1 3 3 1C C C and C C C  

    And expand to obtain

    1 1 1 1 1 1 0a b c b a c a b

    Divide by  1 1 1a b c

    39 Two tallest boy can be different groups in  2 2 11 1n nC C  ways

    40 , 22

    α γ α γ δ β α δ γ β γ δ

     

    413

    2

    04 13 | sin3

     xt at t x

     x

    212 39 3sin /   x x a x

    212 39 3sin

     a x x

     x

    2

    6 3 sin 1a

     x x

    sin 1, 66

    a x

    42 From 2sin sin 1, x x we get 2sin cos x x . Now, the given expression is equal to

    6 6 4 2cos cos 3cos 3cos 1 1 x x x x

    3

    6 2cos cos 1 1 x x

    33

    sin sin 1 1 x x

    3

    2sin sin 1 1 1 0 x x

    43 We have 1 1 sin2S x   β 2 1 2 cos2S x x   β 3 1 2 3 cosS x x x   β 4 1 2 3 4 sinS x x x x   β

    So that4

    1 1 1 3

    1 2 4

    tan tan

    1i

    i

    S S  x

    S S 

    1 sin 2 costan1 cos 2 sin

    β β

    β β

     

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    1cos 2 sin 1

    tansin 2sin 1

    β β

    β β

     

    1 1tan cot tan tan / 2β π β  / 2π β

    44   33 87 y m x

    1 87 33 33 872

    m A mm

    2

    20 0

    dA d A

    dm dm

    45 Perpendicular distance from centre to the line1

    2

    common difference

    11

    2 1 2 22

    2 2 4

    or or  

    46 Common tangent nearer P is x=1

    directrix of ellipse is x=1e=1/2

    1,1

    2s

     

    47 Perpendicular bisector of the base must meet the parabola at the vertex of the triangle.

    48 Let P( a,b,c) be the foot of the perpendicular from the origin to the plane, then direction rations of 

    OP are

    0, 0, 0a b c i.e, a,b,c

    So the equation of the plane passing through P(a,b,c) the direction ratios of the normal to which are

    a,b,c is

    0a x a b y b c z c 2 2 2

    ax by cz a b c

    49 Since   ' 2 cos 0 , f x x for all x R so f is one-to-one. Moreover,

     f x as x and f x as x , hence the range of f is R. Therefore, f is onto aswell

    50 Conceptual

    51   0'9 limh f x h f x

     f xh

    0 0

    0lim lim

    0

    h

    h h

     f x f h f x e g h

    h h

       

    0

    lim 'h hh

    e g h e g h

    ' 0 0 4g g

    Hence   4 10 10 0 f x x c but f g

    So   4 f x x

    52 Conceptual

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    53    

        1/ 1/  

    1 21n n

    n n

     f x   x f o f x

     x f x f x

    Similarly  

    1/ 

    1 3n

    n

     x f o f o f x

     x

    and likewise  

    1/ 

    .....1

    nn

     x f o f o f n times x

    nx

     

    11/ 0

    2

    1/  . 11

    nn

    n n

    nn

     x x g x dx dx Put nx t 

    nx

    We get the above integral as

    111 1

    1

    nnt 

    dt t K  n t n n

     

    111

    11

    n nnx K n n

    54   h x h I  π π

    Where sin 4

     x

     I t dt 

    π

    π

    Put ,t    θ π so that

    4

    0sin

     x

     I d π θ θ

    4

    0sin

     x

    d h xθ θ h x h h xπ π

    55 conceptual

    56

        2 2

    2 ' ' 2 0d 

     f x g x f x f x g x g x f x g x f xdx

    Hence   2 2 f x g x is constant . Thus

    22 2 2 2 216 16 2 2 2 ' 2 16 16 32 f g f g f f 

    57 Let   1/ 

    1  x

     y x

    2 3 41 1

    log log 1 ...2 3 4

     x x x y x x

     x x

    2 3

    1 ..2 3 4

     x x x

    2 2

    1 .. ..2 3 2 3

     x x x xa

     y e ee

    2

    2 211 ..... ..... ....

    2 3 2! 2 3

     x x x xe

    2

    21 1 1 10 0 .....2 3 2 2

     y e ex ex x x

    (0,(x) in terms containing x)

    20

    121 1 112lim3 8 24 x

     y ex

    e e x

    58 Conceptual

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    59 Conceptual

    60 Vertex is (-2,1), length of the latus return =4a where a=1/2 latus rectum is

    parallel to the tangent x+2=0 at the vertex, at a distance ½ from it. So its

    equation is x=-3/2,1+1) and (-3/2, 1-1) i.e (-3/2,2) and (-3/2,0). The point not

    lying on   2 3 0 3/ 2,2 x y is

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    CHEMISTRY

    61

    4 2

    1

     f 

     f 

    T KCl   i KCl

    T X i x i x

    20.5

    4ix

    for association of 3 molecules   1

    1 1i xn

    α

    11 1 0.5

    0.75α

    62 The boyle’s temperature of both 2 H and He is very low.

    63 Along the body diagonal two   B- ions and one   A+ are removed

    64 At high concentration of sulphide ions the cations of both II and IV groups are precipitated.

    65 Follow CIP rules.

    66 2   r n p l =2

    12 nr n p l Þ =

    67 Depends on stability of carbocations

    68 (i) Molecules move faster for which  T 

     M greater. obviously 2 H  molecule move faster.

    69 Cannizzarrows reaction

    70 Rate of reaction depends on leaving ability of the group

    71 Nucleophilic substitution

    72 In the partial hydrolisys of  6 Xe F  different products formed or 4 2 2 Xe O F and Xe O F 

    73 Tollen’s reagent oxidizes aldehyde group only

    74 3 B PH = 2 2 A NaH PO=

    75 Conductivity 6 6 64 2 10 1 10 1 10 BaSO 

    2 24 4

    0 0 0

     BaSO  Ba SOλ λ λ Molar conductivities =

    1 2 160 2 20 100ohm cm mol

    In the case of sparingly soluble salt4

    60 1000 1000 10

    100 BaSO V 

    C C λ λ

    3510

    10 / 100

    C moles litre

    76 1C  epimers are called anomers77 a) basic strength in vapour state depends on +I – effect

    c) +R group increase basic strength at para and decrease the basic strength at meta due to – I.

    d) Lesser the surface volume more the basic strength, hence NH3 is more basic. R – OH > H2O due to

    +I – effect of ‘R’ group

    78 Conceptual

    79 Conceptual

    80 3 B NH = 2C N = 3 2 D Mg N =

    81 Conceptual

    82

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    83 Iodoform reaction84 Teflon, polystyrene and PVC are formed by addition polymerization

    85 Conceptual

    86 Ratio of concentration of reactants and products is same in all three.

    87 0   t Kt C C  = -

    88 Follow the structure of dichromate ion.

    89

    2CH 

    2 H N 

    20

     / 

    0.5.........

     NaNO HCl

    C  

     N N 

    2 N 

    H

    or 

     H 

    90 Sod. Benzoate is metabolized to hippuric acid 6 5 2 .C H CO NH CH COOH