ge energy gas turbine fuel flexibility for · pdf fileigcc + carbon captureavailable today!...

Gas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCCGas Turbine Fuel Flexibility for IGCC

GE EnergyGE EnergyGE EnergyGE Energy

S4FE Sustainable EnergyRome, Italy

July 07, 2009

Marcus H. ScholzKlaus Payrhuber

© Copyright General Electric Company, 2009

OutlineOutlineOutlineOutline

• Gasification Gasification Gasification Gasification –––– a prea prea prea pre----combustion Ccombustion Ccombustion Ccombustion C----separation historyseparation historyseparation historyseparation history

• Fuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel spaceFuel flexibility… a changing fuel space

• High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel ---- IGCC IGCC IGCC IGCC


• High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel High Hydrogen Fuel ---- IGCC IGCC IGCC IGCC

• Advanced technology developmentAdvanced technology developmentAdvanced technology developmentAdvanced technology development

• SummarySummarySummarySummary

• Petroleum Coke• Asphalt• Heavy Oil• Vacuum Residue• Natural Gas

Gasification SolutionsGasification SolutionsGasification SolutionsGasification Solutions

Substitute Natural Gas• SNG

…since > 50 years !


1950 1970 1960 1980 1990 2000 2010

Gas Liquid Solid

Current Operating Gasification Plants: 65Under Construction: 12

Montebello Test Facility Operations

Plants in Progress 120MW IGCCTechnical Demo

Cool Water

250MW IGCCCommercial DemoTECO/Polk Power

1946 2004

Gasification Gasification Gasification Gasification ---- Decades of ExperienceDecades of ExperienceDecades of ExperienceDecades of Experience

Over 3 GW Commercial Feedstock Experience


1,132

760

1,120

Syngas Power Syngas & Power

Over 3 GW GE IGCC

Experience

(MWs)> Natural GasNatural GasNatural GasNatural Gas> Refinery Off GasRefinery Off GasRefinery Off GasRefinery Off Gas

> Crude OilCrude OilCrude OilCrude Oil> Fuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel OilFuel Oil/Heavy Fuel Oil> NaphthaNaphthaNaphthaNaphtha> Vacuum ResidueVacuum ResidueVacuum ResidueVacuum Residue> Asphalt/Deasphalter Asphalt/Deasphalter Asphalt/Deasphalter Asphalt/Deasphalter

ResidueResidueResidueResidue> Visbreaker TarVisbreaker TarVisbreaker TarVisbreaker Tar> Steam Cracked TarSteam Cracked TarSteam Cracked TarSteam Cracked Tar

Liquids

> Range of coalsRange of coalsRange of coalsRange of coals> Petroleum CokePetroleum CokePetroleum CokePetroleum Coke> Coal/Coke BlendsCoal/Coke BlendsCoal/Coke BlendsCoal/Coke Blends

Gas

Solids

Commercial Feedstock Experience

Integrated Gasification Combined CycleIntegrated Gasification Combined CycleIntegrated Gasification Combined CycleIntegrated Gasification Combined Cycle

GasificationGasificationGasificationGasification Syngas Syngas Syngas Syngas cooling & cooling & cooling & cooling & shiftingshiftingshiftingshifting

Syngas Syngas Syngas Syngas CleanCleanCleanClean----

upupupup

CoalCoalCoalCoal

SlagSlagSlagSlag

COCOCOCO2222

SulfurSulfurSulfurSulfur

HgHgHgHg

Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2HeatHeatHeatHeatOOOO2222

IGCCIGCCIGCCIGCC


AirAirAirAirSeparationSeparationSeparationSeparationSystemSystemSystemSystem

Combined Cycle Combined Cycle Combined Cycle Combined Cycle SystemSystemSystemSystem

SlagSlagSlagSlag

AirAirAirAir Air/NAir/NAir/NAir/N2222

Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2Cleaned Syngas / H2HeatHeatHeatHeat

ElectricityElectricityElectricityElectricity

OOOO2222

Five Basic Process Steps Five Basic Process Steps Five Basic Process Steps Five Basic Process Steps –––– all commercial provenall commercial provenall commercial provenall commercial proven

IGCC + COIGCC + COIGCC + COIGCC + CO2222 Separation “Capture” Separation “Capture” Separation “Capture” Separation “Capture”


Produce Produce Produce Produce SyngasSyngasSyngasSyngasGasifierGasifierGasifierGasifier

H2 & COH2 & COH2 & COH2 & CO

Shift SyngasShift SyngasShift SyngasShift SyngasWater gas shift reactorWater gas shift reactorWater gas shift reactorWater gas shift reactor

•Copper or Zinc Oxide Based

CO + H2O > CO2 + H2CO + H2O > CO2 + H2CO + H2O > CO2 + H2CO + H2O > CO2 + H2

Separate CarbonSeparate CarbonSeparate CarbonSeparate CarbonAGR & CO2 AGR & CO2 AGR & CO2 AGR & CO2 CompressionCompressionCompressionCompression

Selexol Refrigeration: >90% Removal

H2 & CO2H2 & CO2H2 & CO2H2 & CO2

Produce PowerProduce PowerProduce PowerProduce PowerDiffusion flame for HDiffusion flame for HDiffusion flame for HDiffusion flame for H2222+ Diluent(N+ Diluent(N+ Diluent(N+ Diluent(N2222, Steam), Steam), Steam), Steam)

H2H2H2H2

Syngas shift & extract carbon photos courtesy of Air Products, Baytown, TX facility.

Owner: Owner: Owner: Owner: Sarlux S.r.lLocation:Location:Location:Location: Cagliari, Sardinia, ItalyStartup: Startup: Startup: Startup: 2001Feedstock: Feedstock: Feedstock: Feedstock: Visbreaker tarDesign Capacity: Design Capacity: Design Capacity: Design Capacity: 1,200 mTPD Operation Pressure:Operation Pressure:Operation Pressure:Operation Pressure: 38 barGasifier Size:Gasifier Size:Gasifier Size:Gasifier Size: 3 x 900 ft³Power: Power: Power: Power: 3 x GE 9E GT’s, 3 x GE STEPC ContractorEPC ContractorEPC ContractorEPC Contractor : Snamprogetti S.p.A.

IGCC IGCC IGCC IGCC – Polygeneration, SarluxPolygeneration, SarluxPolygeneration, SarluxPolygeneration, Sarlux


EPC ContractorEPC ContractorEPC ContractorEPC Contractor : Snamprogetti S.p.A.

GE GE GE GE Gasification Gasification Gasification Gasification & Carbon & Carbon & Carbon & Carbon ExtractionExtractionExtractionExtraction

Gas Gas Gas Gas Cooling &Cooling &Cooling &Cooling &

COS COS COS COS HydrolysisHydrolysisHydrolysisHydrolysis

OxygenOxygenOxygenOxygen

Visbreaker Visbreaker Visbreaker Visbreaker TarTarTarTar

SulfurSulfurSulfurSulfur

Sulphur Sulphur Sulphur Sulphur Removal & Removal & Removal & Removal & RecoveryRecoveryRecoveryRecovery

Steam to RefinerySteam to RefinerySteam to RefinerySteam to Refinery

Power to GridPower to GridPower to GridPower to GridGE GE GE GE

Combined Combined Combined Combined CycleCycleCycleCycle

Hydrogen Hydrogen Hydrogen Hydrogen ProductionProductionProductionProduction

H2 to RefineryH2 to RefineryH2 to RefineryH2 to Refinery

3,600 t/day3,600 t/day3,600 t/day3,600 t/day

551 MW551 MW551 MW551 MW

40,000 Nm3/h40,000 Nm3/h40,000 Nm3/h40,000 Nm3/h

MP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/hMP = 100 t/h; LP =85 t/h

WastewaterWastewaterWastewaterWastewaterPretreatmentPretreatmentPretreatmentPretreatment

Filter CakeFilter CakeFilter CakeFilter Cake

to metals to metals to metals to metals reclaimerreclaimerreclaimerreclaimer

Steam to exportSteam to exportSteam to exportSteam to export

90+% availability (no 90+% availability (no 90+% availability (no 90+% availability (no spare)spare)spare)spare)

Sulfur RemovalSulfur RemovalSulfur RemovalSulfur Removal

Gasifier & SGCGasifier & SGCGasifier & SGCGasifier & SGC

IGCC IGCC IGCC IGCC –––– Power Generation, TECPower Generation, TECPower Generation, TECPower Generation, TEC–––– S107FAS107FAS107FAS107FATampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)IGCC IGCC IGCC IGCC –––– Power Generation, TECPower Generation, TECPower Generation, TECPower Generation, TEC–––– S107FAS107FAS107FAS107FATampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)Tampa, FL (Coal + Petcoke)


Combined CycleCombined CycleCombined CycleCombined Cycle

ASU/Oxygen PlantASU/Oxygen PlantASU/Oxygen PlantASU/Oxygen Plant


Tampa Electric Polk, 1996Tampa Electric Polk, 1996Tampa Electric Polk, 1996Tampa Electric Polk, 1996----PresentPresentPresentPresent• 250 MW net IGCC• GE gasifier/RSC• GE 7FA turbine• GE steam turbine• 12 years of operation


• 12 years of operation�High availability > 85%� Low emissions < 50ppm SO2/SO3

� Low cost electricity – Petcoke/coal blend

Courtesy: Tampa Electric Company

IGCC Reference Plant IGCC Reference Plant IGCC Reference Plant IGCC Reference Plant –––– 207F207F207F207F• Nominal 630MW net plant outputNominal 630MW net plant outputNominal 630MW net plant outputNominal 630MW net plant output• 207F gas turbine combined cycle207F gas turbine combined cycle207F gas turbine combined cycle207F gas turbine combined cycle• Base load/load following operationBase load/load following operationBase load/load following operationBase load/load following operation• Turndown to ~50% loadTurndown to ~50% loadTurndown to ~50% loadTurndown to ~50% load• Fuel flexibilityFuel flexibilityFuel flexibilityFuel flexibility

> Wide range of bituminous Wide range of bituminous Wide range of bituminous Wide range of bituminous coalscoalscoalscoals

> Coal/pet coke blendsCoal/pet coke blendsCoal/pet coke blendsCoal/pet coke blends

• 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine 15 ppm NOx Gas Turbine • Natural gas or distillate backup Natural gas or distillate backup Natural gas or distillate backup Natural gas or distillate backup

fuelfuelfuelfuel• Full plant performance guaranteesFull plant performance guaranteesFull plant performance guaranteesFull plant performance guarantees• Configuration optimized forConfiguration optimized forConfiguration optimized forConfiguration optimized for

– COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex COE, RAM, Perf, & Capex • Allows for future COAllows for future COAllows for future COAllows for future CO2222 capture capture capture capture

blockblockblockblock


> Coal/pet coke blendsCoal/pet coke blendsCoal/pet coke blendsCoal/pet coke blends blockblockblockblock

GE IGCC plant under ConstructionGE IGCC plant under ConstructionGE IGCC plant under ConstructionGE IGCC plant under Construction630MWnet IGCC Plant 630MWnet IGCC Plant 630MWnet IGCC Plant 630MWnet IGCC Plant ---- Duke Energy Duke Energy Duke Energy Duke Energy • Indiana 5 coal - Edwardsport• NTP in 2008, COD in 2012• Detailed engineering completed 2009• Construction on-track • RSC arrived on site in June 2009• 7F Syngas turbines ship in 2010


• 7F Syngas turbines ship in 2010• Successful siting & permittingSuccessful siting & permittingSuccessful siting & permittingSuccessful siting & permitting 2008200820082008

“ We have an opportunity to make history with the Edwardsport plant. The facility could very well be one of the cleanest coal-fired power plants in the

world. It will produce nearly 10 times as much energy as the existing Edwardsport plant with much less environmental impact.” - Jim Turner,

President & COO, U.S. Franchised Electric and Gas-Duke Energy Duke Energy press release, Jan. 25, 2008

Duke Energy Duke Energy Duke Energy Duke Energy Edwardsport site construction, January 2009Edwardsport site construction, January 2009Edwardsport site construction, January 2009Edwardsport site construction, January 2009

IGCC MilestonesIGCC MilestonesIGCC MilestonesIGCC MilestonesPilotPilotPilotPilot

(1984-89)

CommercialCommercialCommercialCommercial(1996 – Present)

LargeLargeLargeLargeCommercialCommercialCommercialCommercial(2012 - tomorrow)


Coolwater• 120 MW IGCC

• 7E Gas Turbine

• N/A time to maturity

TEC• 250 MW IGCC

• 7FA Gas Turbine

• 5 yr time to maturity

Duke Edwardsport• 630 MW IGCC

• 7FB Gas Turbine

• 1 yr time to maturity

Increasing demand for fuel flexibilityIncreasing demand for fuel flexibilityIncreasing demand for fuel flexibilityIncreasing demand for fuel flexibility

Segment conditionsSegment conditionsSegment conditionsSegment conditions• Nat Gas Fuel diversification

• Price volatility

• Emission regulations / constraints

• Carbon Capture provisions50

60

70

80

90

100

110

Mod

Wob

be In

dex@

70F

C5H12

C4H10

H2CH4

C3H8

C2H6

NG50

60

70

80

90

100

110

Mod

Wob

be In

dex@

70F

C5H12

C4H10

H2CH4

C3H8

C2H6

NG

LNG Field LNG Field LNG Field LNG Field (High C(High C(High C(High C2222))))

RefineryRefineryRefineryRefineryLNG FieldLNG FieldLNG FieldLNG Field

NG/LNG Wide NG/LNG Wide NG/LNG Wide NG/LNG Wide WobbeWobbeWobbeWobbe

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

33 33


Source: GE

• Carbon Capture provisions

GE responseGE responseGE responseGE response• 50+ years of experience in

non-traditional fuels• Extending low emissions

technology• Investing in technology for fuel

flexibility

0

10

20

30

40

50

0 5 10 15 20 25 30 35 40 45 50 55

Fuel Lower Heating Value, BTU/lb/1000

Mod

Wob

be In

dex@

70F

CO

NG

0

10

20

30

40

50

0 5 10 15 20 25 30 35 40 45 50 55

Fuel Lower Heating Value, BTU/lb/1000

Mod

Wob

be In

dex@

70F

CO

NGHigh H2High H2High H2High H2

RefineryRefineryRefineryRefineryOffgasOffgasOffgasOffgasLNG FieldLNG FieldLNG FieldLNG Field

(High Inert)(High Inert)(High Inert)(High Inert)

BFG/COGBFG/COGBFG/COGBFG/COG

O2 Blown SyngasO2 Blown SyngasO2 Blown SyngasO2 Blown Syngas

Air Blown SyngasAir Blown SyngasAir Blown SyngasAir Blown Syngas

0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110 0 10 20 30 40 50 60 70 80 90 100 110

Fuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kgFuel Lower Heating Value, MJ/kg

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

Wob

be In

dex,

MJ/

Nm

GE fuel flexibility experienceGE fuel flexibility experienceGE fuel flexibility experienceGE fuel flexibility experience

Natural Gas

NGL

Marine

Propane

LPG

LNG

Kerosene

Naphtha

Perc

ent H

ydro

gen,

(by

mas

s)Pe

rcen

t Hyd

roge

n, (b

y m

ass)

Perc

ent H

ydro

gen,

(by

mas

s)Pe

rcen

t Hyd

roge

n, (b

y m

ass)

Hydrogen (to 95%)


Residual

RefineryGas

Butane

Ethanol

Marine Fuels

Heavy Gas Oil

Kerosene

Crude

Distillate

Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)Specific Energy, (Btu/lb)

Perc

ent H

ydro

gen,

(by

mas

s)Pe

rcen

t Hyd

roge

n, (b

y m

ass)

Perc

ent H

ydro

gen,

(by

mas

s)Pe

rcen

t Hyd

roge

n, (b

y m

ass)

Methanol

Weak Natural

Gas

Coke Oven gas

IGCC

GE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsGE Syngas Gas Turbine ApplicationsPlant Type COD MW

Power

Block Application Integration Gasifier Fuel

Coal IGCC ExperienceCoolwater IGCC 1984 120 107E Power Steam GE Coal

SUV Vresova IGCC 1996 350 209E Cogen Steam ZVU Coal

SVZ IGCC 1996 70 6B Cogen/ MeOH Steam GSP Coal

Wabash IGCC 1996 250 107FA Power Steam E-Gas Coal/Pet Coke

Tampa Polk IGCC 1996 250 107FA Power Steam/N2 GE Coal

Refinery IGCC ExperienceFrontier Refinery 1996 40 6B Cogen Steam/Air/N2 GE Pet Coke

Shell Pernis Refinery 1997 120 206B Cogen/H2 Steam Shell Oil

Sarlux Refinery 2000 550 3x109E Cogen Steam GE vis breaker tar


Sarlux Refinery 2000 550 3x109E Cogen Steam GE vis breaker tar

Motiva Refinery 2000 180 2- 6FA Cogen Steam/N2 GE Pet Coke

Exxon Singapore Refinery 2000 173 2- 6FA Cogen Steam GE Oil

Nexen/Opti Refinery 2008 160 2- 7EA Cogen Steam Shell Asphaltene

Fujian JV Refinery 2009 253 2- 9E Cogen N2 Shell Oil

Steel ExperienceILVA ISE Steel 1996 520 3x109E Cogen None Steel Mill BFG/COG/LDG

Piombino Edison Steel 2001 180 1x109E Cogen None Steel Mill BFG/COG/LDG

Tonghua Steel 2003 50 6B Cogen None Steel Mill BFG/COG

Jinan Steel 2004 100 6B Power None Steel Mill BFG/COG

Baosteel Luojing Steel 2008 174 1x109E Cogen None Steel Mill COREX

Enhanced Enhanced Enhanced Enhanced Increased Area Increased Area Increased Area Increased Area

S1NS1NS1NS1N

9F Syngas Features9F Syngas Features9F Syngas Features9F Syngas Features

Mark VIe Mark VIe Mark VIe Mark VIe Control Control Control Control SystemSystemSystemSystem

Combustion System: Combustion System: Combustion System: Combustion System: Proven IGCC MNQCProven IGCC MNQCProven IGCC MNQCProven IGCC MNQC

Axial

Exhaust

9FA+e HGP9FA+e HGP9FA+e HGP9FA+e HGP


Cold

End

Drive

FA+e Aero compressor bladingFA+e Aero compressor bladingFA+e Aero compressor bladingFA+e Aero compressor bladingFB Wheels for Compressor & FB Wheels for Compressor & FB Wheels for Compressor & FB Wheels for Compressor &

TurbineTurbineTurbineTurbine

Leveraging “F” Product Line Experience & Technology Advancements of H

Cleaner Energy

Objective Approach Capability

IGCCwithCarbon Capture

• High-H2 GT fleet• Successful

operation• Diffusion flame• Diluent for NOx

TodayTodayTodayToday

IGCC & CCS Combustion LandscapeIGCC & CCS Combustion LandscapeIGCC & CCS Combustion LandscapeIGCC & CCS Combustion Landscape


Energy fromCoal

Capture

AdvancedSeparation

& GasificationTechnology

• Diluent for NOx

• Advanced pre-mix combustion

• Membranes --O2, CO2, H2

• DOE program

Future

Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE Conceptual FutureGen plant courtesy US DOE

Syngas turbines Syngas turbines Syngas turbines Syngas turbines –––– MNQC CombustorMNQC CombustorMNQC CombustorMNQC Combustor

N2/Steam

Syngas

Air Extraction

Air from Compressor

Fuel Nozzle

• Same combustor architecture Same combustor architecture Same combustor architecture Same combustor architecture for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas for 6FA, 7EA, 9E, 7/9F Syngas turbinesturbinesturbinesturbines

• End cover/fuel nozzle End cover/fuel nozzle End cover/fuel nozzle End cover/fuel nozzle assembly identical, assembly identical, assembly identical, assembly identical,


Natural Gas/ Syngas To

Turbine Nozzles

Compressor

Liner

Flow Sleeve Transition Piece

assembly identical, assembly identical, assembly identical, assembly identical, except for minor scalingexcept for minor scalingexcept for minor scalingexcept for minor scaling

• Combustor liner and cap Combustor liner and cap Combustor liner and cap Combustor liner and cap designs similar, scaled to designs similar, scaled to designs similar, scaled to designs similar, scaled to different operating conditionsdifferent operating conditionsdifferent operating conditionsdifferent operating conditions

300

400

500

600

700

800

BT

U/s

cf

of

Fu

el

Process

Gases

IGCC

Gases300

400

500

600

700

800

BT

U/s

cf

of

Fu

el

Process

Gases

IGCC

Gases

Hydrogen Fuel ExperienceHydrogen Fuel ExperienceHydrogen Fuel ExperienceHydrogen Fuel Experience

Video capture of flame Video capture of flame Video capture of flame Video capture of flame structure structure structure structure ---- 85858585----90% H90% H90% H90% H2222


0

100

200

300

0 10 20 30 40 50 60 70 80 90 100

Percent Hydrogen

BT

U/ Gases

MNQC H2

Testing0

100

200

300

0 10 20 30 40 50 60 70 80 90 100

Percent Hydrogen

BT

U/ Gases

MNQC H2

Testing

GE High HGE High HGE High HGE High H2222 GT Commercial ExperienceGT Commercial ExperienceGT Commercial ExperienceGT Commercial Experience

• 6B 95% H2 (Daeson)• 6FA 44.5% H2 (Exxon,

Motiva)• 7FA 37.2% H2 (Tampa, PSI)

Customer/ Site GT Model No. Gas Features1 ExxonMobil Singapore MS6241FA 2 IGCC 44.5% H2

2 Georgia Gulf MS7001EA 3 Blend Methane+50% H2

3 SUV Vresova MS9001E 2 IGCC 46.8% H2

4 BASF/ Geismer MS6001B 1 PG Up to 80% H2

5 Koch Refinery MS6001B 1 RFG 12% to 50% H2

6 Daeson Korea MS6001B 1 PG up to 95% H2

7 Shell Int'l MS5001P 1 RFG 60% H2, propane

8 Reutgerswerke MS3002J 1 PG 60% H2

9 Tenerife MS6001B 1 RFG ~70% H2

10 Cartagena MS6000B 1 RFG 66% H2

11 San Roque MS6000B 2 RFG 70% H2

12 Antwerpen MS6000B 1 RFG 78% H2


12 Antwerpen MS6000B 1 RFG 78% H2

13 Puertollano MS6000B 2 RFG Up to 60% H2

14 La Coruna MS6000B 1 RFG Up to 52% H2

15 Rotterdam MS6000B 1 RFG 59% H2

16 AGIP/ Milazzo MS5001P 1 RFG 30% to 50% H2

17 Cochin Refineries MS5001P 1 RFG 50% H2

18 Mobil/ Paulsboro MS5001P 2 RFG 20% to 60% H2

19 Uhde NUP MS3002J 1 TG ~60% H2

20 Donges GE10 1 RFG 76% H221 Zarqa Refinery PGT10 1 RFG 82% H2

IGCC=Syngas; RFG=Refinery Gas; PG=Process Gas; TG=Tail GasF-class H2 Combustion Validation … Video Capture of Flame Structure 85-90% H2

FFFF----Class Hydrogen ExperienceClass Hydrogen ExperienceClass Hydrogen ExperienceClass Hydrogen Experience


IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!IGCC + Carbon Capture…available today!

COCOCOCO2222SSSSHgHgHgHg

Water Gas ShiftWater Gas ShiftWater Gas ShiftWater Gas ShiftCO+HCO+HCO+HCO+H2222O O O O ----> CO> CO> CO> CO2222+H+H+H+H2222

Power

Oxygen,Oxygen,Oxygen,Oxygen,FeedstockFeedstockFeedstockFeedstock

Process Gas OnlyProcess Gas OnlyProcess Gas OnlyProcess Gas OnlyHigh P, Low VolumeHigh P, Low VolumeHigh P, Low VolumeHigh P, Low VolumeHigh Driving ForceHigh Driving ForceHigh Driving ForceHigh Driving Force

SlagSlagSlagSlag

AGR / SRU

Diffusion Diffusion Diffusion Diffusion CombustorCombustorCombustorCombustorDiluent NOx Diluent NOx Diluent NOx Diluent NOx

ControlControlControlControl

Proven Turbine Proven Turbine Proven Turbine Proven Turbine Proven Proven Proven Proven

HHHH2222Gasification CO Shift

Proven Process Proven Process Proven Process Proven Process TechnologyTechnologyTechnologyTechnology

Proven Turbine Proven Turbine Proven Turbine Proven Turbine HHHH2222 CapabilityCapabilityCapabilityCapability

Proven Proven Proven Proven GasificationGasificationGasificationGasification

• 25 GE gas turbines 25 GE gas turbines 25 GE gas turbines 25 GE gas turbines operating at 50%+ Hoperating at 50%+ Hoperating at 50%+ Hoperating at 50%+ H2222

• FFFF----class combustion class combustion class combustion class combustion validation up to validation up to validation up to validation up to 90% H90% H90% H90% H2222

• 65 GE gasifier 65 GE gasifier 65 GE gasifier 65 GE gasifier commercially commercially commercially commercially operating operating operating operating worldwideworldwideworldwideworldwide

• 26 GE gasifier 26 GE gasifier 26 GE gasifier 26 GE gasifier commercially commercially commercially commercially operating using operating using operating using operating using shift reaction to shift reaction to shift reaction to shift reaction to produce Hproduce Hproduce Hproduce H2222

• 33 GE gasifier 33 GE gasifier 33 GE gasifier 33 GE gasifier plants commerplants commerplants commerplants commer----cially operating cially operating cially operating cially operating using AGR techusing AGR techusing AGR techusing AGR tech----nology to remove nology to remove nology to remove nology to remove COCOCOCO2 2 2 2 from shifted from shifted from shifted from shifted syngassyngassyngassyngas

Technology development for future high H2 turbines

Source: US Department of Energy

Objective

GE PG7321FBGE PG7321FBGE PG7321FBGE PG7321FB----H2H2H2H2

Cleaner energy

Approach Capability

IGCCwithCarbon capture

• High-H2 GT fleet• Successful

operation• Diffusion flame• Diluent for NOx

Today

IGCC & CCS combustion landscapeIGCC & CCS combustion landscapeIGCC & CCS combustion landscapeIGCC & CCS combustion landscape


energy fromcoal Advanced

Separation & Gasification

Technology

• Advanced pre-mix combustion

• Membranes --O2, CO2, H2

• DOE program

FuturePrePrePrePre----mix combustionmix combustionmix combustionmix combustion

GE’s DOE HGE’s DOE HGE’s DOE HGE’s DOE H2222/IGCC turbines program/IGCC turbines program/IGCC turbines program/IGCC turbines program

• Advanced combustion development� Flame imaging� Alternate nozzle concepts

• Full scale, multi-nozzle testing

• Technology advancement for future gas turbines:IGCC - syngas fuelIGCC with carbon capture - H2 fuel

• Objectives:Lower NOxHigher efficiencyLower capital cost


• Full scale, multi-nozzle testing

Oxygen

• Switch from Nat Gas Switch from Nat Gas Switch from Nat Gas Switch from Nat Gas to Coals & Petcoketo Coals & Petcoketo Coals & Petcoketo Coals & Petcoke

• Reduce Industry Reduce Industry Reduce Industry Reduce Industry dependency from dependency from dependency from dependency from Nat GasNat GasNat GasNat Gas

Future CO2 CaptureCombined Cycle Power Block – 209FB

Create integrated Create integrated Create integrated Create integrated Refinery solutionsRefinery solutionsRefinery solutionsRefinery solutions- Hydrogen- Fischer Tropsch Liquids- Methanol- Carbon Monoxide- Higher Alcohols

Phased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementationPhased NGCC IGCC CCS implementation


Sulfur

SulfurRemoval

SyngasSyngasSyngasSyngas

Slag

GasifierGasifierGasifierGasifier

MarketableByproducts

Mercury & Sulfur Removal

Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as Build Nat Gas fired Combined Cycle as –––– ‘IGCC ready’‘IGCC ready’‘IGCC ready’‘IGCC ready’

• Fuel flexibility Fuel flexibility Fuel flexibility Fuel flexibility – lower cost fuels than lower cost fuels than lower cost fuels than lower cost fuels than natural gas natural gas natural gas natural gas – will gain importance will gain importance will gain importance will gain importance

• Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support Syngas and Hydrogen fuels will support a low Carbon economya low Carbon economya low Carbon economya low Carbon economy

• Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery Low cost feed stocks (coals, refinery residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low

Fuel space of the futureFuel space of the futureFuel space of the futureFuel space of the future

residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low residue) will continue to challenge low emission conversion emission conversion emission conversion emission conversion

• IGCC can leverage lower overall IGCC can leverage lower overall IGCC can leverage lower overall IGCC can leverage lower overall emission footprint than conventional emission footprint than conventional emission footprint than conventional emission footprint than conventional combustion (PM, Hg, S, COcombustion (PM, Hg, S, COcombustion (PM, Hg, S, COcombustion (PM, Hg, S, CO2222, ash/slag), ash/slag), ash/slag), ash/slag)

• Technology is commercially proven at Technology is commercially proven at Technology is commercially proven at Technology is commercially proven at scalescalescalescale…including COincluding COincluding COincluding CO2222 capturecapturecapturecapture

ge energy gas turbine fuel flexibility for · pdf fileigcc + carbon captureavailable today!...

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