facile synthesis of substituted alkynes by cyclopalladated ferrocenylimine catalyzed cross-coupling...

1
2007 Polyphenylalkyne derivatives Q 0750 Facile Synthesis of Substituted Alkynes by Cyclopalladated Ferrocenylimine Catalyzed Cross-Coupling of Arylboronic Acids/Esters with Terminal Alkynes. — FPC is an efficient catalyst at low loading in the presence of Ag2O as additive. The method is successfully applied to electron-poor alkynes, for which the traditional Sonogashira reaction does not proceed. — (YANG, F.; WU*, Y.; Eur. J. Org. Chem. 2007, 21, 3476-3479; Dep. Chem., Zhengzhou Univ., Zhengzhou 450052, Henan, Peop. Rep. China; Eng.) — Klein 45- 091

Upload: fan-yang

Post on 11-Jun-2016

215 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: Facile Synthesis of Substituted Alkynes by Cyclopalladated Ferrocenylimine Catalyzed Cross-Coupling of Arylboronic Acids/Esters with Terminal Alkynes

2007

Polyphenylalkyne derivativesQ 0750 Facile Synthesis of Substituted Alkynes by Cyclopalladated Ferrocenylimine

Catalyzed Cross-Coupling of Arylboronic Acids/Esters with Terminal Alkynes. — FPC is an efficient catalyst at low loading in the presence of Ag2O as additive. The method is successfully applied to electron-poor alkynes, for which the traditional Sonogashira reaction does not proceed. — (YANG, F.; WU*, Y.; Eur. J. Org. Chem. 2007, 21, 3476-3479; Dep. Chem., Zhengzhou Univ., Zhengzhou 450052, Henan, Peop. Rep. China; Eng.) — Klein

45- 091