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Environmental Laboratory Sampling and Analysis Guide

Environmental Laboratory Section

Public Health Laboratory Division

Minnesota Department of Health

601 Robert Street North PO Box 64899

Saint Paul, MN 55164-0899 (651) 201-5300

http://www.health.state.mn.us/divs/phl/environmental/index.html

http://www.health.state.mn.us/divs/phl/environmental/index.html

Environmental Lab Handbook Environmental Laboratory Rev. 3, revised, October 30, 2017 601 Robert Street N. of 70 St. Paul, MN 55164 651-201-5300

TABLE OF CONTENTS

Page #

Table of Contents 2

Contact Information 3

Method Guide by Analytical Area 4-19

1) Organic Chemistry 4-5 2) Inorganic Chemistry 6-18

a) Radiochemistry 6 b) Wet Chemistry 7-9 c) Microbiology 10 d) Metals 11-18

Additional Analyses 19

Method Guide by Analyte 20-53


a) Radiochemistry 34-39 b) Wet Chemistry 40-44 c) Microbiology 45 d) Metals 46-53

Sample Containers 54-69


a) Radiochemistry 60-61 b) General Chemistry 62-66 c) Microbiology 67-68 d) Metals 69

Environmental Lab Handbook Environmental Laboratory Rev. 3, revised, October 30, 2017 601 Robert Street N. of 70 St. Paul, MN 55164 651-201-5300

Contact Information

Environmental Laboratory Section Public Health Laboratory Division Minnesota Department of Health

Inquiries about Environmental lab analyses and sample status can be directed to the Environmental Laboratory Operations Unit at (651) 201-5300 or send an email to: [email protected] For inquiries related to sample receiving, please call (651) 201-4952 or send an email to: [email protected] For inquiries related to bottle orders, please call (651) 201-4952 or send an email to: [email protected] The MDH Environmental Laboratory provides analytical services primarily for government agencies, some counties, and select associations. To inquire about establishing an account, please contact the Environmental Laboratory Operations Unit at (651) 201-5300 or send an email to: [email protected] Private Citizens who are seeking analytical services are encouraged to contact their county health agency for access to lab services. Lists of laboratories certified by MDH to perform analytical tests are provided by the MDH Environmental Laboratory Accreditation Program at: http://www.health.state.mn.us/divs/phl/accreditation/index.html

mailto:[email protected]





http://www.health.state.mn.us/divs/phl/accreditation/index.html

ops020 Environmental Lab Handbook Environmental Laboratory Rev. 3, revised, October 30, 2017 601 Robert Street N. of 70 St. Paul, MN 55164 651-201-5300

Method Guide by Analytical Area

ORGANIC CHEMISTRY

Analysis Matrix Method Container/Preservative Type

Volume Required

(mL) Temp Requirement BNAs in Drinking Water Drinking Water EPA 525.2/EPA 508.1 1 L Amber, Na2SO3, HCL 1000 Cool, 0 to ≤6°C, not frozen Carbamates Drinking Water EPA 531.1 40 mL Vial, Na2SO3/Carb 40 Cool, 0 to ≤6°C, not frozen Diesel Range Organics Drinking Water WI DNR 1 L Amber, HCl 1000 N/A Diesel Range Organics Non-potable Water WI DNR 1 L Amber, HCl 1000 Cool, ≤6 °C, not frozen EDB & DBCP Drinking Water EPA 504.1 40 mL Vial, Na2S2O3 40 Cool, 0 to ≤6°C, not frozen EDB & DBCP Non-potable Water EPA 504.1 40 mL Vial, Na2S2O3 40 N/A Flash Point Non-potable Water ASTI/ASTM D93-79 250 mL Tall Glass Jar, Unpreserved 60 Cool, ≤6 °C, not frozen Glyphosate Drinking Water EPA 547 40 mL Amber Vial, Na2S2O3 40 Cool, 0 to ≤6°C, not frozen Gasoline Range Organics Drinking Water WI DNR 40 mL Vial, HCl (In triplicate) 40 N/A Gasoline Range Organics Non-potable Water WI DNR 40 mL Vial, HCl (In triplicate) 40 Cool, ≤6 °C, not frozen Haloacetic Acids Drinking Water EPA 552.2 250 mL Amber, NH4Cl 250 Cool, 0 to ≤6°C, not frozen

Herbicides Drinking Water EPA 515.4 250 mL Amber, Na2SO3, Wide Mouth 250 Cool 0 to ≤10°C first 48 hrs, 0

to ≤6°C thereafter, not frozen PAHs Water SIM/GC/MS Expd Non-potable Water EPA 8270D 1 L Amber, Unpreserved 1000 Cool, ≤6 °C, not frozen PAHs Water SIM/GC/MS Short Non-potable Water EPA 8270D 1 L Amber, Unpreserved 1000 Cool, ≤6 °C, not frozen PCB Aroclors Non-potable Water EPA 8082 1 L Amber, Unpreserved 500 Cool, ≤6 °C, not frozen

PFC Expanded List Drinking Water MDH 555 250 mL HDPE Jar, Unpreserved 250 N/A PFC Expanded List Non-potable Water MDH 555 250 mL HDPE Jar, Unpreserved 250 Cool, ≤6 °C, not frozen SVOCs by Full Scan GC/MS Non-potable Water EPA 8270D 1 L Amber, Unpreserved 1000 Cool, ≤6 °C, not frozen THMs Drinking Water EPA 524.2 40 mL Vial, Ascorbic Acid/HCl; (In triplicate) 40 Cool, 0 to ≤6°C, not frozen Toxaphene in Water Non-potable Water EPA 8081 1 L Amber, Unpreserved 500 Cool, ≤6 °C, not frozen Vinyl Chloride Drinking Water EPA 524.2 40 mL Vial, HCl (In triplicate) 40 Cool, 0 to ≤6°C, not frozen Vinyl Chloride Non-potable Water EPA 524.2 40 mL Vial, HCl (In triplicate) 40 N/A VOCs Drinking Water EPA 8260B 40 mL Vial, HCl (In triplicate) 40 Cool, 0 to ≤6°C, not frozen



Volume Required

(mL) Temp Requirement VOCs Non-potable Water EPA 8260B 40 mL Vial, HCl (In triplicate) 40 Cool, ≤6 °C, not frozen VOCs Drinking Water EPA 524.2 40 mL Vial, HCl (In triplicate) 40 Cool, 0 to ≤6°C, not frozen VOCs Non-potable Water EPA 524.2 40 mL Vial, HCl (In triplicate) 40 Cool, ≤6 °C, not frozen


INORGANIC CHEMISTRY

RADIOCHEMISTRY

Analysis Matrix Method Container/Preservative Type Volume Required

(mL) Temp Requirement Alpha & Beta Radiation, gross Air MDH Filter 1 Filter N/A Alpha & Beta Radiation, gross Wipe/Solid MDH Wipes 1 Wipe N/A Alpha &Beta Radiation, gross Drinking and Non-potable Water EPA 900.0 4 L LDPE Cubitainer, Unpreserved* 4000 N/A Alpha Radiation, gross Drinking and Non-potable Water EPA 900.0 4 L LDPE Cubitainer, Unpreserved* 4000 N/A Gamma Analysis Air SM 7120 Filter 1 Filter N/A Gamma Analysis Wipe/Solid and Chem. Mat. SM 7120 Wipes 1 Wipe N/A Gamma Analysis Drinking and Non-potable Water SM 7120 4 L LDPE Cubitainer, Unpreserved** 4000 N/A Ni-63 Wipes by LSC Wipe/Solid MDH Wipes 1 Wipe N/A Radium 226/228 Drinking Water EPA 903.0/904.0 4 L LDPE Cubitainer, Unpreserved* 4000 N/A Strontium 89/90 Drinking Water EPA 905.0 4 L LDPE Cubitainer, Unpreserved* 4000 N/A Strontium 89/90 Non-potable Water EPA 905.0 4 L HDPE Jug, Unpreserved* 4000 N/A Strontium 89/90 Biological Materials EPA 520/5-84-006 4 L LDPE Cubitainer, Unpreserved* 4000 N/A Tritium Drinking Water EPA 600/4-75-008 4 L LDPE Cubitainer, Unpreserved 4000 N/A Tritium Non-potable Water EPA 600/4-75-008 4 L HDPE Jug, Unpreserved 4000 N/A

*PRESERVED IN THE LAB WITH NITRIC ACID TO A PH <2 PRIOR TO ANALYSIS.

**IF I-131 IS REQUESTED, I-131 WILL BE ANALYZED PRIOR TO ACIDIFICATION IN THE LAB WITH NITRIC ACID TO A PH <2.


WET CHEMISTRY


Volume Required

(mL) Temp Requirement Acetate Non-potable Water EPA 300.1 125 mL HDPE, Unpreserved 125 N/A Alkalinity, Total Drinking Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, 0 to ≤6°C, not frozen Alkalinity, Total Non-potable Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, ≤6 °C, not frozen Alkalinity, Bicarbonate as CaCO3 Drinking Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, 0 to ≤6°C, not frozen Alkalinity, Bicarbonate as CaCO3 Non-potable Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, ≤6 °C, not frozen Alkalinity, Carbonate as CaCO3 Drinking Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, 0 to ≤6°C, not frozen Alkalinity, Carbonate as CaCO3 Non-potable Water SM 2320B 1 L HDPE, Unpreserved, Wide-Mouth 250 Cool, ≤6 °C, not frozen Ammonia, Total Drinking Water EPA 350.1 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen Ammonia, Total Non-potable Water EPA 350.1 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Ammonia, Dissolved Drinking Water EPA 350.1 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen Ammonia, Dissolved Non-potable Water EPA 350.1 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen BOD, 5 Day Non-potable Water Hach 10360 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, ≤6 °C, not frozen Bromide Drinking and Non-potable Water EPA 300.1 125 mL HDPE, Unpreserved 125 N/A CBOD, 5 Day, NI Non-potable Water Hach 10360 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, ≤6 °C, not frozen Chloride Drinking and Non-potable Water EPA 300.1 125 mL HDPE, Unpreserved 125 N/A Chlorophyll-A Drinking and Non-potable Water SM 10200H Filter - Glass Fiber 1 Filter N/A Chlorophyll-A – Lab Filter Drinking Water SM 10200H 1 L Amber, Unpreserved 1000 N/A Chlorophyll-A – Lab Filter Non-potable Water SM 10200H 1 L Amber, Unpreserved 1000 Cool, ≤6 °C, not frozen COD, Total Drinking Water EPA 410.4 250 mL HDPE, H2SO4 250 N/A COD, Total Non-potable Water EPA 410.4 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen



Volume Required

(mL) Temp Requirement Color Drinking Water SM 2120B 1 L HDPE, Unpreserved, Wide-Mouth 100 Cool, 0 to ≤6°C, not frozen Color Non-potable Water SM 2120B 1 L HDPE, Unpreserved, Wide-Mouth 100 Cool, ≤6 °C, not frozen Conductivity, Specific Drinking Water SM 2510B 250 mL HDPE, Unpreserved 250 Cool, 0 to ≤6°C, not frozen Conductivity, Specific Non-potable Water SM 2510B 250 mL HDPE, Unpreserved 250 Cool, ≤6 °C, not frozen Cyanide, Total Drinking Water EPA 335.4 500 mL HDPE, NaOH 500 Cool, 0 to ≤6°C, not frozen Cyanide, Total Non-potable Water EPA 335.4 500 mL HDPE, NaOH 500 Cool, ≤6 °C, not frozen Cyanide, Free Drinking Water SM 4500-CN F 500 mL HDPE, NaOH 500 Cool, 0 to ≤6°C, not frozen DOC Drinking Water SM 5310C 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen DOC Non-potable Water SM 5310C 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Fluoride, Total Drinking and Non-potable Water SM 4500-F C 125 mL HDPE, Unpreserved 125 N/A Fluoride, Dissolved Drinking and Non-potable Water SM 4500-F C 125 mL HDPE, Unpreserved 125 N/A Nitrate + Nitrite, Total Drinking Water SM 4500-NO3 F 125 mL HDPE, H2SO4 125 N/A Nitrate + Nitrite, Total Non-potable Water EPA 353.2 250 mL HDPE, H2SO4 125 Cool, ≤6 °C, not frozen Nitrate + Nitrite, Dissolved Drinking Water SM4500-NO3 F 125 mL HDPE, H2SO4 125 N/A Nitrate + Nitrite, Dissolved Non-potable Water EPA 353.2 250 mL HDPE, H2SO4 125 Cool, ≤6 °C, not frozen Nitrite Nitrogen, Total Drinking Water SM4500-NO2 B 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Nitrite Nitrogen, Total Non-potable Water SM4500-NO2 B 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen Nitrite Nitrogen, Dissolved Drinking Water SM4500-NO2 B 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Nitrite Nitrogen, Dissolved Non-potable Water SM4500-NO2 B 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen TKN Drinking Water EPA 351.2 250 mL HDPE, H2SO4 250 N/A TKN Non-potable Water EPA 351.2 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen TKN, Dissolved Drinking Water EPA 351.2 250 mL HDPE, H2SO4 250 N/A TKN, Dissolved Non-potable Water EPA 351.2 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Nitrogen, Total Drinking Water SM4500N B 125 mL HDPE, H2SO4 125 N/A Nitrogen, Total Non-Potable Water SM4500N B 250 ml HDPE, H2SO4 125 N/A Orthophosphate, Total Drinking Water SM4500P E 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Orthophosphate, Total Non-potable Water SM 4500-P F 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen Orthophosphate, Dissolved Drinking Water SM4500P E 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Orthophosphate, Dissolved Non-potable Water SM 4500-P F 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen pH Drinking and Non-potable Water SM 4500-H+B 250 mL HDPE, Unpreserved 250 N/A Pheophytin-A Non-potable Water SM 10200 H Filter - Glass Fiber 1 Filter Cool, ≤6 °C, not frozen Phosphorus, Total Drinking Water SM4500P I 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen



Volume Required

(mL) Temp Requirement Phosphorus (Non-potable) Non-Potable Water SM4500-P I (F) 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Phosphorus, Dissolved Drinking Water SM4500P I 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen Phosphorus, Dissolved Non-potable Water SM4500P I 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Silica Drinking Water SM 4500-SiO2 C 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Silica Non-potable Water SM 4500-SiO2 C 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen Silica, Dissolved Drinking Water SM 4500-SiO2 C 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Silica, Dissolved Non-potable Water SM 4500-SiO2 C 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen TSS Drinking and Non-potable Water SM 2540D 1 L HDPE, Unpreserved, Wide-Mouth 1000 N/A TS Drinking and Non-potable Water SM 2540B 1 L HDPE, Unpreserved, Wide-Mouth 1000 N/A TDS Drinking and Non-potable Water SM 2540C 1 L HDPE, Unpreserved, Wide-Mouth 1000 N/A TVS Drinking Water SM 2540E 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, 0 to ≤6°C, not frozen TVS Non-potable Water SM 2540E 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, ≤6 °C, not frozen TSVS Drinking Water SM 2540E 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, 0 to ≤6°C, not frozen TSVS Non-potable Water SM 2540E 1 L HDPE, Unpreserved, Wide-Mouth 1000 Cool, ≤6 °C, not frozen Sulfate Drinking Water EPA 300.1 125 mL HDPE, Unpreserved 125 Cool, 0 to ≤6°C, not frozen Sulfate Non-potable Water EPA 300.1 125 mL HDPE, Unpreserved 125 Cool, ≤6 °C, not frozen TOC Drinking Water SM 5310C 250 mL HDPE, H2SO4 250 Cool, 0 to ≤6°C, not frozen TOC Non-potable Water SM 5310C 250 mL HDPE, H2SO4 250 Cool, ≤6 °C, not frozen Turbidity Drinking Water SM 2130B 1 L HDPE, Unpreserved, Wide-Mouth 200 Cool, 0 to ≤6°C, not frozen Turbidity Non-potable Water SM 2130B 1 L HDPE, Unpreserved, Wide-Mouth 200 Cool, ≤6 °C, not frozen UV 254 Drinking Water SM 5910B 250 mL HDPE, Unpreserved 250 Cool, 0 to ≤6°C, not frozen UV 254 Non-potable Water SM 5910B 250 mL HDPE, Unpreserved 250 Cool, ≤6 °C, not frozen UV 440 Drinking Water MDH 250 mL HDPE, Unpreserved 250 Cool, 0 to ≤6°C, not frozen UV 440 Non-potable Water MDH 250 mL HDPE, Unpreserved 250 Cool, ≤6 °C, not frozen


MICROBIOLOGY

Analysis Matrix Method Container Type

Volume Required

(mL) Temp Requirement Total Coliform and E. coli - PA Drinking Water SM 9223B 150 mL Clear HDPE (sterile), Na2S2O3 100 N/A Total Coliform and E. coli - PA (Surface Source Water) Drinking Water SM 9223B 150 mL Clear HDPE (sterile), Na2S2O3 100 Cool 0 to ≤10°C, not frozen MPN, Total Coliform and E. coli - QT Drinking Water SM 9223B 150 mL Clear HDPE (sterile), Na2S2O3 100 N/A MPN, E. coli - QT - 2000 Drinking Water SM 9223B 150 mL Clear HDPE (sterile), Na2S2O3 100 N/A

MPN, E. coli - QT - 2000 Non-potable Water SM 9223B 150 mL Clear HDPE (sterile), Na2S2O3 100 Cool, <10 °C, not frozen

Link to micro container 150 mL Clear HDPE (sterile), Na2S2O3

Link to sampling instructions


METALS

Summary of the Resource Conservation and Recovery Act

42 U.S.C. §6901 et seq. (1976)

Approved metals methods for non-potable water 6010 and 6020

The Resource Conservation and Recovery Act (RCRA) gives EPA the authority to control hazardous waste from the "cradle-to-grave." This includes the generation, transportation, treatment, storage, and disposal of hazardous waste. RCRA also set forth a framework for the management of non-hazardous solid wastes. The 1986 amendments to RCRA enabled EPA to address environmental problems that could result from underground tanks storing petroleum and other hazardous substances.

HSWA - the Federal Hazardous and Solid Waste Amendments - are the 1984 amendments to RCRA that focused on waste minimization and phasing out land disposal of hazardous waste as well as corrective action for releases. Some of the other mandates of this law include increased enforcement authority for EPA, more stringent hazardous waste management standards, and a comprehensive underground storage tank program.

Clean Water Act

Approved metals methods for non-potable water 200.7 and 200.8


The 1972 amendments to the Federal Water Pollution Control Act (known as the Clean Water Act or CWA) provide the statutory basis for the NPDES permit program and the basic structure for regulating the discharge of pollutants from point sources to waters of the United States. Section 402 of the CWA specifically required EPA to develop and implement the NPDES program.

The CWA gives EPA the authority to set effluent limits on an industry-wide (technology-based) basis and on a water-quality basis that ensure protection of the receiving water. The CWA requires anyone who wants to discharge pollutants to first obtain an NPDES permit, or else that discharge will be considered illegal.

The CWA allowed EPA to authorize the NPDES Permit Program to state governments, enabling states to perform many of the permitting, administrative, and enforcement aspects of the NPDES Program. In states that have been authorized to implement CWA programs, EPA still retains oversight responsibilities.

The key sections of the CWA that directly relate to the NPDES Permit Program include:

Safe Drinking Water Act (SDWA)

Approved metals methods for drinking water 200.7 and 200.8

The Safe Drinking Water Act (SDWA) is the main federal law that ensures the quality of Americans' drinking water. Under SDWA, EPA sets standards for drinking water quality and oversees the states, localities, and water suppliers who implement those standards.

SDWA was originally passed by Congress in 1974 to protect public health by regulating the nation's public drinking water supply. The law was amended in 1986 and 1996 and requires many actions to protect drinking water and its sources:


rivers, lakes, reservoirs, springs, and ground water wells. (SDWA does not regulate private wells which serve fewer than 25 individuals.)

Link to 250 ml HDPE, HNO3 container

Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Aluminum Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Aluminum, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Antimony Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A

Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A

Antimony, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Arsenic Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Arsenic, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Barium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Barium, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Beryllium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A



Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Beryllium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Boron Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A

Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A

Boron, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Cadmium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Cadmium, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Calcium Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Calcium, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Ca as CaCO3 Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Calcium as CaCO3, Dissolved Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Chromium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Chromium, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Cobalt Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Cobalt, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A

Copper Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A


Copper, Low Level Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Copper, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Copper, Dissolved Low Level Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Hardness (200) Drinking and Non-potable Water SM 2340B 250 mL HDPE, HNO3 250 N/A Hardness (6010B) Non-potable Water SM 2340B 250 mL HDPE, HNO3 250 N/A Hardness Diss. (6010B) Non-potable Water SM 2340B 250 mL HDPE, HNO3 250 N/A Iron Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Iron, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Iron, Low Level Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Iron, Low Level Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Iron Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Iron, Dissolved Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A


Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Lead Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Lead, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Lithium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Lithium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Magnesium Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Magnesium, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Magnesium, Dissolved Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Mg as CaCO3 Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Mg as CaCO3, Dissolved Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Manganese Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Manganese, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Mercury Drinking and Non-potable Water EPA 245.2 120 mL HDPE, HNO3/HCL 120 N/A Mercury, Dissolved Drinking and Non-potable Water EPA 245.2 120 mL HDPE, HNO3/HCL 120 N/A Mercury, Methyl Non-potable Water EPA 1630 250 mL PETG, HCl 250 N/A


Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Mercury, Methyl Dissolved Non-potable Water EPA 1630 250 mL PETG, HCl 250 N/A Mercury, Ultra Low Level Drinking and Non-potable Water EPA 1631 250 mL PETG, HCl 250 N/A Mercury, Dissolved Ultra Low Level Drinking and Non-potable Water EPA 1631 250 mL PETG, HCl 250 N/A Molybdenum Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Molybdenum, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Nickel Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Nickel, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Potassium Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Potassium, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Selenium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Selenium, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Silver Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Silver, Dissolved Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A


Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Sodium Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Sodium, Dissolved Drinking and Non-potable Water EPA 200.7 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6010B 250 mL HDPE, HNO3 250 N/A Strontium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Strontium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Thallium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Thallium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Tin Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Tin, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Titanium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Titanium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Uranium Drinking Water EPA 200.8 4 L LDPE Cubitainer 4000 N/A

Non-potable Water EPA 200.8 4 L HDPE Jug, Unpreserved 4000 N/A

Vanadium Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Vanadium, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A


Analysis Matrix Method Container Type Volume Required (mL) Temp Requirement Zinc Drinking and Non-potable Water EPA 200.8 250 mL HDPE, HNO3 250 N/A Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A Zinc, Dissolved Non-potable Water EPA 6020 250 mL HDPE, HNO3 250 N/A

ADDITIONAL ANALYSES

**PRIOR APPROVAL REQUIRED TO REQUEST ANALYSES BELOW**

Analysis Matrix Method 1, 4-Dioxane in Water Non-potable Water EPA 8260B Acrylamide in Water Drinking & Non-Potable Water MDH Method As (As+3, As+5) ICP-MS Drinking Water MDH Method As Diss. (As+3, As+5) ICP-MS Drinking Water MDH Method BPA and BPS in Solids Solid and Chem. Mat. MDH Method Diesel Range Organics Solid and Chem. Mat. WI DNR Drugs in Water Non-potable Water MDH Method Ethanol in Water Non-potable Water EPA 8260B Ethanol in Solids Solid and Chem. Mat. EPA 8260B Gasoline Range Organics Solid and Chem. Mat. WI DNR PAHs Solids FS/GC/MS Expd List Solid and Chem. Mat. EPA 8270D PAHs Solids FS/GC/MS Short List Solid and Chem. Mat. EPA 8270D PAHs Solids by SIM/GC/MS Expd List Solid and Chem. Mat. EPA 8270D PAHs Solids SIM/GC/MS Short List Solid and Chem. Mat. EPA 8270D PAHs Water FS/GC/MS Expd List Non-potable Water EPA 8270D PAHs Water FS/GC/MS Short List Non-potable Water EPA 8270D PCB Aroclors Solid and Chem. Mat. EPA 8082 Sulfide Non-potable Water SM 4500-S2 E Sulfide, Acid-Volatile Solid and Chem. Mat. SM4500-S2 J


SVOCs by Full Scan GC/MS Solid and Chem. Mat. EPA 8270D VOCs Solid and Chem. Mat. EPA 8260B


Method Guide by Analyte

ORGANIC CHEMISTRY

Analysis Method Matrix

Extract/ Analysis Hold Time (days) Analyte Reporting Limit Units

BNA in Water EPA 508.1 Drinking Water 14/30 Alachlor 0.15 ug/L

Butachlor 0.25 ug/L

Dieldrin 0.20 ug/L

Endrin 0.10 ug/L

Heptachlor 0.10 ug/L

Methoxychlor 0.10 ug/L

Metolachlor 0.25 ug/L

Propachlor 0.20 ug/L

Technical Chlordane 0.10 ug/L

Toxaphene 0.80 ug/L

EPA 525.2 Drinking Water 14/30 Aldrin 0.25 ug/L

Atrazine 0.10 ug/L

Benzo[a]pyrene 0.050 ug/L

Di(2-ethylhexyl) adipate 0.60 ug/L

Di(2-ethylhexyl) phthalate 1.8 ug/L

g-BHC (Lindane) 0.10 ug/L

Heptachlor epoxide 0.10 ug/L

Hexachlorobenzene 0.090 ug/L

Hexachlorocyclopentadiene 0.30 ug/L

Metribuzin 0.50 ug/L

Simazine 0.20 ug/L




Carbamates in Water EPA 531.1 Drinking Water 28 3-Hydroxycarbofuran 0.40 ug/L Aldicarb 0.40 ug/L Aldicarb sulfone 0.40 ug/L

Aldicarb sulfoxide 0.40 ug/L

Carbaryl 0.40 ug/L

Carbofuran 0.40 ug/L

Methomyl 0.40 ug/L Oxamyl 0.40 ug/L

DRO in Water WI DNR Drinking and Non-Potable Water 7/40 DRO 100 ug/L

EDB & DBCP in Water EPA 504.1 Drinking and Non-Potable Water 14/1 1,2-Dibromo-3-chloropropane (DBCP) 0.02 ug/L

1,2-Dibromoethane (EDB) 0.04 ug/L

Ethanol in Water EPA 8260B Non-potable Water 14 Ethanol 100 ug/L

Flash Point in Water ASTI/ASTM D93-79 Non-potable Water 14 Flash Point

°F

Glyphosate in Water EPA 547 Drinking Water 14 Glyphosate 5.0 ug/L

GRO in Water WI DNR Drinking and Non-Potable Water 14 GRO 100 ug/L

HAA in Water EPA 552.2 Drinking Water 14/14 Dibromoacetic Acid 1.0 ug/L Dichloroacetic Acid 1.0 ug/L

Monobromoacetic Acid 1.0 ug/L

Monochloroacetic Acid 2.0 ug/L

Trichloroacetic Acid 1.0 ug/L




Herbicides in Water EPA 515.4 Drinking Water 14/21 2,4,5-TP (Silvex) 0.20 ug/L 2,4-D 0.50 ug/L Dalapon 0.50 ug/L

Dinoseb 0.50 ug/L

Pentachlorophenol (PCP) 0.10 ug/L

Picloram 0.50 ug/L

PAHs Water SIM/GC/MS Expd List EPA 8270D Non-potable Water 7/40 1-Methylnaphthalene 0.02 ug/L

1-Nitropyrene 0.2 ug/L

2-Methylnaphthalene 0.02 ug/L

2-Nitrofluorene 0.2 ug/L

3-Methylcholanthrene 0.02 ug/L

4-Nitropyrene 0.02 ug/L

5-Methylchrysene 0.02 ug/L 5-Nitroacenaphthene 0.2 ug/L 6-Nitrochrysene 0.2 ug/L 7,12-Dimethylbenz[a]anthracene 0.02 ug/L 7H-Dibenzo[c,g]carbazole 0.02 ug/L

Acenaphthene 0.02 ug/L

Acenaphthylene 0.02 ug/L

Anthanthrene 0.02 ug/L

Anthracene 0.02 ug/L

Benz[a]anthracene 0.02 ug/L


Benzo[b]fluoranthene 0.02 ug/L

Benzo[c]fluorene 0.02 ug/L

Benzo[e]pyrene 0.02 ug/L

Benzo[g,h,i]perylene 0.02 ug/L Benzo[j]fluoranthene 0.02 ug/L

Benzo[k]fluoranthene 0.02 ug/L

Carbazole 0.02 ug/L Chrysene 0.02 ug/L




PAHs Water SIM/GC/MS Expd List EPA 8270D Coronene 0.02 ug/L Cyclopenta [c,d] pyrene 0.02 ug/L Dibenz[a,h]anthracene 0.02 ug/L Dibenz[a,h]acridine 0.02 ug/L Dibenz[a,j]acridine 0.02 ug/L Dibenzo [a,e] fluoranthene 0.02 ug/L

Dibenzo[a,e]pyrene 0.02 ug/L

Dibenzo[a,h]pyrene 0.02 ug/L Dibenzo[a,i]pyrene 0.02 ug/L Dibenzo[a,l]pyrene 0.02 ug/L Dibenofuran 0.02 ug/L

Dibenzothiophene 0.02 ug/L

Fluoranthene 0.02 ug/L

Fluorene 0.02 ug/L Indeno[1,2,3-cd]pyrene 0.02 ug/L

Naphthalene 0.02 ug/L

Perylene 0.02 ug/L

Phenanthrene 0.02 ug/L

Pyrene 0.02 ug/L

Quinoline 0.1 ug/L Retene 0.02 ug/L

Triphenylene 0.02 ug/L

PAHs Water SIM/GC/MS Short List EPA 8270D Non-potable Water 7/40 2-Methylnaphthalene 0.02 ug/L Acenaphthene 0.02 ug/L


Anthracene 0.02 ug/L

Benzo[a]anthracene 0.02 ug/L


Benzo[b]fluoranthene 0.02 ug/L Benzo[g,h,i]perylene 0.02 ug/L




PAHs Water SIM/GC/MS Short List EPA 8270D Benzo[k]fluoranthene 0.02 ug/L Chrysene 0.02 ug/L

Dibenz[a,h]anthracene 0.02 ug/L


Fluorene 0.02 ug/L

Indeno[1,2,3-cd]pyrene 0.02 ug/L Naphthalene 0.02 ug/L


Pyrene 0.02 ug/L

PCB Aroclors in Water EPA 8082 Non-potable Water 7/40 Aroclor 1016 0.25 ug/L

Aroclor 1221 0.50 ug/L






PFC Expanded List in Water MDH 555

Drinking and Non-Potable Water 14 Perfluorobutanesulfonate (PFBS) 0.050 ug/L

Perfluorobutanoic acid (PFBA) 0.050 ug/L

Perfluorohexanesulfonate (PFHxS) 0.050 ug/L

Perfluorohexanoic acid (PFHxA) 0.050 ug/L

Perfluorooctanesulfonate (PFOS) 0.050 ug/L

Perfluorooctanoic acid (PFOA) 0.050 ug/L Perfluoropentanoic acid (PFPeA) 0.050 ug/L




SVOCs in Water by GC/MS EPA 8270D Non-potable Water 7/40 1,2,4,5-Tetrachlorobenzene 5.0 ug/L 1,2,4-Trichlorobenzene 10.0 ug/L 1,2-Dichlorobenzene 10.0 ug/L

1,2-Diphenylhydrazine 2.0 ug/L

1,3-Dichlorobenzene 10.0 ug/L


1-Chloronaphthalene 5.0 ug/L

1-Naphthylamine 10.0 ug/L

2,3,4,6-Tetrachlorophenol 10.0 ug/L

2,4,5-Trichlorophenol 10.0 ug/L

2,4,6-Trichlorophenol 10.0 ug/L

2,4-Dichlorophenol 10.0 ug/L

2,4-Dimethylphenol 10.0 ug/L

2,4-Dinitrophenol 20.0 ug/L

2,4-Dinitrotoluene 5.0 ug/L

2,6-Dichlorophenol 10.0 ug/L

2,6-Dinitrotoluene 5.0 ug/L 2-Chloronaphthalene 5.0 ug/L 2-Chlorophenol 10.0 ug/L 2-Methyl-4,6-dinitrophenol 10.0 ug/L 2-Methylnaphthalene 2.0 ug/L

2-Methylphenol 10.0 ug/L

2-Naphthylamine 10.0 ug/L

2-Nitroaniline 10.0 ug/L

2-Nitrophenol 10.0 ug/L 2-Picoline 10.0 ug/L

3,3'-Dichlorobenzidine 10.0 ug/L

3+4-Methylphenol 20.0 ug/L

3-Methylcholanthrene 10.0 ug/L


4-Aminobiphenyl 5.0 ug/L




SVOCs in Water by GC/MS EPA 8270D

4-Bromophenyl phenyl ether 5.0 ug/L

4-Chloro-3-methylphenol 10.0 ug/L

4-Chloroaniline 5.0 ug/L

4-Chlorophenyl phenyl ether 10.0 ug/L


4-Nitrophenol 20.0 ug/L

7,12-Dimethylbenz[a]anthracene 2.0 ug/L

Acenaphthene 2.0 ug/L


Acetophenone 10.0 ug/L

Aniline 5.0 ug/L

Anthracene 2.0 ug/L

Benzidine 20.0 ug/L

Benz[a]anthracene 2.0 ug/L


Benzo[b,k]fluoranthene 2.0 ug/L Benzo[g,h,i]perylene 2.0 ug/L

Benzoic acid 40.0 ug/L

Benzyl alcohol 10.0 ug/L Bis(2-chloroethoxy)methane 2.0 ug/L Bis(2-chloroethyl)ether 5.0 ug/L

Bis(2-chloroisopropyl)ether 2.0 ug/L

Bis(2-ethylhexyl) phthalate 10.0 ug/L

Butyl benzyl phthalate 10.0 ug/L

Carbazole 2.0 ug/L

Chrysene 2.0 ug/L Dibenz[a,j]acridine 10.0 ug/L

Dibenz[a,h]anthracene 2.0 ug/L

Dibenzofuran 2.0 ug/L

Diethyl phthalate 10.0 ug/L

Dimethyl phthalate 2.0 ug/L




SVOCs in Water by GC/MS EPA 8270D

Di-n-butyl phthalate 10.0 ug/L

Di-n-octyl phthalate 10.0 ug/L

Diphenylamine 2.0 ug/L Endrin ketone 10.0 ug/L Ethyl methanesulfonate 2.0 ug/L


Fluorene 2.0 ug/L

Hexachlorobenzene 2.0 ug/L

Hexachlorobutadiene 10.0 ug/L Hexachlorocyclopentadiene 20.0 ug/L Hexachloroethane 10.0 ug/L Indeno[1,2,3-cd]pyrene 2.0 ug/L

Isophorone 5.0 ug/L

Methoxychlor 10.0 ug/L

Methyl methanesulfonate 10.0 ug/L

Naphthalene 2.0 ug/L

Nitrobenzene 5.0 ug/L

N-Nitrosodimethylamine (NDMA) 10.0 ug/L

N-Nitroso-di-n-butylamine 2.0 ug/L

N-Nitroso-di-n-propylamine 10.0 ug/L

N-Nitrosopiperidine 5.0 ug/L p-Dimethylaminoazobenzene 10.0 ug/L

Pentachlorobenzene 2.0 ug/L

Pentachloronitrobenzene 10.0 ug/L

Pentachlorophenol (PCP) 10.0 ug/L

Phenacetin 10.0 ug/L


Phenol 10.0 ug/L

Pronamide 5.0 ug/L

Pyrene 2.0 ug/L




THMs in Water EPA 524.2 Drinking Water 14 Bromodichloromethane 0.5 ug/L Bromoform 0.5 ug/L Chlorodibromomethane 0.5 ug/L

Chloroform 0.5 ug/L

Toxaphene in Water EPA 8081 Non-potable Water 7/40 4,4´-DDD 10.0 ug/L

4,4´-DDE 10.0 ug/L

4,4´-DDT 10.0 ug/L a-BHC 10.0 ug/L

Aldrin 10.0 ug/L

b-BHC 10.0 ug/L

d-BHC 10.0 ug/L

Dieldrin 10.0 ug/L

Endosulfan I 10.0 ug/L

Endosulfan II 10.0 ug/L

Endosulfan sulfate 10.0 ug/L

Endrin 10.0 ug/L

Endrin aldehyde 10.0 ug/L

g-BHC (Lindane) 10.0 ug/L

Heptachlor 10.0 ug/L

Heptachlor epoxide 10.0 ug/L

Technical Chlordane 200 ug/L

Toxaphene 0.50 ug/L

Vinyl Chloride in Water, Low Level EPA 524.2 Drinking Water 14 Vinyl chloride 0.20 ug/L




VOCs in Water EPA 8260B Drinking and Non-Potable Water 14 1,1,1,2-Tetrachloroethane 1.0 ug/L

1,1,1-Trichloroethane 1.0 ug/L

1,1,2,2-Tetrachloroethane 1.0 ug/L


1,1,2-Trichlorotrifluoroethane 1.0 ug/L

1,1-Dichloroethane 1.0 ug/L

1,1-Dichloroethene 1.0 ug/L 1,1-Dichloropropene 1.0 ug/L 1,2,3-Trichlorobenzene 1.0 ug/L

1,2,3-Trichloropropane 1.0 ug/L

1,2,4-Trichlorobenzene 1.0 ug/L

1,2,4-Trimethylbenzene 1.0 ug/L

1,2-Dibromo-3-chloropropane (DBCP) 5.0 ug/L

1,2-Dibromoethane (EDB) 1.0 ug/L


1,2-Dichloroethane 1.0 ug/L 1,2-Dichloropropane 1.0 ug/L 1,3,5-Trimethylbenzene 1.0 ug/L 1,3-Dichlorobenzene 1.0 ug/L 1,3-Dichloropropane 1.0 ug/L


2,2-Dichloropropane 1.0 ug/L

2-Chlorotoluene 1.0 ug/L

4-Chlorotoluene 1.0 ug/L

Acetone 20 ug/L

Allyl chloride 1.0 ug/L

Benzene 1.0 ug/L

Bromobenzene 1.0 ug/L Bromochloromethane 1.0 ug/L

Bromodichloromethane 1.0 ug/L




VOCs in Water EPA 8260B

Bromoform 1.0 ug/L

Bromomethane 2.0 ug/L

Carbon tetrachloride 1.0 ug/L

Chlorobenzene 1.0 ug/L Chlorodibromomethane 1.0 ug/L

Chloroethane 1.0 ug/L

Chloroform 1.0 ug/L

Chloromethane 1.0 ug/L

cis-1,2-Dichloroethene 1.0 ug/L

cis-1,3-Dichloropropene 1.0 ug/L Dibromomethane 1.0 ug/L Dichlorodifluoromethane 1.0 ug/L

Dichlorofluoromethane 1.0 ug/L

Ethyl ether 1.0 ug/L

Ethylbenzene 1.0 ug/L

Hexachlorobutadiene 1.0 ug/L

Isopropylbenzene 1.0 ug/L Methyl ethyl ketone (MEK) 10 ug/L

Methyl isobutyl ketone (MIBK) 5.0 ug/L

Methyl tertiary butyl ether (MTBE) 2.0 ug/L Methylene chloride 2.0 ug/L Naphthalene 1.0 ug/L

n-Butylbenzene 1.0 ug/L

n-Propylbenzene 1.0 ug/L

o-Xylene 1.0 ug/L

p&m-Xylene 1.0 ug/L

p-Isopropyltoluene 1.0 ug/L

sec-Butylbenzene 1.0 ug/L

Styrene 1.0 ug/L tert-Butylbenzene 1.0 ug/L Tetrachloroethene 1.0 ug/L




VOCs in Water EPA 8260B

Tetrahydrofuran (THF) 10 ug/L

Toluene 1.0 ug/L

trans-1,2-Dichloroethene 1.0 ug/L

trans-1,3-Dichloropropene 1.0 ug/L

Trichloroethene (TCE) 1.0 ug/L

Trichlorofluoromethane 1.0 ug/L

Vinyl chloride 1.0 ug/L

VOCs in Water, Low Level EPA 524.2

Drinking and Non-Potable Water 14 1,1,1,2-Tetrachloroethane 0.20 ug/L


1,1,2,2-Tetrachloroethane 0.20 ug/L 1,1,2-Trichloroethane 0.20 ug/L 1,1,2-Trichlorotrifluoroethane 0.20 ug/L 1,1-Dichloroethane 0.20 ug/L 1,1-Dichloroethene 0.50 ug/L 1,1-Dichloropropene 0.20 ug/L 1,2,3-Trichlorobenzene 1.0 ug/L 1,2,3-Trichloropropane 0.50 ug/L 1,2,4-Trichlorobenzene 0.50 ug/L 1,2,4-Trimethylbenzene 0.50 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 2.0 ug/L 1,2-Dibromoethane (EDB) 0.50 ug/L 1,2-Dichlorobenzene 0.20 ug/L 1,2-Dichloroethane 0.20 ug/L 1,2-Dichloropropane 0.20 ug/L 1,3,5-Trimethylbenzene 0.50 ug/L 1,3-Dichlorobenzene 0.20 ug/L 1,3-Dichloropropane 0.20 ug/L 1,4-Dichlorobenzene 0.20 ug/L 2,2-Dichloropropane 0.50 ug/L




VOCs in Water, Low Level EPA 524.2 2-Chlorotoluene 0.50 ug/L 4-Chlorotoluene 0.50 ug/L Acetone 20 ug/L Allyl chloride 0.50 ug/L Benzene 0.20 ug/L Bromobenzene 0.20 ug/L Bromochloromethane 0.50 ug/L Bromodichloromethane 0.20 ug/L Bromoform 0.50 ug/L Bromomethane 1.0 ug/L Carbon tetrachloride 0.20 ug/L Chlorobenzene 0.20 ug/L Chlorodibromomethane 0.50 ug/L Chloroethane 0.50 ug/L Chloroform 0.10 ug/L Chloromethane 1.0 ug/L cis-1,2-Dichloroethene 0.20 ug/L cis-1,3-Dichloropropene 0.20 ug/L Dibromomethane 0.50 ug/L Dichlorodifluoromethane 1.0 ug/L Dichlorofluoromethane 0.50 ug/L Ethyl ether 2.0 ug/L Ethylbenzene 0.50 ug/L Hexachlorobutadiene 1.0 ug/L Isopropylbenzene 0.50 ug/L Methyl ethyl ketone (MEK) 10 ug/L Methyl isobutyl ketone (MIBK) 5.0 ug/L Methyl tertiary butyl ether (MTBE) 2.0 ug/L Methylene chloride 0.50 ug/L Naphthalene 1.0 ug/L n-Butylbenzene 0.50 ug/L n-Propylbenzene 0.50 ug/L




VOCs in Water, Low Level EPA 524.2 o-Xylene 0.20 ug/L p&m-Xylene 0.30 ug/L p-Isopropyltoluene 0.50 ug/L sec-Butylbenzene 0.50 ug/L Styrene 0.50 ug/L tert-Butylbenzene 0.50 ug/L Tetrachloroethene 0.20 ug/L Tetrahydrofuran (THF) 10 ug/L Toluene 0.20 ug/L trans-1,2-Dichloroethene 0.10 ug/L trans-1,3-Dichloropropene 0.20 ug/L Trichloroethene (TCE) 0.10 ug/L Trichlorofluoromethane 0.50 ug/L Vinyl chloride 0.20 ug/L


INORGANIC CHEMISTRY

RADIOCHEMISTRY

Analysis Method Matrix Holding Time (days) Analyte

Reporting Limit Units

Alpha & Beta (Filters) MDH Air 180 Gross Alpha 1.0 pCi/m3

Gross Beta 1.0 pCi/m3

Alpha & Beta (Wipes) MDH Solid and Chem. Mat. 180 Gross Alpha 5.0 pCi/wipe

Gross Beta 5.0 pCi/wipe

Alpha & Beta (Wipes) MDH Wipe 180 Gross Alpha 5.0 pCi/wipe


Alpha & Beta, gross EPA 900.0

Drinking and Non-potable Water 180 Gross Alpha 3.0 pCi/L


Alpha, gross EPA 900.0

Drinking and Non-potable Water 180 Gross Alpha 3.0 pCi/L

Gamma SM 7120 Air 180 Americium-241 Variable pCi/m3

Barium-133 Variable pCi/m3

Barium-140 Variable pCi/m3

Beryllium-7 Variable pCi/m3

Bismuth-212 Variable pCi/m3

Bismuth-214 Variable pCi/m3

Cerium-141 Variable pCi/m3

Cerium-144 Variable pCi/m3

Cesium-134 Variable pCi/m3

Cesium-137 Variable pCi/m3




Gamma SM 7120 Chromium-51 Variable pCi/m3 Cobalt-57 Variable pCi/m3 Cobalt-58 Variable pCi/m3

Cobalt-60 Variable pCi/m3

Iodine-131 Variable pCi/m3





Iron-59 Variable pCi/m3

Krypton-88 Variable pCi/m3

Lead-210 Variable pCi/m3



Manganese-54 Variable pCi/m3

Niobium-95 Variable pCi/m3

Potassium-40 Variable pCi/m3

Radium-224 Variable pCi/m3

Radium-226 Variable pCi/m3

Ruthenium/Rhodium-106 Variable pCi/m3

Ruthenium-103 Variable pCi/m3

Strontium-91 Variable pCi/m3

Tellurium-132 Variable pCi/m3

Thallium-208 Variable pCi/m3

Thorium-228 Variable pCi/m3

Thorium-230 Variable pCi/m3

Xenon-133 Variable pCi/m3

Xenon-135 Variable pCi/m3

Zinc-65 Variable pCi/m3 Zirconium-95 Variable pCi/m3




Gamma SM 7120 Wipe 180 Americium-241 Variable pCi/L Barium-133 Variable pCi/L Barium-140 Variable pCi/L Beryllium-7 Variable pCi/L

Bismuth-212 Variable pCi/L


Cerium-141 Variable pCi/L


Cesium-134 Variable pCi/L


Chromium-51 Variable pCi/L

Cobalt-57 Variable pCi/L



Iodine-131 Variable pCi/L





Iron-59 Variable pCi/L

Krypton-88 Variable pCi/L

Lead-210 Variable pCi/L



Manganese-54 Variable pCi/L

Niobium-95 Variable pCi/L

Potassium-40 Variable pCi/L

Radium-224 Variable pCi/L

Radium-226 Variable pCi/L

Ruthenium/Rhodium-106 Variable pCi/L

Ruthenium-103 Variable pCi/L

Strontium-91 Variable pCi/L

Tellurium-132 Variable pCi/L




Gamma SM 7120

Thallium-208 Variable pCi/L

Thorium-228 Variable pCi/L

Thorium-230 Variable pCi/L Xenon-133 Variable pCi/L Xenon-135 Variable pCi/L

Zinc-65 Variable pCi/L

Zirconium-95 Variable pCi/L

Gamma SM 7120

Drinking and Non-potable Water 180 Americium-241 Variable pCi/L

Barium-133 Variable pCi/L

Barium-140 Variable pCi/L

Beryllium-7 Variable pCi/L







Chromium-51 Variable pCi/L




**Analyzed Unpreserved.

**Iodine-131 Variable pCi/L




Iodine-135 Variable pCi/L Iron-59 Variable pCi/L Krypton-88 Variable pCi/L Lead-210 Variable pCi/L Lead-212 Variable pCi/L




Gamma SM 7120 Lead-214 Variable pCi/L Manganese-54 Variable pCi/L Niobium-95 Variable pCi/L Potassium-40 Variable pCi/L Radium-224 Variable pCi/L Radium-226 Variable pCi/L Ruthenium/Rhodium-106 Variable pCi/L Ruthenium-103 Variable pCi/L Strontium-91 Variable pCi/L Tellurium-132 Variable pCi/L Thallium-208 Variable pCi/L Thorium-228 Variable pCi/L Thorium-230 Variable pCi/L Xenon-133 Variable pCi/L Xenon-135 Variable pCi/L Zinc-65 Variable pCi/L Zirconium-95 Variable pCi/L

Ni-63 Wipes MDH

Solid and Chem. Mat./Wipe 180 Nickel-63 2500 pCi/wipe

Ra-226 & Ra-228 EPA 903.0/904.0 Drinking Water 180 Radium-226 1.0 pCi/L

Radium-228 1.0 pCi/L

Strontium EPA 905.0

Drinking and Non-potable Water 180 Strontium-89 2.0 pCi/L

Strontium-90 2.0 pCi/L




Strontium, Milk EPA 520/5-84-006 Biological Materials 180 Strontium-89 2.0 pCi/L

Strontium-90 2.0 pCi/L

Tritium EPA 600/4-75-008

Drinking and Non-potable Water 180 Tritium 200 pCi/L


WET CHEMISTRY

Analysis Method Matrix Holding Time (Days) Analyte


Acetate IC EPA 300.1 Non-potable Water 28 Acetate 1.00 mg/L

Alkalinity as CaCO3 SM 2320B Drinking and Non-potable Water 14 Alkalinity, Total 10 mg/L

Alkalinity, Bicarbonate as CaCO3 SM 2320B

Drinking and Non-potable Water 180 Alkalinity, Bicarbonate 10 mg/L

Alkalinity, Carbonate as CaCO3 SM 2320B

Drinking and Non-potable Water 180 Alkalinity, Carbonate 1.0 mg/L

Ammonia-N EPA 350.1 Drinking and Non-potable Water 28 Ammonia Nitrogen, Total 0.05 mg/L

Ammonia-N, Diss. EPA 350.1 Drinking and Non-potable Water 28

Ammonia Nitrogen, Dissolved 0.05 mg/L

BOD SM 5210B Non-potable Water 2 Biochemical Oxygen Demand 0.5 mg/L

Bromide EPA 300.1 Drinking and Non-potable Water 28 Bromide 0.0050 mg/L

CBOD SM 5210B Non-potable Water 2 Carbonaceous Biochemical Oxygen Demand 0.5 mg/L

Chlorate & Chlorite EPA 300.1 Drinking Water 14 Chlorate 0.050 mg/L Chlorite 0.050 mg/L




Chloride EPA 300.1 Drinking and Non-potable Water 28 Chloride 1.00 mg/L

Chlorine, residual SM 4500Cl G Drinking and Non-potable Water 8 Hours Residual Chlorine 0.1 mg/L

Chlorophyll-A SM 10200H

Drinking and Non-potable Water 30 Chlorophyll-A 1.00 ug/L

Chlorophyll-A Lab Filter SM 10200H

Drinking and Non-potable Water 30 Chlorophyll-A 1.00 ug/L

COD EPA 410.4

Drinking and Non-potable Water 28

Chemical Oxygen Demand, Total 10 mg/L

COD, Diss. EPA 410.4

Drinking and Non-potable Water 28

Chemical Oxygen Demand, Dissolved 10 mg/L

Color SM 2120B

Drinking and Non-potable Water 2 Color 5.0 Color Units

Conductivity SM 2510B

Drinking and Non-potable Water 28 Specific Conductance 2.0

umhos/cm at 25°C

Cyanide EPA 335.4

Drinking and Non-potable Water 14 Cyanide, Total 0.001 mg/L

Cyanide, Free SM 4500-CN F Drinking Water 14 Cyanide, Free 0.05 mg/L

DOC SM 5310C Drinking and Non-potable Water 28 Dissolved Organic Carbon 1.0 mg/L

Fluoride SM 4500-F-C Drinking and Non-potable Water 28 Fluoride, Total 0.20 mg/L

Fluoride, Diss. SM 4500-F-C Drinking and Non-potable Water 28 Fluoride, Dissolved 0.20 mg/L




Nitrate + Nitrite EPA 353.2 Non-potable Water 28 Nitrate + Nitrite Nitrogen, Total 0.05 mg/L

SM4500-NO3 F Drinking Water 28 Nitrate + Nitrite Nitrogen, Total 0.05 mg/L

Nitrate + Nitrite, Diss. EPA 353.2 Non-potable Water 28 Nitrate + Nitrite Nitrogen, Dissolved 0.05 mg/L

SM4500-NO3 F Drinking Water 28 Nitrate + Nitrite Nitrogen, Dissolved 0.05 mg/L

Nitrite SM 4500NO2 B Drinking and Non-potable Water 2 Nitrite Nitrogen, Total 0.01 mg/L

Nitrite, Diss. SM 4500NO2 B Drinking and Non-potable Water 2 Nitrite Nitrogen, Dissolved 0.01 mg/L

TKN EPA 351.2 Drinking and Non-potable Water 28 Kjeldahl Nitrogen, Total 0.20 mg/L

TKN, Diss. EPA 351.2 Drinking and Non-potable Water 28 Kjeldahl Nitrogen, Dissolved 0.20 mg/L

Nitrogen, Total SM 4500N B Drinking and Non-Potable Water 28 Nitrogen, Total 0.05 mg/L

Orthophosphate SM 4500-P F Non-potable Water 2 Orthophosphate Phosphorus, Total 0.005 mg/L

Orthophosphate SM4500P E Drinking Water 2 Orthophosphate Phosphate 0.015 mg/L

Orthophosphate, Diss. SM 4500-P F Non-potable Water 2 Orthophosphate Phosphorus, Dissolved 0.005 mg/L




Orthophosphate, Diss. SM4500P E Drinking Water 2 Orthophosphate Phosphate, Dissolved 0.015 mg/L

pH SM 4500-H+B Drinking and Non-potable Water 15 Minutes pH 0.0 units

Pheophytin-A SM 10200H Non-potable Water 28 Pheophytin-A 1.00 ug/L

Phosphorus as P, Total SM 4500P I Drinking Water 28 Phosphorus as Phosphate, Total 0.03 mg/L

Phosphorus (Non-potable) SM 4500P I (F) Non-potable Water 28 Phosphorus, Total 0.003 mg/L

Phosphorus, Diss. SM 4500P I (F) Drinking and Non-potable Water 28 Phosphorus, Dissolved 0.010 mg/L

Sand Petrology of Sedimentary Rocks, 2nd ed Drinking Water 28 Sand 1.0 mg/L

Clay/Silt 1.0 mg/L

Silica SM 4500-SiO2 C Drinking and Non-potable Water 28 Silica, Total Reactive 0.50 mg/L

Silica, Diss. SM 4500-SiO2 C Drinking and Non-potable Water 28 Silica, Dissolved Reactive 0.50 mg/L

Solids, Suspended SM 2540D Drinking and Non-potable Water 7 (TSS) Solids, Suspended 1.0 mg/L

Solids, Total SM 2540B Drinking and Non-potable Water 7 (TS) Solids, Total 10 mg/L

Solids, Total Dissolved SM 2540C Drinking and Non-potable Water 7 (TDS) Solids, Total Dissolved 10 mg/L




Solids, Total Volatile SM 2540E Drinking and Non-potable Water 7 Solids, Total Volatile 10 mg/L

Solids,Suspended Volatile SM 2540E Drinking and Non-potable Water 7 Solids,Suspended Volatile 1.0 mg/L

Sulfate 300.1 EPA 300.1 Drinking and Non-potable Water 28 Sulfate 1.00 mg/L

Sulfide SM4500-S2 E Non-potable Water 14 Sulfide 0.01 mg/L

TOC SM 5310C Drinking and Non-potable Water 28 Total Organic Carbon 1.0 mg/L

Turbidity SM 2130B Drinking and Non-potable Water 2 Turbidity 0.20 NTU

UV 254 SM 5910 B Drinking and Non-potable Water 2 UV Absorbance, 254 nm 0.005 Abs uns/cm

UV 440 MDH Drinking and Non-potable Water 2 UV Absorbance, 440 nm 0.001 L/mg-m


MICROBIOLOGY

Analysis Method Matrix Holding Time (hours) Analyte


Coliform - PA SM 9223 Drinking Water 30 Coliform, Total 1 /100 mL Escherichia coli 1 /100 mL Coliform- PA (Surface Source Water) SM 9223 Drinking Water 8 Coliform, Total 1 /100 mL Escherichia coli 1 /100 mL Coliform-MPN-QT SM 9223 Drinking Water 30 Coliform, Total 1 MPN/100 mL Escherichia coli 1 MPN/100 mL E. Coli - MPN - QT SM 9223 Drinking Water 30 Escherichia coli 1 MPN/100 mL Non-potable Water 24 Escherichia coli 1 MPN/100 mL


METALS

INDIVIDUAL

Analysis Method Matrix Holding Time (days) Analyte Reporting

Limit Units

Al EPA 200.8 Drinking Water 180 Aluminum 5.00 ug/L Non-potable Water 180 Aluminum 20.0 ug/L Al EPA 6020 Non-potable Water 180 Aluminum 20.0 ug/L Al Diss. EPA 6020 Non-potable Water 180 Aluminum, Dissolved 20.0 ug/L Sb EPA 200.8 Drinking Water 180 Antimony 0.60 ug/L Non-potable Water 180 Antimony 1.00 ug/L Sb EPA 6020 Non-potable Water 180 Antimony 1.00 ug/L Sb Diss. EPA 6020 Non-potable Water 180 Antimony, Dissolved 1.00 ug/L As EPA 200.8 Drinking and Non-potable Water 180 Arsenic 1.00 ug/L As EPA 6020 Non-potable Water 180 Arsenic 1.00 ug/L As Diss. EPA 200.8 Drinking and Non-potable Water 180 Arsenic, Dissolved 1.00 ug/L As Diss. EPA 6020 Non-potable Water 180 Arsenic, Dissolved 1.00 ug/L Ba EPA 200.8 Drinking Water 180 Barium 20.0 ug/L Non-potable Water 180 Barium 5.00 ug/L Ba EPA 6020 Non-potable Water 180 Barium 5.00 ug/L Ba Diss. EPA 200.8 Drinking Water 180 Barium, Dissolved 20.0 ug/L Non-potable Water 180 Barium, Dissolved 5.00 ug/L



Limit Units Ba Diss. EPA 6020 Non-potable Water 180 Barium, Dissolved 5.00 ug/L Be EPA 200.8 Drinking and Non-potable Water 180 Beryllium 0.40 ug/L Be EPA 6020 Non-potable Water 180 Beryllium 0.40 ug/L Be Diss. EPA 6020 Non-potable Water 180 Beryllium, Dissolved 0.40 ug/L B EPA 200.7 Drinking and Non-potable Water 180 Boron 20.0 ug/L B EPA 6010B Non-potable Water 180 Boron 20.0 ug/L B Diss. EPA 200.7 Drinking and Non-potable Water 180 Boron, Dissolved 20.0 ug/L B Diss. EPA 6010B Non-potable Water 180 Boron, Dissolved 20.0 ug/L Cd EPA 200.8 Drinking Water 180 Cadmium 0.50 ug/L Non-potable Water 180 Cadmium 0.10 ug/L Cd EPA 6020 Non-potable Water 180 Cadmium 0.10 ug/L Cd Diss. EPA 200.8 Drinking Water 180 Cadmium, Dissolved 0.50 ug/L Non-potable Water 180 Cadmium, Dissolved 0.10 ug/L Cd Diss. EPA 6020 Non-potable Water 180 Cadmium, Dissolved 0.10 ug/L Ca/CaCO3 EPA 200.7 Drinking and Non-potable Water 180 Ca as CaCO3 5.0 mg/L Ca/CaCO3 EPA 6010B Non-potable Water 180 Ca as CaCO3 5.0 mg/L Ca/CaCO3 Diss. EPA 6010B Non-potable Water 180 Ca as CaCO3, Dissolved 5.0 mg/L Ca EPA 200.7 Drinking and Non-potable Water 180 Calcium 2.0 mg/L



Limit Units Ca EPA 6010B Non-potable Water 180 Calcium 2.0 mg/L Ca Diss. EPA 200.7 Drinking and Non-potable Water 180 Calcium, Dissolved 2.0 mg/L Ca Diss. EPA 6010B Non-potable Water 180 Calcium, Dissolved 2.0 mg/L Cr EPA 200.8 Drinking Water 180 Chromium 10.0 ug/L Non-potable Water 180 Chromium 1.00 ug/L Cr EPA 6020 Non-potable Water 180 Chromium 1.00 ug/L Cr Diss. EPA 200.8 Drinking Water 180 Chromium, Dissolved 10.0 ug/L Non-potable Water 180 Chromium, Dissolved 1.00 ug/L Cr Diss. EPA 6020 Non-potable Water 180 Chromium, Dissolved 1.00 ug/L Co EPA 200.8 Drinking and Non-potable Water 180 Cobalt 1.00 ug/L Co EPA 6020 Non-potable Water 180 Cobalt 1.00 ug/L Co Diss. EPA 6020 Non-potable Water 180 Cobalt, Dissolved 1.00 ug/L Cu EPA 200.8 Drinking and Non-potable Water 180 Copper 10.0 ug/L Cu EPA 6020 Non-potable Water 180 Copper 10.0 ug/L Cu Low Level EPA 6020 Non-potable Water 180 Copper 1.00 ug/L Cu Diss. EPA 6020 Non-potable Water 180 Copper, Dissolved 10.0 ug/L Cu Diss. Low Level EPA 6020 Non-potable Water 180 Copper, Dissolved 1.00 ug/L Hardness (200) SM 2340B Drinking and Non-potable Water 180 Hardness 10 mg/L Hardness (6010B) SM 2340B Non-potable Water 180 Hardness 10 mg/L



Limit Units Hardness Diss. (6010B) SM 2340B Non-potable Water 180 Hardness 10 mg/L Fe EPA 200.7 Drinking and Non-potable Water 180 Iron 20.0 ug/L Fe Diss. EPA 200.7 Drinking and Non-potable Water 180 Iron, Dissolved 20.0 ug/L Fe Low Level EPA 200.7 Drinking and Non-potable Water 180 Iron 14.0 ug/L Fe Diss. Low Level EPA 200.7 Drinking and Non-potable Water 180 Iron, Dissolved 14.0 ug/L Fe EPA 6010B Non-potable Water 180 Iron 20.0 ug/L Fe Diss. EPA 6010B Non-potable Water 180 Iron, Dissolved 20.0 ug/L Pb EPA 200.8 Drinking and Non-potable Water 180 Lead 1.00 ug/L Pb EPA 6020 Non-potable Water 180 Lead 1.00 ug/L Pb Diss. EPA 200.8 Drinking and Non-potable Water 180 Lead, Dissolved 1.00 ug/L Pb Diss. EPA 6020 Non-potable Water 180 Lead, Dissolved 1.00 ug/L Li EPA 200.8 Drinking and Non-potable Water 180 Lithium 20.0 ug/L Li EPA 6020 Non-potable Water 180 Lithium 20.0 ug/L

Li Diss. EPA 6020 Non-potable Water 180 Lithium, Dissolved 20.0 ug/L Mg/CaCO3 EPA 200.7 Drinking and Non-potable Water 180 Mg as CaCO3 5.0 mg/L Mg/CaCO3 EPA 6010B Non-potable Water 180 Mg as CaCO3 5.0 mg/L Mg/CaCO3 Diss. EPA 6010B Non-potable Water 180 Mg as CaCO3, Dissolved 5.0 mg/L



Limit Units Mg EPA 200.7 Drinking and Non-potable Water 180 Magnesium 2.00 mg/L Mg EPA 6010B Non-potable Water 180 Magnesium 2.00 mg/L Mg Diss. EPA 200.7 Drinking and Non-potable Water 180 Magnesium, Dissolved 2.00 mg/L Mg Diss. EPA 6010B Non-potable Water 180 Magnesium, Dissolved 2.00 mg/L Mn EPA 200.8 Drinking and Non-potable Water 180 Manganese 10.0 ug/L Mn EPA 6020 Non-potable Water 180 Manganese 10.0 ug/L Mn Diss. EPA 6020 Non-potable Water 180 Manganese, Dissolved 10.0 ug/L Hg EPA 245.2 Drinking and Non-potable Water 28 Mercury 0.010 ug/L Hg Diss. EPA 245.2 Drinking and Non-potable Water 28 Mercury, Dissolved 0.010 ug/L Hg Methyl EPA 1630 Non-potable Water 180 Mercury, Methyl 0.050 ng/L Hg Methyl, Diss. EPA 1630 Non-potable Water 180 Mercury, Methyl Dissolved 0.050 ng/L Hg Ultra Low Level EPA 1631 Drinking and Non-potable Water 90 Mercury 0.400 ng/L Hg Diss. Ultra Low Level EPA 1631 Drinking and Non-potable Water 90 Mercury, Dissolved 0.400 ng/L Mo EPA 200.8 Drinking and Non-potable Water 180 Molybdenum 1.00 ug/L

Mo EPA 6020 Non-potable Water 180 Molybdenum 1.00 ug/L Mo Diss. EPA 6020 Non-potable Water 180 Molybdenum, Dissolved 1.00 ug/L Ni EPA 200.8 Drinking Water 180 Nickel 10.0 ug/L Non-potable Water 180 Nickel 1.00 ug/L



Limit Units Ni EPA 6020 Non-potable Water 180 Nickel 1.00 ug/L Ni Diss. EPA 6020 Non-potable Water 180 Nickel, Dissolved 1.00 ug/L K EPA 200.7 Drinking and Non-potable Water 180 Potassium 0.50 mg/L K EPA 6010B Non-potable Water 180 Potassium 0.50 mg/L K Diss. EPA 200.7 Drinking and Non-potable Water 180 Potassium, Dissolved 0.50 mg/L K Diss. EPA 6010B Non-potable Water 180 Potassium, Dissolved 0.50 mg/L

Se EPA 200.8 Drinking Water 180 Selenium 5.00 ug/L Non-potable Water 180 Selenium 1.00 ug/L

Se EPA 6020 Non-potable Water 180 Selenium 1.00 ug/L Se Diss. EPA 200.8 Drinking Water 180 Selenium, Dissolved 5.00 ug/L Non-potable Water 180 Selenium, Dissolved 1.00 ug/L Se Diss. EPA 6020 Non-potable Water 180 Selenium, Dissolved 1.00 ug/L

Ag EPA 200.8 Drinking Water 180 Silver 5.00 ug/L Non-potable Water 180 Silver 0.20 ug/L Ag EPA 6020 Non-potable Water 180 Silver 0.20 ug/L

Ag Diss. EPA 200.8 Drinking Water 180 Silver, Dissolved 5.00 ug/L Non-potable Water 180 Silver, Dissolved 0.20 ug/L Ag Diss. EPA 6020 Non-potable Water 180 Silver, Dissolved 0.20 ug/L Na EPA 200.7 Drinking and Non-potable Water 180 Sodium 0.50 mg/L



Limit Units Na EPA 6010B Non-potable Water 180 Sodium 0.50 mg/L Na Diss. EPA 200.7 Drinking and Non-potable Water 180 Sodium, Dissolved 0.50 mg/L Na Diss. EPA 6010B Non-potable Water 180 Sodium, Dissolved 0.50 mg/L Sr EPA 200.8 Drinking Water 180 Strontium 2.00 ug/L Non-potable Water 180 Strontium 5.00 ug/L Sr EPA 6020 Non-potable Water 180 Strontium 5.00 ug/L Sr Diss. EPA 6020 Non-potable Water 180 Strontium, Dissolved 5.00 ug/L Tl EPA 200.8 Drinking and Non-potable Water 180 Thallium 1.00 ug/L Tl EPA 6020 Non-potable Water 180 Thallium 1.00 ug/L Tl Diss. EPA 6020 Non-potable Water 180 Thallium 1.00 ug/L Sn EPA 200.8 Drinking and Non-potable Water 180 Tin 5.00 ug/L Sn EPA 6020 Non-potable Water 180 Tin 5.00 ug/L Sn Diss. EPA 6020 Non-potable Water 180 Tin, Dissolved 5.00 ug/L Ti EPA 200.8 Drinking and Non-potable Water 180 Titanium 5.00 ug/L Ti EPA 6020 Non-potable Water 180 Titanium 5.00 ug/L Ti Diss. EPA 6020 Non-potable Water 180 Titanium, Dissolved 5.00 ug/L U EPA 200.8 Drinking and Non-potable Water 180 Uranium 0.67 pCi/L V EPA 200.8 Drinking and Non-potable Water 180 Vanadium 2.00 ug/L



Limit Units V EPA 6020 Non-potable Water 180 Vanadium 2.00 ug/L V Diss. EPA 6020 Non-potable Water 180 Vanadium, Dissolved 2.00 ug/L Zn EPA 200.8 Drinking Water 180 Zinc 20.0 ug/L Non-potable Water 180 Zinc 10.0 ug/L Zn EPA 6020 Non-potable Water 180 Zinc 10.0 ug/L Zn Diss. EPA 6020 Non-potable Water 180 Zinc, Dissolved 10.0 ug/L


SAMPLE CONTAINERS

Organic Sample Containers:

40mL Clear Glass Vial, Pre-preserved with 25 mg of Ascorbic Acid; (Chlorinated water sources); Preserved at collection with three drops of 1:1 Hydrochloric Acid

40mL Clear Glass Vial, Pre-preserved with 0.5mL of Hydrochloric Acid; (Non-chlorinated water sources)


40mL Clear Glass Vial; Pre-preserved with 3mg of Sodium Thiosulfate

40mL Clear Glass Vial; Pre-preserved with 1.2mL of Monochloro Acetic Acid and 3.2 mg of Sodium Thiosulfate


40mL Amber Glass Vial; Pre-preserved with 4 mg of Sodium Thiosulfate

250mL Amber Glass Jar; Pre-preserved with 2.5 mL of Ammonium Chloride


250mL Amber Glass Jar; Pre-preserved with 12.5 mg of Sodium Sulfite

1L Amber Glass Bottle, Pre-preserved with 40-50mg of Sodium Sulfite; Preserved at collection with 3 ml of 1:1 Hydrochloric Acid


1L Amber Glass Bottle, Unpreserved

1L Amber Glass Bottle; Preserved at collection with 3mL of Hydrochloric Acid


250mL Clear Glass Tall Jar; Unpreserved

250mL HDPE Bottle, Unpreserved; PFC only


Inorganic Sample Containers:

Radiation Sample Containers:

4L HDPE Jug; Unpreserved

47mm Glass Fiber Filter


4L LDPE Cubitainer; Unpreserved


General Chemistry Sample Containers:

1L Amber Glass Bottle; Unpreserved

47mm Glass Fiber Filter


125mL HDPE Bottle; Pre-preserved with 2.5 mL of 10% Sulfuric Acid

125mL HDPE Bottle; Unpreserved Nitrate


125mL HDPE Bottle; Fluoride Only

500mL HDPE Bottle, Preserved at collection with 20mL – 2.5N Sodium Hydroxide; Cyanide


250mL HDPE Bottle, Preserved at collection with 5mL – 10% Sulfuric Acid; Nutrient Parameters

125mL HDPE Bottle; General Chemistry Parameters


250mL HDPE Bottle; General Chemistry Parameters

1L HDPE Bottle; General Chemistry Parameters


Microbiology Sample Containers:

150mL HDPE (Sterile) Bottle, Pre-preserved with 10-35mg Sodium Thiosulfate; Microbiological Parameters


Microbiology sampling instructions

Please fill container between the 120ml and the 100ml lines.

There are TWO lines on the sample container, one at 100ml level and one at 120ml level. The water level must be filled between the 100ml and 120ml lines. A minimum of 100ml is needed to meet the analytical requirements and less than 120ml to allow for adequate headspace for proper mixing. If there is too little or too much water, this

will result in the sample being rejected and you will be required to recollect the sample.

Metals Sample Containers:

Overfilled

Filled correctly

Underfilled


120mL HDPE Bottle, Preserved at collection with 2.5mL – 25% Hydrochloric acid & 25% Nitric Acid solution; Mercury

250mL HDPE Bottle, Preserved at collection with 2.5 mL – 20% Nitric Acid; Metals Parameters

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