cheminform abstract: diels-alder reactions of chiral 1,3-dienes

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1997 fused pyrrole derivatives fused pyrrole derivatives R 0160 17 - 100 Diels-Alder Reactions of Chiral 1,3-Dienes. The influence of the OH-protecting group in (I) is investigated in the title reaction under different reaction conditions. The initial Diels- Alder adducts cannot be isolated as they rearrange spontaneously to the isoindolones (III) and (IV). Mechanistical aspects are discussed in detail. — (CRISP, G. T.; GEBAUER, M. G.; J. Org. Chem. 61 (1996) 24, 8425-8431; Dep. Chem., Univ. Adelaide, Adelaide, S. Aust. 5005, Australia; EN) 1

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1997 fused pyrrole derivatives

fused pyrrole derivativesR 0160

17 - 100Diels-Alder Reactions of Chiral 1,3-Dienes. — The influence of theOH-protecting group in (I) is investigated in the title reaction under differentreaction conditions. The initial Diels- Alder adducts cannot be isolated asthey rearrange spontaneously to the isoindolones (III) and (IV). Mechanisticalaspects are discussed in detail. — (CRISP, G. T.; GEBAUER, M. G.; J. Org.Chem. 61 (1996) 24, 8425-8431; Dep. Chem., Univ. Adelaide, Adelaide, S.Aust. 5005, Australia; EN)

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