boilers of thermal power plants
TRANSCRIPT
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Boilers Of Thermal Power
PlantsDebanjan Basak
CESC Ltd
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Points of Discussion
Thermodynamic Cycles Discussion on Sub and Supercritical
Boilers
Performance Indicators and Benchmarks
o a ower a on Constructional and design features of
Boilers
Boiler Auxiliaries
Losses and performance optimisation
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First Law of Thermodynamics
Energy cannot be created nor destroyed.
Therefore, the total energy of the universe
is a constant.
nergy can, owever, e conver e rom
one form to another or transferred from a
system to the surroundings or vice versa.
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Spontaneous Processes
Spontaneous processes
are those that can
proceed without any
outside intervention.
The gas in vessel B will
spontaneously effuse into
vesselA, but once the
gas is in both vessels, it
will not spontaneously
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Spontaneous Processes
Processes that are
spontaneous in one
direction are
nonspontaneous in
the reverse direction.
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Spontaneous Processes
Processes that are spontaneous at one
temperature may be nonspontaneous at other
temperatures.
Above 0 C it is spontaneous for ice to melt.
Below 0 C the reverse process is spontaneous.
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Reversible Processes
In a reversible processthe system changes insuch a way that thesystem andsurroundings can beput back in their original
reversing the process.
Changes areinfinitesimally small in
a reversible process.
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Irreversible Processes
Irreversible processes cannot be undone by
exactly reversing the change to the system.
All Spontaneous processes are irreversible.
All Real processes are irreversible.
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Entropy
Entropy (S) is a term coined by Rudolph
Clausius in the 19th century.
Clausius was convinced of the significance
temperature at which it is delivered,
q
T
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Entropy is used to define the unavailable
energy in a system.
Entropy defines the relative ability of one
system to act on an other. As things move
toward a lower energy level, where one is
less able to act u on the surroundin s theentropy is said to increase.
For the universe as a whole the entropy is
increasing!
Entropy is not conserved like energy!
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Entropy
Entropy can be thought of as a measure of
the randomness of a system.
It is related to the various modes of motion
.
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Entropy
Like total energy, E, and enthalpy, H,
entropy is a state function.
Therefore,
= final initial
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Second Law of
ThermodynamicsThe second law of thermodynamics:
The entropy of the universe does not
change for reversible processes and
Reversible (ideal):
Irreversible (real, spontaneous):
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Entropy on the Molecular Scale
Molecules exhibit several types of motion: Translational: Movement of the entire molecule from
one place to another.
Vibrational: Periodic motion of atoms within a molecule.
rotation about bonds.
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Entropy on the Molecular Scale
Each thermodynamic state has a specific number ofmicrostates, W, associated with it.
Entropy is
S = k lnW
where k is the Boltzmann constant, 1.38 10 23 J/K.
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Entropy on the Molecular Scale
The number of microstates and,
therefore, the entropy tends to increase
with increases in
. Volume (gases).
The number of independently moving
molecules.
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Entropy and Physical States
Entropy increases with
the freedom of motion
of molecules.
Therefore,
S(g) > S(l) > S(s)
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Solutions
Dissolution of a solid:
Ions have more entropy
(more states)
But,
Some water molecules
have less entropy
(they are grouped
around ions).
Usually, there is an overall increase in S.(The exception is very highly charged ions that
make a lot of water molecules align around them.)
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Entropy Changes
In general, entropy
increases when
Gases are formed from
qu s an so s.
Liquids or solutions are
formed from solids.
The number of gas
molecules increases.
The number of moles
increases.
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Third Law of Thermodynamics
The entropy of a pure crystall inesubstance at absolute zero is 0.
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Standard Entropies
Larger and more complex molecules have
greater entropies.
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Link S and H: Phase changes
A phase change is isothermal
(no change in T).
Entropysystem
For water:
Hfusion = 6 kJ/mol
Hvap = 41 kJ/mol
If we do this reversibly: Ssurr= Ssys
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Change in entropy
> 0
irreversible
Change in entropy
= 0
reversible
Change in entropy
< 0
impossible
process process process
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When a liquid evaporates its go
through a process where
the liquid heats up to the evaporation
temperature
the liquid evaporate at the vaporation
from fluid to gas
the vapor heats above the vaporation
temperature - superheating
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The heat transferred to a substance
when temperature changes is oftenreferred to as sensible heat.
The heat required for changing state as
evaporation is referred to as latent heat
of evaporation.
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Enthalpy of a system is defined as the mass of the system - m -
multiplied by the specific enthalpy - h - of the system and can
be expressed as:
H = m h (1)where
H = enthalpy (kJ)
m = mass (kg)
h = specific enthalpy (kJ/kg)
Specific Enthalpy
Specific enthalpy is a property of the fluid and can be expressed
as:h = u + p v (2)
where
u = internal energy (kJ/kg)
p = absolute pressure (N/m2)
v = specific volume (m3/kg)
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Dryness Fraction of Saturated Steam (x or q)
It is a measure of quality of wet steam.It is the ratio of the mass of dry steam (mg) to the mass of total wet
steam (mg+mf), where mf is the mass of water vapor.
X= mg
mg + mf
Quality of Steam
It is the representation of dryness fraction in
percentage: Quality of Steam = x X 100
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Steam Quality
Steam should be available at the point of
use:
At the correct temperature and pressure
Free from air and incondensable gases
CleanDry
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Advantages of Superheated Steam
At a given pressure, its capacity to do the work will be comparatively
higher.
It improves the thermal efficiency of boilers and prime movers
It is economical and prevents condensation in case of Steam turbines
Rise in Superheated temperature poses problems in lubrication
Initial cost is more and depreciation is higher
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Carnot Cycle
Most efficient cycleoperating betweentwo heat sources
Practically impossible
cu y n en ng econdensation process
High energyconsumption forpumping /compression
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Rankine Cycle
Practical Carnot cyclewith much lessefficiency
Pump power is much
turbine output (within1%)
Efficiency limited forlower steam inlet
temperature
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Rankine Cycle
Process 1-2: Pump Work
Process 2-3: Sensible
and latent heat addition in
the boiler at constant
Process 3-4: Expansion
in steam turbine
Process 4-1:
condensation of the
steam in condenser
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Rankine cycle with Reheat
Average temp of heataddition increaseswith higher pressure
Restricted for
Reheating theexpanded steam toimprove efficiency
Exit Dryness Fractionimproved
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Rankine cycle with Reheat and
Regeneration Most commonly used
in power plant
Bled steam is utilised
to exchange heat
before being cooled
at the condenser
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Steam Condition Vs Design efficiency
Steam Pr (Bar) Steam Temp
(0C)
Reheat Steam
Temp (0C)
Design
Efficiency (%)
Size of set
(MW)
41.4 462 27.5 30
89.1 510 30.5 60
103.4 566 33.7 100
. .162 566 538 37.3 200
158.6 566 566 37.7 275
158.6 566 566 38.4 550
241.3 593 566 39.0 375
158.6 566 566 39.25 500
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Heat Rate Improvement
Parameters at Turbine Inlet(bar/oC / oC)
% Improvement In StationHeat Rate
170 / 538 / 538 Base
170 / 538 / 565 0.5%
170 / 565 / 565 1.3%
246 / 538 / 538 1.6%
246 / 538 / 565 2.1%
246 / 565 / 565 3.0%
246 / 565 / 598 3.6%
306 / 598 / 598 5.0%
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Steam cycle theory and constraints
Higher the size of plant, lower is the capital cost
per MW and higher is the plant efficiency
The terminal steam condition tend to increase
with the size of plant
Limitation in metallurgy is the constraints for
higher terminal condition and hence efficiency
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Heat addition-Sensible Heat
The sensible heat is mostlyadded in the feed water
heaters and the economisers
The cycle operates between
100 bar (310.9610C saturation
.saturation temp)
Sensible heat at A =101 KJ/Kg
Sensible heat at B =1408
KJ/Kg
Sensible heat added = 1307KJ/Kg
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Variation of sensible heat with Pressure
Absolute
pressure
(bar)
Saturation
Temperature
(C )Sensible
Heat
( kj / kg )
. .
100 311.0 1408.0
150 342.1 1611.0
200 365.7 1826.5
221.2 374.15 2107.4
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Heat addition - Latent Heat
The latent heat is mostly addedin the water wall tubes of theboiler
Latent heat diminishes withpressure and is zero at critical
pressure The latent heat is added from B
to C at constant temp
Entropy at C is 5.6198 kj/KgK
Entropy at B is 3.3605 kj/KgK
Latent heat added = 1319.7KJ/Kg
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Absolute
pressure
(bar)
Saturation
Temperatur
e
(C )
Latent
Heat
( kj / kg )
50 263.9 1639.7
Variation of Latent heat with Pressure
100 311.0 1319.7
150 342.1 1004.0
200 365.7 591.9
221.2 374.15 0
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Heat addition - Super heat
The Super heat is mostlyadded in the superheatertubes of the boiler arisingout from the drum
from C to D at constantpressure
The amount of superheatcan be found by deducting
the total heat of Point Cfrom total heat of point D
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Variation of Superheat with Pressure
Absolute pressure
(bar)
Superheat required
( kj / kg )
50 800.9
100 821.5
150 885.4
200 1033.2
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Useful Heat
Useful heat : Total Heat Rejected Heat
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Effect of Back Pressure
Improvement of back pressure induces
certain losses too:
Increase in the CW pumping power
Higher Leaving loss
Reduced condensate temperature
Increased wetness of the steam
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Back pressure correction curve
Back Pressure in mb
Heat
cons
Optimum Back
pressure
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Causes for departure of back pressure
CW inlet temperature different from designBalance between increase T/A output to extra pumping power required
CW quantity flowing through the condenser is incorrectLow across temperature requires closing of the valves otherwise will result
in under coolin of condensate. Flow to be o timised to et desired across
Fouled tube plateIf the CW across rise is independent of increase of flow then it is assumed
that the tube plates are fouled with debris
Dirty tubesCondenser back pressure is independent of increase of flow
Air ingress into the system under vacuumIncrease of TTD. More air ejection improves the vacuum.
Helium leak testing may be employed
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Calculation of Ideal EfficiencyBasic Rankine Cycle between 100bar and 30 mbar
Total Heat supplied: 2626.7.3 kj/Kg
Total Heat rejected, [T X (S2-S1))]: 1917.2 kj/Kg
Useful heat : Total Heat Rejected heat
Thermal Efficiency = 27.01 %
The Highest possible efficiency for a basic
Rankine cycle with steam at 100 bar (abs) and dry
saturated condition and back pressure at 30mbar
is 27.01 %
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Ideal Efficiency of
Rankine Cycle with superheat
Total Heat supplied: 3438.3 kj/Kg
Total Heat rejected, [T X (S2-S1))]:
1917.2 kj/Kg
Useful heat : Total Heat
Thermal Efficiency = 44.23 %
The Efficiency of basic Rankine
cycle can be improved with
superheat
The scope however is limited dueto materials to withstand high
temperature
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Ideal Efficiency of
Rankine Cycle with Reheat
The same 100 bar cycle with
reheat
At pressure 20 bar after
expansion in the turbine, the
566 0C
The steam expands to the
condenser pressure in IP/LP
turbine
The efficiency of this cycle is46.09%
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Ideal Efficiency of
Rankine Cycle with Reheat and regeneration
Sensible heat addition from
M to B
Latent heat and superheat
addition as before
.Kj/Kg
Heat rejected = 1192.2
Kj/Kg
Thermal Efficiency =
51.4%
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Increasing the maximum operating temperature can also increaseefficiency, as this takes steam to the superheated region, whichincreases the area and also enhances the quality of steam exiting theturbine.
The maximum temperature is limited by the metallurgicalquality of the pipes of boiler.
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Advantages of Reheat CycleIncreases the dryness fraction of steam
Reduces fuel consumption by 4 to 5%Reduces steam flow with corresponding reductions
in boiler, turbine and feed heating equipments
capacity.
Reduction in exhaust blade erosion of turbine
Reduction in steam volume and heat to the
condenser is reduced by 7 to 8%.
Condenser size and cooling water flow also
reducedSize of the LP turbine blades is reduced because
sp. Steam volume is reduced by 8%
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Disadvantages of Reheat Cycle
Cost increases for additional pipes and
reheaters
Greater floor space required for longer
turbine
At light loads, steam passing through the
last blade rows are highly superheated if
same reheat is maintained
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Boiler: Definition as per IBR
Boilermeans any closed vessel
exceeding 22.75 litres (five gallons)
in ca acit which is used ex ressl
for generating steam under pressure
and includes any mounting or other
fitting attached to such vessel, which
is wholly or partly under pressurewhen steam is shut off:
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Classification of PF Boilers
Based on Operating
Pressure
Super-CriticalUltra-Super-
Critical
Sub-Critical
u - r ca : < Critical Pr.221.2 Bar
Super critical: > Critical
Pr. 221.2 Bar
Ultra-super critical >Pr > 300 Barand Temp > 1100 0 F or 593 0C 4
THERMAL EFFICIENCY IMPROVEMENT
169 246 310
STEAM PRESSURE (kg/cm2)
Base
%
1.8
0.8
0.8
1.0
0.8
5380C/5380C
5380C/5660C
5660C/5660C
5660C/5930C
6000C/6000C
EfficiencyIncrease
%
1.0
5660C/5660C
Super cri tical and ul tra supercritical conditions
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Super cri tical and ul tra supercritical conditions
Critical Conditions
Temperature -374.150C
Pressure-225.56kg/cm2
Ultra super critical condit ions
Temperature above 5930C
Pressure above 306kg/cm2
Improvement of thermal efficiency
Increasing the steam temperature ( increases 0.31%
every 100C of increase of main steam temperature &0.24% every 100C of increase of reheat steam
temperature )
Increasing in the steam pressure ( increases 0.1%
increase with increase of 10 bar pressure)
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Based on Types of Circulation
Natural Circulation Boiler
Classification of PF Boilers
Assisted circulation Boiler
Once through Boiler
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Circulation in Boiler
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Natural Circulation The water flows from the drum vide down comer pipes
and returns through riser tubes after being heated in thefurnace
The static head difference generated due to densitydifference of the steam and water mixture in the risertubes and water in the down comer is the driving force
for the circulation. This is called Thermo-Siphon The steam and water mixture is separated in the boiler
drum
As the pressure rises, the difference between thedensities tend to decrease and Natural circulation head
cannot overcome the frictional resistance Higher the heat input, higher should be the flow rate
through the tubes to avoid overheating
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Circulation Quantity VS Steam Produced
End Point
The circulation increases
with increase in Heat inputLosses due to friction from
high specific volume is
higher than the pressure
differential
Steam Produced
Total
Circulation
Quantity
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Circulation Ratio
Circulation ratio is the weight of water fed to thesteam generating circuits to the steam actuallygenerated
Kg. of water
Circulation ratio =
Kg. of Steam
Circulation ratio depends upon operatingpressure, available circulation head and flowresistance
For sub critical boilers, circulation ratio variesfrom 10-30
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Relationship
of density of
water-steam
withoperating
pressure
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Forced circulation (Once through)
No drum to separate change of state
Once through boiler can operate at anypressure below or above critical pressure
to the load and hence a minimum flow of25-30 % is needed always by recirculationpumps or by dumping
Spirally wound tube to average the heatinput per tube
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Once Through Boilers
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Based on Types of firing
Wall fired: Front / Opposed
Classification of PF Boilers
Corner fired: Tangential
Down-shot fired : Single / Double
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Wall Firing (TGS Boiler)
The stability is imposed by a combination ofsecondary of air swirl and a flow reversal in theprimary air by an impeller
The refractory quarl though acts as a radiantheat source but its major role is aerodynamic
flow stabiliser 80 % combustion air through secondary air and
20 % through primary air
Modern design incorporate axial swirl whichconsumes less fan power, intimate mixing and
better control
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Down shot Firing (BBGS Boiler)
Adopted for burning of low volatile coal < 16% (Anthracite)
Long particle residence time for completecombustion
The coal is fed downwards from the archalong with about 30-40 % combustion air
The secondary air and tertiary air isdistributed to form the flame characteristicsand shape
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Tangential Firing (SGS / BBGS#3 Boiler)
A turbulent zone is created in the center of thefurnace by the turbulent flames fired from thecorners towards the imaginary circle to which theflame path is tangent
of coal
The mixing of coal and air is obtained by theadmission of coal and air in alternate layers
There can be provisions for tilting of the burners for
super heater temperature control (not in SGS, available inBBGS #3)
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Our BoilersOur BoilersTitagarh Generating StationTitagarh Generating Station
Designed for Coal wi th
Calori fic Value 4500
Ash + Moisture 35.5%
Volatile Matter 25%
Fixed Carbon 39.5%
Southern Generating StationSouthern Generating Station
Designed for Coal wi th
Calori fic Value 3800
Ash + Moisture 44%
Volatile Matter 17%
Fixed Carbon 39%
BBGS Generating StationBBGS Generating Station
Designed for Coal wi th Calori fic Value 3850
Ash + Moisture 50%
Volatile Matter 15%
Fixed Carbon 32%
Front wall firinFront wall firin Down shot firinDown shot firin
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Heat Transfer Zones
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Heat Transfer Zones
The Furnace: High temperature gases ofcombustion is used for heating water and steam
with low to medium superheat
gases is used to heat steam with medium to high
superheat
Heat Recovery zone: Comparatively cool gasesexchange heat to feed water to saturation temperature or
with low superheat
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Types of Boiling
Sub-cooled water heating: Initial stage of heating, Water in contact with thetube evaporates-bulk fluid is below the saturation temp
Sub-cooled Nucleate Boiling: Formation and collapsing of bubbles due totransfer of latent heat
Nucleate boiling: Bulk of the liquid reaches to saturation temperature, bubbles, .
this stage (Water velocity 1.5-3 mps)
DNB (Departure from Nucleate boiling): Even higher heat flux will result incollapsing of bubble to form a layer of superheated steam on the tube face.
Breakdown of mode of heat transfer-leads to burn out of the tube to
overheating.
Film Boiling: Complete film of steam is formed at the solid liquid interface,results in reduction in heat transfer, High velocities of steam is required
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Types of Boiling
Log Heat
A-B: Water Heating
B-S: Sub cooled Nucleate Boiling
S-C: Nucleate Boiling
C-D: Onset of Film Boiling
F
C
D
Critical Heat Flux or
DNB
Log (Tsurface Tbulk)
Flux D-E: Unstable Film BoilingE-F: Stable Film Boiling
ES
A
B
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Furnace- Duty
Furnace to have suitable surface area to
reduce the temperature of the furnace gas
to a level acceptable to super heater
Adequate water circulation in the furnace
tubes to prevent overheating
To avoid flame impingement in the
opposite wall tubes
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Furnace- Duty
Width sufficient to accommodate all
burners at an acceptable pitching
Overall dimension to ensure optimum
To reduce the furnace temperature below
ash softening temp to avoid slagging
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Coal Vs Oil Fired Furnace
Average oil droplet burnout time is half to
that of coal
Coal particle require higher residence time
Sticky ash hinders wall tube heat
absorption hence higher surface area
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Furnace- Performance & Control
Operation procedures
Firing Pattern
Soot blowing
Excess airOther methods
Gas recirculation (GR) as in BBGS
Tilting burners for Corner fired boiler
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Furnace Construction
Basically two types Tangent wall tube: Tubes are arranged tangentially and the
skin casing is used to seal. The skin casing is supported from mainstays
Advanta e: Easy maintenance
Older design
Membrane wall tube: Tubes joined with fins to form a fullywelded structure, the membrane wall
Advantage: Minimum ingress of tramp air
The outer casing requires only heat shielding
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Super heaters and Re heaters
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Super heaters and Re heaters
Convective: The heat transfer is through convection and Heat absorption rate increaseswith the boiler output
Radiant: Radiant su er heaters receives heat throu h radiation onl
With increase load in the boiler, the heat absorption in the furnace surfacesis increased at a lesser rate hence, the radiant superheat decrease with
load
Combination Fairly flat superheat curve with wide range of load
Type of material, tube diameter, positioning in the furnace, gas temperature
zone, superheating surface etc. are important factors for designing a super
heater
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RE,SCALEARBITRARY
20 40 60 80 100
STEAM OUTPUT PERCENTAGE
A SUBSTANTIALLY UNIFORM FINALSTEAM TEMPERATURE OVER A RANGE OF OUTPUT CAN BE ATTAINED BY A SERIES
OF ARRANGEMENT OF RADIANT AND CONVECTION SUPERHEATER COMPONENT
STEAMTEMPERAT
STEAM TO IP TURBINE STEAM TO HP TURBINE
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PRIMARY
REHEATER
VERTICAL
PIMARY
SUPERHEATER
VERTICAL
PRIMARY
FINAL
REHEATER
FINAL
SUPER
HEATER
PLATEN
SUPERHEAER
STEAM
FROM
COMBUSTION
GASES
STEAMFROM DRUM
TO DRUM
FEED WATER
TO DRUM
FEED WATER
REHEATER
ECONOMISER
SUPERHEATER
ECONOMISER
FURNACE
AIR HEATER
GAS TO STACK
REHEATER PRIMARY
SUPERHEATER
AIR
COAL
TURBINE
BLOCK DIAGRAM SHOWING BOILER
ELEMENTS AND FLOWPATHS
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OXIDE
STEAM
WATERFOULING
GAS
FILM
BULK GAS
TEMPERATUE
TUBE
WALL
COMPOSITE TEMPERATURE DROP FROM GAS TO STEAM / WATER
THROUGH A BOILER TUBE WALL
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GAS
GAS
1025*C
568*C
1025*C
930*C
568*C
930*C
STEAM
COUNTER FLOW PARALLEL FLOW
492*C
492*C
Tin=447.4*c Tin=442.0*c
SUPER HEATER GAS AND STEAM TEMPERATURE
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General
Arrangement of
a 210 MW
-
boiler
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Typical section
of a Double
,250 MW Boiler
at BBGS,
CESC
Super heater temperature is affected by
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Super heater temperature is affected by
Load Excess Air
Feed Water temperature
Heating surface cleanliness
Burner operation
Burner tilt
Coal burnt
Super heater temperature control
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Super heater temperature control
Direct Attemperation / De super heaters Excess Air
Furnace division
Gas recirculation
Adjustment of burner tilt
Type pf burners
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Steam Separation and purity
Boiler operating below critical pressure needdrum to separate saturated steam from a
mixture of steam-water discharged by the boiler
tubes
Drum also serves as vessel for chemicaltreatment of water and storage of water
The drum sizing is done primarily to house the
separation equipment and should accommodate
the changes in water level with variation of load
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RWATER
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0.30
0.25
0.20
0.15
ATIO=
SILICACONTE
NTOFSTEAM
SILICACONTE
NTOFBOILER
0 1000 2000 3000 4000
.
0.05
0.00
STEAM DRUM PRESSURE IN , psi
DISTRIBUTION
EFFECT OF PRESSURE ON SILICA DISTRIBUTION RATIO
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Performance Indicators and
Benchmarkin
B h ki Obj i
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Benchmarking-Objectives
Benchmarking is
a continuous formal process of measuring,
understanding, and adapting
more e ec ve prac ces rom es - n-c assorganizations that lead to superior
performance.
Benchmarking is essential to
provide the best service to our customers.
B h ki B fit
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Benchmarking-Benefits
Improve our performance and organization
Learn about industry leaders and competitors
Determine what world-class performance is
Achieve breakthrough results
Improve customer satisfaction
Become the best in the business
St f b h ki
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Steps of benchmarking
What to benchmark
With whom to benchmark
Identification of potential improvement areas
based on benchmarkin .
Adoption of best practices for improvement
Monitor effectiveness of new practice
Modify practice as per requirement
Standardise practice
Key Benefits from Benchmarking at
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Key Benefits from Benchmarking at
CESC Ltd
Reduction in Annual overhaul time High pressure jet cleaning of boiler tubes
Operating at zero pressure differential of
Ammonia dosing system at ESP
Boiler Insulation survey
Destaging of Condensate Extraction Pump
Installation of SS-304 chutes at CHP
K P f I di t
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Key Performance Indicators
Cost of Generation Plant Load Factor (PLF)
Plant Availability Factor (PAF)
Loss In Production
Specific Coal Consumption
Specific Oil Consumption
Auxiliary Power Consumption
Environmental Emissions
No of Accidents Implementation of Quality and SHE systems
K M it i
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Key Monitoring
PF Sample analysis PA and PF flow distribution
Performance of Boiler feed pumps
Performance of Fans
Insulation survey of boiler casings
Thermographic assessment of valves
Reject analysis from pulverisers Helium leak test of condensers
Energy consumption of major axillaries
Physical inspection of fly ash
Measurement of boiler and air heater efficiency
Measurement of turbine efficiency
Fuel sampling and analysis from coal feeders
Introduction to Supercritical
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Technology
What is Supercritical Pressure ?
Critical point in water vapour cycle is a
thermod namic state where there is no clear
114
distinction between liquid and gaseous stateof water.
Water reaches to this state at a critical
pressure above 22.1 MPa and 374 oC.
What is Supercritical Pressure ?
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What is Supercritical Pressure ?
Critical point in water vapour cycle is athermodynamic state where there is no
clear distinction between liquid and
.
Water reaches to this state at a
crit ical pressure above 22.1 MPa and
374 oC.
R ki C l S b iti l U it
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Rankine Cycle Subcritical Unit
1 - 2 > CEP work
2 - 3 > LP Heating
3 - 4 > BFP work
4 - 5 > HP Heating
5 6 > Eco, WW
uper ea ng
7 8 > HPT Work8 9 > Reheating
9 10 > IPT Work
1011 > LPT Work
11 1 > Condensing
R ki C l S iti l U it
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Rankine Cycle Supercritical Unit
1 - 2 > CEP work
2 2s > Regeneration
2s - 3 > Boiler Superheating
>
4 5 > Reheating5 6 > IPT & LPT Expansion
6 1 > Condenser Heat rejection
VARIATION OF LATENT HEAT
WITH PRESSURE
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WITH PRESSURE
AbsoluteAbsolute
PressurePressure
(Bar)(Bar)
SaturationSaturation
TemperatureTemperature
((ooC)C)
LatentLatent
HeatHeat
(K J/Kg.)(K J/Kg.)
5050 264264 16401640
150150200200
221221
342342366366
374374
10041004592592
00
D t f N l t B il i
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Departure from Nucleate Boiling
Nucleate boiling is a type of boiling that takes place when the surface temp is hotterthan the saturated fluid temp by a certain amount but where heat flux is below the
critical heat flux. Nucleate boiling occurs when the surface temperature is higher than
the saturation temperature by between 40C to 300C.
YWATER
PRESSURE(ksc)
DENS
IT
STEAM
175 224
No Religious Attitude
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Supercritical Boiler Water Wall
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p
Rifle Tube And Smooth Tube
Natural Circulation Vs. Once
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Through System
Mixer Header
To HP
TurbineTo IP
Turbine
5340C
5710C
5690C
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From CRH Line
LTRH
LTSH
4430C
FRH
Platen
Heater
FSH
Separator
3260C
4230C
4730C
4620C
534 C5260C
3240C
From FRS Line
Boiler
Recirculation Pump
Economizer
Phase 1Economizer
Phase 2
Bottom Ring
Header
2830C
2800C
NRV
Feed water control
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Feed water control
In Drum type Boiler Feed water flowcontrol by Three element controller1.Drum level
2.Ms flow
3.Feed water flow. Drum less Boiler Feed water control by
1.Load demand
2.Water/Fuel ratio(7:1)
3.OHD(Over heat degree)
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Difference ofSubcritical(500MW) and
Su ercritical 660MW
COMPARISION OF SUPER CRITICAL & SUB CRITICAL
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DESCRIPTION SUPERCRITICAL
(660MW)
SUB-CRITICAL
(500MW)
Circulation Ratio 1 Once-thru=1
Assisted Circulation=3-4
Natural circulation= 7-8
Feed Water Flow Control -Water to Fuel Ratio
7:1
Three Element Control
-Feed Water Flow
-OHDR(22-35 OC)-Load Demand
-MS Flow-Drum Level
Latent Heat Addition Nil Heat addition more
Sp. Enthalpy Low More
Sp. Coal consumption Low High
Air flow, Dry flu gas loss Low High
Continue..
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DESCRIPTION SUPERCRITICA
L(660MW)
SUB-CRITICAL
(500MW)
Coal & Ash handling Low High
Aux. Power
Consumption
Low More
Overall Efficiency High
(40-42%)
Low
(36-37%)
Total heating surfacearea Reqd Low(84439m2)High
(71582m2)
Tube diameter Low High
Continue..
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DESCRIPTION SUPERCRITIC
AL(660MW)
SUB-
CRITICAL(500MW)
Material / Infrastructure
(Tonnage)
Low
7502 MT
High
9200 MT
Blow down loss Nil More
Water Consumption Less More
Advanced Supercritical Tube Materials
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p
(300 bar/6000c/6200c)
129
Material Comparison
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DescriptionDescription 660 MW660 MW 500 MW500 MWStructural SteelStructural Steel Alloy SteelAlloy Steel Carbon SteelCarbon Steel
Water wallWater wall T22T22 Carbon SteelCarbon Steel
SH CoilSH Coil T23, T91T23, T91 T11, T22T11, T22
RH CoilRH CoilT91,SuperT91,Super304 H304 H
T22,T22,T91,T11T91,T11
LTSHLTSH T12T12 T11T11
EconomizerEconomizer SA106SA106--CC Carbon SteelCarbon Steel
Welding Joints (Pressure Parts)Welding Joints (Pressure Parts) 42,000 Nos42,000 Nos 24,000 Nos24,000 Nos
Advantages of SC Technology
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Advantages of SC Technology
I ) Higher cycle efficiency meansPrimarily less fuel consumption
less per MW infrastructure investments
131
less auxiliary power consumption less water consumption
II ) Operational f lexibil ity
Better temp. control and load change flexibility
Shorter start-up time
More suitable for widely variable pressure operation
ECONOMY
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ECONOMY
Higher Efficiency (%)
Less fuel input.
Low capacity fuel handling system.
Low capacity ash handling system.
132
.
Approximate improvement in Cycle
Efficiency
Pressure increase : 0.005 % per bar
Temp increase : 0.011 % per deg K
Challenges of supercritical technology
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g p gy
Water chemistry is more stringent in super critical oncethrough boiler.
Metallurgical Challenges
More complex in erection due to spiral water wall.
losses in spiral water wall. Maintenance of tube leakage is difficult due to complex
design of water wall.
Ash sticking tendency is more in spiral water wall incomparison of vertical wall.
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CombustionCombustion
Combustion Basics
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Fuel
Combustion Stoichiometry
Air/Fuel Ratio
Air Pollutants from Combustion
5/8/2013 135Aerosol & Particulate Research Laboratory
Fuel
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q Gaseous Fuels
Natural gas
Refinery gas
q Liquid Fuels
Kerosene
Gasoline, diesel
Alcohol (Ethanol) Oil
q Solid Fuels
Coal (Anthracite, bituminous, subbituminous, lignite)
Wood
5/8/2013 136Aerosol & Particulate Research Laboratory
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Combust ion Stoichiometry
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q Combustion in Air (O2 = 21%, N2 = 79%)
22222 )78.3( NOHCONOHC mn
222224
78.32
)78.3(4
Nm
nOHm
nCONOm
nHC mn
222224 56.72)78.3(2 NOHCONOCH
2222266 35.2836)78.3(5.7 NOHCONOHC
1. What if the fuel contains O, S, Cl or other elements?
2 Is it better to use O2 or air?
Air-Fuel Ratio
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q Air -Fuel (AF) ratio
AF = m Air / m Fuel
Where: m air= mass of air in the feed mixture
m fuel = mass of fuel in the feed mixture
Fuel-Air ratio: FA = m Fuel /m Air = 1/AF
qAir -Fuel molal rat io
AFmole = nAir / nFuel
Where: nair= moles of air in the feed mixture
nfuel = moles of fuel in the feed mixture
What is the Air-Fuel ratio for stoichiometric combustion of
methane and benzene, respectively?
5/8/2013 139Aerosol & Particulate Research Laboratory
Air-Fuel Ratio
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q Rich mixture
- more fuel than necessary(AF) mixture < (AF)stoich
q Lean mixture
- more air than necessary
(AF) mixture > (AF)stoich
Most combustion systems operate under lean conditions.
Why is this advantageous?
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Formation of NOx and CO in Combustion
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q Thermal NOx
- Oxidation of atmospheric N2
at high temperatures
- Formation of thermal NOx is favorable at higher temperature
NOON 222
2221 NOONO
q Fuel NOx
- Oxidation of nitrogen compounds contained in the fuel
q Formation of CO
- Incomplete Combustion
- Dissociation of CO2 at high temperature
221
2 OCOCO
Air Pollutants from Combustion
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How do you explain the trends of the exhaust HCs, CO,
and NOx as a funct ion of air-fuel ratio?
How do you minimize NOx and CO emission?
Source: Seinfeld, J. Atmospheric Chemistry and Physics of Air Pollution.
Facilitators of Combustion
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Facilitators of Combustion
Time Temperature
Turbulence
Improper Combustion
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Improper Combustion
Excess Combustion Explosion
Tube burn out
Refractory damages
Incomplete Combustion Waste of fuel
Fall in steam parameters
Fall in thermal efficiency
Fall in thermal efficiency Generation of pollutants
Slagging
Generation of pollutants High FGET
Explosion
Main types of combustion
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Main types of combustion
Flame combustion Cyclone Combustion
Fluidised Bed combustion
Flame Combustion
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Flame Combustion
Burning of pulverized coal or coal dust in asuspended state inside the furnace.
Fine particles of coal are easily moved by the
flow of air and combustion products through the
section of the furnace Combustion takes place in a short time of the
presence of particles in the furnace ( 1 to 2 secs)
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Fluidized Bed Combustion
(FBC)
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(FBC)
Solid fuel ground to particle size of 16mm isplaced on a grate.
It is blown from beneath with an airflow at suchspeed that the fuel particles are lifted above the
The speed of the gas-air flow within the bed ishigher than above it
The finer and partially burnt particles rise to theupper portion of the bed where the flow velocity
decreases and are burnt completely.
Boiler Auxillaries
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o e u a es
Fans Blowers
Feed Pumps & Circulation Pumps
Airheaters Dampers and gates
Soot Blowers