crystal growth methods and mechanisms · primary defects are partial disloca- tions that exist in...

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Crystal Growth Methods and MechanismsIan McDougall

What makes a crystal?● Ordered● Exotic variations:

– Aperiodic

– Liquid

– Colloidal

– Time crystals

Why study crystallization?● Separation● Fouling● Characterization● Production

How do you grow a crystal?

● Solid growth– Annealing

– Gel growth

– Whiskering

● Melt growth– Freezing

– Kryopoulos, Czochralski, and Bridgman techniques

– Floating zone

● Growth from solution– Precipitation

● Vapor growth– Deposition– Vapor transport– Precipitation– Vapor-Liquid-Solid

● Other Considerations– Biomineralization– Naturally formed– Microgravity

Crystal Growth HabitsCaused by anisotropy of growth rates.

Hoppered and Dendritic GrowthCaused by concentration gradients across a surface.

Epitaxial and Spiral GrowthBurton-Cabrera-Frank theory

Proposed Research

Gold-functionalized Langmuir-Blodgett film

AFM observation of spiral growth

Questions?

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