cheminform abstract: the stereocontrolled synthesis of alkaloid (-)-actinidine
Post on 06-Jun-2016
217 Views
Preview:
TRANSCRIPT
1999 alkaloids
alkaloidsU 0600
14 - 256The Stereocontrolled Synthesis of Alkaloid (-)-Actinidine. — Thestereoselective synthesis of (-)-actinidine (XII) starting from (-)-citronellol(I) is presented involving the intramolecular [3 + 2] dipolar cycloaddi-tion of silylnitronates, generated in situ from nitro derivatives (VII) andbis(trimethylsilyl)acetamide (VIII), as a key step. — (STEPANOV, A. V.;LOZANOVA, A. V.; VESELOVSKY, V. V.; Izv. Akad. Nauk, Ser. Khim.(1998) 11, 2357-2362; Inst. org. khim. im. Zelinskogo Ross. Akad. nauk,Moskva 117913, Russia; RU)
1
top related