cheminform abstract: the stereocontrolled synthesis of alkaloid (-)-actinidine

1999 alkaloids alkaloids U 0600 14 - 256 The Stereocontrolled Synthesis of Alkaloid (-)-Actinidine. — The stereoselective synthesis of (-)-actinidine (XII) starting from (-)-citronellol (I) is presented involving the intramolecular [3 + 2] dipolar cycloaddi- tion of silylnitronates, generated in situ from nitro derivatives (VII) and bis(trimethylsilyl)acetamide (VIII), as a key step. — (STEPANOV, A. V.; LOZANOVA, A. V.; VESELOVSKY, V. V.; Izv. Akad. Nauk, Ser. Khim. (1998) 11, 2357-2362; Inst. org. khim. im. Zelinskogo Ross. Akad. nauk, Moskva 117913, Russia; RU) 1

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Page 1: ChemInform Abstract: The Stereocontrolled Synthesis of Alkaloid (-)-Actinidine

1999 alkaloids

alkaloidsU 0600

14 - 256The Stereocontrolled Synthesis of Alkaloid (-)-Actinidine. — Thestereoselective synthesis of (-)-actinidine (XII) starting from (-)-citronellol(I) is presented involving the intramolecular [3 + 2] dipolar cycloaddi-tion of silylnitronates, generated in situ from nitro derivatives (VII) andbis(trimethylsilyl)acetamide (VIII), as a key step. — (STEPANOV, A. V.;LOZANOVA, A. V.; VESELOVSKY, V. V.; Izv. Akad. Nauk, Ser. Khim.(1998) 11, 2357-2362; Inst. org. khim. im. Zelinskogo Ross. Akad. nauk,Moskva 117913, Russia; RU)

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