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Centre for Applied ChemistryCentral University of Jharkhand, Ranchi

5 Year IntegratedM.c. in Applied Chemistry !"#$# % $5

&atch'(Revised

)etailed Co*rse tr*ct*re !Revised'

1

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Centre for Applied ChemistryCentral University of Jharkhand, Ranchi

5 Year IntegratedM.c. in Applied Chemistry !"#$# % $5

&atch'(Revised

)etailed Co*rse tr*ct*re !Revised'

+M++R-I +M++R-II

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1 General Biology-I 3+0+0 3 1 General Biology-II 3+0+0 3

2 General Physics-I 3+0+0 3 2 General Physics-II 3+0+0 3

3 General Chemistry-I 3+0+0 3 3 General Mathematics-II 3+0+0 3

4 General Mathematics -I 3+0+0 3 4 General Chemistry-II 3+0+0 3

5Humanities !ocial!ciences

2+0+0 2 5 "iterature 2+0+0 2

# $n%ironmental !cience 2+0+0 2 #Com&uter Programming 'ata !tructure "a(oratory

3+0+2 5

) Physics "a(oratory-I 0+0+3 3 ) Chemistry "a(oratory-I 0+0+3 3* Biology "a(oratory-I 0+0+3 3

4A1 CR+)I "" 4A1 CR+)I ""

+M++R-III +M++R-I

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1 Mathematics or chemistry 3+1+0 4 1 !ymmetry Grou& ,heory 3+1+0 4

2 uantum Chemistry-I 3+1+0 4 2 !tatistical Mechanics 3+1+0 43 .rganic chemistry-I 3+1+0 4 3 Physical Chemistry-I 3+1+0 4

4 Inorganic chemistry-I 3+1+0 4 4 Inorganic chemistry-II 3+1+0 4

5Chemistry "a(oratory-II/.GIC

0+0+3 3 5Chemistry "a(oratory-III/PH!IC"

0+0+3 3

2

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#Chemistry "a(oratory-II/I.GIC

0+0+3 3 *Materials $lectronics"a(oratory

0+0+3 3

!3h4A1 CR+)I22

4A1 CR+)I 22

+M++R- !+lective papers only' C6C +M++R-I

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&a&ers loate (y thecentre an other 2&a&ers rom othercentres6schools

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1 nalytical chemistry 3+1+0 4 1Photochemistry eaction'ynamics

3+1+0 4

2 $n%ironmental Chemistry 3+1+0 4 2 .rganic !&ectrosco&y 3+1+0 43 Materials chemistry 3+1+0 4 3 .rganic Chemistry-II 3+1+0 4

4 Chemistry in e%eryay lie 3+1+0 4 4 Biomolecular "a(oratory 0+0+3 35

7ater &ollution anremeiation

3+1+0 4 5 Pro8ect 9or: 0+0+* *

# Heterocyclic Chemistry 3+1+0 4

4A1 CR+)I24

4A1 CR+)I 23

otal credit!s' to &e earned till end of 7thsemester 8 $95

+M++R-II +M++R-III

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1anomaterials- !ynthesis;Characterisation Pro&erties

3+1+0 4 1

+lectives:/1&&lie $lectrochemistry/2ano-Chemistry Green,echnology

3+1+0 4

2.rganic Photochemistry

molecular earrngements3+1+0 4 2

Moern ,echni

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/4o%el synthetic strategyin organic chemistry

5PG la(-I /&&lie InorganicChemistry "a(

3+1+0 4 5PG la(-III /&&lie PhysicalChemistry "a(

0+0+* 4

#PG la(-II /&&lie .rganicChemistry "a(

0+0+4 4 #PG la(-I> /&&lieInustrial Chemistry "a(

0+0+* 4

4A1 CR+)I 24

4A1 CR+)I 24

+M++R-I; +M++R-;

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1

+lectives:/1Chemistry o aturalProucts/2Inustrial eactions earrangements

3+1+0

4 1?nit .&eration in ChemicalInustry

3+1+0 4

2

+lectives:/1%ance =uel,echnology/2Inustrial Materials

3+1+0

4 2Pollution Control Inustrial 7aste 7aterManagement@

3+1+0 4

3

Molecular !imulation

Chem-Inormatics

3+1+

0 4

3Pro8ect 9or:;'I!!$,,I. %i%a%oce

1#4 Corrosion !cience

3+1+0

4

5PG la(-> /&&lie InustrialChemistry "a(

0+0+*

4

# P.A$C,6!$MI 4

4A1 CR+)I24

4A1 CR+)I 24

otal credit to &e earned till end of $#thsemester 8 "9$

4

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$st < "nd emester

+M++R-I +M++R-II

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1 Mathematics-I 3+1+0 4 1 Mathematics-II 3+1+0 4

2 Introuctory &hysics-I 3+1+0 4 2 Introuctory &hysics-II 3+1+0 4

3 Princi&le o chemistry-I 3+0+0 3 3 Princi&le o chemistry-II 3+1+0 4

4=unamental o Com&uter C &rogramming 2+0+4 4 4 General Chemistry-I 3+1+0 4

5 $n%ironmental stuies 3+0+0 3 5 $nglish or communication 3+0+2 4

# Introuctory (iology 3+1+0 4 # Biology la( 0+0+2 2

)&&lie Chemistry la(-1/common or all

0+0+4 2 )&&lie Chemistry la(-2/common or all

0+0+4 2

* &&lie Physics la(-1 0+0+4 2 * &&lie Physics la(-2 0+0+4 2

4A1 CR+)I "7 4A1 CR+)I "7

5

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$st semester

=eneral Mathematics-I

e%ie9 o limits; continuity; an ierentia(ility@ Mean %alue theorem; ,aylors ,heorem;Maima an Minima@ iemann integrals; =unamental theorem o Calculus; Im&ro&er

integrals; a&&lications to area; %olume@Con%ergence o seolumes 1 an 2; 2neition; 7iley; 1F*0@

3@ A@ !te9artD Calculus; 5theition; ,homson; 2003@

4. Differential Calculus by Shanti Narain

5@ Integral Calculus (y !hanti arain#@ 'ierential $

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systems@ ,he ieal solution; %a&our-li

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=eneral physics-I

>inetics: =orce; e9tonEs la9s o motion; =rames o reerence; Momentum;

Momentum o system o &articles; Conser%ation la9s; Center o mass; >aria(le masssystem; Collision in la(oratory an Center o mass system an !cattering@

Rigid &ody motion: igi (oy; Moment o inertia; igi (oy :inematics; igi (oy

:inetics; Motion o gyrosco&e

Mechanical properties of matter: Moulus o rigiity; PoissonEs ratio; relation

connecting ierent elastic-constants; >iscosity; PoiseulleEs e

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atural resources; rene9a(le an non-rene9a(le resources; natural resources an

associate &ro(lems; orest resources; 9ater resources; mineral resources; oo

resources; energy resources; lan resources; e

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=eneral 6iology -I

!mall an large molecules in (iologyD 7ater; aci; (ases; &H scale; (uers; unctional

grou&s; macromolecules an origin o lie@ Introuction to (iological &olymers /&rimary;seconary; tertiary an

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3hysics 1a& oratory

1@ Measurement o length an error analysis2@ Ma9ellEs neele3@ 'etermination o JgE (y (ar &enulum4@ 'etermination o JgE (y ree all5@ !hear moulus using ,orsional &enulum#@ oungEs moulus /Bening o Beam)@ Moment o Inertia /=ly 9heel*@ >iscosity o li

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actors Bernoulli $

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$. '@A@ Griiths; Introduction to electrodynamics 3rdEd@". $@M@ Purcell; Electricity and Magnetism (Berkeley Physics course) 2ndEd.9. @P@ =eynman; @ B@ "eighton an M@ !ans; The Feynman Lecture o Physics !ol. 2@@. $@ Hecht; "#tics; $thEd@5. =@@ Aen:ins an H@$@ 7hite; =unamentals o .&tics@7. @@ Ghata:; "#tics@

. @@ !harma; "#tics% Princi#les and a##lications@B. G@@ =o9les; Introducton to Modern "#tics@

=eneral Chemistry II

Molec*lar 4r&itals and 6onding

tomic an molecular or(itals o ! an P (loc: elements D ,heir interrelationshi&

9ith car(on an its com&ouns@ >alence shell electron re&ulsion />!$P theory@

s&; s&2; s&3; s&2; s3; s&3 an 2s&3 Molecular %ariants B $y;

B2; B3; B4; B5 an B#; an their %ariants 9ith non (oning or(itals@

BH4; B3$; B2$2; B$3; B5; B4$1; B3$2; B2$3; B#; B5$1; B4$2@

Pro&erties o these ty&es o molecules as electro&hiles; "e9is acis; nucleo&hiles

an (ases@ Bon angles; (on lengths; (on energies an other actors aecting

these &arameters; such as electronegati%ity; resonance; hy&ercon8ugation;

tautomerism; inucti%eeect@ .ther ty&es o (onsD Hyrogen (ons an their

im&act on molecular &ro&erties@ Molecular (ons; charge transer (ons; sigma

(ons; molecules 9ithout (ons@

Catenanes@

*&stit*tion and +limination

ucleo&hillic su(stitution reactions at saturate organic com&ounsD !1 ; !2; !i

reactions; stereochemistry; reaction conitions; a&&lications in synthesis@

$limination reactions D $1 an $2 eliminations@

tereochemistry

.&tical isomerism; asymmetry an o&tical &ro&erties@

Chirality; $nantiomers an their resolution@ an ! coniguration@

'iastereomers; Cahn-Ingol-Prelog se

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o cycloheane eri%ati%es; conormation o other cyclic systems; eect o hetero

atom on conormation@ Isomerism in coorination com&ounsD

Geometrical IsomerismD s

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5@ !tereochemistry o Car(on Com&ouns; $@ "@ $liel; ,ata McGra9-Hill; e9 'elhi;

200)@

#@ Basic Inorganic Chemistry; =@ Cotton; @G@ 7il:inson an P " Gans9iley /1F55@

1iterat*re

?nit-1: Parts o s&eech; articles; auiliary %er(s; &re&osition

?nit-2D Phrases; Clauses; sentences; tense; %oice; narration; unctional elements in

sciences

?nit-3D Paragra&h 9riting; summary 9riting; &ara&hrasing; &rLcis 9riting; letter 9riting;

resumes; C@>@; 8o( a&&lications; re&ort 9riting; note ta:ing; ictation@

?nit-4D eaing com&rehension /rom su(8ect area

?nit-5D =unctional use o language; situational use o language; acaemic use o

language

?nit-#D "istening an s&ea:ing; con%ersation; language la(oratory

=eneral 6iology-II

!mall an large molecules in (iologyD 7ater; aci; (ases; &H scale; (uers;unctional grou&s; macromolecules an origin o lie@ Introuction to (iological

&olymers /&rimary; seconary; tertiary an

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ecommene (oo:sD

4@ "ie; ,he science o (iology; )th$n@ Pur%es; !aa%a; .rians an Heller

5@ "ehninger Princi&les o (iochemistryD 4th$n@; %i "@ elson an Michael M@

Co@

#@ n Introuction to genetic analysisD *th$n@; @A@=@ Griiths; !@ @ 7essler; @ C@

"e9ontin; 7illium M@ Gel(ert; '@ ,@ !uu:i an A@ H@ Miller@

Comp*ter programming < )ata str*ct*re 1a&oratory

Introd*ction

Introuction to com&uter; history; %on-eumann architecture; memory system /hierarchy;

characteristics an ty&es; H67 conce&ts /I6. 'e%ices; !67 conce&ts /!ystem !67

&&lication !67; utilities@ 'ata e&resentationD um(er systems; character re&resentation

coes; Binary ;octal; heaecimal an their intercon%ersions@ Binary arithmetic; loating &ointarithmetic; signe an unsigne num(ers; Memory storage unit@

3rogramming in C

History o C; Introuction o C; Basic structure o C &rogram; Conce&t o %aria(les; constants

an ata ty&es in C; .&erators an e&ressionsD Introuction; arithmetic; relational; "ogical;

ssignment; Increment an ecrement o&erator; Conitional; (it9ise o&erators; $&ressions;

.&erator &receence an associati%ity@ Managing In&ut an out&ut .&eration; ormatting I6.@

*ndamental eat*res in C

C !tatements; conitional eecuting using i; else; nesting o i; s9itch an (rea: Conce&ts oloo&s; eam&le o loo&s in C using or; 9hile an o-9hile; continue an (rea:@ !torage ty&es

/automatic; register etc@; &reeine &rocessor; Comman "ine rgument@

Arrays and *nctions

.ne imensional arrays an eam&le o iterati%e &rograms using arrays; 2-' arrays ?se in

matri com&utations@

Conce&t o !u(-&rogramming; unctions $am&le o user eine unctions@ =unction &rototy&e;

eturn %alues an their ty&es; calling unction; unction argument; unction 9ith %aria(le num(er

o argument; recursion@

Advanced feat*res in C

Pointers; relationshi& (et9een arrays an &ointers rgument &assing using &ointers; rray o

&ointers@ Passing arrays as arguments@

1#

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!trings an C string li(rary@

!tructure an ?nion@ 'eining C structures; Gi%ing %alues to mem(ers; rray o structure;

este structure; &assing strings as arguments@

=ile Hanling@

Recommended &ooks

$. !I C (y $ Balagurusamy". ash9ant anet:ar; "et us CN; BPB Pu(lications; 2n$ition; 2001@9. Her(ert !chilt; CD,he com&lete reerenceN; .s(ourne Mcgra9 Hill; 4 th$ition;

2002@

4@ >@ a8a aman; Com&uter Programming in CN; Prentice Hall o Inia; 1FF5@

Applied Chemistry 1a&-"

D*alitative inorganic analysis of miEt*res containing not more than @ radicals

from the follo0ing

Basic raicalsD a+; +; Ca2+; !r2+Ba2+; l3+; Cr3+; Mn2+; =e3+; Co3+; i3+; Cu2+; Kn2+

ci raicalsD =-; Cl-; Br-; I-; !2-; !.42-; !2.3

2-; .3-; .2

-

Interering raicalsD P.43-

; s.43-

; B.33-

'etermination o strength o aci an (ase (y neutraliation reaction /ou(le titration

in%ol%ing strong aci-9ea: (ase; etc@

Recommended 6ooks:

G@ !%ehlaD >ogelEs tet (oo: o ualitati%e Inorganic nalysis /re%ise; "ongman;

Pearson $ucation@

@ @ a; B@ Maha&atra an @ GhoshalD n %ance Course in Practical Chemistry

Applied 3hysics 1a&-"

1@ aterOs Penulum2@ Cou&le &enulum3@ Magnetic hysteresis loo&

1)

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4@ !urace tension5@ >iscosity#@ 'ielectric constant o ierent materials)@ Charging cur%e o a ca&acitor*@ Magnetic iel o &aire coils in Helmholt arrangement

F@ $lectromagnetic inuction10@=orce o current carrying conuctor11@>elocity o soun using resonance tu(e12@Hall eect

9rd and @th emester

+M++R-III +M++R-I

lno

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!1223'

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1 Mathematics or chemistry 3+1+0 4 1 !ymmetry Grou& ,heory 3+1+0 4

2 uantum Chemistry-I 3+1+0 4 2 !tatistical Mechanics 3+1+0 4

3 .rganic chemistry-I 3+1+0 4 3 Physical Chemistry-I 3+1+0 4

4 Inorganic chemistry-I 3+1+0 4 4 Inorganic chemistry-II 3+1+0 4

5Chemistry "a(oratory-II/.GIC

0+0+3 3 5Chemistry "a(oratory-III/PH!IC"

0+0+3 3

#Chemistry "a(oratory-II/I.GIC

0+0+3 3 *Materials $lectronics"a(oratory

0+0+3 3

4A1 CR+)I22

4A1 CR+)I 22

1*

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9rd emester

Mathematics for Chemistry

.&erator alge(ra 9ith s&ecial reerence to

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D*ant*m Chemistry I

(rie re%ie9 o classical mechanics@ e9tonEs; "agrangeEs an HamiltonEs

e

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Organic Chemistry I

Aromatic *&stit*tion$lectro&hilic !u(stitutionD itration; Halogenation; =rieel-Crats al:ylation an

acylations; metallations@

ucleo&hilic !u(stitutionD !u(stitutions (y aition-elimination reactions@ 'iaonium

meiate reactions@

romatic aical !u(stitutionD Metal-assiste cou&ling an cross cou&ling reactions@ Cu;

i; P; an Kn- assiste arylations in aromatics an heterocycles /Hec:; !uu:i;

egeshi; Buch9ale@

Red*ction Reactions !0ith special emphasis on mechanism, stereochemistry

and selectivity, 0herever necessary'

Catalytic hyrogenationD aney nic:el; &allaium an &latinum uner lo9 an high

&ressure reactions@

Homogeneous catalytic hyrogenation using rhoium &hos&hine com&lees; metal

hyrie reuctions aBH4 ; "ilBH4; hyro(oration; Birch reuction; reuction 9ith

hyraine hyrate@

4Eidation Reactions !0ith special emphasis on mechanism, stereochemistry and

selectivity, 0herever necessary'

.iation 9ith chromium /incluing &yriinium chlorochromate /PCC an &yriinium

ichromate /P'CQ; manganese an osmium com&ouns@

.iation 9ith &eroies; &eracis; oone@ !har&less-asymmetric oiations@ .iations

9ith imethyl sul&hoie; lea tetraacetate; mercuric acetate; selenium ioie an

ruthenium tetroie@

21

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/alogenation Reactions !0ith special emphasis on mechanism, stereochemistry

and selectivity, 0herever necessary'

Halogenation reactions o acti%e methylene com&ouns; alehyes; :etones; esters;

nitriles; sul&hur; nitrites@

=ormation o enolates an their al:ylation stuies@ Chemistry o sul&hur ylis an

&hos&horous ylis; an their reactions in organic synthesis@

Concerted Reactions

$lectrocyclic reactions; sigmatro&ic rearrangements; cycloaition reactions@

Recommended 6ooks

1@ .rganic Chemistry; =@ @ Carey an @ A@ !uner(erg; lu9er caemic Pu(lishers;

4th $n@; 2005@

2@ %ance .rganic Chemistry D eaction Mechanisms an !tructure; A@ March;

7iley Interscience; 200)@

3@ Moern Methos o .rganic !ynthesis; 7@ Carruthers an I@ Colham; Cam(rige

?ni%ersity Press; 200#@

4@ .rganic !ynthesis; M@ B@ !mith; McGra9 Hill; e9 or:; 2000@

5@ .rganic !ynthesis D !&ecial ,echni@ @ hlu9alia an @ ggar9al; arosa

Pu(lications; 2001@

Inorganic Chemistry I

Periodicity, Molecular Structure and Bonding, Chemical Forces

22

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Peri$*ic Table, Per*$icity, Tren$s an$ an*malies, elativistic effects: ) revie *f

Leis Structures inclu$in; f*rmal char;es: 9S#P m*$el: M*lecular symmetry,

+*int ;r*u+s an$ intr*$ucti*n t* Character Tables: M*lecular *rbital the*ry *f

h*m*< an$ heter*

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$@ @ eiter; @"@ eiter an .@ @ Mehi; Pearson $ucation; 200)@

2@ Concise Inorganic Chemistry; A@ '@ "ee; 4th $n@; $"B!; 1FF1@

3@ %ance Inorganic Chemistry; =@ @ Cotton; C@ @ Murillo an M@ Bochman;

7iley Interscience; 2001@

4@ Inorganic Chemistry; '@ =@ !hri%er an P@ 7@ t:ins; .or ?ni%ersity Press;

1FFF@

5@ Molecular !ymmetry an Grou& ,heoryD Programme Introuction

to Chemical &&lications; @ >incent; Aohn 7iley; 2001@

#@ Chemistry o the $lements; @ @ Green9oo an @ $arnsha9; 2n$n@;

$lse%ier; 2005@

Chemistry 1a&oratory-II !organic'

Pre&aration o ollo9ing com&ounsD

o m-initro(enene

o cetanilie

o ,ri(romo&henol

o !ul&hanillic aci

.iation o &rimary alcohols-Benoic aci rom (enyl alcohol

Ientiication o sim&le organic com&ouns /eri%ati%es not inclue

Chemistry 1a&oratory-II !Inorganic'

o Pre&aration o ollo9ing com&leesD

o Potassium trioalato chromate/III

24

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o CoHg/!C4

o Cu/I thiourea com&le

o 'ou(le salts / Chrome alum6 MohrEs salt

o Bis / 2; 4-&entaneionate inc hyrate

@th emester3hysical Chemistry-I

*rfaces:- ,hermoynamics o suraces an interaces; surace tension; %a&our

&ressure surace ilms on liol@ 1; A@ .EM@ Boc:ris an @ @ @ ey; !&ringer;

200)@

4. Physical Chemistry, . S. /erry, S. ). ice an$ -. *ss, 67f*r$ niversity Press, %n$

#$n., %&&&.

25

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5@ ,hermoynamics o Irre%ersi(le Processes; @ Haase; 'o%er Pu(lications; 1FF0@

Inorganic Chemistry II

1@ Representative Chemistry of Main =ro*p +lements

a% 6r;an*metallic chemistry *f lithium an$ ma;nesium( synthesis, structure an$

reactivity.

"% Chemistry *f b*r*n( /*ranes, b*n$in; in b*ranes, t*+*l*;y *f b*ranes, synthesis

an$ reactivity, Carb*ranes an$ metallacarb*ranes. Ne Leis aci$s base$ *n

b*r*n: +*lymer

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"% In*r;anic rin;s an$ +*lymers. Cycl*< an$ heter*cycl*+h*s+ha=enes an$ the

+*lymers $erive$ fr*m them. P*lysilanes. /*ra=ine an$ b*r*n nitri$e.

c% Chemistry *f hal*;ens an$ n*ble ;ases ( recent tren$s. C@CAs an$ *=*ne layer.

&% Organometallic Chemistry

/a & (one ligans D

Metal al:yls; aryls an hyries D !ta(ility; &re&aration an reacti%ity@

Metal - car(onyls 6 Metal - &hos&hines 6 metal - nitrosyls 6 metal isocyanieDstructure; reacti%ity an (oning@

Metal < carbenes, metal < carbynes, @ischer carbenes, Schr*c0 carbenes,

Nb? < b*n$e$ li;an$s(

Metal

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2@ Chemistry o the $lements; @ @ Green9oo an @ $arnsha9; 2n$n@; $lse%ier;

2005@

3@ Moern Inorganic Chemistry; 7@ "@ Aolly; McGra9 Hill; e9 or:; 2n $n@; 1FF1@

4@ Conce&ts an Moels o Inorganic Chemistry; B@ 'ouglas; '@ Mc'aniel an

A@ leaner; Aohn 7iley; e9 or:; 3r$n@; 1FF3@

5@ .rganometallic Chemistry o the ,ransition Metals; @ H@ Cra(tree; 7iley;

e9 or:; 1F**@

ymmetry and =ro*p heory

ymmetry and point gro*ps:

otation; relection; im&ro&er rotation; in%ersion; multi&lication o symmetry o&erators;

grou& theory; classes o symmetry o&erators; &oint grou&s; ,; .h; 'h; Ch; C%; 'nh; 'n; Cnh;

Cn%

; Cn

; Ci

; Cs

; C1

@euci(le matrices; the character; character ta(le o &oint grou&s; irect&rouct; reuction o large matrices using character ta(les; irreuci(le re&resentation o

9a%e unctions; molecules 9ith no central atom; re&resentation o molecular or(itals@

Chemical applications:

Hy(riiation; (oning in organic molecules; electron eicient com&ouns; molecular

sha&es; symmetry conser%ation in chemical reactions@ >isi(le an ?> s&ectrosco&y@

!election rules; chromo&hores; crystal iel theory; s&in-or(it cou&ling; ou(le grou&s;

molecular or(ital theory o com&lees@ Molecular %i(ration an crystal symmetry; I

an aman s&ectrosco&y; selection rules or I an aman s&ectrosco&y;

characteristic (on re

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2@ =unamentals o Molecular !&ectrosco&y; C@ @ Ban9ell an $@ M@ McCash;

,ata McGra9 Hill; 1FF5@

3@ Molecular !&ectrosco&y; G@ M@ Barro9; McGra9 Hill; 1F*5@

4@ !&ectra o toms an Molecules; P@ =@ Bernath; .or ?ni%esity Press; 2005@

5@ Moern !&ectrosco&y; A@ M@ Hollas; Aohn 7iley; 4th $n@; 2004@

#@ Molecular !ymmetry an Grou& ,heory; @ "@ Carter; Aohn 7iley an !ons; 1FF*@

tatistical Mechanics

Introd*ctionD Meaning an sco&e o statistical mechanics@ ,hermoynamics %ersus

statistical mechanics@ ,he &ro(lem o statistical mechanics@ !tatistical mechanics or

systems o ine&enent &articlesD Introuction; statistical 9eight or egeneracy o energy

le%els@ Ma9ell-Boltmann /MB; Bose-$instein /B$ an =ermi-'irac /=' statistics@ ,he

e

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+nergy in molec*les: >i(ration; rotation an translation energy ieal monoatomic gas

&artition unction; thermoynamical &ro&erties translational constant; !ac:ur ,etroe

e

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F@ Conuctometric titration D aci-(ase@10@ Potentiometric titration D aci-(ase@11@ inetics o catalytic ecom&osition o H2.2 /ioine cloc: reaction@12@ inetics o aci-catalyse hyrolysis o sugar /chemical metho@13@ 'etermination o relati%e strengths o t9o acis (y stuying the :inetics o aci

catalyse ester hyrolysis@14@ Critical solution tem&erature

+lectronics < Materials 1a&oratory

1@ ?se o C.@2@ Characteristics o a enner ioe; an setting u& a &o9er su&&ly using a

enner ioe@3@ ,ransistor characteristics an current gain@4@ .&erational an ierential am&liier@

5@ =iltering an &hase shiting net9or:s@#@ 'etermination o !te&hanOs constant@

5th and 7th emester

+M++R- !+lective papers only' C6C +M++R-I

ln

o

*&ect

Code

*&ect /caniatesmay o&t or any 4

&a&ers loate (y thecentre an other 2&a&ers rom othercentres6schools

Contact

/o*rsper

0eek!122

3'

C

redits

lno

*&ect

Code

*&ect

Contact

/o*rsper

0eek!122

3'

C

redits

1 nalytical chemistry 3+1+0 4 1Photochemistry eaction'ynamics

3+1+0 4

2 $n%ironmental Chemistry 3+1+0 4 2 .rganic !&ectrosco&y 3+1+0 4

3 Materials chemistry 3+1+0 4 3 .rganic Chemistry-II 3+1+0 4

4 Chemistry in e%eryay lie 3+1+0 4 4 Biomolecular "a(oratory 0+0+3 3

57ater &ollution anremeiation

3+1+0 4 5 Pro8ect 9or: 0+0+* *

# Heterocyclic Chemistry 3+1+0 4

4A1 CR+)I24

4A1 CR+)I 23

emester-

31

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Analytical Chemistry

Unit-I

tatistical methods in chemical analysis: ,heory o error an treatment o

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Material Chemistry

Unit-I

Crystal structure o solisD =unamental o lattices; unit cell; atomic coorinates; Bra%aislattices; crystal irection an &lanes; ty&es o close &ac:ing; &ac:ing eiciency; raiusratios e9 im&ortant crystal structures@

!ynthesis o Inorganic solis soli state; solution &hase an %a&or &hase synthesis&reci&itation; hyrothermal; sol-gel; suractant (ase synthesis@ Gro9th o singlecrystals@

Crystal structure etermination (y U-ray iraction; -s&acing ormula; symmetricallya(sent relections; Multi&licities; !cattering o U-rays (y an atom an a crystal@ !inglecrystal an &o9er iraction@ $lectron an neutron iraction@ Conce&t o reci&rocallattice@ $lectron microsco&y techni' an M.C>' metho@

anomaterials CharacteriationD U' o nanomaterials; $lectron microsco&y /!$M;,$M; H,$M an $'U o nanomaterials; !canning &ro(e microsco&y@

anomaterial &ro&erties an a&&licationsD Magnetic &ro&erties o nano&articlessu&er&aramagnetism; erromagnetism in antierromagnetic nano&articles an single

omain to multiomain transition@ ?se o magnetic nano&articles as MI contrastagents@

Unit-III

=rontier areas o &olymer science an technologyD

Conucting &olymersD (asic &rinci&les o conucting &olymers; elocalie electronicstates o con8ugate &olymers; &olyanilines; &olyacetylenes; &olythio&hene; a&&licationso conucting &olymers@ Bioegraa(le &olymersD 'einition classiication o natural(ioegraa(le &olymers; cellulose; cellulose acetate; cello&hane; soy &rotein; corn;ein &rotein; 9heat gluten &rotein; synthetic (ioegraa(le &olymers; &olyhyroyal:anoates; &olycar&olactone; &oly/%inyl alcohol; &olyacetic aci; a&&lication o

(ioegraa(le an (iomeical &olymers; contact lens; ental &olymers; artiicial heart;:iney; s:in; an (loo cells@

=i(ersD natural i(ers; cotton; 9ool; sil:; rayon; artiicial i(ers; &olyamies; acrylic aci;P>C; P>@

u((erD Com&ouning an elastomeric &ro&erties; %ulcaniation; reinorcement@

33

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Boo:s an eerences

1@ Khen Guo an "i ,an; Fundamentals and ##lications o ,anomaterials@

2@ Physical methos in chemistryD @ !@ 'rago; !auners college@3@ Chemical a&&lication o grou& theoryD =@ @ Cotton; 7iley $astern "t@4@ Polymer science; >@ @ Go9ari:er; @ >@>is9anathan; A@ !reehar; e9 ge

International@5@ Princi&le o &olymer chemistryD P@ A@ =lory#@ Polymer !cience an technology; Plastics; u((er an com&osites; P@

Ghosh; ,ata McGra9 Hill@

+nvironmental Chemistry

Unit-I

+nvironment:Com&osition o atmos&here; tem&erature %ariation o earth atmos&heric

system /tem&erature %s@ altitue cur%e; (iogeochemical cycles o C; ; P; ! an .

system@

/ydrosphere:Hyrological cycle; a

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eerence Boo:s

1@ 'e@@@$n%ironmental Chemistry; 7iley $astern lt;

2@ Miller ,@G@Ar@; $n%ironmental !cience; 7as9orth &u(lishing House; Meerut.um@$@P@1F)1@

3@ =unamental o $cology@ 7@B@ !auners Co@?@!@@1@ $n%ironmental chemistryD !@ $@ Manahan; "e9is &u(lisher2@ $n%ironmental chemistry; !harma an aur; rishna &u(lishers3@ $n%ironmental chemistry; @ @ 'e; 7iley $astern4@ $n%ironmental Pollution; Monitoring an control; !@M@ ho&:er; e9 ge

International@5@ $n%ironmental chemistry; C@ Bair; 7@H@ =reeman@#@ Princi&les o instrumental analysisD '@ @ !:oog; 5then; !auns College

Pu(lishing Philael&hia /"onon@)@ Basic conce&ts o analytical chemistryD !@M@ho&:ar; 7iley $astern

Chemistry in +veryday 1ife

Unit-I

Respiration and energy prod*ction

es&iration; es&iratory enymes; (rie outline o hemoglo(in an myoglo(in; oygen trans&ort

mechanism in (oy; co-o&erati%ity; es&iration in lo9er animals; hemocyanine; hemerythrine;

non-heme =e-! &roteins@

$nergy &rouction in (oy; ,P; enyme res&onsi(le or oo igestion; mechanism o ooigestion; acti%e site o cytochrome c-oiase@

Unit-II

Chemical aspects of some common health haHards

nemia; sic:le cell anemia; leu:emia;mechanism; (loo &ressure regulation; (loo sugar;

arthritis; car(on monoie &oisoning in mines; cyanie &oisoning; luorosis; &oisoning o Hg; C;

P(; s etc@ ; toicity arising rom aily use chemicals@

Unit-III

itamins and minerals

ee or %itamin in (oy; ty&es o %itamins; 9ater solu(le an at solu(le %itamins; >itamin B-12;

%itamin C /Cyanoco(alamine; '; >itamin @ ole o minerals in (oy; ioine eiciency; eects

an remeies@

Unit-I

35

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ignificance of Radical chemistry in living system

aical &rouction in en%ironment; su&eroie an &eroie; health im&act; action o raicals;

cell mutation; iseases cause (y ree raical; cancer; raical

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/eterocyclic Chemistry

hree-mem&ered rings 9ith one heteroatomD Chemistry o oiranes; airiines

an e&isul&hies - synthetic a&&roaches an reacti%ities@

hree-mem&ered heterocycles 9ith t9o heteroatomsD oairanes; iairiines an

iairines - synthetic a&&roaches an reacti%ities@

o*r-mem&ered heterocyclesD oitanes; aatianes an thietanes - synthetic

a&&roaches an reacti%ities@

,9o natural &rouctsD synthesis o Peniciline an ce&halos&orine@

ive-mem&ered aromatic heterocyclesD

a 7ith one heteroatomD urans; &yrroles an thio&henes - general synthetic

a&&roaches; &ro&erties an reacti%ities@

( 7ith t9o heteroatomsD oaoles; isoaoles; imiaoles; thiaoles; &yraoles

an isothiaoles - general synthetic a&&roaches an reacti%ities@

c 7ith three an our heteroatomsD triaoles an tetraoles - synthetic

a&&roaches; &ro&erties an reacti%ity@

Condensed five-mem&ered /eterocyclesD

Benouran; inoles an (enothiaoles - general synthetic a&&roaches; 9ith

greater em&hasis on the chemistry o Inoles@

ynthesis of Indole alkaloidsD

Harman; harmaine; lysergic aci iethylamie /"!'; yohim(ine an reser&ine@

Brie chemistry o (enoaoles; (enisoaoles; (enimiaoles; (enothiaoles

an inaoles@

3)

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iE-mem&ered /eterocycles 9ith one; t9o an three heteroatomsD

a Chemistry o &yriine grou&

( Chemistry o &yriaines an &yrimiines@

c Chemistry o &yraines an triaines@

D*inoline and IsoG*inoline AlkaloidsD

!ynthesis; reacti%ities an chemistry o their conense %ariants 9ith greater

em&hasis on ol 1-*;

Pergamon Press; 1F*4@

4@ Han(oo: o Heterocyclic Chemistry; @ @ atrit:y; Pergamon Press; 1F*5@

5@ ing ,ransormations o Heterocycles; >ol 1 an 2; H@ C@ >an er &las;

3*

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caemic Press; e9 or:; 1F)3@

3F

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emester-I

3hotochemistry < Reaction )ynamics

@un$amental as+ects *f reacti*n 0inetics, c*llisi*n an$ transiti*n state the*ries *f reacti*ns rates.3inetics an$ mechanisms *f h*m*;ene*us an$ heter*;ene*us catalytic reacti*ns. 3inetics *f

electr*chemical reacti*ns ith s+ecial reference t* hy$r*;en ev*luti*n reacti*n an$electr*$e+*siti*n. Mechanism *f c*m+le7 reacti*n, $erivati*n *f $ifferential rate eHuati*ns,

stea$y state an$ rate limitin; a++r*7imati*ns as a++lie$ f*r c*m+le7 reacti*ns, fast reacti*ns,

techniHues f*r stu$y *f fast reacti*ns. #7+l*si*n reacti*ns. 3inetics an$ Mechanism *f I*nicchain reacti*ns. 3inetic treatment *f $iffusi*n in liHui$s an$ s*luti*ns.

Photophysical and Photochemical processes

Intr*$ucti*n: e7citati*n an$ the e7cite$ states: las *f +h*t*chemistry ( Gr*tthus

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4rganic pectroscopy

4rganic pectroscopy

/asic Princi+les *f 9 S+ectr*sc*+y, )++licati*n *f **$ar$4th e$iti*n? McGra !ill /**0 C*m+any 15'.

%..M. Silverstein, G.C. /assler, T. C. M*rnil >"th e$iti*n? -*hn iley E S*ns, Inc Ne *r0,

4rganic Chemistry-II

Car&ohydrates: 'etermination o the coniguration o monosaccharies; ing structure

o the monosaccharies; glycosies; coniguration o C1 in glucose; HusonEs rules;

methos or etermining the sie o sugar rings; conormational analysis; eam&les o

some sugar eri%ati%es; >itamin C6"/+ ascoro(ic aci; isaccharies; isaccharies;

&olysaccharies; glycosies@

Amino acids and proteins:

Classiication o the amino acis; general methos o &re&aration o the amino acis;

analysis o amino-acis rom &rotein hyrolysates; general &ro&erties o the amino acis;

&roteins; general nature o &roteins; classiication o &roteins; the &e&tie lin:age; the

&rimary structure o &e&ties; synthesis o &e&ties; oytocin; the s&atial arrangement o

&rotein molecules; $nymes; General nature o enymes; nomenclature an

classiication; coactors; s&eciicity o enyme action; mechanism o enyme action;

(iosynthesis o enymes@

itaminesD Introuction; %itamin-B com&le@

41

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Recommended 6ooks

1@ .rganic chemistry; %ol2; !tereochemistry an the chemistry o natural &roucts; I@"@=inar; Per

2011@

1@ $nantioselecti%e !ynthesisD atural Proucts rom Chiral ,er&enes; ,@ "@ Ho; 7iley

Interscience;

2@ atural Prouct Chemistry; @ a:anashi; ,@Goto an !@ atori; >ol@ 1; 2 an 3;

oansha !cientiic Boo:s; ,o:yo; 1F*3@

3@ .rganic Chemistry o Biological Path9ays; A@ McMurray an @ Begly@

4@ ,er&enois; >ol@ I an II; P@ 'e Mayo@

6iomolec*lar 1a&oratory

1@!ystematic ientiication o organic com&ouns /monounctional an sim&le(iunctional an &re&aration o their eri%ati%es@2@ Pre&aration o the ollo9ing com&ounsD !u&hanilic aci; i(enyl acetone; methylorange; initro(enene rom (enene; isolation o caine@3@ $stimation o &henol /(romie-(romate metho an aniline /(romie-(romate anacetylation methos@4@ $aluation shall (e out o 100 mar:s /* creits as &erollo9ingD

Presentation o 9or:D 30 mar:s

!u(mission o re&ort /har co&y nee to (e su(mitteD 50

>i%a-%oceD 20

42

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emester th and Bth

+M++R-II +M++R-III

lno

*&ect

Code*&ect

Conta

ct/o*rsper

0eek!122

3'

Credits

lno

*&ect Code

*&ect

Conta

ct/o*rsper

0eek!122

3'

Credits

1anomaterials- !ynthesis;Characterisation Pro&erties

3+1+0 4 1

+lectives:/1&&lie $lectrochemistry/2ano-Chemistry Green,echnology

3+1+0 4

2.rganic Photochemistryan molecularrearrangements

3+1+0 4 2Moern ,echni

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II-emester

Fanomaterials- ynthesis, Characterisation < 3roperties

Unit-I

Introd*ction to Fanostr*ct*red materials:

Pre&aration methosD thermal an ultrasoun ecom&osition methos@ euctionmethos@Co&reci&itation; s&ry rying; sol-gel an hyrothermal methos@ Ca&&e semiconuctornano&articles@ High energy (all milling an mechanical attrition@ ,hermal e%a&oration@!&uttering@ "aser a(lation@ Chemical %a&our e&osition@ Molecular (eam e&itay@,hermal s&raying@ $lectro an electroless e&osition@ Characteriation techni

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magnetic (eha%iour@ Processing; microstructure; &ro&erties an a&&lications o

magnetic ceramics@

Recommended 6ooks1@ @C@ Buchanan; Ceramic Materials or electronics; Marcel 'e::er; e9 or:@

2@ "@"@ Hench A@@ 7est; Princi&les o electronic ceramics; Aohn 7iley !ons@3@ anostructures an anomaterials; G@ Cao@4@ introuction to anotechnology; charles P@ Poole Ar@ an =@A@ .9ens@5@ anostructure Materials; Carl C@Coch@

4rganic 3hotochemistry and molec*lar rearrangements

Unit I

4rganic 3hotochemistry < ree Radical Reactions:Photochemical &rocesses@ $nergy transer; sensitiation an illiger;Hyro&eroie an (orane rearrangements@ 'a:in reaction

References

1@ '@H@7illiams an I@=leming; !&ectrosco&ic Methos in .rganic ChemistryN; 7iley@2@ 7@em&; .rganic !&ectrosco&yN; "ongman3@ A@March; %ance .rganic ChemistryN; 7iley4@ @.@C@orman an @Coon; Moern !ynthetic eactionsN; Cha&man an Hall5@ M@B@!mith; .rganic !ynthesisN; McGra9-Hill#@ @@Bansal; !ynthetic &&lications in .rganic ChemistryN; arosa

)@ @A@!immons; Chemistry o BiomoleculesN; oyal !ociety o Chemistry*@ I@"@=inar; .rganic ChemistryN >ol1 an 2 ; "ongmanF@ eaction mechanism- Mu:her8ee !ingh

Coordination Mechanisms < Magnetism

45

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UFI-I

Coordination Chemistry: Reaction Mechanism and Method of ynthesis: +lectron

transfer reactions:

Introuction

ey ieas concerning electron transer (et9een transition metals@

.uter s&here electron transer Chemical acti%ation Cross reaction@

Inner s&here electron transer =ormation an rearrangement o &recursor@

$lectronic structure o oiant an reuctant@

ature o (riging ligan =ission o successor com&le@

,9o electron transer@

on-com&limentary reactions@

!ynthesis o coorination com&ouns using electron transer@

UFI-II

*&stit*tion Reactions

e&lacement reactions at =our-coorinate Planar eaction Centers

General mechanism in s

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ci hyrolysis

Base catalye hyrolysis; CB mechanism

,hermoynamic sta(ility

!ynthesis an chemistry o some co(alt an &latinum com&lees@

UFI-III

ome Important Aspects of Coordination Mechanism

.rer o reaction an mechanism

Methos o characteriation o reaction intermeiates

,echni

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,em&erature e&enent an ine&enent magnetism; Curie la9; Curi9-7eiss

la9; Curie an eel tem&erature@

Ind*strial Chemistry

Unit-I3rinciple of Chemical +ngineering:Introuction to chemical engineering@ Com&arison o acaemic an inustrial Chemistry@Material an energy (alances@ ?nit an imensionsD conser%ation o mass an energy;&ro(lem sol%ing techni

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4@ A@M@Betty; &&lie Inustrial CatalysisN; caemic Press5@ Coulson an icharson; Chemical $ngineeringN; >ol@ 1;2; 3#@ McCa(e; ?nit .&eartion o Chemical $ngineeringN)@ Peter 7iseman; Inustrial .rganic ChemistryN*@ @@erris !hre%e; Chemical Process InustriesN

F@ 'riens; .utline o Chemical ,echnologyN10@ B@@!harma; Inustrial Chemistry; Goel Pu(lishing House11@ B@ "@ Bhatt an !@ M@ >ora; !toichiometry; ,ata-McGra9 Hill Pu(lishing Com&any;e9 'elhi@12@ .@ @ Hougen; @ M@ 7atson an @ @ agat; Chemical Process Princi&les Part-I;Aohn 7iley !ons@13@ '@ M@ Himmel(lau; Basic Princi&les an Calculations in Chemical $ngineering;Prentice Hall Inc@14@ Process Calculations or Chemical $ngineeringN; 2n eition; Chemical $ngineering$ucation 'e%elo&ment Centre; II, Maras@

3= 1a&-I !Applied Inorganic Chemistry 1a&oratory'

1@ Pre&aration o ollo9ing com&leesD/i Potassium trioalato chromate/III/ii CoHg/!C4/iii Cu/I thiourea com&le/i% 'ou(le salts / Chrome alum6 MohrEs salt/% Bis / 2; 4-&entaneionate inc hyrate1@ 'etermination o nic:el as nic:el /II imethyl glyoimate /in%ol%ing sol%ent etractioncolorimetrically@2@ 'etermination o P( as ithioone com&le colorimetrically@3@ 'etermination o l or Mg as their oinate colorimetrically@4@ Potentiometric titration in%ol%ing $',@5@ Potentiometric titration o =e2+ 9ith Ce4+@#@ Ao(Es metho o continuous %ariation or etermination o stoichiometry o thecom&lees@)@ Gra%imetric etermination o the ollo9ing using sintere glass cruci(leD/a i as i/'MG2/( Cu as Cu/!C/c l or Mg as oinate/ Kn as Kn H4P.4*@ Chromatogra&hic se&aration o the ollo9ing D/a ClV; BrV; an IV /( C2+ an Hg2+ /c g2+ an P(2+F@ Pre&aration o luminium acetylacetonate an its &uriication (y %acuum su(limation@

!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

3= 1a&-II !Applied 4rganic Chemistry 1a&oratory'

1@ !ystematic ientiication o organic com&ouns /monounctional an sim&le(iunctional an &re&aration o their eri%ati%es@

4F

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2@ Pre&aration o the ollo9ing com&ounsD !u&hanilic aci; i(enyl acetone; methylorange; initro(enene rom (enene; isolation o caine@3@ $stimation o &henol /(romie-(romate metho an aniline /(romie-(romate anacetylation methos@4@ $

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Unit II+lectrodicsD'ierent ty&es o elctroes@ $lectrochemical cells@ Concentration cell an acti%ity

coeicient etermination@ .rigin o electroe &otential@ "i

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Fano-Chemistry < =reen- echnology

Co*rse contents to &e added

Modern echniG*es of Analytical Chemistry

Unit $

+lectrochemical and spectral techniG*es

$lectrochemical an s&ectral analysis; an analytical se&aration

$lectrochemical methosD Conuctometry; Potentiometry; &H-metry@$lectrogra%imetry; Coulometry; cyclic %oltammetry; &olarogra&hy; ierential&ulse &olarogra&hy; Coulometry@

!&ectro&hotometryD "am(ert-Beer la9; "imits to BeerEs la9; Princi&le o

s&ectro&hotometric estimation o iron; manganese an &hos&horous@ 'etectionan estimation o =e; s; Hg; C; P(; H4+; an =-; .3-; .2- in 9ater sam&le@

Princi&les an instrumentations o atomic a(sor&tion /! an atomic emission

s&ectrometry estimation o soium an &otassium in 9ater sam&les@

UFI "

3rinciples and application of chromatography

!igniicance o chromatogra&hic techni

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tatistical methods in Chemical Analysis

!tatistical methos in chemical analysis; mean; meian; moe; stanar

e%iations@

$rrors in chemical analysisD ccuracy an &recision o measurements;

eterminate ineterminate; systematic an ranom errors in chemical analysis9ith eam&les; a(solute an relati%e errors@

source; eect an etection o systematic errors istri(ution o ranom errors;

normal error cur%e; stanar e%iations; stanar e%iation o calculate results-sum or ierence; &rouct or

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1@ '@@!:oog; '@M@7est an =@A@Holler; =unametals o nalytical ChemistryN;!auners College Pu(lishing@2@ C@"@7ilson an '@7@7ilson; Com&rehensi%e nalytical ChemistryN; 'an %anostran3@ A@G@'ic:; nalytical Chemistry; McGra9 Hill

Catalysis < its Ind*strial Applications

Unit I

Catalysis- 3rinciples and Applications:Basic &rinci&les o catalysisD asor&tion isotherms; surace area &ore sie an aci

strength measurement@ $nthal&y an entro&y o asor&tionD inter&retation ochemisor&tions (ase on the structure an the nature o the soli soli state theories role o eects in catalysis@ inetic o surace reactionsD rate etermining ste&;$am&les o %arious ty&es o reaction; sim &arallel an consecuti%e reactions@!election; &re&aration an e%aluation o catalysts test reaction; &romoters; carriersan sta(iliers@ CatalysisD Mechanism an theories o homogeneous anheterogeneous catalysis@ ci (ase an enyme catalysis@ Bimolecular suracereactions@ "angmuir-Hinshel9oo mechanism@

Unit-II

Mechanisms of selected reactions:Hyrogenation an ehyrogenation reaction ehyration o alcohols; oleinhyrogenation; ecom&osition o nitrous oie; oiation o C.etoniation o car(oylicacis; crac:ing o hyrocar(ons@ &&licationsD &etrochemical inustry reorming anreining %alue ae chemicals en%ironmental &rotection autoehaust catalysts o%elcatalytic material clusters; eolites; meso&orous materials@ $lectrocatalysis an Photocatalysis@

Unit-III

Catalysts in =reen Chemistry:Introuction to the &rinci&les o green chemistry &re%ention o 9aste; atom economy;less haarous chemical syntheses; esigning saer chemicals; saer sol%ents anauiliaries; esign or energy eiciency; reuce eri%ati%es; rene9a(le eestoc:;catalysis; esign or egraation; real time analysis or &ollution &re%ention; aninherently saer chemistry or accient &re%ention@ Green synthesis; clean routes;su&ercritical sol%ents; ionic li

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References:

1@ $@@ieal; Conce&ts in catalysisN; caemic Press

2@ @Clar:; ,he ,heory o sor&tion an CatalysisN; caemic Press3@ @Pearce an 7@@Patterson /$s@; Catalysis an Chemical Processes@N;Bac:iean sons4@ A@M@Betty; &&lie Inustrial CatalysisN; caemic Press

+lectives:

rontiers of 6io-inorganic < 6io-mimetic Chemistry

*le *f metalsin bi*l*;y, acti*n *f NaF3 +um+, metal i*n t*7icity.

Carb*nic buffer an$ carb*nic anhy$rase,

Ph*t*system I an$ II, chl*r*+hyll

Su+er*7i$e in c*m+le7es.

67i$ative ;enerati*n *f the 6

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)lc*h*l $ehy$r*;enase

Metall*thi*nines

Gluc*se metab*lism, )TP f*rmati*n

#n=yme inhibiti*n

S*me selecte$ m*$elin; stu$y

Ind*strial 4rganic Chemistry

Contents to &e given

Radiation Chemistry

Radiation Chemistry:Classiication o nuclies; nuclear sta(ility; (ining energy an nuclear moels@Characteristics o raioacti%e ecay; ecay :inetics; &arent-aughter ecay gro9threlationshi&s; etection anmeasurement o raioacti%ity; a%ances in the soli an li

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1@ G@ =rienlaner; A@7@ enney A@M@ Miller uclear an aiochemistry; 7ileyInterscience;e9 or:@2@ B@G@ Har%ey; Introuction to uclear Physics Chemistry; Prentice - Hall; $ngle9ooClis /@A6 Prentice-Hall; Inia; $$$ $n@

3@ @,@ .%erman; Basic conce&t o uclear Chemistry; Cha&man Hall@4@ @ @ esmeyano%; aiochemistry; MI Pu(lication; Mosco9@5@ A@7@,@ !&in:s @A@ 7oos; n Introuction to aiation Chemistry; 7iley; e9or:@#@ H@ A@ rni:ar; $ssentials o uclear Chemistry; 7iley $astern "t@; 2n $ition@

Fovel synthetic strategy in organic chemistry

Unit-I

ynthetic trategyetrosynthetic analysis; isconnection a&&roach; ,y&ical eam&les to illustrate theisconnection a&&roach; =unctional grou& inter-con%ersion; ?m&olung /1;3-ithlane;Con%ergent synthesis@

)esigning =reen ynthesis'esigning Green !ynthesisD choice o starting materials; choice o reagents; choice ocatalysts (io catalysts; &olymer su&&orte catalysts; choice o sol%ents@!ynthesis in%ol%ing (asic &rinci&les o green chemistry 9ith eam&lesD synthesis oai&ic aci; methyl methacrylate; &aracetamol@?ltrasoun assiste reactions esteriication; reuction; cou&ling reactions@ !trec:er

synthesis an reormats:y reaction@

Unit-IIolvent ree 4rganic ynthesis!ol%ent ree micro9a%e assiste organic synthesis micro9a%e acti%ation; micro9a%eheating; an a%antages o micro9a%e e&osure an s&eciic eects o micro9a%es@.rganic synthesis uner micro9a%es (eneits; limitations; e

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$&eriments on catalytic amiation; chemical transormations using a%ance tools %icontinuous hyrogenator /hyrogenation6hyrogenolysis using P6i6Pt catalysts;continuous &rocessing cham(ers@

=reen Chemistry in 3rocess Research

!ol%ent o&timiation; 9or:-u& o&timiation; atom economy; in-situ reactions; reco%eryan reuse; &uriication an se&aration techni

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,o etermine hal 9a%e &otential o a gi%en ion using hal height metho;

ierential metho an 9a%e eeriication o .nsagar $

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4 Manual on 7ater an 7aste 7ater nalysis; $$I- ag&ur '@!@ amte:e an C@ @Moghe

emester Kth and $#th

+M++R-I; +M++R-;

lno

*&ect

Code*&ect

Contact

/o*rs

per0ee

k!1223'

Credits

lno

*&ect Code

*&ect

Contact

/o*rsper

0eek!122

3'

Credits

1

+lectives:/1Chemistry o aturalProucts/2Inustrial eactions earrangements

3+1+0

4 1?nit .&eration in ChemicalInustry

3+1+0 4

2

+lectives:/1%ance =uel,echnology/2Inustrial Materials

3+1+0

4 2Pollution Control Inustrial 7aste 7aterManagement@

3+1+0 4

3Molecular !imulation Chem-Inormatics

3+1+0

4

3Pro8ect 9or:;'I!!$,,I. %i%a%oce

1#4 Corrosion !cience

3+1+0

4

5PG la(-> /&&lie InustrialChemistry "a(

0+0+*

4

# P.A$C,6!$MI 4

4A1 CR+)I24

4A1 CR+)I 24

#0

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I.!Semester

+lectives:

Chemistry of Fat*ral 3rod*cts

Unit-IChemistry of Fat*ral 3rod*cts!tructure an synthesis o al&ha-Pinene; Cam&hor; Caenine an Caryo&hyllene@Homann; $me an %on Braun egraation in al:aloi chemistry@ !tructure eluciationo Pa&a%erine; uinine an Mor&hine@ !ynthesis o uinine an Pa&a%erine@ !tructurean synthesis o (eta-Carotene; =la%one; Isola%one; Cyanin an uercetin@Biosynthesis o ter&enes an al:alois@ Classiication an structure o li&is an their(iounctions@ omenclature; structure /not eluciation an (iosynthesis oProstaglanins PG$2; an PG=1%@

Unit-IIitamins:!ynthesis an structure o (iotin an %itamin B2; synthesis o %itamin B1; (iologicalunctions o B#; B12; olic aci an thiamine@

Recommended &ooks

1@Moern synthetic reactions-/Ben8amin H@ .@ House@2@eagents in organic synthesis-/Aohn 7iley =ieser an =ieser3@Princi&les o organic synthesis-/Methuen @ .@ C@ orman4@Hyro(oration- !@ C@ Bro9n@5@%ances in .rganometallic Chemistry- /@P@=@ C@ @ !tone an @ 7est@#@.rganic Chemistry /"ongman>ol@ I >ol@ II- =inar)@.iation (y-/Marcel 'e::er ugustin*@%ance .rganic chemistry 2n $@ @ Carey an @ A@ !an(erg@F@,etrahyron re&orts in organic chemistry- >ol@1; o@ *@10@.rganic !ynthesis-/Prentice Hall@ $@ Irelan@

#1

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2nd

option Ind*strial Reactions and Rearrangements

Unit IMolec*lar Rearrangements:Mechanism; 9ith e%ience; o 7agner Meer9ein; Pinacol; 'em8ano%; Homann;Curtius; !chmit; "ossen; Bec:mann; 7ol; =ries; ryloo; =ischer-He&&; Homann-Martius; %on icheter; .rton; Bam(erger; !miles; 'ienone-Phenol; Benilic aci;Beniine; =a%ors:ii; !te%ens; 7rittig; !ommelet-Hauser; Baeyer->illiger;Hyro&eroie an (orane rearrangements@ 'a:in reaction

Unit-IIt*dy of ollo0ing Reactions :Mechanism o conensation reaction in%ol%ing enolates Mannich; Benoin; !to((e;'iec:mann; 'iels-ler; o(inson annulation eimer-,ieman; Chichi(a(in; Baeyer>illiger oiation!tuy o ollo9ing reuctions- Catalytic hyrogenation using homogeneous anheterogeneous catalysts@ !tuy o ollo9ing reactionsD 7ol-ishner; Birch;Clemmensen; !oium (orohyrie; "ithium luminium hyrie /"H an !oium inalcohol; =e in HCl@&&lication o ollo9ing oiiing agentsD Mn.4; chromium trioie; Manganeseioie; .smium tetraoie; ''; Chloranil @

!tuy o .rganometallic Com&ounsD.rgano-magnesium; .rgano-inc an .rgano-lithium; Hg an !n reagents ?se olithium ial:yl cu&rate their aition to car(onyl an unsaturate car(onyl com&ouns@

Unit-IIIMethodologies in 4rganic ynthesisDIeas o synthones an retrones@ =unctional grou& transormations an intercon%ersionso sim&le unctionalities@ C-C an CSC (on orming reactions Mannich; eimer-,iemann; !imon-!mith; >ilsmeier-Haac:; eormats:y an ?llmann reactions@ !tro:enamine reaction@ !ha&iro; 7itting Horner; Peterson; Hec:; !tille an McMurrayreactions@ ing ormation (y 'iec:mann; ,hor&e an cyloin conensations@ o(inson

ring annulation@ !ynthesis o small rings@ !imon-!mith reaction@ euction anoiation in synthesis@ Catalytic hyrogenation@ Birch reuction@ 7ol-ishner reuction@Hauang-Milon moiication@ Clemmenson reuction@ Boranes; "H; !oium (orohyrieas reuctants@ 'ehyrogenations; .&&enauer oiation; Hl.4; .s.4 an m-ClC#H#C...H an their a&&lications@

Reference &ooks:

#2

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1@!ome moern methos o .rganic synthesis-/Cam(rige 7@ Carruthares@2@ @A@!immons; Chemistry o BiomoleculesN; oyal !ociety o Chemistry A@Mann anothers; atural Proucts ,heir Chemistry an (iological signiicanceN; "ongman3@ I@"@=inar; .rganic ChemistryN >ol 2; "ongman

4@ 7@ar; Meicinal ChemistryN; 7iley $astern5@ %ance .rganic Chemistry; eaction Mechanism an !tructure; Aerry March; Aohn7iley@#@ Moern !ynthetic eaction; H@.@ House; 7@@ Ben8amin@)@ Princi&les in .rganic !ynthesis; @.@C@ orman an A@M@ Coon@*@eactions Mechanisms Pro(lems in .rganic Chemistry; P Chatta&ahyay; 1 st$n;sian Boo:s Pri%ate "imitte; e9 'elhiF@ .rganic !ynthesis; Michael B !mith; McGra9 Hill; 2n $n; 2004; e9 or:@

+lectives:

Advanced *el Cell echnology

Unit-I*ndamentals and classification of f*el cells:,hermoynamic eiciency@ $lectromoti%e orce o uel cellsD !tanar electroe&otentials $ect o concentration ernst e

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2no&tion

Ind*strial Materials

Unit IChemistry of materials, =lasses, Ceramics and Composites!tructure o glass; glass ormers an glass moiiers@ &&lications o glass@ Ceramicstructure; mechanical &ro&erties; clay &roucts@ Microsco&ic com&osites- is&ersionstrengthene an &article reinorce; i(re reinorce com&osites; macrosco&iccom&osites@ ,hin ilms an "angmuir- Bloget =ilmsD Pre&aration techni

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5@ B@Hannay; !oli !tate Chemistry; Prentice Hall@#@ ,@Moeller; ,he Chemistry o the "anthaniesN; einhol@)@ G@,@!ea(org; Manmae ,ransuranium $lementsN; Prentice Hall

Molec*lar im*lation and Chem-informatics

Moel systems an interaction &otentials@!tuying small systems; &erioic (ounaryconitions; truncating interaction &otentials@Molecular ynamics numerical integration oe

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Corrosion &re%ention (y metallic; organic; inorganic coatings; corrosion inhi(itors@Cathoic an anoic &rotection techni

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4@Canniaro reactionD 4-chloro(enylehye as a su(strate@5@romatic $lectro&hilic su(stitutionsD !ynthesis o &-itroaniline an &-Bromoaniline@#@Pre&aration o Cinnamic aci (y Per:inOs reaction@)@noe%enagel conensation reaction

*@Coumarin !ynthesisF@!ynthesis o Heterocyclic com&ouns@10@ !ynthesis o 'yes11@ nalysis o Pharmaceutical ta(lets@12 ,o %eriy the Beer-"am(erts "a9 an etermine the concentration o gi%en yesolution colorimetrically@13 ,o estimate the amount o '-glucose in gi%en solution colorimetrically@14 ,o etermine the aci %alue o gi%en oil15@ Pre&aration o (enanilie (y Bec:mann rearrangement1#@ Pre&aration o anthranilic aci1)@ Pre&aration o &hthalimie

1*@ Pre&aration o - (romosuccinamie1F@ Pre&aratin o &- mino (enoic aci20@ Pre&aration o &- chloro nitro(enene (y !anmeyer reaction21@ Pre&aration o &- Ionitro(enene (y !anmeyer reaction22@ Pinacol- Pinacolone rearrangement

!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

=ro*p )

1@$stimation o unsaturation@2@$stimation o ormalin@3@Colorimetric $stimation o 'yes4@$stimation o mino acis

!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

=ro*p +1 ,o %eriy Beer-"am(ertEs "a9 or &otassium &ermanganate solution an hence toetermine the molar etinction coeicient an un:no9n concentration o gi%en sam&lecolorimetrically2 ,o etermine the solu(ility o calcium oalate in &resence o Cl / Ionic !trength$ect

3 ,o etermine the solu(ility o calciuum oalate in &resence o HCl / H+ ion $ect!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

=ro*p 1 'etermination o soium rom the ertilier sam&le using cation echangechromatogra&hically@2 'etermination o calcium rom gi%en rug sam&le@

#)

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3 'etermination o harness; al:alinity an salinity o 9ater sam&le4@!e&aration an estimation o chlorie an (romie on anion echanger@5@Pre&aration o organic com&ouns (y multi-ste& reactions in%ol%ing nitration;halogenation; acetylation anoiation@#@ $stimation o ester; acis; reucing sugars; &henols; amines; :etones; nitrogen an

sul&hur@)@ uantitiati%e analysis o /a mil: an (utter; /( ats; oils an soa&s; /c rugs such asacetyl salicylic aci; as&irin; &henacetin an su&hanilie; / caeine; sugar an starchoo*@s&ectro&hotometric etermination o cholesterol; ascor(ic acis; glucose anammonia@4@ Characteriation o organic com&uns using I; ?>->is an M s&ectral methos@

!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

=ro*p = !=eneral methods'1@=oo nalysis2@ Cosmetics nalysis3@ 'rug nalysis4@ >itamin nalysis5@ ,hermal nalysis o Inorganic Materials#@ 7ater analysis

!+Eperiments may &e addeddeleted s*&ect to the availa&ility of facilitiestime'

Reference &ooks:1@ @I@>ogel; ,et(oo: o uantitati%e Inorganic naysisN; "ongman2@ I@M@oltho; >@A@$l%ing an !anell; ,reatise on nalytical ChemistryN; Interscience@

3@ I@M@otho an !trenger; >olumetric nalysisN; Interscience4@ =ruman an 7elcher; !tanar Methos o Inorganic nalysisN; >an ostran5@ G@!ch9aren(ac:; Com&leomtric ,itrationsN; Interscience#@ '@@!:oog an '@M@7est; nalytical Chemistry n IntrouctionN; einholt@)@ 7@G@Palmer; $&erimental Inorganic ChemistryN; Cam(rige ?ni%ersity Press*@ @!@'rago; Physical Methos in Inorganic ChemistryN; iliate $ast-7est PressF@ $&erimental Inorganic Chemistry - 7@ G@ Palmer10@ ,he analysis o minerals an ores o the rarer elements 7@ @ !choeller an @@Po9ell; Charles; Griin an Com&any "imite11@ @ han(oo: o

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.!Semester

/nit Operation in Chemical Industry

3roperties and Classification of fl*ids"aminar an tur(ulent lo9s Pressure ro& an riction actor; Mechanical energy(alance an BernoulliOs e

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3oll*tion Control < Ind*strial ?aste ?ater Management

Unit-Ireatment process of 0aste 0ater:Hyrological cycle@ Physical; Chemical an Biological &ollution o 7ater; methos o

!am&ling an Monitoring o 7ater; 7ater uality &arameters@ Pre an &rimarytreatment; $

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3roect < )issertation

In the final semester !;thsemester', st*dents have to carry o*t proect 0ork atCUJ as per the recommendation of fac*lty committee of the centre *nder the

s*pervision of a cientista*lty mem&er. Joint colla&oration 0ith othercentresschools is enco*raged in order to enhance the G*ality of 0ork andinterdisplinary characteristics in the 0ork. he Area of the 0ork is to &e decided&y the Adviser!s'. 4n completion of the 3roect 0ork, st*dents have to s*&mitthen 0ork in the form of a dissertation follo0ed &y oral presentation in thepresence of ac*lty mem&ers and an eEternal eEpert.