1 © 2017 horiba, ltd. all rights reserved. - infoeco.ru 02 27_04.pdf · ・integration of horiba...

© 2017 HORIBA, Ltd. All rights reserved. 2© 2017 HORIBA, Ltd. All rights reserved. 2

Ambient Monitoring in Germany features, equipment in use and future trends

HORIBA EUROPE GmbHProcess & Environmental

Dr. Torsten Laube

Workshop on the State Air Monitoring: Russian and European Experience

St. Petersburg February 17-28, 2017

© 2014 HORIBA, Ltd. All rights reserved.

Business Segments・Emission Measurement Systems (EMS)・Mechatronics Devices (MCT) ・Test Automation Systems (TAS)・Intelligent Transport Systems (ITS)

・Environmental & Process Systems・Environmental Radiation Monitor・Environmental Regulation & Process Business

・Mass Flow Controller・In-situ Analysis・Synergy among HORIBA HQ, HORIBA STEC

and HORIBA Jobin Yvon’s Technologies

・Synergy of HORIBA and HORIBA Jobin Yvon’s Technologies

・Raman, Grating, and Fluorescence

・In-vitro Diagnostic (IVD) Systems・Integration of HORIBA ABX’s

Technology & Marketing Know-how

Automotive Test Systems

Process & Environmental

Medical

Semiconductor

Scientific

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© 2017 HORIBA, Ltd. All rights reserved. 4

ProductionR&D

Major R&D/Production Sites

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Oberursel, Darmstadt, Germany (Automotive, Process & Environment, Semiconductor, Scientific)

Olomouc, Czech (Automotive)

Kyoto, Japan (Automotive, Process & Environment, Medical, Semiconductor, Scientific)

Ann Arbor MI, USA (Automotive)

Edison NJ, USA (Scientific)

Santa Clara CA, USA(Semiconductor)

Sao Paulo, Brazil(Process & Environment,Medical, Scientific）

Irvine CA, USA (Automotive, Process & Environment, Medical, Semiconductor, Scientific)

Aso, Japan (Automotive, Process & Environment, Medical, Semiconductor, Scientific)

Shanghai, China (Automotive, Process & Environment, Medical, Semiconductor, Scientific)

Northampton, UK (Automotive, Process & Environment, Semiconductor, Scientific)

Montpellier, France (Medical)

Saclay, France (Semiconductor, Scientific)

Longjumeau, France (Semiconductor, Scientific)

India, New Delhi(Automotive, Process & Environment, Medical, Scientific)

Grenoble, France(Semiconductor)


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Table of contents

Ambient Air Monitoring in GermanyRough Overview

Equipment in use – What is needed? Analyzer, Software, Shelter

– Tailor made solutions Current/Future developments and trends

CompAQMS Optical Dust/PM Analyzer

– APDA-372 Characterization of Dust/PM

– PX-375


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Table of contents






– PX-375


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Component Hourly Limit Value Annual Limit Value Remarks

SO2 350 µg/m3 125 µg/m3 (24 h) OnlineNO2 200 µg/m3 (1 h) 40 µg/m3 OnlinePM10 50 µg/m3 (24 h) 40 µg/m3 Online/SamplerPM2.5 25 µg/m3 Online/SamplerO3 120 µg/m3 (highest 8

hour moving average) Online

CO 10 mg/m3 (highest 8 hour moving average)

Online

Pb 0,5 µg/m3 Filter, Laboratory

Cd, As, Ni, 5 / 6 / 20 / 1 ng/m3. Filter, Laboratory

EU Air Quality Standard


Relevant Norms for Gas & Dust measurement

* Published 2017** Predecessor to EN 12341

Norm Description

EN 15267-1 Air quality.Certification of automated measuring systems. General principles

EN 15267-2

Air quality.Certification of automated measuring systems. Initial assessment of the AMS manufacturer's quality management system and post certification surveillance for the manufacturing process

EN 15267-3Air quality.Certification of automated measuring systems. Performance criteria and test procedures for automated measuring systems for monitoring emissions from stationary sources

EN 15267-4*

Air quality.Certification of automated measuring systems. Performance criteria and test procedures for automated measuring systems for periodic measurements of emissions from stationary sources

EN 14181 Stationary source emissions.Quality assurance of automated measuring systems.

EN 12341Ambient air.Standard gravimetric measurement method for the determination of the PM10 or PM2,5 mass concentration of suspended particulate matter

EN 14907**Ambient air quality.Standard gravimetric measurement method for the determination of the PM2,5 mass fraction of suspended particulate matter


9

Air Monitoring Stations

Number of Stations/Instruments

Stations from: States (Networks) Umweltbundesamt (German EPA) Industry (for Example BASF) Others (Airports, Local Hot Spots, Research)


Hessen

Nordrhein-Westfalen

Rheinland-Pfalz

Bayern

Baden-Württemburg

Niedersachsen

Saarland

Thüringen

Sachsen

Sachsen-Anhalt

Brandenburg

Berlin

Bremen

Hamburg

Mecklenburg-Vorpommern

Schleswig-Holstein

29

9

64

20

35

27

12

36

15

25

16

29

28

20

55

BASF: 5

Ambient Air Monitoring Germany States

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Number of Stations


European referenz laboratory in Ispra, Italien

National referenz laboratory in Germany the UBA

Primarymeasurement

Test measure

insprection

Comparisontest

Primaryspan gas

production

Analyzer in the calibration lab( Referenz analyzer )

Gas dillution system for routinekalibration of analyzer and for

comparison test

Transportable standardsAnalyzer after

repairing and newdelivering

Analyzer in the ambientmeasuring stations

Gas bottles in the stationszertified from HLUG

HLUG

EU/National Standard


Table of contents






– PX-375


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What is Needed?

Requirements for correct data and high data availability Approved and reliable Analyzers High Quality Systems including “Housing”

– Tailor made solutions Adequate data communication and

Software solution Highly qualified and motivated staff


14

HORIBA AP-370 Series

•APMA-370: CO(Cross Flow NDIR Method）

•APSA-370: SO2

（UV Luminescence Method）

•APNA-370: NO, NO2, NOx（Chemical Luminescence Method）

•APOA-370: O3(UV Absorption Method）

•APHA-370: THC, CH4, NMHC (FID Method)

EU/GOST approved

HORIBA AP-370 Series


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Complete Integrated Systems

HORIBA designs and assembles complete integrated systems for simultaneously measuring multiple pollutants

“Rack Level”


16

Мониторинг атмосферного воздуха.

Система сбора и обработки данных Эковэб


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Fixed Monitoring Stations

Ambient Air MonitoringIceland (HORIBA)

Airport Berlin Air Quality Monitoring Germany (HORIBA)

Ambient Air Monitoring Turkey (Local partner)

Ambient Air Monitoring Middle East (Local partner)

Each Station Tailor-Made, adapted on local requirements


18

Truck-Mounted Air Monitoring Laboratory Current Project – Dubai Municipality

Horiba’s compact and rugged AP-370 monitors are ideal for mobile laboratories.

Truck similar


19

Table of contents






– PX-375


20

CompAQMS 2016

Compact Ambient Air Quality Monitoring Station:

Campaigns, short term measurement,traffic hot-spot monitoring, special application

Integrated 19”-mini-rack with 4 slots Easy exchange of analyzers Easy to move

Dimensions:145 x 90,4 x 92 cmApprox. 150 kg

Special Application: Hamburg Harbor Police


21

APDA-372 Dust Monitor for PM 2.5 and PM 10

Measurement Principal: Optical Light Scattering on Single Particle

PM 2.5 and PM 10 in one unit EU approved / GOST applied


22

Measurement principle


23

Light source (polychromatic)

Photomultiplier

Optical defined measuring

volume

Measurement system principle

T-aperature


24

Touchscreen Examples


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Comparison optical/ß-ray Dust

Task / Specification APDA-372 e.g. ß-ray(e.g. APDA-371)

One unit for PM2.5 and PM10 Yes NO

Low maintenance cost (no filter tape) Yes NO

No radioactive source, environment friendly technology Yes NO

Longer maintenance intervals Yes NO

Calibration on-site possible Yes NO

Spare pump available (installed) Yes NO

Shorter moving average times Yes NO

Touch screen Yes NO


26

Sampling Head/Inlet (TSP, PM10, PM2,5)

Condenser Unit

Main Unit – Beta Ray & XRFX-ray Identification light

Dimension: 450(w)x550(l)x 285(h) : mmWeight: Approx 40Kg

Continuous PM & Elements Analysis

HORIBA PX-375


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Ion componentInorganic element

Elemental carbonOrganic carbon

Component Method FilterIon Component Ion chromatography PTFE

Inorganic element ICP-MS or XRF PTFEPolycyclic aromatic

hydrocarbon HPLC or GC-MS PTFE

Elemental CarbonOrganic Carbon Thermal/Optical Method Quartz fiber

Breakdown of Element of PM2.5


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Detectable Elements

15 standard elements


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Why we have developed PX-375?

Conventional Method

1. A lot of human cost & time2. Difficult to catch trend3. Bias with the mix of field & Lab analysis

Sampling Filter Replacement Pretreatment Analysis


30

Mass Analysis< Beta-ray >

Elemental Analysis< XRF >

Internal View

PX-375 Composition


31

Signature Elements for Source Identification


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Easy to get the result and compare the PM and the Element

PM Trend

Element Trend

Measurement Progress

Previous Result

User Friendly Display & Operation


33

Peaks are due to fireworks from French national celebration

Results from France 2015

Huge Peak first unknown


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• Start of fire on 21st at around 3pm and lasted 3 days, 30km from station• Fridges, washing machines etc.

Large fire at waste disposal site

Fire start


35

PX-375 Applications Identification of source Source apportionment studies Fence line monitoring Emissions Inventory Metal compliance ( Pb, Hg, As, Cd, Cr ) Clean room monitoring


36

PX-375

Questions ?

Continuous Elemental PM Analyzer

Спросить?


Danke

Grazie

Σας ευχαριστούμε

감사합니다

Obrigado

谢谢

ขอบคุณครับ

ありがとうございました

ध यवाद

நன்ற

Cảm ơn

Dziękuję

Tack ska ni ha

Thank you

Merci

Gracias

Большое спасибо

спасибо


39


40

Current Project – Dubai MunicipalityPhoto of today from our factory


41

Railroad based system – RussiaTROICA. (Transcontinental Observations into the Chemistry of the Atmosphere)

By courtesy of Prof. N. Elansky

Professor Dr. Elansky in Discussion with Professor Dr. Syukuro Manabefrom Princeton University


42

Activities in RUSSIA History

1994 Big Project with AEG

3 mobile Laboratories were sold to AEG and exported to RUSSIA

– Inside the Laboratories are APxA 360 analyzers


43

Activities in RUSSIA Present

Air Quality Monitoring Container


44

Trend Ambient

COST

QU

ALI

TY/P

ER

FOR

MA

NC

E

±2k€ ±30k€ ±100k€

#=50 #= 3 #= 1


45

HORIBA Cross Flow Modulation (CFM)

Only HORIBA AP analyzers utilize cross flow modulation, unique method of measurement

The sample gas and the reference gas (zero gas) are alternately sent to the measuring cell at a specific flow rate and interval by continuously switching solenoid valves

CEM always compares reference gas and signals, so AP-370 analyzers generate a stable concentration signal without zero drift

Long term stability

Keep cell cleanby reference gas


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48

Ambient Air Pollution & Health

Pollutant Acute health effects Chronic/Toxic health effects

Sulphur dioxideNarrowing of the airways, particularly in sensitive individuals, producing symptoms ranging from coughing and asthma; no observable threshold.

Increased prevalence to chronic bronchitis and other respiratory diseases; differences in lung function.

Suspended particulate matter

Increased mortality from cardiovascular and respiratory diseases; no observable threshold.

Increased respiratory mortality and morbidity; decreased pulmonary function; no observable threshold

Nitrogen dioxideSensitizes lungs to other pollutants and allergens; increases frequency of eye irritation, sore throat and phlegm.

No definite effects from outdoor exposure but indoor exposure suggest a range of effect upon lung function; in animal studies morphological, biochemical and immunological changes were detected.

OzonePowerful oxidant reacting with most biological substances; a lung irritant and sensitizer to other pollutants and allergens; can produce runny eyes and sore throats.

It has recently been suggested that ozone is a genotoxin but adequate investigations are not available; high level long-term exposure in animal studies included morphological changes in the lung.

Carbon monoxideReduces oxygen carrying capacity of the blood by binding with haemoglobin.

Excess risk from arteriosclerotic heart disease; affects developing foetus.

Lead None known.Neurotoxin (suggestion of impaired cognitive development); affects blood biochemistry and can raise blood pressure.


49

Ambient Air Pollution & Health


50

Relation between Sectors, Emission, Air Quality

Source: EEA, 2009


51

-370 Series – Measurement methods

NDIR

UV Fluorescence

Chemiluminescence

FID

UV Absorption


52

Truck-Mounted Air Monitoring Laboratory

Chemical plant, Germany (2012)

Horiba equipped this large-scale, full-height laboratory on wheels.

Horiba’s compact and rugged AP-370 monitors are ideal for mobile laboratories.


53

Major Measurement Methods

ReferenceMethod

TEOM

Beta-rayattenuation

Lightscattering

C14

Detector

FilterTape

Detector

Oscillating Element

FilterCartridge


54

Technical Details/Solutions are Important

Supporting Arm Movable Fixing

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