*University of Manitoba

WHMISRevised November 2011

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Workplace Hazardous Materials Information SystemWHMIS Stands for

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*The Workplace Hazardous Materials Information System is a Canada-wide system designed to give employers and workers information about hazardous materials used in the workplace.

WHMIS standards are coordinated between both Federal and Provincial governments.

Manitoba Workplace Safety and Health Act and Regulations sets the WHMIS requirements.WHMIS is

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*WHMIS has 3 Main Parts Labels provide information about the hazards of the product Material Safety Data Sheets (MSDS) provide further detailed information Education how to use the information provided

Identify 6 Classes of Controlled Products Understand the Main Hazards associated with each class Recognize and understand the two types of WHMIS labels Understand how to use Material Safety Data Sheets

The GOAL is

*A Controlled Product isA Controlled Product is any substance or material which meets any of the criteria for inclusion in one or more of the six WHMIS Hazard Classes as defined in the Federal Controlled Product Regulation.

Under WHMIS , there is no comprehensive list of controlled products but only a list of hazard criteria.

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When WHMIS does not apply there may be another Act or regulation that does.

WHMIS does not apply to controlled products that are: Wood or a product made of wood Tobacco or a product made of tobacco A manufactured item that will not release chemicals Products transported under the Transportation of Dangerous Goods Act for more information regarding TDG:

WHMIS Does Not Applyhttp://umanitoba.ca/admin/human_resources/ehso/emanagement/tdg.html

WHMIS does not apply to products covered by:

Explosives Act Food and Drugs Act Pest Control Products Act Certain products in the Hazardous Products Act Nuclear Safety and Control Act

WHMIS Does Not Apply

WHMIS labels and MSDS are still required for:

Mixtures of radioactive nuclide(s) and a non-radioactive carrier material where: The carrier material is greater than 1.0 ml / 1 g The carrier material poses a carcinogenic, toxic, reactive, or infectious hazard

WHMIS Applies forFor more information regarding Radiation Safety:http://umanitoba.ca/admin/human_resources/ehso/rad_safety/index.html

Hazard Classes & SymbolsThere are 6 Hazard Classes

Hazard Classes & SymbolsClass A : Compressed GasesRisks Physical hazard (120kg) Explosive hazard Content hazard

Examples CO2 cylinders N2 cylinders O2 cylinders acetylene

5.psd

Hazard Classes & SymbolsClass A : Compressed GasesHandling and Use Secure cylinder upright with valve cap on when not in use Use gas specific regulator Test connections for leaks Avoid heat & ignition sources Transport using specialized cart Store in cool ventilated area

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Hazard Classes & SymbolsClass A : Liquid N2 & Dry IceRisks Frostbite Samples may explode Asphyxiation

Handling and Use Avoid skin contact Wear insulated gloves and eye protection Store in a well ventilated room Transport securely to prevent accidental spillage Store Liquid N2 in a vented dewar

7.psd

Hazard Classes & SymbolsClass B : Flammable & CombustibleSix Subdivisions1. Flammable gas2. Flammable liquid3. Combustible liquid4. Flammable solid5. Flammable aerosol6. Reactive flammable material

8.psd

Hazard Classes & SymbolsClass B : Flammable & CombustibleRisks Fire hazard will burn if ignited Could ignite spontaneously Could ignite upon mixing with water or other chemicals Many are poisonous

9.psd

Hazard Classes & SymbolsClass B : Flammable & CombustibleExamples1. Flammable gas hydrogen, methane2. Flammable liquid [flash pt 37.8C] kerosene, varsol4. Flammable solid magnesium metal, aluminum dust5. Flammable aerosol propane, butane, isobutane6. Reactive flammable material phosphorus, sodium metal

10.psd

Hazard Classes & SymbolsClass B : Flammable & CombustibleHandling and Use Avoid contact with flames, heat, & ignition sources Cap tightly for storage, vapours are flammable Avoid inhalation and skin contact Ground and bond when dispensing from 25L container Store in flammable storage cabinets if in excess of 50L Transport separate from oxidizing materials Transport securely using secondary containment

11.psd

Hazard Classes & SymbolsClass C : Oxidizing MaterialRisks Increase fire and explosion hazard May cause combustibles to explode or react violently May burn skin and eyes on contact Most are corrosive and poisonous

Examples Peroxides Nitrates Persulfates Hypochlorites (bleach)

12.psd

Hazard Classes & SymbolsClass C : Oxidizing MaterialHandling and Use Wear the recommended protective equipment and clothing Store away from sources of heat and ignition Many oxidizers are shock sensitive, handle carefully Store and transport separately from flammables and organics Store in non-corroding containers Transport securely

13.psd

* Division 1 Materials Causing Immediate and Serious Toxic Effects (acute)

Division 2 Materials Causing Other Toxic Effects (chronic, delayed)

Division 3 Biohazardous Infectious Material

Hazard Classes & SymbolsClass D : Poisonous and Infectious

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Hazard Classes & SymbolsClass D : Poisonous and InfectiousDivision 1Risks Small quantities may be harmful or lethal May be toxic not only if ingested but also if inhaled or absorbed through skin or eyesMany acute toxic compounds act as carcinogens at lower levels

Examples Carbon monoxide All halogens Cyanides

17.psd

Hazard Classes & SymbolsClass D : Poisonous and InfectiousDivision 2Risks Materials which have harmful effects after repeated exposures or over long periods of time

Damage could include:Permanent injury or deathBirth defectsCancerOrgan damageSensitization and allergies

Examples Asbestos Formaldehyde, benzene Ammonia

18.psd

Hazard Classes & SymbolsClass D : Poisonous and InfectiousDivision 3Risks Infectious materials which may cause disease resulting in illness or death

Examples Blood, tissue, and body fluids Tissue culture Experimental cultures

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Hazard Classes & SymbolsClass D : Poisonous and InfectiousHandling and Use Wear protective clothing to avoid all exposures: skin, inhalation, ingestion, and injection Work in a fume hood or BSC Avoid creating dust, vapours, and aerosols Obtain appropriate immunizations Handle exterior containers as though it is contaminated Store and transport securely to prevent accidental spillage

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Hazard Classes & SymbolsClass E : Corrosive MaterialRisks Will burn human tissue including skin, eyes, nose mouth, throat & lungs Will corrode many lab related materials particularly metals Fumes may damage the environment

Examples Strong acids & bases Hydrogen fluorideHydrogen chloride

23.psd

Hazard Classes & SymbolsClass E : Corrosive MaterialHandling and Use Wear appropriate protective clothing When possible work in the fume hood Open containers slowly When diluting acids, always add acid to water Store in non-corroding containers, on non-corroding trays (secondary containers ) Store away from combustibles, organics, and sources of heat and ignition Transport separate from flammables Transport securely using secondary containment

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Hazard Classes & SymbolsClass F : Dangerously ReactiveRisks May be unstable or vigorously polymerize May react with water to release a toxic or flammable gas May self-react when shocked or heated Highly reactive with incompatible materials May burn eyes and skin on contact

Examples Ether Acrylates 1,3-butadiene Metal azides

25.psd

Hazard Classes & SymbolsClass F : Dangerously ReactiveHandling and Use Follow MSDS recommendations for use and storage Wear protective clothing, especially eye protection Open slowly and carefully & use in fume hood Ensure lab equipment is clean and free of impurities Store away from incompatible chemicals Keep away from heat and ignition sources; avoid sudden temperature changes May require inhibitors to prevent reaction during storage Examine storage containers frequently Store & transport securely

26.psd

*Label Types

LabelsSupplier LabelsThe following must be included on a supplier label:

Product NameWHMIS SymbolsRisk PhrasesPrecautionary MeasuresFirst Aid MeasuresMSDS ReferenceSupplier Name

All information must be within a hatched border

*LabelsLaboratory Supply House - Supplier Label

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LabelsWorkplace LabelsThe following must be included on a workplace label:

Product Name Safe Handling Instructions MSDS Reference

Must be present on: Products decanted or transferred from an original container Product where original label is lost or becomes illegible Products produced and used at the workplace

You can print your own WHMIS workplace labels

LabelsWorkplace Labels

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LabelsWorkplace Labels Hazardous WasteThe following must be included on a hazardous waste label:

Product Name Concentration Hazard

Print your own hazardous waste labelsWaste Tags must: Be present on containers that do not have a correct supplier label Must list any chemical over 1% or any quantity if it poses a significant hazard Use only chemical names (no trade names, abbreviations, or formulas)

LabelsWorkplace Labels Hazardous Waste

* Provides detailed information on the hazards of a controlled product An important element for developing safe work procedures and control measures Must be provided by the supplier, or If you have created a product, you must prepare a MSDS Risk Group 2 and higher biological agents also require a MSDS or a Pathogen Safety Data Sheet (PSDS)

Material Safety Data Sheets (MSDS)Must be replaced every 3 yearsAll MSDS must be kept for 30 years

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MSDSInformation ProvidedProduct InformationThis section identifies product name, manufacturer and suppliers names, addresses, and emergency phone numbers, and the intended use of the product.

Hazardous Ingredients This section lists All potentially hazardous ingredients, with the approximate amount (percent), and toxicity data for the individual ingredients. Information regarding the LD50 and LC50 (the amount of a chemical that is expected to kill 50% of a test animal population within a specified time) will also be given. The lower the value the greater the poisoning potential.

MSDSInformation ProvidedPhysical DataProvides information on the physical and chemical properties such as odour, boiling point, and vapour density. Fire or Explosion Hazard DataProvides the conditions under which the product may catch fire or explode, as well as information for developing strategies and procedures to deal with fire and explosion hazards.

First Aid MeasuresLists the procedures for emergency first aid.

MSDSInformation ProvidedReactivity DataProvides information regarding stability, self-reactivity, hazardous decomposition products, and conditions to avoid when using the product.Toxicological PropertiesIdentifies how the substance can enter the body and the possible health effects from short term (acute) exposures such as irritation, sensitization; and long-term (chronic) such as liver or kidney damage, sensitization, cancer, or reproductive effects. Known exposure limits will also be given.

MSDSInformation ProvidedPreventative MeasuresProvides preventive measures you can take to protect yourself from exposure including: extra ventilation, personal protective equipment (PPE), safe use, handling, storage, disposal, transport, and spill control.

Preparation informationIndicated who was responsible for preparation and date of preparation of MSDS. It is 3 years from this date when the MSDS needs to be renewed.

Information may be labeled as Trade Secret if a claim has been filed. The information is released to medical professionals in case of emergency.

MSDSExample

MSDSLocation, Location, Location

The University has well established guidelines and procedures to deal with hazardous waste disposal EHSO provides hazardous waste disposal services at no charge to the University faculties and departments Incorporate waste disposal into lab procedures or experiments NO disposal of Hazardous Waste is permitted down the drain or regular trash can

Remember that your end point is someones starting pointRefer to the EHSO webpage for detailsHazardous Waste Disposal Procedures

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If a spill occurs that poses an immediate risk to people, or if someone is injured it is an EMERGENCY call 555 Minor spills should be cleaned up by trained staff Spills must never be cleaned up by untrained staff Under no circumstance shall caretakers be instructed to clean up any lab spills The best time to learn about and practice cleaning up a spill is before it happens read the MSDS EHSO is also available to assist with the cleanup of non-emergency spills beyond the capabilities of available staff Information on spills cleanup can be found on the EHSO website

Spill Clean-upChemical, Radiological, or Biological

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Chemical StorageGeneral Chemical Organization Organize by compatibility not alphabetically Separate each compatible group In separate cabinets or on separate shelves Or in secondary containers in same cabinet or shelf Make sure all containers are properly closed Containers must be labeled and tightly capped

Chemical StorageGeneral Chemical Organization

FlammablesStore in flammable storage cabinetsBasesStore separately OxidizersStore separatelyAcidsStore in corrosive resistant acid cabinetEXCEPT: chromic, nitric, and perchloric acids which should be stored separatelyGlacial acetic acid should be stored as a flammable

Chemical StoragePotentially Explosive ChemicalsPicric Acid and Nitro Compounds Dry picric acid may explode if subjected to heat, shock, or friction (opening the lid) Picric acid must be stored under wet.Some nitro compounds may have similar requirements

Peroxide Forming Compounds Example ethers, dioxanes, sodium amide Peroxide formation may be initiated by light or air Peroxides are prone to explosive decomposition when subjected to heat, shock, or friction (opening the lid)

Evaluate the conditions of these chemicals regularlyRefer to MSDS for storage and handling requirements

Chemical StorageGeneral Chemical Segregation

Do Not Store:With:OxidizersFlammablesAlkali metalsWater, CO2, CO, or CCl4Acetic AcidChromic, nitric or perchloric acid, peroxides, permanganates, or hydroxides i.e. KOHAcetoneConcentrated sulphuric or nitric acidsHypochloritesAcidsChlorineAmmonia, acetylene, butadiene, benzene, petroleum derivatives, or sodium carbidesCyanides (Alkaline)AcidsPotassium chlorateAcidsChlorates (ClO3)Ammonium salts, acids, metal powders, sulphur, or carbonHydrogen SulphideNitric acidH2O2Flammables, Cu, Cr, Fe, or respective saltsChromic AcidAcetic acid, alcohol, naphthalene, glycerine, or other flammable liquidsAnnhydrous AmmoniaHalogens, Hg, HF, or CaClO4Acids (conc.)Bases (conc.)

Chemical StorageGeneral Chemical Organization & SegregationDo Not: Do not place heavy materials, liquid chemicals, and large containers above eye level Do not store chemicals on the floor Do not store items in fume hoods Do not expose stored chemicals to direct heat or sunlight

*As part of the Manitoba Workplace Safety and Health Act and Regulations, an inventory of chemicals is required at the University.

The University provides the EHS Assistant database. It can be accessed from the EHSO website.Chemical InventoryU of M Chemical Inventory Database

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Your supervisor or a designate is responsible for worksitespecific education that includes:

Hazard information for the controlled products used at your work site Safe use, storage and handling of specific controlled products used at your work site Dealing with fugitive emissions and emergencies at your work site MSDS location

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