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3rd International Congress on Green Process Engineering

CONFERENCEPROGRAMME

MONDAY, 5th DECEMBER

18:00– 21:00 EARLY REGISTRATION

TUESDAY, 6th DECEMBER

8:00 – 9:00 REGISTRATION

9:00 – 10:00 OPENING CEREMONY

10:00 – 10:30 COFFEE BREAK

10:30 – 11:30 PLENARY LECTURE 1CHAIRPERSON: CHRISTOPHE GOURDONSPEAKER: JEAN CLAUDE CHARPENTIERTITLE: In The Framework Of Globalization, Sustainability And Technical Innovation Demand: Green Process Engineering In 2011, Quo Vamus?

11:30 – 13:00 PARALLEL SESSIONS SESSION 1 CHAIRPERSON: ABDUL AZIZ ABDUL RAMANTOPIC: ENERGY SESSION 2CHAIRPERSON: MOHD AZLAN HUSSEINTOPIC: ENVIRONMENT, SAFETY AND RISK MANAGEMENT

13:00 – 14:00 LUNCH

14:00 – 15:00 PLENARY LECTURE 2CHAIRPERSON: JIAN-FENG CHENSPEAKER: KHOO HOCK AUN TITLE : Business Aspects Of Biofuels In South East Asia: Sustainability, Technology And Innovation For Trade In The BiofuelsIndustry

CONFERENCEPROGRAMME

1


TUESDAY, 6th DECEMBER

15:00 – 16:15 PARALLEL SESSIONS SESSION 3CHAIRPERSON: PATRICK COGNETTOPIC: NEW REACTION MEDIA AND GREEN SOLVENTS SESSION 4 CHAIRPERSON: MAHAR DIANA BINTI HAMID TOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES

16:15 – 16:45 COFFEE BREAK/POSTER SESSION

16:45 – 18:00 PARALLEL SESSIONS SESSION 5CHAIRPERSON: GIANG VO-THANHTOPIC: NEW REACTION MEDIA AND GREEN SOLVENTS SESSION 6CHAIRPERSON: CHRISTOPHE GOURDONTOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES

END OF THE DAY

CONFERENCEPROGRAMME

WEDNESDAY, 7th DECEMBER

2


8:00 – 9:00 REGISTRATION

9:00 – 10:00 PLENARY LECTURE 3CHAIRPERSON: MOHD ALI HASHIMSPEAKER: SHIRO SAKATITLE : Technology Innovations In Biofuels And Biochemicals By Thermochemical Conversion


10:30 – 13:00 PARALLEL SESSIONS SESSION 7CHAIRPERSON: BRAHIM SI ALI TOPIC: ENERGYSESSION 8CHAIRPERSON: YEOH HAK KOONTOPIC: PROCESS DESIGN, MODELING AND OPTIMIZATION

13:00 – 14:00 LUNCH

14:00 – 16:00 PARALLEL SESSIONS SESSION 9CHAIRPERSON: CHE ROSMANI CHE HASSANTOPIC: ENVIRONMENT, SAFETY AND RISK MANAGEMENTSESSION 10CHAIRPERSON: NORBANI ABDULLAH TOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES


16:30 – 18:00 PARALLEL SESSIONS SESSION 11CHAIRPERSON: YATIMAH ALIAS TOPIC: NEW REACTION MEDIA AND GREEN SOLVENTS SESSION 12CHAIRPERSON: K.B. RAMACHANDRAN TOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES

20:00 NETWORKING DINNER

CONFERENCEPROGRAMME

THURSDAY, 8th DECEMBER

9:00 – 10:00 PLENARY LECTURE 4CHAIRPERSON: JEAN CLAUDE CHARPENTIERSPEAKER: DANIEL A. CROWL

3


TITLE: Process Safety - An Important Part Of Sustainable And Green Process Design


10:30 – 11:30 PLENARY LECTURE 5CHAIRPERSON: NIK MERIAM SULAIMANSPEAKER: THUMRONGRUT MUNGCHAROENTITLE: Practical Experience on Carbon Footprint of Products and Carbon Footprint of Organizations

11:30 – 13:00 PARALLEL SESSIONS SESSION 13CHAIRPERSON: WAN MOHD ASHRI WAN DAUDTOPIC: ENERGYSESSION 14CHAIRPERSON: BADRUL HISHAM MOHD JANITOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES

13:00 – 14:00 LUNCH

14:00 – 16:30 PARALLEL SESSIONS SESSION 15CHAIRPERSON: MARTINE POUXTOPIC: PROCESS DESIGN, MODELING AND OPTIMIZATIONSESSION 16CHAIRPERSON: EZZAT CHAN BIN ABDULLAH @ CHAN BENG KUANTOPIC: SUSTAINABLE AND CLEAN TECHNOLOGIES

16:30 – 17:00 COFFEE BREAK

17:00 – 18:00 CLOSING CEREMONY

SCHEDULE OFPARALLEL SESSION 1 (TUESDAY, 6th December)

ENERGY

11:30Keynote

Chairperson: Abdul Aziz Abdul RamanSpeaker: Richard Crop

Title: The Risk Of Green Energy – Why Green Power Does Not Equal Green Results ?

Paper ID

Title Authors

4


12:00 91

PURITY AND QUALITY OF BIODIESEL; A MAJOR CONCERN AS FUEL FOR DIESEL ENGINE CONSUMPTION: A CRITICAL REVIEW

ATADASHI IDRIS MUSA, AROUA MOHAMED KHEIREEDINE, ABDUL RAMAN ABDUL AZIZ, NIK SULAIMAN NIK MERIAM

12:15 277

SYNTHESIS AND CATALYTIC PROPERTIES OF Co/CeO2 NANOFIBERS FOR DIESEL SOOT COMBUSTION

ANIL KUMAR PULLUR, DEBORA FINO, NUNZIO RUSSO

12:30 23

ESTERIFICATION OF FREE FATTY ACIDS USING ION EXCHANGE RESINS AS A CATALYST: AN EFFICIENT PRE-TREATMENT METHOD FOR BIODIESEL PRODUCTION

SUMAIYA ZAINAL ABIDIN, BASU SAHA

12:45 297

PRODUCTION OF BIODIESEL FROM JATROPHA CURCAS IN A SINGLE STEP IN SITU TRANSESTERIFICATION PROCESS

FARIZUL KASIM, ADAM HARVEY


ENVIRONMENT, SAFETY AND RISK MANAGEMENT

Paper ID

Title Authors

11:30 231BTEX DEGRADATION AND MINERALISATION BY FENTON PEROXIDATION PROCESS

DIYA’UDDEEN BASHEER HASAN, ABDUL AZIZ ABDUL RAMAN, WAN MOHD ASHRI WAN DAUD

12:00 97

OPTIMIZATION OF PHOTOCATALYTIC DECOLORIZATION OF A TEXTILE DYE SOLUTION USING IMMOBILIZED TIO2 NANOPARTICLES ON CERAMIC PLATES

A. R. KHATAEE, M. FATHINIA

12:15 188TREATMENT OF TEXTILE INDUSTRY EFFLUENT USING ELECTROCOAGULATION

A. BHARADWAJ, V. KHANDEGAR , A.K. SAROHA

CHARACTERIZATION AND ADSORPTION N.N. AMRAN, A.M. SHARIFF, K.K. LAU, F. M.

5


12:30 247EQUILIBRIUM STUDIES FOR NATURAL GAS DEHYDRATION VIA ZEOLITES

HASHIM

12:45 135PINE NEEDLES AS INDICATOR FOR HEAVY METAL POLLUTION IN THE ATMOSPHERE OF TEHRAN CITY, IRAN

BEHROUZ KORD, MAJID SHAMSI,SARA POURABBASI

6



NEW REACTION MEDIA AND GREEN SOLVENTS

15:00Keynote

Chairperson: Patrick CognetSpeaker: Prof. Giang Vo-Thanh

Title: Chiral Ammonium and Imidazolium-based Ionic Liquids: Synthesis and Applications for Asymmetric Synthesis

Paper ID

Title Authors

15:30 50ANOMALOUS MIXING STATE OF IONIC LIQUIDS BASED SOLUTIONS

H. ABE, Y. IMAI AND Y. YOSHIMURA

15:45 107ELIMINATION OF FREE GLYCEROL FROM

PALM OIL-BASED BIODIESEL USING PHOSPHONIUM-BASED IONIC LIQUIDS ANALOGUES

KAVEH SHAHBAZ, FAROUQ SABRI MJALLI, MOHD ALI HASHIM, INAS M ALNASHEF

16:00 112IMPACT OF IONIC LIQUID 1-BUTYL-3-

METHYLPYRIDINIUM DICYANAMIDE TO ANAEROBIC TREATMENT

A. ŽGAJNAR GOTVAJN, E. TRATAR PIRC, P. ŽNIDARŠIČ-PLAZL, J. ZAGORC-KONČAN


7


SUSTAINABLE AND CLEAN TECHNOLOGIES

Paper ID

Title Authors

15:00 190CARBOXYLATION OF CARBON NANOTUBES USING ACOUSTIC CAVITATION AT ROOM TEMPERATURE

CHEE MENG NG, SIVAKUMAR MANICKAM

15:15 193OPTIMISATION OF THE TRAVELLING WAVE THERMOACOUSTIC ENGINE FEEDBACK LOOP

S.T. WEE, D.B. HANN, Y.A. ABAKR, P. RILEY

15:30 289COMPETITIVE ADSORPTION PROCESSES UNDER MICROWAVE

LEGRAS BENOIT, POLAERT ISABELLE, THOMAS MICHEL, ESTEL LIONEL

15:45 291EPOXIDATION OF VEGETABLE OILS UNDER MICROWAVE IRRADIATION

LEVENEUR SÉBASTIEN, LEDOUX ALAIN, ESTEL LIONEL , SALMI TAPIO

16:00 20COMPLETE RECYCLING OF CONCRETE USING MICROWAVE ASSISTED SELECTIVE FRACTURE

NICHOLAS LIPPIATT, FLORENT BOURGEOIS



8


16:45Keynote

Chairperson: Giang Vo-Thanh Speaker: Stephane SARRADE

Title: Green Solvents and Supercritical Fluids from Extraction to Renewable Energy and Nanomaterials Synthesis

Paper ID

Title Authors

17:15 234

GREEN SOLVENTS AND SUPERCRITICAL

FLUIDS FROM EXTRACTION TO RENEWABLE ENERGY AND NANOMATERIALS SYHTHESIS

K. PIZARRO, K. SEAUDEAU AND S. SARRADE

17:30 236

CARBON DIOXIDE SEQUESTRATION AS DIETHYL CARBONATE FROM ETHANOL IN SUPERCRITICAL CARBON DIOXIDE

F. GASC, S. THIEBAUD-ROUX, R. VALENTIN, Z. MOULOUNGUI

17:45 125

NEW CHALLENGES IN THE SEPARATION OF OLEFIN/PARAFFIN MIXTURES. INTEGRATED USE OF RTIL AND MEMBRANE CONTACTORS

MARCOS FALLANZA, ALFREDO ORTIZ, DANIEL GORRI, INMACULADA ORTIZ

18:00 142

CONTINUOUS ENZYMATIC SYNTHESIS OF BIODIESEL IN ILS/SCCO2 BIPHASIC SYSTEMS: THE USE OF SILP AS ENZYME IMMOBILIZATION SUPPORT

PEDRO LOZANOA, E. GARCÍA VERDUGOB, JUANA M. BERNALA M. PUCHEAULTC, M.I. BURGUETEB, S.V. LUISB AND MICHEL VAULTIER

18:15 172SUBCRITICAL WATER EXTRACTION OF GINGER OLEORESIN

MOHD SHARIZAN MD SARIP, NOOR AZIAN MORAD, MUSTAFA KAMAL,ABD AZIZ, NOR AZAH MOHD ALI, MOHD AZIZI CHE YUNUS, MOHD RADZI AHMAD AND MOHD SHAIRAZI ROMAINOR

18:30 16

SUPERCRITICAL CO2-CORROSION IN PIPE STEELS DURING CARBON CAPTURE AND STORAGE CCS

ANJA PFENNIG, BARBARA LINKE, SABRINA SCHULZE, AXEL KRANZMANN



Paper ID

Title Authors

16:45 228SUSTAINABLE PROCESSES FOR THE VALORIZATION AND REUSE OF A LIQUID WASTE : URINE

AURÉLIEN TRIGER, JEAN-STÉPHANE PIC, CORINNE CABASSUD

9


17:00 176CLEAN VALORIZATION OF BIOMASS WASTES INTO TRANSPORTATION FUELS

AUDREY HERNOUX, JEAN-MARC LÉVÊQU, ULLA LASSI,SONIA BOISSEAU, MARIE-FRANCE MARAIS

17:15 180A PROCESS TO RECOVER COPPER FROM TIN STRIP SOLUTIONS

SUDIPTA RO, RACHEL BUCKLE AND S. SOBRI

17:30 239SIMULTANEOUS DENITRIFICATION AND ORGANIC MATTER REMOVAL IN AN UNDIVIDED UPFLOW BIO-ELECTROCHEMICAL REACTOR

W. T. MOOK, W. S. LEE, S. Y. ONG, M. H. CHAKRABARTI, M. K. AROUA

17:45 80FATIGUE BEHAVIOR OF STONE MASTIC ASPHALT MIX REINFORCED WITH WASTE TYRE RUBBER

ASIM HASSAN ALI

SCHEDULE OFPARALLEL SESSIONS 7 (WEDNESDAY, 7th December)

ENERGY

Paper ID

Title Authors

10:30 279

INTEGRATED POLICY FOR BIO-ENERGY PRODUCTION: THE PUGLIA REGION CASE STUDY

BENSAID S., FINO D

10:45 90NUMERICAL MODELING OF A PARTIALLY PREMIXED BIOGAS FLAME

BENAROUS A., KOUADRI MOUSTEFAI S. KARMED D. AND LIAZID A.

THE EFFECT OF NICKEL PROMOTER ON MO- M. OSTADI, A. SHARIATI, A. GHARIBI

10


11:00 170AL2O3 BASED CATALYST OF REVERSE WATER GAS SHIFT REACTION

KHARAJI

11:15 130

ANNUAL PATTERN OF OPTIMIZED USE OF CLIMATIC DESIGN GUIDELINES BASED ON FANGER'S COMFORT MODEL, IN THE QUADRUPLE CLIMATES OF IRAN (CASE STUDIES: KERMAN, BUSHEHR, TABRIZ & RASHT)

MOHAMMAD ALI TARBIATJOO, MOHAMMAD HAGHSHENAS , SARA HOORVASH

11:30 295NUMERICAL AND EXPERIMENTAL APPROACH FOR ENERGY EFFICIENT INDOOR THERMAL ENVIRONMENT MODEL

LEONG WAI YIE

11:45 197CONSTRUCTION AND ASSESSMENT OF A PROPANE DRIVEN, ELECTRICITY-GENERATING COOKING SCORE-STOVE™

B.M. CHEN, RILEY, P.H., Y. A. ABAKR, D.B. HANN

12:00 174

MULTI-CRITERIA DECISION ANALYSIS FOR ASSESSMENT OF WIND POWER IN KAZAKHSTAN

OKAJIMA KEIICHI, UCHIYAMA YOHJI,AKHMETOV ALMAZ

12:15 158

BIOLOGICAL TREATMENT OF AGRO-INDUSTRIAL EFFLUENTS WITH THE AIM OF ENERGETICAL VALORIZATION

CHUPPA GRAZIELLA, ADELARD LAËTITIA, DIEUDONNE JULES, PETIT THOMAS

12:30 14THE STORAGE OF PURE METHANE IN ACTIVATED CARBON

ABIR SOLI


PROCESS DESIGN, MODELING AND OPTIMIZATION

Paper ID

Title Authors

10:30 7

PHOTOOXIDATIVE TREATMENT OF C. I. BASIC BLUE 3 SOLUTION BY UV/H2O2 PROCESS: OPTIMIZATION AND MODELING

KASIRI

10:45 169

ON-LINE MONITORING OF VINYL CHLORIDE POLYMERIZATION REACTION USING RAMAN SPECTROSCOPY

DOROBANTU MIRUNA, PRAT LAURENT, XUEREB CATHERINE, GOURDON CHRISTOPHE, LASUYE THIERRY

11:00 166

A STEAM THERMOLYSIS APPROACH TO RECOVER CARBON FIBRES FROM CFRP WASTE

SHENGYIN YE, YANNICK SOUDAIS, AREZKI BOUNACEUR, RADU BARNA

SIC STRUCTURED REACTOR FOR NIKITINE CLÉMENCE, ZANOTAMARIE-LINE ,

11


11:15 216CONTINUOUS PRODUCTION OF SILICONE OILS

BORNETTE FRÉDÉRIC, MEILLE VALÉRIE, PITAULT ISABELLEA, FUSTIER CÉLINE, GOURDON CHRISTOPHE, CABASSUD MICHEL, VIVIER RICHARD, RAMDANI KAMEL, FERRATO MARC

11:30 78THERMOCHEMICAL ANALYSIS OF SUB- AND SUPERCRITICAL WATER OXIDATION OF BIOMASS-RELATED COMPOUNDS FOR GREEN POWER PROCESSES

YUYA HIRAGA, TOMOHIRO ARAI, KUNIO ARAI, TAKU M. AIDA

11:45 268

PRODUCTION OF SILICA BY THE GASEOUS PHASE HYDROLYSIS OF TETRAETHOXYSILANE

DABOUSSI OLFA, WAKAMORI YUJI, KATO SHIGERU, SATOKAWA SHIGEO,YAMASAKI AKIHIRO AND KOJIMA TOSHINORI

12:00 270GAS PHASE SYNTHRSIS OF TiO2 FOR PHOTOCATALYST

KOJIMA TOSHINORI, SHIOI MASAHIKO, YAMAKAWA TOKO,SAKAI YUKA AND YAMASAKI AKIHIRO

12:15 301OPTIMIZATION OF POLYHYDROXYBUTYRATE (PHB) PRODUCTION FROM GLYCEROL BY PARACOCCUS DENITRIFICANS

KALAIYEZHINI D, RAMACHANDRAN K. B

12:30 290MODELLING OF A LIQUID-LIQUID-SOLID HETEROGENEOUS REACTION SYSTEM: APPLICATION TO THE SYNTHESIS OF PEROXY FATTY ACIDS

LEVENEUR SÉBASTIEN, FILHO CESAR A. DE ARAUJO, ESTEL LIONEL , SALMI TAPIO



Paper ID

Title Authors

14:00 64

PREPARATION OF ACTIVATED CARBON FROM GARCINIA MANGOSTANA SHELL FOR ADSORPTION OF CADMIUM ION FROM AQUEOUS SOLUTION

KANG YEE LI, AZRINA ABD AZIZ, SHALIZA IBRAHIM, PICHIAH SARAVANAN

14:15 272

INFLUENCE OF HNO3 OXIDATION ON SURFACE CHEMISTRY, POROSITY AND PHENOL ADSORPTION

SOUDANI NOUHA, NAJAR-SOUISSI SOUAD, OUEDERNI ABDELMOTTALEB

14:30 121

CHITOSAN-FE0 NANOPARTICLES: SYNTHESIS, CHARACTERIZATION AND OPTIMUM CONDITIONS FOR REMOVAL OF ACID RED 14

M. RASOULIFARD, O. VALINEZHAD ORANG, N. NOZAD ASHAN

12




Paper ID

Title Authors

14:00 249MICROWAVE ASSISTED EXTRACTION OF MANGIFERIN FROM CURCUMA AMADA

PADMAPRIYA K, SURABHI CHAUDHURI, DEBJANI DUTTA

14:15 198

INFLUENCE OF STERILIZATION TIME TO ENZYMATIC DESTRUCTION PROCESS FROM THE MICROWAVE STERILIZATION OF OIL PALM FRUITS

MAYA SARAH AND MOCH. ROZAINEE TAIB

14:30 36CLEANER AND SUSTAINABLE METHOD FOR ALKENE EPOXIDATIONS BY POLYMER-SUPPORTED Mo(VI) CATALYSTS

KRZYSZTOF AMBROZIAK, RENE MBELECK, BASU SAHA AND DAVID SHERRINGTON

14:45 211ELECTRODEPOSITION OF NICKEL PATTERN WITHOUT PHOTOLITHOGRAPHY OF SUBSTRATES

T. WIDAYATNO AND S. ROY

15:00 145TIME ON STREAM ACTIVITY OF NON CHROMIUM CATALYST FOR HYDROGENOLYSIS OF GLYCEROL

RASIKA MANE, CHANDRASHEKHAR

15:15 149INFLUENCE OF A CO-METAL IN Cu CATALYZED HYDROGENOLYSIS OF GLYCEROL TO 1,2-PROPANEDIOL

RASIKA MANE, CHANDRASHEKHAR RODE

15:30 222HETEROGENEOUS REACTION WITH SOLID CATALYST IN MICROFLUIDIC DEVICES

FLAVIE SARRAZIN

13


15:40 192

MICROWAVE ASSISTED PROCESSES AND PHOTOCHEMISTRY TO SYNTHESIZE AND GRAFT PHOSPHONATES: APPLICATION TO MEDICAL IMPLANTS

SAUER CAROLE, MARCHAND GILLES, HOANG ANTOINE, TOULLEC PATRICK, VINET FRANÇOISE, MICHELET VÉRONIQUE

16:00 117

INVESTIGATION ON ELECTROCHEMICAL ROUTE FOR SYNTHESIS OF METAL (CU AND FE) ORGANIC FRAMEWORKS: CHARACTERIZATIONS AND ITS CATALYTIC ACTIVITY

R. SENTHIL KUMAR, S. SENTHIL KUMAR AND M.ANBU KULANDAINATHAN



Paper ID

Title Authors

16:30 163CO2 ABSORPTION USING A MIXTURE OF IONIC LIQUID AND ALKANOLAMINES

NOORHALIZA AZIZ, ROZITA YUSOFF,MOHAMED KHEREIDDINE AROUA

16:45 164

INVESTIGATING THE STABILITY OF SUPEROXIDE ION-RADICAL IN BIS (TRIFLUOROMETHYLSULFONYL) IMIDE-BASED IONIC LIQUIDS

MAAN HAYYAN, FAROUQ S. MJALLI, MOHD ALI HASHIM, INAS M. ALNASHEF

17:00 173VAPOR PRESSURE OF AQUEOUS SOLUTIONS OF CHOLINE CHLORIDE-BASED DEEP EUTECTIC SOLVENTS

SHENG-HONG WU, RHODA B. LERON, AND MENG-HUI LI

17:15 244SEPARATION OF GLUCOSE AND FRUCTOSE USING IONIC LIQUIDS

MOHAMED K. HADJ-KALI, MOHD A. HASHIM, MOHAMMAD Q. AL-HAJ ALI, FAROUQ S. MJALLI, INAS M. ALNASHEF

17:30 305COSMO-RS BASED SCREENING IONIC LIQUIDS FOR SEPARATION OF BENZENE AND CYCLOHEXANE

G. GONFA, M.A. BUSTAM

14




Paper ID

Title Authors

16:30 13STARCH STABILIZED ZEROVALENT IRON NANOPARTICLES FOR CR(VI) REMOVAL FROM AQUEOUS SOLUTION

A. R. KHATAEE, A. REYHANITABAR, L. ALIDOKHT, S. OUSTAN

16:45 98

STUDY OF ADVANCED OXIDATION PROCESS AND BIOLOGICAL TREATMENT MECHANISMS FOR AZO DYE INDUSTRIAL EFFLUENT

FAHMI RIDWAN, CHE ZULZIKRAMI AZNER ABIDIN, NAZERRY ROSMADY RAHMAT

17:00 141

A COMPARATIVE STUDY OF HEAVY METAL REMOVAL BY ACID, CHELANT AND NATURAL SURFACTANT WASHING FROM ALLUVIUM SOIL WITH HIGH IRON CONTENT OBTAINED FROM KLANG VALLEY, MALAYSIA

BHASKAR SEN GUPTA, MOHD ALI HASHIM, JAYA NARAYAN SAHU, YUSOFF ISMAILSOUMYADEEP MUKHOPADHYAY

17:15 265DECOMPOSITION OF ORGANIC COMPOUNDS IN WASTEWATER BY ADVANCED OXIDATION PROCESSES

TAKUMA YASUHIKO, FUJITA HIROYUKI, SUGIMORI HIROKAZU,KATO SHIGERU, KOJIMA TOSHINORI

17:30 266FENTON REACTION MECHANISM WITH LOW CONCENTRATION OF FERROUS IONS AND IRON POWDER

ENDO GO, TAKUMA YASUHIKO, SAITO HIROKI, KATO SHIGERU, SATOKAWA SHIGEO AND KOJIMA TOSHINORI

17:45 12SYNTHESIS OF NANO CATALYSTS FOR WASTEWATER TREATMENT

OROZCO-CERROS S.L., BARRERA-ANDRADE J.M., VALVERDE-AGUILAR G., GARCÍA-MACEDO J.A., RÍOS-ENRÍQUEZ M.A., DURÁN-DOMÍNGUEZ-DE-BAZÚA M.C.

15


SCHEDULE OFPARALLEL SESSIONS 13 (THURSDAY, 8th December)

ENERGY

Paper ID

Title Authors

11:30 264

BEHAVIOR OF ALKALINE AND ALKALINE EARTH METAL ELEMENTS IN BIOMASS DURING ITS PYROLYSIS PROCESS

KATAYAMA DAIKI, IWASAKI TOSHIYUKI, SUGANUMA HIDEKI, KATO SHIGERU,YAMASAKI AKIHIRO, SATOKAWA SHIGEO AND KOJIMA TOSHINORI

11:45 19UPGRADING OF BIOMASS PROPERTIES VIA TORREFACTION

J.J. CHEW A, V. DOSHI A, E.J. LOH

12:00 77

STUDY ON GAS RELEASE DURING TORREFACTION OF WOODY BIOMASS AND ITS CONSTITUENTS FOR INJECTION IN ENTRAINED FLOW GASIFIER

NOCQUET TIMOTHÉEA, DUPONT CAPUCINEA, COMMANDRE JEAN-MICHELB, SOUDAIS YANNICKC, BOACHON CÉLINEC, SALVADOR SYLVAIN

12:15 108MODELING OF A PRESSURIZED ENTRAINED FLOW BIOMASS GASIFIER IN ASPENPLUS

JIM ANDERSSON, JOAKIM LUNDGREN

12:30 258

CATALYTIC FAST PYROLYSIS OF PHYSIC NUT (JATROPHA CURCAS L.) WASTE WITH HYDROTHERMALLY TREATED HZSM-5 ZEOLITE

SUPAWAN VICHAPHUND, DUANGDAO AHT-ONG, VIBOON SRICHAROENCHAIKUL, DUANGDUEN ATONG

16




Paper ID

Title Authors

11:30 288KINETICS OF CO2 ABSORPTION IN THE PRESENCE OF IMPURITIES

WANG MAXIME, LEDOUX ALAIN, ESTEL LIONEL

11:45 33CARBON DIOXIDE CAPTURE USING HOLLOW FIBRE CONTACTORS AND IONIC LIQUIDS

JONATHAN ALBO AND ANGEL IRABIEN

12:00 62SUPERCRITICAL ANTI-SOLVENT RECRYSTALLIZATION OF COLUMN ELUTION FRACTIONATED CAROTENOIDS FROM NANOCHROLOPSIS OCULATA AND LYCIUM BARBARUM

CHIEH-MING J. CHANG, SIANG-EN HONG, LI-PIN CHANG, YI-CHEN SHEN, BING-CHUNG LIAU, SHIH-LAN HSU

12:15 103ELECTRODEPOSITION OF LEAD-FREE SOLDER FOR GREEN ELECTRONICS

YINGXIN GOH, A.S.M.A. HASEEB, MOHD FAIZUL MOHD SABRI

17




14:00Keynote

Chairperson: Martine PouxSpeaker: Jean Marie Aubry

Title: A Further Step Towards “GREEN ALKAHEST” Through The Design And The Classification In Silico Of New Eco-Friendly Solvents: Application To Glycerol-Based

Solvents

Paper ID

Title Authors

14:30 300

RAINBOW REFRACTOMETRY TO CHARACTERIZE HEAT AND MASS TRANSFERS IN A CO2 ABSORPTION PROCESS

TAGUTCHOU JEAN-PHILIPPE, SAENGKAEW SAWITREE, ESTEL LIONEL, GREHAN GÉRARD

14:45 24MODELING OF CARBON DIOXIDE ADSORPTION IN A MONOLITHIC COLUMN

YI PENG TEOH, THOMAS S.Y. CHOONG AND IMAN BAYESTI

15:00 29SIMULATION OF A NOVEL AND GREEN SUPERSONIC GAS LIQUID SEPARATION UNIT

B.MAHMOUDZADEH VAZIRI, A. SHAHSAVAND, M.GHANBARI, A. GARMROODI ASIL, HAMID REZA RASHIDI

15:15 257

A FURTHER STEP TOWARDS “GREEN ALKAHEST” THROUGH THE DESIGN AND THE CLASSIFICATION IN SILICO OF NEW ECO-FRIENDLY SOLVENTS: APPLICATION TO GLYCEROL-BASED SOLVENTS

AUBRY J.M, MOITY L, MOLINIER V. BENAZZOUZ A. DURAND M. PIERLOT C. RATAJ V. GERBAUD V. HEINTZ J. PANDYA N. TELES DOS SANTOS M. MOULOUNGUI Z. DE CARO P. THIEBAUD-ROUX S. ALRIC I. FABRE J.F. NARALINGOM A. BERGEZ-LACOSTE M. MARION P. BALASTRE M.

15:30 88INVESTIGATING THE SENSITIVITY OF DIFFERENT FUELS FED TO SOLID OXIDE FUEL CELLS

S. AHMAD HAJIMOLANA, M. AZLAN HUSSAIN , W. M. ASHRI WAN DAUD

15:45 208LIQUID-LIQUID DISPERSION IN CO-CURRENT PULSED COLUMN

LOBRY EMELINE, GOURDON CHRISTOPHE, XUEREB CATHERINE, LASUYE THIERRY

16:00 21EFFECT OF HEAT TREATEMENT ON THE FATIGUE PERFORMANCE OF CARBON STEEL MATERIALS

RAMADAN O.SAIED AND MOHAMED A. GERBIL

16:15 286A PARTIALLY HEAT INTEGRATED REACTIVE DISTILLATION: SIMULATION AND ANALYSIS

SANTOSH V. MALI AND AMIYA K. JANA

18


16:30 146MOLECULAR DYNAMICS SIMULATION: AN ALTERNATIVE IN GREEN CRYSTALLISATION PROCESS DESIGN



Paper ID

Title Authors

14:00 155ECO-FRIENDLY CORROSION INHIBITOR FOR REINFORCED CONCRETE

A. S. ABDULRAHMAN, MOHAMMAD ISMAIL, MOHAMMAD SAKHAWAT HUSSAIN,

14:15 99IS IT STILL POSSIBLE TODAY TO CONCEIVE DRYING WITHOUT DIC?

ALLAF TAMARA AND MIH ISMAIL

14:30 167NICKEL-BASED FILTERS FOR HOT GAS CLEANING IN FLUIDIZED BED GASIFIER

S. RAPAGNÀ, K. GALLUCCI, M. DI MARCELLO, M. NACKEN S. HEIDENREICH P.U. FOSCOLO

14:45 89INNOVATIVE EXTRACTION PROCESS COMBINATION

ALLAF TAMARA, TOMAO VALÉRIE, CHEMAT FARID

15:00 40THE DEVELOPMENT OF GREEN MANUFACTURING: WHERE ARE WE TODAY?

ALEXANDER CHEE HONC CHEONG

15:15 241SUSTAINABLE URBAN DEVELOPMENT AND IRANIAN SUSTAINABLE URBAN DEVELOPMENT

HAMED AYALISAHAR SADEIAN

15:30 320SUSTAINABLE GREEN ENGINEERING INITIATIVE: REUSED PLASTIC BAGS FOR REINFORCEMENT GEOSYNTHETICS

X. RAMELA B. RAMIREZ, RCE, MMEM

15:45 101GREEN PRODUCTION IN CONCRETE INDUSTRY AND THE ROLE OF NANOTECHNOLOGY

MOHAMAD IBRAHIM MOHAMADPAYAM HOSSEINIS. RAFIEIMOHAMMAD ALI NEKOOIE,

16:00 261A LOW COST, CARBON FRIENDLY AND MODULAR DESIGNED VIBRATING MEMBRANE PROCESS

DANIEL M. CHENG, VICTOR C. LI

16:15 115

POLYSILOXANE NANOPARTICLES MODIFICATION FOR DURABLE AND BREATHABLE SUPERHYDROPHOBIC TEXTILES

K. FIROZ BABU AND M. ANBU KULANDAINATHAN

19


LIST OFPOSTERS (ENERGY)

ENERGY

Paper ID Title Authors

18THE INFLUENCE OF ALLOYING ELEMENTS TO ACHIEVING THE MECHANICAL PROPERTIES OF HIGH TENSILE MATERIALS

MOHAMMED A. GEBRIL

61SOLAR-H2 FUEL CELL: A CLEAN ENERGY FOR THE 21st CENTURY

M. BELLO, A. ABDALLAH, A. AL-AHMED, S. M. J. ZAIDI

67

THE INVESTIGATION OF WATER GAS SHIFT REACTION ACTIVITY OF SIMULATED COAL GAS WITH COMMERCIAL CATALYSTS USING FLUIDIZED BED REACTOR

SANG TAE PARK, JUNG MIN SOHN, SANG MUN JEONG, KYEONG YOUL JUNG, SEE HOON LEE

69CO2 CAPTURE FROM FLUE GAS BY ALKANOLAMINE IN A ROTATING PACKED BED

YU CHENG-HSIU, CHENG HSU-HSIANG, TAN CHUNG-SUNG

72FEASILITY STUDY OF SMALL SCALE SOLAR CHIMNEY POWER PLANT

TAYLOR LIM, CLARENCE LEONG, DIRK GERHARD RILLING, W.H TAN

74

COMBINED WATER OXYGEN PINCH ANALYSIS WITH MATHEMATICAL PROGRAMMING TO REDUCE THE COST OF WASTEWATER TREATMENT PLANT IN ARAK REFINERY

ZAHRA JANDAGHIAN

82

INTEGRATION OF PERFORMANCE BASED MODELING TECHNIQUES WITH BUILDING DESIGN METHOD (INDUSTRY/FACTORY) CONSIDERING ENERGY EFFICIENCY IN BANGLADESH

SAJAL CHOWDHURY AND MD. RABIUL ALAM

87SIMULATION OF SAVONIUS ROTOR AS A VERTICAL AXIS WIND TURBINE FOR GREEN ENERGY PRODUCTION

MANSOUR SHIRVANI, MOHAMMADHASAN KHANOF, MAJID JAMIL,SEYEDMEHDI SHARIFIAN

95DIC APPLICATION FOR THE RECOVERY OF MICROALGAE

BESOMBES COLETTE, KAMAL IBTISAM, ALLAF KARIM

106CORROSION MECHANISM OF ALUMINUM IN PALM BIODIESEL

K.V. CHEW, A.S.M.A. HASEEB, H.H. MASJUKI

111A FEASIBILITY STUDY OF BIOETHANOL PRODUCTION USING GRASSES

SOON ONN LAI

113ELECTRICITY GENERATION FROM LIGNOCELLULOSIC BIOMASS USING SINGLE CHAMBERED MICROBIAL FUEL CELL (SCMFC)

NIK MAHMOOD, N.A, MD GHAZALI, M.N.F, IBRAHIM, K.A AND MENG, L.C.

134SOLUBILITY AND ELECTRICAL CONDUCTIVITY OF COMMON SODIUM SALTS IN SELECTED IONIC LIQUIDS

INAS M. ALNASHEF

20



ENERGY


139OPTIMAL OPERATION OF AIR POLLUTION CONTROL TECHNOLOGY DEVICES FOR COAL COMBUSTION PLANTS

JORGE CRISTOBAL, GONZALO GUILLEN-GOSALBEZ, LAUREANO JIMENEZ, ANGEL IRABIEN

307PERFORMANCE OF MONTMORILLONITE CLAY IN THE BLEACHING OF PALM OIL

FARIHAHUSNAH HUSSIN, MOHAMED KHEIREDDINE AROUA, WAN MOHD ASHRI WAN DAUD, LEE CHING SHYA

154THE EFFECT OF LUMINIOUS ENVIRONMENT AND OCCUPANT SATISFACTION FOR OFFICE BUILDINGS IN HOT-HUMID CLIMATE OF MALAYSIA: A SURVEY

AR. ELINA MOHD HUSINI , MOHD ZIN KANDAR

160

CHEMICAL AND THERMAL CHARACTERIZATION OF SEWAGE SLUDGE FROM WWTP´S IN CANTABRIA (SPAIN)

JOSEFA FERNÁNDEZ AND M JOSEFINA RENEDO

161EVOLUTION OF THE SORBENT STRUCTURE IN THE SIMULTANEOUS RETENTION OF CO2 AND SO2 BY Ca (OH)2

M JOSEFINA RENEDO, CARMEN PESQUERA, FERNANDO GONZÁLEZ, BELÉN ORTIZ AND JOSEFA FERNÁNDEZ

171ELECTROCHEMICAL CHARACTERIZATION OF HIGH-CAPACITY PYROLYTIC CARBONS DERIVED FROM PEANUT SHELLS

GEORGE TING-KUO FEY, YU-YEN LIN, T. PREM KUMAR, KAI-PIN HUANG, AND YI-CHUAN LIN

179

STUDY ON THE HYDROGEN GAS PRODUCTION PROCESS FROM WASTEWATER VIA THE ELECTROCHEMICAL METHOD IN A BATCH REACTOR: A PRELIMINARY STUDY

AZWAR, M.A. HUSSAIN AND A.K. ABDUL-WAHAB

194

OPTIMIZATION OF PRE-TREATMENT PROCESS FOR IMPROVEMENT OF LIPIDS EXTRACTION FROM MUNICIPAL WASTEWATER SLUDGE FOR BIODIESEL PRODUCTION

M. OLKIEWICZ, A. FORTUNY, F. STÜBER, A. FABREGAT, J. FONT, C. BENGOA

202CURRENT SITUATION OF WIND ENERGY POTENTIAL IN MALAYSIA

NURHAYATI ROSLY

215INTENSIFICATION OF THE ATTRITION PROCESS IN FLUIDIZED BED REACTORS

TAREK J. JAMALEDDINE, CEDRIC BRIENS, FRANCO BERRUTI


21


ENERGY


226DEVELOPMENT OF MEMBRANES AND MEMBRANE-ELECTRODE ASSEMBLIES WITH PROTON AND ELECTRON CONDUCTING ENHANCEMENT FOR FUEL CELLS

JIN-SOO PARK, MUN-SIK SHIN, MOON-SUNG KANG

229BIODIESEL PRODUCTION FROM HIGH FREE FATTY ACID KARANJA AND JATROPHA CURCAS OIL

VENU BABU BORUGADDA, VAIBHA V. GOUD

243

OPTIMIZATION ANALYSIS OF COAL TRANSPORTATION FOR INTRODUCING ADVANCED COAL-FIRED POWER GENERATION TECHNOLOGY IN CHINA

UCHIYAMA YOHJI, UENO HIROSHI, OKAJIMA KEIICHI

253CARBON DIOXIDE SEPARATION PROCESS FOR CES OXY-FUEL COMBUSTOR

DAVID KUPKA, JAN KOLONICNY

259

EFFECT OF TRI-METALLIC NI-MG-LA CATALYSTS BY CO- AND SEQUENTIAL-IMPREGNATION IN STEAM TOLUENE REFORMING

SILDARA THASSANAPRICHAYANONT, DUANGDUEN ATONG, AND VIBOON SRICHAROENCHAIKUL

293AXELERA FRENCH CLUSTER : ECO-EFFICIENT PROCESS FOR FACTORY OF THE FUTURE

RAMDANI KAMEL, DE BELLEFON CLAUDE

LIST OFPOSTERS (NEW REACTION MEDIA AND GREEN SOLVENTS)


22



104HYDROGENATION OF AROMATIC COMPOUNDS IN CO2-EXPANDED LIQUID

LIN HSIN-WEI, YEN CLIVE H.,CHEN TENG-YANG, PHAN THE DUY, TAN CHUNG-SUNG

123IMPREGNATION OF BENZOIC ACID ONTO ORGANO-CLAY BY USING SUPERCRITICAL CO2 AND ITS CHARACTERIZATION

OZER GÖK, A. S. OZCAN AND A. OZCAN

150CFD COUPLED TO POPULATION BALANCE: A STRATEGIC TOOL TO DESIGN CRYSTALLIZATION OPERATIONS CARRIED OUT WITH SUPERCRITICAL CO2

ERRIGUIBLE ARNAUD, FADLI TARIK, SUBRA-PATERNAULT PASCALE

162CONDUCTOR-LIKE SCREENING MODEL FOR REAL SOLVENTS PREDICTION FOR DESULPHURISATION OF MODEL OIL USING IONIC LIQUIDS

MOHD RAFIN MOHAMED RAMLI

177ADIPIC ACID PRODUCTION IN WATER MICROEMULSIONS : FROM SMALL SCALE TO PILOT PROCESSES

PEREZ EMILE, FRANCESCHI-MESSANT SOPHIE, BLACH PHILIPPE, RICO-LATTES ISABELLE, LATTES ARMAND, POUX MARTINE, COGNET PATRICK, GEOFFROY LESAGE, ISARIEBEL QUESADA PEÑATE

238

TOP-DOWN STRATEGY FOR THE DESIGN OF A GREEN “ALKAHEST” SOLVENT BY USING COMPUTER AIDED MOLECULAR DESIGN. APPLICATION TO GLYCEROL-BASED AGRO-RESOURCE

GERBAUD V., HEINTZ J., PANDYA N., TELES DOS SANTOS M

246FORMATION OF ALKYLANILIDES FROM FATTY ACIDS AND ANILINE IN AQUEOUS MEDIUM

F. MALKI, A. TOUATI

254BIODIESEL PRODUCTION VIA SUPERCRITICAL METHOD USING BIO-ETHANOL AS CO-SOLVENT

MARTINA CHIAPPERO, NUNZIO RUSSO, DEBORA FINO

273BLOCK MOLECULES BASED ON GLYCEROL SKELETON AS C3 BUILDING BLOCKS FOR ALTERNATIVE SOLVENTS

MOULOUNGUI ZÉPHIRIN, FABRE JEAN-FRANÇOIS, DE CARO PASCALE, THIEBAUD-ROUX SOPHIE, ALRIC ISABELLE, NARALINGOM ANTHONY, BERGEZ-LACOSTE MANON

274COMPUTER-AIDED DESIGN OF FURFURAL-BASED MOLECULES MATCHING SPECIFICATIONS AS ECOFRIENDLY SOLVENTS

BERGEZ-LACOSTE MANON, DE CARO PASCALE, THIEBAUD-ROUX SOPHIE, ALRIC ISABELLE, FABRE JEAN-FRANÇOIS, MOULOUNGUI ZÉPHIRIN

292CHIRAL AMMONIUM AND IMIDAZOLIUM-BASED IONIC LIQUIDS: SYNTHESIS AND APPLICATIONS FOR ASYMMETRIC SYNTHESIS

GIANG VO-THANH

319 CARBON DIOXIDE SOLUBILITY AND RATE OF ABSORPTION IN AQUEOUS MIXTURES OF METHYLDIETHANOLAMINE AND IMIDAZOLIUM-BASED IONIC LIQUIDS

AHMADY AFSHIN AROUA, MOHAMED KHEIREEDINE

LIST OFPOSTERS (ENVIRONMENT, SAFETY AND RISK MANAGEMENT)



9

APPLICATION OF MICROFILTRATION MEMBRANES ASSOCIATED WITH ACTIVATED CARBON TO REMOVE

FLÁVIA VIEIRA DA SILVA, CAMILA CUMANI PAVEZZI, ALUIZIO TORRES DA SILVA JUNIOR,

23


THM AND THM PRECURSORS FROM DRINKING WATER

GILSELAINE AFONSO LOVATO, CÉLIA REGINA GRANHEN TAVARES, ROSÂNGELA BERGAMASCO

15CORROSION INHIBITION OF STAINLESS STEELS IN PHOSPHORIC ACID BY NATURAL ORES

A. GUENBOUR, F. MIFTAH, A. BELLAOUCHOU, A. BEN BACHIR J. GARCÍA-ANTÓN; E. BLASCO-TAMARIT; D.M. GARCÍA-GARCÍA

45USE OF POROUS MEDIA IMPREGNATED WITH METAL TO REMOVE GIARDIA

QUELEN L. SHIMABUKU, ROSÂNGELA BERGAMASCO, LETÍCIA NISHI, FLÁVIA S. ARAKAWA, FLÁVIA V. SILVA, FERNANDO ALVES SILVA, CAROLE SILVEIRA

308AMORPHOUS SILICA FROM BAMBOO LEAVES (PHYLLOSTACHYS AUREA) AND COGONGRASS (IMPERATA CYLINDRICA)

KOW KIEN WOH, ROZITA YUSOFF, ABDUL AZIZ A. RAMAN

65WET WEIGHT AND DRY WEIGHT ANALISYS OF PASPALUM SCROBICULATUM L. Hack IN CONTAMINATED SOIL

SALMI NUR AIN SANUSI, SITI ROZAIMAH SHEIKH ABDULLAH

94PRODUCTION OF LACTIC ACID FROM PALM OIL MILL EFFLUENT (POME)

NUR SHAZWANI ZAINAL ABIDIN AND RAKMI ABD RAHMAN

96

RISK ASSESSMENT AND APPROACHES FOR GREEN PROCESS DEVELOPMENT AND ENGINEERING DESIGN

NHAN NGUYEN

120

SPECTROPHOTOMETRIC ANALYSIS OF ADSORPTION OF A DYE MIXTURE BY Mg/Al-NO3-LAYERED DOUBLE HYDROXIDE

SUMARI S.MARIAM; HAMZAH, ZAINI AND SAMSUDIN, S.S ADAWIAH

137ZERO-VALENT IRON NANOPARTICLES: CHEMICAL SYNTHESIS AND OPTIMUM CONDITIONS FOR THE DECOLORIZATION OF REACTIVE NAVY BLUE SP-BR SOLUTION

S. ABER, N. NOZAD ASHAN, A. R. KHATAEE

143ASSESMENT OF SLUDGE BASED MATERIALS FOR WATER TREATMENTS: ADSORPTION, OXIDATION, AND SEQUENTIAL ADSORPTION-OXIDATION

C. JULCOUR LEBIGUE, C. ANDRIANTSIFERANA, N. KROU, C. AYRAL, E. MOHAMED, H. DELMAS

144UPTAKE OF LEAD BY MELASTOMA MALABATHRICUM L. FROM CONTAMINATED SOIL

SITI NORLEELA SELAMAT, SITI ROZAIMAH SHEIKH ABDULLAH, MUSHRIFAH IDRIS

LIST OFPOSTERS (ENVIRONMENT, SAFETY AND RISK MANAGEMENT)



156INVESTIGATION OF DIOCTYL PHTHALATE MIGRATION FROM PVC INTO SALIVA

KAHINA BOUCHAKOUR, MOHAND OUIDIR BOUSSOUM, NAIMA BELHANECHE- BENSEMRA

159THE WATER BALANCE CHANGES OF THE ARAL SEA, AFTER 1960

BEHZOD GAYBULLAEV

24


165MIGRATION OF BHT AND ITS UVB PRODUCTS DEGRADATION FROM POLYSTYRENE FILMS INTO FATTY FOOD SIMULANT

CHAFIA ZEDDAM, NAIMA BELHANECHE- BENSEMRA, LAN TIGHZERT

196CLEANER PRODUCTION OF BAGASSE WITH POTASH (KOH)

SOMAYEH GHASEMI, RABI BEHROOZ

207P-NITROPHENOL DEGRADATION UNDER MILD CONDITIONS EMPLOYING ZERO VALENT IRON AND DIFFERENT CHELATING AGENTS

I. COTA, A. FORTUNY, F. STÜBER, A. FABREGAT, J. FONT, C. BENGOA

248EVALUATION OF 2-AMINO-2-METHYL-1-PROPANOL AS A SOLVENT FOR CO2 ABSORPTION AT ELEVATED PRESSURE

GHULAM MURSHID, AZMI MOHD SHARIFF, LAU KOK KEONG, MUHAMMAD AZMI BUSTAM AND FAIZAN AHMAD

283CATALYTIC OXIDATION OF VOLATILE ORGANIC COMPOUNDS (VOCS). OXIDATION OF TOLUENE OVER Pd /MESOPOROUS MATERIALS CATALYSTS

H. AZZI, K. BENDAHOU, L. CHÉRIF, F. HAMIDIA, S. SIFFERT, A. BENGUEDDACH, A. ABOUKAIS

284REMOVAL OF LEAD(II) FROM AQUEOUS SOLUTION USING MESOPOROUS CARBON CMK-3

R. BOURI, L. CHERIF and R. DENOYEL

285

HETEROGENEOUS FENTON DEGRADATION OF PHENOLIC AQUEOUS SOLUTIONS OVER IRON-CONTAINING SBA-15 CATALYST

Z. BAILICHE, L.CHERIF, S. FOURMENTIN, S. SIFFERT, A. BENGEDDACH

287 INFLUENCE OF FLY ASHES ON MASS TRANSFER TAGUTCHOU JEAN-PHILIPPE, ESTEL LIONEL, LEDOUX ALAIN, WANG MAXIME

306PRODUCTION OF POROUS MEDIA FILTER TO REMOVE BACTERIA FROM DRINKING WATER

ARAKAW, F.S., SHIMABUKU,Q.L., VIEIRA DA SILVA, F., SILVA, F.A, WURZLER, G.T, MARTINS, T.B.,GARCIA, F.P., BERGAMASCO R

LIST OFPOSTERS (PROCESS DESIGN, MODELING AND OPTIMIZATION)



26

COSMECUTICAL VALUES OF CASHEW LEAVES EXTRACT, ANTIMICROBIAL ACTIVITIES AND ANTIOXIDANT PROPERTIES

SIAVASH HOSSEINPOUR CHERMAHINI, FADZILAH ADIBAH ABDUL MAJID

32EFFECT OF TWIST RATIO ON HEAT TRANSFER INTENSIFICATION BY MODIFIED DESIGNS OF TWISTED TAPE PIPE INSERTS

KUMAR PERUMAL AND RAJAMOHAN GANESAN

34APPLICATION OF A LIPASE-IMMOBILIZED SILICA MONOLITH BIOREACTOR TO PRODUCTION OF BIODIESEL

RYO TAKAHASHI, YASUHIRO ODA, TAKAYUKI TAKEI, HIROYUKI IJIMA, KOEI KAWAKAMI

25


37LOW POWER PASSIVE PHOTOVOLTAIC SYSTEM DEVELOPMENT TO ASSIST INCONVENIENT GRID CONNECTION LOCATIONS

S. S. S. RANJIT

54COMPOSTING AND VERMICOMPOSTING OF FRUIT AND VEGETABLE WASTES

MARIA CRISTINA RIZK, ROSÂNGELA BERGAMASCO, CÉLIA REGINA GRANHEN TAVARES

57PHOTOVOLTAIC SOLAR ELECTRO-OXIDATION PROCESS: MODELING, DESIGN AND APPLICATIONS

ENRIQUE ALVAREZ-GUERRA, ANTONIO DOMINGUEZ-RAMOS, ANGEL IRABIEN

70ADVANCED MATHEMATICAL MODEL AND CONTROL SYSTEM TO DESCRIBE PRODUCTION PROCESS OF BIO-DIESEL

AHMMED S IBREHEM

71MATHEMATICAL MODEL TO AGITATED FLUIDIZED BED GRANULATION OF GINGER TEA POWDER

AHMMED S IBREHEM

83

IMPACT OF THE INSTANT CONTROLLED PRESSURE DROP (DIC) TREATMENT ON DRYING KINETICS AND CAFFEINE EXTRACTION OF GREEN COFFEE BEANS

KAMAL IBTISAM AND ALLAF KARIM

85UV-IRRADIATED PHOTOREACTOR MODELING FOR ADVANCED OXIDATION PROCESSES DESIGN

BRUNO RAMOS; ANTONIO C. S. C. TEIXEIRA

86MODELING OF A SOLAR-DRIVEN PHOTOREACTOR FOR PHOTO-FENTON TREATMENT OF ORGANIC POLLUTANTS

KATIA RIBEIRO.BYCZYK NOGUEIRA, ANTONIO CARLOS SILVA COSTA TEIXEIRA, CLÁUDIO AUGUSTO OLLER DO NASCIMENTO, ROBERTO GUARDANI

138EFFECTS OF CROSSFLOW VELOCITY AND TRANSMEMBRANE PRESSURE ON ULTRAFILTRATION OF NATURALLY-OCCURRING PROTEINS IN SKIM LATEX SERUM

NIK MERIAM SULAIMAN, HO KAR WEI, MOHAMED KHEIREDDINE AROUA

157OPTIMIZATION OF A SOAKING TREATMENT TO REDUCE ADDITIVES MIGRATION FROM PLASTICIZED PVC

MOHAND OUIDIR BOUSSOUM, NAIMA BELHANECHE- BENSEMRA




183EFFECT OF THE AGITATION DURING THE COOLING STAGE OF HIGHLY VISCOUS FLUIDS

MATOVA TANYA, POUX MARTINE, XUEREB CATHERINE

209

CONTINUOUS STARCH GELATINIZATION AND HYDLYSIS WITH A TAYLOR-COUETTE FLOW REACTOR

HAYATO MASUDA, SHINICHIRO MATSUKA, ROBERT HUBACZ, TAKAFUMI HORIE AND NAOTO OHMURA

212

EXPERIMENTAL ANALYSIS ON THE PERFORMANCE AND EFFICIENCY OF PEM FUEL CELL POWER SYSTEM INTERGRATED WITH DC-DC CONVERTER AND ULTRACAPACITOR FOR LIGHT WEIGHT VEHICLE DESIGN

MOHD HADI ANUAR MOHD FAKHARUZI, THOMAS ARTHUR WARD

26


213THERMAL CRACKING OF HEAVY CRUDE OIL IN A LAB SCALE CONTINUOUS MECHANICALLY FLUIDIZED BED REACTOR

ISABELLA AIGNER, CEDRIC BRIENS, FRANCO BERRUTI

214ORGANIC PHOTOVOLTAIC SOLAR CELL EFFICIENCY UPGRADATION THROUGH DEVICE ARCHITECTURE MODIFICATION

ARIFUL HAQUE, ABDUL AWAL, MASHIUR RAHMAN AND FAUZIA SULTANA

233MODELING AND EXPERIMENTAL VALIDATION OF COUPLED COOLING TOWERS

RAFAEL C. DE LIMA JR; LILIAN C. MELLO; TAH W. SONG ; JOSÉ L. DE PAIVA

242CLIMATE STABILITY ELEMENTS IN TRADITIONAL IRANIAN ARCHITECTURE IN HOT AND DRY CLIMATE

HAMED AYALI, SAHAR SADEIAN

245COMPARING GREEN APPROACHES IN PHASES OF DESIGNING PROCESS AND DEVELOPING PROCESS

MOHSEN AKBARZADEH

250VIRTUAL LANDSCAPE OF “GREEN SOLVENTS” USING THE COSMO-RS APPROACH

MOITY L., MOLINIER V., BENAZZOUZ A., DURAND M., PIERLOT C., RATAJ V. AUBRY J.M.,

251GRASS (GENERATOR OF AGRO-BASED SUSTAINABLE SOLVENTS) AS A BOTTOM-UP STRATEGY FOR THE DESIGN OF A "GREEN ALKAHEST"

MOITY L., MOLINIER V., BENAZZOUZ A., DURAND M., PIERLOT C., RATAJ V. BARONE R., AUBRY J.M.

255AUTOHYDROLYSIS STUDY OF CELLULOSE TO GLUCOSE WITH INSTANT CONTROLLED PRESSURE DROP (DIC) TREATMENT AND DILUTE ACID HYDROLYSIS AS POST TREATMENT

SARIP HARUN, ALLAF KARIM, NOOR MOHD AZEMI

260MODELING OF MULTI AGENT SYSTEM IN GREEN SUPPLY CHAIN

MARYAM TAVAKOLI




275COMPUTER-AIDED DESIGN OF GLYCEROL-BASED MOLECULES MATCHING SPECIFICATIONS AS ECO-FRIENDLY SOLVENTS

NARALINGOM ANTHONY, DE CARO PASCALE, THIEBAUD-ROUX SOPHIE,ALRIC ISABELLE, FABRE JEAN-FRANÇOIS, MOULOUNGUI ZÉPHIRIN

276

SUNFLOWER OIL ETHANOLYSIS ON-LINE MONITORED BY NEAR INFRARED SPECTROSCOPY IN A MICROFLUIDIC DEVICE

ROMAIN RICHARD, BRIGITTE DUBREUIL, SOPHIE THIEBAUD-ROUX, LAURENT PRAT

282IMPROVEMENT OF STEVIA GLYCOSIDES GREEN SOLVENT EXTRACTION FROM STEVIA REBAUDIANA BY INSTANTANEOUS CONTROLLED PRESSURE DROP PROCESS

MOHAMED NEGM AND KARIM ALLAF

27


LIST OFPOSTERS (SUSTAINABLE AND CLEAN TECHNOLOGIES)



8ISOLATION OF INDONESIAN CANANGA OIL BY INSTANT CONTROLLED PRESSURE DROP DIC

KRISTIAWAN M., SOBOLIK V., ALLAF. K.

10INORGANIC AND ORGANIC POLLUTANT REMOVAL FROM TANNERY EFFLUENT BY INTEGRATED PHOTO-FENTON AND ELECTRO-COAGULATION PROCESS

ROSANGELA BERGAMASCO, FERNANDO H. BORBA, DIEGO R. MANENTI, APARECIDO N. MÓDENES, FERNANDO R. ESPINOZA-QUIÑONES, SORAYA M. PALÁCIO

11APLICATTION OF PROCESS PHOTO-FENTON IN THE DEGRADATION OF TEXTILE WASTERWATERS

ROSANGELA BERGAMASCO, FERNANDO H. BORBA, DIEGO R. MANENTI, APARECIDO N. MÓDENES, FERNANDO R. ESPINOZA-QUIÑONES, SORAYA M. PALÁCIO

35GREEN EXTRACTION OF NATURAL PRODUCTS. ORIGINS, CURRENT STATUS, AND FUTURE CHALLENGES

PR. FARID CHEMAT

38OPTIMIZATION AND TECHNO-ECONOMIC STUDY OF AUTONOMOUS PHOTOVOLTAIC–WIND HYBRID SYSTEMS FOR ELECTRICITY SUPPLY OF THE FUTURE ASTRONOMICAL OBSERVATORY IN THE MOUNTAIN OF CHELIA IN ALGERIA

AKSAS MOUNIR

39NANOMECHANICAL PROPERTIES OF POLYURETHANE NANOCOMPOSITES STUDIED BY NANOINDENTATION

K. YUSOH AND M. SONG

28


43PARASITIC PROTOZOANS REMOVAL BY COAGULATION/FLOCCULATION WITH SEEDS OF THE NATURAL COAGULANT MORINGA OLEIFERA LAM AND MICROFILTRATION

LETÍCIA NISHI, ANA LÚCIA. F. GUILHERME, ANGÉLICA M. S. VIEIRA, GRASIELE S. MADRONA, FERNANDO A. SILVA, GLEICIELLE T. WURZLER, ROSANGELA BERGAMASCO

44EFFECT OF SALINE SOLUTION ON THE EXTRACTION OF MORINGA OLEIFERA SEEDS FOR THE REMOVAL OF CYANOBACTERIA CELLS IN WATER SUPPLY

FRANCIELE P. CAMACHO; FERNANDO A. SILVA; GLEICIELLE T. WURZLER; LETICIA NISHI; ANGELICA MARQUETOTTI SALCEDO VIEIRA, ÁLVARO ALBERTO DE ARAÚJO, ROSANGELA BERGAMASCO

51OBTAINING POLYMERIZATION KINETIC DATA FROM LOW OR HIGH PRESSURE INTENSIFIED PROCESSES AT THE LABORATORY SCALE

SARRAZIN FLAVIE, MIGNARD EMMANUEL

52EFFECT OF NANOSILICA FILLED POLYAMIDE BASE VARNISH TO PHOTOCHEMICAL DEGRADATION PROCESS OF POLYETHYLENE FILM

CHING YERN CHEE AND ISKANDAR IDRIS YAACOB

53GREEN IT FRAMEWORK FOR DATA CENTERS USING VIRTUALIZATION TO REDUCE CARBON FOOTPRINTS

MUEEN UDDIN, AZIZAH ABDUL RAHMAN




58A SIMULATION STUDY ON MEMBRANE DISTILLATION MODULE

SOON ONN LAI, KOK CHUNG CHONG

59

MICROWAVE FURNACE FOR PYROLYSIS OF GOLDSMITH RESIDUES FINALYSED TO PRECIOUS METALS RECOVERY COMPLETED WITH TREATMENT FOR SMOKE EMISSION

MAURO COLUCCI

63CONCEPTUAL MODELLING AND DESIGN OF FUEL CELL POWER PLANT VEHICLES FOR RACING

M. RIZUWAN MUSTAFFA, RAHIM ATAN, W. A. NAJMI WAN MOHAMED

66DEVELOPMENT OF TRANSPARENT VISUALIZATION TEST RIG FOR TWO-PHASE FLOW ANALYSIS IN A SINGLE CELL PEM FUEL CELL

K. IMRAN SAINAN, RAHIM ATAN, W. A. NAJMI WAN MOHAMED

93SYNTHESIS AND SWELLING BEHAVIOR OF AGRO-WASTE BASED SUPERABSORBENT COMPOSITES

K.N.MOHD AMIN,N.S.SULAIMAN,M.S. HASAN,A.J.SANSURI

109INCORPORATING GREEN ENGINEERING CONCEPTS INTO CHEMICAL ENGINEERING COURSES IN MALAYSIA

SOON ONN LAI

110REMOVAL OF CYANIDE USING PHOTOCATALYSIS-MEMBRANE HYBRID SYSTEM

SOON ONN LAI

114

DIFFERENT TYPES OF ENCAPSULATION BEADS WITH DIFFERENT AMOUNT OF FE2O3 USED FOR REDUCTION OF CR(VI) TO CR(III) USING PHOTOCATALYTIC PROCESS

ANI IDRIS, EFFALIZA MISRAN, NURSIA HASSAN, NUR SURIANI MOHD ISMAIL

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118ENCAPSULATION OF γFE2O3 NANOPARTICLES PHOTOCATALYTS FOR REDUCTION OF CR(VI) TO CR(III)

EFFALIZA MISRAN, ANI IDRIS

122ANTIOXIDANT ACTIVITY OF NATURAL PLANTS AFTER DIC

BERKA BAYA, BESOMBES COLETTE, ALLAF KARIM

124APPLICATION OF H2O2/UV PROCESS FOR AMICARBAZONE DEGRADATION IN AQUEOUS SOLUTIONS

A.L.C. PEIXOTO, J.P. VARGAS GARCIA, C.O. ZAMBRANA, A.C.S.C. TEIXEIRA

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CONTROLLED GAS PHASE HYDROGENATION OF M-DINITROBENZENE: A COMPARISON OF THE CATALYTIC ACTION OF CARBON SUPPORTED GOLD AND SILVER

FERNANDO CÁRDENAS-LIZANA, ZAHARA M. DE PEDRO, SANTIAGO GÓMEZ-QUERO, LIOUBOV KIWI-MINSKER AND MARK A. KEANE




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DEGRADATION OF 2,4-DICHLOROPHENOL IN AQUEOUS SYSTEMS BY THE HOMOGENEOUS H2O2/TRIS(OXALATE) FERRATE III PROCESS IN A SOLAR IRRADIATED REACTOR

ANTONIO CARLOS S. C. TEIXEIRA, JULIANA D. RESENDE, KÁTIA RIBEIRO, CLÁUDIO A. O. NASCIMENTO

128PREPARATION AND CHARACTERIZATION OF POLY(CAPROLACTONE)/FATTY AMIDES MODIFIED CLAY NANOCOMPOSITE

EMAD A. JAFFAR AL-MULLA

129REMOVAL OF CYANOBACTERIA CELLS BY COAGULATION/FLOCCULATION WITH MORINGA OLEIFERA LAM SEEDS

LETÍCIA NISHI, FRANCIELE P. CAMACHO; FERNANDO A. SILVA; GLEICIELLE T. WURZLER GRASIELE S. MADRONA, ANGÉLICA M. S. VIEIRA, ALVARO A. ARAÚJO, ROSANGELA BERGAMASCO

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CHEMICAL COMPOSITION, ANTIMICROBIAL AND ANTIOXIDATIVE PROPERTIES OF ROSELLE SEEDS ESSENTIAL OIL EXTRACTED BY HYDRODISTILLATION

NYAM KAR LIN

140ION SEPARATION BY NANOFILTRATION-COMPLEXATION IN AQUEOUS MEDIUM

PELLET-ROSTAING STÉPHANE, BORRINI JULIEN, FAVRE-RÉGUILLON ALAIN, BERNIER GILLES, LEMAIRE MARC

147THE EFFICACY OF MICROWAVE–ASSISTED PRETREATMENT OF ALMOND SHELL HEMICELLULOSE IN IONIC LIQUID

NAGHMEH TAHERI HERAVI, GEK CHENG NGOH, ADELINE SEAK MAY CHUA, LI WAN YOON

148INVESTIGATION OF THE WATER CONSUMPTION PATTERN IN THE DESERT REGIONS OF IRAN (CASE STUDY: KHARANAQ VILLAGE, YAZD)

MOHAMMAD ALI TARBIATJOO, MOHAMMAD HAGHSHENAS , SARA HOORVASH

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CONTRIBUTION TO THE ENHANCEMENT OF CARVONE EXTRACTION FROM CARUM CARVI L. SEEDS BY MEANS OF ULTRASOUND AND MICROWAVE HEATING PROCESSES

SMAIN CHEMAT

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178DEGRADATION OF THE ANTIEPILEPTIC DRUG CARBAMAZEPINE BY HYDRODYNAMIC-ACOUSTIC-CAVITATION

PATRICK BRAEUTIGAM, RUDOLF J. SCHNEIDER, MARCUS FRANKE, ACHIM STOLLE, BERND ONDRUSCHKA

181REMOVAL OF AZO DYE BY HETEROPHOTO FENTON IN THE PRESENCE OF IRON-SILICA MIXED OXIDE NANOCOMPOSITE FROM CONTAMINATED WATER

M. H. RASOULIFARD, H. HOSSEINI MONFARED, S. MSOUDIAN

182DEHYDROGENATION OF METHYLCYCLOHEXANE FOR THE “ON-BOARD” HYDROGEN STORAGE AND SUPPLY

MUHAMMAD R. USMAN

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EVALUATION OF ANTIBACTERIAL PROPERTY OF EDIBLE COATING BASED ON CARBOXYMETHYL CELLULOSE INCORPORATED WITH SILVER NANOPARTICLES AGAINST ERWINIA HERBICOLA – A MODEL FOR GRAM NEGATIVE BACTERIA

HODA JAFARIZADEH MALMIRI, AZIZAH OSMAN, CHIN PING TAN RUSSLY ABDUL RAHMAN, HANISAH BINTI MUSTAFFA @ HAMZAH




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SELECTION OF SOLVENT FOR RECOVERY OF POLYPHENOLS FROM PINK GUAVA PROCESSING WASTES

LILIS SUKEKSI, NIK MERIAM SULAIMAN, CHE ROSMANI CHE HASSAN, AND MOHAMED KHEIREDDINE AROUA

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EFFECT OF PRE-OXIDATION ON REMOVAL OF SULFONAMIDE ANTIBIOTICS FROM SIMULATED WASTEWATER BY NANOFILTRATION MEMBRANE

MOHD REDZUAN RAMLI, NIK MERIAM NIK SULAIMAN

201REMOVAL OF ZINC AND LEAD IONS FROM AQUEOUS SOLUTIONS BY POLYMER ENHANCED ULTRAFILTRATION

NURUL HUDA BAHARUDDIN, NIK MERIAM NIK SULAIMAN, MOHAMED KHEIREDDINE AROUA

203NATURAL RESOURCES EFFICIENCY IN LATEX CONCENTRATE PROCESSING

SERI MAULINA, NIK MERIAM NIK SULAIMAN, NOOR ZALINA MAHMOOD

205 ULTRASOUND-ASSISTED MOBILIZATION OF OIL HOSSEIN HAMIDI AND ROOZBEH RAFATI

206A ROLE OF THERMOSTABLE NANO-PARTICLES TO IMPROVE GAS INJECTION MOBILITY IN ENHANCED OIL RECOVERY

ROOZBEH RAFATI, HOSSEIN HAMIDI

210HYDRODYNAMIC-ACOUSTIC-CAVITATION (HAC) FOR TECHNICAL APPLICATIONS: BIODIESEL SYNTHESIS

MARCUS FRANKE, PATRICK BRAEUTIGAM, YANZE REN, ZHILIN WU, BERND ONDRUSCHKA

219STUDY OF CO2 ABSORPTION IN A WETTED WALL COLUMN WITH FILM PROMOTER

HENRY RODRIGUEZ, LILIAN MELLO, WILSON SALVAGNINI, JOSÉ LUIS DE PAIVA

220MASS TRANSFER COEFFICIENT FOR CO2 ABSORPTION IN AQUEOUS SOLUTIONS OF MEA AND AMP IN A COLUMN WITH FILM PROMOTER

HENRY RODRIGUEZ; LILIAN MELLO; WILSON SALVAGNINI; JOSÉ LUIS DE PAIVA

221ANTIOXIDANT ACTIVITY OF PYROLYSIS OIL FRACTIONS FROM DIFFERENT BIOMASS FEEDSTOCKS

JAVEED MOHAMMAD, LORENZO FERRANTE, MEREDITH CONROD, FRANCO BERRUTI, AND CEDRIC BRIENS

225PALM OIL AS A RENEWABLE RAW MATERIAL FOR GREEN POLYMERIC MATERIALS

A.R.N.AZIMI, ROSIYAH YAHYA, SENG – NEON GAN

230SYNTHESIS OF BIODEGRADABLE LUBRICANT BASESTOCK FROM EPOXIDISED USED COOKING OIL

VENU BABU BORUGADDA, VAIBHAV V GOUD

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237MEMBRANE PROCESS TO REMOVAL THE HEAVY METALS FROM INDUSTRIAL WASTEWATER

F. HASSAINE-SADI, M.GRAICHE AND A. BOUDAA




252CATALYTIC WET AIR OXIDATION OF MALEIC ACID OVER LANTHANUM-BASED PEROVSKITES

MARCO BERNARDI, NUNZIO RUSSO, DEBORA FINO

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NON SEWAGE PIPE MBR BIO-TOILET – A CASE STUDY ON SEWAGE WATER RECYCLING EXPERIENCE IN COUNTRY PARK AND REMOTE AREA OF HONG KONG

DANIEL M. CHENG, VICTOR C. LI

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TERNARY LIQUID-LIQUID EQUILIBRIA FOR MIXTURES OF [BMIM+][BF4-]+ N-HEXANE + AN ORGANIC COMPOUND INVOLVED IN THE KINETIC RESOLUTIONS OF RAC-1-PHENYL ETHANOL AND RAC-2-PENTANOL

F.J. HERNÁNDEZ-FERNÁNDEZ, A.P. DE LOS RÍOS, M. RUBIO, D. GÓMEZ, G. VÍLLORA

278INSTANT CONTROLLED PRESSURE DROP DIC FOR SHRIMPS TREATMENT

MOUNIR SABAH, AL-HADDAD MAZEN, NGUYEN VAN CUONG, ALLAF KARIM

294CARBON DIOXYDE CAPTURE PILOT INTEGRATION ON INDUSTRIAL PROCESS

AOUINI ISMAËL, LEDOUX ALAIN, ESTEL LIONEL

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PLENARYSPEAKERS (PLENARY LECTURE 1)

JEAN CLAUDE CHARPENTIERMutliphase reactors and electrochemical engineering (SysPol)

LRGPNancy - FRANCE

BIODATA

Prof. Dr. Ing. Sci. Dir. Jean-Claude CHARPENTIER is Professor of Chemical Engineering in the field of multiphase gas-liquid-solid catalytic reactors encountered in the field of air and water depollution and in the field of Process Intensification, at Ecole Supérieure de Chimie Physique Electronique de Lyon (ESCPELyon) and at Ecole Nationale Supérieure des Industries Chimiques (ENSIC), Institut National Polytechnique de Lorraine (INPL), Nancy-University, France. And he is also Emeritus Director of Research at the Centre National de la Recherche Scientific (CNRS) at Laboratoire Réaction et Génie des Procédés LRGP/CNRS/ENSIC/INPL Nancy-Université. He got an Engineer degree (Master degree 1964) at Ecole Centrale de Lille, Université de Lille. He held a doctoral degree in chemical engineering (PhD 1968) at the University of Nancy (Ecole Nationale Supérieure des Industries Chimiques, ENSIC).

J C. Charpentier was the creator and head of a research team on multiphase gas-liquid-solid reactors (1968-1983) and Vice-Director of the Laboratoire des Sciences du Génie Chimique CNRS-ENSIC-Nancy (1978-1983). J.C. Charpentier was Director (Dean) of ENSIC (1983-1985). He was the Scientific Director of the Department of Engineering Sciences of CNRS, Minister of Research and Technology, Paris (1985-1992).

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Then he was the Founder and the Director (Dean) of the Ecole Supérieure de Chimie Physique Electronique de Lyon from 1992 until 2005 (this Institution graduates every year 250 engineers (master degree) in the field of chemistry, chemical engineering and electrical engineering).


Since 2005, Professor Charpentier is back at the Laboratoire des Sciences du Génie Chimique, Department of Chemical Engineering LSGC/ENSIC/ INPL, Nancy-University. The new name of the Laboratory is Laboratoire Réactions et Génie des Procédés since 2010.

Since 1970 Jean-Claude Charpentier has published more than 190 papers in international scientific journals in the field of multiphase gas-solid-liquid reactors and bioreactors, and more recently in the general field of chemical and process engineering. He has presented more than 125 oral lectures including 50 invited plenary or opening lectures in international congresses in the field of chemical and process engineering. He is the coauthor of 3 books on multiphase chemical reactors.

He is Editor of the Journal Entropie, of les Techniques de l’Ingénieur, and Associate-Editor of Chemical Engineering Science UK), of Chemical Engineering Technology (D) and of Recent Patents on Chemical Engineering Journal (USA). He has been consultant and member of the scientific board of several chemical and petrochemical companies.

Honor and Awards

Pr J.C. Charpentier is a member of several French Scientific Institutions : Société Française de Chimie, Société de Chimie Industrielle, Société Française de Génie des Procédés

He is a Member of the European Academy, Academia Europaea and of the New York Academy of Sciences

He is Honorary Fellow of the Institution of Chemical Engineers, IChemE (UK), Fellow of the American Institute of Chemical Engineers AIChE (USA) and Honorary Fellow of the Czech Society of Chemical Engineers CSCE (Cz).

Pr Charpentier has been the Scientific President of the French Society of Chemical Engineers (SFGP) (1997-2002)

Jean-Claude Charpentier has been also the President of the European Federation of Chemical Engineers (2002-2006).

J.C. Charpentier Is Officier de la Légion d’Honneur, Chevalier de l’Ordre National du Mérite, Chevalier du Mérite Agricole

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Médaille d’Argent 1978 (Silver Medal) of CNRS for the quality of his research in Chemical Engineering, i. e, in the field of multiphase reactors


IN THE FRAMEWORK OF GLOBALIZATION, SUSTAINABILITY AND TECHNICAL INNOVATION DEMAND: GREEN PROCESS ENGINEERING IN 2011, QUO VAMUS?

ABSTRACT

Confronted with the globalization of the markets and acceleration of partnerships and innovation, the knowledge of the products and processes that will be competitive in the today global economy is the first requirement intended for the research in chemical engineering. Indeed a great number of the today demands concern the development of biomaterials, the preparation of nanoparticle, the controlled release of drugs, the bio nanotechnologies, the conversion of biomass, the use of ionic liquids and biphasic aqueous systems, the dynamic of relaxation of complex molecular compounds, the design of polyphasique micro structured reactors for selective reactions, and most of theses demands are clearly focused on societal requirements such as CO2 sequestration, chemical looping combustion, methane reforming and catalytic partial oxidation to produce syngas, the synthesis of biodiesel or production of hydrogen. A great number of these topics are listed in the European and North American « roadmaps » published in the last decade which have pointed out a planetary global anxiety and concern where chemical engineering shall play a crucial role: sustainability, health, safety and environment, energy, water, food and drinks, biosystems engineering, solar energy, nuclear fusion, etc. So the existing processes and the future processes will be progressively adapted to the principles of the « green chemistry ». And the roadmaps, proposed to respond to the changing needs of the chemical and related industries in order both to meet the previous today’s economy demands and to remain competitive in global trade, militate for the evolution of chemical engineering in favour of a modern process engineering voluntarily concerned by sustainability (the green process engineering) that will face new challenges bearing on complex systems at the molecular scale, at the product scale and at the process scale.

Indeed this modern chemical and process engineering has to satisfy both the market requirements for specific nano and microscale green end-use properties of products, and the social and environmental constraints of industrial meso and macroscale green production processes. Thus an integrated system approach of complex multidisciplinary, non-linear, non equilibrium processes and transport phenomena occurring on the different time and length scales of the chemical supply chain is required which means a very good understanding how phenomena at a smaller length-scale relates to properties and behaviour at a longer length-scale is necessary (from the molecular-scale up to the production-scales).

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It will be shown in this lecture that the modern scientific approach of chemical engineering, « the green approach of process engineering », is led with four main objectives: (a) a total Multiscale control of the processes to increase selectivity and productivity, (b) design of novel equipment based on scientific principles, new operational modes and new technologies of production, (c) the manufacturing end-use properties and (d) the application of multiscale and multidisciplinary computational chemical engineering modeling and simulation to real-life situations involving process control, safety and life cycle analysis.

These main and parallel objectives are strongly oriented towards investigations on process intensification and on the couple products/processes couple to produce much more and better in using much less, and to sustainabily produce molecules responding to environmental and economic challenges with the help of technical innovation and sustainable technologies for efficient mass and energy utilization. Such progress toward sustainability emphasizes and involves the need to make life cycle analysis, focus on life cycle design, incorporate by-product synergy and account for ecosystem services.

And this methodology is largely emphasized by the objectives and the topics of the congress GPE2011 and will be developed and discussed in the communications during this congress.

Keywords: Green process engineering *The time and length multiscale methodology *Green product/process couple * Process intensification * product design and engineering *

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KHOO HOCK AUNMANAGING DIRECTOR/CEO

Ark Bio Sdn Bhd/Cosmo Biofuels Group

BIODATA

Mr Khoo Hock Aun leads the Ark Bio/Cosmo Biofuels Group which is actively engaged in establishing integrated rubber, oil palm, jatropha curcas, and pongamia plantations, biodiesel downstream processing and trading activities in the Asia Pacific region. He is presently developing markets and partnerships for an oilseed-to-biodiesel supply chain based on the Group’s proprietary processing technology for all oilseed crops including use of oil palm and coconut biomass for second generation biofuel.

He was Senior Advisor from 2004-2006 for the South East Asia operations of D1 Oils plc and maintained a strategic interface with related Government agencies overseeing policy for biofuels and renewable energy. He is Advisor/Strategist for the International Jatropha Organisation, Vice-Chair, Roundtable on Sustainable Biofuels and Secretary-General, Malaysian Bio-Industry Organisation.

The Ark Bio/Cosmo Biofuels Group supplies both the upstream and downstream technologies for its project partners on the ground and monitor the quality aspects so that they adhere to international standards. Cosmopolitan Synergies Sdn Bhd is the trading arm of the Group in transactions involving oilseeds, crude oil feedstock and refined methyl ester undertaking offtake agreements with farms and plantations. Ark Bio Sdn Bhd is the research, development and commercialisaton arm of the Group.

PLENARY

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SPEAKERS (PLENARY LECTURE 2)

Mr Khoo Hock Aun graduated with a Bachelor of Science (Agribusiness) from Universiti Putra Malaysia, Serdang in 1978 and was a Nuffield Foundation Study Fellow in 1988 with the Science Policy Research Unit, University of Sussex, United Kingdom where he examined developments in biotechnology: the institutional basis for innovation, the role of government policy and the various approaches to commercialise and finance innovation in the field of life sciences. He has managed, in a period spanning over two decades, a number of trade associations in both in Malaysia and South East Asia.

BUSINESS ASPECTS OF BIOFUELS IN SOUTH EAST ASIA:SUSTAINABILITY, TECHNOLOGY AND INNOVATION FOR TRADE IN THE BIOFUELS

INDUSTRY

ABSTRACT

Biofuels has emerged as an important sector to reduce fossil fuel dependency, mitigate climate change, spur bioenergy industrues and to develop the rural sector in developing countries. The sustainability of biofuels has emerged as an important area of contention and there is a danger of the debate over its merits and demerits detracting attention away from its true potential.

While the science, technology and management of the nascent biofuels industry is still being developed, standards are already being considered to “regulate” either by mandatory or voluntary means this industry. The role of the Rountable on Sustainable Biofuels in establishing voluntary standards and the implementation of its certification programme will be particularly significant to the oil palm industry and for other biofuels, both from the utilisaiton of its crude oil, waste co-products and its biomass and this has to be examined and understood in great detail in its various aspects.

There is a misconception that biofuels can be produced cheaply in developing countries, commoditised and transported to be consumed in developed countries without enormous impact on existing commodity trade flows and patterns. Biofuels as currently approached as a problem of logistics: shipping vast quantities of bioenergy products from efficient centres of production over large distances to high demand centres willing to pay for the energy and that acceptability is achieved by sustainability standardization and labeling.


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While science, technology and management of the biofuels industry graduate from the first to the second and the third generation such as algae, cellulosic ethanol; present biofuel development in developing countries is better applied to niche applications and in-situ domestic uses Opportunities abound for developing markets and partnerships for an oilseed-to-biodiesel supply chain for all oilseed crops including use of oil palm biomass for second generation biofuel, biogas for power generation and even aviation biofuel.

______________________________________________________________________Khoo Hock Aun. CEO/MD, Cosmo Biofuels GroupNo 17A Jalan Daya 6, Taman Daya 53000 Selangor Darul Ehsan Tel 016-301 4079Tel 03-6272 8498 Fax 03-6272 8499Email address: [email protected] Institution: Vice-Chair, Roundtable on Sustainable Biofuels, www.rsb.org


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mailto:[email protected]


SHIRO SAKALaboratory of Energy Ecosystem

Department of Socio-Environmental Energy ScienceGraduate School of Energy Science

Kyoto University Japan

BIODATA

Shiro Saka was graduated from Department of Wood and Paper Science, North Carolina State University, Raleigh, USA for MS in 1977 and PhD in 1980. He worked as a Post-Doctoral Fellow for Pulp and Paper Research Institute of Canada/Department of Chemistry, McGill University, Montreal, Canada in 1980-1983, then as a senior chemist in Research Center, Daicel Chemical Industries, Ltd., Himeji, Japan in 1983-1988. Since 1988, he became Associate Professor in Department of Wood Science & Technology, Kyoto University, and Professor in 1996 of Graduate School of Energy Science, Kyoto University.

Now, he has produced over 160 original papers, 80 review papers, about 330 international conference proceedings, 100 books and 56 patent applications including 29 patents granted. Current projects include research on biofuels through thermochemical conversions of biomass to bioethanol by supercritical water and on oils/fats to biodiesel by supercritical fluid technologies, and related research on biofuels and biochemicals. He has been the Editor of the Journals of Wood Science and MokuzaiGakkaishi, The Japan Wood Research Society. Additionally, he was the former President of Biomass Division, Japan Institute of Energy, Japan, and elected as Fellow of the International Academy of Wood Science in 2008, and currently, the country representative of Japan for the International Energy Agency (IEA) Task 39 (Liquid Biofuels). PLENARYSPEAKERS (PLENARY LECTURE 3)

Representative awards he received are Wood Award 1980 in USA, 2008 Japan Prize of Agricultural Science, 2008 Yomiuri Prize of Agricultural Science, 2008 Japan Institute of Energy Award, and the 23rd Best Technology Award of Japan Society of Energy and Resources in 2009. He was a chair of the

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session of “Future and Developing Production Technologies” in the 2nd International Congress on Biodiesel: The Science and The Technologies, held in Munich, Germany on November, 2009. In addition, he is a chair of National Advisory Committee of Renewable Energy 2010 International Conference and Exhibition held in Yokohama, Japan, June, 2010. He has been also a chair of Biomass Expo 2010 and 2011 held in Tokyo.

TECHNOLOGY INNOVATIONS IN BIOFUELS AND BIOCHEMICALS BY THERMOCHEMICAL CONVERSION

ABSTRACT

Thermochemical conversion by supercritical and subcritical fluid science and technology has been considered to be an environmentally benign treatment. Therefore, its technology was applied for biomass to useful fuels and chemicals so as to mitigate the environmental loading. For example, supercritical or subcritical water treatment has demonstrated that lignocellulosics can be decomposed to be lignin-derived products for useful aromatic chemicals and carbohydrate-derived products for subsequent ethanol fermentation as well as acetic acid fermentation to produce bioethanol. If this treatment is prolonged, lignocellulosics were found to be converted to dehydrated and fragmented products, and finally into organic acids which can be further converted to methane as one of the useful biofuels. If alcohols such as methanol, ethanol etc. are used in their supercritical condition for lignocellulosics, some other useful products were achieved and its liquefied products were found to have a potential as liquid biofuel, while, as methanol are used for oils and fats from woody biomass, biodiesel as fatty acid methyl esters can be produced under non-catalytic conditions. In addition, a potential of carboxylate ester and dimethyl carbonate in supercritical state for biodiesel production has been also demonstrated. Based on these lines of our pioneering research work, our achievements by supercritical fluid technologies will be presented on biorefineries from lignocellulosics in clean and green chemistry, particularly focusing on the new technologies of bioethanol and biodiesel production methods.

Key Words: Biofuels and Biochemicals, Thermochemical Conversion, Lignocellulosics, Green ChemistryPLENARYSPEAKERS (PLENARY LECTURE 4)

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DANIEL A. CROWLHerbert H. Dow Professor for Chemical Process Safety - Department of Chemical Engineering

Michigan Technological University, United States1400 Townsend Drive, Houghton, MI 49931

Email: [email protected]

BIODATA

Dr. Daniel A. Crowl is the Herbert H. Dow Professor for Chemical Process Safety in the Department of Chemical Engineering at Michigan Technological University. Professor Crowl received his B.S. in fuel science from the Pennsylvania State University and his M.S. and PhD in chemical engineering from the University of Illinois. After graduation, Professor Crowl spent two years as a Senior Process Control Engineer with St. Regis Paper Company, followed by 16 years as a faculty member in chemical engineering at Wayne State University in Detroit. In 1993 he moved to Michigan Technological University to assist in the development of their program in process safety.

He is co-author of the textbook Chemical Process Safety: Fundamentals with Applications, 1st, 2nd and 3rd editions published by Prentice Hall, and author of the books Guidelines for Consequence Analysis of Chemical Releases and Understanding Explosions, published by the American Institute of Chemical Engineers (AICHE). He was also the executive producer of the videotape series Safety in the Chemical Process Industries. He also edited (with S. S. Grossel) the Handbook of Highly Toxic Materials Handling and Management (published by Marcel Dekker in 1994), Inherently Safer Chemical Processes - A Life Cycle Approach, Layer of Protection Analysis and Human Factors Methods for Improving Performance in the Process Industries published by AICHE. He is the editor of the safety section for the 8th edition of Perry’s Chemical Engineers’ Handbook. He has also published many technical papers on flammability, source models and chemical reactivity. PLENARYSPEAKERS (PLENARY LECTURE 4)

Professor Crowl is a member of the AICHE Loss Prevention Committee, and past chair of the AICHE Loss Prevention Symposium. He is past President of the Safety and Health Division of AICHE. He serves on several AICHE/CCPS committees, including the Undergraduate Education Committee and

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the Technical Steering Committee. In 1990 Professor Crowl received the Bill Doyle award from the American Institute of Chemical Engineers, in 1992 he received the Chemical Engineer of the Year Award from the Detroit Local Section of the AICHE, in 1994 he received the Chemical Health and Safety Award from the American Chemical Society, in 1998 he received the Catalyst Award from the Chemical Manufacturers’ Association, in 1999 he received the Safety and Health in Chemical Engineering Education Award of Excellence from the Joint Council for Health, Safety, and Environmental Education of Professionals, in 2002 he received the Walton/Miller award from the Safety and Health Division of AICHE, in 2007 he received the Gary Leach Award from AICHE council for his participation in the Chem-E-Car safety program development, and in 2010 he received the Merit Award from the Mary K. O’Connor Process Safety Center at Texas A&M University. Professor Crowl is a Fellow of AICHE, American Chemical Society and the Center for Chemical Process Safety.

PROCESS SAFETY – AN IMPORTANT PART OF SUSTAINABLE AND GREEN PROCESS DESIGN

ABSTRACT

Major accidents continue to impact chemical plants throughout the world. These accidents involve fires, explosions and toxic releases and result in loss of life and injury, damage to the environment, and loss of equipment and inventory. It can be easily concluded that an unsafe chemical plant is not sustainable and not green due to the higher than normal risk for a catastrophic accident.

This talk will present methods that are used to prevent chemical plant accidents. This includes layer of protection systems, inherently safer designs, and risk-based process safety.

One of the major concerns in process safety is risk shifting. This occurs when risks are reduced by shifting those risks into another domain, such as shifting risk from the plant domain to the public domain. Examples will be provided. Finally, this talk will show how many of the methods commonly employed for process safety are applicable for sustainable and green process design.

Key Words: Process Safety, Process Safety Management, Inherently Safer Design, Layers of Protection.PLENARYSPEAKERS (PLENARY LECTURE 5)

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THUMRONGRUT MUNGCHAROENNational Science and Technology Development Agency, Thailand

and Kasetsart University, Thailand50 Ngamwongwan Road,

Chatujak, Bangkok, 10900, ThailandEmail: [email protected], [email protected]

BIODATA

Dr. Thumrongrut Mungcharoen, born in Thailand in 1955, is an Associate Professor of Chemical Engineering Department at Kasetsart University. He obtained his Bachelor of Engineering with honors from Chulalongkorn University and PhD from the University of Texas at Austin, USA. He had 2 years experience as a technical engineer at Toray Nylon Thai Co., Ltd. and 2 more years as a lecturer at Chemical Technology Department, Bangkok Technical College. After that, he has been teaching at Kasetsart University.

He has been involved extensively, during the past 15 years, as a consultant/ expert in several projects on cleaner production, 3Rs (reduce, reuse, recycle), life cycle assessment, and eco-design for Thailand Environment Institute (TEI), Federation of Thai Industries (FTI), United Nations Industrial Development Organization (UNIDO), United Nations Environment Programme (UNEP), Asian Productivity Organization (APO), Asia-Pacific Economic Cooperation (APEC), Economic Research Institute for ASEAN and East Asia (ERIA), and other organizations. He used to be an executive board member and a chairperson of education and research sub-committee of the Thailand Network of Eco-efficiency and Cleaner Production (TNEC). He sits in an advisory board of the Industrial Environment Institute under the FTI.


His teaching and research interests are focused on Cleaner Technology, Recycling, Life Cycle Assessment, Eco-Design and Risk Analysis. He has more than 150 technical publications.

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Representative awards he received are Fellow Award from Petroleum Institute of Thailand in 1999, Outstanding Person- Academic Award from Kasetsart University in 2000, Best Presentation Award from Thai Institute of Chemical Engineering and Applied Chemistry in 2007, and Outstanding Person- Academic Service Award from Kasetsart University in 2010.

He is one of the key persons who initiated the “Thai National Life Cycle Inventory Database” in 2007, “Pilot Project on Carbon Footprint of Products and National Scheme of Thai Carbon Footprint Label” in 2009, and “Pilot Project on Carbon Footprint for Organizations” in 2010. He is currently also the Director of Sustainable Environment Program and the Chairperson of Energy and Environment Cluster under the National Science and Technology Development Agency (NSTDA), Ministry of Science and Technology, Thailand.

PRACTICAL EXPERIENCE ON CARBON FOOTPRINT OF PRODUCTS AND CARBON FOOTPRINT OF ORGANIZATIONS

ABSTRACT

Calculation of greenhouse gas (GHG) generated throughout the life cycle of a product or carbon footprint of product (CFP) and GHG generated from organizational activities or carbon footprint of organization (CFO) are gaining popularity due to the global effort to reduce the greenhouse gas emissions. The life cycle assessment (LCA) methodology and the life cycle inventory (LCI) database are the two key elements for determination of the CFP and CFO. Thailand has started the collection of a LCI database in 2005 and officially started the National LCI database project in 2007. After obtaining quite enough LCI datasets together with quite a number of local LCA experts, Thailand has launched the pilot project on CFP since February 2009. It is a joint collaboration between Thailand Greenhouse Gas Management Organization (TGO) and National Metal and Materials Technology Center (MTEC) under National Science and Technology Development Agency (NSTDA). TGO acts as a label issuing authority while MTEC/NSTDA acts as a technical supporter with the help from several Thai LCA experts and the Japanese government through Green Partnership Plan. The first sets of CF labels were awarded to 23 products from 16 companies on 25 December 2009. Moreover, approximately 20 local CFP experts and the “Technical Guidelines for Assessment of Carbon Footprint of Products” for Thailand were obtained from this pilot project.


As of October 2011, 349 products were certified for CF labels. On October 2010, TGO and MTEC/NSTDA launched the pilot project on CFO. There were 12 organizations, including TGO and NSTDA, participating voluntarily in the evaluation of the carbon footprint of their organizations.

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In addition to the 15 local CFO experts and the national CFO guideline obtained from the pilot project, all the 12 organizations received the CFO certificates on 22 July 2011. Based on these above pioneering works, the experience and achievements on CFP and CFO will be presented and aimed for the contribution towards the reduction of global greenhouse gas emissions and the promotion of a low carbon society.

Key Words: Carbon Footprint, Life Cycle Inventory Database, Greenhouse Gas Emission, Low Carbon Society

KEYNOTEABSTRACT

THE RISK OF GREEN ENERGY- WHY GREEN POWER DOES NOT EQUAL GREEN RESULTS

RICHARD CROP

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ABSTRACT

Including nature in the motive energy of our worldwide business model has become a green fashion. But if our worldwide adopted business model is not changing, the outcome will still be black. What are the ways to avoid these dire consequences and how to use green energy to rethink the business of the world and the future of human life on earth.

KEYNOTEABSTRACT

CHIRAL AMMONIUM AND IMIDAZOLIUM-BASED IONIC LIQUIDS: SYNTHESIS AND APPLICATIONS FOR ASYMMETRIC SYNTHESIS

GIANG VO-THANH

Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO), CNRS-UMR 8182Université Paris Sud, 91405 Orsay Cedex, France

E-mail :[email protected]

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ABSTRACT

Chiral Ionic Liquids (CILs) have received considerable attention thanks to their potential applications to chiral discrimination, including asymmetric synthesis and optical resolution of racemates. By modifying the structure of the cations or anions of CILs, it has been shown that their properties can be altered in order to influence the outcomes of reactions. Nowadays, the design and synthesis of novel CILs are growing rapidly. The study of CILs applications in asymmetric synthesis presents a challenge and an opportunity to researchers. It is, therefore, essential if not interesting to synthesize different kinds of CILs from various starting materials derived from a chiral pool, especially from biorenewable sources.

We were the first to promote the use of CILs as the only source of chirality in the asymmetric Baylis-Hillman reaction. We also described, for the first time, the use of chiral ILs as new reaction media for the asymmetric aza Diels-Alder reaction between a chiral imine and the Danishefsky’s diene. This reaction has proved to perform better at room temperature in ionic liquid without either Lewis acid catalyst or organic solvent and with significant diastereoselectivity using either chiral ammonium or imidazolium-based ionic liquid.

We have recently designed and synthesized novel functionalized chiral ammonium, imidazolium and pyridinium-based ionic liquids derived from (-)-ephedrine as a chiral pool, using solvent-free reaction under MW activation. Applications of these new CILs as chiral catalyst for the asymmetric Michel addition reaction of diethyl acetylaminomalonate to chalcone derivatives have been studied. Moderate to good yields and enantioselectivities (up to 80% yield and 70% ee) were observed.

KEYNOTEABSTRACT

Some new chiral ILs derived from (S)-pyroglutamic acid have been synthesized and used as precursors to N-heterocyclic carbenes formation. These carbenes were used as chiral ligands for ruthenium-catalyzed asymmetric transfer hydrogenation (ATH) of aromatic ketones, giving excellent yields and good enantioselectivity (up to 90%). This represents the highest ee to date for a transfer hydrogenation catalyst incorporating a chiral NHC ligand.

The results of these studies will be communicated in this communication.

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KEYNOTEABSTRACT

GREEN SOLVENTS AND SUPERCRITICAL FLUIDS:FROM EXTRACTION TO RENEWABLE ENERGY AND NANOMATERIALS SYHTHESIS

K. PIZARRO 1, K. SEAUDEAU 1 AND S. SARRADE1,2

1 : Supercritical Fluid Innovation - http://www.supercriticalfluid.org/2: French Atomic Energy Commission (CEA) - Marcoule Centre and Saclay Center

[email protected]

ABSTRACT

The twelve Principles of Green Chemistry and Green Processes are now well achieved in scientific area. The main target for the next decade will be to spray Green Technologies in Industrial fields. Supercritical fluids have been described for years as possible tools for new sustainable applications.

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mailto:[email protected]


Supercritical CO2 is a suitable solvent for extraction instead of organic usual solvents. Supercritical water is now developed for organic waste destruction and biomass gasification for producing bio fuel. Then, this both previous solvent are used for material science. On the behalf of CEA and Supercritical Fluid Innovation, this paper describes 10 years of green chemistry developed in eastern south of France.

ExtractionThis quite old application of SCF deals with SC CO2. Many natural products were tested in these conditions in Europe and in the world. However, many relevant factories are now producing natural extracts for industrial and commercial purposes.

Supercritical Water Oxidation and Green fuelWithin the framework of nuclear industry some organic wastes, mixing of radio elements and organic solvents, are produced and cannot be treated by usual processes especially due to high concentration of chlorinated compound. Thanks to its former experience in nuclear and high-pressure fields, the CEA carried out research on the promising process of supercritical water oxidation (SCWO) in order to treat chlorinated high level contaminated wastes.On an other hand, CEA team now applies the technology developed for SCWO to the production of syngas from biomass. Two processes are studied: Supercritical Water Gasification (SCWG) and SuperCritical Water Partial Oxidation (SCWPO).

KEYNOTEABSTRACT

Material ScienceProcessing of ceramic precursors by a supercritical CO2 assisted sol-gel method was already investigated as a suitable synthesis pathway yielding SiO2 fibers, TiO2 powders, as well as doped ceria, lanthanum gallates and very recently zirconia. The ceramic powders synthesized by this method do not need any drying step, and their crystallization temperature is generally much lower compared to traditional processes (e.g. classical sol-gel process).

The major step that we achieved was to suggest possible mechanisms occurring during reactions in order to develop semi-continuous reactors from lab scale to pre-industrial scale. The project of the MATCOS platform will be presented, a 1.4 M€ investment project for new inorganic materials produced in supercritical media.

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KEYNOTEABSTRACT

A FURTHER STEP TOWARDS “GREEN ALKAHEST” THROUGH THE DESIGN AND THE CLASSIFICATION IN SILICO OF NEW ECO-FRIENDLY SOLVENTS: APPLICATION TO

GLYCEROL-BASED SOLVENTS

AUBRY J. M, a MOITY L. a MOLINIER V. a BENAZZOUZ A. a DURAND M. a PIERLOT C. a RATAJ V. a GERBAUD V. b HEINTZ J .b PANDYA N. b

TELES DOS SANTOS M. b MOULOUNGUI Z. c DE CARO P. c THIEBAUD-ROUX S. c ALRIC I. c FABRE J.F. c

NARALINGOM A. c BERGEZ-LACOSTE M. c MARION P. d BALASTRE M. d

a Université Lille Nord de France, E.A. 4478 Chimie Moléculaire et Formulation,Cité Scientifique, BP 90108, 59652 Villeneuve d'Ascq Cedex, France ;

b Université de Toulouse, INP, UPS, LGC (Laboratoire de Génie Chimique, UMR CNRS), ENSIACET 31432 Toulouse Cedex 04, France;

c Université de Toulouse, INP, LCA (Laboratoire de Chimie Agro-Industrielle, UMR INRA), ENSIACET, 4 Allées Emile Monso, 31030 Toulouse, France;

d Rhodia Opérations, Centre de Recherches, 52, Rue de la Haie Coq, 93308 Aubervilliers, FranceJean-Marie.Aubry@univ-lille1.

ABSTRACT

The new regulatory constraints have ruled out a large number of common organic solvents and the scientific community is eager to find a green “Alkahest”, name given by Paracelsus, alchemist of the

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mailto:Jean-Marie.Aubry@univ-lille1


XVth cent., to a hypothetical universal solvent able to dissolve every other substance. In this context, the

InBioSynSolv project aims to design new solvents in silico, less toxic and more biodegradable. This project sets a new standard for sustainable solvents: it considers readily available synthons from renewable resources as raw materials and aims at matching a large panel of physico-chemical and functional properties of the solvent, including approximate solubility power, boiling point, melting point, vapour pressure, flash point along with toxicity and environmental indices.

Two approaches are selected: The top-down strategy, presented in another contribution, sets a priori the target values of the desired solvent properties and a computer aided molecular design proprietary program suggests chemical structures that best match the specifications. The bottom-up approach presented here, uses the program GRASS (GeneratoR of Agro-based Sustainable Solvents) to generate systematically all possible compounds derived from a given renewable synthon.

KEYNOTEABSTRACT

GRASS considers all the chemical transformations compatible with the constraints of cost, eco-design and accessibility of co-reagents. Molecules from this first step are further screened through stability and synthesis feasibility criteria and the ones retained are used as starting substrates for the subsequent virtual syntheses (2nd and 3rd generations). Physicochemical and environmental properties are then predicted, in particular to assess the liquid state at 25 °C.

In the third step, solubilizing properties of the most promising virtual solvents are predicted by the COSMO-RS (Conductor-like Screening MOdel for Real Solvents) approach and compared to that of traditional solvents to identify the more likely replacements. The GRASS molecules are compared to the top-down candidates and finally, the selected solvents are synthesized to verify that the expected properties are met. The general approach of computer-aided design of new biosourced solvents matching a large and diverse set of properties is illustrated in the case of glycerol.

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