[transmittal and laboratory report for five soil …

DATE:

FROM:

TO:

ATTN:

U N I T E D STATES E N V I R O N M E N T A L P R O T E C T I O N6603 NORWOOD D R I V E HOUSTON, 7E7.-.5 7707-i

12-11-84

Laboratory Report for- Sikes Pit

oo

Cendall Y^g, ChiejLaboratory Sectirfffj 6ES-HL

James Stiebing, ChiefSurveillance Branch; 6ES-S

Henry Thompson -6ES-SH

Attached herewith is the Laboratory Report for the subject site.Five soil samples were submitted for the priority pollutant analysis.

The laboratory numbers assigned were ABE701 through ABE705. Theseresults were submitted on 10/5/8A to the Emergency Response Branch.

cc: Henry Thompson

23 5 Hi ; i "1 l

983737

smartin

Rectangle

001146

PAGE ] o

ORGANIC ANALYSIS DATA

oo

6ES-HL SAMPLE NO.: ABE701 FIELD SAMPLE NO. (TAG NO.):SOURCE: SIKES PIT SEEPAGE IN NE CORNER OF

SAND PITDATE/TIME COLLECTED: 8-15-84 0910-0930

SAMPLE TYPE: SOILCOLLECTED BY:

VOLATILE COMPOUNDS BY METHOD 624

(2V)(3V)(4V)(6V)(7V)<10V( 1 1 V )(13V)(14V)( 15V)(16V)(19V)(23V)(29V)(30V)(32V)(33V)

(38V)(44V)(45V)( A 6 V )(47V)(4GV)(49V)(50V)(51V)

(86V)(B7V)(QGV)

CAS*07 02-8

107-13-171-43-256-23-5108-90-7107-06-271-55-6/5 4 j>79-00-579-34-575 00-J110-75-3

Z. *7 L. t "267—66 o75-35-4156-60-578-87-5

10061-02-61 0061-01-5

100-41-475-09-274-87-374-83-975-25-275 27 475-69-475-/ 1 o

1 24 4b 1127-18-41 00-88-379-01-675-01-4

acr y 1 on i t r i 1 e — — — _____ ___benzene ————— — — — — — — — — —

ch 1 or oben zene — — _ — — _ — _1,2 d ich 1 or oe t h an e — — — — — — — —1,1,1 — trichloroethane — — — — — —1,1 dichloroethane — — — — —

chloroethane —————— — — — — —2— chloroethyl vinyl ether — — —

1,1 d ich 1 or oe t hen e — — — — —trans 1,2 dichloroethene — —

trans 1 ,3 dichlor opr opene —cis— 1,3 dichloropropene — —ethylbenzene — — — —fiethylene chloride — —

bronoMethane — — — —broMO'ForM — — — — —br o M o d i c h 1 o r o Me t h an e —

tetrachloroethenetoluene — — — — —trichloroethene —vinyl chloride — —

U

— — MU__ NJJ

— — — NU— [VJQ

NU

- NDNU

— — — — j\u— — MU

.— — — [Njy

— N I/— — wi}

— — wi)— — — — ML)

— NUNU

— VJTVMl/XI A— NDXI n

Ml/— _-— XJT\— _— jyy

— MT^WTi

— Kin

MT\

— MHriU— Kjrs

MA

G/KGDL=1DL=1T\lUL—DL=DL-T\(DL —DL=DL-DL=DL=DL=DL=DL=DL=DL=DL=DL=TMJJU —

DL=_—

t AnaDL=

r\i

DL =t AnaDL--r\tUL —DL=

DL =

0000002020202020202020505020202020202020201 y zed502020201 y zed2020202050

smartin

Rectangle

001147

PAGE Z OF7/


00

OO

6ES--HL SAMPLE NO.: ABE701 FIELD SAMPLE NO.<TAG NO.) :SOURCE: Sikes Pit, *TX0027, Seepage fron NE corner of S. pit Stat *0;

DATE/TIME COLLECTED: 8/15/84 0910-0930SAMPLE TYPE: SoilCOLLECTED BY; p| T

BASE/NEUTRAL COMPOUNDS BY METHOD 625

pp*(IB)(5B)<8B)(9B)U2S)( 1SB)(20B)<25B)(26B)C27B)(28B)(35B>(36B)(37B)(39B)<40B)( 41 B ><42B)(43B)(52B)(53B>C54B)(55B)<56B)< 62B ;(63B)(66B)(67IO(68B)(69B)< 7 0 B )C 7 I B )(72B)(73B)

<75B)'. 7 6 B )

/' / L' f

<7BEO(79B)(80B)( S1 B )'(92B>

CAS*83-32-992-87-5120-82-1118-74-167-72-1111-44-491-58-795-50-1541-73-1106-46-791-94-1121-14-2606-20-2122-66-7206-44-0

7005-72-3101-55-3

39638-32-9111-91-187-68-377-47-478-59-191-20-398-95-366-30-6621-64-7117-81-785-6S-784-74-2117-84-084-66-2

131-11-356-55-350-32-6205-99-22D7-OB-9218-01-9208-96-8120-12-7191-24-286-73-785-01-853-70-3193-39-51 2 C - 0 0 - 0

acenathenebenzidine1,2,4-trichlorobenzenehexachlorobenzenehexachloroethanebis(2-chloroethy1)ether2-chloronapthalene1,2-dichlorobenzene1 ,3 -d ich lo robenzene1,4-dichlorobenzene3,3'-dichlor obenzid ine2,4-dinitrotoluene2,6-dinitrotoluene1,2-diphenyIhydrazinefluoranthene4-chloropheny1 phenyl ether4-br ofiopheny 1 phenyl ether •bis(2-chloroisopropyl)etherbis(2-chloroethoxy)fiethane •hexachlorobutadienehexach1 orocyc1 open tadiene -•isophoronenapthalenenitrobenzeneN-nitrosodiphenylanineN-n i tr osodipr op y latiinebis(2-ethyIhexy1)phthalate -b u t y l benzy phthalatedi-n-butyl phthalatedi-n-octyl phthalatediethyl phthalatediwethyl phthalatebenzo(a)anthracenebenzo(a)pyrenebenzo(b)fluorantheneben z o (l<) f 1 u or an thenechryseneace n apt In y Ieneanthracene

fluorenephenanthrenedibenzo(a>h)anthracene

0

UG/GND DL=0ND DL=2

ND DL=0.2ND DL=0.2ND DL=0.2ND DL=0.2ND DL=0.2ND DL=0.2ND DL=0.2ND DL=1.0ND DL=0,6ND DL=0,6ND DL=0.4ND DL=0.2

ND DL=0.4ND DL^O.2ND DL=0.2ND DL=0.2ND DL=1.0ND DL=0.4ND DL=0.2ND DL=0.2ND DL=0.4ND DL=0.62.62. 00 .30 .8ND DL=0.4ND DL=0,2ND DL=0.8ND DL=O.SND DL=0.8ND DL^O.SND DL=0.8ND DL=0.2ND DL^C,2ND DL=0.CND DL=0.2ND DL=0.2ND DL=0.eND DL-0,0

D w r e n =

smartin

Rectangle

001148

ON

PAGE 9 OF? 6s&J*»~*+j- I 5O


6ES-HL SAMPLE NO.: ABE701 FIELD SAMPLE NO,(TAG NO.) :SOURCE: Sikes Pit, *TX0027, Seepage fron NE corner of S. pit Stat *01

SAMPLE TYPE: SoilDATE/TIME COLLECTED: 8/15/84 0910-0930 COLLECTED BY: pr,f

ACID COMPOUNDS BY METHOD 625

PP* CAS* UG/G(21A) 88-06-2 2,4,6 trichlorophenol ND DL-0.6(22A) 59-50-7 p-chloro-w-creso1 ND DL=0.8(24A) 95-57-8 2-chlorophenol ND DL=0.4(31A) 120-83-2 2,4-dichlorophenol ND DL=0,6(34A) 105-67-9 2,4-dir>eth y Iphenol ND DL=0.6(57A) 88-75-5 2-nitrophenol ND DL=1.0<58A) 100-02-7 4-nitrophenol ND DL=2.0(59A) 51-2B-5 2,4-dinitrophenol ND DL=3.0(60A) 534-52-1 4,6-dinitro-2-nethyIphenol ND DL=2.0<64A) 87-86-5 pentachloropheno1 ND DL=1.5(65A) 108-95-2 phenol ND DL=0 . 4

DIOXIN BY METHOD 62

PP* CAS* UG/G(129B) 1746-01-6 2,3,7,8-tetrach1 orodibenzo-p-dioxin Not Analyzed

smartin

Rectangle

001149

PAGE ^-OF 7

ORGANIC ANALYSIS DATAOO

6ES-HL SAMPLE NO.: ABE701 FIELD SAMPLE NO.(TAG NO.) :SOURCE; Sikes Pit, *TXQ027, Seepage fron NE corner of S. pit Stat *01

DATE/TIME COLLECTED: 8/15/84 0910-0930SAMPLE TYPE: SoilCOLLECTED BY:

HAZARDOUS SUBSTANCE LIST COUMPOUNDS

CAS*67-64-178-93-375-15-0519-78-6108-10-1100-42-5108-05-4108-38-395-47-6106-42-3


acetone2-butanonecarbondisulfids2-hexanone4-nethy1-2-pentan onestyreneuinyl acetaten-xyleneo-xylene and/orp-xylene

UG/KG94

ND DL= 10ND DL= 10ND DL= 10ND DL= 10ND DL= 10ND DL= 10ND DL= 10

ND DL= 10

BASE/NEUTRAL COMPOUNDS BY METHOD 625CAStt62-53-3 aniline

100-51-6 benzyl alcohol106-47-8 4-chloroaniline •132-64-9 diben z o-furan91-57-6 2-nethyInapthalene88-74-4 2-nitroaniline99-09-2 3-nitroaniline

100--01-6 4-ni tr oan i line

UG/GND DL= 0 .4ND DL= 0 .4ND DL= 0ND DL=ND DL= 0.2ND DL= 0.8ND DL= 0.8ND DL= 0 .8

40.2

CAS*65-85-095-48-7108-39-495-95-4


ben zoic acid --2-neth yIphen o14-riethy Iphenol:,4,5-trichlorophenol

UG/G< 1 . 0ND DL=ND DL=ND DL=

0 .60 .60 .6

smartin

Rectangle

001150

PAGE *r OF 7

ORGANIC ANALYSIS DATAO°

6ES-HL SAMPLE NO.: ABE701 FIELD SAMPLE NO. (TAG NO.) :SOURCE: Sikes Pit, *TX0027, Seepage froM NE corner of S. pit Stat *01

DATE/TIME COLLECTED: 8/15/84 0910-0930SAMPLE TYPE: SoilCOLLECTED BY: £T/T~

TENATIVELY IDENTIFIED COMPOUNDS BY METHODS 624 & 625

CASi COMPOUND NAME FRACTION

111-90-0 ETHANOL, 2-< 2-ETHOXYETHOXY > BNAUNKNOWN . BNA

SCAN*OR

RET.T.

MATCH ESTIMATED

UG/G

4701241

60 0.50.3

Report Prepared By: J, . >- \K 7 Date;

smartin

Rectangle

001151

SIKES PIT Page & Of 7 3O

PAGE £ OF

PESTICIDE/PCB ANALYSIS

6ES-HL SAMPLE N O . : A B E 7 0 1 FIELD SAMPLE N O . ( T A G NO. ) :SOURCE:SIKES PIT

SAMPLE TYPEiSOILDATE/TIME COLLECTED : <P/T/?y- COLLECTED BY: FIT

ANALYSIS BY: L.C.MINER , JR,

DATE OF ANALYSIS: 9/19/84

CHLORINATED PESTICIDES/PCS'1 3 BY GC/EC

PP* CAS*(89?) 309-00-2 aldrin ND DL=< 0 . 0 4( 9 0 P ) 60-57-1 d e i l d r i n N D D L = < 0 . 1 6(91P) 57-74-9 ch lorodane ND DL=< 1 ,97(92P) 50-29-3 4,4 ' -DDT ND DL=< 0 , 1 2( 9 3 P ) 72-55-9 4,4 ' -DDE • ND DL=< 0 . 0 8( 9 4 P ) 72-54-8 4 ,4 ' -DDD ND DL=< 0 , 0 3(95P) 115-29-7 a-endosulfan ND DL=< 0.08(96P) 115-29-7 b-endosulfan ND DL=< 0.00(97P) 1031-07-B endosulfan sulfate ND DL=< 0,16(9BP) 72-20-B endrin ND DL=< 0 . CS(99P) 7421-93-4 endrin aldehyde ND DL=< 0.16(100P) 76-44-8 heptachlor ND DL=< 0,04(101P) 1024-57-3 heptachlor epoxide ND DL=< 0.04(102P) 319-84-6 a-BHC ND DL=< 0.04(103P) 319-85-7 b-BHC ND DL=< C.04(104P) 319-36-8 d-BHC ND DL=< 0.04(105?) 58-89-9 g-BHC (lindane) ND DL=( 0.04(106P) 53469-21-9 PCB-1242 ND DL=< 1.97(107P) 11097-69-1 PCB-1254 ND DL=< 1.97(108P) 11104-28-2 PCB-1221 ND DL=< 1.97(109P) 11141-16-5 PCB-1232 ND I)L=< 1.97(HOP) 12672-29-6 PCB-124B ND DL=< 1.97(111P) 11096-82-5 PCB-1260 ND DL=< 1.97•:il2P> 12674-11-2 PCB-1016 ND DL=< 1.97(113?) 8001-35-2 toxaphene ND DL=< 1.97

x -x- H E R B1C11) E S B Y C C /' E C * -x- -x- * *:• -x- x- >•:• -x- -x- -x- -x x- * x- * * •» -x- -x- -x- -x- -x- -x- -x- x- -x- x- x94-75-7 2,4-1) ND. DL-< 0.0-193-76-5 2,4,5-T ND DL=< 0..04

smartin

Rectangle

001152

PAGE / OF 7


6ES-HL SAHPLE NO.: ABE702 FIELD SAMPLE NO. (TAG NO.):SOURCE: SIKES PIT 2 M SOUTH OF STA 05

SAHPLE TYPE; SOILDATE/TIME COLLECTED: 8-15-84 1107-1115 COLLECTED BY:jr/y-

oo


PP*(2V)(3V)(4V)(6V)(7V)( 10V( 11V)( 13V)(14V)(15V)(16V)(19V)(23V)(29V)(30V)<32V)(33V)

(.38V)(44V)(45V)(46V)(47V)(4BV)(49V)(50V)(51V)(85V)(86V)(87V)(88V)

CAS*107-02-8107-13-171-43-256-23-5108-90-7107-06-271-55-675-34-379-00-579-34-575-00-3110-75-367-66-375-35-4156-60-578-87-5

10061-02-610061-01-5

100-41-475-09-274-87-374-83-975-25-275-27-475-69-475-71-8124-48-1127-18-4108-88-379-01-675-01-4

UG/KGacrolein ND DL=500acrylonitrile ND DL=500benzene 93carbon tetrachloride ND DL-10chlorobenzene 131,2-dichloroethane ND DL=101 ,1 , 1-trichloroethane ND DL=101,1-dichloroethane ND DL=101,1,2-trichloroethane ND DL-101,1,2,2-tetrachloroethane ND DL=10chloroethane ND DL= 252-chloroethylvinyl ether ND DL= 25chloroforn ND DL=101,1-dichloroethene ND DL=10trans-1,2-dichloroethene ND DL-101,2-dichloropropane ND DL=10trans-1,3-dichloropropene ND DL=10cis-1,3-dichloropropene ND DL=10ethylbenzene 284wethylene chloride 108chlororieThane Not Analyzedbr OMOtiethane ND DL= 25brofioform ND DL=10bronodichloronethane ND DL=10•f lu or o tr ich lor owethane ND DL—10dichlorodifluorowethane Not Analyzedchlor odibr oMofiethane ND DL=10tetrachloroethene ND DL=10toluene ND DL=10trichloroethene ND DL=10uinyl chloride ND DL= 25

smartin

Rectangle

001153

PAGE OF 7

ORGANIC ANALYSIS DATAOo

6ES-HLSOURCE

SAMPLE: Sikes

NO.Pit

ABE702*TX0027, 2 neter S.

FIELD SAHPLE NO. (TAG NO.)of Station 05, Stat *02A

PP*( I B )(5B)(8B)( 9 B )( 1 210( I B B )( 2 0 B )(25B)( 2 6 B )(27B)( 2 8 B )(35B)(36B)( 3 7 B )(39B)( 4 0 B )( 4 1 B )< 4 2 B )(43B)( 5 2 B )(53B)( 5 4 B )(55B)(56B)( 6 2 B )(63B)( 6 6 B )( 6 7 B )( 6 8 B )( 6 9 B )( 7 0 B )( 7 1 B )( 7 2 B )( 7 3 B )( 7 4 B )(75B)

| (76B)( 7 7 B )( 7 8 B )( 7 9 B )( B U B )( S I B )( 8 2 B )t O~T- i

CAS*83-32-992-87-5

120-82-1118-74-167-72-1

111-44-491-58-795-50-1

541-73-1106-46-791-94-1

121-14-2606-20-2122-66-7206-44-0

7005-72-3101-55-3

39638-32-9111-91-187-68-377-47-478-S9-191-20-398-95-386-30-6

621-64-71 17-81-7

8 o ~~ o 3 *~ /84-74-2

117-84-084-66-2

131-11-356-55-350-32--8

205-99-2£07-08-9218-01-9208-96-8120-12-7191-24-286-73-785-01-853-70-3

103-39-5

SAMPLE TYPE: Soil'15/84 1107-1115 COLLECTED BY: f" tT


acenathene — — — — — — — — — — —benzidine — — — —

he x ach 1 or oben zene ~ — ~ ~ — — — —hexachloroethane — — — —

2 ch 1 or onap t h a 1 ene ~- — — —1 , 2— d i c h 1 o r oben z en e ~ — — —

1,4— dichlorobenzene ~ — — —3,3 — d i ch 1 o r o b en z i d i n e — ~ — —2 , 4— d in i t r o t o 1 uen e — — — — — —2 , o~d in i t r o t o 1 u en e — — —

fl u or an t h en e — — — ~

4 broMOphenyl phenyl ether —bis<.ti chloroisopropyl)ether

he x a c h 1 o r ob u t a d i ene — ~he x ach 1 o r oc y c 1 op en t a d i en e — — —

napthalene — — •— — —nitrobenzene — — ~ — — —N n i t r o s o d ip h en y 1 a MI n e ~— ~ —N n itrosodipropylanineb i s ( 2 ethylhexyl)phthal<3te —b u t y l b e n z y p h t h a l a t e —di n — b u t y l phthalats —di n — o c t y l phthalatediethyl phthalate —diMethyl phthalato? — —bc?nzo(a)anthracene — —benzo(a)pyrf?ne —benzo (b )'fluoranthenebenzo<, k)'Tluoranth ene —

a c enap t h y len e —anthracene — —benzo ( ci , h , i jperylene•fluorene ~ —phenanthrene — —dib(?nzo( a, h) anthracene —i n d e r. o ( 1 , 2 , 1 - c , d ) p v r = n e -

UG/G

NDNDNDNDNDND

NDNDNDNDNDNDNDNDNDNDND

NDND

NDNDND<ND0 .ND<NDNDNDNDNDNDNDNDNDNDND

ND

ui_— u . oDL=3.0DL=0 .3DL=0 .3DL=0 .3DL=0.3DL=0 .37\t n -*L>1_— U . O

DL=0 .3DL=0.3DL=1 .5DL=0.9DL=0.9DL=0 .6DL=0 .3

DL=Q .6DL=0 .3DL=0.37-it — n -7

DL=1 .5DL=0.6ni n "7DL=0,3DL=0 .6DL=0.90.6DL=--0,64DL=0 .60.6n i ri ~7UL— U . O

DL=1 .2r> i — 1 °n i _ -t o1JL— 1 : C.

DL=1 .2DL=1 .2DL=0 .3m — n ~\ni — 1 ^n i — n "^DL = 0 .3ni - 1 °DL=i .2

smartin

Rectangle

001154

OFl


OO

6ES-HLSOURCE

SAMPLE NO. :: Sikes Pit,

DATE/TIME COLLECTED

PP*21 H )

( 2 2 A )( 2 4 A )ol A )

( 3 4 A )< 5/ A )( 58A)(59A)( 6 0 A )( 6 4 A )( 6 5 A )

PP*(129EO

CAS*Q Q — A L. OOO U O <Z

95-57-820— DO d

105-67-9DO"'/ U vJ

100-02-751-28-5

534-52-187-B6-5

108-95-2

CAS*1746-01-6

ABE702 FIELD SAMPLE NO. (TAG NO. ) :*TX0027, 2 Meter S. of S ta t ion 05, S ta t *02A

SAMPLE TYPE:: 8/15/84 1107-1115 COLLECTED BY:


p c n i. o 1 Q rn c p c S O x*"1 L. 1 U T

^ A d lch lor°peno: '

T n iTropnsnoi•-* % _j • • j. i_ iA / J 4 « , ^ + V * — O X A f - « < * - K l 1 K*-l 1

-*• l-i T 1-. "lpenTacn ioropneno j . -" — —pnGnox ~ — _ — ^

DIOXIN BY METHOD 625

2 ,3 ,7 ,8- te t rach lorod ibenzo-p-d iox in —

Soil

FIT

UG/GMTN TM noIxU 1>L — u . V

ND DL— 1 , 2- ND DL=0 .6— NU DL— 0 . v- ND DL=0 .9

NU UL— 1 .

ND DL-o . UMn ni /L ^nl/ Ul_— n , jX1T\ TM ~7 flNJU 1/L — o . UND DL — il . O

- ND DL=0 .6

UG/GN o t A n a l y z e

smartin

Rectangle

001155

to

PAGE OF^


JL.OO

6ES-HL SAMPLE NO.: ABE702 FIELD SAMPLE NO.(TAG NO.) :SOURCE: SIKES PIT 2 M SOUTH OF STA 05

DATE/TIME COLLECTED: 8-15-84 1107-1115SAMPLE TYPE: SOILCOLLECTED BY: 77/7-

T E N A T I V E L Y I D E N T I F I E D COMPOUNDS BY METHODS 624 & 625

CAS*

590-21-675-65-060-29-7110-82-776-09-5111-46-6111-90-0

10544-50-0''123-79-5

COMPOUND NAME

1-PROPENE, 1-CHLORO-2-PROPANOL, 2-METHYL-ETHANE, 1,1'-OXYBIS-CYCLOHEXANE (DOT2,3-BUTANEDIOL,2,3-DIMETHYL-ETHANOL, 2>2' -OXYBIS-ETHANOL, 2-<2-ETHOXYETHOXY)-UNIDENTIFIED HYDROCARBONUNKNOWNUNIDENTIFIED HYDROCARBONSULFER , MOLECULAR (SB)HEXANEDIOIC ACID, DIOCTYL

ESTER

FRACTION

VOAUOAVOAMOA

- UOABNA

- BNABNABNABNABNA

SCAN*OR

RET.T.

2182662973656534044721079124012571562

MATCH !

8898008638097217679

———81

ESTIMATED

UG/KG

448414

383691 . 1UG.0.5UG,0.3UG,2.7UG,0 . 5UG.

49.7UG,

BNA 1761 70 1.7UG,

Re p o r t Prepared By: /_ D a t e

smartin

Rectangle

001156

r-

PAGE OF7


Oo

6ES-HL SAMPLE NO.: ABE702SOURCE: SIKES PIT 2 M SOUTH OF STA 05

FIELD SAMPLE NO.(TAG NO.)

SAMPLE TYPE: SOILDATE/TIME COLLECTED: 8-15-84 1107-1115 COLLECTED BY: p; T


VOLATILE COMPOUNDS BY METHOD 624CAS* UG/KG67-64-1 acetone 29978-93-3 2-butanone 2875-15-0 carbondisulfide ND DL= 10519-78-6 2-hexanone ND DL= 10108-10-1 4-nethyl-2-pentanone ND DL= 10100-42-5 styrene ND DL= 10108-05-4 vinyl acetate ND DL= 10108-38-3 n-xylene ND DL= 1095-47-6 o-xylene and/or106-42-3 p-xylene 66

BASE/NEUTRAL COMPOUNDS BY METHOD 625CAS* UG/G62-53-3 aniline ND DL=0.6100-51-6 benzyl alcohol ND DL=0,6106-47-8 4-chloroaniline ND DL=0.6132-64-9 dibenzofuran ND DL=0.391-57-6 2-nethyInapthalene < 0.388-74-4 2-nitroaniline ND DL=1.299-09-2 3-nitroaniline ND DL=1.2100-01-6 4-nitroaniline ND DL=1.2

ACID COMPOUNDS BY METHOD 625CAS* UG/G65--85-0 benzoic acid 1.195-48-7 2-nethylpheriol ND DL=0.9108-39-4 4-nethylphenol ND DL=0.995-95-4 2,4,5-trichlorophenol ND DL=0.9

smartin

Rectangle

001157

00

SIKES PIT Page <£ Of 7OO

PAGE £ OF


6ES-HL SAMPLE NO.:ABE/02SOURCE:SIKES PIT

DATE/TIME COLLECTED :

FIELD SAHPLE NO.(TAG NO.) :

SAMPLE TYPE:SOILCOLLECTED BY: 7=1 T

ANALYSIS BY: L.C,MINER,JR.


CHLORINATED PESTICIDES/PCB"S BY GC/EC

PP*(89P )(90P)(91P)•:92P)<93P)(94P)(95P)<96P)(97P )(9BP)(99P)( 1 0 0 P )U01P)<102P)(103P ><104P)(105P)(106P)(107P)(108P)(109P)< HOP)(IMP)C 112P )(M3P)

CASt309-00-60-57-57-74-50-29-72-55-72-54-115-29-115-29-

1031-07-0-

7421-93-76-44-

I 024-57-319-34-319-85-319-136-58-89-

53469-21-11097-69-11104-28-11 141-16-12672-29-1 1 096-82-12674-1 1-8001-35-

94-75-793-76-5

aldrindeildrinchlorodane4,4'-DDT4,4'-DDE4,4'-DDDa-endosulfanb-eridosulfanendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidea-BHCb-BHCd-BHCg-BI-IC (lindane)PCB-1242PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016toxaphene

2,4-D2,4,5-T

UG/LND DL=< 0.04ND DL=< 0,16ND DL=< 1.97ND DL=< 0.12ND DL=< 0.08ND DL=< 0.08ND DL=< 0.08ND DL=< G.08ND DL=< 0.16ND DL=< 0.08ND DL=< 0.16ND DL=< 0.04ND DL=< C.04ND DL=< 0.04ND DL=< 0.04ND DL=< 0 .04ND DL=< C.04ND DL=< 1.77ND DL=< 1.97ND DL=< 1.97ND DL=< 1,97ND DL=< 1.97ND DL=< 1,97ND BL--C 1 . 97ND DL=< 1.97

ND DL = < 0.04ND DL='< 0 . 0 •;

0 a~

smartin

Rectangle

001158

PAGE

INORGANIC ANALYSIS

JTI OO

SES-HL SAHPLE NO.: ABE702SOURCE: SIKES PIT

FIELD SAHPLE NO.(TAG NO.) :

SAMPLE TYPE: SOILCOLLECTED BY:D. ANDERSONDATE/TIME COLLECTED: 08/15/84

•xxpRlORITY POLLUTANT METALS, PHENOLS, AND CYANIDES ********«******x*******

PARAMETER CONCENTRATION 1 PARAMETER CONCENTRATION

A n T i M o n y , S b —Arsenic, AS - —Bery l l iuM,Be — — -Cadri iun,CdChr o Mi UM , CrCopper , Cu — —Lead , PbMercu ry ~ -

/ 1\ ii 1\ i/ H\ 1

ET

Q

i n

MG/KG

"•**-,

Ol~., i_vJ

Qtr

OR

Q^l

TiCT

fipp

MG/KG

NIC kel , Ni / , 79oeleniun ,Se <l . ,_^Silver, A g \ 1 .95

z.inc,/.n 1 j . 6

COMMENTS:

REPORT PREPARED BY: •-o4fc~/t''ft^

DATE:

smartin

Rectangle

001159

PAGE / O


O\o

oo6ES-HL SAMPLE NO.: ABE703SOURCE: SIKES PIT 70 M FROM EAST WALL OF

PIT; 30 M FROM NORTH WALL OF PITDATE/TIME COLLECTED: 8-15-84 1017-1047

FIELD SAMPLE NO. (TAG NO.):

SAMPLE TYPE: AQUEOUSCOLLECTED BY : pr/j-


PP*(2V)(3V)(4V)(6V)(7V)( 10V(11V)( 13V)( 14V)(1 5V)(16V)(19V)(23V)(29V)<30V)(32V)< 33V)

(3BV)(44V)(45V)(46V)(47V)<4BV)(49V)(50V)(51V)(85V)(86V)(87V)(8SV)

CAS*107-02-8107-13-17 -1 A~Z O

1 *tO L.

C" / o"7 C"DO — tfo >J

108-90-7107-06-271-55-675-34-3*7 o n ft — c./ y u u <j79-34-57 ET ft n _ "7o U U .31 0-/U .567-66-375-35-4

156-60-578-87-5

U Uo 1 U t~ oU U o 1 U 1 u

100-41-4r7 c* no *j/ o U / i~

/ °l O / -J

74-83-975-25-2

5 27 *\r?er / o „ A/O 0 7 "l

75-71-8124-48-1127-18-4108-88-379-01-675-01-4

acrolein — — — —acr y 1 on i t r i 1 e ~ ~ — — •*•

carbon tetrachloride ~~ ~~ ~~c h 1 or ob en zen e — — — — — • —

1,1,1 t r ich 1 or oet h ane — — — — -1 > 1 dichloroethane — — — —1 , 1 , 2 — t r ich loroethane — — — ~

f \ f c. } d. T e T r 3 c n i o r o e T n a n e —chloroethane — — — — —2 ch 1 or oe th y 1 v in y 1 ether — -ch 1 or O'Fo r M — — — — — ~1>1 dichloroe"tnene — — — —

1,2 dichloropropane — —Trans 1,3 d ich lo ropropenE?

br o MO d i ch 1 o r o me t hane —

d i c h 1 o r o d i •F 1 u o r o n e t h a n ech lo rod ib roMoMethanet e t r ach 1 or oe t h enet o 1 u enf? — — ~T r i ch 1 o r o e T h en e —

UG/L"— — ND DL— I

1 — NU DL-1

— — y /-H

— ND DL—~ — 2^

NJJ DL—— — — ND DL-

~— ^7U

-— — — ND DL—-— — — ND DL--— — ND DL—

— ND DL—— ND DL—

— — NU Uu.—. o /,— DO

— — NU UL—NU UL—nu 1JL—

1 1O"7ilO

— NU UL- —

riu U u —— ND UU—

•— NL* DL —XIT\ r\\~ PtD DL—

— 71/ J

ND DL —X17\ l\tNU DL

0 0 00 0 0

20

2020

202050502020

202020

ly zed5020£0201 y zed2020

2050

smartin

Rectangle

001160

0F7


6ES-HL SAMPLE NO.: ABE703 FIELD SAMPLE NO.(TAG NO.) :SOURCE: Sikes Pit, *TX0027, 70 M frori east wall of p i t , 30 M frofinorth wall, Stat #03

SAMPLE TYPE: AqueousDATE/TIME COLLECTED: 8/15/84 1017-1047 COLLECTED BY: -r-

pp*( IB)(5B)(8B)(9B)(12B)< IBB)(20B)<25B)(26B)<27B)(2BB><35B)(36B)(37B)(39B)<40B)(41B)(42B)(''43B)<52B)(53B)(54B)(55B)(56B)(62B)(63B)<66B)(67B)(68B)<69B)(70B)< 7 1 B )(72B)(73B)(741-0(75B)(76B)(77B)(7fiB)(79B)(GOB).(BIB)(G2B)(G3B)

CAS*83 — Oi£ y

. 92-87-5

1 8— / 4 167-72-1U 1-44-491-5B-795-50-1541-73-11 06-46-7O 1 O A 171 7 *t 1

1 O 1 1 A Oil 1 IT i—

i r\ i on oo U o <:U <i122-66-7206-44-07005-72-3101 %ju o96j8 o*i 9

1 1 9 1 187-68-377-47-478-59-191-20-398— 9*j o86-30-6621-64-7117-81-785 oo /84— /4~ 2117-84-084 — oo 2

131-11-356-55-350 J>2 8205-99-2L. U / U o /

218-01-9d. u !J / o a120-12-7191-24-286-73-785-01 -B53-70-3193-39-5120-00-1'

BASE/NEUTRAL COMPOUNDS BY

acenathene ————— _ — _ _ _benzidine — — — — — — — —1 , 2 , 4~- 1 r i ch 1 or ob en zen e —he x ach 1 o r ob en zen e ~~~hexachloroethane — — —

1,2 d ich 1 or ob en zene -~

1,2 diphenylhydrazine —

4-chlor opheny 1 phenyl ether4-br onopheny 1 phenyl etherbis(2-chloroisopropyl)etherbis(2-chloroethoxy)nethanehexachlorobutadiene — —hexachlorocyclopenfadieneisophorone —napthslene — — —nitrobenzene —N n i t r o s od i p hen y 1 an i n eN nitrosodipropylafiinebis ( 2- ethylhexyl) phthalatebutyl benzy phthalated i — n b u t y l phthalated i ~ n octyl phthalatediethyl p IT thai ate

b e n z o >, a ) p y r e n e

benzo(g,h,i)pe?rvylene

phenanthrene • —

METHOD 625

UG/LND

_ ^JJ

— — — — ND

— — — ND— — ND

ND~- ND

N D

— ND

— rtuNUND

— ND

— -- — r jj— — - ND

NU— — ND

NDND

NlJ

J11 n

— xirsND

ND\ND

00

vi n— wn

— r-iu

— x i n

_ f T\— \\uNDMr-.

ND— — NJ "Pi

— xj n

i ; r-

DL=20DL— 2DL= 2DL— 2DL= 2DL= 2DL— 2DL— 2DL= 2UL— 1 0DL- 6DL— ODL— 4DL= 2DL— 4DL— 4r\ i oUU— (I.DL- 2DL— 2D L — 1 0DL— 4

D ] O!_— ii

DL- 64DL— -4

o

DL= 4

DL= 8i'L- uDL= 8DL= 8DL= 8D ! O!_— t:

DL— dDL= 8DL= 2DL— 2l/L — C5

i-'i— — ^

smartin

Rectangle

001161

PAGE J OF 7


6ES-HL SAMPLE NO.: ABE703 FIELD SAMPLE NO.<TAG NO.) ;SOURCE'. Sikes Pit, *TX0027, 70 M frofi east wall of pit, 30 M froMnorth wall, Stat *03

SAMPLE TYPE: AqueousDATE/TIME COLLECTED: 8/15/84 1017-1047 COLLECTED BY: -jr/T


PPS(21A)<22A)<24A)< 3 1 A )(34A)< 57A )<56A)<59A)(60A)(64A)/ / CT A N

CAS*88-06-259-50-795-57-8iiU bo d.105-67-988-75-5U U (id /

t) 1 CO J

534-52-187-86-5

1 no 0"=; o

p chloro M— cresol _ — — __ .

i— 4 d icie t h y Iphen o 1 —<_ nitrophenol — — — — •

2,4 d in i t r ophen o 1 — — — — — •

p en t ac h 1 or ophen o 1 — ~ — — — — —

UC— — ND

— — ND— ND*" ND

ND— NU

— ND— NU

ND_ Mn

;/LDL= 6DL= 8U\—— *tTM UUL— or. 1 i.I/I.— O

DL=10l)L — d UDL=30TM • n nUL. — i_U

DL— 1 *Jni — A


PP# CAS* UG/L(129B) 1746-01-6 2,3,7,8-tetrach1 orodibenzo-p-dioxin Not Analyzed

smartin

Rectangle

001162

PAGE f- OF


6ES-HL SAHPLE NO.: ABE703SOURCE: SIKES PIT 70 M FROM EAST UALL OF

PIT; 30 H FROM NORTH UALL OF PIT

DATE/TIME COLLECTED: 8-15-84 1017-1047


SAHPLE TYPE: AQUEOUSCOLLECTED BY: l


VOLATILE COMPOUNDS BY METHOD 624CAS*67-64-1 acetone78-93-3 2-butanone75-15-0 carbondisulfide519-78-6 2-hexanone108-10-1 4-nethy1-2-pentanone100-42-5 styrene108-05-4 vinyl acetate108-38-3 n-xylene95-47-6 o-xylene and/or106-42-3 p-xylene

UG/LND DL= 20

61DL=DL =DL=

NDNDNDND DL=ND DL =ND DL =

115

202020202020

CAS*62-53-3100-51-6106-47-8132-64-991-57-688-74-499-07-2100-01-6

BASE/NEUTRAL COMPOUNDS BY•METHOD 625

anilinebenzyl alcohol4-chloroanilinsdibenzofuran2-i-iethylnapthalene2-nitroaniline3-nitroaniline4-nitroaniline

UG/LND DL=ND DL =ND DL=ND DL =< 2ND DL=ND DL =ND DL=

4442

e88

ACID COMPOUNDS BYCAS*65-85-095-48-7108-39-495-95-4

benzoic acid2-nethyIpheno 14-nethyIpheno12^4,5-trichlorophenol

UG/LND DL=10ND DL= 6ND DL= 6ND DL= 6

smartin

Rectangle

001163

SIKES PIT Page £ Of 7

OF

PESTICIDE/PCD ANALYSIS

OO

6ES-HL SAMPLE NO.:ABE703SOURCE:SIKES PIT

DATE/TIME COLLECTED: I/!

FIELD SAMPLE NO.(TAG NO.) ;

SAMPLE TYPE:AQUEOUSCOLLECTED BY: F~/T

ANALYSIS BY: M.E.GARZA,JR.


CHLORINATED PESTICIDES/PCBSS BY GC/EC

PP* CAS*(39P) . ^09— 00-2 aldrin - — - — —( 9 0 P ) 60-5/-1 deildrin — - — -(91P) 5/— 74— 9 ch lo rodane — —(92P) 50-29-O 4,4 ' DDT - - — -C93P ) /2-55— 9 *V } ** DUh. — — —( 9 4 P ) /^-54-8 4 , 4 L > l / U - - — ~( 9bP ) 115—29—7 a—end o su Ifan — — — -(96P) 115 ^9 / b— endosul fan -(97'P) 1 0 3 1 — 0 7 — 8 endosul fan sul fate — -< 9 8 P ) / 2 - 2 0 - 8 endrin • - —( 99P ) 7421—93—4 endrin aldehyde — -< 1 0 0 P ) 76-44—8 hep tach lo r —( 1 0 1 P ) 10i^4 — 57 — 3 hep tach lo r epox ide — —

( 1 0 2 P ) jilV — 84-b a t<HL - —( 1 0 3 P ) 319—65-7 b bHL —( 1 0 4 P ) ol9-86-8 d E< H C - - —( 1 0 5 P ) 5B— 89— 9 q— BHC ( l indane) —< 1 0 6 P P b j 4 o 9 2 1 y r L L'- 1 d M <- ~( 1 0 / P ) 1 1 0 9 / o V l PL IS i dul - -< 1 0 G P ) 1110^ d° d. PLi.! 1 ci<^ i -• - — - -( 1 0 9 P ) 11141-16-5 PCB id3<i -( 1 1 0 P ) 126/2-^9-6 PCB 1^453( '1 1 1 P ) 1 1 0 9 6 - 8 d - D PCB 1 d 6 0M 1 2P ) 1 2o /'•!-! 1 -.-' P C - B - l O l o( 1 1 3 P ) 8001-35 d. t o x a p h e n e

x «• H E R B I C I D E S BY G C / E C •:-: * *•4 / 5 / 4- , '» i»

, F t - t - r - O / I C T T9 J> - / 1> - 5 <- > c< > ^ '

UG/L— NU LJL— \ U . O-

Nl/ L'L.— \ 1 . O<

r<u yi_ \ i / i &..— ND DL— \ d , / •

— XIT\ TM / A "7rtu yi_— \ 1 . *i-

ND DL— \ 1 . ^i

NJD 1/L— \ 1 . u<

- — M T i T M / ^ f M— N J J U L - — s ^ . U

NU i/L— \ 1 . o;MA TM ^ A O t

— Kin ni — n ji. £

• ^ i x L ' J L ' L . N U i O C

— Kin ni — n Af

xin ni / n AC

WH "HI — t'"?il 1 fx i n TM s ~i A 1 fr<u u L. — \ w . ILr<U IJU— \ Ji^4 , I L

ND DL- < 4 . 1 L

ND DL— < ^ 4 , l U

ND DL-<Js , 11-

NU L)L-— \ O - 4 . 1 U

(x U L'L— < o-^ . 1 U

X\Ti TM / H i, Criu U L — s, U . O o

— — NU JUL— \ U . oo

/I- tr 7

smartin

Rectangle

001164


6ES-HL SAMPLE NO.: ABE703SOURCE: SIKES PIT 70 M FROM EAST WALL OF

PIT; 30 M FROM NORTH WALL OF PIT



SAMPLE TYPE: AQUEOUSCOLLECTED BY: F/

TENATIVELY IDENTIFIED COMPOUNDS BY METHODS 624 4 625

CAS* COMPOUND NAME FRACTION SCAN*OR

RET.T.

MATCH ESTIMATED

UG/L

UNKNOWN VOA 20860-29-7 ETHANE,1,1'-OXYBIS- VOA 291

110-82-7 CYCLOHEXANE (DOT VOA 36176-09-5 2,3-BUTANEDIOL,2,3-DIMETHYL- VOA 655108-98-5 BENZENETHIOL BNA 398

UNKNOWN BNA 461673-32-5 BENZENE, 1-PROPYNYL- BNA 5361193-18-6 2-CYCLOHEXEN-l-ONE,3-METHYL BNA 5581123-09-7 2-CYCLOHEXENE-l-ONE,

3,5-DIMETHYL BNA 618BENZOFURAN, 2-METHYL BNA 634UNKNOWN BNA 731UNKNOWN BNA 1012UNKNOWN BNA 1249UNKNOWN BNA 1394UNKNOWN BNA 1442UNKNOWN BNA 1513

98296076286

9670

79

21360

18178278332

532164

19003500440360

Report Prepared ByQ—

Date

smartin

Rectangle

001165

PAGE \j OFT T a .fi IZZZr OI • O

INORGANIC ANALYSIS

6ES-HL SAMPLE NO.: ABE703 FIELD SAMPLE NO.(TAG NO.) :SOURCE; SIKES PIT

SAMPLE TYPE: AQUEOUSDATE/TIME COLLECTED: 08/15/84 COLLECTED BY: R. SNYDER

Fir•xxPRlQRITY POLLUTANT METALS, PHENOLS, AND CYANIDES **x*xxx***x************

PARAMETER

kHn t iMon y > Sb —Arsenic, ASBe, y lliuM ,BeC,adMiuM,Cd

oniun , CrCo p p er , Cu ~ —Lead,rbMer c u r y —

CONCENTRATIONUG/L

— <' 1 -T> ^

.- «' n— / *3 n

< o n

^ n Q

PARAMETER CONCENTRATIONUG/L

oeieniun^oe — \iti.o

T K j s i i - » i i * « i T i — « / = :

COMMENTS:

REPORT PREPARED BY: _£>. Vf kJ - - /•" • r<^—r DATE:

smartin

Rectangle

001166

ooPAGE / O


6ES-HL SAMPLE NO.: ABE704SOURCE; SIKES PIT 20 M FROM EAST WALL OF

PIT; 30 M FROM NORTH UALL OF PITDATE/TIME COLLECTED! B-15-B4 0957-1005


SAMPLE TYPE:COLLECTED BY

AQUEOUS


PP*(2V)(3V)(4V)(6V)(7V)(10V( 1 1 V)(13V)( 14V)(15V)( 16V)(19V)(23V)(29V)(30V)(32V)(33V)

(3.8V)(44V)(45V)(46V)(47V)(48V)(49V)(50V)(51V)(85V)(86V)(B7V)(88V)

CAS*107-02-8107-13-171 —43-256-23-508— 90— /

107-06-271 C"f=" A/I ^JwJ O

75-34-3/ y— 0 U — u79-34-575-0 0->i

1 10-75-367-66-375-35-4

156-60-578-87-5

0 0 6 1 — Ut; o1 0061-01-5

100-41-4/ u UV cL74 87 -i74-83-975 i£5 d75 2/ 4/ 5 6y 475-71-6

124-48-11 2/-1 8-4108-88-379-0 1 -6TC: n 1 A

scrolein — — — — — — — — — — — — — — —

benzene -" ~* — —

1 > 1 ^ 2 > 2 tet r^chloroeth^ne *• — —chloroeth^ne — — — — — — — —

ch loro ' forM ~~ — — —1^1 dichloroethene —

1^2 d ich loropropane — — — —

brono ' fo rM — — — —

te t rdch lo roe thene — —t o 1 u en e -~trichl or oethene

UG— — — ND

nu

•— NU

1NU

NU117-1— — Ni;

— ptJU

r*uMTNND

N1J

fxUKin

(NU

NUxir»NUMA

— — MH

— M n +

\ \T \

— XJT\— nu\)T\NU

NU

/LDL=10T\I _ i nUL— 1 U

36OL —DL —3.7DL=27DL=i)L-DL =DL=DL=DL=3.7UL =DL=DL=L/L —

DL=Ana 1

TMUL—DL=DL=DL =

AnalDL =DL=T\\UL-TMl)L-

1 T

0

0

22

0L

2255Oi—

2

2ot_222y zed5OL.

22y zedo£_

22o

smartin

Rectangle

001167

oo

PAGE 2-OF 7


Oo

6ES-HL SAMPLE NO,: ABE704 FIELD SAMPLE NO. (TAG NO.) :SOURCE: Sikes Pit, *TX0027, £0 M fro* east wall of pit, 20 M frcmnorth wall, Stat *04

SAMPLE TYPE: AqueousDATE/TIME COLLECTED: 8/15/84 0957-1005 COLLECTED BY: pfT


PP*(IB)<5B)(8B)<9B)(12B)( 18B)(2QB)<25B>(26B)<27B)(20B)(35B)(36B)(37B)(39B)< A 0 B)(41 B )(42B)(43B)(523)(53B)(54B)(55B)(56B)(.62B)( 63B)(66B)( 67B)(6SB)(69B)( 7 0 B )( 71 B)<72B)( 73B)(74B)(75B)76B)77B)(7BB)(79B)(SOB)(81B)(G2EO

CAS*83-32-992-87-5120-82-1118-74-167-72-1111-44-491-58-795-50-1

541-73-1106-46-791-94-1121-14-2606-20-2122-66-7206-44-07005-72-3101-55-3

39633-32-9111-91-187-68-377-47-478-59-191-20-398-95-386-30-6621-64-7117-81-785-68-784-74-2117-84-084-66-2

131-11-356-55-350-32-8205-99-2207-00-9218-01-9203-96-8120-12-7191-24-286-73-785-01-853-70-3

UG/Lacenathene ND DL= 2benzidine ND DL=201,2,4-trichlorobenzene ND DL= 2hexachlorobenzene ND DL= 2hexachlor oethane ND DL= 2bis(2-chloroethyl)ether ND DL= 22-chloronapthalene ND DL= 21,2-dichlorobenzene ND DL= 21,3-dichlorobenzene ND DL= 21,4-dichlorobenzene ND DL= 23,3'-dichlorobenzidine ND DL = 102,4-dinitrotoluene ND DL= 62,6-dinitrotoluene ND DL= 61 ,2-diphenyIhydrazine ND DL= 4fluoranthene ND DL= 24-chloropheny1 phenyl ether ND DL= 44-bronopheny1 phenyl ether ND DL= 4bis<2-chloroisopropy1)ether ND DL= 2bis(2-chloroethoxy)nethane ND DL= 2hexach1 orobutadiene ND DL= 2hexachlorocyclopen Tadiene ND DL^IOisophorone ND DL= 4napthalene ND DL= 2nitrobenzene ND DL= 2N-nitrosodiphenylawine ND DL= 4N-nitrosodipropy1anine ND DL= 6bis(2-ethylhexyl)phthalate 14b u t y l benzy phthalate ND DL= 4di-n-butyl phthalate 2di-n-octyl phthalate ND DL= 4diethyl phthalate 20diwethyl phth<3late ND DL= 2benzo(a)anthracene ND DL= 8ben zo ( a ) p yrene ND DL= 8benzo(b)fluoranthene ND DL^ 8benzoCk)fluoranthene ND DL= 8chrysene ND DL= 8acenapthy Iene ND DL= 2anthracene • ND DL- 2benzo(g,h,i)peryIene ND DL= 8fluorene ND DL= 2phenanthrene ND DL= 2d i b e n z o ( a , h ) a n t h r a c e n a ND DL= 6i n u J e n o ' ] . C . 3-r i-• r - ' - " E^ e ND !>!_= 'B

smartin

Rectangle

001168

OF

ORGANIC ANALYSIS DATA °

6ES-HL SAMPLE NO.: ABE/04 FIELD SAMPLE NO.<TAG NO.) :SOURCE: Sikes Pit, *TX0027, 20 M fron east wall of pit, 20 M frownorth wall, Stat *04

SAMPLE TYPE: AqueousDATE/TIME COLLECTED: 8/15/84 0957-1005 COLLECTED BY:p/y~


PP* CAS* UG/L(21A) 8B-06-2 2,4,6 trichloropheno1 ND DL= 6(22A) 59-50-7 p-chloro-ri-creso 1 ND DL= 8(24A) 95-57-8 2-chlorophenol ND DL= 4(31A) 120-63-2 2,4-dichlorophenol ND DL= 6(34A) 105-67-9 2,4-diwethylphenol ND DL= 6(57A) 88-75-5 2-n itropheno 1 ND DL=10<58A) 100-02-7 4-nitrophenol ND DL~20<59A) 51-28-5 2,4-dinitrophenol ND DL=30(60A) 534-52-1 4,6-dinitro-2-MethyIpheno 1 ND DL=20(64A) 87-86-5 pentach1 orophenol ND DL=15(65A) 108-95-2 phenol ND DL= 4


PP* CAS* UG/L(.J29B) 1746-01-6 2 >3,7,8-tetrachlorodibenzo-p-d i o x in Not Analyzed

smartin

Rectangle

001169

PAGE q


Oo

6ES-HL SAMPLE NO.: ABE704SOURCE: SIRES PIT 20 M FROM EAST WALL OF

PIT; 30 M FROM NORTH WALL OF PIT


FIELD SAMPLE NO.(TAG NO.) ;

SAMPLE TYPE: AQUEOUSCOLLECTED BY: p / J"

HAZARDDUS SUBSTANCE LIST COUMPOUNDS

VOLATILE COMPOUNDS BY METHOD 624CAS* UG/L67-64-1 acetone 3.178-93-3 2-butanone 6.675-15-0 carbondisulfide ND DL=519-78-6 2-hexanone ND DL=108-10-1 4-nethy1-2-pentanone ND DL=100-42-5 styrene ND DL=100-05-4 vinyl acetate ND DL=108-3B-3 n-xylene ND 1JL=95-47-6 o-xylene and/or106-42-3 p-xylene 2.5

BASE/NEUTRAL COMPOUNDS BY METHOD 625CAS*62-53-3 aniline100-51-6 benzyl alcohol106-47-8 4-ch1 oroani1ine132-64-9 dibenzofuran91-57-6 2-nethyInapthalene86-74-4 2-nitroaniline99-09-2 3-nitroaniline100-01-6 4-nitroani1ine

UG/LND DL =ND DL =ND DL =ND DL=ND DL=ND DL=;ND DL=ND DL =

4442.2888

ACID COMPOUNDS BY METHOD 625CAS*65-85-095-40-7108-39-495-95-4

benzoic acid2-wethyIpheno14-nethyIpheno1 ;

2,4,5-trichlorophenol

UG/LND DL=10ND DL- 6ND DL= 6ND DL'-= 6

smartin

Rectangle

001170

PAGE <>- OF <?


6ES-HL SAMPLE NO.: ABE704SOURCE: SIKES PIT 20 H FROM EAST WALL OF

PIT; 30 M FROM NORTH UALL OF PIT



SAMPLE TYPE: AQUEOUSCOLLECTED BY:

TENATIVELY IDENTIFIED COMPOUNDS BY METHODS 624

CAS* COMPOUND NAME FRACTION SCAN*OR

RET.T,

MATCH ESTIMATED

UG/L

1-PROPENE,2-CHLORO- VOA60-29-7 ETHANE,!,1'-OXYBIS- VOA

110-32-7 CYCLOHEXANE < DOT UOA76-09-5 2,3-I<UTANEDIOL,2,3-DIMETHYL- VOA

UNKNOWN BNAUNKNOWN BNAUNKNOWN BNAUNKNOWN BNAUNKNOWN BNAUNKNOWN BNAUNKNOWN BNA

2152953636561042124113811401144014701508

974986947920

219,92.62939116663373833160

Report Prepared By : Date:

smartin

Rectangle

001171

SIKES PIT Page 6 Of 7

PAGE


r-

oo

6ES-HL SAMPLE NO.:ABE/04SOURCE:SIKES PIT

DATE/TIME COLLECTED:

FIELD SAMPLE NO.<TAG NO.) :

SAMPLE TYPE:AQUEOUSCOLLECTED BY:

ANALYSIS BY: M.E.GARZA , JR,


CHLORINATED PESTICIDES/RGBvS BY GC/EC

PP*(89P )( 9 0 P )( 91 P )(92P)(93P)(94P)(95P)(96P)(97P)<98P)(99P)( 1 0 0 P )(1 0 1 P )(102P)<103P)(104P)(105P)(106P)(107P)(108P)(109P)(11 OP )( 1 1 IP)(112P )(113P)

CAS*309-00-260-57-157-74-950-29-372-55-972-54-8115-29-7115-29-71031-07-872-20-8

7421-93-476-44-8

1024-57-3319-84-6319-85-7317-86-B5S-89-9

53469-21-911097-69-111104-2S-211141-16-512672-29-611096-82-512674-11-28001

94-75-793-76-5

aldrindeiidrinchlorodane4,4'-DDT4,4'-DDE4,4'-ODDa-endosuIfanb - e n d o s u 1-fanendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidea-BHCb-BHCd-BHCg-BHC (lindane)PCB-1242PCB-1254PCB-1221PCB-1232PCB-124SPCB-1260PCB-10'16toxaphene

**HER BIG IDES BY GC/EC-)2,4-DO A '-" — T<- > > -' '

UG/LND DLND DLND DLND DLND DLND DLND DLND DLND DLND DLND DL =ND DL =ND DL=ND DL=ND DL =ND DL =ND DL =ND DL =ND DL =ND DL =ND DL =ND DL =ND DL=ND DL-

=

< 0.6E< 1 .36<17.25< 2.73< 1 .36< 1 .36< 1 .36< 1 ,36< 4. 09

1 . 36< 4.09< 0 .68< 0.68< 0 .68< 0 .68< 0.63< 0 . 68<34.10<34,10<34,10<34.10<34,10< 34. 1 0

-X- •» -X- * -S

= <34. 10ND DL=<34.10

\ ,j£ :£ %..%. .. . . .v. .y-\.%

/ >>' A .

(T

smartin

Rectangle

001172

PAGE>? OF /

INORGANIC ANALYSIS

oo.

6ES-HL SAMPLE NO.: ABE704SOURCE: SIKES PIT

DATE/TIME COLLECTED: 08/15/84


SAMPLE TYPE: AQUEOUSCOLLECTED BY: R. SNYDER

fir•x-x-PRIORITY POLLUTANT METALS, PHENOLS, AND CYANIDES ***x*x**x**************

PARAMETER

AntiMOny,Sb -Arsen ic , AS -Ber y 1 1 i DM , BeCadniuMjCdChr OMI un,CrCopper, Cu — ~ "Lead , r bMer c ur y ~ ~

CONCENTRATIONUG/L

- _ 1 =* 1i U . 1

< O ft

— / t) Q

^/ ~zni n P

PARAMETER CONCENTRATIONUG/L

0Nickel, Ni <_8SeleniUM,Se ^ '

^ '^r ' T-| (c/.inc^Z-n — ti^o

COMMENTS:

R E P O R T P R E P A R E D B Y ; D A T E ;

smartin

Rectangle

001173

PAGE / OF?


oo

6ES-HL SAMPLE NO.; ABE/05SOURCE: SIKES PIT 12 M UEST OF STA 03



SAMPLE TYPE: AQUEOUSCOLLECTED BY :

pp*(2V)

(6V)(7V)( 10V(11V)( 13V)(14V)( 15V)(16V)(19V)(23V)(29V)(30V)(32V)(33V)

(38V)(44V)C45V)(46V)(47V)(48V)(49V)(50V)(51V)(85V)(86V)(87V)(88V)

CAS*107-02-8107-13-171-43-256-23-5108-90-7107-06-271-55-675-34-379-00-579-34-575-00-3110-75-367-66-375-35-4156-60-578-87-5

10061-02-610061-01-5

100-41-475-09-274-87-374-83-975-25-275-27-475-69-475-71-8124-48-1127-18-4108-88-379-01-675-01-4


UG/Llein —• ND DL=100

acrylonitrile ND DL=100benzene 612carbon tetrachloride ND DL= 2chlorobenzene 311,2-dichloroethane 121,1,1-trichloroethane ND DL= 21,1-dich1oroethane 3861,1,2-trichloroethane ND DL= 21,1,2,2-tetrachloroethane ND DL= 2chloroethane ND DL= 52-chloroethyIwiny1 ether ND DL= 5chloroforM ND DL= 21,1-dichloroethene ND DL= 2trans-1,2-dichloroethene 1031,2-dichloropropane ND DL= 2trans-1,3-dich1 oropropens 11cis-1,3-dichloropropene 9.3ethylbenzene 71Methylene chloride ND DL= 2chlor one thane Not Analyzedbrononethane ND DL= 5broMoforri ND DL= 2br oriodichlor onathane ND DL= 2fluorotrichloronethane ND DL= 2dichlorodifluoronethane Not Analyzedch1 orodibroMOMethane ND DL= 2tetrach1 oroethene ND DL= 2toluene 153trich1 oroethene 5.7vinyl chloride 106

smartin

Rectangle

001174

PAGE


r-

oo

6ES-HL SAMPLE NO,: ABE705 FIELD SAMPLE NO,(TAG NO.) :SOURCE: Sikes Pit, *TX0027, 12 M west of Stat 03, Stat *05

DATE/TIME COLLECTED: 8/15/84 1050-1105SAMPLE TYPE: AqueousCOLLECTED BY: p / T~

pp*( IB)< 5 B )(8B)<9B)(12B)( 18B)( 2 0 B )C 2 5 B )(26B)(27B)(20B)(35B)(36B)(37B)(39B)( 4 0 B )(.41 B)(4-2B)< 4 3 B ><52B)(53B)(54B)(55B)(56B)(62B)(63B)(66B)(67B)< 6 3 B >(69B)( 7 0 B )( 7 1 B )(72B)<73B)(74B)( 75B)(763)( 77B)(7GB)(793).( B O B )( 8 1 B )(8210

CAS*83-32-92-8/-u

20 Bd-1118-74-167-72-1

11 1-44-491-58-795-50-1

541-73-1106-46-791-94-1d 1 -1 4 2

606-20-2122 06 /2 06— 44— u

7005-72-3101-55-3

^96o8 3 2 911 VI 18/ 68 J>// 4/ 4•"7O cr r, -j/ O J / 1

91 <iu ^98 95 j86-30-6

6^1 64 /1 / 81 /6 5 — 1> b /84- / 4 — ii

1 1 / 84 084-66-2

13 l-l 1-3*r /_ _ cr ST. _ "7wJ W wJ (-» i-*

50-32-3205 V V dd U / U b 7ti i O (VI Qd l<3 (1 1 7

208-96-8120-12 /1 91 -<^4 J8 6 - 7 >i 785-01 853-70-3

acenathene — — — — — — — _ _ _ _benzidine — ~ — — — — — — — — — — —l ,2,4~tr ichlorob(?nzene — —~ —he x ach 1 or oben zene — —h e x ach 1 o r o e t hane — — — — —

iss i iCn j . o roeTny j . ^e tne r —2 ch 1 or onap tha lene — —1 ,2 d i ch 1 o r o b en zHne — — —1 ,3 d ich 1 o r oben z ene — — —1 ,4 die hloroben zene3,3 d ich 1 o r oben z id in e— — —2,4 d in i t roto luene — — —2,6 d in i t r o t o 1 u ene — —1 , 2 — diphenylhydrazine — —•fl u or an t hene — —

4— broMophenyl phenyl ether —b is (2— ch lo ro i sop ropy l )ether

hexach lo robu tad iene —h e x a ch 1 o r o c y c 1 o p en t a d i en e —

napthalene — — — —ni t robenzeneN n i t rosodiphenylc in ine —N n i t rosod ipropy ld f i inebis(2 e t h y l h e x y l ) p h t h a l a t e —b u t y l b e n z y p h t h a i a t e — —di n bu t y l ph tha la ted i — n o c t y l ph tha la tsdiethyl ph tha la te

UG/L— — — MT\ r\ i e"NV UL— ^_ _ M r\ TM AD— NU DL~ 4o

jS^p l)l_— u

ND DL- u— — — kir\ TM cr"" ~~ ND DL— u

" ND DL— ^j

— ~ •" ND DL— u— xi n rn c"~ NU i/L— u

— — _ — JOTS TM ^— -. jy^ uL— o— — — wn TM — c

ND DL— iJ— — — . MTN TM — OAND i/L — tin

— MT\ TM 1 AND DL— 1 *+

ND UL— i *t

ND DL— 1 U— — — — iHD UL— u

— wn TM 1 nNU UL— 1 U

~ (HD UL— 1 U— — xin TM c1

tx D UL— *J

— wn TM c".— NL» DL— sJ— M TS TM *3 /I— iNU DL — £-*?

"" NU DL— 1 U

wn TM ts*ND DL~ <J— Mn TM • 1 nNU UL— 1 U

NU DL— 1 *t41

n D D L — 1 U/ =r\ U

ND DL— 1 Uoot-C>.»T\ TSi ir

Mf\ ni 10

KITS T\l 1OINJJ UL— i /

— xin n i -\ f->

XI T\ T-. t -J (T

-<- >-IT\ TM ^* N U U L — *J— Mf> Til ^— NL1 UL— %J

xrn n I -to

xj T\ ni -- »^

— MD HI ^

— xin ni — 1 o

- —

smartin

Rectangle

001175

OF 7

ORGANIC ANALYSIS DATAoo

6ES-HL SAMPLE NO.; ABE705 FIELD SAMPLE NO.<TAG NO.)SOURCE: Sikes Pit, *TX0027, 12 M west of Stat 03, Stat *05

DATE/TIME COLLECTED: B/15/B4 1050-1105SAMPLE TYPE: AqueousCOLLECTED BY: p( -j-

ACID COMPOUNDS BY METHOD 62J

PP*(21A)(22A)(24A)(31 A)(34A)(57A)(5BA)(59 A)<60A)(64A)(65A)

CAS*88-06-259-50-795-57-8120-83-2105-67-968-75-5100-02-751-28-5534-52-187-86-5108-95-2

UG/L2,4,6 trichlorophenolp-chlor o-rt-cresol2—chlor ophen ol2,4~dichlorophenol2,4-dinethyIphenol2-nitrophenol4-nitrophenol2,4-dinitropheno14,6-dinitro-2-nethyIphenolpentach1 oropheno1phenol

NDNDNDNDNDNDNDNDNDNDND

DL=14DL=19DL=10DL=14DL=14DL=24DL=48DL=71DL-48DL=36DL-10


(129B)CAS*1746-01-6 2,3,7,8-teTrachlorodibenzo-p-dioxin

UG/LNot Analyzec

smartin

Rectangle

001176

PAGE


f-r-

oo

6ES-HL SAHPLE MO.: ABE705SOURCE: SIKES PIT 12 M UEST OF STA 03


SAMPLE TYPE; AQUEOUSDATE/TIME COLLECTED: 8-15-84 1050-1105 COLLECTED BY: p { T


VOLATILE COMPOUNDS BY METHOD 624CAS* UG/L67-64-1 acetone ND DL= 27B-93-3 2-botanone 4.575-15-0 carbondisulfids ND DL= 2519-78-6 2-hexanone ND DL= 2108-10-1 4-nethyl-2-pentanone ND DL= 2100-42-5 styrene ND DL= 210B-05-4 vinyl acetate ND DL= 2108-38-3 n-xylene 1295-47-6 o-xylene and/or106-42-3 p-xylene 212

BASE/NEUTRAL COMPOUNDS BY METHOD 625CAS* UG/L62-53-3 aniline ND DL= 10100-51-6 benzyl alcohol ND DL= 10106-47-0 4-chloroaniline ND DL= 10132-64-9 dibenzofuran ND DL= 591-57-6 2-nethy.lnap thalene ND DL= 580-74-4 2-ni troaniline ND DL= 1999-09-2 3-nitr oaniline ND DL= 19100-01-6 4-nitroaniline ND DL= 19

ACID COMPOUNDS BY METHOD 625CAS* UG/L65-85-0 benzole acid — 3795-48-7 2-nethylphenol ND DL= 14108-39-4 4-nethylphenol ND DL= 1495-95-4 2,4,5-trichlorophenol ND DL= 14

smartin

Rectangle

001177


oc

oo

6ES-HL SAMPLE NO.: ABE705 FIELD SAMPLE NO.(TAG NO.) :SOURCE: SIKES PIT 12 M WEST OF STA 03

DATE/TIME COLLECTED: 8-15-84 1050-1105SAMPLE TYPE: AQUEOUSCOLLECTED BY: f= I T

TENATIVELY IDENTIFIED .COMPOUNDS BY METHODS 624 & 625

CAS*

590-21-660-29-7

1 1 0-82-7

108-87-2590-50-176-09-5123-91-1

13609-56-0

11-93-18-6

COMPOUND NAME FRACTION

1-PROPENE, 1-CHLORO-ETHANE,! , 1 '-OXYBIS-CYCLOHEXANE < DOTUNKNOWNCYCLOHEXANE, METHYL-2-PENTANONE, 4, 4-DIMETHYL-2,3-BUTANEDIOL, 2 ,3-DIMETHYL-1 ,4-DIOXANEUNKNOWNCYCLDHEPTANEONE, 3-METHYLUNKNOWN2-CYCLOCHEXEN-l-ONE, 3-METHYLUNKNOWNUNKNOWNUNKNOWN

VOAVOAVOAUOAVGAVOAVOABNABNABNABNABNABNABNABNA

SCAN*OR

RET ,T.

21129436348650856765810

40446153555861912491394

— — = = = — — — — __5 — =_ __

MATCH ESTIMATED

891833

MANUAL

62863768S89

—56

—75

———

UG/L

57769

62029252978469873344382570476

R e p o r t Prepared By £>. Date: /

smartin

Rectangle

001178

SIKES PIT Page Of 7

PAGE £ OF/


Oo

6ES-KL SAMPLE NO.:ABE705SOURCE:SIKES PIT

DATE/TIME COLLECTED:

FIELD SAMPLE NO.(TAG NO.) :

SAMPLE TYPE .-AQUEOUSCOLLECTED BY: ?=/ T

ANALYSIS BY: M.E.GARZA,JR,


CHLORINATED PESTICIDES/PCB%S BY GC/EC

PP*<89P)(90P)(91P)(92P)(93?)(94P)(95P)(96P)(-.97P )(98P)(99P)< 1 OOP )(101P)(102P)(103P)( 1 04P)(105P)( 1 06P )(107P)( 108P)( 1 09P)(HOP)( 1 1 IP )( 1 1 2P )(1 13P)

CAS*309-00-2aO-57-157-74-950-29-372-55-972-54-8115-29-7115-29-7

1031-07-872-20-8

7421-93-476-44-8

1024-57-3319-84-6319-85-7319-86-858-89-9

53469-21-911097-69-11 1 1 04-28-21 1 141-16-512672-29-611096-82-512674-1 1-28001-35-2

aldrindeildrinchlorodane4,4'-DDT4,4'-DDE4,4'-DDDa-endosulfanb-endosulfanendosulfan sulfateendrinendrin aldehydehep tach .1 orheptachlor epoxidea-BHCb-I

g-BHC ( l indanc?)

B-1248

94-75-793-76-5

t o x a p h e n e —

•x-x-HERBICIDES2,4-D2,4 ,5-T

UG/LNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=<DL=(DL=<DL=<DL=<

01

1721111414000000

3434343434343434

.6f

. 3>, 21. 7".3;.3t. 3(. 3i, 0'.. 3i. (\r-. 6C. 6S,6£,6£. 6£. 6.c

. 1 C

. 1C, 10. 1C. 10. 10. 1C. 1 0

BY GC/EC-x--x--x--x--x-x-*-x-x--x-*-x--x--x--x-*-X"X--x-#x--x-*-x-*-X"X--x--x-ND DL=< OMD DL=< 0

//.

smartin

Rectangle

001179

OF 7INORGANIC ANALYSIS

Ooo

8

&ES-HL SAMPLE NO.: ABE703SOURCE: SIKES PIT

DATE/TIME COLLECTED: 08/15/84


SAMPLE TYPE: AQUEOUSCOLLECTED BY: D. ANDERSON

FITxxpRiORITY POLLUTANT METALS, PHENOLS, AND CYANIDES xxxxxxxxxxxx*****x***x*

PARAMETER

Ant iMony ,Sb —Arsenic, AS —Beryll iuM,Be — — -CadMium,CdChrofi iuM,Cr — -Copper , CuLead , r o —Mer c ur y — — -

CONCENTRATIONUG/L

__. _ / 1 o •*:- — — / ^ n- — \ c.U

/ on

— — / *7n/ n P

PARAMETER

M-i f - l /eaT rJ-i —

CONCENTRATIONUG/L

2u1 c . ucu

44

COMMENTS:

REPORT PREPARED BY: DATE:

smartin

Rectangle

001180

[transmittal and laboratory report for five soil …

Documents