thermal and pore pressure history of the haynesville shale

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Louisiana State University LSU Digital Commons LSU Master's eses Graduate School 2012 ermal and pore pressure history of the Haynesville Shale in north Louisiana: a numerical study of hydrocarbon generation, overpressure, and natural hydraulic fractures William C. Torsch Louisiana State University and Agricultural and Mechanical College Follow this and additional works at: hps://digitalcommons.lsu.edu/gradschool_theses Part of the Earth Sciences Commons is esis is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Master's eses by an authorized graduate school editor of LSU Digital Commons. For more information, please contact [email protected]. Recommended Citation Torsch, William C., "ermal and pore pressure history of the Haynesville Shale in north Louisiana: a numerical study of hydrocarbon generation, overpressure, and natural hydraulic fractures" (2012). LSU Master's eses. 268. hps://digitalcommons.lsu.edu/gradschool_theses/268

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Louisiana State UniversityLSU Digital Commons

LSU Master's Theses Graduate School

2012

Thermal and pore pressure history of theHaynesville Shale in north Louisiana: a numericalstudy of hydrocarbon generation, overpressure, andnatural hydraulic fracturesWilliam C. TorschLouisiana State University and Agricultural and Mechanical College

Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_theses

Part of the Earth Sciences Commons

This Thesis is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSUMaster's Theses by an authorized graduate school editor of LSU Digital Commons. For more information, please contact [email protected].

Recommended CitationTorsch, William C., "Thermal and pore pressure history of the Haynesville Shale in north Louisiana: a numerical study of hydrocarbongeneration, overpressure, and natural hydraulic fractures" (2012). LSU Master's Theses. 268.https://digitalcommons.lsu.edu/gradschool_theses/268

THERMAL AND PORE PRESSURE HISTORY OF THE HAYNESVILLE SHALE IN NORTH LOUISIANA: A NUMERICAL STUDY OF HYDOCARBON GENERATION,

OVERPRESSURE, AND NATURAL HYDRAULIC FRACTURES

A Thesis

Submitted to the Graduate Faculty of the Louisiana State University and

Agricultural and Mechanical College in partial fulfillment of the

Requirements for the degree of Masters of Science

in

The Department of Geology and Geophysics

by William Cross Torsch

B.S., Baylor University, 2010 December 2012

ii

Acknowledgments I would like to thank my advisory Dr. Jeffrey Nunn for mentoring me at

Louisiana State University and for guidance in the classroom and research. I would also

like to thank my committee members Dr. Jeffrey Hanor and Dr. Arash Dahi for their help

and support. I would like to thank Marathon Oil and the LSU Department of Geology

and Geophysics for financial support. Additionally, thanks to Halliburton and

Schlumberger for software donations.

Special thanks to Richard Campbell of Edgewood Exploration for mentoring me

in the field of petroleum geology and sharing his knowledge of the geology of south

Louisiana. Thanks to my fellow students in the Department of Geology and Geophysics.

Lastly, I would like to thank the faculty and staff at Baylor University for providing me

with a strong foundation that enabled me to achieve my goals at LSU.

iii

Table of Contents Acknowledgments ............................................................................................................... ii

List of Tables ....................................................................................................................... v

List of Figures .................................................................................................................... vi

Abstract .............................................................................................................................. ix

Chapter 1. Introduction ....................................................................................................... 1

Chapter 2. Geologic Overview ............................................................................................ 2

2.1 Study Area ................................................................................................................. 2

2.2 Tectonic Framework ................................................................................................. 3

2.3 The Haynesville Shale ............................................................................................... 5

2.4 Fluid Overpressure .................................................................................................. 11

2.5 Hydraulic Fractures ................................................................................................. 12

Chapter 3. Data and Methods ............................................................................................ 14

3.1 Data ......................................................................................................................... 14

3.2 Well Tops and Lithologies ...................................................................................... 14

3.3 Modeling ................................................................................................................. 17

3.4 Geologic Ages ......................................................................................................... 18

3.5 Erosion Estimates .................................................................................................... 20

3.6 Present Day Heat Flow ............................................................................................ 21

3.7 Paleoheat Flow ........................................................................................................ 23

3.8 Thermal Maturity .................................................................................................... 24

3.9 Porosity and Pressure .............................................................................................. 25

3.10 Paleowater Depths and Sediment Water Interface Temperature .......................... 26

Chapter 4. Results ............................................................................................................. 27

4.1 Thermal Maturation................................................................................................. 27

4.2 Fluid Pressure .......................................................................................................... 28

4.3 Fluid Migration ....................................................................................................... 31

Chapter 5. Discussion ....................................................................................................... 46

iv

5.1 Sensitivity Studies ................................................................................................... 46

5.2 Fluid Pressure Transfer ........................................................................................... 57

5.3 Hydrocarbon Migration ........................................................................................... 60

5.4 Natural Hydraulic Fractures .................................................................................... 65

Chapter 6. Conclusions ..................................................................................................... 67

References ......................................................................................................................... 69

Appendix A. Well Tops ................................................................................................... 75

Appendix B. Basin Modeling ........................................................................................... 76

Appendix C. Thermal Maturity ......................................................................................... 81

Vita .................................................................................................................................... 82

v

List of Tables Table 1:. Lithologies used for modeling ........................................................................... 17

Table 2: Cenozoic and Mesozoic unconformities of north Louisiana ............................. 21

Table B1:. Fundamental physical transport laws and variables ........................................ 80

vi

List of Figures Figure 1: Map showing the locations of the Gulf Coast sub-basins.................................... 2

Figure 2: Structural elements of the northern Gulf of Mexico ............................................ 4

Figure 3: Model of crust from gravity data along a north-south line through the Sabine Uplift along the Texas-Louisiana border ............................................................................ 5

Figure 4: Stratigraphic column for north Louisiana ............................................................ 6

Figure 5: Pressure contour map of the Haynesville Shale from well test data .................... 9

Figure 6: Twenty feet of image log showing natural fractures at mid level position in Haynesville Shale. Well is located in DeSoto Parish ........................................................ 10

Figure 7: Map of north Louisiana with well control shown by circles ............................. 15

Figure 8: Type log for north Louisiana ............................................................................. 16

Figure 9: Discretization of 2 D models ............................................................................. 19

Figure 10: Eroded thickness of the missing Cretaceous section and well locations ......... 22

Figure 11: North America heat flow map ......................................................................... 23

Figure 12: Paleo heat flow models used in this study ....................................................... 25

Figure 13: . Map of study area indicating the locations of the four wells shown in the results and discussion sections .......................................................................................... 28

Figure 14: Burial history plots with EASY Ro% overlay ................................................. 29

Figure 15: Plot of vitrinite reflectance vs. time for four wells .......................................... 30

Figure 16: 1D pressure versus depth models for 1 Gish, 1 Cates, 1 Foster, and C1 Tremont wells .................................................................................................................... 32

Figure 17: 2D cross section, north to south, at 0 Ma with pore pressure overlay ............. 33

vii

Figure 18: 2D cross section, west to east, at 0 Ma with pore pressure overlay ................ 34

Figure 19: Pore pressure versus depth at 0 Ma extracted from 2D models ...................... 35

Figure 20: Pore and fracture pressures versus time. Extractions from 2D models .......... 36

Figure 21: 2D cross section, north to south, at 87 Ma with pore pressure overlay ........... 37

Figure 22: 2D cross section, west to east, at 87 Ma with pore pressure overlay .............. 38

Figure 23: 2D cross section, north to south, at 0 Ma with pore pressure overlay. Haynesville Shale gas (red) and oil (green) migration pathways indicated by arrows ..... 39

Figure 24: 2D cross section, west to east, at 0 Ma with pore pressure overlay. Haynesville Shale gas (red) and oil (green) migration pathways indicated by arrows ..... 41

Figure 25: 2D cross section, north to south, at 87 Ma with pore pressure overlay. Haynesville Shale gas (red) and oil (green) migration pathways indicated by arrows ..... 42

Figure 26: 2D cross section, west to east, at 87 Ma with vertical permeability overlay. Haynesville Shale gas (red) and oil (green) migration pathways indicated by arrows ..... 43

Figure 27: 2D cross sections from north to south and east to west at 0 Ma with vertical permeability overlay. Blue arrows represent water flow pathways ................................. 44

Figure 28: 2D cross sections from north to south and east to west at 87 Ma with vertical permeability overlay. Blue arrows represent water flow pathways ................................. 45

Figure 29: . Haynesville hydrocarbon generation pressure versus time extracted from 2D models at the 1-Gish and 1-Cates wells ............................................................................ 47

Figure 30: Pressure increase due to hydrocarbon generation in the north to south cross-section at 105 and 88 Ma................................................................................................... 48

Figure 31: Pressure increase due to hydrocarbon generation in the north to south cross-section at 87 and 85 Ma..................................................................................................... 49

Figure 32: Pressure versus depth for variable permeabilities of the Hosston, Cotton Valley, and Bossier formations ......................................................................................... 51

viii

Figure 33: Porosity and permeability versus depth profile for 1 Gish well at 0 Ma. The permeability of the Hosston, Cotton Valley, and Bossier Formations vary by one and two orders of magnitude. .......................................................................................................... 52

Figure 34: Cross section B-B’ with pressure overlay and arrows indicating direction of gas (red) and oil (green) migration. Smackover Limestone permeability values are one order of magnitude less those used in final model. ........................................................... 54

Figure 35: Cross section B-B’ with pressure overlay and arrows indicating direction of gas (red) and oil (green) migration. Smackover Limestone permeability values are two orders of magnitude less those used in final model. ......................................................... 55

Figure 36: Pressure versus depth for the 1 Gish D well at 0 Ma for 0 ft, 500 ft, and 1500 ft of Eocene erosion. ........................................................................................................ 56

Figure 37: Smackover and Haynesville hydrocarbon generation pressure in the north to south cross section at 105 and 88 Ma. ............................................................................... 58

Figure 38: Smackover and Haynesville hydrocarbon generation pressure in the north to south cross section at 87 and 85 Ma. ................................................................................. 59

Figure 39: Present day pore pressure comparison of 1D vs 2D models for 1-Gish well .. 61

Figure 40: Present day pore pressure comparison of 1D vs 2D models for 1-Cates well . 61

Figure 41: Present day pore pressure comparison of 1D vs 2D models for 1-Foster well 62

Figure 42: Present day pore pressure comparison of 1D vs 2D models for C1-Tremont well .................................................................................................................................... 62

Figure 43: Smackover structure map at 0 Ma. Red arrows indicate the direction of fluid migration. Well control is shown by black dots ............................................................... 63

Figure 44: Smackover structure map at 0 Ma. Red arrows indicate the direction of fluid migration. Well control is shown by black dots ............................................................... 66

Figure B1: Major geologic processes in basin modeling .................................................. 77

Figure B2: Process workflow diagram for numerical basin modeling.............................. 78

ix

Abstract

New drilling technology has led to a revival of drilling in mature petroleum basins

such as the Haynesville Formation in east Texas and north Louisiana. In north Louisiana,

the Upper Jurassic (Kimmeridgian) aged Haynesville shale has a basinward SW dip and

is located at depths ranging from around 10,500 ft to the northeast and 14,000 ft to the

southwest with local minimums at the Sabine and Monroe Uplifts. Formation thickness

ranges from 100 to 400 feet. Prolific natural gas production is attributed to relatively

high average porosity (8 to 14%) and a high geopressure gradient > 0.9 psi/ft. (Wang and

Hammes, 2010). Using subsurface data, 1-dimensional and 2-dimensional models across

the North Louisiana Salt Basin were created to estimate the thermal, pressure, and fluid

flow histories of the Haynesville Shale. Disequilibrium compaction from rapid

sedimentation in the low permeability (nanodarcy) Haynesville Shale coupled with

hydrocarbon generation has resulted in high pore pressures ranging from about 7000 psi

to 12000 psi. Hydrocarbon generation resulted in a maximum pressure increase of 500

psi at 88 Ma; however models created with and without hydrocarbon generation produced

nearly identical results for present day pore pressure indicating that disequilibrium

compaction is the most significant mechanism in generating overpressure. Updip fluid

migration to the Sabine Uplift within the Haynesville Shale and underlying Smackover

Limestone has resulted in abnormally high fluid pressures on the Sabine Uplift. 1D and

2D models did not calculate pressures in excess of the fracture gradient; however natural

fractures likely aided in lateral fluid migration within the Haynesville Shale. A 3D model

that incorporates fluid migration from the entire basin and the East Texas Salt Basin is

needed to accurately estimate the pressure history of the Haynesville Shale.

1

Chapter 1. Introduction The Upper Jurassic (Kimmeridgian) Haynesville Shale is a prolific natural gas

producing rock that has led to the revival of exploration and drilling in the heavily

explored North Louisiana Salt Basin and East Texas Salt Basin (Figure 1) (Mancini et

al, 2005). New drilling and completion techniques allow companies to produce

hydrocarbons directly from the source rock. The Haynesville is a particularly

attractive shale gas play because of high overpressures (Wang and Hammes, 2010).

High overpressures tend to enhance the porosity, gas content, and apparent

brittleness of gas shales (Wang and Hammes, 2010). The pore pressure of the

Haynesville is near the fracture pressure. Low effective stress makes the

Haynesville easy to hydraulically fracture using modern well completion techniques.

(Wang and Lui, 2011)

The Haynesville Shale consists of a dark, organic rich, mudstone-marl facies

with ubiquitous pyrite (Buller and Dix, 2009). The Haynesville is known to contain

natural hydraulic fractures that have been mineralogically healed as a result of fluid

flow (Buller and Dix, 2009). Disequilibrium compaction coupled with hydrocarbon

generation can result in significant overpressures in low permeability (nanodarcy)

rocks (Swarbrick et al, 2002) such as the Haynesville Shale. The purpose of this

study is to use 1D and 2D basin models to estimate the burial, thermal, maturation,

pore pressure, and fluid migration history of the Haynesville Shale to further our

understanding of the distribution of overpressures and the propagation of natural

hydraulic fractures (Nunn et al., 1984; Li, 2006; Mancini et al., 2008).

2

Chapter 2. Geologic Overview

2.1 Study Area

The Haynesville Shale gas play occurs over a broad area covering the East Texas

Salt Basin and the North Louisiana Salt Basin. This study is confined to north Louisiana

(Figure 1). The main play occurs over the Sabine Uplift corresponding to relatively

shallower Jurassic strata and high gas production (Hammes et al., 2011). The initial

basin architecture and extensional history created a series of high standing basement

blocks separated by areas of more extended crust influencing the distribution and

deposition of salt and younger Jurassic rocks. Cretaceous uplift likely affected thermal

history, burial history, and thermal maturity of the basin (Hammes et al., 2011).

Figure 1. Map showing the locations of the Gulf Coast sub-basins. The study area is shown in red (modified after Mancini et al., 2005).

3

2.2 Tectonic Framework

The formation of the North Louisiana Salt Basin is related to the opening of the

Gulf of Mexico in the Jurassic (Wood and Walper, 1974). The Gulf of Mexico is a

passive continental margin characterized by extension occurring in the Late Triassic to

Early Jurassic (Pilger, 1981). The North Louisiana Salt Basin is a negative feature that is

bounded by positive features known as the Sabine Uplift to the west and the Monroe

Uplift to the northeast (Figure 1). Sediment deposition was influenced by rift tectonics.

Maximum subsidence occurred in areas of more extended crust resulting from isostatic

subsidence due to cooling and contraction of crust. This led to thicker salt and sediment

deposition in areas corresponding with more extended crust (Nunn et al., 1984).

Subsidence and reactivation of the Sabine and Monroe Uplifts in the Cretaceous and

Tertiary had a profound impact on deposition and erosional patterns of the overlying

strata (Li, 2006).

The Sabine and Monroe Uplifts are part of a larger area of positive and negative

features that stretch from Texas to Florida and are located to the north of the Gulf of

Mexico basin (Figures 1 and 2). Geophysical evidence suggests that the uplifts

correspond to blocks of less extended crust (Mikus and Keller, 1992) (Figure 3). Thin

salt deposited over the Sabine Uplift is evidence that it was a positive feature during the

mid-Jurassic (Pilger, 1981). The feature subsided during the Late Jurassic and Early

Cretaceous and had no topographic expression during this time (Nunn et al., 1984). The

Sabine and Monroe Uplifts were reactivated during the Late Cretaceous resulting in

extensive erosion of early Cretaceous sediment. Several hypotheses have been proposed

to explain the Cretaceous reactivation including tectonic compression during Cordilleran

thrust faulting in western North America (Jackson and Laubach, 1988; Laub

Jackson, 1990) and partial relaxation of the lithosphere due to buoyant crustal blocks of

different thicknesses (Nunn, 1

in Texas and northeastern Mexico

uplifts are a result of thermal

and Monroe Uplifts were reactivated during the Eocene as evidenced by thinning of the

Wilcox formation (Jackson and Laubach, 1988).

Figure 2. Structural elements of the northern Gulf of Mexico. basement in kilometers modified from Sawyer et al. (1991). Partial cross section Afor Figure 3 is shown. SU=Sabine Uplift; WU=Wiggins Uplift; MGA=Middle Ground Arch; SA=Sarasota Arch, ETSB=East Texas Salt Basin; NLSB=North Louisiana Salt Basin; MSB=Mississippi Salt Basin; Green lines are transform faults; dark orange=continental crust, light orange=thick transitional crust; light green = thin transitionaafter Hammes et al, 2011).

4

estern North America (Jackson and Laubach, 1988; Lauba

Jackson, 1990) and partial relaxation of the lithosphere due to buoyant crustal blocks of

different thicknesses (Nunn, 1990). However, lack of Cretaceous anticlinal development

in Texas and northeastern Mexico as well as the absence of strike slip faulting suggest

relaxation of the lithosphere (Ewing, 2009). The Sabine

reactivated during the Eocene as evidenced by thinning of the

n (Jackson and Laubach, 1988).

Figure 2. Structural elements of the northern Gulf of Mexico. Contours: depth to modified from Sawyer et al. (1991). Partial cross section A

for Figure 3 is shown. SU=Sabine Uplift; WU=Wiggins Uplift; MGA=Middle Ground Arch; SA=Sarasota Arch, ETSB=East Texas Salt Basin; NLSB=North Louisiana Salt Basin; MSB=Mississippi Salt Basin; DSSB=De Soto Salt Basin; TB=Tampa Basin. Green lines are transform faults; dark orange=continental crust, light orange=thick transitional crust; light green = thin transitional crust; purple = oceanic crust

ach and

Jackson, 1990) and partial relaxation of the lithosphere due to buoyant crustal blocks of

development

as well as the absence of strike slip faulting suggest the

The Sabine

reactivated during the Eocene as evidenced by thinning of the

depth to modified from Sawyer et al. (1991). Partial cross section A-A’

for Figure 3 is shown. SU=Sabine Uplift; WU=Wiggins Uplift; MGA=Middle Ground Arch; SA=Sarasota Arch, ETSB=East Texas Salt Basin; NLSB=North Louisiana Salt

DSSB=De Soto Salt Basin; TB=Tampa Basin. Green lines are transform faults; dark orange=continental crust, light orange=thick

(modified

Figure 3. Model of crust from gravity data along a northUplift along the Texas-Louisiana borderObserved gravity is represented by a triangle, and the calculated gravity isa plus symbol. (B) Interpretation of Crust. Numbers represent density in g/cm3. mi mafic intrusions (3.05 g/cm3)A-A’ shown in Figure 2.

2.3 The Haynesville Shale

The Late Jurassic (Kimme

Smackover Limestone (Figure 4)

dominated, matrix supported carbonate

grainstones of the Upper Smackover (

Overlying the Haynesville

Group consists of the Bossier, Cotton Valley, Hosston and Sligo Formation

Valley Formation is predominately shale interbedded with tight

porosity and 0.1 mD permeability) and limestone

5

Figure 3. Model of crust from gravity data along a north-south line through the Sabine Louisiana border. (A) Gravity data measured in Gal x 1000.

Observed gravity is represented by a triangle, and the calculated gravity is represented by a plus symbol. (B) Interpretation of Crust. Numbers represent density in g/cm3. mi mafic intrusions (3.05 g/cm3) (modified after Mickus and Keller, 1992). Line of section

Jurassic (Kimmeridgian) aged Haynesville Shale is underlain by the

(Figure 4). The lower Smackover consists of mudstone

dominated, matrix supported carbonates that grade upwards into packstones and

grainstones of the Upper Smackover (Presley and Reed, 1984).

Overlying the Haynesville Shale is the Cotton Valley Group. The Cotton Valley

the Bossier, Cotton Valley, Hosston and Sligo Formations. The C

ormation is predominately shale interbedded with tight sandstones (8

.1 mD permeability) and limestones (Zimmerman, 1999).

ine through the Sabine . (A) Gravity data measured in Gal x 1000.

represented by a plus symbol. (B) Interpretation of Crust. Numbers represent density in g/cm3. mi –

1992). Line of section

is underlain by the

mudstone

that grade upwards into packstones and

is the Cotton Valley Group. The Cotton Valley

s. The Cotton

sandstones (8-10 %

6

Figure 4. Stratigraphic column of north Louisiana (Li, 2006).

7

The Lower Cretaceous Trinity Group is composed mainly of chalky to oolitic

limestone, calcareous shale with stringers of anhydrite, and a massive anhydrite unit

(Ferry Lake). The Washita Fredericksburg group is composed of sandstones, shelly

limestones, and calcareous shales (Martin et al., 1954). The remaining Upper Cretaceous

section is composed mainly of gray chalk, chalky shales interbedded with limestone, and

marl (Murray, 1948). The Tertiary section marks a shift from carbonate to clastic

deposition. The section is composed mainly of shale with interbedded sandstone

(Zimmerman, 1999).

The organic rich Haynesville Shale currently targeted for natural gas exploration

is present in both the East Texas Salt Basin and the North Louisiana Salt Basin. There is

not complete agreement on the exact stratigraphic relationships or terminology used for

rock units believed to be equivalent to the Haynesville Shale deposited along the Gulf

Coast (Goldhammer, 1998; Ewing, 2001; Hammes, 2009). Therefore a broader

definition of the Haynesville Formation is adopted as a heterolithic assemblage of later

Kimmeridgian siliciclastics, evaporites, carbonates and mudstones that extend from

eastern Texas to offshore of the Florida Panhandle (Ewing 2001). In north Louisiana the

Haynesville Shale has a basinward southwest dip and is located at depths ranging from

around 10,500 ft. to 14,000 feet with local highs at the Sabine and Monroe Uplifts.

Thicknesses range from 100 to 400 feet. Local variations in depth may be attributed to

post-depositional uplift, subsidence, or salt movement (Hammes et al., 2011).

The Haynesville Shale exhibits lateral variations in lithology across the basin in

response to relative changes in siliciclastic versus carbonate input. Siliciclastic input was

dominantly to the north and east. Carbonate production was dominantly in the south and

8

west. Calcite content is controlled by erosion of nearby carbonate shoals (Goldhammer,

1998; Ewing 2001). The Haynesville shale is inferred to be more carbonate rich in the

south and southeast and more silica rich in the north and northwest (Buller and Dix,

2009). The Haynesville Shale is inferred to be more carbonate rich in north Louisiana

versus more clastic rich in east Texas.

A unique feature of the Haynesville Shale compared to other shale gas plays is

that it has abnormally high pressures (Wang and Liu, 2011). The pore pressure gradient

is about 0.9 psi/ft (Wang and Hammes, 2010), which is much higher than a normal

pressure gradient of 0.465 psi/ft. for typical Gulf Coast waters (Schlumberger Oilfield

Glossary). High pressures enhance porosity, gas content, and apparent brittleness in the

shale. Wang and Hammes (2010) estimated bottom hole pore pressures from well test

data (Figure 5). They observed that in Louisiana, Haynesville pore pressures exceeding

10,000 psi are found in Desoto and Red River Parishes and pore pressures decrease to the

north and south of this area.

Natural fractures play an important role in many shale plays (Gale et al., 2007;

Engelder et al., 2009). The Haynesville Shale is known to be brittle and naturally

fractured in some areas (Figure 6) (Buller and Dix, 2009). Very few natural fractures are

open and most are cemented with minerals such as calcite (Buller and Dix, 2009).

Although the Haynesville Shale is known to be hydraulically fractured, little research has

been made public as to the characterization or orientation of the fractures.

Figure 5. Pressure contour map of the Haynesville shale from well test data (Wang and Hammes, 2010)

9

map of the Haynesville shale from well test data (Wang and

map of the Haynesville shale from well test data (Wang and

10

Figure 6. Twenty feet of image log showing natural fractures at mid-level position in Haynesville Shale (Buller and Dix, 2009). The well is located in Desoto Parish, LA.

11

2.4 Fluid Overpressure

Much of the world’s oil and gas was generated from overpressured source rocks

(Hunt, 1990). If the pore pressure in a sedimentary rock is greater than the pressure

predicted by the weight of the overlying water column than it is referred to as

overpressured. Many theories have been proposed to explain the generation of

overpressures in sedimentary basins. The mechanisms that have the most impact on the

generation of overpressure in sedimentary basins are disequilibrium compaction,

hydrocarbon generation, or some combination of both (Swarbrick et al., 2002).

Disequilibrium compaction refers to the incomplete dewatering of low

permeability sediments during rapid sedimentation. Rapid sedimentation causes an

increase in vertical stress in a relatively short time span. Because the sediment does not

have adequate time to dewater, some portion of the weight of the increased load is

supported by the pore fluid (Swarbrick et al., 2002). Disequilibrium compaction will

result in sediments having greater pore pressure than the predicted hydrostatic pressure

(weight of the overlying water column) and a higher porosity relative to a normally

pressured and fully compacted rock. Disequilibrium compaction occurs at depth when

the permeability of the sediment is too low to allow for complete dewatering to occur.

According to Luo and Vasseur (1992) the main factors controlling the generation of

overpressure due to disequilibrium compaction are sedimentation rate, compaction

coefficient (rock “compressibility”), temperature, and permeability.

The conversion of kerogen to hydrocarbons may also play a role in the generation

of overpressure in sedimentary basins. Organic rich source rocks are exposed to

increasing temperatures as depth of burial increases which may convert kerogen to

12

hydrocarbons. The pore space in these source rocks becomes filled with petroleum and

water. Pore pressure will increase as the high-density kerogen in the source rocks is

converted into low-density hydrocarbons which results in an increase in volume.

Overpressure will occur as long as the rate of volume increase is faster than the rate of

fluid expulsion out of the source rock. (Guo et al., 2011).

2.5 Hydraulic Fractures A hydraulic fracture is a fracture that propagates as a result of the migration of

highly pressured fluid through a brittle rock (Hubbert and Willis 1957). It is important to

distinguish external hydraulic fractures from internal hydraulic fractures (Mandl and

Harkness 1987). External hydraulic fractures result from a fluid that originates from the

outside and penetrates an impermeable rock. This mechanism is used to explain the

migration of magmatic dikes and sills. Internal hydraulic fractures occur when

overpressured fluids migrate through the pore spaces within a rock and create fractures at

an internal point of weakness. This mechanism is generally used to explain mineral filled

veins in low permeability rocks. Primary migration of hydrocarbons through low-

permeability source rocks may be assisted by hydraulic fracture propagation (Nunn

1996).

The fracture pressures calculated in this study are the minimum pressure needed

for hydraulic fractures to propagate perpendicular to the least principal stress. In a

passive continental margin setting such as the North Louisiana Salt Basin, the least

effective stress is horizontal and fractures should be vertical (Sibson, 2003). The

Haynesville Shale may contain horizontal factures (J. A. Nunn, personal communication

2012). However, detailed fracture data are not yet available in the public domain.

13

Horizontal fractures within the Haynesville Shale may be explained by at least

one of the following conditions: 1) horizontal compression from tectonic forces, 2) high

susceptibility for fractures along bedding planes (anisotropic tensile strength) (Lash and

Engelder, 2005), or 3) vertical seepage forces from migrating fluid cause the least

principal stress to become vertical (Cobbold and Rodrigues, 2007).

14

Chapter 3. Data and Methods

3.1 Data Wireline logs from 49 wells containing gamma ray, spontaneous potential, and/or

resistivity curves were used in this study (Figure 7). Logs were obtained from the

Louisiana Department of Natural Resources (SONRIS).

3.2 Well Tops and Lithologies

Formation tops were picked from well logs based on their characteristic SP,

gamma ray, and resistivity signatures. (Li, 2006; Geological Consulting Services, 1976).

Figure 8 shows a type log concatenated from three north Louisiana well logs with picks

for each interval used in this study. The Haynesville Shale differs from the overlying

Bossier Shale in most common log responses. The Haynesville Shale gamma ray

response is slightly higher than that of the Bossier shale, the spontaneous potential is

slightly more positive, and there is generally an increase in resistivity at the top of the

Haynesville Shale (Figure 8). The Smackover Limestone was picked based on a

significant increase in resistivity. Lithologies may exhibit spatial variation due to lateral

facies changes across the basin. The Haynesville Shale is more carbonate rich in north

Louisiana and becomes more clay rich in east Texas (Buller and Dixon, 2009). The log

data used in this study was not of the quality needed to interpret subtle mineralogical

changes in the Haynesville Shale, thus, spatial lithology variations were not considered in

this study. Lithologies used in modeling were based on work by Zimmerman (1999) and

Buller and Dix (2009). (Table 1)

15

Fi

gure

7.

Map

of n

orth

Lou

isia

na w

ith w

ell c

ontr

ol s

how

n by

cir

cles

.

16

SP Resistivity SP Resistivity

Figure 8. Type log for north Louisiana. The spontaneous potential curve in the left track and the resistivity curve in the right track. The type log is an aggradation of three wells located in north Louisiana. All logs are 1 inch with 100 ft. spacing. Logs were downloaded from the State of Louisiana Department of Natural Resources (sonris.com).

SP Resistivity

SP Resistivity

17

Table 1. Lithologies used for modeling Layer Lithology Tertiary Shale (typical) 75%/Sandstone (typical) 25% Wilcox Shale (typical) 75%/Sandstone (typical) 25% Midway Shale (typical) 75%/Sandstone (typical) 25% Navarro Limestone (chalk, typical) 60%/Sandstone

(typical) 25%/Shale (typical) 15% Austin Limestone (chalk, typical) Eagle Ford, Wash/Fred undifferentiated Shale (typical) 40%/Sandstone (typical) 30%/

Limestone (chalk, typical) 30% Glen Rose Shale (typical) 40%/Sandstone (typical) 30%/

Limestone (chalk, typical) 30% Mooringsport Limestone (shaly) Ferry Lake Shale (typical) Rodessa Limestone (shaly) Bexar Shale (typical) James Limestone (shaly) Pine Island Shale (typical) Sligo Limestone (shaly) Hosston Shale (sandy) default κ lowered 1 [log(mD)] Cotton Valley Shale (sandy) default κ lowered 1 [log(mD)] Bossier Shale (sandy) default κ lowered 1 [log(mD)] Haynesville Limestone (chalk, typical) 70%/Shale

(typical) 30% Smackover Limestone (micrite)

3.3 Modeling

Basin models were created using Schlumberger’s PetroMod® software suite.

Thirty nine 1D models were created from well information (Figure 7) to calculate

thermal, maturation, hydrocarbon generation and pressure history in one dimension. 2D

profiles were created to study the effects of fluid migration by concatenating selected 1D

input files. Two nineteen layer regional cross section models were created over the

Sabine Uplift using PetroMod®. A-A’ is a north to south cross section over the Sabine

Uplift. B-B’ is an east to west cross section that spans the Sabine Uplift, the North

Louisiana Salt Basin, and the southwestern flank of the Monroe Uplift. For

18

unconformities, stratigraphic thickness was restored to original thickness and removed

later as erosional events. 1D models were gridded using a maximum cell thickness of 20

m for all layers and a maximum time step duration of 1 Ma. 2D models were gridded

using a maximum vertical cell thickness of 20 m for the Haynesville layer, 50 m for the

Bossier and Smackover layers, and 400 m for the remaining layers. Running the models

with tighter grids for formations younger than the Bossier did not impact the

Haynesville’s geohistory and required significantly longer run times. 300 horizontal grid

points and maximum time step durations of 1 Ma were used in each 2D model (Figure 9).

Appendix B contains a more detailed explanation of the numerical modeling used in this

study.

3.4 Geologic Ages Stratigraphic intervals observed in well log data used in this study range from

Jurassic to Eocene in age. Geologic ages were assigned to the stratigraphic intervals

(Figure 4) using extensive biostratigraphic work done in the Gulf Coast region

summarized by Li (2006). Ages of the Tertiary units are from the work of Mancini and

Tew (1991). For the Upper Cretaceous strata, outcrop work of Christopher (1982),

Puckett (1985), Mancini et al. (1996), and the subsurface work of Mancini and Payton

(1981) were used to assign ages. Ages of the Lower Cretaceous units are from Imlay

(1940) and Young (1970). Ages of the Upper Jurassic strata are from Imlay and Herman

(1984) and Young and Oloritz (1993). Li also used geologic age data published by Todd

and Mitchum (1997) and Salvador (1987).

19

Fi

gure

9.

Dis

cret

izat

ion

of 2

D m

odel

s. 2

0 m

max

imum

cel

l thi

ckne

ss w

as u

sed

for t

he H

ayne

svill

e la

yer,

50 m

for t

he B

ossi

er a

nd

Smac

kove

r lay

ers,

and

a m

axim

um c

ell t

hick

ness

of 4

00 m

was

use

d fo

r all

othe

r lay

ers.

300

hor

izon

tal g

rid

poin

ts w

ere

used

.

Wes

t Ea

st

20

3.5 Erosion Estimates Erosion in the North Louisiana Salt Basin is related to activation of the Sabine

and Monroe Uplifts. The uplifts became active in the mid-Cretaceous (Jackson and

Laubach, 1988; Nunn, 1990). Uplift and erosion continued through the late Cretaceous.

On the Sabine and Monroe, uplift occurred as recently as the Eocene (Laubach and

Jackson, 1990). Significant erosion of Cretaceous strata on the Monroe Uplift is

observed as truncation of strata down to the Hosston Formation. Erosion is less

significant on the Sabine Uplift (Li, 2006), and maximum erosion has truncated sediment

as deep as the Upper Glen Rose Formation. Erosion in the North Louisiana Salt Basin

exists primarily on the north flank of the basin and has removed sediment as deep as the

Mooringsport Formation (Li, 2006).

Six major unconformities are interpreted to have occurred within the Mesozoic

and Cenozoic strata of north Louisiana and the unconformities were broken down into

two categories, depositional hiatus or sediment erosion (Li, 2006) (Table 2).

On the Sabine Uplift, Cretaceous sediment erosion varies from 200 to 600 feet

(Figure 10) (Li, 2006). The largest amounts of erosion occurred over the Monroe Uplift.

Maximum erosion is estimated at 7,200 feet (Li, 2006). Uplift and erosion occurred as

recently as the early Eocene, but the original thicknesses of Eocene sediments deposited

on the Sabine are not known and the Sabine was likely subaerially exposed during this

time (Jackson and Laubach, 1988; Laubach and Jackson, 1990).

Due to the thin stratigraphic thickness of Cretaceous units including the Eagle

Ford, Tuscaloosa, and Washita/Fredericksburg Formations (Figure 8), the units were

consolidated into a single layer for modeling. The layer is referred to as the Eagle Ford

21

Table 2. Cenozoic and Mesozoic unconformities of North Louisiana.

Unconformity Type Age (Ma) Stratigraphic Location

Middle Jurassic Depositional Hiatus 195-176 Top Eagle Mills

Early Cretaceous Depositional Hiatus 137-132 Top Cotton Valley

Late Cretaceous Sediment Erosion 99-98 Top Washita Fredericksburg

Post Eagle Ford Sediment Erosion 88-87 Top Eagle Ford

Post Austin Sediment Erosion 85-82 Top Austin

Early Tertiary Sediment Erosion 68-61.5 Top Midway

Wash/Fred undifferentiated unit. The deposition of these formations spans the 99-98 Ma

and 88-87 Ma unconformities. Erosion associated with the two unconformities was

accounted for in the model in the 88-87 Ma unconformity (Figure 10). Consolidating the

erosion into one event did not have a significant impact on the geohistory of the

Haynesville. Erosion on the Austin Chalk (85-82 Ma) was not significant enough to have

an effect on modeling and was therefore ignored (Li, 2006).

3.6 Present Day Heat Flow Present day heat flow values for north Louisiana were taken from Southern

Methodist University’s Geothermal Laboratory surface heat flow map (Blackwell and

Richards, 2004) (Figure 11). Heat flow values on this map were determined from the

geothermal gradient and thermal conductivities of the basin sediments.

Heat flow values for North Louisiana range from about 50 to 70 mW/m2. These

values are anomalously high when compared to adjacent areas surrounding north

Louisiana. High surface heat flow values may be attributed to salt domes in the area

22

Figure 10. A) Eroded thickness (feet) of the missing Cretaceous section in north Louisiana from Li (2006). Well control is shown by red and blue dots (Li, 2006) B) locations of wells used by Li ( 2006).

A. B.

B.

Figure 11. North America heat flow map (Blackwell and Richards, 2004) and/or an increase of radioactive elements in the basement rocks. Salt has a thermal

conductivity on the order of 2 to 4 times greater than other sedimentary rocks (Gray and

Nunn, 2010). An average present day heat flow value of 60

study. Slight variations in present day heat flow

day %Ro values, but do not significantly impact the thermal history of the Haynesville

and timing of hydrocarbon generation.

3.7 Paleoheat Flow The North Louisiana Salt Basin formed as a result of rifting during the opening of

the Gulf of Mexico from the Late Triassic to Early Jurassic (

flow values associated with the opening of the basin were calculated

simple extensional model (McKenzie, 1978).

23

Figure 11. North America heat flow map (Blackwell and Richards, 2004)

ncrease of radioactive elements in the basement rocks. Salt has a thermal

conductivity on the order of 2 to 4 times greater than other sedimentary rocks (Gray and

An average present day heat flow value of 60 mW/m2 was used in this

Slight variations in present day heat flow result in negligible differences in present

Ro values, but do not significantly impact the thermal history of the Haynesville

and timing of hydrocarbon generation.

Louisiana Salt Basin formed as a result of rifting during the opening of

the Gulf of Mexico from the Late Triassic to Early Jurassic (Pilger, 1981). Paleoheat

associated with the opening of the basin were calculated in PetroMod

extensional model (McKenzie, 1978).

ncrease of radioactive elements in the basement rocks. Salt has a thermal

conductivity on the order of 2 to 4 times greater than other sedimentary rocks (Gray and

was used in this

result in negligible differences in present

Ro values, but do not significantly impact the thermal history of the Haynesville

Louisiana Salt Basin formed as a result of rifting during the opening of

Pilger, 1981). Paleoheat

in PetroMod using a

24

Paleoheat flow values calculated by the McKenzie model are impacted by rifting

and the amount of lithospheric extension. A rifting period from 190-170 mya was used.

Lithospheric extension is quantified using the beta factor (β), which is the ratio of

lithosphere thickness before and after extension. The beta factor for North Louisiana is

approximately 1.5-2 (Nunn et al., 1984). Paleoheat flow increased to a maximum at the

end of the rifting phase.

Two paleoheat flow models were used in this study. Paleoheat flows of

sediment overlying the Sabine and Monroe Uplifts were calculating using a beta factor of

1.5 (Figure 11) because it is inferred the crust there is less extended. Sediments

deposited in the North Louisiana Salt Basin are inferred to overlie more extended crust

and paleoheat flow values were calculated using a beta factor of 1.8 (Figure 12).

3.8 Thermal Maturity Thermal maturity of the Haynesville Shale was computed from the burial history

and thermal history using The EASY %Ro kinetic model (Burnham and Sweeny, 1989) in

PetroMod®. Observed TOC (total organic carbon) values in the Haynesville Shale

typically range from 2-6% (Dix et al., 2010) a value of 5% was used for modeling. TOC

weight percent is not an approximate estimation of resource present, and must be used

with caution when estimating the amount of hydrocarbons generated (Dembicki, 2009).

As the source rock generates and expels hydrocarbons, the amount of organic matter in

the source rock (TOC) and hydrogen index (HI) will decrease.

25

A)

B)

Figure 12. Paleo heat flow models used in this study. A) Calculated using a beta factor of 1.5 and used for wells located on the Sabine Uplift. B) Calculated using a beta factor of 1.8 and used for wells located in the deep basin and south of the Sabine Uplift.

3.9 Porosity and Pressure

Porosity estimates were calculated using the PetroMod® software. Porosity

estimates are based on Athy’s Law (1930) of mechanical sediment compaction.

Sediments progressively lose their porosity as a function of depth due to the effects of

loading. Athy used the following equation to estimate porosity:

Φ=Φ0 e(-az) (1)

Where Φ is estimated porosity, z = sub bottom depth (in meters), and Φ0 and a are

constants that vary with sediment type and burial history. Initial porosity of sediment

depends on lithology. Shales and mudstones start with porosities > 60%, sandstones

~40%, and carbonates can start as high as ~70% (Sclater and Christie, 1980). Fluid

pressures were computed as a function of overburden stress and fluid expansion in 1D

and 2D using PetroMod® software.

26

3.10 Paleowater Depths and Sediment Water Interface Temperature Paleowater depths and eustatic sea level correlations have not been

incorporated in this study because it is assumed that the sediments were deposited

in a shallow water environment (Nunn, 1984). The maximum estimated water

depth in north Louisiana in the Tertiary through the Jurassic is approximately 100

to 150 meters (Zimmerman, 1999). The effects of water loading at these depths are

believed to be negligible (Li, 2006).

27

Chapter 4. Results Models from four wells were chosen to display how burial, maturation, and

pressure history varies across the basin (Figure 13).

4.1 Thermal Maturation The transformation of kerogen to oil is interpreted to initiate at a vitrinite

reflectance (R0) value of 0.55%. The process of oil generation reaches completion at a

vitrinite reflectance value of 1%. The last liquid hydrocarbons are cracked to wet gas at

an R0 value of 1.3%. The shift from wet gas to dry gas occurs at an R0 value of 2.0%.

The production of dry gas ceases at an R0 value of 4.0% (Sweeney and Burnham, 1990).

The kerogen types associated with the Haynesville Shale were mainly gas prone type III

and some oil and gas prone type II/III (Mancini et al., 2008). Because oil generation

results in greater overpressure than gas generation, type II kerogen was used for all

models to simulate maximum pressures resulting from hydrocarbon generation. In the

North Louisiana Salt Basin, the Haynesville Shale began hydrocarbon generation in the

early Cretaceous and has continued into the Tertiary (Figure 14). On the Sabine Uplift,

calculated present day R0 values fall in the wet gas range. South and east of the Sabine

Uplift, Haynesville Shale maturity increases as depth of burial increases. R0 values fall

into the dry gas range.

1D basin models show that the earliest hydrocarbon generation within the

Haynesville Shale began in the deepest part of the basin and occurred at progressively

younger times for shallower beds (Figure 15). The onset of hydrocarbon generation

ranges from about 140-130 Ma in the study area. Modeled Haynesville R0 values range

from about 1.5% on the Sabine Uplift to 2.7% in the deep basin to 0.8% on the Monroe

28

Uplift (Appendix C). R0 values suggest the Haynesville has generated mostly gas.

Thermal maturity values are consistent with measured data (Mancini et al., 2008).

Figure 13. Map of study area showing the locations of the four wells discussed in the results and discussion sections. North to south cross section, A-A’, and west to east cross section, B-B; used in 2D models are shown in black.

4.2 Fluid Pressure In this study, 1D models were created to predict pore pressure as a function of

disequilibrium compaction and hydrocarbon generation. By definition 1D models do not

incorporate the effects of lateral fluid migration. Pore pressure, hydrostatic pressure,

lithostatic pressure, and the fracture pressure are plotted versus depth. The fracture

pressure computed in PetroMod® for all lithologies is 80% of the difference between the

29

A)

1-G

ish

(Sab

ine)

C

) 1-F

oste

r (Sa

bine

)

B)

C1-C

ates

(So

uth

of S

abin

e)

D)

C1-

Tre

mon

t (N

LSB

)

Figu

re 1

4. B

uria

l his

tory

plo

ts fr

om 1

D m

odel

s w

ith E

ASY

%R

O (S

wee

ny a

nd B

urnh

am, 1

990)

ove

rlay

for A

) 1-G

ish

(Sab

ine

Upl

ift)

, B

) 1-C

ates

(sou

th o

f Sab

ine

Upl

ift)

, C) 1

-Fos

ter (

Sabi

ne U

plif

t), a

nd D

) C1-

Tre

mon

t (ba

sin

cent

er) w

ells

.

30

Figure 15. Plot of vitrinite reflectance versus time from 1D models for the Haynesville Shale for four wells. The onset of hydrocarbon generation occurs at R0 = 0.55%, wet gas at R0 = 1.3%, and dry gas at R0 = 2% hydrostatic pressure and lithostatic pressure. 1D models show that the onset of present

day (0 Ma) overpressure begins in the Hosston Formation and increases with depth. 1D

models predict Haynesville overpressure to be greatest in areas of deep burial and for

pressure to decrease with burial depth (Figure 16). 1D modeling predicts the 1-Gish well

(Sabine Uplift) to have a present day pressure of 6,000 psi, the 1 Cates well (south of the

Sabine) 9,300 psi, 1-Foster (Sabine) 7,300 psi and the C1-Tremont well (deep basin) to

have a pressure of 11,100 psi. 1D models based on compaction disequilibrium and

hydrocarbon generation underestimate pressures observed on the Sabine Uplift (1-Gish

and 1-Foster wells) by an average of 1,000 psi (Figure 5).

Due to the underestimation of pressure resulting from 1D model calculations

compared to pressure data from well tests (Wang and Hammes, 2010) (Figure 5), 2D

basin models were created to study the effect of fluid migration on the occurrence of

overpressure in the Haynesville Shale (Figures 17 and 18). Two regional cross sections

Time [Ma]

Vitrinite Reflectance [%Ro]

Gish (Sabine)

Foster (Sabine)

Cates (south of Sabine)

Tremont (basin center)

31

were created from well data (Figure 13) to reflect the subsurface architecture of north

Louisiana. Two depth extractions were taken from each cross section at the well

locations: 1 Gish, 1 Cates, 1 Foster, and C1 Tremont (Figure 19). Extractions from the

2D model were used to compare the difference in pressure calculated using 1D and 2D

models. 2D pressure models predict present day (0 Ma) overpressure to begin at the top

of the Hosston Formation. 2D models A-A’ (Figure 17) and B-B’ (Figure 18) predict that

the greatest Haynesville Shale pore pressures are generated in the deep basin and pressure

progressively decreases as the depth to the Haynesville Shale decreases. In the north to

south cross section, A-A’ (Figure 17), estimated Haynesville Shale pore pressure ranges

from 9,000 psi south of the Sabine Uplift to 7,000 psi over the Sabine Uplift. South of

the Sabine Uplift a decrease in pressure relative to the overlying strata occurs in the lower

Bossier and Haynesville Formations. In the west to east cross section, B-B’ (Figure 18),

estimated Haynesville Shale pore pressures range from 10,000 in the deep basin to 8,200

on the Sabine Uplift. In the deepest part of the basin there is a decrease in pressure that

occurs in the lower Bossier and Haynesville relative to the overlying and underlying

strata. Haynesville Shale fluid pressure is nearest the fracture gradient on the Sabine

Uplift (Figure 20) directly after the Cretaceous reactivation of the Sabine Uplift and

erosion event occurring at 87 Ma (Figures 21 and 22)

4.3 Fluid Migration

Hydrocarbon flow path modeling shows that lateral fluid migration and vertical

migration into overburden and underburden formations has occurred in the Haynesville

Shale. In the north to south cross section model A-A’ (Figure 23), model results show

hydrocarbons generated in the Haynesville are expelled vertically into the overlying

32

A) 1 Gish at 0 Ma B) 1 Foster at 0

C) 1 Cates at 0 Ma D) C1 Tremont at 0 Ma

Figure 16. Pressure versus depth from 1D models. Modeled pressure estimates at the Haynesville Shale are as followed: a) 1 Gish - 6,000 psi, b) 1 Cates – 9,300 psi, c) 1 Foster – 7,000 psi, and d) C1 Tremont – 11,100 psi. Estimated pressure from well test data (Wang and Hammes, 2010) shown by the blue stars. C) and D) are outside the data used by Wang and Hammes (2010).

33

Fi

gure

17.

2D

cro

ss s

ectio

n, n

orth

to s

outh

, at 0

Ma

with

por

e pr

essu

re o

verl

ay.

The

loca

tions

of t

he 1

Cat

es a

nd 1

Gis

h w

ells

are

sh

own

in b

lack

.

1 G

ish

1 Ca

tes

Nor

th

Sout

h

Hor

izon

tal g

rid

poin

ts

34

Fi

gure

18.

2D

cro

ss s

ectio

n, e

ast t

o w

est,

at 0

Ma

with

por

e pr

essu

re o

verl

ay.

The

loca

tions

of t

he 1

Fos

ter a

nd C

1 T

rem

ont w

ells

are

sh

own

in b

lack

.

1 Fo

ster

C1 T

rem

ont

Wes

t Ea

st

Hor

izon

tal g

rid

poin

ts

35

1 Gish at 0 Ma 1 Foster at 0 Ma

1 Cates at 0 Ma C1 Tremont at 0 Ma

Figure 19. Pressure at 0 Ma from 2D model at well locations. Pressures at the well locations are as follows: a) 1Gish – 6,900 psi b) 1 Foster – 8,200 c) 1 Cates – 8,400 psi and d) C1 Tremont – 10,000 psi. Estimated pressure from well test data (Wang and Hammes, 2010) shown by the blue stars.

36

1-Gish (Sabine)

1-Cates (South of Sabine)

1-Foster (Sabine)

C1-Tremont (deep basin)

Figure 20. Pore pressure and fracture pressure versus time. Extractions from 2D models at well locations. Pressures from wells located on the Sabine Uplift (1 Gish and 1 Foster) are nearest the fracture gradient at 87 Ma

Time [Ma]

Time [Ma]

Time [Ma]

Time [Ma]

Fracture Pressure

Pore Pressure

Fracture Pressure

Pore Pressure

Fracture Pressure

Pore Pressure

Fracture Pressure

Pore Pressure

150 100 50 0

150 100 50 0

150 100 50 0

150 100 50 0

37

Fi

gure

21.

2D

cro

ss s

ectio

n, n

orth

to s

outh

, at 8

7 M

a w

ith p

ore

pres

sure

ove

rlay

.

Nor

th

Sout

h

1 G

ish

1 Ca

tes

Hor

izon

tal g

rid

poin

ts

38

Fi

gure

22.

2D

cro

ss s

ectio

n, w

est t

o ea

st, a

t 87

Ma

with

por

e pr

essu

re o

verl

ay.

Wes

t Ea

st

1 Fo

ster

C1 T

rem

ont

Hor

izon

tal g

rid

poin

ts

39

Figu

re 2

3. 2

D c

ross

sec

tion,

nor

th to

sou

th, a

t 0 M

a w

ith p

ore

pres

sure

ove

rlay

. H

ayne

svill

e Sh

ale

gas

flow

pat

hs a

re in

dica

ted

by re

d ar

row

s an

d oi

l flo

w p

aths

are

indi

cate

d by

gre

en a

rrow

s.

Nor

th

Sout

h

1 G

ish

1 Ca

tes

Hor

izon

tal g

rid

poin

ts

40

Bossier Formation and the underlying Smackover Formation. Hydrocarbons generated

south of the Sabine are expelled downward into the more permeable Smackover

Formation and migrate updip along the Haynesville/Smackover interface toward the

Sabine Uplift. In the west to east cross section B-B’ (Figure 24), model results show

hydrocarbons generated in the deep basin migrate downward into the Smackover

Formation and then migrate updip along the Haynesville/Smackover interface to the

Sabine and Monroe Uplifts.

Similar hydrocarbon migration flow paths are observed at 87 Ma (Figures 25 and

26). In the deep basin or south of the Sabine, fluids are expulsed downward into the

Smackover formation and travel updip along the Haynesville/Smackover interface toward

the Sabine and Monroe Uplifts. Some lateral fluid migration occurs within the

Haynesville, but this model does not incorporate a possible increase in effective

permeability due to the propagation of natural hydraulic fractures which could greatly

enhance lateral fluid migration within the Haynesville Shale. Fluids are also expulsed

vertically into overlying formations at this time.

Water migration pathways are shown for the north to south cross section and the

west to east cross section (Figures 27 and 28). At 0 Ma and 87 Ma water from the

Haynesville Shale is expelled upward into overlying formations at the Sabine Uplift. Off

structure, water is expelled vertically into the underlying Smackover Formation. At 0 Ma

all water in the Smackover is migrating from south to north and east to west. At 87 Ma,

and throughout most of the basin history, water migrated updip toward the Sabine and

Monroe uplifts.

41

Figu

re 2

4. 2

D c

ross

sec

tion,

wes

t to

east

, at 0

Ma

with

por

e pr

essu

re o

verl

ay.

Hay

nesv

ille

Shal

e ga

s fl

ow p

aths

are

indi

cate

d by

red

arro

ws

and

oil f

low

pat

hs a

re in

dica

ted

by g

reen

arr

ows.

Wes

t Ea

st

1 Fo

ster

C1 T

rem

ont

Hor

izon

tal g

rid

poin

ts

42

Figu

re 2

5. 2

D c

ross

sec

tion,

nor

th to

sou

th, a

t 87

Ma

with

por

e pr

essu

re o

verl

ay.

Hay

nesv

ille

Shal

e ga

s fl

ow p

aths

are

indi

cate

d by

re

d ar

row

s an

d oi

l flo

w p

aths

are

indi

cate

d by

gre

en a

rrow

s.

Nor

th

Sout

h

1 G

ish

1 Ca

tes

Hor

izon

tal g

rid

poin

ts

43

Figu

re 2

6. 2

D c

ross

sec

tion,

wes

t to

east

, at 8

7 M

a w

ith p

ore

pres

sure

ove

rlay

. H

ayne

svill

e Sh

ale

gas

flow

pat

hs a

re in

dica

ted

by re

d ar

row

s an

d oi

l flo

w p

aths

are

indi

cate

d by

gre

en a

rrow

s.

Wes

t Ea

st

1 Fo

ster

C1 T

rem

ont

Hor

izon

tal g

rid

poin

ts

44

Figure 27. 2D cross sections, north to south and west to east, at 0 Ma with vertical permeability overlay. Water flow paths are represented by blue arrows.

North South

0 Ma West

0 Ma

1 Gish

1 Cates

1 Foster

East

C1 Tremont

Horizontal grid points

Horizontal grid points

45

Figure 28. 2D cross sections from north to south and west to east at 87 Ma with vertical permeability overlay. Water flow paths are represented by blue arrows.

1 Gish

1 Cates

1 Foster

C1 Tremont

87 Ma North South

West 87 Ma

East

Horizontal grid points

Horizontal grid points

46

Chapter 5. Discussion

5.1 Sensitivity Studies Thermal maturation of the Hayneville Shale resulted in the onset of hydrocarbon

generation in the early Cretaceous. 1D and 2D models run with and without the effects

of hydrocarbon generation produced nearly identical results for present day pore pressure

indicating that much of the pressure resulting from hydrocarbon generation has dissipated

over time. Previous numerical modeling studies have shown that although hydrocarbon

generation contributes to overpressure, disequilibrium compaction is the most important

mechanism (Chi et al., 2010). Hydrocarbon generation plays an important role in the

pressure history of the Haynesville Shale. Hydrocarbon generation may result in an

increase in pressure (hydrocarbon generation pressure) due to the conversion of high

density kerogen into low density hydrocarbons. 2D model results show hydrocarbon

generation pressure maximums occurring in the late Cretaceous between 105-85 Ma

(Figure 29) with hydrocarbon generation pressure greatest just prior to Cretaceous uplift

and erosion at 88 Ma. Hydrocarbon generation pressure nears 500 psi at 88 Ma south of

the Sabine Uplift near the 1-Cates well (Figures 30 and 31). On the Sabine Uplift

hydrocarbon generation pressure at the 1-Gish well reaches a maximum of 60 psi (Figure

29). Due to the dynamic nature of fluids and the relatively thin stratigraphy of the

Haynesville Shale, large pressure increases due to hydrocarbon generation observed

south of the Sabine Uplift are not sustained over geologic time. Modeled hydrocarbon

generation pressures from 1D calculations are at least one order of magnitude lower than

hydrocarbon generation pressures calculated from 2D models. Haynesville Shale

overpressures resulting from disequilibrium compaction alone are at least one to two

47

orders of magnitude greater than the largest pressure increases due to hydrocarbon

generation.

Haynesville Shale Hydrocarbon Generation Pressure 1-Gish

Haynesville Shale Hydrocarbon Generation Pressure 1-Cates

Figure 30. Haynesville Shale hydrocarbon generation pressure versus time extracted from 2D model at the 1-Gish well (Sabine) and 1-Cates well (south of Sabine). Peaks in pressure occur from 105 – 85 Ma.

48

Figure 30. Pressure increases due to Haynesville Shale hydrocarbon generation in the north to south cross-section at 105 and 88 Ma. Haynesville Shale hydrocarbon generation pressure reaches a maxium at 88 Ma.

1 Gish

1 Cates

North South Hydrocabon Generation Pressure– 105 Ma

North South

1 Gish

1 Cates

Hydrocabon Generation Pressure– 88 Ma

Horizontal grid points

Horizontal grid points

49

Figure 31. Pressure increases due to Haynesville Shale hydrocarbon generation in the north to south cross-section at 87 and 85 Ma.

North South

North South

1 Gish

1 Cates

1 Gish

1 Cates

Hydrocarbon Generation Pressure– 87 Ma

Hydrocarbon Generation Pressure– 85 Ma

Horizontal grid points

Horizontal grid points

50

Fluid overpressure related to disequilibrium compaction is sensitive to rock

permeability and permeability values for a given lithology can vary over several orders of

magnitude. Simulations for fluid pressure were carried out varying the permeability of

the Hosston, Cotton Valley, and Bossier Formations by one and two orders of magnitude

lower than the PetroMod® software default permeability for the Shale (sandy) lithology.

PetroMod® assigns permeability based a multipoint porosity/permeability model. Each

point in this model is assigned porosity and permeability value. Each permeability value

at a given porosity was decreased by either one or two orders of magnitude during this

sensitivity study. Fluid overpressure increased significantly with decreasing permeability

as shown from the pressure profile from the 1-Gish well (Sabine Uplift) (Figure 33).

Varying the permeability in these formations also has an effect on the porosity and

permeability development of the Haynesville Shale and Smackover Limestone (Figure

34). Lowering the permeability of the Hosston, Cotton Valley, and Bossier Formations

by one order of magnitude resulted in porosity and permeability values for these

formations and the Haynesville that are consist with values published from literature

(Mancini et al., 2008). Lowering the permeability of these formations by one order of

magnitude results in a 900 psi pressure increase for the 1 Gish well (1D calculation).

Rock permeability has an effect on fluid flow pathways. 2D models were run

varying the permeability of the Smackover Limestone by 1 and 2 orders of magnitude

lower than the default permeability for limestone (micrite) lithology. Using default

permeability, hydrocarbons expelled into the Smackover migrate updip along the

Haynesville/Smackover interface and reenter the Haynesville at the Sabine Uplift (Figure

23). If the Smackover permeability is decreased by 1 order of magnitude, hydrocarbons

51

continue to migrate downward into the Smackover Formation and laterally along the

Smackover/Haynesville interface.

Figure 32. 1D present day pore pressure versus depth profile for the 1 Gish well with variable permeabilities for the Hosston, Cotton Valley, and Bossier Formations. The red line represents pressure using a default PetroMod® permeability, the black line represents a one order of magnitude permeability decrease, and the purple line represents a 2 order of magnitude permeability decrease. The blue star represents pressure estimated from well test data (Wang and Hammes, 2010).

52

Figure 33. Present day A) porosity and B) permeability versus depth profiles for 1 Gish well at 0 Ma. The permeability of the Hosston, Cotton Valley, and Bossier Formations vary by one and two orders of magnitude.

A.

B.

53

The change in permeability does not significantly alter the pore pressure across the basin

(Figure 34). When the Smackover permeability was decreased by two orders of

magnitude downward hydrocarbon migration from the Haynesville Shale in the deep

basin continues, and hydrocarbons continue to migrate laterally along the

Haynesville/Smackover interface. The distribution of fluid pressure across the basin is

not significantly altered (Figure 34). The permeability of the Smackover must be

decreased much more significantly to have a profound impact on hydrocarbon migration

pathways through the Smackover.

The pre-erosional thicknesses of early Eocene sediment on the Sabine Uplift are

unknown. Facies distributions indicate the Sabine may have been subaerially exposed

during Eocene deposition (Jackson and Laubach, 1988; Laubach and Jackson, 1990).

Eocene erosion is not believed to have occurred on the Sabine Uplift and was not

accounted for in previous modeling studies (Li, 2006; Mancini et al., 2008). However, if

Eocene sediments were in fact deposited and eroded it could impact the pressure history

of the Haynesville Shale. Sensitivity analyses were run varying the magnitude of Eocene

erosion by 0 ft, 500 ft, and 1500 ft (Figure 36). 500 ft of Eocene deposition and

subsequent erosion increases present day Haynesville pore pressure at the 1 Gish well by

200 psi. 1500 ft of Eocene deposition and subsequent erosion increases present day

Haynesville pore pressure at the 1 Gish well by 800 psi. Results show that Eocene

erosion would have an effect on the pressure history of the Haynesville, but erosion on

the scale of thousands of feet would be needed to have a significant impact on the present

day pressure. It is unlikely Eocene erosion of that magnitude occurred on the Sabine

Uplift

54

Fi

gure

34.

Cro

ss s

ectio

n B

-B’ w

ith p

ore

pres

sure

ove

rlay

at 0

Ma.

Red

(ga

s) a

nd g

reen

(oil)

arr

ows

indi

cate

hyd

roca

rbon

flow

pa

thw

ays.

Sm

acko

ver L

imes

tone

per

mea

bilit

y va

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are

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rder

of m

agni

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less

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ed in

the

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l mod

el.

Wes

t Ea

st

1 Fo

ster

C1 T

rem

ont

Hor

izon

tal g

rid

poin

ts

55

Fi

gure

35.

Cro

ss s

ectio

n B

-B’ w

ith p

ore

pres

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ove

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. R

ed (g

as) a

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esto

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re 2

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the

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56

Figure 36. Pressure versus depth for 1 Gish D well at 0 Ma with varied amounts of Eocene erosion. (Jackson and Laubach, 1988; Laubach and Jackson, 1990).

The focus of this study is the Haynesville Shale. However, the Smackover

Formation is the major petroleum source rock in the North Louisiana Salt Basin (Sassen

et al., 1987; Mancini et al., 2005). The Smackover Limestone has a measured present-

57

day TOC average of 0.58% and a calculated original TOC average of 1.00% (Mancini et

al, 2005). The kerogen found in the Smackover is type I and the majority of

hydrocarbons generated are believed to have been expelled into younger formations

(Mancini et al., 2005). A model was run with Smackover hydrocarbon generation along

with Haynesville generation to test the impact of Smackover hydrocarbon generation on

the pressure history of the Haynesville. Smackover hydrocarbon generation resulted in

maximum overpressure of 1900 psi occurring in the upper Smackover at 88 Ma (Figures

38 and 39). The incorporation of Smackover hydrocarbon generation into the model does

not significantly alter the pressure history of the Haynesville Shale nor did it result in

overpressures great enough to hydraulically fracture the Haynesville at any point in time.

Hydrocarbons generated in the Smackover Formation migrate updip towards the Sabine

and Monroe Uplift.

5.2 Fluid Pressure Transfer

The effect of lateral fluid pressure transfer is observed by comparison of 1D and

2D models. In the N-S profile the 1 Gish well, located on the Sabine Uplift, shows an

increase of 1000 psi when migration is incorporated into the model (Figure 39). South

of the Sabine Uplift, the 1 Cates well shows a decrease in pressure in the Bossier Shale,

Haynesville Shale, and Smackover Limestone when fluid migration is applied to the

model. In the 2D model Haynesville Shale pore pressure decreases by 900 psi relative to

the 1D model (Figure 40). In the E-W profile, the 2D 1-Foster well, located on the

Sabine Uplift, shows an increase of 1200 psi relative to the 1D model (Figure 41). East

of the Sabine Uplift, in the deep basin, the 2D C1 Tremont well model shows a decrease

in pressure in the Bossier Shale, Haynesville Shale, and Smackover Limestone relative to

58

Figure 37. North to south 2D model showing Smackover and Haynesville hydrocarbon generation pressures at 105 and 88 Ma.

North South Generation Pressure– 105 Ma

North Generation Pressure– 88 Ma

1 Gish

1 Cates

1 Gish

1 Cates

Horizontal grid points

Horizontal grid points

59

Figure 38. North to south 2D model showing Smackover and Haynesville hydrocarbon generation pressures at 105 and 88 Ma.

1 Gish

1 Cates

1 Gish

1 Cates

Generation Pressure– 87 Ma North South

North South Generation Pressure– 85 Ma

Horizontal grid points

Horizontal grid points

60

1D model. Haynesville pore pressure decreases by 1300 psi (Figure 42). The increase in

pressure observed on the Sabine Uplift and decrease in pressure in the deep basin in the

2D models relative to the 1D models is evidence that lateral fluid pressure transfer has

occurred within the Haynesville Shale and underlying Smackover Formation.

2D fluid migration modeling indicates that lateral fluid pressure transfer is largely

influenced by burial depth. Overpressures increase as depth of burial increases. Fluids

migrate from areas of deep burial and high overpressure to structural highs. Therefore

fluid pressure transfer occurring at 0 Ma is strongly influenced by the present day

structure of the basin. The top of the Smackover Formation was contoured to estimate

basin wide fluid migration at 0 Ma (Figure 43).

5.3 Hydrocarbon Migration

The direction of hydrocarbon migration is dependent on the pressure gradient,

permeability of the strata, capillary effects, and buoyancy force (Hubbert, 1953). The

model results indicate that the maximum occurrence of overpressure in the Haynesville

Shale occurs where depth of burial is the greatest. In the central basin of the west to east

cross section an increase in fluid pressure relative to the Haynesville Shale occurs in the

overlying Bossier Shale, forming a pressure barrier for upward fluid migration (Figure

24). The variations in fluid pressures in the deep basin resulted in a pressure gradient

favorable for the downward migration of fluid into the Smackover Limestone. Once

fluids were expelled into the underlying Smackover Limestone, the fluids migrate

laterally updip toward structural highs.

2D basin models predict that the Haynesville Shale pressure was nearest the

fracture gradient directly following the Cretaceous reactivation of the Sabine Uplift at 87

61

B) 1 Gish 2D

B) 1 Cates 2D

Figure 39. A) Present day pore pressure at 1 Gish well estimated from 1D model – 6,000 psi and B) pore pressure at 1 Gish well estimated from 2D model – 6,900 psi. The blue stars show pore pressure estimated from well test data (Wang and Hammes, 2010).

Figure 40. A) Present day pore pressure at 1 Cates well estimated from 1D model – 9,300 psi and B) pore pressure at 1 Gish well estimated from 2D model – 8,400 psi.

A) 1 Gish 1D

A) 1 Cates 1D

62

B) 1 Foster 2D

B) C1 Tremont 2D

Figure 41. A) Present day pore pressure at 1 Foster well estimated from 1D model – 7,000 psi and B) pore pressure at 1 Gish well estimated from 2D model – 8,200 psi. The blue stars show pore pressure estimated from well test data (Wang and Hammes, 2010)

Figure 42. A) Present day pore pressure at C1 Tremont well estimated from 1D model – 11,000 psi and B) pore pressure at C1 Tremont well estimated from 2D model – 10,000 psi.

A) 1 Foster 1D

A) C1 Tremont 1D

63

Figure 43. Smackover structure map at 0 Ma. Red arrows indicate the direction of fluid migration. Well control is shown by black dots. Scale is depth (feet). The basin deepens to the south. Dashed contours at the southern end of the map mark false closures resulting from poor well control. Ma (Figure 20). Hydrocarbon generation pressures reached a maximum of 60 psi on the

Sabine Uplift at 88 Ma, but the additional pressure was not enough to hydraulically

fracture the rock at this time. 2D migration modeling indicates that fluids migrate from

the deep basin updip to the Sabine and Monroe Uplifts resulting in higher pressures on

the Sabine. However the models only estimate fluid migration from a 2D plane. Fluid

pressure is likely migrating to the Sabine Uplift from other areas of the basin as well as

from the East Texas Salt Basin. Excess pressures from fluids migrating to the Sabine

Feet

64

may result in overpressures great enough to hydraulically fracture the Haynesville Shale

at 87 Ma (Figure 20).

5.4 Natural Hydraulic Fractures

Anisotropy due to natural fractures in the Haynesville was not accounted for in

this study but likely has an influence on hydrocarbon flow pathways. Lateral fluid

migration may have been facilitated through increased permeability along bedding planes

and natural hydraulic fractures. The propagation of natural hydraulic fractures would

increase the effective permeability of the Haynesville Shale and aid lateral fluid

migration. Haynesville Shale overpressure was closest to the fracture gradient on the

Sabine Uplift directly following the Cretaceous erosional event at 87 Ma. 2D models

show fluid migration occurring from the deep basin to the Sabine Uplift. A 3D model is

needed to incorporate fluid migration from the North Louisiana Salt Basin and East

Texas Salt Basin to the Sabine Uplift. 2D modeling suggests that at 87 Ma Haynesville

Shale overpressure was very near the fracture gradient. It is likely that 3D focusing of

fluid flow to structural highs would predict overpressures in excess of the fracture

gradient at this time. This would greatly enhance the effective permeability of the

Haynesville and fluid flow at this time. In order to estimate fluid migration pathways at

87 Ma 39 wells were decompacted and the top of the Smackover at 87 Ma was mapped

across the North Louisiana Salt Basin (Figure 44). 2D pressure models indicate that

Haynesville Shale fluids migrate from the deep basin towards the Sabine and Monroe

Uplifts. The propagation of natural hydraulic fractures during this time may have aided

fluid migration.

65

The Haynesville Shale is characterized by low permeability on the nanodarcy

scale (Wang and Hammes, 2010). Natural fractures can play a role in increasing the

permeability of this otherwise tight rock. Little research has been made public on

Haynesville Shale fractures, therefore the role of hydraulic fractures in fluid migration

within the Haynesville Shale is poorly understood. However, natural fractures are

common in petroleum source rocks (Gale et al., 2007; Engelder et al., 2009) and have

been observed in the Haynesville Shale (Buller and Dix, 2009). Most natural fractures in

the Haynesville have been mineralogically healed evidencing paleo fluid flow.

Horizontal hydraulic fractures may have increased the effective permeability and aided

the lateral migration of fluid pressure within the Haynesville Shale. Horizontal hydraulic

fractures may connect with joints or faults to aid expulsion of fluid pressure into

overlying and underlying formations. Hydrocarbon generation causes a localized

pressure increase within the Haynesville allowing fluids to be expulsed vertically into

overlying and underlying formations. Fluids expulsed into the underlying, more

permeable Smackover Limestone migrate laterally updip. On the Sabine Uplift, fluid

pressures increase within the Haynesville and Smackover due to lateral fluid pressure

transfer.

66

Figure 44. Smackover structure map at 87 Ma. Arrows indicate the direction of fluid migration Well control is shown by black dots. Scale is depth (feet). The basin deepens to the south. Dashed contours at the southern end of the map mark false closures resulting from poor well control. .

Feet

67

Chapter 6. Conclusions 1D and 2D basin models were created to estimate the burial history, thermal

history, and pressure history of the Haynesville Shale. Disequilibrium compaction

coupled with hydrocarbon generation has resulted in significant overpressures within the

Haynesville Shale. However disequilibrium compaction is the main control over the

occurrence of overpressure as hydrocarbon generation in the Haynesville resulted in a

maximum pressure increase of 500 psi compared to compaction disequilibrium results.

1D pore pressure models underestimate pore pressures calculated from well test data

from wells located on the Sabine Uplift (Wang and Hammes, 2010) by an average of

2000 psi. 2D pore pressure models underestimate well test data from wells located on the

Sabine Uplift by an average of 500 psi. Results from 2D models show higher pore

pressure on the Sabine Uplift compared to 1D model, and lower pressures in the deep

basin compared to 1D models, thus indicating that lateral fluid pressure transfer plays a

significant role in distribution of Haynesville fluid pressure. Hydrocarbon and water

migration modeling show that fluids expelled from the Haynesville Shale into the

underlying Smackover Formation migrate laterally updip along the

Haynesville/Smackover interface towards the Sabine and Monroe Uplifts. 1D and 2D

models did not produce Haynesville pore pressures in excess of the fracture gradient.

However, 2D Haynesville pressure models were very near the fracture gradient on the

Sabine Uplift following the Cretaceous erosion event due to a decrease in overburden

stress coupled with maximum hydrocarbon generation pressures. A 3D fluid migration

model that incorporates the entire North Louisiana Salt Basin and the East Texas Salt

Basin are needed to accurately estimate the pressure history of the Haynesville Shale on

68

the Sabine Uplift. Natural hydraulic fractures would increase the effective lateral

permeability of the Haynesville Shale and aid fluid migration toward the Sabine Uplift.

69

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Wang, F. P., U. Hammes. 2010, Key petrophysical factors affecting fluid flow in geopressured Haynesville Shale: AAPG Search and Discover, Article #90104. Wang, J., and Y. Liu, 2011, Simulation based well performance modeling in Haynesville Shale reservoir. SPE 142740. Wood, M. L., and J. L. Walper, 1974, The evolution of the interior Mesozoic basin and

the Gulf of Mexico: Gulf Coast Association of Geological Societies Transactions, v. 24, p. 21-41.

Young, K., 1972, Cretaceous paleogeography: implications of endemic ammonite

faunas: Texas Bureau of Economic Geology Geological Circular 72-2, p. 1-13.

Young, K., and F. Oloriz, 1993, Ammonites from the Smackover Limestone, Cotton Valley field, Webster Parish, Louisiana, U.S.A.: Geobios, v. 15, p. 401-409.

74

Zimmerman, R. K., 1999, Potential Oil Generation Capacity of the North Louisiana Hydrocarbon System: Gulf Coast Association of Geological Societies Transactions, v. 49, p. 532-540.

75

Appendix A. Well Tops

Top

Su

bse

a W

ell

Nam

eA

PI

Wil

cox

MD

YN

VR

AST

NEF

WF

un

dif

fG

LRS

MR

SPFR

LKR

OD

SB

XR

Jam

es

PI

Slig

oH

SSTN

CV

BO

SSR

HN

SVSM

K1-

AN

DR

EWS,

B. 3

3

17-0

31-2

4388

-00

-239

-1,0

42-1

,781

-2,5

11-3

,189

-3,9

04-4

,669

-4,8

95-5

,154

-5,4

54-5

,687

-5,8

38-6

,582

-9,0

24-1

0,95

9-1

1,58

0-1

1,80

41-

AN

TRIM

TR

UST

17

-015

-215

59-0

0-2

04-6

83-1

,356

-2,1

33-2

,387

-3,0

52-3

,822

-4,5

95-4

,833

-4,9

41-5

,348

-5,5

68-5

,757

-6,0

28-7

,972

-10,

061

-10,

586

-10,

712

1-B

AK

ER

17-0

13-2

0382

-00

159

-719

-1,3

32-2

,015

-2,5

25-3

,255

-3,8

99-4

,126

-4,4

57-4

,647

-4,9

15-5

,082

-5,2

71-7

,575

-10,

089

-10,

413

-10,

629

1-B

EEN

E 22

17

-027

-222

21-0

0-4

00-1

,251

-2,8

20-2

,230

-3,0

35-3

,765

-4,0

62-4

,229

-4,4

47-4

,706

-4,9

24-5

,119

-7,4

15-8

,714

-9,4

08-9

,632

1-B

LAC

KM

ON

P E

17

-061

-200

83-0

0-1

,382

-2,0

07-2

,306

-2,6

45-3

,055

-3,4

20-3

,957

-4,1

63-4

,329

-4,6

45-4

,959

-5,1

90-5

,429

-8,2

36-1

0,53

5-1

1,41

1-1

1,70

11-

BO

STW

ICK

HO

LT

17-0

17-2

0762

-00

-480

-1,3

12-2

,144

-2,5

67-3

,024

-3,7

59-4

,516

-4,7

62-4

,959

-5,2

91-5

,460

-5,6

29-5

,905

-7,3

22-9

,720

-10,

014

-10,

118

1-B

UR

TON

, CA

RTE

R

17-0

15-0

0100

-00

-179

-650

-1,4

71-2

,307

-2,7

33-3

,303

-4,1

07-4

,804

-5,0

34-5

,169

-5,4

79-5

,729

-5,9

18-6

,155

-7,9

60-1

0,02

3-1

0,27

2-1

0,37

41-

CA

TES

17

-085

-205

50-0

017

7-5

34-1

,419

-2,0

58-2

,871

-3,4

47-4

,256

-4,9

94-5

,210

-5,5

17-5

,830

-6,1

18-6

,236

-6,8

73-9

,639

-11,

702

-12,

342

-12,

518

1-C

RO

WN

ZEL

LER

BA

CH

A

17-0

69-2

0088

-00

-249

-997

-1,4

92-2

,391

-3,1

35-4

,057

-4,8

21-4

,952

-5,4

56-5

,672

-5,9

96-6

,150

-6,7

65-9

,178

-11,

969

-12,

627

-12,

896

1-FO

STER

17

-031

-214

23-0

0-1

57-1

,046

-1,6

63-2

,343

-2,6

63-3

,372

-4,1

29-4

,382

-4,6

52-4

,926

-5,1

43-5

,302

-5,7

69-7

,280

-9,0

87-1

0,15

7-1

0,48

41-

FULL

ER E

ST

17-0

61-2

0495

-00

-1,1

86-1

,794

-2,0

94-2

,582

-3,3

14-3

,519

-3,6

28-3

,847

-4,2

35-4

,502

-4,6

97-7

,305

-9,6

04-1

0,41

0-1

0,62

41-

GEO

RG

IA P

AC

IFIC

"W

"

17-0

67-2

1801

-00

-1,2

56-1

,879

-2,2

96-2

,467

-4,1

09-5

,441

-6,0

48-6

,190

1-G

ISH

, D.

17-0

17-2

2848

-00

135

-517

-1,1

42-1

,831

-2,5

59-3

,326

-3,5

78-4

,008

-4,0

81-4

,280

-4,4

28-4

,848

-7,0

06-8

,434

-9,1

20-9

,311

1-G

LOR

IA'S

RA

NC

H 1

6

17-0

17-3

4300

-00

-496

-1,2

81-1

,995

-2,7

35-2

,995

-3,6

95-4

,477

-4,7

30-4

,980

-5,2

62-5

,465

-5,6

19-6

,139

-7,4

36-9

,614

-10,

241

-10,

434

1-H

OD

GES

33

17

-119

-219

89-0

0-4

8-8

66-1

,718

-2,1

27-2

,698

-3,5

00-4

,149

-4,3

37-4

,464

-4,6

48-4

,960

-5,2

86-5

,521

-7,7

12-9

,330

-9,8

52-1

0,08

01-

KEN

DR

ICK

"A

"

17-0

27-2

1485

-00

-757

-1,5

04-2

,114

-2,3

63-2

,805

-3,4

52-4

,134

-4,3

56-4

,520

-4,8

42-5

,128

-5,3

58-5

,564

-7,8

55-9

,088

-9,7

37-9

,922

1-K

ENN

EBR

EW, M

AM

IE M

. 17

-027

-020

99-0

0-9

59-1

,705

-2,3

26-2

,571

-3,0

12-3

,654

-4,3

30-4

,553

-4,6

75-4

,883

-5,1

87-5

,395

-5,6

76-8

,010

-9,8

60-1

0,56

9-1

0,72

51-

LON

GW

OO

D

17-0

17-0

2848

-00

-165

-1,0

49-1

,658

-2,1

35-2

,663

-3,3

86-4

,134

-4,3

99-4

,578

-4,7

70-5

,084

-5,2

11-5

,522

-7,4

18-9

,288

-10,

181

-10,

420

1-M

C C

RA

RY

17

-119

-202

50-0

0-1

,044

-1,7

60-2

,409

-3,3

42-3

,426

-3,8

50-4

,637

-4,8

89-5

,215

-5,4

45-5

,704

-5,9

15-6

,195

-8,4

52-1

0,91

1-1

1,19

7-1

1,33

41-

MO

NC

LA 3

1

17-0

17-3

4486

-00

-473

-1,3

62-1

,978

-2,6

84-2

,986

-3,7

79-4

,488

-4,7

50-5

,038

-5,3

08-5

,514

-5,6

76-6

,069

-7,4

76-9

,225

-10,

045

-10,

296

1-M

OR

GA

N

17-0

81-2

0443

-00

-136

-1,0

13-1

,582

-2,1

80-2

,997

-4,0

68-4

,703

-4,9

31-5

,230

-5,5

30-5

,848

-6,0

25-6

,770

-8,7

68-1

1,51

1-1

2,23

4-1

2,47

61-

NA

BO

RS

10-1

2-12

H

17-0

31-2

4464

-00

-676

-1,3

01-1

,978

-2,6

72-3

,401

-4,1

71-4

,394

-4,7

97-5

,068

-5,2

30-5

,374

-5,9

77-8

,941

-10,

926

-11,

515

-11,

736

1-P

AR

DEE

17

-069

-200

82-0

0-9

91-1

,732

-2,4

08-2

,911

-3,9

20-4

,877

-5,7

16-5

,961

-6,4

12-6

,598

-6,9

80-7

,188

-7,9

14-1

0,97

7-1

4,09

5-1

5,43

4-1

5,67

41-

PR

ICE

17

-111

-255

93-0

0-1

,158

-1,7

79-2

,324

-2,8

29-3

,189

-3,7

38-6

,092

-7,2

02-7

,804

-8,0

381-

PR

IMO

S LB

R.(

EXX

ON

)

17-1

11-2

4454

-00

-846

-1,4

63-1

,984

-2,4

14-2

,866

-3,1

65-5

,001

-6,3

52-7

,063

-7,3

471-

RA

BB

17

-061

-201

85-0

0-1

,376

-2,0

73-2

,503

-2,8

42-3

,249

-3,7

13-4

,441

-4,6

66-4

,821

-5,1

38-5

,470

-5,7

00-6

,003

-8,4

77-1

2,11

7-1

2,82

4-1

3,00

91-

RO

YE

17-1

11-2

2863

-00

-1,3

87-1

,995

-2,2

96-2

,693

-2,7

38-3

,395

-3,6

17-3

,746

-4,0

83-4

,408

-4,6

51-4

,824

-7,8

37-1

0,27

8-1

1,32

9-1

1,61

31-

RU

SS R

EALI

TY

17-0

81-2

0267

-00

-648

-1,2

16-1

,809

-2,6

25-3

,703

-4,4

84-4

,703

-5,1

02-5

,316

-5,6

20-5

,761

-6,4

98-9

,138

-11,

511

-12,

218

-12,

494

1-SA

RTO

R

17-0

83-2

0440

-00

-1,0

63-1

,689

-2,2

37-2

,604

-3,1

97-3

,447

-3,7

01-3

,795

-4,1

91-4

,428

-5,0

85-8

,376

-10,

394

-10,

959

-11,

238

1-SE

C 1

3 U

NIT

17

-015

-015

25-0

0-2

5-5

37-1

,276

-1,9

36-2

,301

-2,8

38-3

,522

-3,7

42-3

,997

-4,2

37-4

,453

-4,6

18-5

,004

-7,3

36-9

,444

-9,9

50-1

0,25

41-

SIB

LEY

17-0

85-2

0576

-00

-504

-1,3

00-2

,183

-2,8

24-3

,639

-4,3

80-5

,121

-5,8

87-6

,150

-6,5

25-6

,708

-6,9

94-7

,261

-8,0

73-1

0,56

0-1

2,55

2-1

3,21

3-1

3,44

61-

WES

T 28

17

-119

-218

23-0

0-1

,368

-2,0

87-2

,511

-2,9

72-3

,484

-4,1

59-4

,945

-5,1

94-5

,525

-5,7

54-6

,009

-6,2

20-6

,541

-8,6

89-1

1,25

6-1

1,66

4-1

1,90

725

-BEN

TON

17-0

15-0

0708

-00

-164

-839

-1,6

16-1

,872

-2,5

97-3

,274

-3,9

94-4

,219

-4,3

51-4

,633

-4,9

10-5

,084

-5,3

55-7

,274

-9,9

17-1

0,23

2-1

0,46

22-

CU

MM

ING

S, T

. 17

-013

-001

83-0

0-1

,143

-1,8

40-2

,381

-2,9

50-3

,463

-4,2

59-5

,027

-5,2

77-5

,593

-5,7

41-6

,136

-6,3

33-6

,707

-9,0

14-1

1,30

3-1

2,43

7-1

2,66

12-

JOH

NSO

N D

DD

17

-085

-204

16-0

0-8

30-1

,652

-2,0

36-2

,640

-3,4

43-4

,302

-5,0

62-5

,290

-5,6

16-5

,931

-6,2

61-6

,392

-7,0

33-9

,441

-12,

364

-12,

994

-13,

259

2-W

OO

D 1

17

-013

-200

35-0

0-6

84-1

,559

-2,1

71-2

,748

-3,5

54-4

,651

-5,2

76-5

,486

-5,7

09-5

,818

-6,2

07-6

,398

-7,0

25-9

,099

-12,

087

-12,

945

-13,

185

3-D

AV

IS, N

. 17

-119

-015

30-0

0-7

41-1

,438

-2,0

78-2

,599

-3,1

15-3

,886

-4,6

60-4

,952

-5,2

39-5

,499

-5,8

28-6

,060

-6,5

21-8

,803

-11,

223

-12,

284

-12,

530

C1-

TREM

ON

T LB

R

17-0

49-0

0099

-00

-916

-2,0

59-2

,716

-3,0

99-4

,046

-4,5

10-5

,154

-5,9

85-6

,191

-6,4

95-6

,615

-6,8

44-7

,221

-7,7

07-1

1,39

4-1

2,94

4-1

3,84

6-1

4,06

0

76

Appendix B. Basin Modeling

Basin modeling software packages, such as PetroMod®, use deterministic

forward modeling to predict past and present basin processes using inferred starting

conditions (Peters et al., 2007). Forward modeling is a technique of determining what a

sensor would measure in a given formation and environment by applying a set of

theoretical equations (Schlumberger Oilfield Glossary). Basin processes that are

modeled include, but are not limited to deposition, pressure, heat flow, petroleum

generation, fluid analysis, and reservoir volumetrics (Hantschel and Kauerauf, 2009)

(Figure 45). This history of a basin is subdivided into a continuous sequence of

deposition, non-deposition, and erosional events of a specified age and duration (Peters et

al., 2007). Numerical values are required for all input parameters (Figure 46). Input data

include gridded surfaces of buried rock formations interpreted from well logs and/or

seismic, present and past formation thicknesses, porosity, and permeability. Boundary

conditions such as past and present basal heat flow, water depths, and sediment-water

interface temperatures are required. Geochemical data such as the type and amount of

organic matter in the source rocks and the kinetics for the conversion of kerogen into

hydrocarbons are required (Peters et al., 2007).

Pore pressure calculations are primarily a one-phase water flow problem driven

by changes in overburden stress due to sedimentation. Internal pressure increases due to

gas generation, cementation, clay dehydration, and mineral conversions may also be

taken into account (Hantschel and Kauerauf, 2009).

Figure B1. Major geological processes in basin modeling (Hantschel and Kauerauf, 2009).

77

. Major geological processes in basin modeling (Hantschel and Kauerauf,

. Major geological processes in basin modeling (Hantschel and Kauerauf,

Figure B2. Process workflow diagram for2007).

78

. Process workflow diagram for numerical basin modeling (Peters et al.,

numerical basin modeling (Peters et al.,

79

Temperature calculations are the main goal of heat flow analysis. Past and

present temperatures are necessary for the determination of geochemical reaction rates

such as the conversion of kerogen into petroleum. It is possible to use basin models to

predict vitrinite reflectance. Because vitrinite reflectance is temperature sensitive, it can

be compared to measured data so that uncertain thermal input data, such as paleo heat

flow can be calibrated (Hantschel and Kauerauf, 2009).

Petroleum generation modeling includes the conversion of hydrocarbons from

kerogen (primary cracking) and the secondary cracking of petroleum described with sets

of parallel reactions of decomposition kinetics. Adsorption models are used to describe

the release of hydrocarbons into pore space of the source rock (Hantschel and Kauerauf,

2009).

Darcy flow is used for fluid migration. Darcy flow describes multicomponent

three-phase flow on the basis of pressure gradient and relative permeability. Migration

velocities and accumulation saturations are calculated in one step. Special algorithms are

used to describe migration due to natural fracture propagation and migration across

faults. Diffusion effects may evaluate the transport of light hydrocarbons in the water

phase (Hantschel and Kauerauf, 2009).

Alternatively, migration and accumulation can be modeled using invasion

percolation assuming that on geologic timescales, hydrocarbons move instantaneously

through the basin driven by buoyancy and capillary pressure. Time control is neglected

and the petroleum volume is subdivided into very small amounts. This method is

convenient for one phase flow and in-fault flow (Hantschel and Kauerauf, 2009).

Heat flow, pore pressure,

processes and follow a similar scheme of deviation and formulation of the basic

equations. The difficulties in these calculations result from the interaction of two

quantities, the state and flow variable

the influence of the flow variable from any location acting on any neighboring location.

Energy and mass balance is used to formulate a boundary value and calculate the state

and flow variables through ge

the basin into cells (Hantschel and Kauerauf, 2009)

Table B1. Fundamental physical transport laws and variables Kauerauf, 2009).

80

Heat flow, pore pressure, Darcy flow migration, and diffusion are transport

processes and follow a similar scheme of deviation and formulation of the basic

equations. The difficulties in these calculations result from the interaction of two

state and flow variable (Table 3). The mathematical formulation relies on

the influence of the flow variable from any location acting on any neighboring location.

Energy and mass balance is used to formulate a boundary value and calculate the state

and flow variables through geologic time. These calculations require the discretization of

(Hantschel and Kauerauf, 2009).

. Fundamental physical transport laws and variables (Hantschel and

Darcy flow migration, and diffusion are transport

processes and follow a similar scheme of deviation and formulation of the basic

equations. The difficulties in these calculations result from the interaction of two

). The mathematical formulation relies on

the influence of the flow variable from any location acting on any neighboring location.

Energy and mass balance is used to formulate a boundary value and calculate the state

ologic time. These calculations require the discretization of

(Hantschel and

81

Appendix C. Thermal Maturity Well Name %Ro (PetroMod®) 1-Antium Trust 1.57 1-Beene 1.45 1-Blackmon 1.84 1-Bostwick Holt 1.65 1-Burton Carter 1.43 1-Fuller 1.65 1-Gloria's Ranch 16 1.52 1-Hodges 1.43 1-J Davis 1.55 1-Johnson Odd 2.21 1-Kendrick 1.38 1-Longwood 1.52 1-McCrary 1.71 1-Moncala 31 1.57 1-Morgan 2.26 1-Pardee 3.16 1-Price 0.92 1-Primos 1.04 1-Rabb 2.24 1-Roye 1.82 1-Russ Reality 2.15 1-Sartor 1.89 1-Sec 13 1.49 1-West 28 1.83 1-Foster 1.56 1-Andrews B 1.86 1-Baker 1.62 1-Cates 2.16 1-Crown Zellerbach A 2.34 1-Gish D 1.61 1-Nabors 10 2.03 1-Sibley 2.21 2-Cummings 2.17 25-Benton 1.11 2-Wood 1 2.35 3-Davis 2.18 C1-Tremont Lbr 2.75 Georgia Pacific W 0.91 1-Kennebrew 1.56

82

Vita

Will Torsch was born in Louisville, Kentucky in 1987. He and his family settled

in Birmingham, Alabama, where he grew up. Will earned a Bachelor of Science degree in

geology from Baylor University in May of 2010. He then went on to pursue a Master of

Science degree in the Department of Geology and Geophysics from Louisiana State

University under the advisement of Dr. Jeffrey Nunn. After completing his degree Will

will work full-time as a geophysicist for Newfield Exploration in Houston, Texas.