１　全原著論文[1969-1974] 1 Steric Course in Oxidative Ring Opening of Aziridine-1-carboxylates with Dimethyl Sulphoxide S. Fujita, T. Hiyama, H. Nozaki, Tetrahedron Lett., (21), 1677-1678 (1969). 2 The Acid-Catalyzed Ring-Opening of Cyclooctenimine Derivatives S. Fujita, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 43 (10), 3239-3241 (1970). 3 Oxidative Ring-Opening of Aziridine-1-carboxylates with Sulphoxides S. Fujita, T. Hiyama, H. Nozaki, Tetrahedron, 26, 4347-52 (1970). 4 Photoinduced Transannular Reaction of 4,5-Octamethylene-1,3-dioxolen-2-one T. Hiyama, S. Fujita, H. Nozaki, Bull. Chem. Soc. Jpn., 44 (11), 3222 (1971). 5 The Photolysis and Thermolysis of Ethyl Azidoformate in the Presence of Ketones T. Hiyama, H. Taguchi, S. Fujita, H. Nozaki, Bull. Chem. Soc. Jpn., 45 (6), 1863-1866 (1972). 6 The Photochemistry of 4,5-Disubstituted 1,3-Dioxolen-2-ones. T. Hiyama, S. Fujita, H. Nozaki, Bull. Chem. Soc. Jpn., 45 (9), 2797-2801 (1972). 7 The Photochemical and Thermal Reaction of Ethyl Azidoformate with Cyclohexanone Ethylene Acetal T. Hiyama, S. Fujita, H. Nozaki, Bull. Chem. Soc. Jpn., 45 (11), 3500-3501 (1972). 8 [6]Metacyclophane and Related Compounds S. Hirano, T. Hiyama, S. Fujita, H. Nozaki, Chem. Lett., 707-708 (1972). 9 Metabridged Tropone and Phenols T. Hiyama, Y. Ozaki, H. Nozaki, Chem. Lett., 963-964 (1972). 10 A Facile, Stereospecific Preparation of Olefins from Pinacols T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 46 (7), 2248-2249 (1973). 11 Reaction of N-Alkoxycarbonylaziridines with Nitriles T. Hiyama, H. Koide, S. Fujita, H. Nozaki, Tetrahedron, 29, 3137-3139 (1973). 12 Hexamethylene Bridged Cycloheptatrienes. Synthesis and Structure S. Hirano, T. Hiyama, H. Nozaki, Tetrahedron Lett., (16), 1331-1332 (1973). 13 Oxidation of Cyclopropylamines and 2-Phenylaziridine with Lead Tetraacetate T. Hiyama, H. Koide, H. Nozaki, Tetrahedron Lett., (24), 2143-2144(1973). 14 Acid-Catalyzed Cyclization of Cross-Conjugated Dienone Moiety to Cyclopentenones S. Hirano, T. Hiyama, H. Nozaki, Tetrahedron Lett., (15), 1429-1430 (1974). 15 The Syntheses and Conformational Studies of [n](2,4)Heterophanes and [7](3,5)Pyrazolophane S. Hirano, T. Hiyama, S. Fujita, T. Kawaguti, Y. Hayashi, H. Nozaki, Tetrahedron, 30, 2633-2640 (1974). 16 A Novel Oxazole Synthesis Utilizing Tungsten(VI) Catalyzed Decomposition of α-Diazo Carbonyl

Compounds in Nitriles K. Kitatani, T. Hiyama, H. Nozaki, Tetrahedron Lett., (16), 1531-1532 (1974). 17 Preparation of β-Methylated α,β-Unsaturated Ketones via Dichlorocarbene Adducts of Enol Ethers.

Synthesis of dl-Muscone from Cyclotetradecanone T. Hiyama, T. Mishima, K. Kitatani, H. Nozaki, Tetrahedron Lett., (37), 3297-3300 (1974). 18 1-Bromocyclopropyllithium Derivatives. Carbenoid Intermediates for the Preparation of Cyclobutanones,

Cyclopropyl Ketones, and 1,1-Cyclopropanedicarboxylates T. Hiyama, S. Takehara, K. Kitatani, H. Nozaki, Tetrahedron Lett., (37), 3295-3296 (1974). 19 Nonamethylene-Bridged Phenols and Tropones T. Hiyama, Y. Ozaki, H. Nozaki, Tetrahedron, 30, 2661-2668 (1974). 20 The Reaction of Ethyl Azidoformate with Electron Deficient Olefins and the Thermal Ring Opening of

the Resulting Aziridines T. Hiyama, H. Taguchi, H. Nozaki, Bull. Chem. Soc. Jpn., 47 (11), 2909-2910 (1974). 21 Acid-Catalyzed Reaction of Dichlorocyclopropylcarbinols. Preparation of 2-Cyclopentenones T. Hiyama, M. Tsukanaka, H. Nozaki, J. Am. Chem. Soc., 96, 3713-3714 (1974). 22 [8](3,6)Pyridazinophane. Synthetic and Structural Studies T. Hiyama, S. Hirano, H. Nozaki, J. Am. Chem. Soc., 96, 5287-5289 (1974).

[1975-1980] 23 Stereoselective Alkylation of 1-Lithiocyclopropyl Bromides K. Kitatani, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 97, 949-950 (1975). 24 Oxidation of Cyclopropylamines and Aziridines with Lead Tetraacetate T. Hiyama, H. Koide, H. Nozaki, Bull. Chem. Soc. Jpn., 48 (10), 2918-2921 (1975).

5 25 Synthetic and Structural Studies of [6]-, [7]- and [10]Metacyclophanes S. Hirano, H. Hara, T. Hiyama, S. Fujita, H. Nozaki, Tetrahedron, 31, 2219-2227 (1975). 26 β-Hydroxyethyltrialkylammonium Ion as a Selective Phase-Transfer Catalyst for Dihalocyclopropanation T. Hiyama, H. Sawada, M. Tsukanaka, H. Nozaki, Tetrahedron Lett., (34), 3013-3016 (1975). 27 Stereoselective One-Pot Dialkylation of gem-Dihalocyclopropanes. A Simple Route to dl-Sesquicarene

and dl-Sirenin K. Kitatani, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 98, 2362-2364 (1976). 28 Hexamethylene Bridged Cycloheptatrienes S. Hirano, T. Hiyama, H. Nozaki, Tetrahedron, 32, 2381-2383 (1976). 29 Stereoselective One-pot Dialkylation of gem-Dihalocyclopropanes by Means of Dialkylcopperlithiums K. Kitatani, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 50 (6), 1600-1607 (1977). 30 Tungsten Hexachloride-catalyzed Decomposition of Diazo Compounds. A Novel Oxazole Synthesis K. Kitatani, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 50 (6), 1647-1648 (1977). 31 Substitution on Carbenoid Carbon of α-Halocyclopropyllithium. A Novel Stereoselective Synthesis of

Geminally Substituted Cyclopropanes K. Kitatani, H. Yamamoto, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 50 (8), 2158-2160 (1977). 32 Stereoselective Monoalkylation of α-Halocyclopropyllithiums. A Versatile Method for the Synthesis of

α-Alkylcyclopropyl Acetates and Alkylidenecyclopropanes K. Kitatani, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 50 (12), 3288-3294 (1977). 33 Grignard-Type Carbonyl Addition of Allyl Halides by Means of Chromous Salt. A Chemospecific

Synthesis of Homoallyl Alcohols Y. Okude, S. Hirano, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 99, 3179-3181 (1977). 34 Stereospecific Alkylation of Cyclopropyl Bromides by Means of Dibutylcopperlithium and Alkyl Halides H. Yamamoto, K. Kitatani, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 99, 5816-5817 (1977). 35 Reduction of Organic Haldies by Means of CrCl3-LiAlH4 Reagent in Anhydrous Media Y. Okude, T. Hiyama, H. Nozaki, Tetrahedron Lett., (43), 3829-3830 (1977). 36 Cyclopentenone Synthesis from Ketones and 1,1-Dichloroallyllithium T. Hiyama, M. Shinoda, H. Nozaki, Tetrahedron Lett., (8), 771-774 (1978). 37 1-Bromo-2-ethoxycyclopropyllithium as a Synthetic Equivalent of 2-Lithiopropenal Moiety T. Hiyama, A. Kanakura, H. Yamamoto, H. Nozaki, Tetrahedron Lett., (33), 3047-3050 (1978). 38 General Route to α,β-Unsaturated Aldehydes of Homoterpenoid and Terpenoid Structure. Synthesis of

JH-II and β-Sinensal T. Hiyama, A. Kanakura, H. Yamamoto, H. Nozaki, Tetrahedron Lett., (33), 3051-3054 (1978). 39 Regio- and Stereoselective Cyclopentenone Annulation by Means of Ketone-Propargyl Alcohol Adducts T. Hiyama, M. Shinoda, H. Nozaki, J. Am. Chem. Soc., 101, 1599-1600 (1979). 40 A Novel Synthesis of α-Methylene-γ-butyrolactones from 1-(N,N-Dimethylaminomethyl)cyclopropane-

carboxylate Esters T. Hiyama, H. Saimoto, K. Nishio, M. Shinoda, H. Yamamoto, H. Nozaki, Tetrahedron Lett., (22),

2043-2046 (1979). 41 A New Stereoselective Synthesis of (±)-Nootkatone by Means of Cyclopentenone Annulation T. Hiyama, M. Shinoda, H. Nozaki, Tetrahedron Lett., (37), 3529-3532 (1979). 42 Alkylation of Benzyl, Cyclopropylmethyl and Allyl Acetates with Trialkyl-aluminum. A Stereochemical

Study A. Itoh, K. Oshima, S. Sasaki, H. Yamamoto, T. Hiyama, H. Nozaki, Tetrahedron Lett., (49), 4751-4754

(1979). 43 Alkylation of Bromocyclopropanes and Bromoarenes by Means of Dibutylcopperlithium and Alkyl

Haldies T. Hiyama, H. Yamamoto, K. Nishio, K. Kitatani, H. Nozaki, Bull. Chem. Soc. Jpn., 52 (12), 3632-3636

(1979). 44 Abnormal Nazarov Reaction. A New Synthetic Approach to 2,3-Disubstituted 2-Cyclopentenones S. Hirano, S. Takagi, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 53 (1), 169-173 (1980). 45 Cyclopentenone Synthesis from 1,1-Dichloroallyllithium-Ketone Adducts as Well as from

Dichlorocarbene-Allyl Alcohol Adducts T. Hiyama, M. Shinoda, M. Tsukanaka, H. Nozaki, Bull. Chem. Soc. Jpn., 53 (4), 1010-1014 (1980). 46 Stereochemical Studies on the Nucleophilic Substitution in the Reaction of Allylic Phosphates with

Organoaluminum Reagents A. Itoh, S. Ozawa, K. Oshima, S. Sasaki, H. Yamamoto, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 53

(8), 2357-2362 (1980).

6 47 A New Synthesis of dl-Muscopyridine Based on the Regioselective Cyclopentenone Annulation H. Saimoto, T. Hiyama, H. Nozaki, Tetrahedron Lett., 21, 3897-3898 (1980).

[1981-1983] 48 A New Synthesis of 3(2H)-Furanones from Ketones T. Hiyama, M. Shinoda, H. Saimoto, H. Nozaki, Heterocycles, 15 (1), 263-264 (1981). 49 Chromium(II) Mediated Threo Selective Synthesis of Homoallyl Alcohols T. Hiyama, K. Kimura, H. Nozaki, Tetrahedron Lett., 22, 1037-1040 (1981). 50 Bis(trimethylsilyl) Sulphate Catalyzed γ-Lactonization of Cyclopropanecarboxylates Having a Carbonyl

Substituent at Cyclopropane α-Carbon Y. Morizawa, T. Hiyama, H. Nozaki, Tetrahedron Lett., 22 (24), 2297-2300 (1981). 51 Reaction of Organoaluminium Reagents with Cyclopropylmethyl Acetates and 2-Vinylcyclopropane-1,1-

dicarboxylate Esters T. Hiyama, Y. Morizawa, H. Yamamoto, H. Nozaki, Bull. Chem. Soc. Jpn., 54 (7), 2151-2160 (1981). 52 Regio- and Stereoselective Cyclopentannulation with Ketones and Propargyl Alcohol Derivatives

Synthesis of dl-Nootkatone and dl-Muscopyridine T. Hiyama, M. Shinoda, H. Saimoto, H. Nozaki, Bull. Chem. Soc. Jpn., 54 (9), 2747-2758 (1981). 53 Regiocontrolled Hydration of 2-Butyne-1,4-diol Derivatives to Give 4,5-Dihydro-3(2H)-furanones.

Practical Synthesis of Bullatenone and Geiparvarin H. Saimoto, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 103, 4975-4977 (1981). 54 Bis(trimethylsilyl) Sulfate-Catalyzed Alcohol Protection with Dihydropyran, Deprotection, and

Transesterification Y. Morizawa, I. Mori, T. Hiyama, H. Nozaki, Synthesis, (11), 899-900 (1981).

[1982] 55 Highly Selective Carbon-Carbon Bond Forming Reactions Mediated by Chromium(II) Reagents T. Hiyama, Y. Okude, K. Kimura, H. Nozaki, Bull. Chem. Soc. Jpn., 55 (2), 561-568 (1982). 56 Synthesis and Reactions of 1-Bromocyclopropyltrimethylsilane Derivatives T. Hiyama, A. Kanakura, Y. Morizawa, H. Nozaki, Tetrahedron Lett., 23 (12), 1279-1280 (1982). 57 Reaction of Ethyl 2-Azidopropenoate with Nucleophiles M. Kakimoto, M. Kai, K. Kondo, T. Hiyama, Chem. Lett., 527-528(1982). 58 A New Synthesis of 3-Amino-2-alkenoates T. Hiyama, K. Kobayashi, Tetrahedron Lett., 23 (15), 1597-1600 (1982). 59 Synthesis of 1-Azidocyclopropanecarboxylates from 2-Azido-2-alkenoates T. Hiyama, M. Kai, Tetrahedron Lett., 23 (20), 2103-2104 (1982). 60 Grignard-Type Carbonyl Addition of Allyl Unit with MnCl2-LiAlH4 Reagent T. Hiyama, M. Obayashi, A. Nakamura, Organometallics, 1, 1249-1250 (1982).

[1983] 61 Epoxidation of Allyl and Homoallyl Trimethylsilyl Ethers with t-Butyldioxytrimethylsilane and Silicon

Lewis Acid/Vanadium Catalyst T. Hiyama, M. Obayashi, Tetrahedron Lett., 24 (4), 395-398 (1983). 62 Generation of Metal-Free Silyl Anions from Disilanes and Fluoride Catalyst. Synthetic Reactions with

Aldehydes and 1,3-Dienes T. Hiyama, M. Obayashi, I. Mori, H. Nozaki, J. Org. Chem., 48, 912-914 (1983). 63 Carbon-Carbon Bond Formation with Metallic Manganese T. Hiyama, M. Sawahata, M. Obayashi, Chem. Lett., 1237-1238 (1983). 64 A General Synthesis of 3-Amino-2-Alkenenitriles by the Cross-Thorpe Reaction K. Kobayashi, T. Hiyama, Tetrahedron Lett., 24 (33), 3509-3512 (1983). 65 Insertion of Alkanal Carbonyl and 1,3-Diene Units Between Si-Si Bonds of Trisilanes. Synthesis of

Novel Silicon-Containing Materials T. Hiyama, M. Obayashi, Tetrahedron Lett., 24 (38), 4109-4112 (1983). 66 Preparation and Carbonyl Addition of γ,γ-Difluoroallylsilanes T. Hiyama, M. Obayashi, M. Sawahata, Tetrahedron Lett., 24 (38), 4113-4116 (1983). 67 Regiocontrolled Formation of 4,5-Dihydro-3(2H)-furanones from 2-Butyne-1,4-diol Derivatives.

Synthesis of Bullatenone and Geiparvarin H. Saimoto, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 56 (10), 3078-3087 (1983). 68 New Methods for the Synthesis of 3(2H)-Furanones and 2(5H)-Furanones

7 H. Saimoto, M. Shinoda, S. Matsubara, K. Oshima, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 56 (10),

3088-3092 (1983). 69 A Novel Synthesis of α-Methylene-γ-butyrolactones H. Saimoto, K. Nishio, H. Yamamoto, M. Shinoda, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 56 (10),

3093-3098 (1983). 70 Selective Grignard-Type Addition of Alkenyl Halides Mediated by Chromium(II) Chloride K. Takai, K. Kimura, T. Kuroda, T. Hiyama, H. Nozaki, Tetrahedron Lett., 24 (47), 5281-5284 (1983).

[1984] 71 A New Synthesis of N-Benzoyl L-Acosamine T. Hiyama, K. Nishide, K. Kobayashi, Tetrahedron Lett., 25 (5), 569-572 (1984). 72 A Stereoselective Synthesis of N-Benzoyl L-Daunosamine T. Hiyama, K. Nishide, K. Kobayashi, Chem. Lett., 361-362 (1984). 73 Bis(trimethylsilyl) Sulfate Catalysis in γ-Lactonization of Cyclopropanecarboxylates Activated by

Carbonyl Substituents on α-Carbon Y. Morizawa, T. Hiyama, K. Oshima, H. Nozaki, Bull. Chem. Soc. Jpn., 57 (4), 1123-1127 (1984). 74 Carbon-Carbon Bond Formation by the Use of Manganese Metal Fine Particles T. Hiyama, M. Sawahata, M. Obayashi, 日化誌,, (6), 1022-1026(1984). 75 1-Bromo-2-ethoxycyclopropyllithium: A Synthetic Equivalent of 2-Lithio- or 3-Lithiopropenal.

Application to the Synthesis of Juvenile Hormone (JH-II), β-Sinensal, and Jasmonoids Y. Morizawa, A. Kanakura, H. Yamamoto, T. Hiyama, H. Nozaki, Bull. Chem. Soc. Jpn., 57 (7),

1935-1942 (1984). 76 Practical Synthesis and Polymerization of Trifluorovinylsilanes. A Possible Precursor of Poly(difluoro-

acetylene) T. Hiyama, K. Nishide, M. Obayashi, Chem. Lett., 1765-1768 (1984). 77 Highly Diastereocontrolled Reduction of Ketones by Means of Hydrosilanes. Practical Synthesis of

Optically Active 1,2-Diols and 2-Amino Alcohols of Threo or Erythro Configuration M. Fujita, T. Hiyama, J. Am. Chem. Soc., 106, 4629-4630 (1984). 78 Synthesis of 1-Substituted (S)-4-Acetoxy-1-penten-3-ones Using (S)-Lactic Acid as a Chiral Source and

Their Synthetic Reactions T. Hiyama, K. Kobayashi, M. Fujita, Tetrahedron Lett., 25 (43), 4959-62 (1984).

[1985] 79 Manganese-Mediated Allyl Addition to Enolizable Aldehyde and Ketones. An Approach for Introduction

of Acetonyl Side Chain at C(9) or Anthracycline Antibiotics T. Hiyama, M. Sawahata, Y. Kusano, Chem. Lett., 611-612 (1985). 80 New Synthetic Methods for 4-Amino-2(5H)-furanones T. Hiyama, H. Oishi, H. Saimoto, Tetrahedron Lett., 26 (20), 2459-2462 (1985). 81 Asymmetric Coupling of Arylmagnesium Bromides with Allylic Esters T. Hiyama, N. Wakasa, Tetrahedron Lett., 26 (27), 3259-3262 (1985). 82 Fluoride Ion Catalyzed Aldehyde Addition of Labile α− or β-Halocarbanion Species Generated from the

Corresponding α- or β-Halo Organosilanes M. Fujita, T. Hiyama, J. Am. Chem. Soc., 107, 4085-4087 (1985). 83 Carbometallation of 1,4-Bis(trimethylsilyl)-1,3-butadiyne with Trimethylaluminium T. Kusumoto, K. Nishide, T. Hiyama, Chem. Lett., 1409-1410 (1985). 84 Hydrosilylation of 1,4-Bis(trimethylsilyl)-1,3-butadiyne T. Kusumoto, T. Hiyama, Chem. Lett., 1405-1408 (1985). 85 Highly Stereoselective Reduction of α-Substituted β-Keto Amides by Means of Hydrosilane/F– and

Hydrosilane/H+ Reagent. A Practical Approach to Aldols of Both Threo and Erythro Configurations M. Fujita, T. Hiyama, J. Am. Chem. Soc., 107, 8294-8296 (1985).

[1986] 86 A General Highly Efficient Access to Prenylated Phenolic Natural Products. Synthesis of Colletochlorins H. Saimoto, T. Hiyama, Tetrahedron Lett., 27 (5), 597-600 (1986). 87 A Mild Procedure for Hydrolysis of Alkoxymethyl Aryl Ethers to Give Hydroxyarenes. A Rational

Synthesis of Ascofuranone H. Saimoto, Y. Kusano, T. Hiyama, Tetrahedron Lett., 27 (14), 1607-1610 (1986). 88 Reduction of Oximes with Hydrosilane/H+ Reagent

8 M. Fujita, H. Oishi, T. Hiyama, Chem. Lett., 837-838 (1986). 89 Efficient Carbon-Carbon Bond Formation with Thermally Stable 1,1-Dihalo-2,2,2-trifluoroethylzinc

Reagent M. Fujita, T. Morita, T. Hiyama, Tetrahedron Lett., 27 (19), 2135-2138 (1986). 90 Practical and Stereocontrolled Syntheses of Both (1R*,3S*)- and (1R*,3R*)-3-(2-Chloro-3,3,3-trifluoro-1-

propenyl)-2,2-dimethyl-cyclopropanecarboxylates M. Fujita, T. Hiyama, K. Kondo, Tetrahedron Lett., 27 (19), 2139-2142 (1986). 91 Practical Ways from Aldehydes to 2-Chloro-1,1,1-trifluoro-2-alkenes and 2-Chloro-1,1-difluoro-1-

alken-3-ols M. Fujita, T. Hiyama, Tetrahedron Lett., 27 (31), 3655-8 (1986). 92 Highly Regio- and Stereocontrolled Halogenation of 1,1-Difluoro-2-halo-1-alken-3-ols as Applied to

Poly-fluorinated Pyrethroid Synthesis M. Fujita, T. Hiyama, Tetrahedron Lett., 27 (31), 3659-60 (1986). 93 Asymmetric Synthesis of (S)-2-(6-Methoxy-2-naphthyl)propanoic Acid T. Hiyama, K. Saito, K. Sato, N. Wakasa, M. Inoue, Chem. Lett., 1471-1472 (1986). 94 Synthesis of 5-Amino-2-cyano-4-silylpyrroles from Silylacetylenes and Trimethylsilyl Cyanide T. Kusumoto, T. Hiyama, K. Ogata, Tetrahedron Lett., 27 (35), 4197-4200 (1986). 95 Substitution at Secondary Benzylic Carbon with Aluminum Reagents: A Facile Synthesis of (±)-

Naproxen T. Hiyama, M. Inoue, Synthesis, (8), 689-690 (1986). 96 A Facile Route to (±)-2-Arylpropanoic Acids T. Hiyama, M. Inoue, K. Saito, Synthesis, (8), 645-647 (1986).

[1987] 97 Palladium Catalyzed Double Silylation of Bis(trimethylsilyl)butadiyne by Means of Disilanes T. Kusumoto, T. Hiyama, Tetrahedron Lett., 28 (16), 1807-1810 (1987). 98 Reduction and Oxidation of Carbon-Carbon Double Bonds of 1,1,4,4-Tetrakis(trimethylsilyl)butatriene T. Kusumoto, T. Hiyama, Tetrahedron Lett., 28 (16), 1811-1812 ((1987). 99 Mechanistic Aspects of Fluoride Ion-Catalyzed Reduction of Carbonyl Compounds with Hydrosilanes M. Fujita, T. Hiyama, Tetrahedron Lett., 28 (20), 2263-2264 (1987). 100 A New Synthesis of 3-Amino-2-alkenoates. Novel Synthetic Route to Amino Sugars N-Benzoyl-L-

daunosamine and -L-acosamine T. Hiyama, K. Kobayashi, K. Nishide, Bull. Chem. Soc. Jpn., 60 (6), 2127-37 (1987). 101 Synthesis of 4-Amino-2(5H)-furanones through Intra- and Intermolecular Nitrile Addition of Ester

Enolates. Construction of Carbon Framework of an Antitumor Antibiotic Basidalin T. Hiyama, H. Oishi, Y. Suetsugu, K. Nishide, H. Saimoto, Bull. Chem. Soc. Jpn., 60 (6), 2139-50 (1987). 102 Palladium-Mediated Silylation of Organic Halides with Disilane/F- Reagent Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 28 (40), 4715-4718 (1987). 103 Efficient Carbonyl Addition of Polyfluorochloroethyl, -ethylidene and -ethenyl Units by Means of 1,1,1-

Trichloro-2,2,2-trifluoroethane and Zinc M. Fujita, T. Hiyama, Bull. Chem. Soc. Jpn., 60 (12), 4377-4384 (1987). 104 Practical, Stereocontrolled Synthesis of Polyfluorinated Artificial Pyrethroids M. Fujita, K. Kondo, T. Hiyama, Bull. Chem. Soc. Jpn., 60 (12), 4385-4394 (1987).

[1988] 105 Cross-coupling of Organosilanes with Organic Halides Mediated by Palladium Catalyst and Tris

(diethylamino)sulfonium Difluorotrimethylsilicate Y. Hatanaka, T. Hiyama, J. Org. Chem., 53, 918-920 (1988). 106 Fluoride Ion-Catalyzed Generation and Carbonyl Addition of α-Halo Carbanions Derived fromα-Halo

Organosilicon Compounds M. Fujita, M. Obayashi, T. Hiyama, Tetrahedron, 44, 4135-4145 (1988). 107 Pentacoordinate Organosilicate as an Alkylating Reagent: Palladium Catalyzed Methylation of Aryl

Halides Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 29 (1), 97-98 (1988). 108 Differentiation Induction of Human Promyelocytic Leukemia Cells by Colletochlorin B and Its Analogues N. Takahashi, H. Osada, N. Numao, H. Saimoto, T. Kawabata, T. Hiyama, Chem. Pharm. Bull., 36 (1)

452-455 (1988). 109 Polymerization of Monomers Containing Two Ethynyldimethylsilyl Groups

9 T. Kusumoto, T. Hiyama, Chem. Lett.,1149-1152 (1988). 110 Facile Conversion of Aldehydes into 1-Substituted 2-Chloro-3,3-difluoro-2-propen-1-ols with 1,1-

Dibromo-1-chloro-2,2,2-trifluoroethane/Magnesium Reagent M. Fujita, T. Hiyama, Bull. Chem. Soc. Jpn., 61, 3321-3322 (1988). 111 Fluoride Ion Catalyzed Reduction of Aldehydes and Ketones with Hydrosilanes. Synthetic and

Mechanistic Aspects and an Application to the Threo-Directed Reduction of α-Substituted Alkanones M. Fujita, T. Hiyama, J. Org. Chem., 53, 5405-5415 (1988). 112 Erythro-Directive Reduction of α-Substituted Alkanones by Means of Hydrosilanes in Acidic Media M. Fujita, T. Hiyama, J. Org. Chem., 53, 5415-5421 (1988). 113 A Facile Entry to β,δ-Diketo and syn-β,δ-Dihydroxy Esters T. Hanamoto, T. Hiyama, Tetrahedron Lett., 29, 6467-6470 (1988).

[1989] 114 Alkenylfluorosilanes as Widely Applicable Substrates for the Palladium-Catalyzed Coupling of

Alkenylsilane/F- Reagents with Alkenyl Iodides Y. Hatanaka, T. Hiyama, J. Org. Chem., 54, 268-270 (1989). 115 A Facile and Practical Synthesis of 1-Aryl-3,3,3-trifluoropropynes T. Hiyama, K. Sato, M. Fujita, Bull. Chem. Soc. Jpn., 62, 1352-1354 (1989). 116 A One-pot Synthesis of Conjugated Dienynes by Palladium-Mediated Three Component Cross-Coupling

Reaction Y. Hatanaka, K. Matsui, T. Hiyama, Tetrahedron Lett., 30, 2403-2406 (1989) 117 A New Synthesis of β-Lactams through Stereoselective Oxidative Coupling of the Dianions of Acyclic

Amides T. Kawabata, K. Sumi, T. Hiyama, J. Am. Chem. Soc., 111, 6843-6845 (1989). 118 Selective Synthesis of Unsymmetrical Biaryls via Palladium-Catalyzed Cross-Coupling of

Arylfluorosilanes with Aryl Iodides Y. Hatanaka, S. Fukushima, T. Hiyama, Chem. Lett., 1711-1714 (1989). 119 Regio- and Chemoselective Epimerization of cis-3-Amino-β-lactams to the trans-Isomers: A New

Synthesis of Aztreonam T. Kawabata, K. Itoh, T. Hiyama, Tetrahedron Lett., 30, 4837-48740 (1989). 120 Palladium-Catalyzed Carbonylative Coupling of Arylfluorosilanes with Aryl Iodides. A Convenient

Synthesis of Diaryl Ketones Y. Hatanaka, T. Hiyama, Chem. Lett., 2049-2052 (1989).

[1990] 121 A Convenient Synthesis of Substituted Heteroaromatic Compounds via the Palladium-Catalyzed Cross-

Coupling Reaction of Organosilicon Compounds Y. Hatanaka, S. Fukushima, T. Hiyama, Heterocycles, 30, 303-306 (1990). 122 A Facile Synthesis of 2-Trifluoromethylbiphenyls and -terphenyls via the Diels-Alder Reaction of 1-

Aryl-3,3,3-trifluoropropynes T. Hiyama, K. Sato, Synlett, 53-54 (1990). 123 A Facile, Practical Synthesis of 2-(6-Methoxy-2-naphthyl)propenoic Acid T. Hiyama, N. Wakasa, T. Ueda, T. Kusumoto, Bull. Chem. Soc. Jpn., 63, 640-642 (1990). 124 Ferroelectric Lquid Crystalline Compounds Having a Chiral Center Directly Connected to the Core

Aromatic Ring. Synthesis of Chiral 4-(1-Propoxyethyl)benzenol and -benzoic Acid, 4-(1-Carboxyethyl)benenol and the Esters Derived Therefrom

T. Kusumoto, T. Ueda, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T. Kuriyama, K. Nakamura, T. Fujisawa, Chem. Lett., 523-526 (1990).

125 Optically Active Sulfoxides as Ferroelectric Liquid Crystals and Chiral Dopants for Them K. Nishide, A. Nakayama, T. Kusumoto, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T. Kuriyama, K.

Nakamura, T. Fujisawa, Chem. Lett., 623-626 (1990). 126 A Wide Range of Organosilicon Compounds Couples with Enol and Aryl Triflates in the Presence of Pd

Catalyst and Fluoride Ion Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 31, 2719-2722 (1990). 127 Carbometallation of 1,4-Bis(trimethylsilyl)butadiyne with Trimethylaluminium Using a Bis

(cyclopentadienyl)metal Dichloride Catalyst T. Kusumoto, K. Nishide, and T. Hiyama, Bull. Chem. Soc. Jpn., 63, 1947-1950 (1990). 128 Synthesis of Optically Active α-Cyanobenzyl Alkyl Ethers

10 T. Kusumoto, T. Hanamoto, K. Sato, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T. Kuriyama, K.

Nakamura, T. Fujisawa, Tetrahedron Lett., 31, 5343-5344 (1990). 129 A Facile Stereoselective Synthesis of (E)-1-Aryl-1,2,3,3,3-pentafluoropropenes and (E)-1-Aryl-2-

chloro-1,3,3,3-tetrafluoropropenes M. Kuroboshi, T. Hiyama, Chem. Lett., 1607-1610 (1990). 130 Optically Active O-Acyl Cyanohydrins as Chiral Dopants for Ferroelectric Liquid Crystals T. Kusumoto, T. Hanamoto, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T. Kuriyama, K. Nakamura, T.

Fujisawa, Chem. Lett., 1615-1618 (1990). 131 Stereochemistry of the Cross-Coupling Reaction of Chiral Alkylsilanes with Aryl Triflates: A Novel

Approach to Optically Active Compounds Y. Hatanaka, T. Hiyama, J. Am. Chem. Soc., 112, 7793-7794 (1990). 132 Double Silylation of 1,4-Bis(trimethylsilyl)butadiyne with Disilanes Using a Palladium Catalyst T. Kusumoto, T. Hiyama, Bull. Chem. Soc. Jpn., 63, 3103-3110 (1990). 133 Erythro-Directed Reduction of α,β-Keto Amide: erythro-1-(3-hydroxy-2-methyl-3-phenylpropanoyl)

piperidine [piperidine, 1-(3-hydroxy-2-methyl-1-oxo-3-phenylpropyl)-, (R*,R*)-] M. Fujita, T. Hiyama, Organic Syntheses, 69, 44-54 (1990).

[1991] 134 Aluminium-Mediated [4 + 1] Cyclization Reaction: Novel Synthesis of 2,2,5,5-Tetramethylcyclopentane-

carboxylic Acid G. Bhaskar Reddy, T. Hanamoto, T. Hiyama, Tetrahedron Lett., 32, 521-524 (1991). 135 Synthesis of New Optically Active Cyanocyclopropanes as Chiral Dopants for Ferroelectric Liquid

Crystals T. Kusumoto, A. Nakayama, K. Sato, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T. Kuriyama, K.

Nakamura, T. Fujisawa, Tetrahedron Lett., 32, 939-942 (1991). 136 Dilute Hydrofluoric Acid as a Fluorinating Agent: Iodofluorination of Olefins with Dilute Hydrofuoric

Acid, N-Iodosuccinimide, and a Phase Transfer Catalyst M. Kuroboshi, T. Hiyama, Synlett, 185-186 (1991). 137 Halofluorination of Alkenes Using Tetrabutylammonium Dihydrogentrifluoride M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 32, 1215-1218 (1991). 138 Synthesis and Properties of New Optically Active γ-Lactones as Chiral Dopants for Ferroelectric Liquid

Crystals T. Kusumoto, A. Nakayama, K. Sato, K. Nishide, T. Hiyama, S. Takehara, T. Shoji, M. Osawa, T.

Kuriyama, K. Nakamura, T. Fujisawa, J. Chem. Soc. Chem. Commun., 311-312 (1991). 139 Hydroesterification of 6-Methoxy-2-naphthylethene T. Hiyama, N. Wakasa, T. Kusumoto, Synlett, 569-760 (1991). 140 Correlation between Absolute Configuration of Benzylic Chiral Centre and Sign of Spontaneous

Polarization of Chiral Dopants for Ferroelectric Liquid Crystals T. Kusumoto, A. Nakayama, K. Sato, T. Hiyama,S. Takehara, M. Osawa, K. Nakamura, J. Mater. Chem.,

707-708 (1991). 141 Synthesis and Properties of Optically Active 3-Aryl-5-alkyloxazolidin-2-ones. New Chiral Dopants for

Ferroelectric Liquid Crystals T. Kusumoto, K. Sato, T. Hiyama, S. Takehara, M. Osawa, K. Nakamura, T. Fujisawa, Chem. Lett.,

1623-1624 (1991). 142 γ-Selective Cross-Coupling Reaction of Allyltrifluorosilanes: A New Approach to Regiochemical Control

in Allylic Systems Y. Hatanaka, Y. Ebina, T. Hiyama, J. Am. Chem. Soc., 113, 7075-7076 (1991). 143 Enantioselective Synthesis of β-Hydroxy δ-Lactones: A New Approach to the Synthetic Congeners of 3-

Hydroxy-3-methylglutaryl Coenzyme A Reductase Inhibitors G. Bhaskar Reddy, T. Minami, T. Hanamoto, T. Hiyama, J. Org. Chem., 56, 5752-5754 (1991). 144 Design, Synthesis and Properties of New Ferroelectric Liquid Crystalline Compounds Having a Chiral

Center Directly Connected to the Core Aromatic Ring T. Hiyama, T. Kusumoto, S. Takehara, Ferroelectrics, 121, 159-166 (1991). 145 A Facile Synthesis of Difluoromethylene Compounds by Oxidative Fluorodesulfurization of Dithioacetals

Using Tetrabutylammonium Dihydrogentrifluoride and N-Halo Compounds M. Kuroboshi, T. Hiyama, Synlett, 909-910 (1991).

[1992]

11 146 A Facile Synthesis of 4-Formyl-1,2,3-thiadiazole T. Kobori, M. Fujita, T. Hiyama, K. Kondo, Synlett, 95-96 (1992). 147 Stereoselective Synthesis of β-Lactams by Oxidative Coupling of Dianins of Acyclic Tertiary Amides T. Kawabata, T. Minami, T. Hiyama, J. Org. Chem., 57, 1864-1873 (1992). 148 Carbonylative Coupling Reaction of Organofluorosilanes with Organic Halides Promoted by Fluoride Ion

and Palladium Catalyst Y. Hatanaka, S. Fukushima, T. Hiyama, Tetrahedron, 48 (11), 2113-2126 (1992). 149 Oxidative Desulfurization-Fluorination of Methyl Arenedithiocarboxylates. A Convenient Synthesis of Trifluoromethylated Aromatic Compounds M. Kuroboshi, T. Hiyama, Chem. Lett., 827-830 (1992). 150 Hydrosilylation of 1,4-Bis(trimethylsilyl)butadiyne and Silyl-Substituted Butenynes T. Kusumoto, K. Ando, T. Hiyama, Bull. Chem. Soc. Jpn., 65, 1280-1290 (1992). 151 Oxidative Desulfurization-Fluorination of Xanthates. A Convenient Synthesis of Trifluoromethyl Ethers

and Difluoro(methylthio)methyl Ethers M. Kuroboshi, K. Suzuki, T. Hiyama, Tetrahedron Lett., 33 (29), 4173-4176 (1992). 152 A Facile Synthesis of Trifluoromethylamines by Oxidative Desulfurization-Fluorination of

Dithiocarbamates M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 33 (29), 4177-4178 (1992). 153 Synthesis and Electro-Optical Properties of Silicon-Containing Chiral Cyanocyclopropanes and γ-

Lactones as Dopants for Ferroelectric Liquid Crystals T. Kusumoto, A. Nakayama, K. Sato, T. Hiyama, S. Takehara, M. Osawa, K. Nakamura, Chem. Lett.,

2047-2056 (1992). 154 光学活性フルオロシクロプロパンおよびトリフルオロメチルシクロプロパン骨格を有する強誘

電性液晶 楠本哲生, 佐藤健一, 黒星　学, 檜山爲次郎, 竹原貞夫, 大澤政志, 中村佳代子, 日化誌, (10),

1189-1196 (1992). 155 A Novel Enantioselective Synthesis of HMG Co-A Reductase Inhibitor NK-104 and a Related Compound T. Minami, T. Hiyama, Tetrahedron Lett., 33 (49), 7525-7526 (1992).

[1993] 156 On the Regioselectivity in the Hurd-Mori Reaction M. Fujita, T. Kobori, T. Hiyama, K. Kondo, Heterocycles, 36 (1), 33-36 (1993). 157 Stereoselective Reduction of β,δ-Diketo Esters Derived from Tartaric Acid. A Facile Route to Optically

Active　6-Oxo-3,5-syn-isopropylidenedioxyhexanoate, a Versatile Synthetic Intermediate of Artificial HMG Co-A Reductase Inhibitors

T. Minami, K. Takahashi, T. Hiyama, Tetrahedron Lett., 34 (3), 513-514 (1993). 158 Synthesis and Electro-Optical Properties of 3-Fluoroalkyl-Substituted Phenylpyrimidines as Chiral

Dopants for Ferroelectric Liquid Crystals T. Kusumoto, K. Ogino, K. Sato, T. Hiyama, S. Takehara, K. Nakamura, Chem. Lett., 1243-1246 (1993). 159 Synthesis and Properties of Optically Active 1,3-Diols and their Derivatives as Chiral Dopants for

Ferroelectric Liquid Crystals T. Kusumoto, K. Sato, K. Ogino, T. Hiyama, S. Takehara, M. Osawa, K. Nakamura, Liquid Crystals, 14

(3), 727-732 (1993). 160 Second-Harmonic Generation in Antiferroelectric Liquid Crystal T. Fujioka, K. Kajikawa, H. Takezoe, A. Fukuda, T. Kusumoto, T. Hiyama, Jpn. J. Appl. Phys., 32 (Part 1,

10), 4589-4593 (1993). 161 Synthesis and Biological Properties of 3-[(Z)-2-(1,2,3-Thiadiazolyl)ethenyl]-Substituted Cephalosporins

and Related Compounds: New Oral Cephalosporins T. Kobori, M. Fujita, R. Yamamoto, T. Hiyama, K. Kondo, K. Numata, K. Sugita, T. Akashi, Y. Kaneda, T.

Nagate, K. Hanada, Bioorg. Med. Chem. Lett., 3 (11), 2225-3220 (1993). 162 A New Synthesis of HMG-CoA Reductase Inhibitor NK-104 Through Hydrosilylation-Cross Coupling

Reaction K. Takahashi, T. Minami, Y. Ohara, T. Hiyama, Tetrahedron Lett, 34 (51), 8263-8266 (1993). 163 A Novel Synthetic Method of HMG-CoA Reductase Inhibitor NK-104 via A Hydroboration-Cross

Coupling Sequence N. Miyachi, Y. Yanagawa, H. Iwasaki, Y. Ohara, T. Hiyama, Tetrahedron Lett, 34 (51), 8267-8270 (1993). 164 Synthesis of Optically Active t-Butyl (3R,5S)-3,5-Isopropylidenedioxy-6-heptynoate Through Baker's

Yeast Reduction of Methyl 3-Oxo-4-pentynoate

12 M. H. Ansari, T. Kusumoto, T. Hiyama, Tetrahedron Lett, 34 (51), 8271-8274 (1993). 165 Fluoroalkyl-substituted Phenylpyrimidines as Chiral Dopants for Ferroelectric Liquid Crystals T. Kusumoto, K. Ogino, K. Sato, T. Hiyama, S. Takehara, K. Nakamura, Ferroelectrics, 148, 147-152

(1993). 166 Design, Synthesis and Properties of New Chiral Dopants for Ferroelectric Liquid Crystals T. Kusumoto, T. Hiyama, S. Takehara, Ferroelectrics, 148, 153-160 (1993). 167 New Chiral Dopants for FLC Materials: Optically Active Cyclic Ethers S. Takehara, M. Osawa, K. Nakamura, T. Kusumoto, K. Sato, A. Nakayama, T. Hiyama, Ferroelectrics,

148, 195-202 (1993).

[1994] 168 On the Regioselectivity of Palladium Catalyzed Cross-Coupling Reactions of Alkenylsilanes:

Participation of β-Cationic Organosilicate-Palladium Species during the Transmetallation Y. Hatanaka, K. Goda, T. Hiyama, J. Organomet. Chem., 465, 97-100 (1994). 169 Regio- and Stereoselective Cross-Coupling Reaction of Optically Active Allylsilanes: Stereocontrol of

Palladium-Mediated SE' Reactions Y. Hatanaka, K. Goda, T. Hiyama, Tetrahedron Lett., 35 (8), 1279-1282 (1994). 170 A General Approach for the Synthesis of Phenolic Natural Products. Facile Syntheses of Grifolin and

Colletochlorines B and D H. Saimoto, J. Ueda, H. Sashiwa, Y. Shigemasa, T. Hiyama, Bull. Chem. Soc. Jpn., 67, 1178-1185 (1994). 171 A Facile Synthesis of α,α-Difluoroalkyl Ethers and Carbonyl Fluoride Acetals by Oxidative

Desulfurization-Fluorination M. Kuroboshi, T. Hiyama, Synlett, (4), 251-252 (1994). 172 Palladium-catalyzed Cross-Coupling Reaction of Organometalloids through Activation with Fluoride Ion T. Hiyama, Y. Hatanaka, Pure & Appl. Chem., 66 (7), 1471-1478 (1994). 173 A Convenient Synthesis of Perfluoroalkylated Amines by Oxidative Desulfurization-Fluorination M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 35 (23), 3983-3984 (1994). 174 Highly Selective Cross-Coupling Reactions of Aryl(halo)silanes with Aryl Halides: A General and

Practical Route to Functionalized Biaryls Y. Hatanaka, K. Goda, Y. Okahara, T. Hiyama, Tetrahedron, 50 (28), 8301-83066 (1994). 175 Palladium Catalyzed Cross-Coupling Reaction of Functionalized Alkyltrifluorosilanes with Aryl Halides H. Matsuhashi, M. Kuroboshi, Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 35 (35), 6507-6510 (1994). 176 Synthesis of Perfluoroalkyl-substituted Arenes by Oxidative Desulfurization-Fluorination M. Kuroboshi, T. Hiyama, J. Fluorine Chem., 69, 127-128 (1994). 177 Catalytic Asymmetric Hydrosilylation of Conjugated Dienes: Effective Control of Regio- and

Enantioselectivities Y. Hatanaka, K. Goda, F. Yamashita, T. Hiyama, Tetrahedron Lett., 35 (43), 7981-7982 (1994).

[1995] 178 Stereoselective Reduction of β,δ-Diketo Esters. A Novel Strategy for the Synthesis of Artificial HMG-

CoA Reductase Inhibitors T. Hiyama, G. Bhaskar Reddy, T. Minami, T. Hanamoto, Bull. Chem. Soc. Jpn., 68 (1), 350-363 (1995). 179 Synthesis of Artificial HMG-CoA Reductase Inhibitors Based on the Olefination Strategy T. Hiyama, T. Minami, K. Takahashi, Bull. Chem. Soc. Jpn., 68 (1), 364-372 (1995). 180 Synthesis of Trifluoromethylamino-Substituted Pyridines and Pyrimidines by Oxidative Desulfurization-

Fluorination M. Kuroboshi, K. Mizuno, K. Kanie, T. Hiyama, Tetrahedron Lett., 36 (4), 563-566 (1995). 181 Anti-Selective Alkylation of Carboxylate Enolates with 2-Sulfonyloxyalkanes: A New Route to Optically

Active 2-Arylalkanoic Acids T. Kusumoto, S. Ichikawa, K. Asaka, K. Sato, T. Hiyama, Tetrahedron Lett., 36 (7), 1071-1074 (1995). 182 Palladium-Catalyzed Cross-Coupling of Allylic Carbonates with Alkenylfluorosilanes in the Absence of

Fluoride Ion H. Matsuhashi, Y. Hatanaka, M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 36 (9), 1539-1540 (1995). 183 Synthesis of Ferroelectric Liquid Crystals Having Chiral Nitrodihydrobenzofuran Structure H. Matsutani, K. Sato, T. Kusumoto, T. Hiyama, S. Takehara, H.Takezoe, T. Furukawa, Mol. Cryst. Liq.

Cryst., 263, 131-138 (1995) 184 The Importance of the Electric Interaction for Stabilizing the Antiferroelectric Smectic Liquid-Crystalline

Phase

13 T. Kusumoto, T. Isozaki, Y. Suzuki, Y. Takanishi, H. Takezoe, A. Fukuda, T. Hiyama, Jpn. J. Appl. Phys.,

34, L830-1832 (1995). 185 Halofluorination of Alkenes Using Dilute Hydrofluoric Acid M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 68, 1799-1805 (1995). 186 Synthesis and Electro-Optical Properties of Dihydrobenzofurans and Dihydrofuropyridines as Chiral

Dopants for Ferroelectric Liquid Crystals T. Kusumoto, K. Sato,T. Hiyama, S. Takehara, K. Ito, Chem. Lett., 537-538 (1995). 187 Synthesis and Properties of Dimeric Antiferroelectric Liquid Crystals Y. Suzuki,T. Isozaki, T. Kusumoto, T. Hiyama, Chem. Lett., 719-720 (1995). 188 Synthesis and Properties of New Liquid Crystals Containing Trifluoromethylamino Group K. Kanie, K. Mizuno, M. Kuroboshi, S. Takehara, T. Hiyama, Chem. Lett., 683-684 (1995). 189 Synthesis of an Artificial HMG-CoA Reductase Inhibitor NK-104 via a Hydrosilylation–Cross-coupling

Reaction K. Takahashi, T. Minami, Y. Ohara, T. Hiyama, Bull. Chem. Soc. Jpn., 68, 2649-2656 (1995). 190 Catalytic Asymmetric Hydrosilylation of 1,3-Dienes with Difluoro(phenyl)silane H. Ohmura, H. Matsuhashi, M. Tanaka, M. Kuroboshi, T. Hiyama, Y. Hatanaka, K. Goda, J. Organomet.

Chem., 499, 167-171 (1995). 191 Total Synthesis of dl-Ascofuranone and Related Compounds H. Saimoto, S. Ohrai, H. Sashiwa, Y. Shigemasa, T. Hiyama, Bull. Chem. Soc. Jpn., 68, 2727-2734

(1995). 192 Allylation of Quinones with Allyl(trifluoro)silanes: Direct Synthesis of Isoprenoid Quinones E. Hagiwara, Y. Hatanaka, K. Gohda, T. Hiyama, Tetrahedron Lett., 36 (16), 2773-2776 (1995). 193 Silylation of 1-Alkynes with Chlorosilanes Promoted by Zinc: Preparation of Alkynylsilanes in a Single

Step H. Sugita, Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 36 (16), 2769-2772 (1995). 194 Oxidative Desulfurization-Fluorination of 1-Substituted 2,2,2-Tri(methylthio)ethanol Induces Difluorina-

tion under Oxidation or Rearrangement M. Kuroboshi, S. Furuta, T. Hiyama, Tetrahedron Lett., 36 (34), 6121-6122 (1995). 195 Stereoselective Synthesis of (E)-ArCF=CFR and (E)-ArCH=CFR from ArCH(OH)CFBr2

M. Kuroboshi, N. Yamada, Y. Takebe, T. Hiyama, Tetrahedron Lett., 36 (35), 6271-6274 (1995). 196 Generation and Carbonyl Addition of Dibromofluoromethyllithium M. Kuroboshi, N. Yamada, Y. Takebe, T. Hiyama, Synlett, 987-988 (1995). 197 Isolation of Δ3-1,2,3-Thiadiazolin-1-ones, a Key Intermediate of the Hurd-Mori Reaction M. Fujita, K. Nimura, T. Kobori, T. Hiyama, K. Kondo, Heterocycles, 41 (11), 2413-2417 (1995). 198 Fluoro-Pummerer Rearrangement under Oxidative Desulfurization Fluorination Conditions. Facile

Syntheses of Oligofluoroalkyl Sulfides S. Furuta, M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 36 (45), 8243-8246 (1995). 199 Synthesis and Properties of Deuterated Antiferroelectric Liquid Crystals T. Kusumoto, K. Sato, G. Kumaraswamy, T. Hiyama, T. Isozaki, Y. Suzuki, Chem. Lett., (12), 1147

(1995).

[1996] 200 Synthesis of 5-Substituted Pyrimidine Nucleosides Through a Palladium-Catalyzed Cross-Coupling of

Alkenylhalosilanes H. Matsuhashi, Y. Hatanaka, M. Kuroboshi, T. Hiyama, Heterocycles, 42 (1), 375-384 (1996). 201 Photochemical Switching of Ferroelectric Liquid Crystals Using a Photoswitchable Chiral Dopant M. Negishi, O. Tsutsumi, T. Ikeda, T. Hiyama, J. Kawamura, M. Aizawa, S. Takehara, Chem. Lett.,

319-320 (1996). 202 A Convenient Synthesis of Alkynylsilanes by Silylation of Copper(I) Alkynides H. Sugita, Y. Hatanaka, T. Hiyama, Chem. Lett., 379-380 (1996). 203 Novel Synthetic Strategy for HMG-CoA Reductase Inhibitors T. Hiyama, Pure & Appl. Chem., 68 (3), 609-612 (1996). 204 A Facile Preparation and Polymerization of 1,1-Difunctionalized Disiloxanes A. Mori, H. Sato, K. Mizuno, T. Hiyama, K. Shintani, Y. Kawakami, Chem. Lett., 517-518 (1996). 205 Scandium(III) Triflate Catalyzed Friedel-Crafts Alkylation with Benyl and Alkyl Alcohols T. Tsuchimoto, K. Tobita, T. Hiyama, S. Fukuzawa, Synlett, 557-558 (1996). 206 Synthesis and Photochemical Switching of the Antiferroelectric Liquid Crystals M. Negishi, K. Kanie, T. Ikeda, T. Hiyama, Chem. Lett., 583-584 (1996).

14 207 Stability of the Antiferroelectric Phase in Dimeric Liquid Crystals Having Two Chiral Centers with CF3

or CH3 Groups: Evaluation of Conformational and Electric Interactions Y. Suzuki, T. Isozaki, S. Hashimoto, T. Kusumoto, T. Hiyama, Y. Takanishi, H. Takezoe, A. Fukuda, J.

Mater. Chem., 6 (5), 753-760 (1996). 208 A Novel Reduction of Zinc(II) Chloride with Samarium Metal and its Application to Silylation of 1-

Alkynes H. Sugita, Y. Hatanaka, T. Hiyama, Synlett, 637-638 (1996). 209 Samarium(II) Triflate as a New Reagent for the Grignard-Type Carbonyl Addition Reaction S. Fukuzawa, K. Mutoh, T. Tsuchimoto, T. Hiyama, J. Org. Chem., 61 (16), 5400-5405 (1996). 210 Antiferroelectric Liquid Crystals Having a Chiral Ring Structure T. Kusumoto, K. Ogino, T. Hiyama, T. Isozaki, Y. Suzuki, Chem. Lett., 865-866 (1996). 211 Cross-Coupling Reactions of Aryl Chlorides with Organochlorosilanes: Highly Effective Methods for

Arylation or Alkenylation of Aryl Chlorides K. Goda, E. Hagiwara, Y. Hatanaka, T. Hiyama, J. Org. Chem., 61 (21), 7232-7233 (1996). 212 Generation and Aldehyde Addition of a Zinc Carbenoid Substituted by Fluorine T. Hata, M. Shimizu, T. Hiyama, Synlett, 831-832 (1996). 213 Facile Synthesis of the 1,3-Disilacyclohexane Ring K. Mizuno, N. Inamasu, M. Shimizu, T. Hiyama, Chem. Lett., 1083-1084 (1996). 214 Diastereoselective Generation of Lithium Carbenoid Reagent RCH(OMEM)FCBrLi and Its Reaction with

Electrophiles M. Shimizu, Y. Takebe, M. Kuroboshi, T. Hiyama, Tetrahedron Lett., 37 (41), 7387- 7390 (1996). 215 Scandium(III) Trifluoromethanesulfonate-Catalyzed Reductive Friedel-Crafts Benzylation of Aromatic

Compounds Using Arenecarbaldehydes and Propane-1,3-diol T. Tsuchimoto, T. Hiyama, S. Fukuzawa, Chem. Commun., 2345-2346 (1996). 216 Difluorination of 2-Substituted 1,1,1-Tris(methylthio)ethanes by Oxidative Desulfurization-Fluorination.

A New Route to Partially Fluorinated Olefins S. Furuta, T. Hiyama, Tetrahedron Lett., 37 (44), 7983-7986 (1996). 217 Chirality Transfer via the Palladium-Catalyzed Cross-Coupling Reaction of Optically Active 2-

Cyclohexenylsilane: Stereochemical and Mechanistic Aspects T. Hiyama, H. Matsuhashi, A. Fujita, M. Tanaka, K. Hirabayashi, M. Shimizu, A. Mori, Organometallics,

15 (26), 5762- 5765 (1996). 218 A Facile Synthesis of Substituted 3,3,3-Trifluoropropenes by Oxidative Desulfurization-Fluorination of

the Corresponding dithiopropenoates S. Furuta, T. Hiyama, Synlett., (12) 1199-200 (1996).

[1997] 219 NaOH-Promoted Cross Coupling Reactions of Organosilicon Compounds with Organic Halides: Practical

Routes to Biaryls, Alkenylarenes and Conjugated Dienes E. Hagiwara, K. Gouda, Y. Hatanaka, T. Hiyama, Tetrahedron Lett., 38 (3), 439-442 (1997). 220 Superacid-Catalyzed Reductive Friedel-Crafts Reaction of Arenes Using Arenecaraldehyde Acetals S. Fukuzawa, T. Tsuchimoto, T. Hiyama, J. Org. Chem., 26 (1), 151-156 (1997). 221 Palladium-Catalyzed Cross-Coupling Reaction of Alkyltrifluorosilanes with Aryl Halides H. Matsuhashi, S. Asai, K. Hirabayashi, Y. Hatanaka, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 70 (2),

437-444 (1997). 222 Synthesis of Cyclopropylsilanols by the Simmons-Smith Reaction of Alkenylsilanols and Lithium

Alkenyl-silanolates K. Hirabayashi, A. Mori, T. Hiyama, Tetrahedron Lett., 38 (3), 461-464 (1997). 223 Oxidative Desulfurization-Fluorination of Alkanol Xanthates. Control of the Reaction Pathway to

Fluorination or Trifluoromethoxylation K. Kanie, Y. Tanaka, M. Shimizu, M. Kuroboshi, T. Hiyama, Chem. Commun., (3), 309-310 (1997). 224 Copper(I) Salt Promoted Homo-coupling Reaction of Organosilanes K. Ikegashira, Y. Nishihara, K. Hirabayashi, A. Mori, T. Hiyama, Chem. Commun., (6), 1039-1040

(1997). 225 Synthesis and Lewis Acid-Catalyzed Nucleophilic Substitution of Chiral 1-Alkoxyalkyl Carboxylates H. Matsutani, S. Ichikawa, J. Yaruva, T. Kusumoto, T. Hiyama, J. Am. Chem. Soc., 119 (19), 4541-4542

(1997). 226 Synthesis of Novel Liquid-Crystalline Thiophene Derivatives and Evaluation of Their Photoresponsive

Behavior

15 Y. Nabeshima, A. Shishido, A. Kanazawa, T. Shiono, T. Ikeda, T. Hiyama, Chem. Mater., 9 (6),

1480-1487 (1997). 227 Synthesis and Electro-optical Properties of Novel Liquid Crystals Having a Cyclohexyl Trifluoromethyl

Ether Moiety K. Kanie, Y. Tanaka, M. Shimizu, S. Takehara, T. Hiyama, Chem. Lett., 827-828 (1997). 228 The Palladium-Catalyzed Cross-Coupling Reaction of Organosilicon Compounds with Allylic Carbonates

or Diene Monoxides H. Matsuhashi, S. Asai, K. Hirabayashi, Y. Hatanaka, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 70,

1943-1952 (1997). 229 Bromo(t-butyldimethylsilyl)fluoromethyllithium: A Fluorinated Nucleophilic Carbenoid Reagent

Stabilized by a Silyl Substituent M. Shimizu, T. Hata, T. Hiyama, Tetrahedron Lett., 38 (26), 4591-4594 (1997). 230 TBAHF2 and TBAH2F3

as Activating Agents of Organosilanes A. Mori, A. Fujita, K. Ikegashira, Y. Nishihara, T. Hiyama, Synlett, (6), 693-694 (1997). 231 On the Catalytic Cycle of the Palladium-Catalyzed Cross-Coupling Reaction of Alkynylstannane with

aryl Iodide E. Shirakawa, H. Yoshida, T. Hiyama, Tetrahedron Lett., 38 (29), 5177-5180 (1997). 232 Scandium(III) Triflate-Catalyzed Friedel-Crafts Alkylation Reactions T. Tsuchimoto, K. Tobita, T. Hiyama, and S. Fukuzawa, J. Org. Chem., 62 (20), 6997-7005 (1997). 233 Cu(I)/Pd(0)-Catalyzed Cross-Coupling Reaction of Alkynylsilanes with Aryl or Alkenyl Triflates: Sila-

Sonogashira-Hagihara Coupling Y. Nishihara, K. Ikegashira, A. Mori, T. Hiyama, Chem. Lett.,(12), 1233-1234 (1997). 234 Homocoupling of Organostannanes Catalyzed by Iminophosphine-Palladium E. Shirakawa, Y. Murota, Y. Nakao, T. Hiyama, Synlett, (10), 1143-1144 (1997). 235 Cyclic Polyamides Consisting of 1,1'-Binaphthyls. 'Chiral Twist' of Glycine Residues K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama, Tetrahedron: Asymmetry, 8 (20), 3431-3436 (1997). 236 Nickel-catalysed Cross-coupling Reactions of Aryl Halides with Organostannanes E. Shirakawa, K. Yamasaki, T. Hiyama, J. Chem. Soc., Perkin Trans. 1, 2449-2450 (1997). 237 Copper(I) Salt Mediated 1,4-Reduction of α,β-Unsaturated Ketones Using Hydrosilanes A. Mori, A. Fujita, Y. Nishihara, T. Hiyama, Chem. Commun., (22), 2159-2160 (1997). 238 Stereo- and Regioselective Bromination of 1,5-Cyclooctadiene Derivatives and Their Substitution

Reactions with Organocopper Reagents Y. Baba, C. Noutary, S. Ichikawa, T. Kusumoto, H. Watanabe, M. Adachi, H. Hotta, Y. Nakajima, K. Arai,

T. Hiyama, Synlett, (12), 1393-1394 (1997). 239 Mechanistitc Aspects of the Alternating Copolymerization of Propene with Carbon Monoxide Catayzed

by Pd(II) Complexes of Unsymmetrical Phosphine–Phosphite Ligands K. Nozaki, N. Sato, Y. Tonomura, M. Yasutomi, H. Takaya, T. Hiyama, T. Mastubara, N. Koga, J. Am.

Chem. Soc., 119 (52), 12779-12795 (1997).

[1998] 240 Double-Helical Oligo Esters: Chiral Twist of Two Aromatic Ester Chains K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama, Angew. Chem. Int. Ed., 37 (12), 131-133 (1998). 241 A Practical Synthesis of (1S,2R)-1-Amino-2-indanol, a Key Component of HIV Protease Inhibitor,

Indinavir H. Kajiro, S. Mitamura, A. Mori, T. Hiyama, Synlett (1), 51-52 (1998). 242 Enantioselective Synthesis of 2-Hydroxy-1-indanone, a Key Precursor of Enantiomerically Pure 1-

Amino-2-indanol H. Kajiro, S. Mitamura, A. Mori, T. Hiyama, Tetrahedron: Asymmetry, 9, 907-910 (1998). 243 Carbostannylation of Alkynes Catalyzed by an Iminophosphine–Palladium Complex E. Shirakawa, H. Yoshida, T. Kurahashi, Y. Nakao, T. Hiyama, J. Am. Chem. Soc., 120, 2975-2976 (1998). 244 Asymmetric Hydroformylation of Olefins in a Highly Cross-Linked Polymer Matrix K. Nozaki, Y. Ito, F. Shibahara, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama, J. Am. Chem. Soc., 120

(16), 4051-4052 (1998). 245 Chiral and achiral phosphine-phosphite ligands in Pd(II)-catalyzed alternating copolymerization of

propene with CO K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama, Polyhedron, 27 (7), 1159-1164 (1998). 246 Alkylation Methodology for the Synthesis of 1,4-Disilacyclohexanes Using α,α'-Dilithiated Silanes M. Shimizu, M. Iwakubo, Y. Nishihara, T. Hiyama, Tetrahedron Lett., 39, 3197-3200 (1998).

16 247 Bis[bis(methylthio)lithiomethyl]dimethylsilanes: A Useful Reagents for the Synthesis of Polysilacarba-

cycles via Disilylation M. Shimizu, M. Iwakubo, Y. Nishihara, T. Hiyama, Tetrahedron Lett., 39, 3193-3196 (1998). 248 Copper(I)-Catalyzed Cross-Coupling Reaction of Alkynylsilanes with 1-Chloroalkynes Y. Nishihara, K. Ikegashira, A. Mori, T. Hiyama, Tetrahedron Lett., 39, 4075-4078 (1998). 249 Asymmetric Synthesis of 1-Alkoxy-2,2,2-trifluoroethanol Derivatives H. Poras, H. Matsutani, J. Yaruva, T. Kusumoto, T. Hiyama, Chem. Lett., 665-667 (1998). 250 Nucleophilic Substitution of Optically Active 1-Alkoxypolyfluoroalkyl Sulfonates H. Matsutani, H. Poras, T. Kusumoto, T. Hiyama, Chem. Commun., 1259-1260 (1998). 251 Fluorination of Orthothioesters through Oxidative Desulfurization–Fluorination S. Furuta, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 71 (8), 1939-1951 (1998). 252 A Facile Synthesis of Trifluoromethylamines by Oxidative Desulfurization–Fluorination of

Dithiocarbamates K. Kanie, K. Mizuno, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 71 (8), 1973-1991 (1998). 253 Chiral and Achiral Phosphine–Phosphite Ligands in Pd(II)-catalyzed Alternating Copolymerization of

Propene with CO K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama, Polyhedron, 17 (7), 1159-1164 (1998). 254 An Unusual Endothermic Transition to an Optically Isotropic Phase Organized by Chiral Molecular

Recognition A. Yoshizawa, J. Umezawa, N. Ise, R. Sato, Y. Soeda, T. Kusumoto, K. Sato, T. Hiyama, Y. Takanishi, H.

Takezoe, Jpn. J. Appl. Phys., 37, L942-944 (1998). 255 A Facile Preparation and Cyclopropanation of 1-Alkenylsilanols K. Hirabayashi, E. Takahisa, Y. Nishihara, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 71 (10), 2409-2417

(1998). 256 A Facile Synthesis and Electro-optical Properties of New Liquid Crystals Having a vic-Difluoro Olefinic

Moiety K. Kanie, Y. Tanaka, S. Takehara, T. Hiyama, Chem. Lett., 1169-1170 (1998). 257 Novel Cage Polycarbosilanes. Preparation and Characterization of Dodecamethyl-2,3,5,6,7,8-

hexasilabicyclo[2.2.2]octane and Its Derivatives M. Shimizu, N. Inamasu, Y. Nishihara, T. Hiyama, Chem. Lett., 1145-1146 (1998). 258 Facile Synthesis of α-Fluoroalkyl Sulfides under the Oxidative Desulfurization–Fluorination Conditions S. Furuta, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 71 (11), 2687-2694 (1998). 259 A Novel C-C Bond Forming Reaction of Aryl- and Alkenylsilanols. A Halogen-Free Mizoroki-Heck Type

Reaction K. Hirabayashi, Y. Nishihara, A. Mori, T. Hiyama, Tetrahedron Lett., 39, 7893-7896 (1998). 260 Cross-Coupling Reaction of Organostannanes with Aryl Halides Catalyzed by Nickel-Triphenylphosphine

or Nickel-Lithium Halide Complex E. Shirakawa, K. Yamasaki, T. Hiyama, Synthesis, (10), 1544-1549 (1998). 261 Generation and Carbonyl Addition Reactions of Dibromofluoromethyllithium Derived from

Tribromofluoromethane as Applied to the Stereoselective Synthesis of Fluoro Olefins and 2-Bromo-2-fluoro-1,3-alkanediols

M. Shimizu, N. Yamada, Y. Takebe, T. Hata, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 71 (12), 2903-2921 (1998).

262 Facile synthesis of 1-Sila-4-stannacyclohexanes from 1,5-Distannyl-3-silapentanes M. Shimizu T. Sasaki, T. Hiyama, Synlett (11), 1267-1269 (1998). 263 Stereospecific Nucleophilic Substitution of Optically Active 1-Benzyloxy-2,2,2-trifluoroethyl Tosylate

with Lithium Tetraalkylaluminataes Prepared by the Ti-Catalyzed Hydroalumination of Olefins H. Matsutani, H. Poras, T. Kusumoto, T. Hiyama, Synlett (12), 1353-1354 (1998).

[1999] 264 Scandium Trifluoromethanesulfonate-Catalyzed Mild, Efficient, and Selective Cleavage of Acetates

Bearing a Coordinative Group H. Kajiro, S. Mitamura, A. Mori, T. Hiyama, Tetrahedron Lett., 40, 1689-1692 (1999). 265 A Coupling Reaction of Aryltributyltin with Olefins Mediated by Palladium(II) Acetatte K. Hirabayashi, J. Ando, Y. Nishihara, A. Mori, T. Hiyama, Synlett (1) 99-101 (1999). 266 A Facile Synthesis of Trifluoromethyl- and 3,3,3-Trifluoropropenyl-Substituted Aromatic Compounds by

the Oxidative Desulfurization-Fluorination of the Corresponding Carbodithioates S. Furuta, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 72, 805-19 (1999).

17 267 Conjugate Reduction of α,β-Unsaturated Ketones with Hydrosilane Mediated by Copper(I) Salt A. Mori, A. Fujita, H. Kajiro, Y. Nishihara, T. Hiyama, Tetrahedron, 55, 4573-4582 (1999). 268 Palladium-Catalyzed Dimerization-Carbostannylation of Alkynes: Synthesis of Highly Conjugated

Alkenylstannanes E. Shirakawa, H. Yoshida, Y. Nakao, T. Hiyama, J. Am. Chem. Soc., 121 (17), 4290-4291 (1999). 269 A Practical Synthesis of (1S,2R)-1-Amino-2-indanol, a Key Component of an HIV Protease Inhibitor,

Indinavir H. Kajiro, S. Mitamura, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 72, 1093-1100 (1999). 270 A Chiral Bimetallic Lewis Acid as a Reaction Template. Asymmetric Reduction of Unsymmetric Ketones

with LiBH4

K. Nozaki, K. Kobori, T. Uemura, T. Tsutsumi, H. Takaya, T. Hiyama, Bull. Chem. Soc. Jpn., 72, 1109-1113 (1999).

271 A Facile Synthesis of Optically Active 1,1,1-Trifluoro-3-alkyn-2-ols by Stereospecific Substitution of Optically Active 1-Benzyloxy-2,2,2-trifluoroethyl Tosylate with Lithium Alkynyltriethylaluminates

H. Matsutani, T. Ksumoto, T. Hiyama, Chem. Lett., 529-530 (1999). 272 A Unique Chelating Effect of Sc(OTf)3 to Organofluorine Compounds H. Kajiro, A. Mori, Y. Nishihara, T. Hiyama, Chem. Lett., 459-460 (1999). 273 Synthesis and Optical Resolution of Novel Chiral Silanols A. Mori, F. Toriyama, H. Kajiro, K. Hirabayashi, Y. Nishihara, T. Hiyama, Chem. Lett., 549-550 (1999). 274 Scandium Trifluoromethanesulfonate-Catalyzed Cleavage of Esters Bearing a Coordinative Group at a

Vicinal Position H. Kajiro, S. Mitamura, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 72, 1553-1560 (1999). 275 Synthesis and Electro-optical Properties of 3-Substituted Phenyl Trifluoromethyl Ethers K. Kanie, M. Kuroboshi, S. Takehara, T. Hiyama, J. Fluorine Chem., 97, 201-206 (1999). 276 Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes K. Nozaki, F. Shibahara, Y. Itoi, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama, Bull. Chem. Soc. Jpn., 72

(8), 1911-1918 (1999). 277 Asymmetric Terpolymerization of Propene, Vinylarene, and Carbon Monoxide K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama, Macromolecules, 32 (15), 5168-5170 (1999). 278 A New Transformation of Silanols. Palladium-Catalyzed Cross-Coupling with Organic Halides in the

Presence of Silver(I) Oxide K. Hirabayashi, J. Kawashima, Y. Nishihara, A. Mori, T. Hiyama, Org. Lett., 1 (2), 299-302 (1999). 279 A Facile Route to 3,7-cis-Disubstituted Cycloocta-1,5-diene-1,2,5,6-tetracarboxylates Through

Photochemical [2 + 2] Cycloaddition of 3-Substituted Cyclobutene-1,2-dicarboxylates and Thermal Isomerization

H. Watanabe, Y. Nakajima, M. Adachi, H. Hotta, K. Arai, Y. Baba, C. Noutary, S. Ichikawa, T. Kusumoto, T. Hiyama, Chem. Commun., 1753-1754 (1999).

280 FC(SiMe3)3 and FC(SiMe3)2SnBu3: A Novel C1 Building Block for Fluoro Olefins M. Shimizu, T. Hata, T. Hiyama, Tetrahedron Lett., 40, 7375-8 (1999). 281 Molecular Recognition of the Dichiral Liquid Crystals Containing Fluorines T. Kusumoto, K. Sato, M. Katoh, H. Matsutani, A. Yoshizawa, N. Ise, J. Umezawa, Y. Takanishi, H.

Takezoe, T. Hiyama, Mol. Cryst. Liq. Cryst., 330, 227-234 (1999). 282 Photochemical Control of Conductivity of Polythiophenes with Photochromic Moieties H. Mochizuki, Y. Nabeshima, T. Kitsunai, A. Kanazawa, T. Shiono, T. Ikeda, T. Hiyama, T. Maruyama, T.

Yamamoto, N. Koide, J. Mater. Chem., 9, 2215-2219 (1999). 283 Alternating Copolymerization of Various Alkenes with Carbon Monoxide Using a Cationic Pd(II)

Complex of (R,S)-BINAPHOS as an Initiator K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama, Polymer J., 31 (11-2), 1057-1060 (1999). 284 Syntheses and Properties of Novel Liquid Crystals Containing a Trifluoromethylamino Group K. Kanie, K. Mizuno, M. Kuroboshi, S. Takehara, T. Hiyama, Bull. Chem. Soc. Jpn., 72 (11), 2523-2535

(1999). 285 Nickel-Catalyzed Carbostannylation of Alkynes with Allyl-, Acyl-, and Alkynylstannanes: Stereoselective

Synthesis of Trisubstituted Vinylstannanes E. Shirakawa, K. Yamasaki, H. Yoshida, T. Hiyama, J. Am. Chem. Soc., 121 (43), 10221-1022 (1999). 286 Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide and

Carbon Dioxide K. Nozaki, K. Nakano, T. Hiyama, J. Am. Chem. Soc., 121 (47), 11008-11009 (1999). 287 Synthesis of Polysilacage Compounds Containing a Trisilane Bridge

18 M. Shimizu, S. Ishizaki, H. Nakagawa, T. Hiyama, Synlett, (11), 1772-1773 (1999). 288 A Facile Synthesis of 1,3-Disilacyclohexanes M. Shimizu, K. Mizuno, N. Inamasu, H. Masai, T. Hiyama, Inorg. Chim. Acta, 296, 231-235 (1999).

[2000] 289 A Convenient Synthesis of Trifluoromethyl Ethers by Oxidative Desulfurization-Fluorination of

Dithiocarbonates K. Kanie, Y. Tanaka, K. Suzuki, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn., 73, 471-484 (2000). 290 Novel Synthesis of 1-Fluoro-1-silyloxiranes Using Bromo(tert-Butyldimethylsilyl)fluoromethyllithium

and Carbonyl Compounds M. Shimizu, T. Hata, T. Hiyama, Hetereocycles, 52 (2), 707-717 (2000). 291 Regio- and Stereocontrolled Hydrosilylation Polyaddition Catalyzed by RhI(PPh3)3. Syntheses of

Polymers Containing (E)- or (Z)-Alkenylsilane Moieties A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, T. Hiyama, Macromolecules, 33 (4), 1115-1116 (2000). 292 Coupling Reactions of Alkynylsilanes Mediated by a Cu(I) Salt: Novel Syntheses of Conjugate Diynes

and Disubstituted Ethynes Y. Nishihara, K. Ikegashira, K. Hirabayashi, J. Ando, A. Mori, T. Hiyama, J. Org. Chem., 65 (6),

1780-1787 (2000). 293 Homo-Coupling Reactions of Alkenyl- and Arylfluorosilanes Mediated by a Copper (I) Salt Y. Nishihara, K. Ikegashira, F. Toriyama, A. Mori, T. Hiyama, Bull. Chem. Soc. Jpn., 73 (4), 985-990

(2000). 294 A Novel Cross-Coupling Polycondensation of Alkynylsilanes with Aryl Triflates Catalyzed by CuCl/Pd

(PPh3)3

Y. Nishihara, J. Ando, T. Kato, A. Mori, T. Hiyama, Macromolecules, 33 (8), 2779-81 (2000) 295 High-Pressure NMR Studies on the Alternating Copolymerization of Propene with Carbon Monoxide

Catalyzed by a Palladium(II) Complex of an Unsymmetrical Phosphine-phoshite Ligand K. Nozaki, T. Hiyama, S. Kacker, I. T. Horváth, Organometallics, 19 (10), 2031-2035 (2000). 296 Vapor-Phase Asymmetric Hydroformylation K. Nozaki, F. Shibahara, T. Hiyama, Chem. Lett., 694-695 (2000). 297 Stereodivergent Hydrosilylation of 1-Alkynes Catalyzed by RhI(PPh3)3 Leading to (E)- and (Z)-

Alkenylsilanes and the Application to Polymer Synthesis A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, T. Hiyama, Polyhedron, 19, 567-568 (2000). 298 Optical Switching and Alignment of Antiferreolectric Liquid Crystals Containing an Azo Group K. Shirota, I. Yamaguchi, K. Kanie, T. Ikeda, T. Hiyama, I. Kobayashi, Y. Suzuki, Liquid Crystals, 27 (5),

555-558 (2000). 299 Novel Carbon–Carbon Bond Formation through Mizoroki–Heck Type Reaction of Silanols and Organotin

Compounds K. Hirabayashi, J. Ando, J. Kawashima, Y. Nishihara, A. Mori, T. Hiyama, Bull. Chem Soc. Jpn., 73 (6),

1409-1417 (2000). 300 A Facile Transformation of Terminal Olefins to vic-Difluoro Olefins: Electro-optical Properties of Liquid

Crystalline Materials Having a vic-Difluoro Olefinic Moiety K. Kanie, Y. Tanaka, S. Takehara, T. Hiyama, Bull. Chem. Soc. Jpn., 73 (7), 1633-1643 ((2000). 301 Novel C1 Building Blocks for Fluoro Olefin Synthesis: FC(SiMe3)3 and FC(SiMe3)2SnBu3

M. Shimizu, T. Hata, T. Hiyama, Bull. Chem. Soc. Jpn., 73 (7), 1685-1690 (2000). 302 Chemoselective Aldehyde Addition of Zinc Carbenoid Generated from Tribromofluoromethane T. Hata, H. Kitagawa, M. Shimizu, T. Hiyama, Bull. Chem. Soc. Jpn., 73 (7), 1691-1695 (2000). 303 Practical Stereoselective Synthesis of (2,3,4,5-Tetrahydro-1H-benzo[b]azepin-5-yl)acetic Acid T. Shinohara, K. Kondo, H. Ogawa, T. Mori, K. Nozaki, T. Hiyama, Chirality, 12, 425-430 (2000). 304 Mechanistic Aspects of Palladium-Catalyzed Allylstannylation of Alkynes E. Shirakawa, H. Yoshida, Y. Nakao, T. Hiyama, Org. Lett., 2 (15), 2209-2211 (2000). 305 A Facile Synthesis of Novel Liquid Crystalline Materials Having a Trifluoromethoxy Group and Their

Electro-Optical Properties K. Kanie, S. Takehara, T. Hiyama, Bull. Chem. Soc. Jpn., 73 (8), 1875-1892 (2000). 306 Asymmetric Reduction of an Enantiomerically Pure γ-Polyketone K. Nozaki, N. Kosaka, S. Muguruma, T. Hiyama, Macromolecules, 33 (15), 5340-5346 (2000). 307 Solid-phase Cross-coupling Reaction of Aryl(fluoro)silanes with 4-Iodobenzoic Acid F. Homsi, K. Nozaki, T. Hiyama, Tetrahedron Lett., 41, 5869-5872 (2000). 308 Palladium-Catalyzed Cross-Coupling of Silanols, Silanediols, and Silanetriols Promoted by Silver(I)

19Oxide

K. Hirabayashi, A. Mori, J. Kawashima, M. Suguro, Y. Nishihara, T. Hiyama, J. Org. Chem., 65 (17), 5342-5349 (2000).

309 Diphenylphosphinophenolate: a Ligand for the Palladium-catalysed Silylation of Aryl Halides Activating Simultaneously Both Palladium and Silicon

E. Shirakawa, T. Kurahashi, H. Yoshida, T. Hiyama, Chem. Commun., 1895-1896 (2000). 310 Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes E. Shirakawa, Y. Nakao, H. Yoshida, T. Hiyama, J. Am. Chem. Soc., 122 (37), 9030-9031 (2000). 311 Formation of Optically Isotropic Cubic Phase Based on Chiral Recognition in Dichiral Compounds Y. Takanishi, H. Takezoe, A. Yoshizawa, T. Kusumoto, T. Hiyama, Mol. Cryst. Liq. Cryst., 347, 257-264

(2000). 312 Palladium–Iminophosphine-Catalyzed Alkynylstannylation of Alkynes H. Yoshida, E. Shirakawa, T. Kurahashi, Y. Nakao, T. Hiyama, Organometallics, 19 (26), 5671-5678

(2000).

[2001] 313 Nickel-catalysed Acylstannylation of 1,2-Dienes: Synthesis and Reactions of α-(Acylmethyl)

vinylstannanes E. Shirakawa, Y. Nakao, T. Hiyama, Chem. Commun., 263-264 (2001). 314 Geminal Difunctionalization of Alkenylidene-type Carbenoids by Using Interelement Compounds T. Hata, H. Kitagawa, H. Msai, T. Kurahashi, M. Shimizu, T. Hiyama, Angew. Chem. Int. Ed., 40 (4),

790-792 (2001). 315 Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of

(R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama, Adv. Synth. Catal., 343 (1), 61-63 (2001). 316 Predominant 1,2-Insertion of Styrene in the Pd-Catalyzed Alternating Copolymerization with Carbon

Monoxide K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama, T. Matsubara, J. Am. Chem. Soc., 123 (4), 534-544

(2001). 317 Dimerization–Carbostannylation of Alkynes Catalyzed by a Palladium–Diimine Complex:

Regioselectivity, Stereoselectivity and Mechanism H. Yoshida, E. Shirakawa, Y. Nakao, Y. Honda, T. Hiyama, Bull. Chem. Soc. Jpn., 74, 637-647 (2001). 318 In vitro and in vivo Antibacterial Activity and Pharmacokinetics of SC-002 and Its Derivative, SC-004:

New Oral Cephalosporins T. Nagate, T. Kashi, K. Numata, K. Sugita, Y. Kaneda, M. Matsuyama, H. Saito, M. Nozawa, A. Onodera,

K. Hanada, T. Kobori, M. Fujita, R. Yamamoto, T. Hiyama, K. Kondo, Chemotherapy, 47, 157-169 (2001).

319 Solid Phase Cross-coupling Reaction of Aryl(halo)silanes with 4-Iodobenzoic Acid F. Homsi, K. Hosoi, K. Nozaki, T. Hiyama, J. Organomet. Chem., 624, 208-216 (2001). 320 Novel Synthesis of 2,3-Bisboryl-1,3-dienes from 1-Bromo-1-lithioethene and 1,1-Bisborylalkenes M. Shimizu, T. Kurahashi, T. Hiyama, Synlett, 1006-1008 (2001). 321 New, General, and Stereoselective Synthesis of CF3-Containing Tri- and Tetrasubstituted Oxiranes and

Tetrasubstituted Alkenes M. Shimizu, T. Fujimoto, H. Minezaki, T. Hata, T. Hiyama, J. Am. Chem. Soc., 123 (28), 6947-6948

(2001). 322 Methylenation of an Optically Active γ-Polyketone: Synthesis of a New Class of Hydrocarbon Polymers

with Main-Chain Chirality K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama, Macromolecules, 34 (18), 6167-6168 (2001). 323 Spectral Assignment of Poly[cyclohexene oxide-alt-carbon dioxide] K. Nakano, K. Nozaki, T. Hiyama, Macromolecures, 34 (18), 6325-6332 (2001). 324 Homo-Coupling Polycondensation of Bis(alkynylsilane)s Mediated by Copper(I) Chloride: A New

Synthesis of Poly(arylenebutadiynylene)s Y. Nishihara, T. Kato, J. Ando, A. Mori, T. Hiyama, Chem. Lett., 950-951 (2001). 325 Alternating Copolymerization of ω-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by

Homogeneous and Polymer-supported Pd-Complexes K. Nozaki, F. Shibahara, S. Elzner, T. Hiyama, Can. J. Chem., 79, 593-597 (2001). 326 Transition Metal-catalysed Acylation of α,β-Unsaturated Carbonyl Compounds with Acylstannanes E. Shirakawa, Y. Yamamoto, Y. Nakao, T. Tsuchimoto, T. Hiyama, Chem. Commun., 1926-1927 (2001).

20 327 Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted

arylstannanes H. Yoshida, Y. Honda, E. Shirakawa, T. Hiyama, Chem. Commun., 1880-1881 (2001). 328 Aryl-1-substituted Cage Molecules ArC(SiMe2SiMe2)3CR: Preparation, Properties, and Application to

Liquid Crystalline Compounds M. Shimizu, K. Watanabe, H. Nakagawa, T. Becker, S. Sugimoto, T. Hiyama, Chem. Lett., 1090-1091

(2001). 329 Isomerizaton of (Z)-alkenylsilanes to (E)-isomers with hydrosilane and RhI(PPh3)3

A. Mori, E. Takahisa, Y. Nishihara, T. Hiyama, Can. J. Chem., 79, 1522-1524 (2001). 330 Silyl-1-boryl-2-alkenes: Reagents for Stereodivergent Allylation Leading to 4-Oxy-(E)-1-

alkenylboronates and 4-Oxy-(Z)-1-alkenylsilanes M. Shimizu, H. Kitagawa, T. Kurahashi, T. Hiyama, Angew. Chem. Int. Ed., 40 (22), 4283-4286 (2001).

[2002] 331 Alkenyldimethyl(2-thieny)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-

Coupling Reaction K. Hosoi, K. Nozaki, T. Hiyama, Chem. Lett., 138-139 (2002). 332 Synthesis and Liquid Crystalline Behavior of Stereoregular Polyketones with Mesogenic Side Chains K. Nozaki, Y. Kawashima, T. Oda, T. Hiyama, K. Kanie, T. Kato, Macromolecules, 35, 1140-1142 (2002). 333 Structures in Optically Isotropic and Bluish Colored Cubic Phases Formed by Enantiomeric Association

in an (R,S) Dichiral Compound and a Stereoisomeric (R,R) and (S,S) Mixture Y. Takanishi, T. Ogasawara, A. Yosizawa, J. Umezawa, T. Kusumoto, T. Hiyama, K. Ishikawa, H.

Takezoe, J. Mater. Chem., 12, 1325-1330 (2002). 334 Methylenation of Optically Active γ-Polyketones K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama, Polymer J., 34, 376-382 (2002). 335 Synthesis of Functionalized Alkenes by Transition Metal-catalyzed Carbostannylations of Alkynes and

Dienes Followed by Cross-coupling Reactions E. Shirakawa, T. Hiyama, J. Organomet. Chem., 653, 114-121 (2002). 336 Palladium-catalyzed Cross-coupling Reaction uising Alkenyldimethyl(2-thienyl)silanes K. Hosoi, K. Nozaki, T. Hiyama, Proc. Japn Acad., 78, Ser. B (6), 154-160 (2002). 337 Geminal Dimetalation of Alkylidene-type Carbenoids with Silylboranes and Diborons T. Kurahashi, T. Hata, H. Masai, H. Kitagawa, M. Shimizu, T. Hiyama, Tetrahedron, 58 (32), 6381-6395

(2002). 338 Synthesis of Polycyclic Compounds Utilizing the Nickel-catalysed Alkynylstannylation of 1,2-Dienes E. Shirakawa, Y. Nakao, T. Tsuchimoto, T. Hiyama, Chem. Commun., 1962-1963 (2002). 339 Addition of Ureas to Arynes: Straightforward Synthesis of Benzodiazepine and Benzodiazocine

Derivatives,H. Yoshida, E. Shirakawa, Y. Honda, T. Hiyama, Angew. Chem. Int. Ed., 41 (17), 3247-3249 (2002).

340 Carbon Monoxide Free Aminocarbonylation of Aryl and Alkenyl Iodides Using DMF as an Amide Source K. Hosoi, K. Nozaki, T. Hiyama, Org. Lett., 4 (17), 2849-2851 (2002). 341 Rodlike organogelator: fibrous aggregation of azobenzene derivatives with a syn-chiral carbonate moiety J. Mamiya, K. Kanie, T. Hiyama, T. Ikeda, T. Kato, Chem. Commun., 1870-1871 (2002). 342 Novel convenient synthesis and chemoselective derivatization of 1-sila-4-stannacyclohexanes M. Shimizu, T. Sasaki, T. Hiyama, Silicon Chemistry, 1, 333-344 (2002).

[2003] 343 gem-Silylborylation of an sp-Carbon: Novel Synthesis of 1-Boryl-1-silylallenes M. Shimizu, T. Kurahashi, H. Kitagawa, T. Hiyama, Org. Lett., 5 (2), 225-227 (2003). 344 High-Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)-(R,S)-

BINAPHOS K. Nozaki, T. Matsuo, F. Shibahra, T. Hiyama, Organometallics, 22 (3), 594-600 (2003). 345 Palladium–iminophosphine-catalyzed homocoupling of alkynylstannanes and other organostannanes

using allyl acetate or air as an oxidant E. Shirakawa, Y. Nakao, Y. Murota, T. Hiyama, J. Organomet. Chem., 670, 132-136 (2003). 346 Asymmetric Alternating Copolymerization of Cyclohexene Oxide and CO2 with Dimeric Zinc Complexes K. Nakano, K. Nozaki, T. Hiyama, J. Am. Chem. Soc., 125 (18), 5501-5510 (2003). 347 The Double N-Arylation of Primary Amines: Toward Multisubstituted Carbazoles with Unique Optical

Properties

21 K. Nozaki, K. Takahashi, K. Nakano, T. Hiyama, H.-Z. Tang, M. Fujiki, S. Yamaguchi, K. Tamao, Angew.

Chem. Int. Ed., 42 (18), 2051-2053 (2003).348 Aymmetric terpolymerization of styrene or its derivative and aliphatic 1-alkenes with CO catalyzed by Pd–

(R,S)-BINAPHOS Y. Kawashima, K. Nozaki, T. Hiyama, Inorg. Chim. Acta, 350, 577-582 (2003). 349 gem-Silylborylation Approach for Tri- and Tetrametalmethanes: the First Synthesis of Boryl(germyl)

(silyl)(stannyl)methanes M. Shimizu, T. Kurahashi, H. Kitagawa, K. Shimono, T. Hiyama, J. Organometal. Chem., 686.

286-303 (2003). 350 Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Cross-Linked Polystyrene-

Supported (R,S)-BINAPHOS–Rh(I) Complex F. Shibahara, K. Nozaki, T. Hiyama, J. Am. Chem. Soc., 125, 855-8560 (2003).351 Conformational Studies on an Optically Active 1,4-Polyketone in Solution N. Kosaka, K. Nozaki, T. Hiyama, M. Fujiki, N. Tamai, T. Matsumoto, Macromolecules, 36 (8),

6884-6887 (2003) 352 2,3,5,6,7,8-Hexasilabicyclo[2.2.2]octane-1-carboxylic Acids and Esters: Preparation ond Structure M. Shimizu, S. sugimoto, H. Mizukoshi, T. Hiyama, J. Organomet. Chem., 685, 138-144 (2003).353Stereoselective generation of cis-2-lithio-3-CF3-oxirane via CF3-substituted b-oxido carbenoids. Highly

stereoselective synthesis of CF3-substituted tri- and tetrasubstituted oxiranes and tetrasubstituted alkenes M. Shimizu, T. Fujimoto, Xinyu Liu, H. Minezaki, T. Hata, T. Hiyama, Tetrahedron, 59, 9811-23 (2003).354Liquid-Crystalline Stereoregular Polyketone Prepared from a Mesogenic Vinylarene and Carbon Monoxide Y. Kawashima, K. Nozaki, T. Hiyama, M. Yoshio, K. Kanie, T. Kato, J. Polym. Sci., Part A: Polym.

Chem., 41, 3556-63 (2003)355 Cubic and Blue Phases in a Fluorine-containing Dichiral Compound Y. Tananishi, S. Yoshida, T. Ogasawara, K. Ishikawa, H. Takezoe, K. Ema, H. Yao, A. Yoshizawa, T.

Kusumoro, T. Hiyama, Mol. Cryst. Liq. Cryst., 401, 133-147 (2003).356 Triallyl(aryl)silanes serve as a convenient agent for silicon-based cross-coupling reaction of aryl halides Y. Nakao, T. Oda, A. K. Sahoo, T. Hiyama, J. Organomet. Chem., 687, 570-573 (2003).

[2004]357 A Facile Stereocontrolled Approach to CF3-Substituted Triarylethenes: Synthesis of Panomifene X. Liu, M. Shimizu, and T. Hiyama, Angew. Chem. Int. Ed., 43, 879–882 (2004).358 Hydroesterification of Vinylarenes Catalyzed by Palladium Complexes of Dilakylmonoaryl- and

Monoalkyldiarylphosphines Y. Kawashima, K. Okano, K. Nozaki, T. Hiyama, Bull. Chem. Soc. Jpn., 77 (2), 347-355 (2004).359 A Facile approacah to 2-CF3-Subsstituted Seven-membered Oxacycles via Stereoselective preparation and

Cope Rearrangement of 2-CF3-cis-2,3-bis(alkenyl)oxiranes M. Shimizu, T. Fujimoto, Xinyu Liu, T. Hiyama, Chem. Lett., 33 (4), 438-439 (2004).360 A Highly Effective and Practical Biaryl Synthesis with Triallyl(aryl)silanes and Aryl Chlorides A. K. Sahoo, Y. Nakao, T. Hiyama, Chem. Lett., 33 (5), 632-633 (2004).361 Nickel-Catalyzed Tandem Carbostannylation of alkynes and 1,2-Dienes with Alkynylstannanes E. Shirakawa, Y. Yamamoto, Y. Nakao, S. Oda, T. Tsuchimoto, T. Hiyama, Angew. Chem. Int. Ed., 43,

3448-51 (2004).362 Alternative Route to Protected Aldols: Cobalt-Catalyzed Hydroformylation of Epoxides and in situ

Protection of β-Hydroxyaldehydes by HC(OMe)3

K. Nakano, M. Katayama, S. Ishihara, T. Hiyama, K. Nozaki, Synlett, (8) 1367-1370 (2004).363 Facile Synthesis of Dendralenes Based on the Cross-coupling Reaction of 2,3-Bis(pinacolato)boryl-1,3-

butadiene M. Shimizu, K. Tanaka, T. Kurahashi, K. Shimono, T. Hiyama, Chem. Lett., 33, 1066-67 (2004).364 Preparation and Structure of Alkenyl- and Alkynyl-Substituted Polysilamodules HC(SiMe2SiMe2)3CR M. Shimizu, H. Mizukoshi, T. Hiyama, Synthesis, (9) 1363-68 (2004).365 Novel Liquid Crystalline Compounds Based on 4-Aryl-2,3,5,6,7,8-hexasilabicylco[2.2.2]octanes M. Shimizu, M. Nata, K. Watanabe, T. Hiyama, Trans. Mater. Soc. Jpn., 29 [3], 793-4 (2004).366 A Novel Mild Deprotection Method for Phosphine–Boranes M. Schröder, K. Nozaki, T. Hiyama, Bull. Chem. Soc. Jpn., 77 (10), 1931-2 (2004).367 Nickel-Catalyzed Aylcyanation of Alkynes Y. Nakao, S. Oda, T. Hiyama, J. Am. Chem. Soc., 126, 13904-5 (2004).

22２　引用の比較的多い原著論文10編 Stereoselective Alkylation of 1-Lithiocyclopropyl Bromides K. Kitatani, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 97, 949-950 (1975). （引用79件）

Grignard-Type Carbonyl Addition of Allyl Halides by Means of Chromous Salt. A Chemospecific Synthesis of Homoallyl Alcohols

Y. Okude, S. Hirano, T. Hiyama, H. Nozaki, J. Am. Chem. Soc., 99, 3179-3181 (1977). （引用223件）　当初、檜山・野崎反応と呼ばれていた。

Highly Selective Carbon-Carbon Bond Forming Reactions Mediated by Chromium(II) Reagents T. Hiyama, Y. Okude, K. Kimura, H. Nozaki, Bull. Chem. Soc. Jpn., 55 (2), 561-568 (1982).（引用137

件）

Selective Grignard-Type Addition of Alkenyl Halides Mediated by Chromium(II) Chloride K. Takai, K. Kimura, T. Kuroda, T. Hiyama, H. Nozaki, Tetrahedron Lett., 24 (47), 5281-5284 (1983).

（引用116件）　野崎・檜山・岸反応 (NHK Reaction) の速報

Carbon-Carbon Bond Formation with Metallic Manganese T. Hiyama, M. Sawahata, M. Obayashi, Chem. Lett., 1237-1238 (1983). （引用54件）

Highly Diastereocontrolled Reduction of Ketones by Means of Hydrosilanes. Practical Synthesis of Optically Active 1,2-Diols and 2-Amino Alcohols of Threo or Erythro Configuration

M. Fujita, T. Hiyama, J. Am. Chem. Soc., 106, 4629-4630 (1984). （引用99件）

Fluoride Ion Catalyzed Aldehyde Addition of Labile α− or β-Halocarbanion Species Generated from the Corresponding α- or β-Halo Organosilanes

M. Fujita, T. Hiyama, J. Am. Chem. Soc., 107, 4085-4087 (1985). （引用62件）

Cross-coupling of Organosilanes with Organic Halides Mediated by Palladium Catalyst and Tris(diethylamino)sulfonium Difluorotrimethylsilicate

Y. Hatanaka, T. Hiyama, J. Org. Chem., 53, 918-920 (1988). （引用102件）　檜山カップリングの速報

Photochemical Switching of Ferroelectric Liquid Crystals Using a Photoswitchable Chiral Dopant M. Negishi, O. Tsutsumi, T. Ikeda, T. Hiyama, J. Kawamura, M. Aizawa, S. Takehara, Chem. Lett.,

319-320 (1996). （引用24件）

Carbostannylation of Alkynes Catalyzed by an Iminophosphine–Palladium Complex E. Shirakawa, H. Yoshida, T. Kurahashi, Y. Nakao, T. Hiyama, J. Am. Chem. Soc., 120, 2975-2976

(1998). （引用43件）

23３　著書 学位論文 Studies on the Chemistry of New Cyclic Structures and Synthetic Application 新しい環状化合物の化学とその合成的応用に関する研究，1975, 京都大学

1 現代化学 14，「物質の合成 I」，野崎　一 編，岩波，1979 (共著). 2 化学増刊 96，「有機合成の新反応剤 —設計と実際—」，野崎　一，向山光昭，山本　尚 編，

化学同人 II-6 章 「遷移金属塩による新しい還元と酸化」，1982 (共著). 3 「ほしいものだけつくる化学 —有機合成化学—」野崎 一編, 天然物合成の最前線 —合成戦略

—, 裳華房，1982 (共著). 4 化学増刊 99，「新しい有機合成の展望 —第一線化学者の考え方・進め方—」，野崎　一 編，

「Anthracycline 抗生物質の合成」，「D-Glucose を出発原料に用いるTrichothecanes 類の新合成法」，化学同人, 1983 (共著).

5 化学便覧，第３版基礎編II，「均一系触媒反応」，日本化学会，丸善，1984 (共著). 6 有機合成ハンドブック，「酸」, 「クロムとマンガン化合物」，有機合成化学協会，丸善 1990

(共著). 7 Hydrosilylation of C=C and C≡C, T. Hiyama, T. Kusumoto, in Comprehensive Organic Synthesis, Vol 8,

Pergamon Press, 1991 (coauthor). 8 A Playground with Fluorine, Silicon, and Organometallics in Organic Synthesis of Japan, Past, Present,

and Future, Society of Synthetic Organic Chemistry, Tokyo Kagaku Dojin, 1992, pp 121-127. 9 化学便覧，第４版基礎編 II，「均一系触媒反応」, 日本化学会, 丸善, 1993 (共著). 10 化学便覧，第４版応用編,「アルカリ金属」, 「アルカリ土類金属」，日本化学会, 丸善, 1995 (共

著). 11 「有機合成化学」， 4章-II 「典型元素の有機金属」，朝倉書店, 1997. 12 Organosilicon Compounds in Cross-Coupling Reactions in Metal-catalyzed Cross-coupling Reactions, T.

Hiyama, Y. Hatanaka, ed. by F. Diederich and P. J. Stang, Wiley-VCH, Germany, 1998, English. 13 「大学院講義　有機化学 II」，野依良治，柴崎正勝，鈴木啓介，玉尾皓平，中筋一弘，奈良坂

紘一編，「カップリング反応」，東京化学同人．1998. 14 Experimental Methods in Organic Fluorine Chemistry, ed. by T. Kitazume, T. Yamazaki, Kodansha, 1998

(共著). 15 Fluorine-Containing Chiral Liquid Crystals: Syntheses and Properties, T. Kusumoto, T. Hiyama, in

Enatiocontrolled Synthesis of Fluoro-Organic Compounds ed. by V. A. Soloshonok, Johon Wiley & Sons, Chichester, 1999.

16 The Activity of the 116th Committee on Chemistry Creating Organic Compounds with Novel Functions in Science and Society —Co-operation between Academia and Industry—, Ed. by Y. Shiraki, Pilkington Press, Yelvertoft Manor, UK, 1999.

17 Organofluorine Compounds: Chemistry and Applications, T. Hiyama, Springer, Berlin, 2000, pp 272. 18 Synthetic Aspects of Fluorine-Containing Chiral Liquid Crystals, T. Hiyama, T. Kusumoto, H. Matsutani,

in Asymmetric Fluoroorganic Chemistry. Synthesis, Applications, and Future Directions, Ed. by P. V. Ramachandran, American Chemical Society, 2000.

19 「液晶便覧」液晶便覧編集委員会編、「液晶の合成」（分担執筆）、西原康師、森　敦紀、檜山爲次郎、丸善、東京、2000.

20 第15回「大学と科学」公開シンポジウム「現代の匠が創る未来物質」「ケイ素−エレメント結合の切り貼り」，檜山爲次郎，クバプロ，2001.

21 「キラルテクノロジーの新展開」第9章「ファインケミカルズを指向する含フッ素・ケイ素標的分子の効率合成の最前線」 檜山爲次郎，清水正毅，CMC，東京，2001.

22 Invention of Synthetic Reactions with F, Si and/or Metals, T. Hiyama, M. Shimizu, in My Favorite Organic Synthesis, The Sciety of Synthetic Organic Chemistry, Japan, Kagaku Dojin, 2002, Kyoto.

23 「ウォーレン 有機化学」（上）（下）、 監訳、東京化学同人、2003、東京.24 「有機金属反応剤ハンドブック」玉尾皓平編著（フッ素分担執筆），化学同人，2003，京都.25 「有機合成のための触媒反応 103」，編集，東京化学同人，2004，東京．

24４　総説その他

総説 1 強塩基による有機合成 —カルボアニオンによるC-C 結合生成反応を中心に— 檜山爲次郎, 野崎　一, 有合化, 33 (11), 869-888 (1975). 2 環拡大反応 檜山爲次郎, 野崎　一, 有合化, 35 (12), 979-991 (1977). 3 ハロゲンと有機合成 檜山爲次郎, 化学, 33 (6), 440-448 (1977). 4 Li, Na, K 檜山爲次郎, 有合化, 37 (12), 982-990 (1979). 5 炭素−炭素結合生成に役立つ高選択的クロム反応剤 檜山爲次郎, 有合化, 39 (1), 81-85 (1981). 6 ケイ素陰イオンおよび関連種の化学　— 最近の進歩 — 藤田　誠, 檜山爲次郎, 有合化, 42 (4), 293-302 (1984). 7 カルベノイド反応剤のカルボニル付加反応 — ポリハロアルコールの簡便合成法 藤田　誠, 檜山爲次郎, 染料と薬品, 31 (12), 325-35 (1986). 8 トリフルオロメチル基を有する合成ピレスロイドの新規合成法 —亜鉛カルベノイド反応剤 CF3CCl2ZnCl の開発と応用— 藤田　誠, 檜山爲次郎, 有合化, 45 (7), 664-671 (1987). 9 1,4-ビス(トリメチルシリル)ブタジインおよび関連体を用いる有機合成 楠本哲生, 檜山爲次郎, 染料と薬品, 33 (4), 98-108 (1988). 10 有機ケイ素化合物/F–/Pd触媒による高選択的交差カップリング反応 畠中康夫, 檜山爲次郎, 有合化, 48 (9), 834-843 (1990). 11 ビス(トリメチルシリル)ぺルオキシド 黄　利人, 檜山爲次郎, 有合化, 48 (11), 1004-1005(1990). 12 トリス（ジアルキルアミノ）スルホニウムジフルオロトリメチルシリカート（TASF） 黒星　学, 檜山爲次郎, 有合化, 48 (11), 1050-1051 (1990). 13 コアに直結した不斉中心を有する強誘電性液晶の合成と物性 楠本哲生, 檜山爲次郎, 竹原貞夫, 東海林忠生, 有合化, 49, 475-485 (1991). 14 Highly Selective Cross-Coupling Reactions of Organosilicon Compounds Mediated by Fluoride Ion and

Pd Catalyst Y. Hatanaka, T. Hiyama, Synlett, 845-853 (1991). 15 光学活性環構造を有する強誘電性液晶キラルドーパントの設計と合成 楠本哲生, 檜山爲次郎, 竹原貞夫, 日化誌, (12), 1401-1411 (1992). 16 ベンジル位に不斉中心と極性基をもつ強誘電性液晶化合物のデザインと合成 楠本哲生, 檜山爲次郎, 竹原貞夫, 染料と薬品, 38 (3), 57-572 (1992). 17 酸化的フッ素化反応による有機フッ素化合物の合成 黒星　学, 檜山爲次郎, 有合化, 51 (12), 1124-1133 (1993). 18 フッ素を極性基にもつ強誘電性液晶 楠本哲生, 檜山爲次郎, 竹原貞夫, 染料と薬品, 39 (1), 6-17 (1994). 19 有機ケイ素化合物のクロスカップリング反応 檜山爲次郎, Organometallic News, 102-106 (1994). 20 Synthesis and Reactions of 1,4-Bis(trimethylsilyl)butadiyne T. Kusumoto, T. Hiyama, Reviews on Heteroatom Chemistry, 11, 143-163 (1994). 21 フッ化水素を基盤とするフッ素化反応 檜山爲次郎, 黒星　学, 化学, 50 (1), 66-67 (1995). 22 HMG-CoA 還元酵素阻害剤の合成 宮地伸英, 鈴木幹夫, 小原義夫, 檜山爲次郎, 有合化, 53 (3), 186-196 (1995). 23 光学活性オキシランを用いる強誘電性および反強誘電性液晶化合物の合成 楠本哲生, 檜山爲次郎, 染料と薬品, 40 (9), 227-241 (1995). 24 Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of Chiral Phosphine-

Phosphite Ligands K. Nozaki, H. Takaya, T. Hiyama, Topics in Catalysis, 4, 175-185 (1997). 25 二量体型液晶化合物の構造と物性 楠本哲生, 檜山爲次郎, 染料と薬品, 42 (4), 85-106 (1997). 26 一酸化炭素とオレフィンの立体選択的交互共重合 野崎京子, 檜山爲次郎, 有合化, 56 (8), 645-650 (1998).

25 27 パラジウム–イミノホスフィン触媒を用いる有機スズ化合物の反応 白川英二. 檜山爲次郎, 有合化, 56 (10), 810-817 (1998). 28 The palladium-iminophosphine Catalyst for the Reactions of Organostannanes E. Shirakawa, T. Hiyama, J. Organomet. Chem., 576, 169-178 (1999). 29 Stereoselective Alternating Copolymerization of Carbon Monoxide with Alkenes K. Nozaki, T. Hiyama, J. Organomet. Chem., 576, 248-253 (1999). 30 Synthesis and Structures of Polysilacage Compounds Contaning a Silicon–silicon Inter-element Linkage M. Shimizu, T. Hiyama, T. Matsubara, T. Yamabe, J. Organomet. Chem., 611, 12-19 (2000). 31 酸化的脱硫フッ素化反応 —有機フッ素化合物の簡便合成と新規フッ素系液晶材料の開発— 蟹江澄志, 黒星　学, 檜山爲次郎, 日化誌, (11), 749-761 (2000). 32 Oxidative Desulfurization-Fluorination: A Facile Entry to a Wide Variety of Organofluorine Compounds

Leading to Novel Liquid Crystalline Materials M. Kuroboshi, K. Kanie, T. Hiyama, Adv. Synth. Catal., 343 (3), 235-250 (2001). 33 Novel Bifunctional Synthetic Reagents: gem-Dimetallic Compounds Derived from Carbenoid Reagents

and Interelement Compounds M. Shimizu, T. Kurahashi, T. Hiyama, 有合化, 59 (11), 1062-1069 (2001). 34 Organosilicon Compounds T. Hiyama, E. Shirakawa, Topics in Current Chem., 219, 62-85 (2002). 35 Transition Metal-Catalyzed Carbostannylation of Alkynes and Dienes E. Shirakawa, T. Hiyama, Bull. Chem. Soc. Jpn., 75 (7), 1435-1450 (2002). 36 How I Came Across the Silicon-based Cross-coupling Reaction T. Hiyama, J. Organomet. Chem., 653, 58-61 (2002). 37 Synthesis of functionalized alkenes by transition metal-catralyzed carbostannylations of alkynes and

dienes followed by cross-coupling reactions E. Shirakawa, T. Hiyama, J. Organomet. Chem., 653, 114-21 (2002). 38 高架橋ポリスチレン担持(R,S)-BINAPHOS-Rh(I)錯体を用いる不斉ヒドロホルミル化反応 Asymmetric Hydroformylation Catalyzed by Highly Cross-Linked Polystyrene-Supported (R, S)-

BINAPHOS-Rh(I) Complexes! ! !芝原文利，野崎京子，檜山爲次郎，有合化，61 (7), 694-705 (2003). F. Shibahara, K. Nozaki, T. Hiyama, J. Synth. Org. Chem., 61 (7), 694-705 (2003). 39 Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycaronates K. Nakano, N. Kosaka, T. Hiyama, K. Nozaki, Dalton Trans., 4039-50 (2003).

解説など

1 OMCOS-VIIの見どころ・聞きどころ，植村　榮，内本喜一朗，佐藤史衛，鈴木正明，高橋成年，檜山爲次郎，有合化，43 (5), 397-405 (1985).

2 いまやっていること，檜山爲次郎，Oraganometallic News, (1), 1-3 (1987). 3 有機合成とその周辺，檜山爲次郎，化学，44 (2), 125 (1989) 4 有機ケイ素化合物／F–／Pd触媒によるクロスカップリング反応，畠中康夫，檜山爲次郎

Organometallic News, (2), 18-22 (1989). 5 セレンディピティこそ研究の醍醐味，檜山爲次郎，化学，48 (9), 606-610 (1993) 6 おらが春，檜山爲次郎，近畿化学工業界，1994年，1月号. 7 合成のデザインと実験を一体として，檜山爲次郎，Asahi Glass Foundation News, (7), 4 (1994). 8 備えあれば憂いなし — 初めての学会発表のしかた，檜山爲次郎，化学，52 (3), 18-19 (1997). 9 軽薄短省（小・少）時代の化学，檜山爲次郎，化学，55 (1), 34-35 (2000). 10 体験的任期制，きんか，2000年1月号，12-14, 近畿化学協会. 11 有機金属とマテリアルサイエンス，檜山爲次郎，Organometallic News, (1), 2-9 (2000). 12 いま，クロスカップリングが熱い！，清水正毅，檜山爲次郎，化学，56 (12), 45-47 (2001). 13 （財）相模中央化学研究所，東京工業大学資源化学研究所および京都大学材料化学専攻におけ

る檜山研究室，檜山爲次郎，液晶，6 (3), 314-319 (2002).14 材料の創製における有機合成の役割　未来材料、巻頭言 3 (5), 1 (2003)

15 有機合成の過去・現在・未来　有合化，62, 1 (2004)

26５　国際会議での招待講演

1986.8 The First Nozaki Conference (Okayama) 招待1989.9 Symposium on Progress & Prospects in Organic Synthesis (Champéry, Switzerland) 招待1989.10 OMCOS-V (Florence, Italy) 口頭依頼1991.6 3rd International Symposium on Ferroelectric Liquid Crystals (Boulder, USA) 口頭依頼1993.9 OMCOS-VII (Kobe) 招待1994.3 Convention Intercantonale Romande pour l'Enseignement du 3e Cycle en Chimie (Bern,

Neuchâtel, Lausanne, Genève) 招待1994.11 International Symposium on Novel Materials (Osaka) 招待1994.12 International Conference on Organic Synthesis (Bangalore, India) 招待1995.4 ACS Symposium on Cross-Coupling Reaction (Anaheim, USA) 招待1995.12 4th National Organic Symposium Trust (Tirupatti, India) 特別1997.4 Harvard Symposium (Cambridge, USA) 招待1997.4 ACS Symposium on Efficiency in Organic Reactions (San Francisco, USA) 招待1997.11 2nd International Forum on Organic Chemistry (IFOC-II) (Tokyo) 招待1998.5 8th Korea-Japan Joint Symp. on Organometallic and Coordination Chemistry (Kyoto) 招待1998.8 ACS Symposium on Asymmetric Synthesis Fluoroorganic Compounds (Boston,USA) 招待1999.5 The 12th International Symposium on Organosilicon Chemistry (Senda) 招待1999.5 International Silicon Workshop on Si Chemistry-Polymers (Tatsunokuchi, Ishikawa) 特別1999.9 Conf. Fluorinated Bio-active Compnds in the Agricultural and Medical Fields (Bruselles) 招待1999.11 9th Japan-Korea Symp. on Organometallic and Coordination Chemistry (Soeul, Korea) 招待2000.3 ACS Symposium on Fluorine Materials (San Francisco, USA) 招待2000.6 16th International Symposium on Organofluorine Chemistry (Durham, UK) 招待2000.10 Japan-Taiwan Joint Symposium on Organnometallic Chemistry (Kyoto) 招待　2000.12 Pacifichem on Organofluorine Chemistry & Heterocycles (2 lectures) (Honolulu, USA) 招待2001.6 10th Japan-Korea Symposium on Organometallic and Coordination Chemistry (Tsukuba) 招待2001.7 PostOMCOS-X Symposium on Cross-Coupling Reaction (Kyoto) 特別2001.11 2nd Italy-Japan Joint Symposium on Organic Chemistry (Kyoto) 招待2001.12 9th National Organic Symposium Trust (NOST) Symposium (Kovalam, India) 招待2001.12 Singapore International Chemistry Conference (Singapore)　招待2002.11 11th Korea-Japan Joint Symp. on Organometallic and Coordination Chemistry (Pusan) 招待2003.1 The 2nd International Symposium of the Kyoto COE Project "Elements Science" (Kyoto) 招待2003.1 The Ramanbhai Foundation 1st International Symposium: Recent Trends in Pharmaceutical

Sciences"（Ahmedabad, India）特別2003.6 International Symposium on Fluorine in the Life Science (Bürgenstock, Switzerland) 特別2003.10 Germany–Asia Symposium (München, Germany) 招待2004.9 Japan-Italy Workshop on Liquid Crystals (Tsu, Japan) 招待