temperature basics - burns engineering · tolerance at 0°c and as the temperature diverges from...
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© Burns Engineering Temperature Basics
Temperature Basics
Bill Bergquist, Sr. Applications EngineerJeff Wigen, National Sales Manager
Jeff Bill
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© Burns Engineering Temperature Basics
Temperature DefinedTemperature ScalesTypes of Temperature SensorsThermocouple
TypesTemperature rangesLead wire colorsStandards
RTDTemperature coefficientConstructionCalibrationInterchangeabilityStandards
Identification of Sensor TypesSensor Selection - The Four PsCalibrationPreventive Maintenance
Agenda
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What is temperature?
Measure of the average kinetic energy of particles in a substance.
Temperature is the result of the motion of particles. Temperature increases as the energy of this motion increases.
Physical quantity that is a measure of hotness and coldness on a numerical scale.
Temperature
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Temperature of some things:Ice 32°F
Dry ice −78.5°C (−109.3°F) at atmospheric pressure
Liquid nitrogen -196°C
Temperature
“Fahrenheit 451” (Ray Bradbury) approximate auto-ignition point of some paper
Sun 5700K (5430°C)
Earth’s core 5700K (5430°C) (cooling at 100°C per billion years). The core may contain enough gold, platinum, and other siderophile elements that if extracted and poured onto the Earth's surface, would cover the entire Earth with a coating 0.45 m (1.5 feet) deep.
Lightning bolt 50,000K
Earth’s average surface temperature – good luck trying to figure out that one!
In photography K (Kelvin) is used to denote color temperature. Match flame is about 1700K, sunshine is about 5400K.
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Celsius Swedish astronomer Anders Celsius (1701–1744)
By international agreement the unit "degree Celsius" and the Celsius scale are currently defined by two different temperatures: absolute zero, and the triple point of VSMOW (Vienna Standard Mean Ocean Water).
Triple point of water is defined as 273.16K or 0.01°C, the point at which water exists as a vapor, solid, and liquid.
A degree Celsius (or a Kelvin) is what you get when divide the thermodynamic range between absolute zero and the triple point of water into 273.16 equal parts.
In 1948, it was renamed Celsius because centigrade had other meanings in Spanish and French.
Temperature Scales
The Celsius scale is widely used in industry with the Fahrenheit scale a close second. Kelvin is almost exclusively used for scientific and laboratory measurements.
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Kelvin One of the seven base units in the SI system of units named after the Belfast-born, Glasgow University engineer and physicist William Thomson, 1st Baron Kelvin (1824–1907)
Based on absolute zero which is 0K, or −273.15°C or −459.67°F. Theoretical point at which all thermal motion stops.
Fahrenheit Temperature scale based on one proposed in 1724 by the physicist Daniel Gabriel Fahrenheit (1686–1736) freezing of water into ice is defined at 32 degrees, while the boiling point of water is defined to be 212 degrees — on Fahrenheit's original scale the freezing point of brine was zero degrees.
Temperature Scales
A Kelvin or K does not have a degree symbol. It is used by itself such as 273K. On calibration reports you will see the calibration uncertainty expressed in millikelvin or mK so 1mK is 0.001K.
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• Liquid displacement thermometers• Dial thermometers• Thermistors• Optical (DTS, IR)• Thermocouples• RTD’s
Various Temperature Sensors
Infrared
Bimetal coilThermistorsDial
RTDs and Thermocouples
There are other types of sensors that have little practical use or are still in development such as the Johnson Noise Thermometer, and a device that uses a laser as a measure.
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Liquid DisplacementDial
Both have . . . Limited temperature rangesLimited accuracyIndustrial integrityIntroduce human error
Thermometers
Mercury-in-glass is probably the most well known liquid displacement type of thermometer. Other types of fluid are used with some used to deflect a needle that indicates temperature.
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• Very precise• Ceramic, silicon, or polymer resistor• High resistance values• Very limited temperature range• Often have drift error• Self-heating errors• Low price
Thermistors
As temperature increases the resistance increases and can be correlated to a temperature.
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Made by connecting two different metals to form a closed circuit.High durabilityLow initial costVoltage change with temperature
Thermocouples
+
-
As temperature increases, the measured voltage increases and does so in a predictable manner. The thermocouple standards define the voltage vs. temperature relationship for several types of thermocouple junctions.
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Thermocouples
2500
2000
1500
1000
500
32
-45032 32
-328-328 -328
Thermocouples
Industrial RTD
1400
2156
700
1600
1200Temp
F
Type T Type E
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TypesMost common
• Type T: Copper-Constantan Red/Blue• Type J: Iron-Constantan Red/White• Type E: Chromel-Constantan Red/Purple• Type K: Chromel-Alumel Red/Yellow
High temperature types• R, S, B Platinum/Platinum-Rhodium 2640°F• W3, W5 Tungsten/Tungsten-Rhenium 4200°F
Each type has a different temperature range and Voltage vs. Temperature relationshipASTM Standard E230 , ANSI MC 96.1, and IEC 584-3
Thermocouples
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Junctions can be grounded, ungrounded or exposed.
Thermocouples
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Thermocouples
AdvantagesVery wide temperature Range [1.2K to 2300°C]Fast Response TimeAvailable in small sheath sizesLow initial costDurable
DisadvantagesDecreased accuracy vs. RTDsMore susceptible to RFI/EMIRecalibration is difficultRequires expensive TC wire from sensor to recording deviceDifficult to verifyNot as stable as RTDs
Thermocouples are typically used in an application where high temperature or high vibration is present. Their durability is probably their best asset.
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RTDs3 common element styles
Coil in the holeWire woundThin film
Resistor made from platinum, nickel, copper, or other metals
Resistance Temperature Detector
The platinum resistance thermometer (PRT) is the most widely used sensor type in applications where highly accurate, repeatable and stable measurements are required. Other metals are used but none have the wide temperature capability of platinum.
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Basic OperationResistance changes with temperature. As temperature increases, resistance increases in response.Small current is sent through the resistor element and electrical resistance is measuredPerformance defined by IEC 60751 and ASTM E1137
RTD
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Basic OperationTemperature coefficient
• Also called the Temperature Coefficient of Resistance or alpha
• Units are ohms/ohm/°C• The average change in resistance per unit change in
temperature between 0 and 100°C • α = R100 - R0 / 100°C*R0
» R0 = resistance at 0°C» R100 = resistance at 100°C
For the current industry standard 100 ohm RTD the alpha is .00385 which means at 100°C the nominal sensor resistance is 138.5 ohms
RTD
When specifying an RTD it is necessary to select the correct temperature coefficient to match the readout instrument or controller. Failure to do so will result in an inaccurate measurement.
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Most common coefficients• 0.00385 – ASTM E1137 or IEC 60751• 0.003902 – American• 0.003916 – JIS• 0.003925 - SPRT, Secondary SPRT
Must match your instrument to the proper temperature coefficient of your sensor
RTD
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Coefficient exampleA temperature is being measured with a sensor having a temperature coefficient of .003916 (JIS) but due to a sensor failure it was replaced with a sensor having a temperature coefficient of .00385.If the transmitter/controller is not recalibrated, at 100°C it will read 1.7°C low.
RTD
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RTDs are manufactured to have 100 ohms at 0°C.
Interchangeability refers to the “closeness of agreement” between an actual PRT R vs. T relationship and a predefined R vs. T relationship.
Defined by ASTM E1137 and IEC 60751
Nominal R vs. T of ASTM and IEC standards are equivalent but tolerances are different.
Interchangeability
The two main standards in use today are the IEC 60751 and the ASTM E1137. Both have the same nominal R vs. T values but differ in defining some performance characteristics and the tolerances associated with the grades or classes of sensors. The interchangeability tolerances are the target that manufacturers shoot for when building the sensing elements.
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-4
-3
-2
-1
0
1
2
3
4
-300 -200 -100 0 100 200 300 400 500 600 700 800
Temperature (°C)
Tole
ranc
e (±
°C)
IEC Class B
ASTM Grade B
IEC Class A ASTM Grade A
ASTM Grade A
IEC Class A
ASTM Grade B
IEC Class B
Interchangeability
Note that the ASTM standard has slightly tighter tolerances for the two grades of sensors. All RTDs are built with the tightest tolerance at 0°C and as the temperature diverges from 0°C the tolerance increases. The vertical line on the graph represents 0°C and the tolerance on the y axis is expressed in ± °C from nominal.
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Standard Tolerance Defining Equation¹ASTM E1137 Grade A ± [ .13 + 0.0017 | t | ]ASTM E1137 Grade B ± [ .25 + 0.0042 | t | ]IEC 607512 Class AA2 ± [ .1 + 0.0017 | t | ]IEC 60751 Class A ± [ .15 + 0.002 | t | ]IEC 60751 Class B ± [ .3 + 0.005 | t | ]IEC 607512 Class C2 ± [ .6 + 0.01 | t | ]
Note 1: | t | = absolute value of temperature of interest in °CNote 2: These tolerance classes are included in a pending change to
the IEC 60751 standard.
Interchangeability
These equations can be used to calculate the interchangeability at any temperature. Note that the temperature t is an absolute value in °C. The resultant is the interchangeability in ± °C.
© Burns Engineering Temperature Basics
RTDs
AdvantagesVery stable outputLinear and predictableEasy to verify and recalibrateHigh accuracy No special wires required for installation
DisadvantagesMore limited temperature range [-200°C to 500°C]High initial price Slower response time than a thermocoupleLess durable than a thermocouple
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RTD or Thermocouple?Lead wires
• RTD has two, three, or four leads per sensing element• TC has two leads per junction• RTDs typically have red, white, green or black leads (not defined by
the standards)• TC colors match thermocouple type – red (common), yellow, purple,
blue, whiteResistance check
• RTD will have about 109 ohms between leads• TC typically less than 1 ohm
Continuity check• TC grounded junction has path from leads to case
Magnet test• RTD leads are not magnetic – usually copper• TC type J has one iron lead which is highly magnetic
Identification
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How do we decide which technology to use?Thermocouple
Exhaust gasInjection moldingBearingsRefinery
RTDPharmaceuticalsFuel custody transferChemicalTire /rubber
Selection and Application
Accuracy and stability are almost always preferable characteristics to have in a temperature sensor and for that reason I recommend that an RTD be selected unless the environment or process characteristics dictate another technology. Those factors are discussed on the following slides.
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Factors to considerPlacementProtectionPerformancePriceService life
Selection
There are other factors to consider other than these but for most applications these will get you the measurement and service life from the sensor that you desire.
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Two optionsSurface mountImmersion
Placement
For a pipe there are two options, surface mounted or immersion. The two parts on the left are just two of a wide variety of surface mount sensors available and the two on the right are examples of the two most common styles of immersion sensors.
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Surface mount
Placement
Installation of a surface mount sensor can be accomplished with a hose clamp, tape, or an adhesive.
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Placement
A few additional styles of surface mount sensors. Whether RTD or thermocouple they almost all look alike but are very different inside.
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Surface mount - positivesEasy installationNo flow obstructionLow cost
Surface mount - negativesRequires insulation for best accuracyMinimal protection from ambient conditionsDifficult to calibrateMeasures pipe surface
Placement
Installation is very easy to do and is low cost. Accuracy suffers though and measurement accuracy requirements may not be achieved.
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Immersion
Placement
An immersion sensor overcomes the negatives of the surface mount and in most cases dramatically improves the measurement accuracy.
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Immersion (no thermowell)Fast responseLow costShort immersion
LimitationsDurabilityMaintenanceStrength
Placement
Direct immersion of a small diameter sensor gives an accurate measurement at low cost. It is not always possible or desirable though because of maintenance or durability considerations.
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Process connection
Protection
These are just a few of the several styles available. Any piping connection either has been or could be adapted to a thermowell process connection.
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Connection headsAttach extension wiresProtect sensor from ambient conditions
Protection
A connection head is the best method and provides a convenient place to attach lead wires or to house a local transmitter.
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Protection
Numerous styles and materials from plastic to aluminum are available. Some carry ratings for use in hazardous atmospheres.
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Transmitters
Protection
Heads provide protection for transmitters and local indicators.
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Hazardous atmosphere
Protection
Hazardous atmospheres require an RTD and connection head assembly that carry an appropriate rating. A word of caution -- just the addition of a rated head to any sensor does not make the whole assembly rated. The entire assembly must be tagged and identified as having the desired rating.
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OptionsNippleNipple - couplingUnion
• Calibration• Replacement
Protection
Head is attached to the thermowell and sensor typically with a pipe nipple. The most versatile is the union connection. It allows easy removal of the sensor from a thermowell.
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Consideration Thermocouple RTD
Accuracy at 32°F Standard limits: ± 4°F*Special limits: ± 2°F*
Grade B: ± 0.54°F (± .3°C)Grade A: ± 0.27°F (± .15°C)
Calibration Limited to in-situ calibration - Easily recalibrated for longer service life and traceability- Matching transmitter improves performance
Stability Dependent on wire homogeneity and process conditions
Average drift is ± 0.06°C after 1000 hours at 400°C.
Repeatability Highly dependent on process characteristics
Less than ± 0.04% change in ice point resistance after 10 cycles -200 to 500°C.
Performance
*Types J and K. Types T and E special limits are ± 0.9°F
Here are some general performance specifications for RTDs and thermocouples. As you can see the RTD has quite a large accuracy advantage over the thermocouple.
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Cost of inaccuracy
Performance
• Process Fluid: Water• Flow Rate: 25 GPM• Control Temperature: 100 °F• Energy Cost: 2.9¢ / KW-hour
Annual Cost of Energy Per °F Error
$923 / year
High accuracy insures product quality and efficient use of your energy dollar.
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Time response
Performance
Stepped
Tapered
Direct Immersion RTDs
1/4” - 1/8”
1/4”
1/2” - 1/4”
DIAMETERSTIME RESPONSE
2.5 seconds
4 to 6 seconds
22 seconds
26 seconds
Thermowells
6 to 8 seconds
A tapered thermowell will have a 3 to 4 times slower response than the ¼” diameter direct immersion sensor. This can be a big factor in accuracy for processes that are changing temperature rapidly. The sensor needs to be fast enough to keep up with the process.
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Time response – surface mount more dependent on housing style and mounting surface than immersion types
Performance
Surface Mount RTDs
Ranges from 8 to 67 seconds
ThermowellsSurface Mount TCs
8 to 67 seconds dependingon junction type
Surface mount sensors will have a slower time response that an immersion style. They are affected more by the surface they are mounted to rather than by the sensor design.
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TransmittersConverts resistance or voltage to a
variable current of 4 to 20 maLead wire > 250 feet (+0.16°F/100 ft)Accuracy
MatchingLead wire
Robust signalRFI/EMILocal display
Performance
Adding a transmitter can improve accuracy when a long run of lead wire is required. They also provide a more robust signal that is less susceptible to interference from electro-magnetic or radio frequency interference.
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Selection Guide
Accuracy/Stability
Mod. Temp (-50 to 200°C)
High Temp (-200 to 500°C)
Higher Temp (over 500°C)
Time Response (< 6 sec.)
Long-term Stability
High Vibration (g level)
Extra High Vibration, Shock
Critical Temp. Application
Situation
XXX
XX
X
X
Thermocouple Wire Wound RTD Thin Film RTD
XX
X
XX
X
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• Calibration is performed to verify sensor/instrument performance.
• Calibration is the process used to insure that a sensor/instrument maintains specification over time and changing ambient conditions.
• Calibration is the process used to maintain traceability of parameters with reference to national/international standards.
What is Calibration?
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Initial CalibrationNew plant or equipment commissioningVerify vendor data – shipping and installation damage
• Insure accuracy of measurementsRecording data
Ongoing CalibrationMinimize and control random and systematic errorsCompare and complement the quality and reliability of measurements by comparison to international standards
• Provide traceability to national standards, (e.g. NIST) • Meet Regulatory Requirements (FDA, NRC)
Quality System requirements• Ensure consistent product quality • Safety
Cost• Poor accuracy = wasted $$
Why
Calibration should be performed when starting up a new facility or if a new piece of equipment is added. This insures that the instruments have not been damaged during shipping or installation and provides a baseline for comparison to subsequent calibrations.
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RTD has driftedHow do you know?
FrequencyProcess dictates the calibration cycleProbe drift
• Vibration• Shock• Temperature• Cycling
Product valueComplete 5 cycles w/o shift then double the interval
When
When? Is one of the most frequently asked questions about calibration. There is no generic answer for when; it all depends on the process and comfort level of the invested parties. Process conditions that affect the probe drift rate and the product value are the two main considerations. Consult with the manufacturer(s) of your system and they should be able to help you estimate the long term accuracy of their equipment based on your process conditions. After that it’s up to you to pick a frequency that meets your comfort level and that of any 3rd party watch-dogs that oversee your production facility. You may decide because of product value that a calibration is performed before and after each batch. Then if you desire, after 5 cycles are completed without a significant shift, the calibration cycle could be doubled.
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• ITS-90 = International Temperature Scale of 1990• IPTS-68 = International Practical Temperature Scale• TPW – triple point of water 0.01°C or 273.16 K• R0 = resistance at 0°C• SPRT = standard platinum resistance thermometer• Dewar = insulated container• IR = insulation resistance• K – Kelvin temperature scale (used for ITS-90)• mK or milliK = .001 K• NIST – National Institute of Standards and Technology• NVLAP – National Voluntary Laboratory Accreditation Program• A2LA – American Association for Laboratory Accreditation
Terminology
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Evolution of standard temperature scalesIPTS-27 IPTS-48 IPTS-68 ITS-90
ITS-90 (International Temperature Scale)Released in 1990The official international scaleIn better agreement with thermodynamic values than the IPTS-68
ITS-90 vs. IPTS-68 ITS-90
• Uses TPW• Most accurate • Complex equations
IPTS-68• Simpler equations• Less accurate• Callendar-Van Dusen equation
How - Temperature Scales
Beginning in 1927 the International Bureau of Weights and Measures decided that a better standard was required for temperature and the International Practical Temperature Scale was born. Since then about every 20 years the scale has been refined to improve accuracy. In 1990 the name changed to International Temperature Scale and the equations defining the R vs. T relationship became more accurate.
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Factory Calibration OptionsMatched Calibration
• Matched with other probes• Matched to a transmitter
Multiple Point Calibration • -196, -38, 0, 100, 200, 300, and 420 °C
Matched to a Temperature Readout (meters)
How - Calibration Options
Calibrating an RTD and adjusting the readout or transmitter accordingly is a cost effective method to improve measurement system accuracy. This eliminates most of the RTD interchangeability tolerance and can also minimize other instrument errors inherent in the system.
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Ice Bath• Easy to Produce• Uncertainty ±.002°C
Calibration
The ice bath is the easiest and most accurate method of checking an RTD. Addition of a stirring motor insures even temperature throughout the insulated Dewar. Ice is made from pure water, crushed, and packed into the Dewar. Purified water is added to fill in the gaps. Too much water and the ice will float which is not desirable.
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Triple-Point-of-Water Cell
Calibration
The triple point of water (TPW) cell may be the most commonly used type of fixed point and is used in ITS-90 calibrations. Water can exist as a solid, liquid, and vapor at 0.01°C and this device creates this temperature.
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Most common methodComparison of unknown to known sensorsMultiple sensors can be calibrated at the same timeEquipment
Meter, Standard PRT, Recorder, etc. (system) • All add to uncertainty level
The standard PRT should have an accuracy at least four times greater than the unit under test
Comparison Calibration
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More practical and less expensive than fixed point temperature calibration
LaboratoryTypical uncertainty: 0.001°C to 0.01°CVery high accuracy reference resistance bridge, standard PRT, calibration baths, etc.
• Uses some fixed point temperaturesField
Typical uncertainty: 0.05 to 0.5°CAccurate reference meters, secondary PRTs, baths or dry-wellsInstruments are field compatible
Comparison Calibration
Comparison calibrations can be performed in a laboratory or in the field. High accuracy can be obtained with careful selection of equipment. Durability is as important as accuracy when used for field calibrations. Equipment that cannot stand up to field use will drift quickly and not give the expected measurement uncertainties.
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SpecificationsVery fragileUse mainly in laboratory environmentsHighest accuracy, high repeatability, low drift-328 to 1983°F (-200 to 1084°C), accurate to ±.0018°F (±.001°C)
Standard PRTs
This is NOT the type of device to use for field calibrations. It is extremely fragile and very expensive, about $10k with calibration.
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Anatomy of an SPRT
Photo of an SPRT element inside its quartz sheath.
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Anatomy of an SPRT
A little closer look.
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Oooops
-$10K
Anatomy of an SPRT
Yes, the quartz sheath does break very easily and is one of the few things duct tape won’t fix!
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Corroded terminals can cause high resistance in the leads
3-wire circuits are susceptible – accuracy depends on each conductor having exactly the same resistance
Terminals clean and tightTerminal block clean and dry, secured to headWires are tinned, or terminated with spade lugsConnector pins connect firmly and are cleanUse gold plated pins in a high quality connector
4-wire circuits also compensate for some poor maintenanceCompensate fully for all lead wire resistance in the circuit
Preventive Maintenance
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The good and bad
Preventive Maintenance
The connection head shown in the lower right corner had a lot of dust in it that caused some electrical leakage between the terminals resulting in a bad temperature reading.
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RTDFan blowing on sensor locationRadiated heating or cooling from nearby equipmentInsulation covering the external portions of sensorSunlight - solar heating right where you don’t want it
ThermowellBore cleaningHeat transfer compoundProduct buildup on wetted portionCracks in flange weld or leaky gasketRTD bottoms in well and spring loads
ControllerRTD temperature coefficient is set correctly in controller3 or 4 wire circuit connected correctly with correct wire type
TransmitterWires connected securelyCheck output at zero and span
Preventive Maintenance
Something as innocuous as a fan blowing can cause a measurement error if it is directed on the external portions of the temperature assembly.
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RTDCheck insulation resistance 50 VDC > 100 megohms at 25°CCheck ice point resistance 100 ±0.12 ohms or ±0.06 ohmsRTD and transmitter matchingFrequency of checks – process dictates the intervals
Connection headWire insulationShieldingGeneral condition, corrosion, discoloration, threads, cracksCorrosion on terminal connectionsWater inside the connection headConduit seal for hazardous atmospheres
TransmitterWires connected securelyCheck output at zero and span
Preventive Maintenance
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RTDChoose the correct temperature coefficient. Most common is a .00385 conforming to IEC 60751 or ASTM E1137Interchangeability – choose class A for better accuracy3 or 4 wire – 4 wire provides better accuracyChoose correct length to match thermowell or provide significant immersion to avoid stem conduction – for a direct immersion probe minimum immersion = 10x probe diameter + sensitive length
Thermowell selectionCorrosionErosionWake frequency and strengthTime responseImmersion length
Replacement Checklist
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There are many types of temperature sensors. RTD and thermocouple are the most widely used in industry.RTD is the most accurate and TC is the most durableWhen selecting a sensor remember the 4 Ps
PerformancePlacementProtectionPrice
Periodic calibration is necessary to maintain measurement accuracy
Summary
© Burns Engineering Temperature Basics
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