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Supporting Information

Mild Catalytic Pyrolysis of Biomass for Production of Transportation Fuels: A Techno-Economic Analysis

Rajeeva Thilakaratne1, 2, Tristan Brown3, Yihua Li4, Guiping Hu4, Robert Brown1, 2, 3

1Department of Mechanical Engineering 2Center for Sustainable Environmental Engineering

3Bioeconomy Institute 4Industrial and Manufacturing Systems Engineering

Iowa State University Ames, IA 50011

Contents

a) Snapshot of the Chemcad model areas and the details of the stream properties and composition

Figure S-1 Pretreatment and pyrolysis area snapshot of the Chemcad model

Figure S-2 Upgrading area snapshot of the Chemcad model

Figure S-3 Hydrogen generation area snaphot of the Chemcad model

Figure S-4 Utilities area snapshot of the Chemcad model

Table S-1 Streams composition and property data of the Chemcad model

b) Snapshots of the heat exchanger network design

Table S-2 Process heat exchangers

Table S-3 Targeted utility streams

Table S-4 Heat exchanger network design

c) Power consumption of the process

Table S-5 Major power consumption breakdown

d) Detailed capital and operational cost breakdown

Table S-6 Operation cost break down

Table S-7 Capital cost break down

Table S-8 Equipment cost source

Electronic Supplementary Material (ESI) for Green ChemistryThis journal is © The Royal Society of Chemistry 2013

Figure S-1. Pretreatment and pyrolysis area

Hammer Mill

Screw feed

100 101

105

106 107

114

115

116

117

118Screw feed

AirPreheater

Air

FlashSeperator

CatalyticPyrolyzer

Dryer

Regenerator

103

Aqueous Waste

Flash Vent

Pyrolysis Offgas toCombustor

AirCompressor

Cyclone 1

Cyclone 2

Bio OilCondensor

ESP

Ash

Screen

Flue GasHeat Recovery

WoodyBiomass

Dryer Exhaust Combustion Air

Bio Oil

Pyrolysis Offgas to H2 Plant

109

111

112

120

122

124

125

127

129

130

131

132133134

135

136

138

139140

142

143

144

146

110

Screw feed

Fludizing Gas Compressor

113

141

102

104108

Global K value model – NRTL

Global enthalpy model - SRK


Figure S-2. Upgrading area

LP Flash

HP Flash

201

202

204

205

210

214 215

217 218

219 220

221 222

223

208

H2 Compressor 1

H2 to Desulfurification

Hydrotreater 1 Preheater

Hydrotreater 1

Upgraded Oil Cooler

Debutanizer

PSA -Hydroggen Recovery

Bio OIl Pump

H2 RecycleCompressor 1

H2 Recycle Cooler

211

216

209

Hydrotreater 2

Hydrotreater 2 Preheater

H2 RecycleCompressor 2

H2 Compressor 3

H2 Compressor 2

H2 Compressor Cooler 1

H2 Compressor Cooler 2

Fractionator

Aqueous Waste

Fractionator Preheater

Debutanizer Preheater

DieselCooler 1

Gasoline Cooler 1

Bio Oil

Upgrading Offgas to H2 Plant

H2

200

207

213

224

226

227

228229230231

232

235 236 237

238

206

233 234

239




Figure S-3. Hydrogen generation area

H2 PlantProcess water Pump

Offgas Compressor Cooler 1

Offgas Compressor 1

Offgas Compressor 2

Offgas Compressor 3

H2 PlantWater Preheater

Feed GasPreheater

Desulfurifier

Process Water

Prere formerReformerH2

Water Gas Shift

Gas Cooler

Aqueous Waste

FlashSeperator

PSA -H2 Plant

Offgas

Pyrolysis Offgas

Upgrading Offgas

H2 toUpgrading

300

301

302 303 304 305

307

308

309

310

311312

313

314316

320

322

323

325

327 318

317 315

Offgas Compressor Cooler 2

306

319




Figure S-4. Utility area

400

401 402

405

407

408

409

410

411

412

413

418

419

420 421

422600

601

Upgrading Aqueous Waste

Hydrogen Plant Aqueous Waste

Boiler Blowdown

Cooling Plant Blowdown

416

To Waste Water Treatment

Boiler Water Pump

Boiler Preheater BoilerCondensor

TurbineStage 1

TurbineStage 3

Turbine Stage 2

Condensate Pump 1

HP SteamHeat Exchangers

Condensate Pump 2

Makeup Water Tank Deareator

BoilerMakeup Water

Condenstate Tank

BoilerBlow Down

Pyrolysis Aqueous Waste

501

502

503

504

505

507

508

Boiler

Blow Down

Windage

Cooling PlantMakeup Water

Cooling PlantWater Pump

CoolingHeat Exchangers

Cooling Tower

500

602

603

604

605

606

607417

Combustion Air

Pyrolysis Offgas

H2 Plant Offgas

Pyrolysis Flash Vent

Dryer Exhaust

Gas Combustor Heat Recovery

Reformer HE

Gas Combustor

Flue Gas

608

609

423

614

615

403

404

610

611

612

613

Cogeneration Offgas combustion

Aqueous waste



Cooling plant


Table S-1. Streams composition and property data (Continued…)

Stream No. 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119Temp C 25.0 25.0 104.4 99.6 99.6 99.6 99.6 99.6 584.3 499.5 499.5 499.5 499.5 499.5 38.0 38.0 38.0 38.0 37.8 37.8Pres bar 1.0 1.4 1.2 1.0 1.0 1.0 1.0 1.4 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2Enth MJ/h -963940.0 -963940.0 -547300.0 -547330.0 -547330.0 -32.7 -547490.0 -547490.0 -2747300.0 -2747300.0 -2077100.0 -670180.0 -6630.3 -663550.0 -822450.0 -502140.0 -320310.0 -27480.0 -529620.0 -478170.0Vapor mass frac. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1.0 1.0 0.0 1.0 1.0 1.0 0.5 0.0 1.0 0.0 0.0 0.0Total kg/h 118640.0 118640.0 92592.2 92597.8 92597.8 5.5 92592.2 92592.2 585092.2 585095.0 477833.3 107261.3 3141.2 104120.1 104120.1 48685.0 55435.1 3030.9 51716.0 31471.7Flow rates in kg/hWater 35306.9 35306.9 9259.2 9259.8 9259.8 0.6 9259.2 9259.2 9259.2 31037.5 0 31037.5 0 31037.5 31037.5 29316.6 1720.9 1720.9 31037.5 29735Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 164.3 265.1 0 265.1 0 265.1 264.9 0 264.9 0 0 0Carbon Dioxide 0 0 0 0 0 0 0 0 15343.1 24750.6 0 24750.6 0 24750.6 24750.7 10.9 24739.8 0 10.9 9.3Carbon Monoxide 0 0 0 0 0 0 0 0 11124.6 17937.9 0 17937.9 0 17937.9 17938 0.3 17937.7 0 0.3 0.1Methane 0 0 0 0 0 0 0 0 2270.3 3660.8 0 3660.8 0 3660.8 3660.8 0.1 3660.7 0 0.1 0Ethylene 0 0 0 0 0 0 0 0 3597.7 5801.4 0 5801.4 0 5801.4 5801.4 0.4 5801 0 0.4 0.3Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 221.7 0 221.7 0 221.7 221.7 190.8 30.9 30.9 221.7 81.2HydroxyAcetone 0 0 0 0 0 0 0 0 0 2217.5 0 2217.5 0 2217.5 2217.5 2197.1 20.4 20.4 2217.5 973.52-5-Xylenol 0 0 0 0 0 0 0 0 0 5122.5 0 5122.5 0 5122.5 5122.5 5120 2.4 2.4 5122.5 69.3syringol 0 0 0 0 0 0 0 0 0 8249.1 0 8249.1 0 8249.1 8249.1 8249 0.2 0.2 8249.1 559.1N-Heptane 0 0 0 0 0 0 0 0 0 111.1 0 111.1 0 111.1 111.1 0.6 110.5 110.5 111.1 0.6Levoglucosan 0 0 0 0 0 0 0 0 0 44.2 0 44.2 0 44.2 44.2 44.2 0 0 44.2 39.1Toluene 0 0 0 0 0 0 0 0 0 1175 0 1175 0 1175 1175 29.8 1145.1 1145.1 1175 42-Methylnaphthal 0 0 0 0 0 0 0 0 0 2644.2 0 2644.2 0 2644.2 2644.2 2643.6 0.6 0.6 2644.2 0.31-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 881.7 0 881.7 0 881.7 881.7 881.7 0 0 881.7 0Hybrid poplar 83333 83333 83333 83338 83338 5 83333 83333 83333 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 17833.3 17833.3 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 460000 460000 460000 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 1691.7 0 1691.7 1691.7 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 1449.5 0 1449.5 1449.5 0 0 0 0 0 0 0



Stream No. 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139Temp C 37.8 37.8 37.8 37.8 37.8 38.0 38.0 38.0 38.0 38.0 38.0 59.9 25.0 69.1 200.0 200.0 200.0 200.0 200.0 200.0Pres bar 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.5 1.0 1.5 1.5 1.5 1.5 1.5 1.5 1.5Enth MJ/h -478170.0 -51451.0 -51451.0 -4.2 -4.2 -297510.0 -55093.0 -55093.0 -57908.0 -57908.0 -184510.0 -183670.0 -103.7 19932.0 80038.0 32730.0 20826.0 11903.0 11903.0 47308.0Vapor mass frac. 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Total kg/h 31471.7 20243.5 20243.5 0.7 0.7 52404.2 9704.2 9704.2 10200.0 10200.0 32500.0 32500.0 448000.1 448000.1 448000.1 183200.0 116573.2 66626.8 66626.8 264800.1Flow rates in kg/hWater 29735 1302.5 1302.5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 352128 352128 352128 143995.2 91626.6 52368.6 52368.6 208133Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 95872 95872 95872 39204.8 24946.7 14258.1 14258.1 56667.2Hydrogen 0 0 0 0 0 264.9 49.1 49.1 51.6 51.6 164.3 164.3 0 0 0 0 0 0 0 0Carbon Dioxide 9.3 1.2 1.2 0.4 0.4 24739.8 4581.3 4581.3 4815.4 4815.4 15343.1 15343.1 0 0 0 0 0 0 0 0Carbon Monoxide 0.1 0 0 0.1 0.1 17937.7 3321.7 3321.7 3491.4 3491.4 11124.6 11124.6 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 3660.7 677.9 677.9 712.5 712.5 2270.3 2270.3 0 0 0 0 0 0 0 0Ethylene 0.3 0 0 0.1 0.1 5801 1074.2 1074.2 1129.1 1129.1 3597.7 3597.7 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 81.2 140.4 140.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 973.5 1244 1244 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 69.3 5053.2 5053.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 559.1 7690 7690 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0.6 110.5 110.5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 39.1 5.1 5.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 4 1171 1171 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0.3 2643.9 2643.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 881.7 881.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 140 141 142 143 144 145 146 200 201 202 204 205 206 207 208 209 210 211 212 213Temp C 396.2 675.0 675.0 325.0 289.1 117.2 117.2 37.8 40.1 62.6 200.0 200.0 400.0 400.0 40.0 40.0 40.0 38.4 38.4 38.4Pres bar 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 1.5 1.5 1.5Enth MJ/h -2029800.0 -2016100.0 -382770.0 -493650.0 -472830.0 -889470.0 -889470.0 -51451.0 -51190.0 -48882.0 -36466.0 -64508.0 -43821.0 -73073.0 -107410.0 -8635.9 -98775.0 -192.5 -77173.0 -77173.0Vapor mass frac. 1.0 0.0 1.0 1.0 1.0 1.0 1.0 0.0 0.0 0.1 0.2 0.2 0.9 0.9 0.1 1.0 0.0 1.0 0.0 0.0Total kg/h 742634.0 460000.0 282633.2 282633.2 399206.4 425254.1 425254.1 20243.6 20243.6 22655.6 22655.6 22656.1 22656.1 22656.1 22656.1 2658.0 19998.1 37.1 4907.5 4907.5Flow rates in kg/hWater 0 0 0 0 0 26047.7 26047.7 1302.5 1302.5 1302.5 1302.5 3092 3092 4875.4 4875.4 5.5 4869.9 1.1 4865.6 4865.6Nitrogen 208133 0 208133 208133 299759.4 299759.4 299759.4 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 56667.2 0 9518 9518 34464.7 34464.7 34464.7 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 2412 2412 1807.7 1807.7 1206.5 1206.5 1205.4 1.1 1.1 0 0Carbon Dioxide 0 0 64982.4 64982.4 64982.4 64982.4 64982.4 1.2 1.2 1.2 1.2 313.7 313.7 624.7 624.7 607.7 16.9 14.6 1.6 1.6Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0 0 300.2 300.2 598.9 598.9 598 0.9 0.9 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 140.4 140.4 140.4 140.4 71.1 71.1 1.7 1.7 0 1.7 0 0.6 0.6HydroxyAcetone 0 0 0 0 0 0 0 1244 1244 1244 1244 636.2 636.2 26.8 26.8 0 26.8 0.2 26.1 26.12-5-Xylenol 0 0 0 0 0 0 0 5053.2 5053.2 5053.2 5053.2 2519.7 2519.7 2.4 2.4 0 2.4 0 0.1 0.1syringol 0 0 0 0 0 0 0 7690 7690 7690 7690 3845 3845 16 16 0 16 0 12.1 12.1N-Heptane 0 0 0 0 0 0 0 110.5 110.5 110.5 110.5 313.6 313.6 515.6 515.6 19.4 496.2 0.5 0 0Levoglucosan 0 0 0 0 0 0 0 5.1 5.1 5.1 5.1 2.6 2.6 0.1 0.1 0 0.1 0 0.1 0.1Toluene 0 0 0 0 0 0 0 1171 1171 1171 1171 583.6 583.6 0.2 0.2 0 0.2 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 2643.9 2643.9 2643.9 2643.9 1317.3 1317.3 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 1467.1 1467.1 2926.2 2926.2 1.5 2924.7 0.8 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 157 157 312.6 312.6 0.1 312.5 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 1467.1 1467.1 2926.2 2926.2 0.5 2925.7 0.3 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 117.2 117.2 233.8 233.8 1 232.8 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 70.2 70.2 139.9 139.9 0 139.9 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 292.3 292.3 583.1 583.1 0 583.1 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 482.6 482.6 962.5 962.5 0 962.5 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 675 675 1346.4 1346.4 0 1346.4 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 589 589 1174.9 1174.9 0 1174.9 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 36.3 36.3 72.4 72.4 0 72.4 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 770.3 770.3 1536.5 1536.5 0 1536.4 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 28.4 28.4 56.6 56.6 0 56.6 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 180.5 180.5 359.9 359.9 0.1 359.8 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 800.2 800.2 1596.1 1596.1 2.5 1593.6 1.4 0.1 0.1N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 22.5 22.5 44.9 44.9 0 44.9 0 0 0Chrysene 0 0 0 0 0 0 0 881.7 881.7 881.7 881.7 439.3 439.3 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 17833.3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 460000 460000 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 90.9 90.9 181.4 181.4 181.1 0.3 0.3 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 81.4 81.4 162.5 162.5 24.2 138.3 10.5 0.8 0.8I-Butane 0 0 0 0 0 0 0 0 0 0 0 86.2 86.2 171.9 171.9 11 160.9 5.5 0.3 0.3Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233Temp C 38.4 100.0 70.0 130.0 210.0 169.5 130.0 221.8 130.0 65.7 40.0 42.4 42.4 40.0 171.2 38.0 150.1 38.0 87.0 175.8Pres bar 1.5 1.5 1.4 1.5 1.5 1.5 1.4 1.6 1.5 1.4 2.0 1.4 1.4 2.0 5.5 5.5 13.3 13.3 13.3 25.0Enth MJ/h -21662.0 -20064.0 -518.8 -18690.0 -12396.0 -11917.0 -15204.0 -2292.3 -3381.1 -711.3 -8870.4 -9581.7 -9581.7 233.2 2292.2 203.1 1963.8 266.4 2230.3 5457.9Vapor mass frac. 0.0 0.0 1.0 0.0 1.0 1.0 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0Total kg/h 15053.4 15053.4 249.2 14804.2 14804.2 9691.2 9691.2 5113.1 5113.1 286.3 1573.1 1859.4 1859.4 1084.9 1084.9 1084.9 1084.9 1407.8 2492.7 2492.7Flow rates in kg/hWater 3.2 3.2 0.1 3.1 3.1 3.1 3.1 0 0 1.2 5.5 6.7 6.7 0 0 0 0 0 0 0Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 1.1 120.5 121.6 121.6 1084.9 1084.9 1084.9 1084.9 1407.8 2492.7 2492.7Carbon Dioxide 0.7 0.7 0.7 0 0 0 0 0 0 15.3 607.7 623 623 0 0 0 0 0 0 0Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0.9 598 598.9 598.9 0 0 0 0 0 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 1.1 1.1 0 1.1 1.1 1 1 0.1 0.1 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0.6 0.6 0 0.6 0.6 0.5 0.5 0 0 0.2 0 0.2 0.2 0 0 0 0 0 0 02-5-Xylenol 2.3 2.3 0 2.3 2.3 1 1 1.4 1.4 0 0 0 0 0 0 0 0 0 0 0syringol 4 4 0 4 4 0 0 4 4 0 0 0 0 0 0 0 0 0 0 0N-Heptane 495.7 495.7 12.3 483.4 483.4 479.4 479.4 4 4 12.8 19.4 32.2 32.2 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0.2 0.2 0 0.2 0.2 0.2 0.2 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 2923.8 2923.8 21.5 2902.3 2902.3 2724 2724 178.3 178.3 22.3 1.5 23.8 23.8 0 0 0 0 0 0 03-3-5-Trimethylh 312.5 312.5 0.3 312.2 312.2 274.7 274.7 37.5 37.5 0.3 0.1 0.4 0.4 0 0 0 0 0 0 0N-Propylcyclohex 2925.4 2925.4 2.2 2923.2 2923.2 2558.1 2558.1 365.1 365.1 2.4 0.5 2.9 2.9 0 0 0 0 0 0 0Mesitylene 232.8 232.8 0 232.8 232.8 198.6 198.6 34.2 34.2 0 1 1 1 0 0 0 0 0 0 0N-ButylCycHexane 139.9 139.9 0 139.9 139.9 106.7 106.7 33.2 33.2 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 583 583 0 583 583 389.5 389.5 193.6 193.6 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 962.4 962.4 0 962.4 962.4 620.6 620.6 341.9 341.9 0 0 0.1 0.1 0 0 0 0 0 0 0N-Tridecane 1346.4 1346.4 0 1346.4 1346.4 15.6 15.6 1330.8 1330.8 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 1174.8 1174.8 0 1174.8 1174.8 320.7 320.7 854.1 854.1 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 72.4 72.4 0 72.4 72.4 0.8 0.8 71.5 71.5 0 0 0 0 0 0 0 0 0 0 0Diphenyl 1536.4 1536.4 0 1536.4 1536.4 0.2 0.2 1536.3 1536.3 0 0 0 0 0 0 0 0 0 0 0Tetralin 56.6 56.6 0 56.6 56.6 28.4 28.4 28.2 28.2 0 0 0 0 0 0 0 0 0 0 01-Nonene 359.8 359.8 0.9 358.9 358.9 327.2 327.2 31.6 31.6 1 0.1 1 1 0 0 0 0 0 0 0MthCyclohexane 1592.2 1592.2 36.6 1555.6 1555.6 1533.3 1533.3 22.3 22.3 37.9 2.5 40.4 40.4 0 0 0 0 0 0 0N-C15-CycloC5 44.9 44.9 0 44.9 44.9 0 0 44.9 44.9 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0.3 181.1 181.4 181.4 0 0 0 0 0 0 0Propane 127.1 127.1 104.1 23 23 23 23 0 0 114.5 24.2 138.7 138.7 0 0 0 0 0 0 0I-Butane 155.1 155.1 70.6 84.6 84.6 84.6 84.6 0 0 76.1 11 87.1 87.1 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 234 235 236 237 238 239 300 301 302 303 304 305 306 307 308 309 310 311 312 313Temp C 35.0 177.9 35.0 88.1 88.1 88.1 38.0 42.4 39.2 181.5 93.3 178.8 110.0 181.9 335.0 88.1 322.8 25.0 25.6 335.0Pres bar 25.0 75.0 75.0 117.0 117.0 117.0 1.2 1.4 1.2 4.8 4.8 10.5 10.5 20.0 20.0 117.0 20.0 1.0 20.0 20.0Enth MJ/h 372.4 5604.3 412.2 2385.4 2308.2 77.2 -57907.0 -9581.9 -67489.0 -64996.0 -66593.0 -65064.0 -66326.0 -65033.0 -61971.0 78.5 -61899.0 -357520.0 -357460.0 -290000.0Vapor mass frac. 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.0 0.0 1.0Total kg/h 2492.7 2492.7 2492.7 2492.7 2412.0 80.7 10200.0 1859.5 12059.4 12059.4 12059.4 12059.4 12059.4 12059.4 12059.4 82.0 12134.6 22518.0 22518.0 22518.0Flow rates in kg/hWater 0 0 0 0 0 0 0 6.7 6.7 6.7 6.7 6.7 6.7 6.7 6.7 0 6.7 22518 22518 22518Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 2492.7 2492.7 2492.7 2492.7 2412 80.7 51.7 121.6 173.3 173.3 173.3 173.3 173.3 173.3 173.3 82 248.5 0 0 0Carbon Dioxide 0 0 0 0 0 0 4815.3 623 5438.4 5438.4 5438.4 5438.4 5438.4 5438.4 5438.4 0 5438.4 0 0 0Carbon Monoxide 0 0 0 0 0 0 3491.4 0 3491.4 3491.4 3491.4 3491.4 3491.4 3491.4 3491.4 0 3491.4 0 0 0Methane 0 0 0 0 0 0 712.5 598.9 1311.4 1311.4 1311.4 1311.4 1311.4 1311.4 1311.4 0 1311.4 0 0 0Ethylene 0 0 0 0 0 0 1129.1 0 1129.1 1129.1 1129.1 1129.1 1129.1 1129.1 1129.1 0 1129.1 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0 0 0 0 0 0 0 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0 0.2 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0 0 0 0 0 0 0 32.2 32.2 32.2 32.2 32.2 32.2 32.2 32.2 0 32.2 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 23.8 23.8 23.8 23.8 23.8 23.8 23.8 23.8 0 23.8 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0 0.4 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 2.9 2.9 2.9 2.9 2.9 2.9 2.9 2.9 0 2.9 0 0 0Mesitylene 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 0 1 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0 0.1 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 0 1 0 0 0MthCyclohexane 0 0 0 0 0 0 0 40.4 40.4 40.4 40.4 40.4 40.4 40.4 40.4 0 40.4 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 181.4 181.4 181.4 181.4 181.4 181.4 181.4 181.4 0 181.4 0 0 0Propane 0 0 0 0 0 0 0 138.7 138.7 138.7 138.7 138.7 138.7 138.7 138.7 0 138.7 0 0 0I-Butane 0 0 0 0 0 0 0 87.1 87.1 87.1 87.1 87.1 87.1 87.1 87.1 0 87.1 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 314 315 316 317 318 319 320 321 322 323 324 325 327 400 401 402 403 404 405 406Temp C 327.2 516.2 857.0 857.0 523.8 567.5 40.0 40.0 40.0 40.0 38.0 38.0 38.0 25.0 102.4 104.1 105.9 170.0 450.0 450.0Pres bar 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 13.3 13.3 13.3 4.0 1.7 1.2 60.0 60.0 59.9 59.9Enth MJ/h -351900.0 -351900.0 -325450.0 -284790.0 -311240.0 -311290.0 -386830.0 -244860.0 -244860.0 -141970.0 -142420.0 -142420.0 266.4 -124610.0 -4054700.0 -4065400.0 -4063400.0 -3991200.0 -3316100.0 -99483.0Vapor mass frac. 1.0 1.0 1.0 1.0 1.0 1.0 0.6 0.0 0.0 1.0 1.0 1.0 1.0 0.0 0.0 0.0 0.0 0.0 1.0 1.0Total kg/h 34652.6 34652.8 34652.8 34652.6 34652.6 34652.7 34652.7 15571.7 15571.7 19081.0 17673.2 17673.2 1407.8 7848.5 260722.1 261529.0 261529.0 261529.0 261526.2 7845.8Flow rates in kg/hWater 22524.7 20262.1 20262.1 17225.4 17225.4 15515 15515 15433.8 15433.8 81.2 81.2 81.2 0 7848.5 260722.1 261529 261529 261529 261526.2 7845.8Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 248.5 312.2 312.2 1373.1 1373.1 1564.4 1564.4 0.3 0.3 1564.2 156.4 156.4 1407.8 0 0 0 0 0 0 0Carbon Dioxide 5438.4 10777 10777 10388.8 10388.8 14567.2 14567.2 72.5 72.5 14494.7 14494.7 14494.7 0 0 0 0 0 0 0 0Carbon Monoxide 3491.4 213.9 213.9 5429.5 5429.5 2770.2 2770.2 0.5 0.5 2769.7 2769.7 2769.7 0 0 0 0 0 0 0 0Methane 1311.4 3063.7 3063.7 171.1 171.1 171.1 171.1 0 0 171 171 171 0 0 0 0 0 0 0 0Ethylene 1129.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 32.2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 23.8 23.8 23.8 64.8 64.8 64.8 64.8 64.6 64.6 0.2 0.2 0.2 0 0 0 0 0 0 0 03-3-5-Trimethylh 0.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 2.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 40.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 181.4 0.1 0.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 138.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 87.1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 407 408 409 410 411 412 413 416 417 418 419 420 421 422 423 500 501 502 503 504Temp C 450.0 450.0 450.0 250.0 450.0 207.6 120.3 120.3 120.3 46.0 46.0 46.1 104.8 104.8 104.8 25.0 29.9 30.1 40.2 30.0Pres bar 59.9 59.9 59.9 59.9 59.9 6.5 2.0 2.0 2.0 0.1 0.1 4.3 1.2 1.2 1.7 1.0 1.0 5.0 5.0 5.0Enth MJ/h -99413.0 -3214400.0 -361370.0 -424350.0 -2850900.0 -2949400.0 -2989500.0 -3988.9 -2985500.0 -3065000.0 -3545200.0 -3543800.0 -6732.9 -3926300.0 -3926100.0 -2846100.0 -218610000.0 -218820000.0 -218230000.0 -218600000.0Vapor mass frac. 1.0 1.0 1.0 0.0 1.0 1.0 1.0 1.0 1.0 0.9 0.0 0.0 1.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0Total kg/h 7840.3 253502.0 28500.0 28500.0 224834.5 224834.5 224834.5 300.0 224534.5 224534.5 224534.5 224454.7 506.3 252628.4 252615.4 179263.0 13786885.0 13800400.0 13800400.0 13786707.0Flow rates in kg/hWater 7840.3 253502 28500 28500 224834.5 224834.5 224834.5 300 224534.5 224534.5 224534.5 224454.7 506.3 252628.4 252615.4 179263 13786885 13800400 13800400 13786707Nitrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Oxygen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hydrogen 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Carbon Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Carbon Monoxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Methane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0HydroxyAcetone 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Heptane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 02-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-ts-35-3C 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 03-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0



Stream No. 505 506 507 508 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615Temp C 30.0 30.0 30.0 30.0 200.0 38.0 38.0 37.8 30.6 1642.3 1947.6 260.0 117.2 143.2 37.8 38.0 450.0 30.0 30.0 31.5Pres bar 5.0 5.0 5.0 5.0 1.5 1.2 13.3 1.2 1.2 1.2 1.2 1.2 1.2 1.2 1.2 13.3 59.9 5.0 5.0 1.2Enth MJ/h -2527200.0 -312350.0 -312350.0 -215760000.0 11903.0 -55093.0 -142350.0 -4.2 -197650.0 -185740.0 -145090.0 -352650.0 -889470.0 -1242100.0 -478170.0 265.4 -99418.0 -276410.0 -276410.0 -1275400.0Vapor mass frac. 0.0 0.0 0.0 0.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.0 1.0 1.0 0.0 0.0 0.0Total kg/h 159385.6 19699.4 19699.4 13607622.0 66626.8 9704.2 17665.0 0.7 27388.0 94014.8 94014.8 94014.8 425254.2 519269.0 31471.7 1402.3 7840.7 17432.3 17432.3 83296.0Flow rates in kg/hWater 159385.6 19699.4 19699.4 13607622 0 0 81.2 0 81 5190.7 5190.7 5190.7 26047.7 31238.4 29734.9 0 7840.7 17432.3 17432.3 80022.2Nitrogen 0 0 0 0 52368.6 0 0 0 0 52368.6 52368.6 52368.6 299759.4 352128.1 0 0 0 0 0 0Oxygen 0 0 0 0 14258.1 0 0 0 0 2152.1 2152.1 2152.1 34464.7 36616.8 0 0 0 0 0 0Hydrogen 0 0 0 0 0 49.1 156.6 0 205 0.5 0.5 0.5 0 0.5 0 1402.3 0 0 0 1402.6Carbon Dioxide 0 0 0 0 0 4581.3 14486.3 0.4 19094.2 34216.1 34216.1 34216.1 64982.4 99198.5 9.3 0 0 0 0 82Carbon Monoxide 0 0 0 0 0 3321.7 2769.4 0.1 6086.2 86.7 86.7 86.7 0 86.7 0.1 0 0 0 0 0.6Methane 0 0 0 0 0 677.9 171.3 0 847.2 0 0 0 0 0 0 0 0 0 0 0.1Ethylene 0 0 0 0 0 1074.2 0 0.1 1074.3 0 0 0 0 0 0.3 0 0 0 0 0.3Acetic Acid 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Furfural 0 0 0 0 0 0 0 0 0 0 0 0 0 0 81.2 0 0 0 0 81.2HydroxyAcetone 0 0 0 0 0 0 0 0 0 0 0 0 0 0 973.5 0 0 0 0 973.52-5-Xylenol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 69.3 0 0 0 0 69.3syringol 0 0 0 0 0 0 0 0 0 0 0 0 0 0 559.1 0 0 0 0 559.1N-Heptane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.6 0 0 0 0 0.6Levoglucosan 0 0 0 0 0 0 0 0 0 0 0 0 0 0 39.1 0 0 0 0 39.1Toluene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 42-Methylnaphthal 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.3 0 0 0 0 0.31-ts-35-3C 0 0 0 0 0 0 0.2 0 0.2 0 0 0 0 0 0 0 0 0 0 61.23-3-5-Trimethylh 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Propylcyclohex 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Mesitylene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-ButylCycHexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-DiC1-3C2-Bz 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Cis-Decalin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-Tridecane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-2-4-triethylbe 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-1-Bicyclohexyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Diphenyl 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Tetralin 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 01-Nonene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0MthCyclohexane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0N-C15-CycloC5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Chrysene 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Hybrid poplar 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Char new 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Heat carrier 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ash 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Ethane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Propane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0I-Butane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Pentane 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Zeolite 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0Nitrogen Dioxide 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0


Table S-1. Process heat exchangers

Table S-2. Targeted utilities


Table S-3. Heat exchanger network design


Table S-2. Major power consumption breakdown

Major Power Consumption by Area MW Pretreatment Covered in the feedstock cost Pyrolysis Screw Feed Air Compressor Fluidizing Gas Compressor

0.73 5.57 0.23

Upgrading Bio Oil Pump H2 Compressors H2 Recycle Compressors

0.07 2.88 1.06

H2 Generation Offgas Compressors Feed Water Pump

1.45 0.01

Cogeneration Turbine power generation Feed Water Pump Condensate Pumps

48.05 0.66 0.03

Cooling Plant 1.70 Total -33.73

Table S-6. Operational cost break down

$/gal product

$ million/year

Dry Biomass 1.65 63.4 Catalysts & Chemicals 0.17 6.5 Waste Disposal 0.07 2.9 Electricity and other utilities -0.41 -15.6 Fixed Costs 0.55 21.2 Capital Depreciation 0.50 19.2 Average Income Tax 0.28 10.9 Average Return on Investment 0.87 33.7 Total 3.69 142.1


Table S-7. Capital cost break down

Equipment Number

Number Required Equipment Name

Max size Scaling Stream

Scaling Stream Flow ,

tpdNew Stream

Flowstream flow

unitsSize Ratio

Original Equip Cost (per unit)

Base Year

COST BASIS:

installed (i) or bare (b)

Total Original Equip Cost (Req'd & Spare) in Base

YearScaling

Ex ponentScaled Cost in

Base Year Installation FactorInstalled Cost in

Base Year Installed Cost in 2011$Scaled Uninstalled

Cost in 2011$ source

CE Index base year

CE Index 2011

A100 Pretreatment & Pyrolysis Cost included in feedstock handling1 Feedstock Handling Equipment Cost included in feedstock handling1 Dryer Cost included in feedstock handling1 Hammer Mill Cost included in feedstock handling1 Hammer Mill Screens Cost included in feedstock handling1 Pyrolyser Feed Screw kg/hr 83,333 83,333 kg/hr 1.00 $162,500 2010 b $162,500 0.6 $162,500 4.28 $695,500 $739,075 $172,681 3 550.8 585.31 Catalytic Pyrolyzer BPSD 60,000 17,122 BPSD 0.29 $22,700,000 2001 i $22,700,000 0.6 $10,697,143 4.28 $10,697,143 $15,879,115 $3,710,074 6 394.3 585.31 Regenerator BPSD 60,000 17,122 BPSD 0.29 $50,000,000 2001 i $50,000,000 0.6 $23,561,989 4.28 $23,561,989 $34,976,024 $8,171,968 6 394.3 585.31 Cyclone Seperators Cost included in catalytic pyrolyzer1 Bio Oil Condensor Cost Included in heat exchanger 1 Condensor Flash Cost Included in heat exchanger 1 Electrostatic Precipitator kg/hr 64,795 96,181 kg/hr 1.48 $883,048 2010 b $883,048 0.6 $1,119,214 4.28 $4,790,234 $5,090,355 $1,189,335 3 550.8 585.31 Air Compressor $3,902,200 2010 b $3,902,200 0.6 $3,902,200 4.28 $16,701,416 $17,747,804 $4,146,683 1 550.8 585.31 Air Preheater Cost Included in heat exchanger 1 Fluidizing Gas Compressor $592,667 2010 b $592,667 0.6 $592,667 4.28 $2,536,615 $2,695,540 $629,799 1 550.8 585.31 Flash Phase Seperator $25,823 2010 b $25,823 0.6 $25,823 4.28 $110,522 $138,167 $32,282 2 468.2 585.3

A100 $78,266,238 $40,061,536 $59,093,420 $77,266,081 $18,052,823Equiment contingency 0% $0 $0

$77,266,081 $18,052,823

A200 Hydroprocessing1 Hydrotreater 1 BPSD 50,000 2,867 BPSD 0.06 $100,000,000 2007 i $100,000,000 0.6 $17,991,593 4.28 $17,991,593 $18,301,430 $4,276,035 2 575.4 585.3 Cost Included in heat exchanger 1 Hydrotreater 2 Preheater1 Hydrotreater 2 BPSD 50,000 2,867 BPSD 0.06 $175,000,000 2002 i $175,000,000 0.6 $31,485,287 4.28 $31,485,287 $32,027,503 $7,483,061 2 575.4 585.3 Cost Included in heat exchanger 1 Hydrotreater 1 Preheater Cost Included in heat exchanger 1 Bio Oil Pump Pump $11,414 2010 b $11,414 0.6 $11,414 4.28 $48,850 $51,911 $12,129 1 550.8 585.31 Hydrogen Recycle Compressor1 $929,196 2010 b $929,196 0.6 $929,196 4.28 $3,976,959 $4,226,126 $987,413 1 550.8 585.31 Hydrogen Recycle Compressor2 $842,118 2010 b $842,118 0.6 $842,118 5.28 $4,446,383 $4,724,961 $894,879 1 550.8 585.31 H2 Compressor 1 $1,211,410 2010 b $1,211,410 0.6 $1,211,410 4.28 $5,184,835 $5,509,679 $1,287,308 1 550.8 585.31 H2 Comp. Cooler 1 Cost Included in heat exchanger 1 H2 Compressor 2 $1,637,310 2010 b $1,637,310 0.6 $1,637,310 4.28 $7,007,687 $7,446,737 $1,739,892 1 550.8 585.31 H2 Comp. Cooler 2 Cost Included in heat exchanger 1 H2 Compressor 3 $886,513 2010 b $886,513 0.6 $886,513 4.28 $3,794,276 $4,031,997 $942,055 1 550.8 585.31 Fractionator $86,445 2010 b $86,445 0.6 $86,445 4.28 $369,985 $549,216 $128,321 6 394.3 585.31 Debutanizer $184,437 2010 b $184,437 0.6 $184,437 4.28 $789,390 $986,838 $230,570 2 468.2 585.31 PSA - Hydrogen Recovery H2 MMscfd 10 10.23 H2 MMscfd 1.02 $1,750,000 2004 i $1,750,000 0.6 $1,773,624 4.28 $1,773,624 $2,337,051 $546,040 2 444.2 585.31 HT Output Cooler Cost Included in heat exchanger 1 HP Flash $33,794 2010 b $33,794 0.6 $33,794 4.28 $144,640 $180,818 $42,247 2 468.2 585.31 LP Flash $14,971 2010 b $14,971 0.6 $14,971 4.28 $64,074 $80,101 $18,715 2 468.2 585.31 Fractionator Reboiler Cost Included in heat exchanger 1 Fractionator Condensor Cost Included in heat exchanger 1 Fractionation Preheater Cost Included in heat exchanger


$137,660,630 $18,588,665

A300 Hydrogen Generation1 Hygrogen Plant H2 MMscfd 25 13.141 H2 MMscfd 0.53 $94,527,826 2007 i $94,527,826 0.6 $64,264,734 4.28 $64,264,734 $71,592,564 $16,727,235 6 525.4 585.31 Water Gas Shift Reactor Cost Included in Hydrogen Plant1 Reformer Output Cooler Cost Included in Hydrogen Plant1 H2 Reformer Cost Included in Hydrogen Plant1 H2 Reformer Heater Cost Included in Hydrogen Plant1 Reformer Feed Heater Cost Included in Hydrogen Plant1 Water Gas Shift Output Cooler Cost Included in Hydrogen Plant1 Process Water Pump $6,231 2010 b $6,231 0.6 $6,231 4.28 $26,667 $28,337 $6,621 1 550.8 585.31 Process Water Heater Cost Included in heat exchanger 1 PSA - Hydrogen Plant Cost Included in Hydrogen Plant1 Flash Seperator Cost Included in Hydrogen Plant1 Off Gas Compressor 1 $1,041,010 2010 b $1,041,010 0.6 $1,041,010 4.28 $4,455,523 $4,734,673 $1,106,232 1 550.8 585.31 Off Gas Comp. intercooer 1 Cost Included in heat exchanger 1 Off Gas Compressor 2 $768,605 2010 b $768,605 0.6 $768,605 4.28 $3,289,629 $3,495,733 $816,760 1 550.8 585.31 Off Gas Comp. intercooer 2 Cost Included in heat exchanger 1 Off Gas Compressor 3 $691,568 2010 b $691,568 0.6 $691,568 4.28 $2,959,911 $3,145,357 $734,897 1 550.8 585.31 Off Gas Comp. intercooer 3 Cost Included in heat exchanger


$82,996,665 $19,391,744


Table S-7. Capital cost break down (Continued…)

A400 Co-generation1 Condensate Pump 1 Cost Included in Boiler1 Condensate Pump 2 Cost Included in Boiler1 Boiler Feed Water Pump Cost Included in Boiler1 Deaereator kg/hr 238,686 260,300 kg/hr 1.09 $305,000 2010 b $305,000 0.6 $321,283 4.28 $1,375,093 $1,461,246 $341,413 5 550.8 585.31 Condensate Tank Cost Included in Boiler1 Boiler Condensor 0.6 Cost Included in heat exchanger 1 Boiler & Accessories kg/hr steam 238,686 261,616 kg/hr steam 1.10 $51,300,000 2010 i $51,300,000 0.6 $54,202,607 3.02 $54,202,607 $57,598,545 $19,072,366 4 & 5 550.8 585.3 Scaled using direct installed cost1 Three Stage Turbine MW 42 48.05 MW 1.14 $17,100,000 2010 i $17,100,000 0.6 $18,484,575 3.02 $18,484,575 $19,642,683 $6,504,200 4 & 5 550.8 585.3 Scaled using direct installed cost

$0A400 $68,705,000 $73,008,465 $74,062,274 $78,702,473 $25,917,978

Equiment contingency 0% $0 $0$78,702,473 $25,917,978

A500 Cooling plantE500 1 Cooling Tow er kg/hr 10,037,820 13,800,000 kg/hr 1.37 $1,375,000 2010 b $1,375,000 0.6 $1,664,357 4.28 $7,123,448 $7,569,751 $1,768,633 4 & 5 550.8 585.3 Scaled using Aspen energy analyserE501 1 Cooling Water Pump kg/hr 10,982,556 13,800,000 kg/hr 1.26 $283,671 2010 b $567,342 0.6 $650,654 4.28 $2,784,801 $2,959,276 $691,420 5 550.8 585.3


$10,529,027 $2,460,053

A600 Other1 Off Gas Combustor Cost Included in Hydrogen Plant1 Gas Combustor Heat Recovery Cost Included in heat exchanger 1 Regenerator Heat Recovery Cost Included in heat exchanger 1 Scrubber Cost Included in Boiler1 Process to Process HE $2,840,000 2010 i $2,840,000 0.6 $2,840,000 4.28 $2,840,000 $2,888,908 $674,979 4 575.4 585.3 From HEN 1 LP steam Not required1 MP steam Not required1 HP steam $206,000 2010 i $206,000 0.6 $206,000 4.28 $206,000 $209,548 $48,960 4 575.4 585.3 From HEN 1 Cooling HE $3,748,200 2010 i $3,748,200 0.6 $3,748,200 4.28 $3,748,200 $3,812,749 $890,829 4 575.4 585.3 From HEN 1 HP Steam Generation Included in the Boiler cost1 Process Water Tank kg/hr 250,000 304,000 kg/hr 1.22 $250,000 2009 b $250,000 0.6 $281,125 4.28 $1,203,217 $1,349,404 $315,281 5 521.9 585.31 Bio oil Buffer Check Tank kg/hr 65,000 152,000 kg/hr 2.34 $200,000 2009 b $200,000 0.6 $332,957 4.28 $1,425,056 $1,598,195 $373,410 5 521.9 585.31 Bio oil Check Tank kg/hr 65,000 152,000 kg/hr 2.34 $200,000 2009 b $200,000 0.6 $332,957 4.28 $1,425,056 $1,598,195 $373,410 5 521.9 585.31 Torch Oil Tank kg/hr 65,000 128,000 kg/hr 1.97 $200,000 2009 b $200,000 0.6 $300,336 4.28 $1,285,440 $1,441,616 $0 5 521.9 585.31 Product Storage Tank kg/hr 65,000 300,000 kg/hr 4.62 $200,000 2009 b $200,000 0.6 $500,674 4.28 $2,142,883 $2,403,236 $561,504 5 521.9 585.31 Product Storage Tank kg/hr 65,000 240,000 kg/hr 3.69 $200,000 2009 b $200,000 0.6 $437,934 4.28 $1,874,358 $2,102,086 $491,142 5 521.9 585.31 Product Storage Tank kg/hr 65,000 100,000 kg/hr 1.54 $200,000 2009 b $200,000 0.6 $258,989 4.28 $1,108,475 $1,243,151 $290,456 5 521.9 585.31 Product Storage Tank kg/hr 65,000 644,000 kg/hr 9.91 $200,000 2009 b $200,000 0.6 $791,796 4.28 $3,388,888 $3,800,627 $887,997 5 521.9 585.31 Emergency Flare kg/hr 393,100 205,288 kg/hr 0.52 $32,955 2010 b $32,955 0.6 $22,317 4.28 $95,517 $101,502 $23,715 5 550.8 585.31 Fire Water Pump kg/hr 83,333 83,333 kg/hr 1.00 $15,000 2009 b $15,000 0.6 $15,000 4.28 $64,200 $72,000 $16,822 5 521.9 585.31 Plant Air Compressor mptd 2,000 2,000 mptd biomass 1.00 $87,922 2007 b $87,922 0.6 $87,922 4.28 $376,306 $419,215 $97,947 7 525.4 585.31 Hydraulic Truck Dump w ith Scale mptd 2,000 2,000 mptd 1.00 $80,000 1998 b $80,000 0.6 $80,000 4.28 $342,400 $514,531 $120,218 8 389.5 585.31 Diesel Pump mptd 2,000 2,000 mptd biomass 1.00 $3,842 2007 b $3,842 0.6 $3,842 4.28 $16,444 $18,319 $4,280 7 525.4 585.31 Instrument Air Dryer mptd 2,000 2,000 mptd biomass 1.00 $8,349 2002 b $8,349 0.6 $8,349 4.28 $35,734 $52,870 $12,353 8 395.6 585.31 Plant Air Receiver mptd 2,000 2,000 mptd biomass 1.00 $21,005 2007 b $21,005 0.6 $21,005 4.28 $89,901 $100,152 $23,400 7 525.4 585.31 Firew ater Storage Tank mptd 2,000 2,000 mptd biomass 1.00 $229,900 2007 b $229,900 0.6 $229,900 4.28 $983,972 $1,096,170 $256,115 7 525.4 585.31 Waste w ater treatment plant Cost included in the operating cost

A600 $8,923,173 $22,652,047 $24,822,473 $5,462,817Equiment contingency 0% $0 $0

$24,822,473 $5,462,817


Table S-8. Equipment cost source

1 Chemcad model 2 S. Jones, J. Holladay, C. Valkenburg, D. Stevens, C. Walton, C. Kinchin, D. Elliott and S. Czernik, Production of Gasoline and Diesel from

Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: a design case, Report PNNL-18284, Pacific Northwest National Laboratory, USA, 2009.

3 M. M. Wright, D. E. Daugaard, J. A. Satrio and R. C. Brown, Fuel, 2010, 89, S2-S10. 4 Aspen Energy Analyser using Chemcad model energy balances 5 D. Humbird, R. Davis, L. Tao, C. Kinchin, D. Hsu, A. Aden, P. Schoen, J. Lukas, B. Olthof, M. Worley, D. Sexton and D. Dudgeon,

Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol, Report NREL/TP-5100-47764, National Renewable Energy Laborotary, USA, 2011.

6 R. A. Meyer, in Handbook of Petroleum Refining Processes, McGraw Hill, New York, 3rd edn. 7 Dutta A, Talmadge M, Hensley J, Worley M, Dudgeon D, Barton D, et al. Techno-economics for conversion of lignocellulosic biomass to

ethanol by indirect gasification and mixed alcohol synthesis. Environmental Progress & Sustainable Energy. 2012;31(2):182-90. 8 Phillips SD. Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols

Synthesis. Industrial & Engineering Chemistry Research. 2007;46(26):8887-97.


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