study results of study results of oxyfuel oxyfueloxyfuel...

50
Study Results of Study Results of Study Results of Study Results of Oxyfuel Oxyfuel Oxyfuel Oxyfuel Combustion Combustion Combustion Combustion Technology in IHI Technology in IHI Technology in IHI Technology in IHI 16 th March, 2010 APP OFWG Chinese Course IHI Corporation

Upload: vuongbao

Post on 08-May-2018

220 views

Category:

Documents


1 download

TRANSCRIPT

Copyright © 2010 IHI Corporation All Rights Reserved.

Study Results of Study Results of Study Results of Study Results of OxyfuelOxyfuelOxyfuelOxyfuel Combustion Combustion Combustion Combustion

Technology in IHITechnology in IHITechnology in IHITechnology in IHI

16

th

March, 2010

APP OFWG Chinese Course

IHI Corporation

1Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ContentsContentsContentsContents

1. Outline of IHI

2. Clean coal technology of IHI

3. Callide Oxyfuel Project

4. Study results of oxyfuel combustion technologies

5. Conclusion

2Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

1. Outline of IHI

3Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Company profileCompany profileCompany profileCompany profile

Established : Dec. 1853

Capital : 95.7 Billion YEN (as of Mar. 2008)

Consolidated net sales : 1,350 Billion YEN (as of Mar. 2008)

Employees (consolidated) : 23,722 (as of Mar. 2008)

Works : 12

Branches and sales offices in Japan : 22

Overseas sales offices : 13

4Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Outline of IHIOutline of IHIOutline of IHIOutline of IHI

<Construction Machinery>

Shield tunneling machines

Jib climbing cranes

Materials handling machines

Cranes

Street sweepers

<Ship & Offshore Facilities>

* Oil tankers

* LNG / LPG carriers

* Container ships

* Bulk carriers

* Marine engines

<Storage Plants & Process Plants>

* Storage plants

* Oil / gas plants

* Chemical plants

* Seawater desalination and power

plants

* Pharmaceutical plants

<Bridge & Steel Structures>

* Bridges

* Gate equipments for rivers and dams

* Steel structures for building

* Hybrid caissons

* Floating bridges

<Standard Machinery>

* Turbochargers

* Superchargers

* Centrifuges

* Filters

* Compressors

<Jet Engines>

* Turbofan engines

* Turbojet engines

* Turboshaft engines

* Jet engines maintenance

<Industrial Machinery>

* Rolling mills

* Industrial furnaces

* Pulp & paper production plants

* Compressors

<Energy Systems>

* Boilers

* Components for nuclear power plants

* Gas turbine power generation systems

* Diesel Engines /Gas engines

5Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

IHI Products in Power Systems

Steam Generators

IHI Products in Power Systems

Fluidized Bed boilers(FBB,CFB,PFBC)

Air Pollution Control systems

GT C/C, GE

6Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

2. Boilers & Clean coal technology of IHI

7Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

1952 : L/A with Foster Wheeler Energy Co.

1955 : 1st Boiler, 68MW

1958 : 1st RH Boiler, 75MW

1962 : 1st Oil firing Boiler, 175MW

1971 : 1st Super Critical OTU, Kashima#2:600MW

1980 : 1st SOVR in Japan, Hirono#1:700MW

1985 : 1st Coal fired SOVR in Japan, Tomato#2:700MW

1999 : Expiration of L/A with Foster Wheeler Energy Co.

2000 : 1st 1050MW SOVR in Japan, Tachibanawan #1

2000 : 1st Large Capacity PFBC in Japan, Karita #1

2002: 1st 600MW Tower Type SOVR in Japan, Isogo New No.1

History of the Boiler BusinessHistory of the Boiler BusinessHistory of the Boiler BusinessHistory of the Boiler Business

8Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ALGERIA

164

HUNGARY

15

280

EGYPT 902

SAUDI

ARABIA

LEBANON

520

NIGERIA

600

1,440

ABU

DHABI

IRAN

3,360KUWAIT

3,177

AUSTRALIA

23,804

160

USSR

JAPAN

130,480ANTIGUA

118

BRAZIL

1,480

BANGLA DESH

1,765

KOREA

2,852

PEOPLE'S

REPUBLIC

OF CHINA

8,275

PHILIPPINES

1,125

TAIWAN

75

INDONESIA

2,630

MALAYSIA

5,688

SINGAPORE

7,211

THAILAND

186INDIA

1,193

130

SRILANKA

PAKISTAN

4,283

U.S.A

1,252

CHILE

80

UNIT:STEAM EVAPORATION t/h

(UTILITY AND INDUSTRIAL USE ONLY)

Total 513 units

IHI Boiler Track RecordIHI Boiler Track RecordIHI Boiler Track RecordIHI Boiler Track Record

9Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Recent record of IHI PC fired boilersRecent record of IHI PC fired boilersRecent record of IHI PC fired boilersRecent record of IHI PC fired boilers

Domestic Country Type MW Steam conditions* COD

Kobe Steel No.2 Japan SOVR 700 25.0/541/568 2004

Kureha No.4 Japan S1 43 12.2/540 2006

Sumitomo Kashima No.1 Japan SOVR 507 25.0/542/568 2007

Sumitomo Niihama No.3 Japan SR 150 17.1/569/541 2008

Toso Nanyo No.6 Japan SR 220 17.0/569/541 2008

MC Shiohama Japan S1 34 12.2/541 2008

Shin-Isogo No.2 Japan SOVR 600 27.2/605/623 2009

Maizuru No.2 Japan SOVR 900 25.4/600/598 [2010]

Oversea Country Type MW Steam conditions* COD

Tarong Australia SOVR 450 25.9/569/568 2003

Tanjung Bin o.1/2/3 Malaysia SR 771××××3 17.2/541/568 2006/7

Jimah Energy No.1/2 Malaysia SR 771 x 2 17.2/541/568 2008/9

Nebraska City U.S.A. SR 660 17.9/569/567 2009

Bluewaters Australia SR 230 x 2 17.1/569/568 2009

Plum Point Energy U.S.A. SR 665 17.9/569/567 [2010]

*Steam pressure(MPa)/Steam temperature (degree C) of SH/RH at boiler outlet

10Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Developmental Technologies

Existing Technologies

Clean Coal Technologies in IHIClean Coal Technologies in IHIClean Coal Technologies in IHIClean Coal Technologies in IHI

High efficiency : High efficiency : High efficiency : High efficiency : USCUSCUSCUSC, , , , SCSCSCSC

Environmental : Environmental : Environmental : Environmental : DeNOxDeNOxDeNOxDeNOx, , , , DeSOxDeSOxDeSOxDeSOx, , , ,

Higher efficiency : AHigher efficiency : AHigher efficiency : AHigher efficiency : A----USCUSCUSCUSC

CO2 Capture : CO2 Capture : CO2 Capture : CO2 Capture : OxyfuelOxyfuelOxyfuelOxyfuel combustion technologycombustion technologycombustion technologycombustion technology

Utilization of lignite : Utilization of lignite : Utilization of lignite : Utilization of lignite : TigarTigarTigarTigar (Atmospheric gasification)(Atmospheric gasification)(Atmospheric gasification)(Atmospheric gasification)

FL+80000

SEPARATOR

SEPARATING

TANK

PRI.

SH

RH

ECO

ECO

FURNACE

OAP OAP

SAP SAP

SAP SAP

IAP IAP

BURNER BURNER

BURNER BURNER

BURNER BURNER

SEC.

SH

FINAL

SH

RH

PLATEN

SH

USC/SC boiler

DeSOx DeNOx catalystBend of material for A-USC

11Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

CO2 capture method from coal utilization power plantCO2 capture method from coal utilization power plantCO2 capture method from coal utilization power plantCO2 capture method from coal utilization power plant

Post- combustion

Oxyfuel

ASU

Coal Boiler

Flue gas recirculationH2O

O2

CO2 capture& Storage

Compression & cooling

Air

Non-condensablegas

N2

Dust removal

Pre-combustion

ASU

O2

Air

N2

Gasifier Shift reactor CO2 separation

Coal

CO, H2

CO2, H2

H2

OxyfuelOxyfuelOxyfuelOxyfuel is one of the candidates for CO2 capture from coal fired power is one of the candidates for CO2 capture from coal fired power is one of the candidates for CO2 capture from coal fired power is one of the candidates for CO2 capture from coal fired power plant.plant.plant.plant.

Boiler

CO2

Compression & cooling

Coal

Air

N2,,,,H2O,,,,O2

Flue gas treatment system

CO2 separation

CO2 capture& Storage

Flue gas treatment system

Compression & cooling

CO2 capture& Storage

12Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

CO2 capture using oxyfuel

Coal Boiler

Flue gas recirculation

H2O

O2

Liquefied CO2Air

Non-condensable

gasN2

Flue gas

treatment

system

Dust removal

CO2

purification ;

Compression

& cooling

Applicability and potential

・・・・Applicable for existing and new-installed power plants

・・・・Potential for the reduction of cost and power

consumption by scaling-up of ASU and the integration of

total process

Process・・・・Installation of air separation unit

・・・・Flame temperature is adjusted by flue gas

recirculation

・・・・NOx emission is reduced by flue gas

recirculation

・・・・DeNOx and DeSOx will be compacted in case of

new-installed power plant

Feature

・・・・CO2 is major component in the flue gas

・・・・Amount of flue gas to CO2 purification can be reduced

to be almost one forth

CO2 capture using CO2 capture using CO2 capture using CO2 capture using oxyfueloxyfueloxyfueloxyfuel

Oxyfuel combustion ;

In coal fired power plant, coal combustion by oxygen in stead of air make it possible

to be concentrated of CO2 more than 90% theoretically in the flue gas.

ASU

13Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Development scheduleDevelopment scheduleDevelopment scheduleDevelopment schedule

NowNowNowNow((((Mar. 20Mar. 20Mar. 20Mar. 2010101010))))

Stage 1Stage 1Stage 1Stage 1BasicBasicBasicBasicStage 2Stage 2Stage 2Stage 2DemonstrationDemonstrationDemonstrationDemonstration

Stage 3Stage 3Stage 3Stage 3CommercializationCommercializationCommercializationCommercialization

Collaboration with Collaboration with Collaboration with Collaboration with JJJJ----POWERPOWERPOWERPOWERBasic research and FBasic research and FBasic research and FBasic research and FSSSS((((NEDONEDONEDONEDO))))Development scheduleDevelopment scheduleDevelopment scheduleDevelopment schedule

202020202020202020152015201520152010201020102010200520052005200520002000200020001995199519951995 CallideCallideCallideCallide FSFSFSFS((((NEDONEDONEDONEDO))))

Application Application Application Application to to to to CallideCallideCallideCallide----AAAAResearchResearchResearchResearch((((METIMETIMETIMETI))))

CommisCommisCommisCommissioningsioningsioningsioning Demonstration Demonstration Demonstration Demonstration operationoperationoperationoperationFS of commercial plantFS of commercial plantFS of commercial plantFS of commercial plant((((High efficiency High efficiency High efficiency High efficiency ++++ OxyfuelOxyfuelOxyfuelOxyfuel))))CommercializationCommercializationCommercializationCommercialization

Research of the new type Research of the new type Research of the new type Research of the new type of of of of oxyfueloxyfueloxyfueloxyfuel boilerboilerboilerboilerCallide Oxyfuel Project

・In 1990’s, basic research and FS were performed.

・FS of demonstration was performed under the collaboration with Australia

after 2004 and demonstration project was started in 2008.

14Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

3. Callide Oxyfuel Project

15Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Oxyfuel power plant & CO2 capture CO2 transportation & storage

ASUASUASUASU

CoalCoalCoalCoal

Flue gas recirculationFlue gas recirculationFlue gas recirculationFlue gas recirculation

O2O2O2O2

AirAirAirAir

((((N2N2N2N2、、、、O2O2O2O2))))

NonNonNonNon----condensablecondensablecondensablecondensablegasgasgasgasN2N2N2N2

Dust removalDust removalDust removalDust removal

CO2 liquefaction CO2 liquefaction CO2 liquefaction CO2 liquefaction

plantplantplantplant

BoilerBoilerBoilerBoiler

CO2 underground CO2 underground CO2 underground CO2 underground

storagestoragestoragestorage

CO2 storage TransportationCO2 storage TransportationCO2 storage TransportationCO2 storage Transportation

GGGG

CondenserCondenserCondenserCondenser

STSTSTST

StackStackStackStack

PPPP

Callide Oxyfuel Project

Objectives of Project

* To demonstrate the total CCS system using Oxyfuel combustion technology

in case of the application to the existing 30MWe power plant

* To obtain the data and operation experience for the commercial plant that is

zero emission power plant

16Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Location : 300km west of PSLocation : 300km west of PSLocation : 300km west of PSLocation : 300km west of PS

Transportation : TankerTransportation : TankerTransportation : TankerTransportation : Tanker

AustraliaAustraliaAustraliaAustralia

Power plant sitePower plant sitePower plant sitePower plant site

Queensland, AustraliaQueensland, AustraliaQueensland, AustraliaQueensland, Australia

Power plant and CO2 storage

Power plantPower plantPower plantPower plant

Site : Site : Site : Site : CallideCallideCallideCallide----A No.4, A No.4, A No.4, A No.4, CS EnergyCS EnergyCS EnergyCS Energy

Output : Output : Output : Output : 30MWe30MWe30MWe30MWe

Steam : Steam : Steam : Steam : 136t/h136t/h136t/h136t/h, , , , 460460460460℃℃℃℃, , , , 4.1MPa4.1MPa4.1MPa4.1MPa

Construction : Construction : Construction : Construction : 1966196619661966----68686868

Coal : Coal : Coal : Coal : CallideCallideCallideCallide coalcoalcoalcoal

CO2CO2CO2CO2 capture : max. capture : max. capture : max. capture : max. 75t/d75t/d75t/d75t/d

COCOCOCO2222

storage site storage site storage site storage site

((((candidatecandidatecandidatecandidate))))

・・・・Oxyfuel :::: Callide-A power station No.4 unit, CS Energy・・・・CO2 storage :::: Northern denison trough at 300km west of PS

17Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Project scheduleProject scheduleProject scheduleProject schedule

15151515Stage 1Stage 1Stage 1Stage 1CO2CO2CO2CO2 capture (Installation of capture (Installation of capture (Installation of capture (Installation of ASUASUASUASU & & & & CO2 purification, Boiler CO2 purification, Boiler CO2 purification, Boiler CO2 purification, Boiler modificationmodificationmodificationmodification))))Stage 3Stage 3Stage 3Stage 3ConclusionConclusionConclusionConclusion

05050505

Stage 2Stage 2Stage 2Stage 2CO2 storage CO2 storage CO2 storage CO2 storage ((((Site selection, trial Site selection, trial Site selection, trial Site selection, trial drilling Injectiondrilling Injectiondrilling Injectiondrilling Injection))))Demonstration projectDemonstration projectDemonstration projectDemonstration project

111166661414141413131313121212121010101008080808 09090909Feasibility studyFeasibility studyFeasibility studyFeasibility study 1111111107070707060606062004200420042004FYFYFYFYItemsItemsItemsItemsStudy

CO2 injection &

monitoring

Construction &

commissioning

Demonstration

FS

Conclusion

CO2 storage

Now Now Now Now ((((Mar. 20Mar. 20Mar. 20Mar. 2010101010))))

Oxyfuel demonstration

operation

Construction &

commissioning

Site selection, design

・・・・Ongoing towards the demonstration of CCS process in 2011

18Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Expectation at demonstration operation

ASUASUASUASU

CoalCoalCoalCoal

Flue gas recirculationFlue gas recirculationFlue gas recirculationFlue gas recirculation

O2O2O2O2

AirAirAirAir

((((N2N2N2N2、、、、O2O2O2O2))))

NonNonNonNon----condensable condensable condensable condensable

gasgasgasgas

N2N2N2N2

Dust removalDust removalDust removalDust removal

CO2 purificationCO2 purificationCO2 purificationCO2 purification

ボイラボイラボイラボイラ

CO2 underground CO2 underground CO2 underground CO2 underground

storagestoragestoragestorage

CO2 storage TransportationCO2 storage TransportationCO2 storage TransportationCO2 storage Transportation

GGGG

CondenserCondenserCondenserCondenser

STSTSTST

StackStackStackStack

PPPP

1. Demonstration as CCS system* Performance and economy for CO2 capture

* Operability of CCS system integrated with generation

* Demonstration of CO2 storage from the oxyfuel flue gas

2. Demonstration as the power plant* Performance after the application of oxyfuel to the existing power plant

* Comparison with the performance of air-firing

* Verification of the test results such as heat balance, combustion characteristics etc.

* Plant performance (efficiency, reliability, maintenance etc.)

・・・・To obtain the knowledge for the commercialization ・・・・To evaluate the potential of economy and technology

19Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Retrofit items of boiler

Existing process

IDF

Boiler

A

H

FF

Coal Bunker

Mill

FDF

WB

Study itemsStudy itemsStudy itemsStudy items

1. Extraction point of flue gas1. Extraction point of flue gas1. Extraction point of flue gas1. Extraction point of flue gas →→→→ IDF outletIDF outletIDF outletIDF outlet

2. Mixing point of O2 2. Mixing point of O2 2. Mixing point of O2 2. Mixing point of O2 →→→→ at the downstream of AHat the downstream of AHat the downstream of AHat the downstream of AH

3. Due point of primary 3. Due point of primary 3. Due point of primary 3. Due point of primary →→→→ Primary AH and H2O removerPrimary AH and H2O removerPrimary AH and H2O removerPrimary AH and H2O remover

4. Temperature at FF inlet4. Temperature at FF inlet4. Temperature at FF inlet4. Temperature at FF inlet →→→→ Flue gas coolerFlue gas coolerFlue gas coolerFlue gas cooler

20Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

IDF

BoilerFF

Coal Bunker

Mill

FDF/GMF

WB

ASU

Air

A

H

H2OH2OH2OH2O

remremremrem----

ovovovoverererer

To CO2 recovery unit

A

H

Gas Gas Gas Gas

coolercoolercoolercooler

* O2

N2

* O2

Oxyfuel process after the retrofit

Oxyfuel process after the retrofit

: Installation and retrofit parts

21Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Coal

bunker

Mill/

PAF

Boiler

HR

A

Fabric filter

IDFIDFIDFIDF FDFFDFFDFFDF

Stack

Flue gas Flue gas Flue gas Flue gas

coolercoolercoolercooler

Primary Primary Primary Primary

AHAHAHAH

BurnerBurnerBurnerBurner

Water Water Water Water

scrubberscrubberscrubberscrubber

側面図側面図側面図側面図

ASU & COASU & COASU & COASU & CO2222

compression areacompression areacompression areacompression area

No.4 UnitNo.4 UnitNo.4 UnitNo.4 Unit

LayoutLayoutLayoutLayout

Side elevationSide elevationSide elevationSide elevation

::::Main installation and Main installation and Main installation and Main installation and

retrofit partsretrofit partsretrofit partsretrofit parts

* * * * In case of the retrofit, modification of boiler In case of the retrofit, modification of boiler In case of the retrofit, modification of boiler In case of the retrofit, modification of boiler pressure parts is basically unnecessary.pressure parts is basically unnecessary.pressure parts is basically unnecessary.pressure parts is basically unnecessary.

Oxyfuel plant after the retrofit

22Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

4. Study results of oxyfuel combustion

technologies

23Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

IHI studies

IHI recognize that IHI recognize that IHI recognize that IHI recognize that oxyfueloxyfueloxyfueloxyfuel technology is one of the key technology is one of the key technology is one of the key technology is one of the key

technology to reduce CO2 from coal fired power plant.technology to reduce CO2 from coal fired power plant.technology to reduce CO2 from coal fired power plant.technology to reduce CO2 from coal fired power plant.

In In In In CallideCallideCallideCallide OxyfuelOxyfuelOxyfuelOxyfuel Project, in order to proceed successfully, Project, in order to proceed successfully, Project, in order to proceed successfully, Project, in order to proceed successfully,

some studied have been conducted until now, considering some studied have been conducted until now, considering some studied have been conducted until now, considering some studied have been conducted until now, considering

the commercialization, safety and reliable operation.the commercialization, safety and reliable operation.the commercialization, safety and reliable operation.the commercialization, safety and reliable operation.

In this section, some study results is introduced.In this section, some study results is introduced.In this section, some study results is introduced.In this section, some study results is introduced.

24Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

CallideCallideCallideCallide----A A A A oxyfueloxyfueloxyfueloxyfuel processprocessprocessprocess

IDF

BoilerFF

Coal

Bunker

Mill

FDF/GRF

WB

ASU AirAirAirAir

AH

H2O H2O H2O H2O

removerremoverremoverremover

To CO2 CPU

Flue gas Flue gas Flue gas Flue gas

LP LP LP LP

heaterheaterheaterheater

* O2

N2

* O2

*O2(Direct injection Partially)

CallideCallideCallideCallide----A A A A oxyfueloxyfueloxyfueloxyfuel process after retrofitprocess after retrofitprocess after retrofitprocess after retrofit

25Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Study items for the stable and safety oxyfuel combustion

Study 2 : Mixing simulationStudy 2 : Mixing simulationStudy 2 : Mixing simulationStudy 2 : Mixing simulation

* To confirm the O2 distribution* To confirm the O2 distribution* To confirm the O2 distribution* To confirm the O2 distribution

* To confirm the O2 conc. and temp. on the duct wall* To confirm the O2 conc. and temp. on the duct wall* To confirm the O2 conc. and temp. on the duct wall* To confirm the O2 conc. and temp. on the duct wall

Study 1 : Combustion Study 1 : Combustion Study 1 : Combustion Study 1 : Combustion

testtesttesttest

* To predict the * To predict the * To predict the * To predict the

combustion combustion combustion combustion

characteristicscharacteristicscharacteristicscharacteristics

* To evaluate the heat * To evaluate the heat * To evaluate the heat * To evaluate the heat

absorption in furnaceabsorption in furnaceabsorption in furnaceabsorption in furnace

* To confirm the * To confirm the * To confirm the * To confirm the

possibility of CO2 possibility of CO2 possibility of CO2 possibility of CO2

capturecapturecapturecapture

IDF

BoilerFF

Coal

Bunker

Mill

FDF/GRF

WB

ASU AirAirAirAir

AH

H2O H2O H2O H2O

removerremoverremoverremover

To CO2 CPU

Flue gas Flue gas Flue gas Flue gas

LP LP LP LP

heaterheaterheaterheater

* O2

N2

* O2

*O2(Direct injection partially)

Study 3 : Ignition test of fly ashStudy 3 : Ignition test of fly ashStudy 3 : Ignition test of fly ashStudy 3 : Ignition test of fly ash

* To confirm the ignition of fly ash* To confirm the ignition of fly ash* To confirm the ignition of fly ash* To confirm the ignition of fly ash

26Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

ObjectivesObjectivesObjectivesObjectives

The followings at The followings at The followings at The followings at oxyfueloxyfueloxyfueloxyfuel were confirmed as compared with air.were confirmed as compared with air.were confirmed as compared with air.were confirmed as compared with air.

* Flame stability* Flame stability* Flame stability* Flame stability

* Heat flux* Heat flux* Heat flux* Heat flux

* Combustion characteristics such as * Combustion characteristics such as * Combustion characteristics such as * Combustion characteristics such as NOxNOxNOxNOx, SO2 and Carbon in ash, SO2 and Carbon in ash, SO2 and Carbon in ash, SO2 and Carbon in ash

* CO2 capture* CO2 capture* CO2 capture* CO2 capture

27Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

AirAirAirAir Oxy 1Oxy 1Oxy 1Oxy 1 Oxy 2Oxy 2Oxy 2Oxy 2 Oxy 3Oxy 3Oxy 3Oxy 3

Flue gas flow Flue gas flow Flue gas flow Flue gas flow 142t/h 117t/h 140t/h 170t/h142t/h 117t/h 140t/h 170t/h142t/h 117t/h 140t/h 170t/h142t/h 117t/h 140t/h 170t/h

Inlet OInlet OInlet OInlet O2222 21% 30.2% 26.5% 21.7%21% 30.2% 26.5% 21.7%21% 30.2% 26.5% 21.7%21% 30.2% 26.5% 21.7%

FEGT FEGT FEGT FEGT Base Lower Nearly equal HigherBase Lower Nearly equal HigherBase Lower Nearly equal HigherBase Lower Nearly equal Higher

Heat absorption Heat absorption Heat absorption Heat absorption Base Higher Nearly equal LowerBase Higher Nearly equal LowerBase Higher Nearly equal LowerBase Higher Nearly equal Lower

AirAirAirAir Oxy 1Oxy 1Oxy 1Oxy 1 Oxy 2Oxy 2Oxy 2Oxy 2 Oxy 3Oxy 3Oxy 3Oxy 3

Simplified furnace simulationSimplified furnace simulationSimplified furnace simulationSimplified furnace simulation

Simulation resultsSimulation resultsSimulation resultsSimulation results

30

40

50

60

70

20 25 30 35

O2 content of total gas (wetvol%)

Furnace heat absorption (M

W)

Air case

Oxy case

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

Decide the combustion condition

before combustion test

28Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Air

FDF/GRF

PAF

Stack

IDF

Furnace

Pulverized

coal

Electrical

heater

Steam gas

heater

Water spray

tower

Electrical

heater

Bag

filter

Gas

cooler

Gas

cooler

Air

heater

O2Combustion processCombustion processCombustion processCombustion process

Test facilitiesTest facilitiesTest facilitiesTest facilities

Combustion test facilitiesCombustion test facilitiesCombustion test facilitiesCombustion test facilities

CapacityCapacityCapacityCapacity : max 150kg/h: max 150kg/h: max 150kg/h: max 150kg/h((((coalcoalcoalcoal))))

Furnace : Vertical typeFurnace : Vertical typeFurnace : Vertical typeFurnace : Vertical type

I.D. 1.3m I.D. 1.3m I.D. 1.3m I.D. 1.3m ×××× LLLL 7.5m7.5m7.5m7.5m

Burner Burner Burner Burner :::: IHIIHIIHIIHI----TRTRTRTR burnerburnerburnerburner

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

29Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

3.5 3.5 3.5 3.5 –––– 4.34.34.34.321 (Air)21 (Air)21 (Air)21 (Air)wet%wet%wet%wet%PriamryPriamryPriamryPriamry OOOO222221 (Air)21 (Air)21 (Air)21 (Air)

21 (Air)21 (Air)21 (Air)21 (Air)

3.5 3.5 3.5 3.5 ---- 4.34.34.34.3

75757575

0.8 0.8 0.8 0.8 –––– 0.480.480.480.48

Air modeAir modeAir modeAir mode

27272727wet%, calcwet%, calcwet%, calcwet%, calcInlet O2Inlet O2Inlet O2Inlet O2

35353535wet%wet%wet%wet%Burner windBurner windBurner windBurner wind----box Obox Obox Obox O2222 dry%dry%dry%dry%Flue gas O2 at AH inletFlue gas O2 at AH inletFlue gas O2 at AH inletFlue gas O2 at AH inlet

% under 74% under 74% under 74% under 74µmmmmFineness Fineness Fineness Fineness

MWtMWtMWtMWtHeat inputHeat inputHeat inputHeat input

Oxy mode Oxy mode Oxy mode Oxy mode ────Combustion modeCombustion modeCombustion modeCombustion mode

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[air dry%][air dry%][air dry%][air dry%]

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[dry%][dry%][dry%][dry%]

[[[[drydrydrydry·MJMJMJMJ/kg]/kg]/kg]/kg]

────

74.474.474.474.4

4.24.24.24.2

1.911.911.911.91

11.811.811.811.8

0.880.880.880.88

65.665.665.665.6

5.35.35.35.3

0.720.720.720.72

9.79.79.79.7

0.570.570.570.57

63.563.563.563.5

2.82.82.82.8

0.730.730.730.73

13.513.513.513.5

0.240.240.240.24

Ultimate analysisUltimate analysisUltimate analysisUltimate analysis

CCCC

HHHH

NNNN

OOOO

SSSS

14.014.014.014.0

6.96.96.96.9

34.134.134.134.1

59.059.059.059.0

4.14.14.14.1

18.218.218.218.2

40.940.940.940.9

40.940.940.940.9

8.88.88.88.8

19.319.319.319.3

25.725.725.725.7

55.055.055.055.0

PrxomatePrxomatePrxomatePrxomate analysisanalysisanalysisanalysis

IMIMIMIM

AshAshAshAsh

VMVMVMVM

FCFCFCFC

30.030.030.030.027.927.927.927.923.723.723.723.7HHVHHVHHVHHV

Coal CCoal CCoal CCoal CCoal BCoal BCoal BCoal BCoal ACoal ACoal ACoal ACoal typeCoal typeCoal typeCoal type

Coal & combustion conditionCoal & combustion conditionCoal & combustion conditionCoal & combustion condition

CoalCoalCoalCoal

ConditionConditionConditionCondition

****Non staged Non staged Non staged Non staged

combustioncombustioncombustioncombustion

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

30Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Air modeAir modeAir modeAir mode Oxy modeOxy modeOxy modeOxy mode

0.8MWt0.8MWt0.8MWt0.8MWt

0.64MWt0.64MWt0.64MWt0.64MWt

0.48MWt0.48MWt0.48MWt0.48MWt

Primary air

/ gas

Wind-box

Air register

Secondary

air / gas

Furnace

Flame stabilityFlame stabilityFlame stabilityFlame stability

・・・・Stable flame at higher burner loadStable flame at higher burner loadStable flame at higher burner loadStable flame at higher burner load

・・・・Flame at low load is blown out Flame at low load is blown out Flame at low load is blown out Flame at low load is blown out

((((UncontrolledUncontrolledUncontrolledUncontrolled))))

・・・・Support by direct O2 injectionSupport by direct O2 injectionSupport by direct O2 injectionSupport by direct O2 injection

・・・・Limit of minimum loadLimit of minimum loadLimit of minimum loadLimit of minimum load

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

31Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Heating elementHeating elementHeating elementHeating element

Heating element in the furnaceHeating element in the furnaceHeating element in the furnaceHeating element in the furnace

Air inletAir inletAir inletAir inlet

Air outletAir outletAir outletAir outlet

FurnaceFurnaceFurnaceFurnace

BurnerBurnerBurnerBurner

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

32Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

900

1000

1100

1200

1300

1400

1500

1600

1700

1800

0 1 2 3 4 5 6

Distance from burner throat (m)

Flam

e tem

p. (degree C

.)

Coal B/Oxy

Coal B/Air

Flame temperatureFlame temperatureFlame temperatureFlame temperature

Heat fluxHeat fluxHeat fluxHeat flux

0

50

100

150

200

250

300

0:00 0:20 0:40 1:00

経過時間(h)

熱流

束 (kW

/m

2)

酸素燃焼

空気燃焼

Heat flux (kW

/m

2)

Oxy-fuel

Air

Time (h)

Same level with heat flux at Same level with heat flux at Same level with heat flux at Same level with heat flux at

airairairair

50 degree C lower than 50 degree C lower than 50 degree C lower than 50 degree C lower than

that of airthat of airthat of airthat of air

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

33Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

0100200300400500

0 100 200 300 400 500NOx, Air mode (mg/MJ)NOx, Oxy mode (mg/MJ)

Coal ACoal BCoal C0100200300400500

0 100 200 300 400 500SO2, Air mode (mg/MJ)SO2, Oxy mode (mg/MJ)

Coal ACoal BCoal C0246810

0 2 4 6 8 10Carbon-in-ash, Air mode (%)Carbon-in-ash, Oxy mode (%)

Coal ACoal BCoal C0200400600800100012001400

0 200 400 600 800 1000 1200 1400NOx, Air mode (ppm)Nox, Oxy mode (ppm)

Coal ACoal BCoal C

02505007501000125015001750

0 250 500 750 1000 1250 1500 1750SO2, Air mode (ppm)SO2, Oxy mode (ppm)

Coal ACoal BCoal CCombustion characteristicsCombustion characteristicsCombustion characteristicsCombustion characteristics

Reduction of Reduction of Reduction of Reduction of NOxNOxNOxNOx and SOand SOand SOand SO2222

emissionemissionemissionemission

Improvement of carbon in Improvement of carbon in Improvement of carbon in Improvement of carbon in

ashashashash

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

34Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Liquefied CO2Liquefied CO2Liquefied CO2Liquefied CO2

70707070

75757575

80808080

85858585

90909090

95959595

100100100100

2.52.52.52.5 3.03.03.03.0 3.53.53.53.5 4.04.04.04.0 4.54.54.54.5

Flue gas OFlue gas OFlue gas OFlue gas O2222((((drydrydrydry%%%%))))

CO

CO

CO

CO

2

2

2

2 conc

conc

conc

conc.. ..(( ((dry

dry

dry

dry%% %%)) ))

Coal BCoal BCoal BCoal B

Coal CCoal CCoal CCoal C

OthersOthersOthersOthers

CO2 conc. in flue gasCO2 conc. in flue gasCO2 conc. in flue gasCO2 conc. in flue gas

****85858585~~~~95% CO2 at positive furnace pressure95% CO2 at positive furnace pressure95% CO2 at positive furnace pressure95% CO2 at positive furnace pressure

COCOCOCO2222

capturecapturecapturecapture

****Connection of Liquefied equipment with Connection of Liquefied equipment with Connection of Liquefied equipment with Connection of Liquefied equipment with

combustion test facilitiescombustion test facilitiescombustion test facilitiescombustion test facilities

****Possible to capture CO2 under zero degree Possible to capture CO2 under zero degree Possible to capture CO2 under zero degree Possible to capture CO2 under zero degree

C and 7MPaC and 7MPaC and 7MPaC and 7MPa

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

35Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Study 1 Combustion testStudy 1 Combustion testStudy 1 Combustion testStudy 1 Combustion test

Air OxyAir OxyAir OxyAir Oxy

Conc. Emission Conc. EConc. Emission Conc. EConc. Emission Conc. EConc. Emission Conc. Emissionmissionmissionmission

CarbonCarbonCarbonCarbon----inininin----ash Base ash Base ash Base ash Base ---- ----30303030~~~~40% 40% 40% 40% ----

NOxNOxNOxNOx Base Base Base Base BaseBaseBaseBase +20+20+20+20~~~~50% 50% 50% 50% ----60606060~~~~70%70%70%70%

SO2SO2SO2SO2 Base Base Base Base BaseBaseBaseBase ××××3333 ----30303030~~~~40%40%40%40%

* * * * Almost 27% inlet O2 is the same level of heat flux with air.Almost 27% inlet O2 is the same level of heat flux with air.Almost 27% inlet O2 is the same level of heat flux with air.Almost 27% inlet O2 is the same level of heat flux with air.

* Flame is stable at higher burner load.* Flame is stable at higher burner load.* Flame is stable at higher burner load.* Flame is stable at higher burner load.

* From the test results, we can obtain the good relationship of * From the test results, we can obtain the good relationship of * From the test results, we can obtain the good relationship of * From the test results, we can obtain the good relationship of combustion combustion combustion combustion

characteristics at between air and oxy.characteristics at between air and oxy.characteristics at between air and oxy.characteristics at between air and oxy.

* CO2 from * CO2 from * CO2 from * CO2 from oxyfueloxyfueloxyfueloxyfuel combustion can be captured.combustion can be captured.combustion can be captured.combustion can be captured.

ConclusionConclusionConclusionConclusion

36Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ObjectivesObjectivesObjectivesObjectives

To confirm the To confirm the To confirm the To confirm the followings;followings;followings;followings;

*O2 conc. & temp. on the duct wall*O2 conc. & temp. on the duct wall*O2 conc. & temp. on the duct wall*O2 conc. & temp. on the duct wall

*O2 distribution at the inlet of burner wind*O2 distribution at the inlet of burner wind*O2 distribution at the inlet of burner wind*O2 distribution at the inlet of burner wind----box (Optimization of O2 nozzle)box (Optimization of O2 nozzle)box (Optimization of O2 nozzle)box (Optimization of O2 nozzle)

Input dataInput dataInput dataInput data

More than 90More than 90More than 90More than 90More than 90More than 90More than 90More than 90Delta O2 conc. [O2Delta O2 conc. [O2Delta O2 conc. [O2Delta O2 conc. [O2----RFG]RFG]RFG]RFG]

2.02.02.02.02.22.22.22.2Flow ratio [RFG/O2]Flow ratio [RFG/O2]Flow ratio [RFG/O2]Flow ratio [RFG/O2]

16,30016,30016,30016,300

----5555

1.441.441.441.44

98989898

20,00020,00020,00020,000

15151515

1.441.441.441.44

98989898

O2 inputO2 inputO2 inputO2 input

Flow rate [Nm3/h]Flow rate [Nm3/h]Flow rate [Nm3/h]Flow rate [Nm3/h]

Temp.[Temp.[Temp.[Temp.[℃℃℃℃]]]]

DensityDensityDensityDensity [[[[kg/Nm3kg/Nm3kg/Nm3kg/Nm3]]]]

O2 conc. [%]O2 conc. [%]O2 conc. [%]O2 conc. [%]

32,80032,80032,80032,800

250250250250

1.571.571.571.57

Approx. 5Approx. 5Approx. 5Approx. 5

44,40044,40044,40044,400

310310310310

1.571.571.571.57

Approx. 5Approx. 5Approx. 5Approx. 5

RFG inputRFG inputRFG inputRFG input

Flow rate [Nm3/h]Flow rate [Nm3/h]Flow rate [Nm3/h]Flow rate [Nm3/h]

Temp.[Temp.[Temp.[Temp.[℃℃℃℃]]]]

DensityDensityDensityDensity [[[[kg/Nm3kg/Nm3kg/Nm3kg/Nm3]]]]

O2 conc. [%]O2 conc. [%]O2 conc. [%]O2 conc. [%]

<Reference> 80%<Reference> 80%<Reference> 80%<Reference> 80%

(as the worst case)(as the worst case)(as the worst case)(as the worst case)

100%100%100%100%ItemsItemsItemsItems

Study 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulation

37Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Burner & windBurner & windBurner & windBurner & wind----box arrangementbox arrangementbox arrangementbox arrangement

<<<<CallideCallideCallideCallide----A>A>A>A>

* 6 burners* 6 burners* 6 burners* 6 burners

* 4 burners in * 4 burners in * 4 burners in * 4 burners in survicesurvicesurvicesurvice at 30MWeat 30MWeat 30MWeat 30MWe

If there is the If there is the If there is the If there is the unbalance of O2 unbalance of O2 unbalance of O2 unbalance of O2

conc. at burner windconc. at burner windconc. at burner windconc. at burner wind----box inletbox inletbox inletbox inlet, , , ,

flame temperature will be flame temperature will be flame temperature will be flame temperature will be

different (uncontrollable).different (uncontrollable).different (uncontrollable).different (uncontrollable).

Impact to boiler heat balance Impact to boiler heat balance Impact to boiler heat balance Impact to boiler heat balance

(Unstable condition)(Unstable condition)(Unstable condition)(Unstable condition)

Study 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulation

38Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ModelModelModelModel

One side of duct out of both side was modeled.One side of duct out of both side was modeled.One side of duct out of both side was modeled.One side of duct out of both side was modeled.

Overview of Overview of Overview of Overview of CallideCallideCallideCallide----AAAA

****Various type of O2 nozzle were studied.Various type of O2 nozzle were studied.Various type of O2 nozzle were studied.Various type of O2 nozzle were studied.

Study 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulation

39Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Results of mixing simulationResults of mixing simulationResults of mixing simulationResults of mixing simulation

Operation loadOperation loadOperation loadOperation load 100%100%100%100% 100%100%100%100% 80%80%80%80%

Nozzle type Nozzle type Nozzle type Nozzle type Case1 Case 2 Case 2Case1 Case 2 Case 2Case1 Case 2 Case 2Case1 Case 2 Case 2

(Normal) (Optimum) (Optimum)(Normal) (Optimum) (Optimum)(Normal) (Optimum) (Optimum)(Normal) (Optimum) (Optimum)

O2 conc. on O2 conc. on O2 conc. on O2 conc. on

the duct wallthe duct wallthe duct wallthe duct wall

[%][%][%][%]

(Max.)(Max.)(Max.)(Max.)

O2 conc. at O2 conc. at O2 conc. at O2 conc. at

the estimation the estimation the estimation the estimation

area [%]area [%]area [%]area [%]

(Max.(Max.(Max.(Max.----Min.)Min.)Min.)Min.)

(98%) (34%) (34%)(98%) (34%) (34%)(98%) (34%) (34%)(98%) (34%) (34%)

(3.3%) (1.3%) (0.7%)(3.3%) (1.3%) (0.7%)(3.3%) (1.3%) (0.7%)(3.3%) (1.3%) (0.7%)

****Type of injection nozzle is optimized.Type of injection nozzle is optimized.Type of injection nozzle is optimized.Type of injection nozzle is optimized.

****

****

<Reference><Reference><Reference><Reference>

Study 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulation

40Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ConclusionConclusionConclusionConclusion

By the optimization of O2 injection nozzle,By the optimization of O2 injection nozzle,By the optimization of O2 injection nozzle,By the optimization of O2 injection nozzle,

�Possibility of higher O2 concentration on the duct is low.Possibility of higher O2 concentration on the duct is low.Possibility of higher O2 concentration on the duct is low.Possibility of higher O2 concentration on the duct is low.

�Risk ofRisk ofRisk ofRisk of ignition of the fly ash on the duct is very low, ignition of the fly ash on the duct is very low, ignition of the fly ash on the duct is very low, ignition of the fly ash on the duct is very low,

considering the results of ignition test and mixing simulation.considering the results of ignition test and mixing simulation.considering the results of ignition test and mixing simulation.considering the results of ignition test and mixing simulation.

� Risk of unbalance of O2 distribution at burner inlet is Risk of unbalance of O2 distribution at burner inlet is Risk of unbalance of O2 distribution at burner inlet is Risk of unbalance of O2 distribution at burner inlet is

lower lower lower lower

Study 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulationStudy 2 Mixing simulation

41Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ObjectivesObjectivesObjectivesObjectives

To confirm the possibility of ignition To confirm the possibility of ignition To confirm the possibility of ignition To confirm the possibility of ignition

of flyof flyof flyof fly ash and carbon at the ash and carbon at the ash and carbon at the ash and carbon at the

atmosphere of high temp. and high O2 atmosphere of high temp. and high O2 atmosphere of high temp. and high O2 atmosphere of high temp. and high O2

conc. conc. conc. conc.

Test conditionTest conditionTest conditionTest condition

Temp. /Temp. /Temp. /Temp. /

320320320320℃℃℃℃, 520, 520, 520, 520℃℃℃℃

O2 conc.O2 conc.O2 conc.O2 conc. ////

25, 50, 100%25, 50, 100%25, 50, 100%25, 50, 100%

Carbon content /Carbon content /Carbon content /Carbon content /

5%(fly ash) 5%(fly ash) 5%(fly ash) 5%(fly ash) ---- 25, 50, 100%25, 50, 100%25, 50, 100%25, 50, 100%

(fly ash + activated carbon)(fly ash + activated carbon)(fly ash + activated carbon)(fly ash + activated carbon)

Test apparatusTest apparatusTest apparatusTest apparatus

Sample cellSample cellSample cellSample cell

(1cm3)(1cm3)(1cm3)(1cm3)

Study 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ash

42Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Test resultsTest resultsTest resultsTest results

Temperature : 520 degree CTemperature : 520 degree CTemperature : 520 degree CTemperature : 520 degree C Temperature : 320 degree CTemperature : 320 degree CTemperature : 320 degree CTemperature : 320 degree C

<Case of <Case of <Case of <Case of CallideCallideCallideCallide----A>A>A>A>

Carbon content in FA : < 5%Carbon content in FA : < 5%Carbon content in FA : < 5%Carbon content in FA : < 5%

Temp. of RFG : Approx. 300 degree C Temp. of RFG : Approx. 300 degree C Temp. of RFG : Approx. 300 degree C Temp. of RFG : Approx. 300 degree C

(After mixing : 230 degree C)(After mixing : 230 degree C)(After mixing : 230 degree C)(After mixing : 230 degree C)

CallideCallideCallideCallide----A conditionA conditionA conditionA condition

Study 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ash

43Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ConclusionConclusionConclusionConclusion

Possibility of ignition of fly ash at Possibility of ignition of fly ash at Possibility of ignition of fly ash at Possibility of ignition of fly ash at CallideCallideCallideCallide----A condition is A condition is A condition is A condition is

very lowvery lowvery lowvery low

Further studyFurther studyFurther studyFurther study

� Gather the data at various temperature, atmosphere and Gather the data at various temperature, atmosphere and Gather the data at various temperature, atmosphere and Gather the data at various temperature, atmosphere and

volume of sample, etc.volume of sample, etc.volume of sample, etc.volume of sample, etc.

Study 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ashStudy 3 Ignition test of fly ash

44Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

ObjectivesObjectivesObjectivesObjectives

Study of efficiency and cost in case of the application to the Study of efficiency and cost in case of the application to the Study of efficiency and cost in case of the application to the Study of efficiency and cost in case of the application to the

existing 1000MW class power plantexisting 1000MW class power plantexisting 1000MW class power plantexisting 1000MW class power plant

****USC 1000MWe classUSC 1000MWe classUSC 1000MWe classUSC 1000MWe class

in Japanin Japanin Japanin Japan

****Capture rate : 9Capture rate : 9Capture rate : 9Capture rate : 90000%%%%

*Pressure : 7MPa*Pressure : 7MPa*Pressure : 7MPa*Pressure : 7MPa

Power plantPower plantPower plantPower plant

COCOCOCO2222

capture conditioncapture conditioncapture conditioncapture condition

Study 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plant

45Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Main parameter

2,494MW2,494MW2,494MW2,494MW2,494MW2,494MW2,494MW2,494MWHeat inputHeat inputHeat inputHeat input((((①①①①))))1111,,,,050MW050MW050MW050MW1111,,,,050MW050MW050MW050MWGeneration outputGeneration outputGeneration outputGeneration output((((②②②②))))

740MW740MW740MW740MW997MW997MW997MW997MWSendSendSendSend----out output out output out output out output ((((④④④④====②②②②----③③③③))))53MW53MW53MW53MW ((((5.0%5.0%5.0%5.0%))))53MW53MW53MW53MW((((5.0%5.0%5.0%5.0%))))BoilerBoilerBoilerBoiler ((((Mills, fansMills, fansMills, fansMills, fans他他他他)))) 163MW163MW163MW163MW ((((15.5%15.5%15.5%15.5%))))----ASUASUASUASU

29.7%29.7%29.7%29.7%40.0%40.0%40.0%40.0%Plant efficiency Plant efficiency Plant efficiency Plant efficiency ((((S.O.S.O.S.O.S.O.)))) ((((④④④④////①×①×①×①×100100100100))))95MW95MW95MW95MW ((((9.0%9.0%9.0%9.0%))))----CO2CO2CO2CO2 purificationpurificationpurificationpurification

310MW310MW310MW310MW ((((29.5%29.5%29.5%29.5%))))53MW53MW53MW53MW ((((5.0%5.0%5.0%5.0%))))Power consumptionPower consumptionPower consumptionPower consumption 合計合計合計合計((((③③③③)))) 90% 90% 90% 90% <<<<5.3 million t5.3 million t5.3 million t5.3 million t----CO2/yearCO2/yearCO2/yearCO2/year>>>>----CO2 capture rate CO2 capture rate CO2 capture rate CO2 capture rate <<<<AmountAmountAmountAmount>>>>OxyfuelOxyfuelOxyfuelOxyfuel with Cwith Cwith Cwith CO2O2O2O2 capturecapturecapturecapture

Normal airNormal airNormal airNormal air

((((without without without without CO2CO2CO2CO2 capturecapturecapturecapture))))

ItemsItemsItemsItems

※※※※Availability:80%※※※※(((( )))) shows the in-house power consumption rate

Study 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plant

46Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

CostCostCostCost

* Availability* Availability* Availability* Availability : : : : 80%80%80%80%

* * * * COCOCOCO2222 capturecapturecapturecapture : : : : Approx.Approx.Approx.Approx. 5 Mt5 Mt5 Mt5 Mt----COCOCOCO2222* Excluding the cost for CO* Excluding the cost for CO* Excluding the cost for CO* Excluding the cost for CO2222 transportation and storage transportation and storage transportation and storage transportation and storage

Study 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plantStudy 4 FS of 1000MWclass power plant

Energy

CO

2 c

ap

ture

co

st

(yen

/t-C

O2)

Capital, O&M

0000

500500500500

1,0001,0001,0001,000

1,5001,5001,5001,500

2,0002,0002,0002,000

2,5002,5002,5002,500

3,0003,0003,0003,000

3,5003,5003,5003,500

22%22%22%22%

36%36%36%36%

17%17%17%17%

5%5%5%5%

3%3%3%3%

16%16%16%16%

Power

Capital, O&M

CO2Compressors (Power)

Air separation units (Power)

O&M

Flue gas ducts etc. (capital)

CO2 compressors (Capital)

Air separation units (Capital)

In case of the improvement of cost & power consumption at ASU & In case of the improvement of cost & power consumption at ASU & In case of the improvement of cost & power consumption at ASU & In case of the improvement of cost & power consumption at ASU & COCOCOCO2222

compression unit, it will be possible to reduce the COcompression unit, it will be possible to reduce the COcompression unit, it will be possible to reduce the COcompression unit, it will be possible to reduce the CO2222

capture cost further.capture cost further.capture cost further.capture cost further.

47Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

5. Conclusion

48Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

Technical issues for commercializationTechnical issues for commercializationTechnical issues for commercializationTechnical issues for commercialization

Oxygen production (ASU)

Flue gas recirculation

Coal

storage

Non-condensable gas

N2

Boiler

CO2

storage

CO2 transportation & injection

EPGAH GGH DeSOxIDF

BUFP

A

F

DeNOx

Coal

bunker

CO2 purification unitCO2 purification unitCO2 purification unitCO2 purification unit

Air

AirFDF

ST

Power Generation by oxyfuel

Stack

Mill

P

O2

◇◇◇◇ Scale-up of ASU, oxyfuel boiler and CO2 purification unit◇◇◇◇ More efficient of total system◇◇◇◇ Safety and reliability

49Copyright © 2010 IHI Corporation All Rights Reserved. APP OFWG Chinese Course 2010

OxyOxyOxyOxy----fuel technology is the one candidate of the hopeful and costfuel technology is the one candidate of the hopeful and costfuel technology is the one candidate of the hopeful and costfuel technology is the one candidate of the hopeful and cost----

effective CCS technology in the future.effective CCS technology in the future.effective CCS technology in the future.effective CCS technology in the future.

We are going to proceed to do our best for the further developmeWe are going to proceed to do our best for the further developmeWe are going to proceed to do our best for the further developmeWe are going to proceed to do our best for the further development on nt on nt on nt on

oxyoxyoxyoxy----fuel technology under fuel technology under fuel technology under fuel technology under ““““CallideCallideCallideCallide OxyfuelOxyfuelOxyfuelOxyfuel ProjectProjectProjectProject””””, hoping the , hoping the , hoping the , hoping the

environmentally and friendly pulverized coal firing power plantsenvironmentally and friendly pulverized coal firing power plantsenvironmentally and friendly pulverized coal firing power plantsenvironmentally and friendly pulverized coal firing power plants

These studies for the demonstration project were greatly supportThese studies for the demonstration project were greatly supportThese studies for the demonstration project were greatly supportThese studies for the demonstration project were greatly supported by ed by ed by ed by

METI, NEDO, JCOAL, JMETI, NEDO, JCOAL, JMETI, NEDO, JCOAL, JMETI, NEDO, JCOAL, J----Power and Mitsui as well as by Australian Power and Mitsui as well as by Australian Power and Mitsui as well as by Australian Power and Mitsui as well as by Australian

organizations such as CCSD, CS Energy, University of Newcastle aorganizations such as CCSD, CS Energy, University of Newcastle aorganizations such as CCSD, CS Energy, University of Newcastle aorganizations such as CCSD, CS Energy, University of Newcastle and nd nd nd

others.others.others.others.

ConclusionConclusionConclusionConclusion

Thank you for your kind attention !!