structural and geochemical controls on … · s.mple no. 8102 tiol a1203 fewj(tol) feo(equlv.) mno...
TRANSCRIPT
S.m
ple
No.
8102 T
IOl
A1203
FeW
J(toL
) F
eO(equlv.)
Mn
O
M&
(> C
aO
Na20
K2
0
P203
82
03
0
20
+
02
0-
CO
l s F L
OI
Totab
S.G
. P
eDium
lnous Index
Tr.ce E
lern<nl5 (ppm
)
v Za
c. N
l P
b S
a w
La T
il B
a Z
r y C
e u 81 S
b A
s 8
02
u R
b S
r N
b C
r
111494
15.10 o.os
12.90 1.33
O.o3 0.14 0.46 3.20 4.92 0.02
0.66
98.80
l.SO
<2
24.00 34.00 4.00
20.00 8.00 <10 <
20 14.00 ss.oo 30.00 62.00 20.00 24.00
8.00 <4
38.00 <O.OS
111495 A
v. of 3*
73.40 0.04
12.30 1.68
0.07 0.17 0.85 0.48 7.70
<1>.01
1.3S
98.00
1.36
4.00 8S.OO 60.00 4.00
190.00 20.00
<10 <20
24.00 390.00 26.00 60.00
<20 25.00
135.00 s.oo
450.00 <1l.OS
73
.90
0
.08
1
4.7
5
1.61 0
.02
0
.60
0
.13
3
.20
4
.60
0
.02
1.0
0
0.21
<0.2
10
0.1
0
1.86
25
.00
7
.00
0
.00
0
.00
2
7.0
0
32
.00
8
8.0
0
23
.00
12
0.0
0
75
4.0
0
8.0
0
AP
PE
ND
IX lla
Chem
ical composition of the P
ine Hill G
ranite -U
naltered Granite
14
24
*
73
.10
0
.12
1
5.0
0
1.9
0
0.0
2
0.7
0
0.1
0
3.2
0
4.8
0
0.0
2
0.9
0
0.2
5
100.11
1.85
29
.00
6
.00
0
.00
0
.00
1
5.0
0
25
.00
6
8.0
0
40
.00
38
.00
8
24
.00
7
.00
14
28
*
74
.40
0
.05
1
4.4
0
2.1
0
0.0
2
0.6
0
0.1
2
2.3
0
4.5
0
0.0
2
1.3
0
0.2
2
10
0.0
3
2.08
31
.00
7
.00
0
.00
0
.00
3
7.0
0
59
.00
6
3.0
0
22
.00
29
9.0
0
76
5.0
0
6.0
0
14
27
*
Av.
of 2•
74
.20
0
.02
1
4.8
0
0.9
0
0.0
2
0.5
5
0.1
6
4.1
0
4.5
0
0.0
2
0.8
0
0.1
6
10
0.2
3
1.69
15
.00
7
.00
0
.00
0
.00
2
7.0
0
12
.00
1
33
.00
7.0
0
24
.00
6
72
.00
1
2.0
0
72
.70
0.01
14
.95
3.6
7
0.0
9
0.8
5
1.0
9
0.5
5
4.0
0
0.0
4
1.3
2
0.1
2
0.8
0
99
.79
2.6S
92
.00
5
.00
1
0.0
0
27
.00
5
9.0
0
43
.00
1
90
.00
32
.00
54
.00
7
84
.00
6
.00
14
17
8*
70
.40
0.01
15
.90
4.0
0
0.1
0
0.5
5
0.0
4
0.2
5
4.2
0
.0.0
7
1.6
7
0.1
2
97.31
3.S4
68
.00
4
.00
1
1.0
0
16
.00
1
04
.00
25
.00
3
29
.00
17
.00
34
.00
8
34
.00
3
.00
14111. 8
17
00
(1)t
81
70
0(2
)t
76
.80
0
.02
1
3.4
0
1.8
0
0.0
2
0.6
0
0.6
4
0.7
0
4.9
0
0.0
4
0.9
7
0.11
10
0.0
0
2.1S
11
3.0
0
6.0
0
9.0
0
38
.00
1
4.0
0
81
.00
5
0.0
0
46
.00
74
.00
7
34
.00
8
.00
74
.69
0
.05
1
3.2
5
0.4
9
1.3
5
0.0
3
<0
.10
0
.63
3
.55
4
.74
<
0.0
3
0.0
7
1.2
9
10
0.3
4
1.49
19
.00
2
.00
5
.00
7.0
0
48
.00
17
.00
1
05
.00
2
01
.00
19
5.0
0
84
3.0
0
18
.00
5
2.0
0
75
.13
0
.04
13.01
,.83
0.0
3
<0.10 0
.64
4
.33
4
.58
<
0.03
0.1
2
0.8
3
10
0.5
4
1.36
61
70
1t
75
.58
0
.04
1
3.3
8
1.2
4
0.0
3
<0.10 0
.60
4
.66
4
.57
<
0.03
0.0
7
0.7
4
100.91
1.36
15
.00
6
.00
2
.00
11
.00
*Gro
ves (1968), t W
ard (1981), o Patterson (1979),
A B
ajwah et a
l(in press)
81
70
3t
75
.00
0
.08
1
2.7
9
0.3
2
1.1
7
0.0
3
<0
.10
0
.78
2
.88
4
.98
<
0.0
3
0.1
8
1.1
5
99
.34
1.48
17
.00
4
.00
5
.00
10
7.0
0
42
.00
54
.00
1
04
.00
1
55
.00
30
5.0
0
75
1.0
0
14
.00
5
2.0
0
81
70
5t
70
.79
0
.44
1
4.2
3
0.5
2
2.21 0
.03
0
.79
2
.09
2
.22
5.11 0
.14
0.7
4
0.9
6
99
.57
I.SI
12
.00
8
.00
4
.00
4.0
0
<4
39
8.0
0
18
9.0
0
44
.00
55
.00
2
79
.00
1
23
.00
2
0.0
0
81
70
8t
68
.62
0
.53
1
3.8
0
0.6
9
2.8
4
0.0
3
0.9
5
2.1
2
2.6
7
4.8
3
0.1
7
0.0
4
1.2
9
98
.58
1.43
21
.00
1
1.0
0
4.0
0
6.0
0
<4
33
9.0
0
21
6.0
0
40
.00
75
.00
3
27
.00
1
20
.00
2
0.0
0
81
70
7t
70
.97
0
.39
1
3.8
0
2.6
8
0.0
3
0.4
4
1.71 2
.26
5
.47
0
.09
0.0
5
0.7
4
98
.63
1.46
36
.00
1
2.0
0
4.0
0
<3
<4
37
3.0
0
17
0.0
0
59
.00
29
0.0
0
97
.00
2
0.0
0
10
37
15
•
70
.58
0
.43
1
3.1
7
3.3
0
0.0
8
1.1
3
3.1
8
2.4
0
5.11 0
.13
0.5
2
101.41
1.23
~
0 h.)
Sam
ple No.
SIO%
TIO%
Al%
03 F
e203(1oL)
FeO
(eqalv.) M
nO
M
gO
c.o
N•2
0
K%
0 P%
03 8
20
3
lllO+
Ill(). co:z s F
L
OI
Totals
S.G
. P
enlu
mln
ou
o
Index
10
37
18
"
72
.30
0
.40
1
3.5
3
3.2
0
0.1
4
0.91 1
.98
2
.80
5
.48
0
.13
0.5
2
10
1.3
5
1.32
Tr•ce E
leme• Is (ppm
)
v Zn
C
u
Nl
Pb
Sn
w
La
Tb
8
• Z
r y C
e u 81 S
b A
s SO%
u R
b S
r N
b
Cr
10
30
53
•
72
.33
0
.37
1
3.8
6
2.1
7
0.0
2
0.6
0
1.8
0
2.7
5
5.2
2
0.11
1.1
8
100.41
1.42
AP
PE
ND
IX lla
Ch
em
ical com
position of the P
ine Hill G
ranite -U
naltered Gra
nite
1031157"
73
.67
0
.19
1
3.0
6
1.6
5
0.1
2
0.3
3
1.5
9
3.4
9
5.0
8
0.1
0
1.1
3
100.41
1.29
10311511"
76
.15
0
.38
1
2.6
9
1.6
8
0.0
9
0.3
7
1.4
3
2.1
5
5.3
4
0.0
6
0.9
4
10
1.2
8
1.42
1031160°
73
.23
0
.38
1
3.7
5
2.1
6
0.01 0
.64
1
.92
2
.94
5
.12
0
.13
0.5
5
10
0.8
3
1.38
Z·1
•
73
.62
0
.05
1
2.6
9
2.5
0
0.0
7
0.0
8
0.9
3
1.1
2
5.81 0.01 0
.08
0
.99
0
.13
1
.30
0.01 1
.02
100.41
2.6
3
1.61
1.2
9
1.0
0
12
0.0
0
3.0
0
10
4.0
0
24
.00
40
.00
6
1.0
0
49
.00
9
9.0
0
19
2.0
0
86
.00
3
3.0
0
91
8.0
0
28
.00
5
9.0
0
1.0
0
Z·2
•
73
.59
0
.09
1
3.1
7
1.1
7
0.1
0
0.21 0.70. 2
.45
5.91 0
.03
0
.04
0
.97
0.31 0
.95
0
.00
0
.28
99
.97
2.6
2
1.4S
1.1
3
2.0
0
14
.00
0
.00
1
30
.00
2
5.0
0
43
.00
4
6.0
0
96
.00
9
8.0
0
22
1.0
0
10
4.0
0
39
.00
83
9.0
0
22
.00
5
0.0
0
1.0
0
Z·10A
75
.30
0
.08
1
2.3
7
1.1
6
0.0
4
0.1
3
0.7
3
2.3
5
4.9
9
0.0
2
0.0
3
0.3
5
0.0
4
2.2
7
0.0
0
0.3
5
100.21
2.61 I.S3
1.1
7
2.0
0
11
.00
0
.00
1
04
.00
2
8.0
0
32
.00
5
4.0
0
44
.00
9
6.0
0
17
7.0
0
73
.00
2
7.0
0
68
2.0
0
19
.00
4
7.0
0
2.0
0
Z·1
2•
72.31 0
.39
1
3.3
6
2j.51 rJ.o3 0
.64
1
.58
2
.52
5
.34
0
.15
0
.02
0
.52
0
.07
0
.38
0
.12
0
.17
100.11
2.6
4
1.42
1.0
4
26
.00
1
5.0
0
25
.00
1
9.0
0
18
.00
47
.00
3
8.0
0
37
6.0
0
16
1.0
0
58
.00
9
3.0
0
11
.00
35
2.0
0
10
9.0
0
20
.00
8
.00
Z·1
5•
74
.18
0
.15
1
3.1
6
1.3
9
0.0
4
0.3
8
0.9
3
3.1
2
5.1
2
0.0
7
0.01 0
.50
0
.06
0
.39
0
.00
0
.26
99
.77
2.6
2
1.44
1.0
6
8.0
0
15
.00
0
.00
1
9.0
0
27
.00
44
.00
4
9.0
0
19
6.0
0
10
6.0
0
88
.00
8
8.0
0
18
.00
43
1.0
0
58
.00
3
0.0
0
4.0
0
* Groves (1968), t W
ard (1981 ), o Patterson (1979), " B
ajwah et at (in press)
Z·1&
•
71
.04
0
.44
1
3.7
7
2.5
4
0.0
3
0.8
2
2.0
2
2.5
7
5.1
4
0.1
6
0.5
0
0.7
3
0.1
4
0.0
2
0.0
7
0.1
9
10
0.2
7
2.6
5
1.42
1.0
2
1.0
0
44
.00
0
.00
5
4.0
0
14
.00
24
.00
3
5.0
0
17
0.0
0
17
4.0
0
58
.00
6
7.0
0
11
.00
31
8.0
0
12
4.0
0
21
.00
3
.00
Z·28A
75.81 0
.32
1
1.8
0
1.61 0
.47
0
.63
0
.87
1
.88
4.81 0
.09
0
.20
0
.78
0
.18
0
.42
0
.45
0
.09
10
0.2
3
2.8
3
1.60
1.2
2
32
.00
3
61
.00
0
.00
7
6.0
0
38
.00
27
.00
3
2.0
0
16
1.0
0
13
5.0
0
68
.00
6
9.0
0
12
.00
67
9.0
0
31
.00
1
8.0
0
5.0
0
Z·3
0•
70
.90
0
.49
1
3.5
6
2.7
3
0.0
4
0.9
0
2.0
2
3.0
0
4.6
9
0.1
8
0.0
2
0.2
3
0.1
9
0.4
6
0.0
4
0.2
5
99
.68
2.6
5
1.40
0.9
9
33
.00
1
2.0
0
3.0
0
45
.00
1
3.0
0
52
.00
3
6.0
0
30
9.0
0
18
6.0
0
70
.00
1
02
.00
1
1.0
0
34
7.0
0
12
5.0
0
20
.00
7
.00
~
0 (,)
40-l
APPENDIX lla
Chemical composition of the Pine Hill Granite - Albitised Granite
Sample No. Z-7A Z·17A Z·18A Z·27• Z·32A Z-311A
SI02 75.18 73.38 74.69 74.10 74.44 74.15 TI02 0.04 0.01 0.17 0.15 0.12 0.08 Al203 13.02 12.87 12.71 13.25 12.98 12.75 Fe203(toL) FeO(equlv.) 1.29 1.90 1.71 1.55 1.38 1.80 MnO 0.04 0.10 0.04 0.04 0.04 0.05 MgO 0.10 0.78 0.30 0.43 0.30 0.23 CaO 0.77 1.62 1.03 1.01 0.84 0.90 Na20 3.61 3.25 3.17 3.47 3.27 2.79 K20 4.85 2.90 4.72 4.96 4.97 4.72 P203 0.01 0.02 0.07 0.06 0.04 0.01 8203 0.23 1.23 0.02 0.12 0.03 0.95 H20+ 0.11 0.26 0.49 0.28 0.74 0.62 H20- 0.11 0.13 0.08 0.13 0.14 0.17 C02 0.19 0.33 0.28 0.25 0.02 0.12 s 0.00 0.00 0.00 0.00 0.00 0.00 F 0.47 0.64 0.23 0.12 0.23 0.82 LOI
Totals 100.02 99.22 99.71 99.92 99.54 99.94
S.G. 2.64 2.87 2.65 2.63 2.62 2.85 Peraluminous 1.03 1.11 1.04 1.26 1.08 1.12 Index
Trace Elemenl.s(pprt
v 1.00 1.00 8.00 14.00 5.00 1.00 Zn 17.00 43.00 16.00 15.00 14.00 17.00 Cu 0.00 0.00 1.00 0.00 0.00 0.00 Mo Nl 24.00 120.00 75.00 59.00 63.00 82.00 Pb 31.00 10.00 28.00 29.00 27.00 18.00 Sn w La 31.00 24.00 46.00 44.00 41.00 34.00 Th 50.00 19.00 52.00 49.00 54.00 62.00 Ba 21.00 170.00 179.00 190.00 118.00 25.00 Zr 83.00 31.00 114.00 134.00 131.00 99.00 y 206.00 146.00 99.00 62.00 124.00 207.00 c. 81.00 67.00 98.00 104.00 92.00 77.00 u 31.00 12.00 19.00 17.00 25.00 35.00 Bi Sb As S02. Ll Rb 811.00 452.00 487.00 673.00 578.00 698.00 Sr . 13.00 44.00 54.00 53.00 36.00 19.00 Nb 57.00 22.00 27.00 35.00 41.00 64.00
Cr 2.00 2.00 5.00 5.00 3.00 1.00
*Groves (1968), t Ward (1981), o Patterson (1979),,.. Bajwah et al(in press)
S•m
pleN
o.
8102 T
IOl
Al203
•·e203(1oL)
FeO(equiY
.) M
aO
MK
() c.o N
.%0
IU
O
P203 8203 H
20+ IJ2
0-
CO
l s F
LO
I
Touls
S.G
. P
eraluminous
lnd
n
Trace E
lemenl.s(ppm
)
v Z• c. M
o N
l P
b S
a w
L
a T
il B
• Z
r y C
e u 81 S
b ld
S
Ol
u Rb
Sr
Nb
Cr
Av. :r
70.65 0.01
15.25
7.6
0
0.0
9
0.7
5
1.31 0
.80
1.90 0
.03
0
.00
1.63 0
.09
<0.2
100.16
1415° 61695(l)t
61695(l)t
71.00 0.00
15.50
5.10 0.15 0.80 2.58 0.70 2.90 0.02
2.15 0.15
101.05
561.00 4.00
7.00 0.00
104.00
6.00 30.00
7.00
68.00 826.00
11.00
72.88 0.15
12.88 0.10 1.31 0.04 0.17 0.86 2.88 5.05 o.os
0.37
1.82
98.S7
11.00 1.00 9.00 4.00
<3 32.00
231.00 115.00 69.00
95.00 S66.00 52.00 24.00
74.04 0.16
12.15 1.58
0.05 0.22 1.43 2.68 5.29 0.05
0.23
1.77
99.6S
61696t
73.93 0.18
13.18 0.18 1.26 0.04 0.2S 1.04 3.10 5.3S o.os
0.16
1.8S
100.S7
10.00 2.00
14.00 5.00
<3 2S.OO
233.00 113.00 70.00
S42.00 66.00 26.00
AP
PE
ND
IX lla
Chem
ical composition of th
e P
ine Hill G
ranite -S
ericitised Granite
61697t
72.06 0.17
14.02 0.29 1.94 0.08 0.27 1.18 1.87 5.67 0.04
0.17
1.97
99.75
19.00 4.00
<3
6.00
21.00 21.00
302.00 11S.O
O
S2.00
350.00 748.00 79.00 24.00
61698t
71.69 0.16
14.0S 0.27 1.49 0.07 0.36 1.31 2.39 6.13 0.08
0.73
1.92
100.6S
16.00 3.00
<3 s.oo
29.00 28.00
312.00 106.00 S2.00
260.00 879.00 71.00 23.00
61699t
73.30 0.17
13.61 0.06 1.58 0.09 0.22 0.76 3.15 5.39 0.06
0.18
1.78
100.15
24.00 7.00
<3
5.00
<3 48.00
23S.OO
108.00 46.00
7S.OO
596.00
64.00 29.00
6170lt
74.28 o.os
12.62 2.48
0.04 0.11 0.89 2.04 5.48
<0.03
0.34
1.41
99.75
70.00 s.oo
7.00
138.00
61708t 103961°
70.64 <.02
IS.91 0.31 1.35 0.09 0.42 3.17 <
0.3 4.87
<0.03
0.22
3.94
100.73
17.00 3.00
<3 5.00
118.00 <4
79.00 11.00 13.00
105.00 1288.00
7.00 39.00
70.21 0.37
13.31
2.06 0.31 0.66 1.82 O
.S7 S.18 0.12
3.80
98.41
Z-3A
72.31 0
.15
13.63
1.1
5
0.11 0
.34
1.31 2
.73
5
.73
0
.09
0
.05
1.00 0
.06
0
.66
0
.00
1
.19
100.51
2.6
5
1.04
10
.00
15.00
0.0
0
116.00 2
6.0
0
32
.00
3
6.0
0
281.00 9
2.0
0
55.00 71.00 1
6.0
0
864.00 7
6.0
0
24
.00
4
.00
Z-5A
74.88 0
.06
13.19
11
.74
0.0
3
0.1
6
0.9
6
0.11 5
.74
0.01 1.30 1.06 0.22 0.24 0.02 0.66
100.38
2.56 1
.62
1.00 97.00
0.0
0
60.00 16.00
48.00 70.00 78.00 9
8.0
0
170.00 9
6.0
0
15.00
902.00 2
3.0
0
64.00 1.00
Z·IA
73.46 0
.03
12.71
2.58 0
.18
0
.14
0
.76
1.28 4
.90
0.01 0
.12
1.83 0
.37
1.92 0
.0)
0.6
9
100.99
2.7
8
1.4
5
Z·14A
74.21 0.04
13.36
1.42 0
.30
0.18 1
.09
0.51 5.41 0
.08
0
.04
1.26 0
.25
1.48 0
.00
1
.05
10
0.6
8
2.6
5
1.54
1.00 1
.00
1
7.0
0
20
0.0
0
0.0
0
0.0
0
97
.00
1
20
.00
3
1.0
0
98
.00
31
.00
17.00
50
.00
27.00
21
.00
53.00
83
.00
54.00
206.00 1
41
.00
8
1.0
0
53.00 3
1.0
0
21
.00
811.00 1068.00
13.00 13.00
57.00 41.00
2.00 1.00
• Groves (1968), t W
ard (1981), o Patterson (1979), "B
ajw
ah
eta
l(in press)
Z·21A
73
.19
0.11
12.91
1.90 0
.13
0
.45
0
.50
0.97 6.15 0
.03
0
.03
1.65 0
.36
1.18 0
.00
0.37
99
.93
2.6
9
1.41
7.0
0
31.00 0
.00
101.00 12.00
38
.00
51.00
188.00 9
0.0
0
122.00 9
3.0
0
26
.00
996.00 28.00 3
6.0
0
3.0
0
Z·23A
73
.79
0
.06
1
2.0
0
2.44 2.39 0
.63
0
.08
3.01 3.71 0.01 0
.02
0
.73
0
.03
1.38 0
.07
0
.29
100.64
2.75 1.32
2.0
0
43
5.0
0
0.0
0
89
.00
1
43
.00
15
.00
3
9.0
0
29
.00
7
5.0
0
110.00 4
7.0
0
15
.00
93
3.0
0
7.00 3
6.0
0
1.00
05
-IA
73
.72
0
.38
12.88
1.7
7
0.3
6
0.3
2
0.1
9
7.2
5
0.1
4
1.3
3
0.3
5
0.21 1
.50
0
.12
0
.18
nd
100.68
2.6
8
1.4
7
34
.00
5
60
.00
1
8.0
0
83
.00
2
38
.00
71
.00
3
4.0
0
31
8.0
0
22
9.0
0
58
.00
1
29
.00
8
.00
79
7.0
0
38
.00
2
1.0
0
16
.00
Z-31A
74.85 0.05
12
.39
2.51 0
.10
0
.30
0.87 0.14 5.19 0.01 0
.80
1
.25
0
.05
0
.90
0
.46
0
.00
99
.87
2.7
6
1.6
7
1.0
0
44
.00
0
.00
57
.00
7
3.0
0
10
3.0
0
29
.00
5
3.0
0
10
7.0
0
176.00 1
76
.00
5
1.0
0
82
6.0
0
27
.00
6
0.0
0
1.00
.:.. 0 n
Sam
lpleNo.
SIO:Z
TIO:Z
AI:Z03
Fe203(1ol)
FeO
(equlv.) M
DO
M
&()
CeO
N
.:ZO
K2
0
P203
82
03
II:ZO
+ 1120.. co:z s F
L
OI
To
bh
S.G
. P
eralumiD
ous la
d ex
1417A*
70.30 O
.oi 15.00
10.00 0.13 0.70 0.03 0.90 0.90 0.04
1.11 0.03
99.15
Trace E
lemeD
is(ppm)
v Za
c. M
o N
l P
b S
a w
lA
T
h
Ba
Zr
y Ce
u Bl
Sb
A
s so:z u R
b S
r N
b C
r
108.00 4.00
9.00 9.00
87.00
15.00 58.00
5.00
50.00 115.00
7.00
Av. of 3
'
87
.50
0
.04
1
4.9
0
10
.70
0
.06
0
.65
0
.05
1
.00
0
.20
0.01 4
.20
1
.32
0
.02
<0.2
10
0.6
5
14
16
'
63
.60
0
.02
1
6.1
0
12
.20
0
.03
0
.70
0
.07
1
.00
0
.10
0
.02
4
.80
1
.53
0
.02
10
2,1
9
10
4.0
0
4.0
0
11
.00
7
.00
2
8.0
0
11
.00
3
9.0
0
17
.00
41
.00
7
.00
9
.00
AP
PE
ND
IX lla
Chem
ical composition o
f the
Pine H
ill Granite -
Tourm
alinised Granite
14
18
'
66
.80
0
.03
1
4.4
0
10
.80
0
.06
0
.60
0
.03
1
.00
0
.10
0
.00
4
.50
1
.27
0
.02
99
,61
11
7.0
0
4,0
0
5.0
0
18
.00
1
03
.00
5.0
0
40
.00
<3
35
.00
5
.00
6
.00
14
20
'
72
.10
0
.06
1
2.3
0
9.1
0
0.0
8
0.6
0
0.0
5
0.9
0
0.4
0
0.0
2
3.2
0
1.1
6
0.0
2
99
.99
13
5.0
0
8.0
0
4.0
0
18
.00
5
8.0
0
<3
3
5.0
0
11
.00
40
.00
7
.00
3
.00
61694t
71.39 0.02
13.53 6.19 1.98 0.05 0.23 0.06 0.86 0.05
<0.03 6.40
0.06
1.07
99.49
53.00 17.00
<3 <I
21.00 34.00
3.00 42.00 14.00
35.00 7.00 2.00
35.00
z.e•
75
.69
0
.05
1
2.6
9
4.1
5
0.1
6
0.0
8
0.7
2
0.3
2
0.5
9
0.0
2
2.1
0
1.2
6
0.1
4
0.5
4
0.0
0
1.0
8
99
.79
2.7
9
5.21
0.0
0
43
.00
0
.00
96
.00
8
.00
34
.00
6
1.0
0
32
.00
9
1.0
0
21
1.0
0
75
.00
3
0.0
0
11
3.0
0
13
.00
5
8.0
0
0.0
0
Z·1
1"
71
.82
0
.06
1
3.0
6
7.4
9
0.0
6
0.0
4
0.0
2
0.4
9
0.0
8
0.0
4
5.0
7
1.3
0
0.0
2
0.0
5
0.0
0
0.5
8
10
0.1
8
2.8
3
13
.80
1.0
0
60
.00
0
.00
51
.00
8
.00
3.0
0
12
.00
1
.00
8
2.0
0
53
.00
7
.00
6
.14
12
.00
7
.00
4
7.0
0
Z·2
2•
71
.15
0
.02
1
2.6
9
6.8
5
0.0
5
0.1
2
1.1
2
0.3
9
0.3
3
0,0
0
3.8
5
1.7
6
0.0
3
0,7
3
0.0
0
1.41
10
0.5
0
2.7
8
7.7
3
0.0
0
61
.00
0
.00
33
.00
3
.00
27
.00
9
0.0
0
0.0
0
68
.00
1
57
.00
5
5.0
0
16
.00
57
.00
1
6,0
0
36
.00
0
.00
Z·2
4•
71
.39
0
.05
1
3.0
6
7.3
t o.o6 0
.16
0
.02
0
.48
0
.08
0
.00
5
.02
1
.13
0
.10
1
.23
0
.00
0.51
10
0.6
6
2.8
2
14
.10
0.0
0
58
.00
0
.00
0.0
0
5.0
0
3.0
0
9.0
0
0.0
0
75
.00
5
2.0
0
5,0
0
6.0
0
13
,00
6
.00
4
8.0
0
2.0
0
Z·2
5"
73
.32
0
.03
1
4.7
9
3.51 0
.15
0
.17
0
.58
0
.14
1
.86
0
.00
1
.04
1.21 0
.16
0
.77
0.01 4
.48
10
2.2
2
2.7
7
5.2
7
1.0
0
51
.00
0
.00
51
.00
3
9.0
0
3.0
0
12
.00
1
4.0
0
33
.00
9
8.0
0
23
.00
1
3.0
0
53
7.0
0
15
.00
2
8.0
0
1.0
0
*Gro
ves (1968), t W
ard (1981), o Patterson (1979), "B
ajw
ah
eta
! (in press)
Z·2
8•
73
.65
0
.06
1
1.9
2
2.4
7
2.3
4
0.6
2
0.0
8
0.21 3
.68
0.01 2
.13
0.81 0
.13
1
.62
0
.08
0.51
10
0.3
2
2.7
6
2.4
4
0.0
0
15
74
.00
0
.00
65
,00
3
52
.00
14
.00
5
5.0
0
10
.00
9
0.0
0
79
.00
4
3.0
0
27
.00
85
8.0
0
6.0
0
60
.00
1
.00
Z·3
4•
79.51 0
.04
9
.04
3.9
2
0.0
6
0.1
7
1.6
4
0.3
8
0.3
7
0.0
2
2.4
7
0.9
4
0.1
0
0.3
0
0.0
3
2.1
0
10
1.0
9
2.7
8
4.6
6
1.0
0
39
.00
4
5.0
0
52
.00
6
9.0
0
28
.00
5
0.0
0
8.0
0
84
.00
1
93
.00
5
5.0
0
14
.00
75
.00
2
5.0
0
50
.00
2
.00
Z·3
7•
71
.62
0
.06
12.01
5.5
4
0.2
0
0.31 1
.14
0
.42
2.51 0
.00
2
.36
1
.07
0
.22
1
.45
0.01 1
.28
10
0.2
0
2.7
8
2.7
5
1.0
0
24
0.0
0
25
.00
80
.00
7
92
.00
33
.00
5
8.0
0
24
.00
8
9.0
0
17
5.0
0
73
.00
9
7.0
0
57
0.0
0
44
.00
6
9.0
0
1.0
0
Z·4
0•
68.91 0
.04
1
3.6
4
7.~
0.1
6
0.~
0.0
~~
0.1
6
0.0
2
5.1
5
1.1
7
0.~
1.0
2
0.0
0
0.~
10
0.1
4
2.8
3
13
.60
2.0
0
10
3.0
0
15
.00
28
.00
1
9.0
0
29
.00
2
1.0
0
0.0
0
50
.00
1
37
.00
6
0.0
0
13
.00
31
.00
3
2.0
0
23
.00
1
.00
~
0 (")
AP
PE
ND
IX lib
RE
E contents o
f the Pine H
ill Granite
Sa
mp
les a
na
lysed
we
re selected fro
m W
ard (1981), Ge
olo
gy D
ept., University o
f Ta
sma
nia
Sam
ple No.
61
69
4
61
69
6
61
69
7
61
69
8
.61699 6
17
00
(1)
61
70
3
61
70
5
La 1
6.2
1
55
.1
13
3.5
1
27
.5
13
0.3
9
9.0
1
10
.6
17
6.3
C
e 1
4.4
1
40
.6
11
9.6
110.1
11
4.8
1
05
.4
10
9.7
1
54
.7
Pr
11
.2
11
1.3
9
3.9
8
4.5
9
1.8
9
1.4
9
5.3
1
19
.5
Nd
5.5
7
6.3
6
3.5
5
7.9
6
2.5
6
4.9
6
8.2
8
3.6
S
m
6.0
5
2.2
4
5.6
4
0.2
4
4.4
6
6.5
6
4.5
5
1.5
Eu
1.1 9.1
7.6
6
.9
7.8
4
.2
3.3
1
7.0
G
d 4
.6
38
.6
32
.3
28
.2
31.1 5
9.0
5
7.9
3
4.0
T
b
8.2
3
9.8
3
2.0
2
4.5
3
1.4
6
8.8
6
1.0
3
0.6
D
y 1
1.0
3
9.7
2
9.8
25.1
30
.8
80
.7
69
.5
27
.8
Ho
14
.8
40
.8
31
.6
31
.9
89
.3
72
.6
27
.0
Er
15
.3
39
.8
29
.2
19
.8
29
.7
95
.4
76
.9
25
.2
Vb
29.1 4
6.2
3
2.9
2
5.9
3
2.9
1
39
.8
10
9.5
2
5.8
61
70
6
17
9.6
1
57
.2
123.1 8
7.4
5
4.2
1
7.9
3
4.8
3
1.2
2
7.7
2
7.3
2
4.3
2
4.5
61
70
8
14.1 2
1.7
1
8.3
8.1 9
.6
3.7
2
.4
5.6
5.7
1
8.7
.:... 0 ... J
APPENDIX lib
REE contents of the Pine Hill Granite
Samples analysed were selected from Ward (1981), Geology Dept., University of Tasmania
Sample No. 61694 61696 61697 61698 .61699 61700(1) 61703 61705
La 16.2 155.1 133.5 127.5 130.3 99.0 110.6 176.3 Ce 14.4 140.6 119.6 110.1 114.8 105.4 109.7 154.7 Pr 11.2 111.3 93.9 84.5 91.8 91.4 95.3 119.5 Nd 5.5 76.3 63.5 57.9 62.5 64.9 68.2 83.6 Sm 6.0 52.2 45.6 40.2 44.4 66.5 64.5 51.5 Eu 1.1 9.1 7.6 6.9 7.8 4.2 3.3 17.0 Gd 4.6 38.6 32.3 28.2 31.1 59.0 57.9 34.0 Tb 8.2 39.8 32.0 24.5 31.4 68.8 61.0 30.6 Dy 11.0 39.7 29.8 25.1 30.8 80.7 69.5 27.8 Ho 14.8 40.8 31.6 31.9 89.3 72.6 27.0 Er 15.3 39.8 29.2 19.8 29.7 95.4 76.9 25.2 Vb 29.1 46.2 32.9 25.9 32.9 139.8 109.5 25.8
61706
179.6 157.2 123.1 87.4 54.2 17.9 34.8 31.2 27.7 27.3 24.3 24.5
61708
14.1 21.7 18.3
8.1 9.6 3.7 2.4
5.6
5.7 18.7
.:... 0 ... J
AP
PE
ND
IX lie
Plagioclase m
icroprobe data for the Pine H
ill Granite
Sam
ple No.
61
70
5
61
70
5
61
70
5
61
70
5
61
70
5
core
rim
co
re
rim
core
Na20
4.3
7
7.3
7
7.5
0
8.5
0
7.0
8
MgO
0
.00
0
.01
0
.00
0
.00
0
.00
A
l20
3
3b
.35
2
5.9
8
25
.55
2
4.0
9
26
.19
S
i02
5
2.5
3
59
.13
5
9.2
8
61
.50
5
8.3
5
K2
0
0.1
1
0.2
1
0.2
6
0.2
5
0.2
3
CaO
1
2.6
1
7.0
2
6.6
6
4.91 7
.40
C
r20
3
0.0
2
0.0
0
0.0
0
0.0
0
0.0
0
Ti0
2
0.0
4
0.0
0
0.0
3
0.0
1
0.0
0
MnO
0
.02
0
.00
0.01
0.0
6
0.01 FeO
0
.09
0
.13
0
.08
0
.10
0.11
SrO
0
.27
0
.26
0
.28
0
.28
0
.27
B
aO
0.0
0
0.0
1
0.0
0
0.0
0
0.0
0
To
tal
10
0.4
0
10
0.1
3
99
.63
9
9.7
0
99
.63
AB
3
8.2
8
64
.71
6
6.0
7.
74
.71
6
2.5
7
00
0
.65
1
.22
1
.49
1
.44
1.31
AN
6
1.0
7
34
.06
3
2.4
5
23
.85
3
6.1
2
(Fe
+M
n)/(F
e+
Mn
+M
g)
10
0.0
00
9
0.0
10
1
00
.00
0
10
0.0
00
1
00
.00
0
61
70
5
61
70
5
rim
core
7.9
8
6.8
0
0.0
0
0.0
0
24
.88
2
6.0
4
60
.92
5
8.8
3
0.2
6
0.4
3
5.7
6
7.2
7
0.0
2
0.0
0
0.0
1
0.0
0
0.0
6
0.0
5
0.0
2
0.1
4
0.2
4
0.2
7
0.0
0
0.0
0
10
0.1
2
99
.81
70
.42
6
1.2
7
1.4
9
2.5
3
28
.09
3
6.2
1
98
.96
0
10
0.0
00
61
70
5
rim
6.8
7
0.0
0
26
.50
5
8.3
5
0.2
4
7.7
7
0.0
0
0.0
4
0.0
0
0.1
3
0.2
4
0.0
0
10
0.1
4
60
.70
1
.38
3
7.9
2
96
.15
0
~
0 co
40S
APPENDIX lie
Potassium feldspar microprobe data for the Pine Hill Granite
Sample No. 61705 61705 61705
Na20 1.41 1.42 1.30 MgO 0.01 0.01 0.00 Al203 19.18 19.09 19.23 5102 64.31 64.28 64.45 1<20 14.79 14.62 15.12 CaO 0.08 0.14 0.03 Cr203 0.04 0.04 0.01 Ti02 0.03 0.05 0.00 MnO 0.06 0.00 0.14 FeO 0.05 0.04 0.09 SrO 0.18 0.17 0.22 BaO 0.17 0.30 0.14
Total 100.30 100.16 100.74
AB 12.55 12.72 11.52 a:t . 86.78 86.07 88.08 AN 0.37 0.68 0.16 cs 0.30 0.54 0.24
(Fe+Mn)/(Fe+Mn+Mg) 86.660 74.080 100.000
AP
PE
ND
IX lie
Biotite m
icroprobe data for the Pine H
ill Granite
Sam
ple No.
61
70
5
61
70
5
61
70
5
61
70
5
61
70
5
61
70
5
61
70
5
61
70
5
F
1.2
9
1.2
0
1.5
8
0.4
9
1.41 0
.95
1.61
0.3
5
Na
20
0
.12
0
.04
0
.09
0
.04
0
.08
0
.10
0
.07
0
.05
'MgO
7
.09
7
.53
7
.16
7
.18
6
.96
6
.50
7
.07
7
.28
Al2
03
1
3.5
4
13
.52
1
4.2
2
14
.46
1
4.0
2
14
.24
1
4.0
2
14
.20
Si0
2
. 34
.82
3
4.5
9
34
.53
3
5.0
0
35
.32
3
4.6
3
34
.96
3
5.4
3
Cl
0.2
8
0.3
9
0.1
7
0.2
7
0.4
6
0.2
3
0.2
2
0.3
2
K2
0
9.8
6
9.2
3
9.6
8
9.6
3
9.6
5
9.7
8
9.6
3
9.7
0
CaO
0
.00
0
.78
0
.01
0
.02
0
.06
0
.07
0
.00
0
.00
Ti0
2
4.2
4
3.0
0
4.2
2
3.6
2
4.3
9
4.5
5
4.5
6
4.0
4
MnO
0
.16
0
.20
0
.32
0
.15
0
.27
0.11
0.1
7
0.1
4
FeO
23
.23
2
2.8
8
22
.58
2
2.8
0
24
.09
2
2.9
3
22
.64
2
1.6
4
H2
0
3.0
4
3.0
1
2.9
4
3.4
4
3.0
1
3.2
2
2.9
3
3.5
0
O:F
0
.54
20
-0
.50
53
-0
.66
32
-0
.20
68
-0
.59
20
-0
.39
97
-0
.67
96
-0
.14
57
-
O:C
I 0
.06
39
-0
.08
69
-0
.03
78
-0
.06
03
-0
.10
43
-0
.05
24
-0
.04
84
-0
.07
27
-
To
tal
97
.07
9
5.7
7
96
.78
9
6.8
4
99
.00
9
6.8
5
97
.14
9
6.4
4
No. C
ations 1
5.6
2
15
.66
1
5.5
9
15
.57
1
5.5
7
15
.54
1
5.5
2
15
.50
(Fe
+M
n)/(F
e+
Mn
+M
g)
64
.91
6
3.2
2
64
.23
6
4.2
0
66
.26
6
6.5
5
64
.42
6
2.6
7
~
..... C
'
APPENDIX ill- METAL ACCUMULATION DIAGRAMS FEDERAL-BASSETT FAULT
4J•
I'
Federal Bassett Fault - NW-SE Longitudinal Projection - Metal AGcumulation
8 "' 8 "' "' "' N 8 N 8 N N
8 - 8 -Cl) co ~ 8 ~ 8
8 :;;: ~ :;;: ~ 8 8
-67200 -66800 -66400 -66000 -65600 -65200 -67200 -66800 -66400 -66000 -65600 -65200
Unear colour stretch - Red = Sn > 1 0 metres x % Unear colour stretch - Red = S > 200 metres x % Linear colour stretch - Red = Fe > 200 metres x o/o
0 "' 0 ... 8 "' 0 "' 0 "' "' N 8 N 8 N 8 N N N
8 - 8 iii 8 ~ co ~ 8 ~ 8 ~
~ ~ - ~ 8 8 8
-67200 -66800 -66400 -66000 -65600 -65200 -67200 -66800 -66400 ·66000 -66600 -65200 -67200 -66800 -66400 -66000 -65600 -65200
Unear colour stretch - Red = Cu > 5 metres x % Unear colour stretch - Red = Zn > 1 metres x % Unear colour stretch - Red = Pb > 1 metres x %
8 "' 0 "' 8~~~ "' 0 ... N 0 N g :::: .. ' · ... ,lffi'.' .·.. c'. . ·.· 8 N 0 N
~+ ~+ 8 + •wt•LtlD~~~~tt iii iii -Cl)
8 8 ~ . . :: ·· ···4> - -""·· ... ~!:ar . . ... ·· 8
~+ ~__;4--§ ~+~+~§ ~+
-67200 -66800 -66400 -66000 -66600
Unear colour stretch - Red = W > 0.5 metres x %
-66200 -67200 -66800 -66400 -66000 -65600 -66200 -67200 -66800 -66400 -66000 -66600 -65200
Unear colour stretch - Red = Bi > 0.5 metres x % Unear colour stretch - Red = Thickness > 1 0 metres
IDWA2 grlddlng, 10m grid mesh, 150m scan distance Scale: 1 :25,000 - Mine Grid Coordinates
8 "' "' N 8 N
~+I iii 8
~+I
-66800
Unear colour stretch - Red = As > 30 metres x %
8 N N
~+1 iii 8
~+I ~ +-~-/ 8
-66400 -65200
colour stretch - Red = Ag > 200 metres x ppm
8~ ·.:·+= ... ~~ N • • • ---:~M :. ·. • 8 N •• • .. •• •. :• • •. • ~ • • ~. . . . : : ...... ..... : ~
:. . . ... : · .. · :·.:·.:· .. -:. ··"~ :-c •• :~;: ~ •• V;-:.:~ ··~i-W ·i"! ·.~
8 t r ·= =-=·=~. -;..: .... =-~ =----~+··.-... ~~?, .... ,-.+iii co ·::-:-·· .··:····.:::..·:::: :··~':.. •• ....... ·=··· 8 - . . ...•. . ·JI· . ........ :·:.; ... _._ .......... ~ -~"\. .!.• :---. . . . . . . . ·.: •: . . . . . . .. : . .. . . : f.. . + + + t§ . . .. . . . .
-67200 -66800 -66400 -66000 -66600 -66200
Appendix Ill
( )
··-'<t
43500
43500
43500
43900
Sn Linear colour stretch
Red=Sn>Smx%
+
44300
Cu
44700
Linear colour stretch Red = Cu > 0.5 m x o/o
+
43900 44300
w Linear colour stretch
Red = W > 0.1 m X %
+
44700
43900 44300 44700
Shear P - Plan View - Metal Accumulation
43500
43500
43500
43900
s Linear colour stretch
Red=S>50mx%
+
44300
Zn
44700
Linear colour stretch Red = Zn > 0.2 m x %
+
43900 44300
Bi Linear colour stretch
Red = Bl > 0.1 m x %
+
43900 44300
44700
44700
43500
43500
43500
Fe Linear colour stretch
Red = Fe > 100 m x %
+
43900 44300 44700
Pb Linear colour stretch
Red = Pb > 0.2 m x %
43900
43900
+
44300
Thickness Linear colour stretch
Red=>Sm
+
44300
44700
44700
IDW"'2 grlddlng, 1Om grid mesh, 150m scan distance Scale: 1 :20,000 • Mine Grid Coordinates
43500
As Linear colour stretch
Red=As>Smx%
+
44700
Ag Linear colour stretch
Red=Ag>20mxppm
+
44700
Fault R.L. Data Points
+
43900 44300 44700
Appendix IV
43500 43900
43500 43900
43500 43900
Sn Linear colour stretch
Red=Sn>5mx%
+
44300
44300
44300
44700
44700
44700
Shear L - Plan View - Metal Accumulation
43500
43500
43500
43900
43900
43900
s Unear colour stretch
Red=S>SOmx%
+
44300
44300
44300
44700
44700
44700
43500 43900
43500 43900
43500 43900
44300
44300
Thickness Unear colour stretch
Red=> 5 m
+
44300
IDWA2 grlddlng, 1Om grid mesh, 150m scan distance Scale: 1 :20,000 - Mine Grid Coordinates
44700
44700
44700 43500
As Unear colour stretch
Red=As>5mxo/o
+
44700
Ag Unear colour stretch
Red=Ag>20mxppm
+
44700
Fault R.L. Data Points
+
43900 44300 44700
Appendix V
, .. ,-~
41c
APPENDIX VI- OXIDE-SILICATE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 Tm C02 Tm Cl Th
111107 Qz P? 2 356.3 az P? 2 347. Qz P? 2 ·-22 -3 342 Qz P? 2 363 az P? 2 354
111124 Cass(zoned) p 38V 327.2 Cass(zoned) p 38V -24.8 345.8
111125 Cass(zoned) p 1A -28 -7.6 394.5 111160 Cass P? 1A 343.2
Cass P? 1A -2.6 355.2 Cass P? 1A -21.2 353.2 Cass s 1A -4.9 227.3 Cass s 1A -4.9 227.3 Cass s 1A -4.9 227.3 Cass s 1A -4.9 227.3 Cass s 1A -24.5 -5.2 248.3 Cass s 1A -24.5 -5.2 248.3 Cass s 1A -5.2 230.6 Cass s 1A -5.2 230.6 Cass P? 1A 285.1 Cass s 1A -24.5 -5.2 248.3
111f69 Cass(zoned) PS 1A -3.5 374 Cass(zoned) PS 1A 369
Qz PS 38V 295.7 Qz PS 38V -24.9 372 Qz PS 38V -24.2 361.6 Qz PS 38V -25.4 374
111179 Cass(zoned) p 38V -26.4 300.6 Cass(zoned) p 3BV -7 Cass(zoned) PS 1A -39 -5.9 358.6 Cass(zoned) PS 1A 378.6 Cass(zoned) PS 1A 359.9 Cass(zoned) PS 1A 359.8 Cass(zoned) p 38V 302.9 Cass(zoned) p 38V 300.9 Cass(zoned) p 38V 301.9 Cass(zoned) p 3BV 303.5
111200 Qz(zoned) p 3BV 358 Qz(zoned) p 38V 358.4 Qz(zoned) p 38V 390.1 Qz(zoned) p 38V -3 355.7
Qz(zoned) p 1A -21.3 Qz(zoned) p 1A -21.3
111214 Cass P? 3BV 361.3
Cass P? 1A -12 366.4 Cass P? 1A 379.3 Cass P? 38V 361.2
111251 Cass s 38V 331.8
Cass s 38V 339.2
Cass s . 38V 329.1
111257 Cass PS 38V -15 301
Cass PS 38V -12.6 350.8 Cass PS 38V 295.4
Cass PS 38V -12.5 278.7
Cass PS 38V -13.7 279.8
Cass PS 38V -23.2 324.2
Cass PS 38V -23.2 324.2
111262 Cass(zoned) p 38V -5.6 340
Cass(zoned) s 38V -12.5 176
111277 Qz PS 38V -8.9 264.3
Qz PS 38V -28.7 -9.1 248.1
Qz PS 38V -5.5 241.1
Qz s 3BV -5 189
Qz s 38V -5 176.9
Qz s 3BV -5 185
Cass P? 38V -6 351.3
Cass s 1A -5.7 170.6 Cass s 1A -5.4
Cass s 38V -4 189.7
4~'·
APPENDIX VI - OXIDE-SILICATE STAGE
CAT. NO. HOST CLASS IF. TYPE Te Tm H20 Tm C02 TmCI Th Cass s 3BV ·4 229.3 Cass s 3BV ·4 Cass P? 3BV 279 Cass P? 38V 324.8 Cass P? 38V 400.7
111280 Cass(zoned) p 38V ·15.1 359.5 Cass(zoned) p 38V 400 Cass(zoned) p 3BV 400 Cass(zoned) p 3BV 400
111296 Qz(zoned) p 1A -0.5 158.8 Qz(zoned) p 1A ·1.6 140.1 Qz(zoned) p 1A ·1.6 163.7 Qz(zoned) p 1A 169.9 Qz(zoned) p 1A 181 Qz(zoned) p 1A 179.6
111308 Cass(zoned) p 1A 395.2 Cass(zoned) p 1A 407.6
111311 Cass(zoned) p 3BV -54.7 ·4.2 379.6 111321 Cass(zoned) p 1A 374.8
Cass(zoned) p 1A 363.9 Cass(zoned) p 1A 370.4 Cass(zoned) p 1A 367.6 Cass(zoned) p 1A 369.9
110982 Qz(zoned) FS 1A 371.5 Qz(zoned) FS 1A 397.1 Qz(zoned) FS 1A 362.1 Qz(zoned) FS 1A 335.8 Oz(zoned) FS 1A 340.8 Qz(zoned) FS 1A 340.8
110987 Cass P? 1A 409.8 Cass P? 1A 410.7 Cass P? 1A 415.6
111004 Cass P? 1A 300.5 Cass P? 1A 286.9
111014 Au s 1A 341.4 Au s 1A ·0.6 319.7 Au s 1A ·0.6 328 Au P? 1A 369.5
42C
APPENDIX VI- SULPHIDE STAGE
CAT. NO. HOST CLASS IF. TYPE Te Tm H20 TmC02 TmCI Th
111 088 FU s 3AD -0.2 141.8 FU s 3AD -4.4 130.6 FU s 3AD 110.4 FU s 3AD 116.7 FU s 3AD 120.4 FU s 3AD -0.5 117.9 FU s 1A 0 269.3 FU s 1A 0 269.3 FU s 1A 0 269.3 FU s 1A -2.2 269.3 FU s 1A 0 209.6 FU s 1A -0.4 180.9 FU s 1A -0.4 269.3 Fu s 1A 0 179.5 FU s 1A 0 194 FU s 5 2.5 FU s 5 2.5 FU s 5 2.5 FU s 5 2.5 Fu s 38V -10.8 140.6 FU s 38V -31.1 121.7 FU s 38V -17.5 125.7 FU s 38V -17.5 97.4 FU s 38V -51.5 -13.2 188.4 FU s 1A -13.2 318 FU s 38V -2.5 174.9 FU s 1A -60.3 -14.2 FU s 1A -0.8 FU s 1A -60.3 -14.9 146.5 FU s 1A -8.3 386.8 FU s 18 -5 183 FU s 38V -60.3 -14.2 FU s 1A -1.5 210 FU s 18 -56.6 -14.5 188.4 FU s 1A -45 -10 227 FU s 1A -45.6 -14.9 233.5 FU s 1A -45 -13.9 164 FU s 38V -45 -13.9 163.5 FU s 1A -58 -14 393 FU s 1A -46 -11.3 222.7 FU s 1A -1.4 175 Fu s 1A -54 -16.1 221.6 Flu s 1A -66 -6.6 363.7 FU s 1A -0.8 173.7 Flu FS 1A -4.6 265.5 Fu FS 1A -4.6 319.8 Flu FS 1A -4.6 306.3 FU FS 1A -4.6 312.8 FU FS 1A -4.6 257.8 Flu FS 1A -4.6 300.6 . Flu FS 1A -4.6 321.6 FU FS 1A -4.6 237.4 FU FS 1A -4.6 284.5 Flu FS 1A -4.6 286.5 Flu FS 1A -4.6 306
111 091 FU s 38V -37 -2 161 FU s 38V -37 -2 121 FU s 38V -37 -4.5 264.2 FU s 38V -37 -4 Flu s 38V -37 -3 119 FU s 38V -37 -4.2 119 Flu s 38V -37 -4.5 264.2 FU s 38V -37 -3.5 Flu s 38V -37 -3.3 264.2 Flu s 38V -37 -5.3 198.6 FU s 38V -37 -2.4 184.4 FU s 38V -37 -4.2 119 FU s 1A -3.1 197.8 Fh.J s 1A -3.1 175.6
4~·
APPENDIX VI- SULPHIDE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 Tm C02 TmCI Th FkJ s 1A -3.1 220.6 FkJ s 1A -3.1 219.5 Fkl s 1A -3.1 296.5 FkJ s 1A -3.1 263.2 FkJ s 1A -3.1 250.8 Flu s 1A -3.1 157.1 FkJ s 1A -3.1 226 FkJ s 1A -3.1 227.1
111094 FkJ s 1A -5.2 127.8 FkJ s 1A -3.5 FkJ s 1A -1.1 148 FkJ s 1A -2 FkJ s 1A -2.2 148 Flu s 1A -2 154.7 Flu s 1A -2 150 Flu s 1A -1.8 135.2 Flu s 1A -4.4 160.3 Qz s 1A -3.5 221 Qz s 1A -2.9 163.9 Qz s 1A -2.6 182.1 Qz s 1A -4.4 193 Qz s 1A ·4.5 239 Qz s 1A -5 261 Qz s 1A -3.5 292.4 Qz s 1A -3.5 267.5 Qz s 1A -2.7 210.4 Qz s 1A -3.8 203.1 Qz s 1A -4.1 195 Qz s 1A -3.6 198.1 Qz s 1A -3.6 300.5 Qz FS 1A -37.8 -6.5 144.1 Qz FS 3BV -6.5 199.6 Qz FS 3BV -6.5 195.6 Qz FS 3BV -6.5 212.6 Qz FS 3BV -3.6 207.4 Qz FS 5 -6.5 199
111098 Flu( zoned) P? 3BV -21 -8.6 188.6 Flu( zoned) P? 3BV -8 186.2 Flu( zoned) P? 3BV -8.2 222.2
1111 00 Flu FS 3BV -61.8 235 FkJ FS 3BV -61.8 240.4 Flu FS 3BV -61.8 Flu s 3BV 280.7 Flu s 3BV -32.7 -13.5 270 FkJ s 3BV -3.8 Flu s 1A -3.8 156.1 Flu s 1A -1.8 228.2 Flu s 1A 173.5
111112 Qz(zoned) s 1A -0.1 Qz(zoned) s 1A -28 177 Qz(zoned) p - 1A -28.4 -3.3 Qz(zoned) FS 1A -8 184 Qz(zoned) p 1A 177.5
Qz FS 1A -3.3 189 Qz FS 1A -3.3 186 Qz FS 1A 182
111115 Qz(zoned) s 1A 124.6 Qz(zoned) s 1A -2.2 143.2 Qz(zoned) s 1A 149.6 Qz(zoned) s 1A -1.9 159.1 Qz(zoned) s 1A 218 Qz(zoned) s 1A -1.6
Qz s 1A -52.5 -18.5 Qz s 3BV -54 -21 131.6 Qz P? 3BV -5.5 253 Qz s 1A -5.4 Qz P? 1A -55 -21.5 Qz P? 1A -55 -21.5 Qz P? 1A -55 -21.5 Qz P? 1A -55 -21.5
4':"·-~-
APPENDIX VI- SULPHIDE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 Tm C02 Tm Cl Th Qz P? 3BV
111117 Qz(zoned) p 1A ·3.5 Oz(zoned) p 1A -4.4 233.5 Oz(zoned) p 1A -3.7 234.5 Qz(zoned) p 1A 236.7
111135 Oz(zoned) s 1A -3.5 145.5 Qz(zoned) p 3BV -8.5 232
111137 Oz(zoned) p 3BV -29.4 295 Oz(zoned) p 3BV -23.8 -1.5 295 Qz(zoned) p 3BV -23.8 -2 299.1 Qz(zoned) FS 1A -2.5 188 Qz(zoned) FS 1A 185 Qz(zoned) FS 1A -2 183 Qz(zoned) FS 1A -44 -7.8 191.9 Qz(zoned) FS 1A -44 -7.9 222.7 Qz(zoned) F5 1A -44 -3.6 201.9 Qz(zoned) F5 1A -44 -7.9 214.7 Qz(zoned) F5 1A 213 Qz(zoned) F5 1A -44 -7.2 200.1
111140 Qz(+cass) p 1A -7 208.2 Qz(+cass) p 1A -7 205.1 0Z(+Ca5S) p 1A 228 -Oz(+cass) p 1A 209.7 Qz(+Ca5S} p 1A -6.5 211.5 0Z(+Ca5S) p 4 -56.7 -2 9.1 211.5 Qz(+cass) p 1A 311.1 Oz(+cass) p 4 -56.7 Oz(+cass) p 4 -56.7 0Z(+Ca5S) p 4 -57 Oz(+cass) p 4 -57.8 9 0Z(+Ca5S) p 4 -57.5
111143 Qz F5 1A -24.2 -9 264.3 Qz FS 4 -57.8 -10 Qz FS 1A -12.6 200 Qz F5 1A -11.1 227 Qz FS 1A -25.3 -9.8 224.9 Qz FS 1A -23.4 -10.2 207.4
111153 Fl(zoned) p 1A -26.5 -4.7 126 Fl(zoned) p 3BV -26.5 297.3 Fl(zoned) p 3BV -26.5 -8 310.1 Fl(zoned) p 3BV -26.5 -8 323 Fl(zoned) p 3BV -26.5 -8 298.2 Fl(zoned) p 1A -26.5 -5.4 148 Fl(zoned) p 3BV -26.5 -8 298.2 Fl(zoned) p 3BV -26.5 -8 302
111159 Qz(zoned) p 1A -4.9 215.7 Qz(zoned) p 1A -5 230.6 Qz(zoned) p 1A -54.2 -5.6 209.7 Oz(zoned) p 1A -6.3 Oz(zoned) p 1A -3.6 309.9 Qz(zoned) p - 1A -5 170.2 Qz(zoned) p 1A -1.8 209.1
111174 Oz(zoned) p 1A 286 Oz(zoned) p 1A 286 Oz(zoned) p 1A -0.5 165.7 Qz(zoned) p 1A -0.5 163.4 Oz(zoned) p 1A -0.5 158.2 Qz(zoned) p 1A -0.5 158.1 Qz(zoned) p 1A -0.5 158.5 Qz(zoned) p 1A -0.5 156.5 Qz(zoned) p 1A -0.5 160.8
111205 Qz(zoned) p 3BV -4.5 251.8 Qz(zoned) p 3BV -4.4 178 Qz(zoned) p 3BV -4.3 200.1 Qz(zoned) p 3BV -4 185.9 Oz(zoned) p 3BV -4 211.8 Oz(zoned) p 3BV -4.3 223.4
111209 Flu( zoned) p 1A -0.2 254.5 Flu( zoned) p 1A -6.9 240.7 Flu( zoned) p 1A -6.6 249.7
42:..
APPENDIX VI- SULPHIDE STAGE
CAT. NO. HOST Cl.ASSIF. TYPE Te Tm H20 Tm C02 TmCI Th Flu( zoned) p 1A -6.8 220.1 Flu( zoned) p 1A -6.8 220.1 Flu( zoned) p 1A -6.8 220.1 Flu(zoned) p 1A -6.8 220.1
111214 Cass(zoned) p 38V 361.3 Cass(zoned) p 1A -12 366.4 Cass(zoned) p 1A 379.3 Cass(zoned) p 38V 361.2
111221 Qz(zoned) p 1A -5.8 204.9 Qz(zoned) p 1A -5.8 204.9 Oz(zoned) p 1A -5.8 204.9 Qz(zoned) p 1A -5.8 204.9 Qz(zoned) p 1A -5.9 Qz(zoned) p 1A -5.1 185.9 Qz(zoned) p 38V -46 -5.5 198.4 Qz(zoned) p 38V -46 197.8 Qz(zoned) p 38V -4.9
111237 Flu( zoned) p 38V -4 311.2 Flu( zoned) p 38V -4 264 Flu( zoned) p 38V -2.6 269.5 Flu( zoned) p 38V -22.9 177.3
111 244 Qz s 1A -4.6 168.9 Qz s 1A -4.6 Qz s 1A -5.3 133.6 Qz s 5 -5.4 Qz s 5 -3.2
111249 Qz-bi s 1A -6 Oz-bi s 38V 175.9 Qz-bi s 38V -3 195.6 Qz-bi s 38V -1.5 206 Qz-bi s 38V -1.5 207.3 Qz-bi s 1A -1.5 Qz-bi s 1A 145.6 Qz-bi FS 1A -1 196 Qz-bi FS 1A -1 196 Oz-bi FS 1A -1 195.5 Qz-bi FS 1A -5.1 234.1 Qz-bi FS 1A -5.1 232.2
111285 Qz s 38V 257.7 Qz s 38V 245.6 Qz s 3BV 317 Qz P? 38V 370.1
111289 Qz(zoned) p 3BV -22 -9.5 175 Oz(zoned) p 3BV -2.5 171 Qz(zoned) p 38V -21 -7 169.8 Qz(zoned) p 38V -22 -4.8 164.1 Qz(zoned) p 38V -5.4 179.2 Qz(zoned) p 38V -5.4 186.7 Qz(zoned) p 38V -5.4 179.8
111 293 Flu s 1A -21.8 -3.5 215.1 Flu s . 1A -21.8 -3.5 215.1 Flu s 1A -21.8 -3.5 215.2 Flu s 1A -21.8 -3.5 215.2 Flu s 1A -2i .8 -3.5 215.3 Flu s 1A -21.8 -3.5 215.3 Fh.J s 1A -21.8 -3.5 215.4 Flu s 1A -21.8 -3.5 215.4 Fh.J s 1A -21.8 -3.5 215.5 Flu s 1A -21.8 -3.5 215.5 Flu s 1A -21.8 -3.5 215.6 Flu s 1A -21.8 -3.5 215.6 Flu s 1A -21.8 -3.5 215.7 Flu s 1A -21.8 -3.5 215.7 Flu s 1A -21.8 -3.5 215.8 Flu s 1A -21.8 -3.5 215.8 Fh.J s 1A -21.8 -3.5 215.9 Flu s 1A -21.8 -3.5 215.9 Flu s 1A -21.8 -3.5 216 Flu s 1A -21.8 -3.5 216 Flu s 1A -21.8 -3.5 216.1
42•1
APPENDIX VI- SULPHIDE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 TmC02 Tm Cl Th FiJ s 1A ·21.8 -3.5 216.1 FiJ s 1A -21.8 -3.5 216.2 Fu s 1A -21.8 -3.5 216.2 FiJ s 1A -21.8 -3.5 216.3 Fu s 1A -21.8 -3.5 216.3 FiJ s 1A -21.8 -3.5 216.4 FiJ s 1A -21.8 -3.5 216.4 FiJ s 1A ·21.8 -3.5 216.5 FiJ s 1A -21.8 -3.5 216.5 FiJ s 1A -21.8 -3.5 216.6 FiJ s 1A -21.8 -3.5 216.7 FiJ s 1A -21.8 -3.5 216.7 FiJ s 1A -21.8 -3.5 216.8 FiJ s 1A -21.8 -3.5 216.8 Fu s 1A -21.8 -3.5 216.9 FiJ s 1A ·21.8 -3.5 216.9 FiJ s 1A ·21.8 -3.5 217 FiJ s 1A -21.8 -3.5 217 FiJ s 1A -21.8 -3.5 217.1 FiJ s 1A -21.8 -3.5 217.1 FiJ s 1A -21.8 -3.5 217.2 FiJ s 1A -21.8 -3.5 217.2 FiJ s 1A -21.8 -3.5 217.3 FiJ s 1A -21.8 -3.5 217.3 FiJ s 1A -21.8 -3.5 217.4 FiJ s 1A -21.8 -3.5 217.4 FiJ s 1A -21.8 -3.5 217.5 FiJ s 1A -21.8 -3.5 217.5 FiJ s 1A -21.8 -3.5 217.6 FiJ s 1A -21.8 -3.5 217.6
111 308 Cass(zoned) p 1A 395.2 Cass(zoned) p 1A 407.6 Cass(zoned) p 3AD -54.7 -22 2.5 379.6
110979 Qz P? 3BV -40.6 -22.4 164 Qz P? 3BV -39.1" -24.1 194.8 Qz P? 3BV -39.5 -22.7 190.1 Qz P? 3BV -38.3 ·22 Qz P? 3BV -38 -21.7
42c
APPENDIX VI- BASE METAL STAGE
CAT. NO. HOST ClASS IF. TYPE Te Tm H20 Tm C02 TmCI Th
1111 02 Qz(zoned) late vein p 1A -6.1 184 Qz(zoned) late vein p 1A -6 184 Qz(zoned) late vein p 1A : -6.1 183 Qz(zoned) late vein p 1A -6.1 182 Oz(zoned) late vein p 1A 181.5 Qz(zoned) late vein p 1A 190 Qz(zoned) late vein p 1A -5.8 185.5 Qz(zoned) late vein p 1A 190.5 Oz(zoned) late vein p 1A 180.7
111082 Qz(zoned) S? lA -3.5 200.4 Qz(zoned) S? lA -3.2 197.7 Qz(zoned) S? lA -3.2 273.4 Qz(zoned) S? lA -3.2 192.2 Qz(zoned) S? lA -3.6 192 Oz(zoned) S? lA 190.2 Qz(zoned) S? lA 206.3
111084 Au s 3BV -4 140.9 Au s 3BV -5 Au s 3BV -3 127.5 Au s 3BV -6 121.2 Au s 3BV -2.3 131.8 Au s 3BV 131.9 Au s 3BV -5.5 116.2 Au s 3BV 125.4 Au s 3BV 124 Au s 5 -10.1 Au s 5 -10.1 Au s 5 -10.1 Au s 3BV -3.7 152.7
111087 Flu in qz(zoned) P3 3BV -2.2 180 Flu in qz(zoned) FS 3BV 110.5 Flu in qz(zoned) P3 3BV 96.4 Flu in qz(zoned) P3 3BV 141 Flu in qz(zoned) FS 3BV 181
111 095 Qz s 1A -39.7 -6.7 163.6 Qz s 1A -6.7 174.8 Qz s 1A -6.7 158.8 Qz FS 3BV -4.5 193.6 Qz FS 3BV -4.5 Qz FS 3BV -4.5 Oz FS 3BV -4.5 Qz P3 3BV -4.5 198.4
111118 Qz s 1A -2.2 Oz s 3BV -0.6 Qz s 1A 244.5 az s 3BV -0.6 Qz s 3BV -2.5 143.2 Qz s 3BV -2.5 217.9 Qz s 1A -3.3 156.9 Qz s 1A -3.3 166.3 Qz FS. 3BV -1.5 204.5 Qz FS 1A 238 Qz FS 3BV 242 Oz P3 3BV -1.5 183 Oz P3 3BV -2 158.7 Qz FS 3BV -2 174.1 az FS 3BV 221.1
111120 Qz(zoned) p 1A -1.5 191.4 Qz(zoned) p 1A 191.5 Qz(zoned) p 1A -1 177.9 Qz(zoned) p 1A -1 191.5 Qz(zoned) p 3BV -1.5 182.3 Qz(zoned) p 3BV 177.5
111142 Carb(zoned) p 1A 282 Carb(zoned) p 1A 245 Carb(zoned) p 1A -1 187.6
111175 Qz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5
42
APPENDIX VI- BASE METAL STAGE
CAT. NO. HOST CLASSF. TYPE Te Tm H20 Tm C02 TmCI Th
Qz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5 Oz(zoned) p 1A -6 160.5 Oz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5 Oz(zoned) p 1A -6 160.5 Oz(zoned) p 1A -6 160.5 Qz(zoned) p 1A -6 160.5
111231 Oz(zoned) p 3BV -6.8 176.3 Oz(zoned) p 38V 202.4 Oz(zoned) p 38V 191.8 Qz(zoned) p 38V -5.9 201.3 Oz(zoned) p 38V -5 195 Oz(zoned) p 38V 203.4 Oz(zoned) p 38V 203.4 Oz(zoned) p 38V 203.4
42:-
APPENDIX VI- CARBONATE STAGE
CAT. NO. HOST CLASSIF. 1YPE Te Tm H20 Tm C02 TmCI Th
111180 Qz s 1A -0.5 101.1 F\J s 1A -0.5 145.9 F\J s 1A -0.5 145.9 F\J s 1A -0.5 145.9 FkJ s 1A -0.5 145.9
111213 Qz(zoned) p 3BV -7.2 241.9 Qz(zoned) p 3BV -4.6 Qz(zoned) p 3BV 244 Qz(zoned) p 3BV 232.4
111231 Qz(zoned) p 3BV -6.8 176.3 Qz(zoned) p 3BV 202.4 Qz(zoned) p 3BV 191.8 Qz(zoned) p 3BV -5.9 201.3 Oz(zoned) p 3BV -5 195 Qz(zoned) p 3BV 203.4 Qz(zoned) p 3BV 203.4 Qz(zoned) p 3BV 203.4
111252 Oz(zoned) p 1A -6.1 182.4 Qz(zoned) p 1A -0.1 182.8 Oz(zoned) p 1A -0.1 179.6 Qz(zoned) p 1A 143 Qz(zoned) p 1A -2.3 143 Qz(zoned) p 1A -0.6 244.4 Qz(zoned) p 1A -0.1 163.6 Qz(zoned) p 1A -0.1 163.1
111296 Qz(zoned) p 1A -0.5 158.8 Qz(zoned) p 1A -1.6 140.1 Qz(zoned) p 1A -1.6 163.7 Qz(zoned) p 1A 169.9 Qz(zoned) p 1A 181 Qz(zoned) p 1A 179.6
11127 4 Qz s 3BV 127.8 111312 Flu s 1A -20.2 -3.3 213.5
FkJ s 1A -20.2 -3.3 213.5 F\J s 1A -20.2 -3.3 213.6 F\J s 1A -20.2 -3.3 213.6 Flu s 1A -20.2 -3.3 213.7 F\J s 1A -20.2 -3.3 213.7 FkJ s 1A -20.2 -3.3 213.8 Flu s 1A -20.2 -3.3 213.8 Flu s 1A -20.2 -3.3 213.9 Flu s 1A -20.2 -3.3 213.9 Flu s 1A -20.2 -3.3 214 Flu s 1A -20.2 -3.3 214 Flu s 1A -20.2 -3.3 214.1 Flu s 1A -20.2 -3.3 214.1 F\J s 1A -20.2 -3.3 214.2 FkJ s 1A -20.2 -3.3 214.2 F\J s 1A -20.2 -3.3 214.3 F\J s 1A -20.2 -3.3 214.3 FkJ s .
1A -20.2 -3.3 214.4 FkJ s 1A -20.2 -3.3 214.4 Flu s 1A -20:2 -3.3 214.5 Flu s 1A -20.2 -3.3 214.5 Flu s 1A -20.2 -3.3 214.6 FkJ s 1A -20.2 -3.3 214.6 Flu s 1A -20.2 -3.3 214.7 Flu s 1A -20.2 -3.3 214.7 Flu s 1A -20.2 -3.3 214.8 Flu s 1A -20.2 -3.3 214.8 Flu s 1A -20.2 -3.3 214.9 Flu s 1A -20.2 -3.3 214.9 Flu s 1A -20.2 -3.3 215 Flu s 1A -20.2 -3.3 215 Flu s 1A -20.2 -3.3 215.1 Flu s 1A -20.2 -3.3 215.1 Flu s 1A -20.2 -3.3 215.2 Flu s 1A -20.2 -3.3 215.2 Flu s 1A -20.2 -3.3 215.3
42E
APPENDIX VI - CARBONATE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 Tm C02 Tm Cl Th
Flu s 1A -20.2 -3.3 215.3 Flu s 1A -20.2 -3.3 215.4 Flu s 1A -20.2 -3.3 215.4 Flu s 1A -20.2 -3.3 215.5 Flu s 1A -20.2 -3.3 215.5
111325 Qz(zoned) s 1A -4.3 177.5 Qz(zoned) s 1A -4.2 177.5 Qz(zoned) s 1A -4.2 177.5 Qz(zoned) s 1A -4.1 177.5
110984 Qz s 1A -22.5 -6.2 189.7 Qz s 1A -22.5 -6.2 189.7 Qz s 1A -22.5 -6.2 189.7 Qz s 1A -22.5 -6.2 189.8 Qz s 1A -22.5 -6.2 189.8 Qz s 1A -22.5 -6.2 189.8 Qz s 1A -22.5 -6.2 189.9 Qz s 1A -22.5 -6.2 189.9 Qz s 1A -22.5 -6.2 189.9 Qz s 1A -22.5 -6.2 ~90 Qz s 1A -22.5 -6.2 190 Qz s 1A -22.5 -6.2 190 Qz s 1A -22.5 -6.2 190.1 Qz s 1A -22.5 -6.2 190.1 Qz s 1A -22.5 -6.2 190.1 Qz s 1A -22.5 -6.2 190.2 Qz s 1A -22.5 -6.2 190.2 Qz s 1A -22.5 -6.2 190.2 Qz s 1A -22.5 -6.2 190.3 Qz s 1A -22.5 -6.2 190.3 Qz s 1A -22.5 -6.2 190.3 Flu s 1A -22.3 -6.1 231.2 Flu s 1A -22.3 -6.1 231.3 Flu s 1A -22.3 -6.1 231.4 Flu s 1A -22.3 -6.1 231.5 Flu s 1A -22.3 -6.1 231.6 Flu s 1A -22.3 -6.1 231.7 Flu s 1A -22.3 -6.1 231.8 Flu s 1A -22.3 -6.1 231.9 Flu s 1A -22.3 -6.1 232 Flu s 1A -22.3 -6.1 232.1 Flu s 1A -22.3 -6.1 232.2 Flu s 1A -22.3 -6.1 232.3 Flu s 1A -22.3 -6.1 232.4 Flu s 1A -22.3 -6.1 232.5 Flu s 1A -22.3 -6.1 232.6 Flu s 1A -22.3 -6.1 232.7 Flu s 1A -22.3 -6.1 232.8 Flu s 1A -22.3 -6.1 232.9 Flu s 1A -22.3 -6.1 233 Flu s . 1A -22.3 -6.1 233.1 Flu s 1A -22.3 -6.1 233.2
111013 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181.9 Flu s 1A -4.8 181 .9 Flu s 1A -4.8 181.9
42.~
APPENDIX VI- CARBONATE STAGE
CAT. NO. HOST CLASSIF. TYPE Te Tm H20 Tm C02 TmCI Th
Fu s 1A -4.8 181.9 FU. s 1A -4.8 181.9 FU s 1A -4.8 181.9 FU s 1A -4.8 181.9
431
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MINERAL SAMPLE NO. a534-CDT STAGE
111386 Arsenopyrite Shear 'L' 5391: 975.8m 7.1 0/S 111387 Arsenopyrite Shear 'L' S391A(i): 948.0m 6.8 0/S 111392 Arsenopyrite Shear 'L' S876: 88.6m. 5.7 0/S 111398 Arsenopyrite Shear 'L' S1186(i): 177.8m 2.4 0/S-C/M 111401 Arsenopyrite Shear 'L' S1285: 162.0m 6.6 0/S 111404 Arsenopyrite Shear 'L' U695(ii): 20.0m 7.2 0/S-S 111409 Arsenopyrite Shear 'L' U839(i): 31.0m 6.4 0/S 111415 Arsenopyrite Shear 'L' U952(ii): 74.7m 6.5 0/S 111422 Arsenopyrite Shear 'L' U1190(iii): 133.3m 6.8 0/S 111424 Arsenopyrite Shear 'L' U1540: 20.5m 6.8 0/S 111431 Arsenopyrite Shear 'L' U1941(i): 20.5m 5.6 B/M? 111437 Arsenopyrite Shear 'L' U1974(i): 20.0m 6.7 0/S 111441 Arsenopyrite Shear 'P' S1221: 35.5m 6.5 0/S-S 111450 Arsenopyrite Shear 'P' U836(i): 55.0m 7.0 0/S 111453 Arsenopyrite Shear 'P' U840(ii): 31.5m 6.3 0/S 111456 Arsenopyrite Shear •p• U941(i): 153.5m 6.7 0/S 111459 Arsenopyrite Shear 'P' U945(ii): 111.5m 7.2 0/S 111464 Arsenopyrite Shear 'P' U976(i): 15.6m 5.9 B/M? 111337- Arsenopyrite Polaris S422: 45.0m 6.6 0/S-S 111083 Arsenopyrite FBF U638(ii): 87.0m 6.2 B/M 111102 Arsenopyrite FBF U777(v): 105.0m 4.9 OIS 111113 Arsenopyrite FBF U803(iii): 93.0m 7.2 0/S 111122 Arsenopyrite FBF U825(ii): 70.0m 6.0 0/S 111127 Arsenopyrite FBF U833(ii): 196.0m 6.7 0/S 111144 Arsenopyrite FBF U936(ii): 20.4m 7.2 B/M 111156 Arsenopyrite FBF U968(ii): 134.3m 6.4 0/S 111169 Arsenopyrite FBF U1012(ii): 108.0m 7.7 0/S 111175 Arsenopyrite FBF U1023(iii): 41.0m 8.0 0/S 111178 Arsenopyrite FBF U1028(ii): 62.3m 6.8 B/M 111179 Arsenopyrite FBF U1028(iii): 66.5m 7.4 0/S
CAT. No. MINERAL SAMPLE NO. a534-CDT STAGE 111387 Chalcopyrite Shear 'L' S391A(i): 948.0m 6.2 s 111175 Chalcopyrite FBF U1023(iii): 41.0m 5.1 B/M 111207 Chalcopyrite FBF U1176(i): 63.0m 5.3 B/M 111212 Chalcopyrite FBF U1186(ii): 105.5m 5.1 B/M 111215 Chalcopyrite FBF U1186(v): 114.0m 6.7 s 111218 Chalcopyrite FBF U1214(i): 102.0m 6.0 s 111248 Chalcopyrite FBF U1377(ii): 72.5m 7.0 s 111309 Chalcopyrite FBF U1985(ii): 64.6m 6.5 s 110987 Chalcopyrite FBF S342(i): 1052.5m 5.9 s 111015 Chalcopyrite FBF S391 (v): 948.0m 5.8 s 111 021 Chalcopyrite FBF S763(iv): 894.0m 6.5 s 111029 Chalcopyrite FBF S830(i): 714.0m 6.3 s 111034 Chalcopyrite FBF S876(iii): 808.0m 5.7 B/M 111070 Chalcopyrite FBF S1454: 1146.5m 6.7 s 111483 Chalcopyrite COLEBROOK Hill. 5.0 111488 Chalcopyrite CURTAIN DAVIS SoN 7.9
CAT. No. MNERAL SAMPLE NO. a534-CDT STAGE 111426 Galena Shear 'L' U1818(i): 20.5m 3.6 B/M 111082 Galena FBF U638(i): 85.0m 4.1 B/M 111086 Galena FBF U638(v): 93.8m 3.0 B/M 111233 Galena FBF U1253(iii): 16.4m 3.2 B/M 111018 Galena FBF S763(i): 892.5m 3.0 B/M 111048 Galena FBF S939(iv): 847.5m 3.7 B/M 111485 Galena KAPIMINE 8.1
Galena• KAPIMINE 8.6 111487 Galena SOUTH COMET 4.2
Galena• SOUTH COMET 5.2 111489 Galena EVEN[)()'~~ PA:>SPECT 9.7
Galena• GREAT f\ORlHEFIN CREB< 10.2 Galena• McKIMMIE MINE 4.4
CAT. No. MNERAL SAMPLE NO. a534-CDT STAGE 111482 Jamesonite WALLACE'S PROSPECT 6.5 111484 Jamesonite FRAZERCREB< HUT 9.1
43:
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MNERAL SAMPLE NO. ()534-CDT STAGE
111488 Jamesonite CURTAIN DAVIS SN 8.4 Jamesonite• CURTAIN DAVIS SN 8.7 Jamesonite• Ma.BAMINE 5.4
CAT. No. MNERAL SAMPLE NO. ()534-CDT STAGE 111383 Pyrite Shear 'L' S320: 25.5m 6.6 s 111387 Pyrite Shear 'L' S391A(i):948.0m 5.9 s 111390 Pyrite Shear 'L' S526: 42.8m- 6.9 S? 111391 Pyrite Shear 'L' S703: 34.0m 6.1 s 111395 Pyrite Shear 'L' S1136: 145.0m 5.5 s 111400 Pyrite/Po Shear 'L' S1188: 152.9m 11.2 s 111425 Pyrite Shear 'L' U1657: 0.5m 4.8 s 111434 Pyrite Shear 'L' U1954(i): 23.0m 5.3 s 111441 Pyrite Shear 'P' S1221: 35.5m 5.0 s 111444 Pyrite Shear 'P' S1259: 74.5m 6.0 s 111445 Pyrite Shear 'P' S1260: 72.5m 6.3 s 111479 Pyrite Shear 'P' U1787(iii): 21.5m 5.4 s 111333 Pyrite Polaris S318: 62.4m 6.4 s 111335- Pyrite Polaris S329(ii): 147.5m 5.1 s 111337 Pyrite-1 Polaris S422: 45.0m 2.4 s 111337 Pyrite-2 Polaris S422: 45.0m 2.5 s 111338 Pyrite Polaris S425(i): 83.1 m 5.2 s 111342 Pyrite Polaris S433(ii): 40.5m 4.3 s 111344 Pyrite Polaris S437(ii): 130.5m 5.9 s 111083 Pyrite FBF U638(ii): 87.0m 5.4 melnikovite 111093 Pyrite FBF U741(iii): 77.3m 5.7 s 111101 Pyrite FBF U777(iv): 98.5m 6.1 s 1111 03 Pyrite FBF U777(vi): 106.0m 6.2 s 111118 Pyrite FBF U817(ii): 101.7m 6.1 s 111133 Pyrite FBF U844(v): 235.0m 5.5 s 111136 Pyrite FBF U862(iii): 68.0m 6.8 s 111141 Pyrite FBF U892(i): 77.0m 7.0 s 111142 Pyrite FBF U892(ii): 84.3m 6.7 s 111145 Pyrite FBF U936(iii): 26.5m 7.8 s 111146 Pyrite FBF U936(iv): 28.5m 7.5 s 111147 Pyrite FBF U936(v): 33.0m 6.5 s 111150 Pyrite FBF U938(iii): 68.2m 7.2 s 111151 Pyrite FBF U938(iv): 69.8m 9.3 s 111157 Pyrite FBF U968(iii): 145.0m 5.5 s 111161 Pyrite FBF U978(ii)a: 99.1m 4.9 S? 111171 Pyrite FBF U1012(iv): 114.0m 4.6 B/M 111173 Pyrite FBF U1023(i): 40.0m 5.4 s 111174 Pyrite FBF U1023(ii): 40.8m 6.8 s 111185 Pyrite FBF U1 045(ii): 61.0m 5.8 s 111195 Pyrite FBF U1115(i): 31.5m 6.0 s 111196 Pyrite FBF U1115(ii): 32.5m 5.6 s 111197 Pyrite FBF U1115(iii): 38.7m 5.4 s 111205 Pyrite FBF U1160(iv): 43.0m 5.3 s 111213 Pyrite FBF U1186(iii): 107.4m 5.2 melnikovite 111230 Pyrite FBF U1240(iii): 42.0m . 6.2 VIC? 111254 Pyrite FBF U1408(i): 63.8m 6.3 s 111260 Pyrite FBF U1522(i): 88.0m 6.8 s 111267 Pyrite FBF U1564(ii): 115.0m 6.8 s 111268 Pyrite FBF U1586(i): 91.0m 7.5 s 111270 Pyrite FBF U1614(i): 41.8m 6.9 s 111279 Pyrite FBF U1647(iii): 51.3m 6.1 melnikovite 111279 Pyrite FBF U1647(iii): 51.3m 5.7 s 111287 Pyrite FBF U1786(v): 52.0m 6.5 s 111289 Pyrite FBF U1853(ii): 44.5m 6.6 s 111298 Pyrite FBF U1897(iv): 29.6m 6.4 melnikovite 111307 Pyrite FBF U1947(iii): 86.5m 6.3 s 111319 Pyrite FBF U2064(iv): 118.1m 6.7 s 111327 Pyrite FBF U2127(vi): 110.2m 5.6 s 110986 Pyrite FBF S310(v): 819.5m 5.9 B/M 110987 Pyrite FBF S342(i): 1052.5m 6.5 s 110995 Pyrite FBF S366(i): 31.0m 7.2 s 111000 Pyrite FBF S371(i): 310.5m 13.0 s
433
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MINERAL SAMPLE NO. il534-CDT STAGE
111007 Pyrite FBF 5382: 119.9m 6.5 s 111015 Pyrite FBF S391(v): 948.0m 5.0 s 111022 Pyrite FBF S763(v): 894.9m 6.3 melnikovite 111026 Pyrite FBF 8781 (iii): 39.0m 6.7 s 111027 Pyrite FBF S821(i): 52.5m 7.4 s 111035 Pyrite FBF S876(iv): 809.0m 6.1 melnikovite 111043 Pyrite FBF S918(iii): 698.8m 8.9 s 111048 Pyrite FBF S939(iv): 847.5m 5.5 s 111056 Pyrite FBF S1336(ii): 60.8m -26.6 melnikovite 111056 Pyrite FBF S1336(ii): 60.8m 7.6 s 111061 Pyrite FBF S1450A(ii): 1085.7m 5.9 s 111067 Pyrite FBF S1450C(i): 1037.2m 12.0 s 111070 Pyrite FBFS1454: 1146.5m. 6.3 s 111071 Pyrite FBF S1454A(i): 1063.0m 12.1 s 111078 Pyrite FBF S1464(i): 672.3m 13.4 s 111081 Pyrite FBF S1474: 907.0m 6.4 s 111482 Pyrite WALLACE'S PROSPECT 9.8
Pyrite• WALLACE'S PROSPECT 9.4 111484- Pyrite FRAZERCREB< HUT 10.2 111486 Pyrite FAHL MINE (ORE) 9.8
Pyrite• FAHL MINE (ORE) 12.0 111488 Pyrite CURTAIN DAVIS SW 8.1
Pyrite• CURTAIN DAVIS SW 10.0 Pyrite• GREAT SOUTH COMET 9.6 Pyrite• GREAT SOUTH COMET 10.8 Pyrite• TEXfo.l PROSPECT 9.7
CAT. No. MINERAL SAMPLE NO. ilS34-CDT STAGE 111383 Pyrrhotite Shear 'L' S313(i):155.5m 6.8 s 111391 Pyrrhotite Shear 'L' 5703: 34.0m 7.7 s 111394 Pyrrhotite Shear 'L' S1135: 53.7m 6.1 s 111395 Pyrrhotite Shear 'L' S1136: 145.0m 5.0 s 111396 Pyrrhotite Shear 'L' S1141(i): 84.7m 6.3 s 111397 Pyrrhotite Shear 'L' S1141(iij: 85.5m 6.8 s 111400 Pyrrhotite Shear 'L' $1188: 152.9m 9.2 s 111401 Pyrrhotite Shear 'L' 51285: 162.0m 6.1 s 111402 Pyrrhotite Shear 'L' S1374: 73.2m 5.2 s 111404 Pyrrhotite Shear 'L' U695(ii): 20.0m 6.8 s 111407 Pyrrhotite Shear 'L' U802(i): 14.0m 5.4 s 111408 Pyrrhotite Shear 'L' U802(ii): 18.5m 6.3 s 111409 Pyrrhotite Shear 'L' U839(i): 31.cim 5.9 s 111410 Pyrrhotite Shear 'L' U839(ii): 31.5m 5.6 s 111412 Pyrrhotite Shear 'L' U897(ii): 61.5m 5.7 s 111413 Pyrrhotite Shear 'L' U950: 56.0m 5.5 s 111414 Pyrrhotite Shear 'L' U952(i): 71.0m 5.8 s 111415 Pyrrhotite Shear 'L' U952(ii): 74.7m 6.4 s 111423 Pyrrhotite Shear 'L' \)1255: 62.8m 6.3 s 111424 Pyrrhotite Shear 'L' U1540: 20.5m 6.2 s 111426 Pyrrhotite Shear 'L' U1818(ii): 23.5m 6.0 s 111432 Pyrrhotite Shear 'L' U1941(ii): 26.5m 6.2 s 111433 Pyrrhotite Shear 'L' U1941(iii): 30.5m 6.3 s 111425 Pyrrhotite Shear 'L' U1657: 0.5m 5.1 s 111434 Pyrrhotite Shear 'L' U1954(i): 23.0m 6.1 s 111437 Pyrrhotite Shear 'L' U1974(i): 18.0m 5.0 s 111438 Pyrrhotite Shear 'L' U1974(ii): 18.0m 5.3 s 111441 Pyrrhotite Shear 'P' S1221: 35.5m 5.2 s 111443 Pyrrhotite Shear 'P' S1248(ii): 139.5m 6.1 s 111444 Pyrrhotite Shear 'P' 51259: 74.5m 5.7 s 111445 Pyrrhotite Shear 'P' S1260: 72.5m 6.7 s 111446 Pyrrhotite Shear 'P' U615: 58.9m 7.0 s 111449 Pyrrhotite Shear 'P' U797: 36.7m 6.3 s 111451 Pyrrhotite Shear 'P' U836(ii): 55.2m 5.8 s 111458 Pyrrhotite Shear 'P' U945(i): 104.5m 5.4 s 111462 Pyrrhotite Shear 'P' U964(i): 80.7m 6.4 s 111466 Pyrrhotite Shear 'P' U976(iii): 23.0m 12.1 s 111467 Pyrrhotite Shear 'P' U1114(i): 26.2m 5.6 s 111469 Pyrrhotite Shear 'P' U1117: 74.5m 5.2 s
43.:
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MINERAL SAMPLE NO. ilS34-CDT STAGE
111470 Pyrrhotite Shear 'P' U1257: 53.8m 6.2 s 111471 Pyrrhotite Shear ·p• U1258(i): 36.0m 6.7 s 111472 Pyrrhotite Shear 'P' U1258(ii): 48.0m 6.9 s 111473 Pyrrhotite Shear 'P' U1623(i): 12.0m 6.1 s 111474 Pyrrhotite Shear 'P' U1623(ii): 12.5m 6.3 s 111476 Pyrrhotite Shear 'P' U1716(ii): 41.5m 5.3 s 111477 Pyrrhotite Shear 'P' U1787(i): 16.0m 5.4 s 111480 Pyrrhotite Shear 'P' U1794: 60.2m 5.5 s 111481 Pyrrhotite Shear 'P' U1896: 45.5m 6.0 s 111335 Pyrrhotite Polaris S329(ii): 147.5m 4.0 s 111336 Pyrrhotite Polaris S329(iii): 148.0m 4.6 s 111338 Pyrrhotite Polaris S425(i): 83.1 m 5.9 s 111339 Pyrrhotite Polaris S425(ii): 83.1 m 4.0 s 111342 Pyrrhotite Polaris S433(ii): 40.5m 0.3 s 111344 Pyrrhotite Polaris S437(ii): 130.5m 4.6 s 111082 Pyrrhotite FBF U638(i): 85.0m 5.4 s 111083 Pyrrhotite FBF U638(ii): B7.0m 5.5 s 111084 Pyrrhotite FBF U638(iii): 87.0m 6.5 s 111088- Pyrrhotite FBF U638(vii): 97.9m 6.1 s 111089 Pyrrhotite FBF U685(i): 113.5m 6.9 s 111092 Pyrrhotite FBF U741(ii): 57.0m 4.1 s 111093 Pyrrhotite FBF U741 (iii): 77.3m 5.7 s 111100 Pyrrhotite FBF U777(iii): 97.5m 5.8 s 111103 Pyrrhotite FBF U777(vQ: 106.0m 6.4 s 1111 04 Pyrrhotite FBF U790(i): 55.2m 5.8 s 111105 Pyrrhotite FBF U790(ii): 55.6m 6.6 s 111107 Pyrrhotite FBF U797(i): 114.2m 6.9 s 111112 Pyrrhotite FBF U803(ii): 92.6m 6.1 s 111113 Pyrrhotite FBF U803(iii): 93.0m 6.0 s 111114 Pyrrhotite FBF U809(i): 98.0m 7.0 s 111115 Pyrrhotite FBF U809(ii): 99.5m 7.4 s 111116 Pyrrhotite FBF U809(iii): 105.3m 6.0 s 111117 Pyrrhotite FBF U817(i): 99.8m 5.8 s 111118 Pyrrhotite FBF U817(iQ: 101.7m 5.7 s 111120 Pyrrhotite FBF U817(iv): 107.2m 5.7 s 111122 Pyrrhotite FBF U825(ii): 77.0m 7.0 s 111123 Pyrrhotite FBF U825(iii): 72.5m 4.9 s 111124 Pyrrhotite FBF U825(iv): 77.5m 5.6 s 111130 Pyrrhotite FBF U844(ii): 215.3m 8.3 s 111133 Pyrrhotite FBF U844(v): 235.0m 5.9 s 111135 Pyrrhotite FBF U862(ii): 65.0m 6.7 s 111136 Pyrrhotite FBF U862(iii): 68.0m 6.7 s 111137 Pyrrhotite FBF U862(iv): 78.8m 6.3 s 111139 Pyrrhotite FBF U870(i): 117.1m 6.5 s 111140 Pyrrhotite FBF U870(ii): 118.0m 6.4 s 111141 Pyrrhotite FBF U892(i): 77.0m 6.1 s 111143 Pyrrhotite FBF U936(i): 12.0m 7.0 s 111145 Pyrrhotite FBF U936(iii): 26.5m 7.6 s 111148 Pyrrhotite FBF U938(i): 51.8m 6.9 s 111149 Pyrrhotite FBF U938(ii): 66.2m 5.7 s 111150 Pyrrhotite FBF U938(iii): 68.2m 6.3 s 111151 Pyrrhotite FBF U938(iv): 69.8m 3.7 s 111153 Pyrrhotite FBF U943(i): 44.5m 5.9 s 111154 Pyrrhotite FBF U943(ii): 53.2m 7.0 s 111158 Pyrrhotite FBF U968(iv): 145.3m 6.0 s 111159 Pyrrhotite FBF U968(v): 155.0m 5.9 s 111161 Pyrrhotite FBF U978(ii)a: 99.1m 5.0 s 111163 Pyrrhotite FBF U978(iv): 106.8m 5.7 s 111164 Pyrrhotite FBF U978(v): 113.0m 6.2 s 111167 Pyrrhotite FBF U1006(iii): 114.9m 6.0 s 111168 Pyrrhotite FBF U1012(i): 103.0m 5.6 s 111173 Pyrrhotite FBF U1023(i): 40.0m 7.2 s 111174 Pyrrhotite FBF U1 023(ii): 40.8m 7.3 s 111175 Pyrrhotite FBF U1023(iii): 41.0m 6.9 s 111177 Pyrrhotite FBF U1 028(i): 55.6m 11.4 s 111179 Pyrrhotite FBF U1028(iii): 66.5m 5.8 s 111181 Pyrrhotite FBF U1036(ii): 36.1m 5.8 s
43;:
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MNERAL SAMPLE NO. aS34-CDT STAGE
111182 Pyrrhotite FBF U1036(iii): 47.0m 6.1 s 111184 Pyrrhotite FBF U1 045(i): 52.6m 5.8 s 111185 Pyrrhotite FBF U1045(ii): 61.0m 5.9 s 111190 Pyrrhotite FBF U1092(iii): 52.0m 5.2 s 111191 Pyrrhotite FBF U1107(i): 29.6m 6.8 s 111191 Pyrrhotite FBF U1107(i): 29.6m 6.2 s 111193 Pyrrhotite FBF U1112(i): 21.0m 5.8 s 111195 Pyrrhotite FBF U1115(i): 31.5m 5.8 s 111196 Pyrrhotite FBF U1115(ii): 32.5m 5.9 s 111197 Pyrrhotite FBF U1115(iii): 38.7m 5.5 s 111200 Pyrrhotite FBF U1118(ii): 37.0m 6.3 s 111203 Pyrrhotite FBF U1160(ii): 40.8m 5.6 s 111205 Pyrrhotite FBF U1160(iv): 43.0m 5.5 s 111206 Pyrrhotite FBF U1160(v): 45.9m 5.4 s 111208 Pyrrhotite FBF U1176(ii): 66.2m 6.8 s 111209 Pyrrhotite FBF U1176(iii): 71.0m 5.9 s 111210 Pyrrhotite FBF U1176(iv): 71.6m 5.9 s 111215 Pyrrhotite FBF U1186(v): 114.0m 6.8 s 111216- Pyrrhotite FBF U1186(vi): 117.0m 5.3 s 111218 Pyrrhotite FBF U1214(i): 102.0m 6.0 s 111221 Pyrrhotite FBF U1214(iv): 108.0m 7.0 s 111223 Pyrrhotite FBF U1214(vi): 115.0m 6.1 s 111224 Pyrrhotite FBF U1214(vii): 1 01.5!11 5.9 s 111225 Pyrrhotite FBF U1226(i)a: 74.7m 5.8 s 111229 Pyrrhotite FBF U1240(ii): 36.0m 6.1 s 111232 Pyrrhotite FBF U1253(ii): 15.4m 6.2 s 111237 Pyrrhotite FBF U1267(ii): 57.5m 6.1 s 111241 Pyrrhotite FBF U1305(i): 114.0m 6.7 s 111243 Pyrrhotite FBF U1343(i): 102.7m 6.2 s 111244 Pyrrhotite FBF U1361(i): 106.1m 6.0 s 111246 Pyrrhotite FBF U1361(iii): 107.2m 5.8 s 111248 Pyrrhotite FBF U1377(ii): 72.5m 6.4 s 111249 Pyrrhotite FBF U1377(iii): n.5m 6.8 s 111250 Pyrrhotite FBF U1377(iv): 80.2m 7.5 s 111251 Pyrrhotite FBF U1390(i): 69.0m 6.4 s 111253 Pyrrhotite FBF U1390(iii): 78.0m 6.0 s 111254 Pyrrhotite FBF U1408(i): 63.8m 6.5 s 111255 Pyrrhotite FBF U1408(ii): 67.0m 6.9 s 111256 Pyrrhotite FBF U1408(iii): 76.0m 6.8 s 111257 Pyrrhotite FBF U1414(i): 206.2m 6.3 s 111260 Pyrrhotite FBF U1522(i): 88.0m 6.5 s 111261 Pyrrhotite FBF U1522(ii): 88.0m 6.0 s 111264 Pyrrhotite FBF U1563(ii): 119.7m 6.3 s 111265 Pyrrhotite FBF U1563(iii): 125.7m 6.6 s 111266 Pyrrhotite FBF U1564(i): 11 0.6m 6.6 s 111269 Pyrrhotite FBF U1586(ii): 94.0m 6.8 s 111270 Pyrrhotite FBF U1614(i): 41.8m 6.4 s 111271 Pyrrhotite FBF U1614(ii): 47.1m 6.8 s 111275 Pyrrhotite FBF U1625(i): 63.0m 5.9 s 111282 Pyrrhotite FBF U1647(vi): 58.0m 6.1 s 111287 Pyrrhotite FBF U1786(v): 52.0m · 6.2 s 111289 Pyrrhotite FBF U1853(ii): 44.5m 6.9 s 111293 Pyrrhotite FBF U1892(ii): 39.7m 6.9 s 111298 Pyrrhotite FBF U1897(iv): 29.6m 6.8 s 111305 Pyrrhotite FBF U1947(i): 76.8m 6.7 s 111309 Pyrrhotite FBF U1985(ii): 64.6m 6.3 s 111312 Pyrrhotite FBF U1992(i): 162.4m 6.7 s 111314 Pyrrhotite FBF U2013(i): 65.7m 5.8 s 111319 Pyrrhotite FBF U2064(iv): 118.1m 6.5 s 111323 Pyrrhotite FBF U2127(ii): 102.4m 5.7 s 111327 Pyrrhotite FBF U2127(vi): 110.2m 5.8 s 111332 Pyrrhotite FBF U2194(ii): 114.3m 5.7 s 110978 Pyrrhotite FBF S309(i): 496m 6.7 s 110982 Pyrrhotite FBF S310(i): 807.5m 6.2 s 110987 Pyrrhotite FBF S342(i): 1052.5m 5.8 s 110996 Pyrrhotite FBF S366(ii): 31.8m 7.1 s 111000 Pyrrhotite FBF S371(i): 310.5m 12.5 s
43E
APPENDIX VII: SULPHUR ISOTOPE ANALYSES
CAT. No. MNERAL SAMPLE NO. ilS34-CDT STAGE
111003 Pyrrhotite F8F S381(i): 387.2m 7.4 s 111008 Pyrrhotite F8F S385(i): 309.5m 6.0 s 111021 Pyrrhotite F8F S763(iv): 894.0m 6.4 s 111023 Pyrrhotite F8F S770: 21.0m 6.8 s 111024 Pyrrhotite F8F S781(i): 35.6m 6.8 s 111027 Pyrrhotite F8F S821(i): 52.5m 7.1 s 111029 Pyrrhotite F8F S830(i): 714.0m 5.8 s 111032 Pyrrhotite F8F S876(i): 805.7m 6.1 s 111042 Pyrrhotite F8F S918(ii): 689.7m 5.4 s 111045 Pyrrhotite F8F S939(i): 842.7m 6.8 s 111049 Pyrrhotite F8F S952(i)a: 746.0m 6.5 s 111 051 Pyrrhotite F8F S952A(i): 763.3m 6.3 s 111055 Pyrrhotite F8F S1336(i): 60.8m 11.0 s 111059 Pyrrhotite F8F S14008: 1042.4m 4.8 s 111061 Pyrrhotite F8F S1450A(ii): 1085.7m 7.7 s 111066 Pyrrhotite F8F S14508(iii): 1032.0m 6.1 s 111067 Pyrrhotite F8F S1450C(i): 1037.2m 13.2 s 111070 Pyrrhotite F8F S1454: 1146.5m 6.7 s 111071- Pyrrhotite F8F S1454A(i): 1063.0m 11.6 s 111073 Pyrrhotite F8F S14548: 1028.7m 8.5 s 111074 Pyrrhotite F8F S1454C: 1001.5m 6.0 s 111077 Pyrrhotite F8F S14558(ii): 678.5m 6.4 s 111079 Pyrrhotite F8F S1464(ii): 678.5m 6.8 s 111 081 Pyrrhotite F8F S1474: 907.0m 6.6 s 111483 Pyrrhotite COLEBROOK HILL 1.9 111490 Pyrrhotite GRAND PRIZE 6.7 102736 Pyrrhotite PAZOABAa< 7.2 111486 Pyrrhotite FAHLMINE 9.8
CAT. No. MINERAL SAMPLE NO. ilS34-CDT STAGE 111402 Sphalerite Shear 'L' S1374: 73.2m 5.3 s 111428 Sphalerite Shear 'L' U1913(i): 39.0m 4.7 8/M 111434 Sphalerite Shear 'L' U1954(i): 23.0m 3.1 8/M 111436 Sphalerite Shear 'L' U1959: 5.0m 4.3 8/M 111334 Sphalerite Polaris S329(iii): 148.0m 5.2 s 111082 Sphalerite F8F U638(i): 85.0m 5.3 8/M 111107 Sphalerite F8F U797(i): 114.2m 10.6 8/M 111142 Sphalerite F8F U892(ii): 84.3m 6.2 8/M 111171 Sphalerite F8F U1012(iv): 114.0m 5.2 8/M 111211 Sphalerite F8F U1186(i): 103.5m 6.1 8/M 111233 Sphalerite FBF U1253(iii): 16.4m 5.3 B/M 111256 Sphalerite FBF U1408(iii): 76.0m 5.6 B/M 111267 Sphalerite FBF U 1564(ii): 115.0m 6.6 B/M 111268 Sphalerite F8F U1586(i): 91.0m 7.8 8/M 111271 Sphalerite F8F U1614(ii): 47.1m 7.2 s 111277 Sphalerite F8F U1647(i)b: 45.0m 5.1 8/M 111305 Sphalerite F8F U1947(i): 76.8m 6.1 s 111316 Sphalerite F8F U2064(i): 106.0m 5.7 8/M 111327 Sphalerite FBF U2127(vi): 110.2m 5.7 B/M 111011 Sphalerite FBF S391 (i): 931.5m 5.3 B/M 111017 Sphalerite FBF S391A(ii): 936.5m 5.3 B/M 111028 Sphalerite F8F S821(ii): 56.0m 7.1 B/M 111032 Sphalerite FBF S876(i): 805.7m 5.5 B/M 111048 Sphalerite F8F S939(iv): 847.5m 5.7 8/M 111484 Sphalerite FRAZER CREEK HUT 10.5 111485 Sphalerite KAPIMINE 10.8
Sphalerite• KAPIMINE 6.8 111487 Sphalerite SOUlHCOMET 8.7
Sphalerite• SOUlHCOMET 7.0 Sphalerite• SOUlHCOMET 8.9 Sphalerite• GREAT~ERNCREB< 10.7 Sphalerite• Md<I~IE MINE 5.8
• Analyses provided by Dr GeoH Green, Mineral Resources Tasmania. 0/S: oxide-silicate stage S: main sulphide stage 8/M: base metal stage VIC: vug-fill carbonate stage
APPENDIX VIII: C/0 ISOTOPE ANALYSES ~~
COLLECTOR SPECIMEN NO. MINERAL ()C13% (POB) ()018% (SMOW)
Patterson 79 104128 Siderite --6.00 12.70 104272 vein calcite -4.20 14.90 104273 vein calcite - -4.40 15.30 104276 vug calcite 4.30 24.00 103735 No.2 Dolomite -2.80 20.90 103768 RBM Dolomite -1.90 19.80 103772 No.2 Dolomite -1.1 0 11.40 104129 No.3 Dolomite 1.30 21.30
Holyland '87 45630 No.3 Dolomite -2.60 14.30 45633 No.3 Dolomite -6.30 12.80
45633(rept) No.3 Dolomite -6.40 13.30 45643 No.3 Dolomite -1.30 16.20 45604 No.3 Dolomite -0.30 20.00 45615 No.3 Dolomite 3.20 24.10 45616 No.3 Dolomite -2.20 20.70
45616(rept) No.3 Dolomite -1.00 20.90 45601 No.3 Dolomite 1.50 22.20 45600 No.3 Dolomite 1.80 22.30 45644 No.3 Dolomite -6.00 17.00 45614 No.3 Dolomite 2.10 23.60 45617 No.3 Dolomite 2.50 23.30 45613 No.3 Dolomite 0.70 20.90 45631 No.2 Dolomite -1.10 23.30 45607 No.1 Dolomite -3.00 17.80 45606 No.2 Dolomite 1.00 24.00 45618 No.2 Dolomite -3.40 13.60 45627 No.2 Dolomite 1 .1 0 24.80 45626 No.2 Dolomite 1.30 27.50 45625 No.2 Dolomite 2.90 26.50 45623 No.2 Dolomite -5.20 13.70 45622 No.2 Dolomite -1.60 23.10 45624 No.2 Dolomite 0.30 24.20 45621 No.2 Dolomite 0.10 25.00 45620 No.2 Dolomite 1.30 22.20 45619 No.2 Dolomite 1.00 25.40 45643 No.3 Siderite -1.30 16.20 45646 No.3 Siderite -4.10 14.60 45635 No.3 Siderite -4.10 14.20 45644 No.3 Siderite -6.00 17.00 45638 No.3 Siderite -5.20 12.70 45636 No.3 Siderite -5.50 13.80 45640 No.2 Siderite -5.60 13.80 45647 No.2 Siderite -5.30 13.90 45634 No.3 Siderite -5.50 14.10 45639 No.3 Siderite -4.20 13.10 45602 No.3 Siderite -6.60 15.50 45637 No.3 Siderite 0.60 14.60 45645 No.1 Siderite -3.20 13.90 45641 No.2 Siderite -2.40 15.40 45661 No.2 Siderite -5.50 14.70
U786/75m No.2 Siderite -0.30 12.70 45607 No.2 Siderite -4.20 11.20 S436/5 No.2 Siderite -3.70 13.30 Dr 2015 No.2 Siderite -5.20 10.10 45624 No.3 Siderite -6.30 12.10 45664 No.2 Siderite -6.30 12.50
APPENDIX VIII: C/0 ISOTOPE ANAL VSES 43~
COLLECTOR SPECIMEN NO. MINERAL ()C13% (PDB) d018% (SMOW)
Holyland '87 45648 No.3 Siderite -5.10 25.00 45602 No.2 Siderite -5.10 13.70 45606 No.2 Siderite· -2.50 20.80 45651 No.2 Siderite -7.60 14.60 45649 No.2 Siderite -2.60 16.20 45664 No.2 Siderite -5.70 13.70 45660 No.3 Dolomite 0.50 20.80 45660a No.3 Dolomite -0.10 18.80 45660b No.3 Dolomite -4.70 13.90 45660c No.3 Dolomite -2.70 12.20 45661a No.2 Siderite -0.90 15.70 45653 No.2 Siderite -4.20 14.30
Dr 2125 No.2 Siderite -5.50 14.80 45486 No.2 Siderite -6.30 14.50 51264 No.2 Siderite -4.50 9.40 U1189 No.2 Siderite -2.60 10.40
S385/813 No.2 Siderite 1.60 16.50 45486 No.2 Siderite -2.20 23.10
U716/1 07 No.2 Siderite 1.40 23.50 45662 No.3 Siderite -6.20 10.00 45607 No.3 Siderite -1.80 19.20 45862 No.3 Siderite -4.30 13.50 45654 No.2 Siderite -5.60 13.70 45650 No.2 Siderite -6.30 13.20 45648 No.3 Siderite -4.40 12.40 45657 No.3 Siderite -4.70 15.50 45609 No.2 Dolomite -1.1 0 20.60 45609a No.2 Dolomite -0.60 21.80 45609a No.2 Dolomite 0.30 24.80 45602 No.2 Dolomite 2.30 25.60 45602a No.2 Dolomite 2.50 25.60 45602b No.2 Dolomite 2.20 25.60 45602c No.2 Dolomite 2.80 27.10 45602d No.2 Dolomite 2.70 28.10
Jones & Evans 52118 dolomite 1.24 23.07 52119 dolomite -0.76 21.15
28558/2 dolomite 1.85 22.81 28570 dolomite 1.37 21.23
28585/3 dolomite -0.61 11.96 52120 dolomite 2.84 21.94 28551 dolomite 5.01 23.86 52121 dolomite· 1.70 21.71 28596 dolomite 1.71 21.28 28619 dolomite 1.06 20.42 52122 dolomite -0.60 26.81 52123 dolomite 2.91 24.40 52124 dolomite 1.82 22.64 28624 dolomite 1.68 20.46 28600 dolomite 2.63 22.30 52125 dolomite -3.81 11.35 28591 dolomite 1.49 22.33 28594 dolomite 0.51 21.21 52126 dolomite 4.27 22.63 52127 dolomite 2.84 21.15 52128 dolomite 2.40 23.53 52129 dolomite 1.16 22.15
APPENDIX VIII: C/0 ISOTOPE ANALYSES 44C
COLLECTOR SPECIMEN NO. MINERAL ()C13% (PDB) ()018% (SMOW)
Jones & Evans '85 28532 dolomite 2.81 20.58 52130 dolomite 3.47 23.36 52131 dolomite -2.99 19.11
28540/2 dolomite 2.26 18.78 28544 dolomite 1.08 21.19 28616 dolomite 0.69 14.98 52132 dolomite 0.86 18.38 52133 dolomite 2.12 22.51 52134 dolomite -0.99 13.02 52135 dolomite 3.07 24.95 52136 dolomite 1.03 19.83 28523 dolomite 5.58 25.94 28529 dolomite 2.79 23.61 52137 dolomite -1.26 17.69 52138 dolomite 3.18 21.29 52139 dolomite 4.67 25.10 28607 dolomite 0.46 20.38 52140 dolomite 1.93 23.89 52141 dolomite -0.46 15.96 52142 dolomite 1.75 17.27 28567 siderite -5.90 15.96 28566 siderite -5.36 16.43
28558/1 siderite -4.10 15.64 28585/2 siderite -4.99 15.26 28597 siderite -3.15 15.63 28625 siderite -5.50 16.40 28590 siderite -4.25 15.38 28595 siderite -7.93 16.77 28537 siderite -4.33 14.64 28542 siderite -3.42 13.72 28615 siderite -4.97 11.44 28525 siderite -4.20 15.32 28527 siderite -4.20 18.00 28609 siderite -6.91 17.27
APPENDIX IX- FLUID-ROCK COMPUTER PROGRAM FOR CARBON-OXYGEN ISOTOPES
441
APPENDIX IX- FLUID-ROCK PROGRAM FOR C/0 ISOTOPES
c c
PROGRAM decarb
INTEGER I, J ,sttype,steps REAL RA,fl(4, 101 ),rock(4, 1 OO).fraco(2),fracc,fracp(2) REAL flin(4).rin(4)
c fluid in 1 =0 moles 2=delta 0 3=C moles 4=C delta c rock " " " c need reactant amount(RA) =initial fluid deplete over 10 steps c calculate dx from reaction stoichiometry and rock c stoichiometry 1 XC03 = XO + C02 c stoichiometry 2 XC03 = X C02 + H20
CHARACTER*1 STREAD(30) CHARACTER* 13 FNAM E
c c
4 DO 5 1=1,30 STREAD(I)=''
--s CONTINUE WRITE(*, 1 00) 100 FORMAT(1X,'ENTER FILE NAME:',$) 1 02 FORMAT(30A 1) READ(*,102,ERR=10) (STREAD(I),I=1 ,13) 10 DO 15 1=1,13 FNAME(I:I)=STREAD(I) 5 CONTINUE OPEN(5,FILE=FNAME,IOSTAT =IOS,STATUS='OLD') OPEN(6, FILE='carb.out' ,ST ATUS='unknown')
Read (5,*) STtype,steps X0=2 XC=1 if(STtype.eq.2) X0=3 READ (5,*) RA,tfluid,trock
c RA reaction amount moles used then to calculate dx c tfluid=input T of fluid trock=initial t of rock Cent c use Cp fluid=4.216 j/gm/C rock =1.05 j/gm/C c that is fluid 75.9 j/m/c rock=111.3 j/mole/C c rr=3.0 E4 c rr moles/m3 of carbonate c 1 cub m contains ?moles dolomite = 3.11 *E 4 c ?moles calcite = 2. 7 E4 c ?moles siderite = 3.4 E4 . c use 3E5 moles/m3 in this c for initial fluid use 1% porosity 1 gm/cc density and roughly 50%C02 c this is 160 moles C02 and 160 mole water
dx= RA * 1 0/rr c read fractionation factors
READ(5,*) fracp(1 ),fracp(2),disp c trace dolomite-C02 for C c fraco( 1) dolomite-H20 for 0 fraco(2) H20-C02 for 0 c fracp proportion of requilibration 0-1 0 is diseq 1 is full eq c used for post reaction zoning i.e after rrleft=O.O
READ(5,*) (flin(l),l=1 ,4) READ(5,*) (rin(l).l=1 ,4) t1 =flin(3)/(flin(1 )-flin(3)) write (6,94) disp,steps,dx,tfluid,trock,tracp(2),t1 94 format(' disp=',f4.2,' Steps=',l4,' dX=',f6.2,' m Tfl=',f5.0, 1 'C Tr=',f5.0,' C Xfrac2=',f4.2,' Xco2=',f4.2) set rock volume to require 10 cub m of water for complete reaction
44::
APPENDIX IX- FLUID-ROCK PROGRAM FOR C/0 ISOTOPES
c
rin(1 )=dx*rin(1) rin(3)=dx*rin(3)
c read in initial rock value and then enter all values c start cycle c
do 1150 1=1,100 do 1150 j=1 ,4 1150 rock(J,I)=rin(J) do 1140 i=1 ,4 1140 fl(j, 1 )=flin(j)
c get fractionation values and calculate 1% fluid in pore space xco2=0.5 T =trock+273.15
c c
c c c
c
fraco(1 )=-3.23E6/(T*T)+3.29 fraco(2)=9.8E5/(T*T) + 10.611 E3/T -5.67 fracc=-8. 737E6/(T*T) +8.914E8/(T**3) + 18.11 E3/T -8.44 do 1130 i=2, 100
""1t(1 ,i)=dx*161*3 fl(2,i)=rock(2,i)-fraco(1 )+0.67*fraco(2) fl(3,i)=dx*161 fl(4,i)=rock(4,i)-fracc 1130 continue CALL equil(rock,fi,RA,xc,xo,fracp,tfluid,trock,dx,steps,disp)
STOP END
subroutine equil(rock,fi,RA,xc,xo,fracp,tfl,tro,dx,steps,disp) integer steps real rock(4, 1 00) ,fl(4, 101 ),fraco(2),fracp(2) ,rrleft(1 01) real newo,newc,tfluid(1 01 ),trock(1 OO),disp rrleft( 1 )=RA do 121 i=2,101 121 rrleft(i)=O.O tfluid(1 )=tfl do 122 i= 1 , 1 00 trock(i)=tro tfluid(i+ 1 )=tro 122 continue do 200 k=1 ,steps ****************************
for calculation with reequilibration ****************************
do 195 i=100,1,-1
c if rock depleted c
if (rock(1 ,i).le.0.0001.or.rock(3,i) .le.0.0001) then rrleft(i+ 1 )=rrleft(i) do 110 j=1 ,4 110 fl(j,i+ 1 )=fl(j,i)
c now to get temperature assuming C02 has same molar Cp as H20 c molar Cp H20 =75.9 j/m/C c and no other component has any Cp c rock Cp is 2.8 tonnes* 1.05 Vgm/C
trock(i)=(trock(i)*2.94*dx + tfluid(i)*(fl(1 ,i)-fl(3,i)) 1 *75.9E-6)/(2.94*dX+(fl(1 ,i+ 1 )-fl(3,i+ 1 ))*75.9E-6)
44~·
APPENDIX IX- FLUID-ROCK PROGRAM FOR C/0 ISOTOPES
c
tfluid(i+ 1 )=trock(i) else
c if fluid is depleted c
if (rrleft(i).le.0.0001) then rrleft(i+ 1 )=rrleft(i) do 112 j=1 ,4 112 fl(j,i+ 1 )=fl(j,i)
c now to correct T trock(i)=(trock(i)*2.94*dx + tfluid(i)*(fl(1,i)-fl(3,i)) 1 *75 .9E-6)/(2.94 *dx+(fl( 1,i+ 1 )-fl(3,i+ 1) )*75.9E-6) tfluid(i+ 1 )=trock(i)
c and then to find new fractionation values T =trock(i)+273.15 fraco( 1 )=-3.23E6/(T*T)+3.29 fraco(2)=9.8E5/(T*T) + 10.611 E3/T -5.67
rracc=-8.737E6/(T*T) +8.914E8/(T**3) + 18.11 E3/T -8.44 c now to allow reequilibration c for 0 need to calculate bulk fractionation factor c fraco is dol-h2o 2 is h2o-co2
fro=fraco(1) + fraco(2)*2*fl(3,i+1)/fl(1,i+1) ttalo=fl(1,i+ 1 )+rock(1,i) dsyso=(fl(1,i+ 1 )*fl(2,i+ 1) + rock(1,i)*rock(2,i))/ttalo ettalo=fl(1,i+ 1 )+fracp(2)*rock(1,i) edsys=(fl(1,i+ 1 )*fl(2,i+ 1) + 1 fracp(2)*rock(1,i)*rock(2,i))/ettalo del1 =edsys +fro*rock(1,i)*fracp(2)/ettalo fl(2,i+ 1 )=del1 rock(2,i)=( dsyso *ttalo-fl( 1,i+ 1 )*fl(2,i+ 1 ))/rock( 1, i)
c fore ttalc=fl(3,i+ 1 )+rock(3,i) dsysc=(fl(3,i+ 1 )*fl(4,i+ 1) + rock(3,i)*rock(4,i))/ttalc ettalc=fl(3,i+ 1 )+fracp(2)*rock(3,i) edsys=(fl(3,i+ 1 )*f1(4,i+ 1) + 1 fracp(2)*rock(3,i)*rock(4,i))/ettalc del1 =edsys +fracc*rock(3,i)*fracp(2)/ettalc fl(4,i+ 1 )=del1 rock( 4,i)=( dsysc*ttalc-fl(3,i+ 1 )*fl( 4,i+ 1) )/rock(3,i)
c put a dispersive loss factor in here c if fluid 0 greater than 0.5% rock 0 (-porosity indicator) c
c
if(fl(1,i+ 1) .gt.0.005*rock(1,i)) then fl(1,i+ 1 )=fl(1,i+ 1 )*disp fl(3,i+ 1 )=fl(3,i+ 1 )*disp end if else
c now to look in the reaction zone where decarbonation is occurring c use fracp(1) for portion of reequilibration c
if (rrleft(i).gt.rock(3,i)) then newo=XO*rock(3,i) newc=XC*rock(3,i) rrleft(i+ 1 )=rrleft(i)-rock(3,i) else newo=XO*rrleft(i) newc=XC*rrleft(i) rrleft(i+ 1 )=0.0 end if
444
APPENDIX IX- FLUID-ROCK PROGRAM FOR C/0 ISOTOPES
fl(2,i+ 1 )=(fl( 1 ,i)*fl(2,i)+ newo*rock(2,i))/(fl(1 ,i)+newo) fl(1 ,i+ 1 )=fl(1 ,i)+newo rock(1 ,i)=rock(1 ,i)-newo fl(4,i+ 1 )=(fl(3,i)*fl(4,i)+ newc*rock(4,i))/(fl(3,i)+newc) fl(3,i+ 1 )=fl(3,i)+newc rock(3,i)=rock(3,i)-newc
c now to correct T trock(i)=(trock(i)*2.94*dx + tfluid(i)*(fl(1 ,i)-fl(3,i)) 1 *75.9E-6)/(2.94 *dX+(fl(1 ,i+ 1 )-fl(3,i+ 1 ))*75.9E-6) tfluid(i+ 1 )=trock(i)
c and then to find new fractionation values T =trock(i)+273.15 fraco(1 )=-3.23E6/(T*T)+3.29 fraco(2)=9.8E5/(T*T) + 10.611 E3/T -5.67 fracc=-8. 737E6/(T*T) +8.914E8/(T**3) + 18.11 E3/T -8.44
c now we can adjust the isotopic rations for fractional reequilibration c now to allow reequilibration c TOr 0 need to calculate bulk fractionation factor c fraco is dol-h2o 2 is h2o-co2
fro=fraco(1) + fraco(2)*2*fl(3,i+ 1 )/fl(1 ,i+ 1) ttalo=fl(1 ,i+ 1 )+rock(1 ,i) dsyso=(fl(1 ,i+ 1 )*fl(2,i+ 1) + rock(1 ,i)*rock(2,i))/ttalo ettalo=fl(1 ,i+ 1 )+fracp(1 )*rock(1 ,i) edsyso=(fl(1 ,i+ 1 )*fl(2,i+ 1) + 1 fracp( 1 )*rock(1 ,i)*rock(2,i))/ettalo del1 =edsyso +fro*rock(1 ,i)*fracp(1 )/ettalo fl(2,i+ 1 )=del1 if (rock(1 ,i).gt.0.0001) then rock(2,i)=(dsyso*ttalo-fl(1 ,i+ 1 )*f1(2,i+ 1 ))/rock(1 ,i) else rock(2,i)=-1 00.0 end if
c for C ttalc=fl(3,i+ 1 )+rock(3,i) dsysc=(fl(3,i+ 1 )*fl(4,i+ 1) + rock(3,i)*rock(4,i))/ttalc ettalc=fl(3,i+ 1 )+fracp(1 )*rock(3,i) edsysc=(fl(3,i+ 1) *fl(4,i+ 1) + 1 fracp(1 )*rock(3,i)*rock(4,i))/ettalc del1 =edsysc +fracc*rock(3,i)*fracp(1 )/ettalc fl(4,i+ 1 )=del1 f (rock(3,i) .gt.0.0001) then rock(4,i)=(dsysc*ttalc-fl(3,i+ 1 )*fl(4,i+ 1 ))/rock(3,i) else rock(4,i)=-1 00.0 end if
end if end if 195 continue 200 continue
c write or store array c
c
do 93 kk=1,100 write( 6,96) fl(2,kk) ,fl( 4,kk) ,rock(2,kk) ,rock( 4,kk) ,trock(kk) 96 format(5f1 0.2) 93 continue
c end of routine return end
445
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t ---J
.sAQ Soecies
1 H+ 2 H20 3 Cl-4 H2S (aq) 5 HC03-6 H2 (aq) 7 Si~ (aq) 8 AI 9 ca+2 10 Mg+2 -11 Fe+2 12 K+ 13 Na+ 15 zn+2 16 cu+ 17 Pb+2 18 Ag+ 23 F-25 H3As03 (aq) 39 sn+2
APPENDIX XI- REVISED SOLTHERM DATABASE
COMPONENT SPECIES
All reactions are written to the following species
Charae
+1 0
-1 0
-1 0 0
+3 +2 +2 +2 +1 +1 +2 +1 +2 +1 -1 0
+2
Molecular Weicht
1.00797 18.0153 35.453 34.0780 61.0172 2.01594
60.0848 26.9815 40.08 24.312 55.847 39.102 22.9898 65.37 63.54
207.19 107.87
18.998 125.928 118.690
AQUEOUS DERIVED SPECIES Complexes, ion pairs, redox species.
Ag++ + 0.5 H2 (aq) = 1.0 H+ + 1.0 Ag+ 35.153 32.962 29.441 26.741 24.617 22.919 21.554 20.470 0.37658E+02-0.1 0776E+00 0.30808E-03-0.57559E-06 0.49765E-09
AgCI = 1.0 Cl- + 1.0 Ag+ -3.262 -3.076 -2.858 -2.784 -2.821 -2.970 -3.269 -3.913 -0.35434E+01 0.13096E-01-0.85408E-04 0.27177E-06-0.40918E-09
AgCI2- = 2.0 Cl- + 1.0 Ag+ . -5.214 -4.884 -4.519 -4.413 -4.494 -4.741 -5.192 -6.069 -0.56939E+01 0.22395E-01-0.14180E-03 0.41287E-06-0.56925E-09
AgCI3= = 3.0 Cl" + 1.0 Ag+ -4.979 -4.399 -3.731 -3.480 -3.506 -3.751 -4.225 -5.110 -0.57700E+01 0.36583E-01-0.21 015E-03 0.55429E-06-0.67733E-09
AgCI4-3 = 4.0 Cl" + 1.0 Ag+ -3.565 -2.671 -1.812 -1.696 -2.028 -2.669 -3.579 -4.898 -0.48121 E+01 0.58881 E-01-0.37113E-03 0.93454E-06-0.10196E-08
AgF = 1.0 Ag+ + 1.0 F-·.36 -.19 .13 .44 .78 1.19 1.79 -0.52555E+00 0.66103E-02 0.38106E-05-0.64190E-07 0.21260E-09
44:
J092
J092
J092
J092
J092
W082
AgHS + 1.0 H+ = 1.0 H2S (aq) + 1.0 Ag+ -6.925 -6.348 -5.075 -3.707 -2.333 -1.011 0.183 -0.74468E+01 0.19621 E-01 0.53217E-04-0.12581 E~06 0.43321E-10
Ag(HS)2- + 2.0 H+ = 2.0 H2S (aq) + 1.0 Ag+ -3.900 -3.006 -1.450 -0.034 1.414 2.738 4.286 -0.48113E+01 0.38127E-01-0.51701 E-04 0.62832E-07 0.75302E-10
Ag(C.03t + 1.0 H+ = 1.0 HC03- + 1.0 Ag+ 7.539 7.600 7.738 7.884 8.032 8.180 8.325 8.461 0.74807E+01 0.21954E-02 0.48124E-05-0.11533E-07 0.78017E-11
Ag(C03)2-3 + 2.0 H+ = 2.0 HC03- + 1.0 Ag+ 18.298 18.296 18.375 18.545 18.802 19.159 19.662 20.497 0.18368E+02-0.39044E-02 0.55664E-04-0.19179E-06 0.32637E-09
Alf++ = 1.0 Al+3 + 1.0 F--7.00 -7.1 L-7.54 -8.21 -9.17 -10.59 -13.00 -0.70465E+01 0.50002E-02-0.14923E-03 0.62984E-06-0.13613E-08
AIF2+ = 1.0 Al+3 + 2.0 F--12.60 -12.81 -13.58 -14.77 -16.49 -19.04 -23.37 -0.12656E+02 0.74748E-02-0.25070E-03 0.1 0609E-05-0.23498E-08
AIF3 = 1.0 Al+3 + 3.0 F--16.70 -16.94 -17.85 -19.33 -21.49 -24.72 -30.24 -0.16807E+02 0.10910E-01-0.31929E-03 0.13378E-05-0.29734E-08
AIF 4- = 1.0 Al+3 + 4.0 F--19.10 -19.38 -20.45 -22.17 -24.67 -28.40 -34.76 -0.19222E+02 0.12669E-01-0.37338E-03 0.15665E-05-0.34595E-08
Alfs= = 1.0 Al+3 + 5.0 F--20.97 -21.16 -22.10 -23.76 -26.24 -30.01 -36.50 -0.21223E+02 0.18577E-01-0.40657E-03 0.16732E-05-0.36330E-08
AI(OH)++ + 1.0 H+ = 1.0 Al+3 + 1.0 H20 -8.893 -8.875 -8.955 -9.147 -9.437 -9.839-10.401 -11.306 -0.89854E+01 0.51061 E-02-0.66165E-04 0.21798E-06-0.35627E-09
AI(OH)2+ + 2.0 H+ = 1.0 Al+3 + 2.0 H20 1 0.13 8.53 6.00 4.00 2.50 1.00 0.0 0.12104E+02-0.86561 E-01 0.34341 E-03-0.10235E-05 0.13065E-08
AI(OH)3 + 3.0 H+ = 1.0 Al+3 + 3.0 H20 6.130 14.190 10.990 8.430 6.290 4.450 2.850 2.000 18.4637E+00-1.00946E-01 3.47304E-04-9.7658~E-07 1.21179E-09
AI(OH)4- + 4.0 H+ = 1.0 Al+3 + 4.0 H20 22.16 19.88 16.70 14.80 13.30 12.20 10.60 0.24956E+02-0.12466E+00 0.52048E-03-0.10347E-05 0.51200E-09
H2As03- + 1.0 H+ = 1.0 H3As03 (aq) 9.240 8.890 8.580 8.620 8.880 9.300 9.850 0.97459E+01-0.23959E-01 0.15501 E-03-0.35873E-06 0.37363E-09
HAs03= + 2.0 H+ = 1.0 H3As03 (aq)
450
SR89/J092
SR89/J092
J092
J092
W082
W082
W082
W082
W082
J092
RS84
P&H92
RS84
SR89b
21.360 20.630 19.900 19.840 20.240 20.960 21.930 0.22378E+02-0.47447E-01 0.28001 E-03-0.59687E-06 0.58037E-09
As03-3 + 3.0 H+ = 1.0 H3As03 (aq) 34.760 33.720 32.670 32.560 33.120 34.120 35.480 0 .36208E+02-0 .67376E-O 1 0 .39446E-03-0 .83555 E-06 0 .80786E-09
AsO+ + 2.0 H20 = 1.0 H+ + 1.0 H3As03 (aq) 0.300 0.070 -0.320 -0.570. -0.780 -0.820 -0.860 0.54041E+00-0.99309E-02 0.77755E-05 0.76375E-07-0.14574E-09
H3As04 + 1.0 H2 (aq) = 1.0 H20 + 1.0 H3As03 (aq) 22.280 20.644 17.981 15.859 14.141 12.726 11.486 0.24119E+02-0.78677E-01 0.20566E-03-0.36433E-06 0.28383E-09
H2As04- + 1.0 H2 (aq) + 1.0 H+ = 1.0 H20 + 1.0 H3As03 (aq) 24.480 23.034 20.781 19.289 18.311 17.726 17.366 0.26199E+02-0.74241 E-01 0.23155E-03-0.31355E-06 0.13159E-09
HAs04= + 1.0 H2 (aq) + 2.0 H+ = 1.0 H20 + 1.0 H3As03 (aq) 31.450 30.004 27.941 26.839 26.371 26.406 26.716 0.33243E+02-0.78906E-01 0.30121 E-03-0.43585E-06 0.22271 E-09
As04-3 + 1.0 H2 (aq) + 3.0 H+ = 1.0 H20 + 1.0 H3As03 (aq) 42.960 41.294 39.081 38.069 37.861 38.286 39.066 0.45071 E+02-0.94170E-01 0.40403E-03-0.65072E-06 0.42642E-09
AsH3(aq) + 3.0 H20 = 3.0 H2 (aq) + 1.0 H3As03 (aq) -4.639 -3.841 -2.233 -0.605 0.947 2.444 3.954 -0.53802E+01 0.28699E-01 0.49937E-04-0.24997E-06 0.36775E-09
HAs3Ss= + 9.0 H20 + 2.0 H+ = 6.0 H2S (aq) + 3.0 H3As03 (aq) -25.010 -21.528 -15.600 -10.722 -6.558 -2.916 0.268 -0.28935E+02 0.16671 E+00-0.41 049E-03 0.85072E-06-0.84383E-09
H2As3S5- + 1.0 H+ + 9.0 H20 = 6.0 H2S (aq) + 3.0 H3As03 (aq) -31.560-27.948-21.890-16.952-12.788 -9.336 -6.572 0.0 -0.35642E+02 0.17427E+00-0.45877E-03 0.10379E-05-0.12279E-08
H3As3S5 + 9.0 H20 = 6.0 H2S (aq) + 3.0 H3As03 (aq) -36.820-32.858-26.490-21.592-17.688-14.656-12.442 0.0 -0.41412E+02 0.19839E+00-0.61587E-93 0.14064E-05-0.16164E-08
CaCI+ = 1.0 ca+2 + 1.0 Cl-0.720 0.653 0.384 0.001 -0.469 -1.030 -1.730 -2.770 0.70023E+00 0.24985E-02-0.79657E-04 0.27418E-06-0.42248E-09
CaCI2 = 1.0 Ca+2 + 2.0 Cl-0.706 0.717 0.452 -0.062 0.769 -1.675 -2.873 -4.771 0.51349E+00-0.11258E-01-0.16562E-03 0.55727E-06-0.85464E-09
CaC03 + 1.0 H+ = 1 .0 Ca+2 + 1.0 HC03-6.911 6.506 5.894 5.427 5.017 4.596 4.074 3.201 0.73359E+01-0.18304E-01 0.39644E-04 0.10194E-07-0.20111 E-09
CaHC03+ = 1.0 Ca+2 + 1.0 HC03--1.034 -1.104 -1.403 -1.829 -2.344 -2.952 -3.698 -4.781 -0.10564E+01 0.28309E-02-0.88149E-04 0.29825E-06-0.44665E-09
45:
SR89b
SR89b
SR89b
SR89/J092
SR89/J092
SR89/J092
SR89/J092
SR89/J092
SR89/J092
SR89/J092
SR89/J092
B086/J092
B086/J092
J092
J092
Caf+ = 1.0 Ca+2 + 1.0 F--0.629 -0.751 -1.119 -1.585 -2.128 -2.756 -3.521 -4.631 -0.58831 E+00-0.13005E-04-0.75612E-04 0.27127E"06-0.42676E-09
CaOH+ + 1.0 H+ = 1.0 Ca+2 + 1.0 H20 12.60 11.78 10.47 9.47 8.58 7.65 6.40 0 .13540E+02-0 .40391 E-0 1 0 .11167E-03-0 .12684E-06-0.20338E-09
CaS04 + 4.0 H2 (aq) + 2.0 H+ = 1.0 Ca+2 + 1.0 H2S (aq) + 4.0 H20 51.072 47.510 41.743 37.263 33.653 30.634 27.989 25.414 0.55094E+02-0.17238E+00 0.45968E-03-0.76115E-06 0.46529E-09
CH4(aq) + 3.0 H20 = 1.0 HC03- + 1.0 H+ + 4.0 H2 (aq) -40.436-37.173-31.860-27.724-24.423-21.743-19.561 -17.856 -0.44161 E+02 0.15975E+00-0.44388E-03 0.84525E-06-0.76456E-09
HCI = 1.0 H+ + 1.0 Cl-0.860 o.85Q_ o.7oo o.43o o.o4o -0.480 -1.240 -2.650 0.73664E+00 0.70840E-02-0.11052E-03 0.43541 E-06-0.73231 E-09
co3= + 1.0 H+ = 1.0 Hco3-1 0.199 10.042 9.960 10.073 10.326 10.705 11.246 12.132 0.10472E+02-0.13478E-01 0.11220E-03-0.33616E-06 0.46932E-09
H2CD3 = 1.0 H+ + 1.0 HCo3--6.231 -6.162 -6.287 -6.622 -7.089 -7.660 -8.359 -9.349 -0.64265E+01 0.10688E-01-0.12507E-03 0.37279E-06-0.48811 E-09
Cu++ + 0.5 H2 (aq) = 1.0 H+ + 1.0 Cu+ 4.266 4.371 4.523 4.630 4.721 4.814 4.927 5.072 0.41384E+01 0.56717E-02-0.23421 E-04 0.55589E-07-0.37718E-1 0
CuCI+ + 0.5 H2 (aq) = 1.0 Cu+ + 1.0 H+ + 1.0 Cl-4.310 3.912 3.050 2.130 1.101 0.133 -0.827 0.46755E+01-0.14179E-01-0.20786E-04-0.40207E-08 0.90456E-10
CuCI2 + 0.5 H2 (aq) = 1.0 Cu+ + 1.0 H+ + 2.0 Cl-5.010 4.532 3.440 2.340 1.101 0.033 -1.327 0.53637E+01-0.11814E-01-0.11595E-03 0.50726E-06-0.79012E-09
CuCI3- + 0.5 H2 (aq) = 1.0 Cu+ + 1.0 H+ + 3.0 Ql-6.610 5.962 4.550 3.179 1.701 0.333 -1.327 0.71770E+01-0.20806E-01-0.89119E-04 0.43249E-06-0.73015E-09
CuCI4= + 0.5 H2 (aq) = 1.0 Cu+ + 1.0 H+ + 4.0 Cl-8.91 0 8.002 6.220 4.520 2.801 1.033 -0.928 0.98425E+01-0.37562E-01 0.11881E-04 0.42820E-07-0.21319E-09
CuCI = 1.0 Cu+ + 1.0 Cl--4.21 -4.10 -3.94 -3.94 -4.06 -4.35 -4.44 -0.42681 E+01 0.13716E-02 0.57618E-04-0.47120E-06 0.85802E-09
CuCI2-x = 1.0 Cu+ + 2.0 Cl--4.940 -4.580 -4.300 -4.530 -4.510 -4.820 -5.400 -0.56512E+01 0.36078E-01-0.34877E-03 0.13850E-05-0.20475E-08
CuCI3=X = 1.0 Cu+ + 3.0 Cl-
452
J092
HH70
J092
AR82
sv91
J092
J092
J092
HH69/J092
HH69/J092
HH69/J092
HH69/J092
BA79B
MR88
-5.140 -4.480 -3.880 -3.820 -3.820 -3.960 -4.300 -0.61820E+01 0.50788E-01-0.39827E-03 0.13762E-05-0.18110E-08
Cu(HS)2- + 2.0 H+ = 1.0 Cu+ + 2.0 H2S (aq) -4.890 -4.136 -2.560 -1.074 0.344 1.688 3.536 -0.55103E+01 0.21875E-01 0.14767E-03-0.87106E-06 0.15690E-08
HF = 1.0 H+ + 1.0 F--3.1 06 -3.322 -3.785 -4.267 -4.773 -5.321 -5.965 -6.887 -0.29342E+01-0.61577E-02-0.37982E-04 0.17739E-06-0.31642E-09
HF2- = 1.0 H+ + 2.0 F-·2.443 -2.743 -3.282 -3.771 -4.249 -4.758 -5.364 -6.266 -0.21562E+01-0.11614E-01-0.36991 E-05 0.97868E-07-0.25223E-09
FeCI+ = 1.0 Fe+2 + 1.0 Cl-0.182 0.105 -0.176 -0.560 -1.023 -1.575 -2.262 -3.288 0.17754E+00-0.18020E-02 0.75705E-04 0.26669E-06-0.41678E-09
FeCI2 = 1.0 Fe+2 + 2.0 Cl-121.437 111.978 96.789 85.084 75.707 67.911 61.128 54.642 0.13218E+03-0.46153E+00 0.12839E-02-0.22416E-05 0.15228E-08
Fe+3 + 0.5 H2 (a ) = 1.0 H+ + 1.0 Fe+2 14.529 1~.984 13.126 12.493 12.025 11.685 11.450 11.288 0.15152E+02-0.26867E-01 0.77687E-04-0.12718E-06 0.98384E-1 0
FeCJ+2 + 0.5 H2 (aq) = 1.0 Fe+2 + 1.0 H+ + 1.0 Cl-12.770 11.922 10.310 8.800 7.611 6.303 4.612 0.13548E+02-0.29442E-01-0.90533E-04 0.73288E-06-0.14501 E-08
FeCJ2+ + 0.5 H2 (aq) = 1.0 Fe+2 + 1.0 H+ + 2.0 Cl-13.500 12.932 11.930 11.040 10.251 9.523 8.803 0.141 00E+02-0.24939E-01 0.34533E-04-0.22023E-07 -0.40541 E-1 0
FeCI3 + 0.5 H2 (aq) = 1.0 Fe+2 + 1.0 H+ + 3.0 Cl-13.020 11.852 9.730 7.689 5.711 3.873 2.753 0.14373E+02-0.58299E-01 0.19852E-03-0.97261 E-06 0.17606E-08
FeCI4- + 0.5 H2 (aQ) = 1.0 Fe+2 + 1.0 H+ + 4.0 Cl-14.940 13.792 11.1 00 8. 760 6.511 4.673 2.953 0.16063E+02-0.40714E-01-0.15329E-03 0.82412E-06-0.11545E-08
FeF+ = 1.0 Fe+2 + 1.0 F-·1.45 -1.66 -2.10 -2.61 -3.21 -4.00 -5.25 -0.12977E+01-0.51982E-02-0.48639E-04 0.25845E-06-0.61627E-09
FeOH+ + 1.0 H+= 1.0 Fe+2 + 1.0 H20 10.18 9.62 8.74 8.06 7.53 7.10 6.74 6.45 0.10828E+02-0.28045E-01 0.88086E-04-0.18710E-06 0.17903E-09
Fe(OH)2 + 2.0 H+ = 1.0 Fe+2 + 2.0 H20 21.42 19.79 17.28 15.44 14.05 12.98 12.14 11.47 0.23341 E+02-0.83743E-01 0.28703E-03-0.62423E-06 0.61047E-09
KCI = 1.0 K+ + 1.0 Cl-1.537 1.335 0.969 0.629 0.286 -0.093 -0.570 -1.354 0.17111 E+01-0.68438E-02-0.15914E-04 0.12984E-06-0.28548E-09
453
MR88
BA79/J092
J092
J092
HS90/J092
HS90/J092
J092-PAUL
W082-PAUL
W082-PAUL
HH69-PAUL
HH69-PAUL
W082
TL80
TL80
J092
MgCI+ = 1.0 Mg+2 + 1.0 Cl-0.157 0.116 -0.153 -0.563 -1.072 -1.677 -2.422 -3.509 0.97987E-01 0.45520E-02-0.98128E-04 0.32558E-06-0.47560E-09
MgC03 + 1.0 H+ = 1.0 Mg+2 + 1.0 HCo3-7.264 6.953 6.502 6.173 5.884 5.567 5.132 4.338 0.75898E+01-0.14139E-01 0.32610E-04 0.19090E-07-0.20741 E-09
MgF+ = 1.0 Mg+2 + 1.0 F--1.298 -1.377 -1.683 -2.099 -2.597 -3.184 -3.912 -4.995 -0.13069E+01 0.22078E-02-0.84762E-04 0.29939E-06-0.46057E-09
MgHC03+ = 1.0 Mg+2 + 1.0 HCo3--1.026 -1.1 05 -1.420 -1.849 -2.358 -2.950 -3.670 -4.709 -0.1 0330E+01 0.21721 E-02-0.85033E-04 0.29256E-06-0.43725E-09
MgOH+ + 1.0 H+ = 1.0 Mg+2 + 1.0 H20 11.80 1 0.7!L 9.34 8.05 7.15 6.25 5.32 0.12960E+02-0.52371 E-01 0.19856E-03-0.50541 E-06 0.47544E-09
NaCI = 1.0 Na+ + 1.0 Cl-0.809 0.720 0.506 0.257 -0.030 -0.379 -0.846 -1.642 0 .84390E+00-0 .58289E-03-0 .43991 E-04 0. 19583E-06-0 .35229E-09
Naco3- + 1.0 H+ = 1.0 Na+ + 1.0 HCo3-9.36 9.13 8.93 8.84 8.83 9.06 10.14 14.33 0.97926E+01-0.22075E-01 0.22310E-03-0.10856E-05 0.20002E-08
NaF = 1.0 Na+ + 1.0 F-1.040 0.922 0.665 0.392 0.087 -0.279 -0.766 -1.588 0.11136E+01-0.23065E-02-0.36016E-04 0.17709E-06-0.33802E-09
NaHC03 = 1.0 Na+ + 1.0 HC03-1.1 0 0.90 0.57 0.34 -0.06 -0.34 -0.95 -1.9 0.12832E+01-0.77188E-02 0.24715E-05 0.70360E-07-0.25096E-09
NaOH + 1.0 H+ = 1.0 Na+ + 1.0 H20 14.70 13.93 12.80 12.06 11.49 11.04 1 0.57 0.15628E+02-0.40790E-01 0.15568E-03-0.31845E-06 0.21807E-09
02 (aq) + 0.5 H2 (aq) = 2.0 H20 . 92.409 84.867 72.532 62.847 55.002 48.471 42.881 37.850 0.99149E+02-0.28160E+00-0.44747E-04 0.26712~-05-0.48397E-08
OH- + 1.0 H+ = 1.0 H20 13.89813.183 12.17311.54411.18311.03911.11811.577 0.14 799E+02-0 .40 196E-01 0.17858E-03-0.44979E-06 0.55002E-09
PbCI+ = 1.0 Pb+2 + 1.0 Ct" -1.412 -1.503 -1.779 -2.135 -2.563 -3.079 -3.740 -4.771 -0.13957E+01 0.69977E-03-0.66025E-04 0.25008E-06-0.41660E-09
PbCI2 = 1.0 Pb+2 + 2.0 Cl--1.938 -2.095 -2.550 -3.131 -3.827 -4.672 -5.773 -7.552 -0.19128E+01 0.12388E-02-0.11300E-03 0.44630E-06-0.75700E-09
PbCI3- = 1.0 Pb+2 + 3.0 Cl-
454
J092
J092
J092
J092
MH73
J092
BS78
J092
SW76
W082
J092
J092
J092
J092
-1.569 -1.736 -2.252 -2.926 -3.743 -4.738 -6.033 -8.110 -0.15580E+01 0.23016E-02-0.13582E-03 0.52451 E-06-0.87980E-09
PbCI4= = 1.0 Pb+2 + 4.0 Ct" -1.298 -1.297 -1.677 -2.369 -3.286 -4.425 -5.880 -8.086 -0.15148E+01 0.13192E-01-0.20492E-03 0.67140E-06-0.99072E-09
PbC03 + 1.0 H+ = 1.0 HCo3- + 1.0 Pb+2 0.36 0.27 0.14 -0.10 -0.24 -0.14 1.07 0 .52896E+00-0 .88200E-02 0 .11279E-03-0 .81769 E-06 0. 18652E-08
Pbf+ = 1.0 f· + 1.0 Pb+2 -2.09 -2.24 -2.59 -3.00 -3.53 -4.26 -5.43 -0.19820E+01-0.34717E-02-0.41586E-04 0.20734E-06-0.52605E-09
Pb(HS)2 + 2.0 H+ = 2.0 H2S (aq) + 1.0 Pb+2 -0.090 -0.546 -0.890 -0.544 0.584 1.868 3.076 0.53217E+00-0.27570E-01 0.10155E-03 0.42260E-06-0.12025E-08
Pb(HS)3- + 3.0 H+ = 3.0 H2S (aq) + 1.0 Pb+2 4.855 5.136 6.055 7.239 8.571 9.997 11.509 0.47164E+01 0.19229E-02 0.15111 E-03-0.41724E-06 0.47922E-09
PbOH+ + 1.0 H+= 1.0 Pb+2 + 1.0 H20 6.20 5.66 4.86 4.26 3.78 3.30 2.95 0.67511 E+01-0.23970E-01 0.54807E-04-0.44246E-07 O.OOOOOE+OO
S2-2 + 1.0 H2 (aq) + 2.0 H+ = 2.0 H2S (aq) 26.707 25.376 23.553 22.476 21.914 21.761 22.025 23.012 0.28406E+02-0.76311 E-01 0.35713E-03-0.90973E-06 0.11041 E-08
HS- + 1.0 H+ = 1.0 H2S (aq) 6.925 6.662 6.425 6.433 6.607 6.919 7.393 8.211 0.73284E+01-0.19231 E-01 0.13558E-03-0.39024E-06 0.51542E-09
HS04- + 4.0 H2 (aq) + 1.0 H+ = 1.0 H2S (aQ) + 4.0 H20 51.244 47.463 41.280 36.454 32.589 29.431 26.822 24.680 0.55546E+02-0.18418E+00 0.49807E-03-0.90878E-06 0.76971 E-09
HSi03- + 1.0 H+ = 1.0 Si02 (aq) + 1.0 H20 9.847 9.503 9.005 8.770 8.750 8.912 9.261 9.929 0.10318E+02-0.20819E-01 0.95121 E-0~-0.20568E-06 0.27061 E-09
H2Si04= + 2.0 H+ = 1.0 Si02 (aq) + 2.0 H20 21.33 20.61 20.00 20.10 20.36 21.13 22.20 24.0 0.22397E+02-0.51768E-01 0.37939E-03-0.11540E-05 0.15250E-08
H3Si04- + 1.0 H+ = 1.0 Si02 (aq) + 2.0 H20 9.69 9.35 8.94 8.78 8.77 8.87 9.10 0.10161 E+02-0.21676E-01 0.12366E-03-0.32958E-06 0.39641 E-09
SnCI+ = 1.0 Sn+2 + 1.0 Ct" 9.174 6.936 3.526 1.248 -0.285 -1.476 -2.746 -4.582 0.11820E+02-0.11459E+00 0.35899E-03-0.40437E-06-0.19555E-09
SnCI2 = 1.0 Sn+2 + 2.0 Cl-4.455 3.036 0.826 -0.752 -1.985 -3.176 -4.646 -6.782 0.61197E+01-0.71907E-01 0.21887E-03-0.27064E-06-0.19602E-09
455
J092
J092
W082
W082
BA79/J092
BA79/J092
HC88&TG75
J092
J092
J092
J092
C064
FC82
RP86/J092
RP86/J092
SnCJs· = 1.0 Sn+2 + 3.0 Cl--4.145 -2.864 -1.474 -1.352 -2.185 -3.676 -5.546 -7.582 -0.58803E+01 0.79093E-01-0.40113E-03 0.52936E"06-0.19602E-09
SnCJ4= = 1.0 Sn+2 + 4.0 Ct" -6.839 -4.364 -1.374 -0.452 -0.985 -2.376 -4.046 -5.482 -0.10081 E+02 0.14611 E+00-0.68125E-03 0.92976E-06-0.19649E-09
SnOH2CI2 + 1.0 H2 (aq) = 1.0 Sn+2 + 2.0 Ct + 2.0 H20 0.224 -0.864 -2.274 -2.952 -3.285 -3.676 -4.546 -6.382 0.16202E+01-0.62587E-01 0.27899E-03-0.40437E-06-0.19555E-09
ZnCJ+ = 1.0 zn+2 + 1.0 cJ--0.178 -0.802 -1.965 -3.035 -4.056 -5.080 -6.185 -7.602 0.44053E+00-0.24988E-01 0.14118E-06 0.12329E-06-0.30636E-09
ZnCI2 = 1.0 zn+2 + 2.0 Cl--0.195 -0.686. -1.770 -2.920 -4.136 -5.462 -7.013 -9.204 0.18796E+00-0.13422E-01-0.96464E-04 0.42568E-06-0.74125E-09
ZnCJs· = 1.0 zn+2 + 3.0 CJ· 0.124 -0.144 -0.946 -1.951 -3.108 -4.432 -6.025 -8.303 0 .22492E+00-0 .62245E-03-0.15823E-03 0.56555E-06-0 .87762E-09
ZnCJ4= = 1.0 zn+2 + 4.0 Cl--0.689 -0.870 -1.614 -2.651 -3.889 -5.324 -7.045 -9.462 -0.71406E+00 0.54951 E-02-0.20138E-03 0.66677E-06-0.97200E-09
ZnF+ = 1.0 zn+2 + 1.0 F· -1.15 -1.45 -1.95 -2.47 -3.09 -3.90 -5.17 -0 .86040E+00-0.12128E-01 0.1 0989E-04 0.36678E-07 -0.32694E-09
ZnHCOs+ = 1.0 zn+2 + 1.0 HC03· -1.42 -1.55 -1.82 -2.20 -2.71 -3.41 -4.55 -6.03 -0.13512E+01-0.21118E-02-0.39514E-04 0.17292E-06-0.45378E-09
Zn(HS)2 + 2.0 H+ = 1.0 Zn+2 + 1.0 H2S (aq) 0.900 0.704 0.550 0.566 0.314 0.038 -0.214 0.122 0.13225E+01-0.21910E-01 0.23365E-03-0.10441 E-05 0.15066E-08
Zn(HS)s- + 3.0 H+ = 1.0 zn+2 + 1.0 H2S (aq) . 0.900 0.704 0.550 0.566 0.314 0.038 -0.214 0.122 0.13225E+01-0.21910E-01 0.23365E-03-0.10441 E-05 0.15066E-08
Zn(HS)4= + 4.0 H+ = 1.0 Zn+2 + 4.0 H2S (aq) 14.300 13.498 12.700 12.432 12.428 12.676 13.572 15.744 0.15487E+02-0.57189E-01 0.41938E-03-0.14833E-05 0.21654E-08
ZnOH+ + 1.0 H+ = 1.0 zn+2 + 1.0 H20 7.50 6.44 4.85 3.63 2.67 1.82 1.10 0.000 0.85679E+01-0.46209E-01 0.94896E-04-0.52949E-07 O.OOOOOE+OO
ZnOH2 + 2.0 H+ = 1.0 Zn+2 + 2.0 H20 8.42 17.56 16.20 15.15 14.33 13.67 13.12 0.19405E+02-0.42558E-01 0.12752E-03-0.25331 E-06 0.22777E-09
ZnOHs· + 3.0 H+ = 1.0 zn+2 + 3.0 H20
45€'
RP86/J092
RP86/J092
RP86/J092
J092
J092
J092
J092
W082
6086
6086/J092
6086/J092
6083/J092
HC88&KY75
6086
29.90 28.09 25.39 23.51 22.21 21.31 20.71 0.32053E+02-0.94390E-01 0.34066E-03-0.70651 E-06 0.66553E-09
ZnOH4= + 4.0 H+ = 1.0 zn+2 + 4.0 H20 42.71 40.40 37.06 34.88 33.52 32.73 32.36 0.45504E+02-0.12328E+00 0.47554E-03-0.97 451 E-06 0.90790E-09
GASES
H20(g) = 1.0 H20 1.507 0.921 -0.071 -0.722 -1.209 -1.580 -1.866 -2.084 0.22480E+01-0.31797E-01 0.10666E-03-0.20423E-06 0.16565E-09
C02 (g) + 1.0 H20 = 1.0 HC03- + 1.0 H+ -7.842 -8.011 -8.380 -8.777 -9.202 -9.671 -10.227 -11.046 -0.77199E+01-0.41771 E-02-0.38195E-04 0.16957E-06-0.29675E-09
CH4 (g)+ 3.0 H20 = 1.0 HC03- + 4.0 H2 (aq) + 1.0 H+ -43.447-40.319-35.059 -30.816-27.317-24.381 -21.889-19.772 -0 .46953E+02 0.14886E+00-0.35434E-03 0.60223E-06-0.4887 4E-09
H2 (g) = 1.0 H2 (aq) -3.215 -3.244 -3.194 -3.064 -2.889 -2.684 -2.450 -2.152 -0.31420E+01-0.40264E-02 0.46450E-04-0.13059E-06 0.15382E-09
H2S(g) = 1 .0 H2S (aq) -1.140 -1.357 -1.602 -1.693 -1.690 -1.628 -1.520 -1.361 -0.85396E+00-0.13219E-01 0.72603E-04-0.17095E-06 0.17032E-09
HCI(g) = 1.0 H+ + 1.0 Cl-6.30 5.26 3.46 1.96 0.69 -0.46 -1.49 0.74647E+01-0.49115E-01 0.1 0837E-03-0.19099E-06 0.14594E-09
HF(g) = 1.0 H+ + 1.0 F-0.95 0.14 -1.35 -2.63 -3.79 -4.72 -5.64 0.17775E+01-0.33608E-01 0.12507E-04 0.14015E-06-0.27679E-09
S02 (g) + 3.0 H2 (aq) = 2.0 H20 + 1.0 H2S (aq) 44.741 40.626 33.906 28.641 24.382 20.842 17.810 15.065 0.49391 E+02-0.19900E+00 0.52531 E-Q3-0.90990E-06 0.66572E-09
02 (g) + 2.0 H2 (aq) = 2.0 H20 . 89.378 81.709 69.308 59.705 52.029 45.730 40.433 35.821 0.98105E+02-0.37471 E+OO 0.10407E-02-0.18952E-05 0.15090E-08
45-
8086
8086
J092
J092
J092
J092
J092
RS91
RS91
J092
J092
458
MINERALS
acanthit + 2.0 H+ = 1.0 H2S (aq) + 2.0 Ag+ -29.047-26.258-21.669-18.038-15.108-12.710-10.703 -9.022 J092 -0.32189E+00 0.13412E+00-0.34294E-03 0.5901-0E-06-0.471 05E-09 7.246
akermani + 6.0 H+ = 2.0 ca+2 + 1.0 Mg+2 + 2.0 Si02 (aq) + 3.0 H20 45.186 41.151 34.708 29.867 26.079 22.902 19.798 15.196 RS91 0.49832E+02-0.19967E+00 0.56821 E-03-0.87430E-06 0.28848E-09 2.938
albit-hi + 4.0 H+ = 1.0 Na+ + 1.0 AJ+3 + 3.0 Si02 (aq) + 2.0 H20 3.025 2.203 0.532 -0.872 -2.029 -3.032 -3.993 -5.097 BM88 0.39100E+01-0.34676E-01-0.14008E-04 0.29976E-06-0.53376E-09 2.611
albit-lo + 4.0 H+ = 1.0 Na+ + 1.0 AJ+3 + 3.0 Si02 (aq) + 2.0 H20 1.547 0.908 -0.470 -1.651 -2.632 -3.493 -4.336 -5.341 BM88 0.22217E+01-0.25616E-01-0.40573E-04 0.35011 E-06-0.57583E-09 2.620
almandin + 12.0 H+ .=_3.0 Fe+2 + 2.0 AJ+3 + 3.0 Si02 (aq) + 6.0 H20 39.270 33.515 23.902 16.337 10.159 4.859 0.008 -4.915 BM88 0.45775E+02-0.27639E+00 0.671 07E-03-0.97017E-06 0.36265E-09 4.320
analcime + 4.0 H+ = 1.0 Na+ + 1.0 AJ+3 + 2.0 Si02 (aq) + 3.0 H20 6.094 5.000 3.039 1.469 0.190 -0.919 -1.968 -2.752 J092 0.74111 E+01-0.55397E-01 0.14481 E-03-0.30121 E-06 0.29271 E-09 2.267
anal-dhy + 4.0 H+ = 1.0 Na+ + 1.0 AJ+3 + 2.0 Si02 (aq) +. 2.0 H20 11.987 10.392 7.844 5.957 4.490 3.211 1.766 -1.063 RS91 0.13810E+02-0.77945E-01 0.20318E"03-0.17924E-06-0.26000E-09 2.269
andalusi + 6.0 H+ = 2.0 AJ+3 + 1.0 Si02 (aq) + 3.0 H20 12.304 9.537 4.922 1.250 -1.803 -4.475 -6.962 -9.469 BM88 0.15431 E+02-0.13312E+00 0.33215E-03-0.54525E-06 0.29212E-09 3.145
andradit + 1.0 H2 (aq) + 10.0 H+ = 2.0 Fe+2 + 3.0 ca+2 + 3.0 Si02 (aq) + 6.0 H20 62.881 57.539 48.600 41.570 35.865 31.025 26.653 22.185 J092 0.68887E+02-0.25476E+00 0.59441 E-03-0.76222E-06 0.15539E-09 3.854
grossula + 12.0 H+ = 3.0 Ca+2 + 2.0 AJ+3 + 3.0 Si02 (aq) + 6.0 H20 48.792 43.233 33.935 26.599 20.594 15.434 10.706 5.888 BM88 0.55062E+02-0.26626E+00 0.63839E-03-0.90637E-06 0.31184E-09 3.595
anglesit + 4.0 H2 (aq) + 2.0 H+ = 1.0 H2S (aq) + 4.0 H20 + 1.0 Pb+2 45.494 42.112 36.486 31.983 28.257 25.069 22.221 19.427 J092 0.49266E+02-0.16036E-OO 0.38004E-03-0.57517E-06 0.29313E-09 6.324
annite + 10.0 H+ = 1.0 K+ + 3.0 Fe+2 + 1.0 AJ+3 + 3.0 Si02 (aq) + 6.0 H20 29.035 25.525 19.567 14.875 11.061 7.792 4.765 1.563 J092 0 .32987E+02-0 .16684E+00 0.36787E-03-0.39347E-06-0.81472E-1 0 3.317
anorthit + 8.0 H+ = 1.0 ca+2 + 2.0 AJ+3 + 2.0 Si02 (aq) + 4.0 H20 21.804 18.181 12.080 7.229 3.225 -0.248 -3.458 -6.724 BM88 0.25886E+02-0.17308E+00 0.40699E-03-0.58111 E-06 0.20190E-09 2.760
. anthophy + 14.0 H+ = 7.0 Mg+2 + 8.0 Si02 (aq) + 8.0 H20 70.620 63.505 51.355 41.908 34.428 28.241 22.739 17.095 BM88 0.78658E+02-0.33840E+00 0.72125E-03-0.60202E-06-0.37756E-09 2.953
459
antig/16 + 6.0 H+ = 3.0 Mg+2 + 2.125 Si02 (aq) + 4.938 H20 30.703 27.727 22.840 19.129 16.224 13.831 11.708 9.544 BM88 0.34105E+02-0.14513E+00 0.37562E-03-0.51744E-06 0.16041E-09 2.593
aragonit + 1.0 H+ = 1.0 ca+2 + 1.0 HCo3-2.111 1.726 1.015 0.350 -0.310 -1.008 -1.819 -2.980 J092 0.24728E+01-0.14501 E-01-0.10740E-04 0.13080E-06-0.31 098E-09 2.931
arsenic + 3.0 H20 = 1.5 H2 (aq) + 1.0 H3As03 (aq) . -17.290-15.805 -13.302 -11.198 -9.412 -7.856 -6.439 SR89/J092 -0.18922E+02 0.69120E-01-0.15247E-03 0.26225E-06-0.19915E-09 5.700
arsenoli + 3.0 H20 = 2.0 H3As03 (aq) -1.460 -1.100 -0.480 0.080 0.580 1.060 1.540 RS91 -0.18440E+01 0.16135E-01-0.29339E-04 0.51348E-07-0.25023E-1 0
arsenopy +3.0 H20 + 2.0 H+ = 1.0 fe+2 + 1.5 H2 (aq) + 1.0 H2S (aq) + 1.0 H3As03 {aq) -15.896-14.779-12.804-10.978 -9.388 -8.105 -7.208 SR89/J092 -0.17049E+02 0.48022E-01-0.66492E-04 0.16078E-06-0.36097E-09
artinHe + 3.0 H+ = 2.0 Mg+2 + 1.0 HC03- + 5.0 H20 19.936 18.153 15.368 13.289 11.605 10.041 8.171 4.471 RS91 0.21989E+02-0.8861 OE-01 0.26028E-03-0.35790E-06-0.12286E-09 2.030
As20s(S) + 1.0 H20 + 2.0 H2 (aq) = 2.0 H3As03 (aq) 52.739 49.047 43.142 38.537 34.882 31.951 29.451 SR89/J092 0.56930E+02-0.18031 E+OO 0.50942E-03-0.95344E-06 0.99071 E-09
beide-Mg + 7.32 H+ = 0.165 Mg+2 + 2.33 Al+3 + 3.67 Si02 (aq) + 4.66 H20 6.299 4.048 0.439 -2.250 -4.398 -6.409 -8.985 -14.697 RS91 0 .88387E+01-0 .1 0809E+00 0.25414E-03-0.5039?E-07-0.85244E-09 2.840
beide-Na + 7.32 H+ = 0.33 Na+ + 2.33 Al+3 + 3.67 Si02 (aq) + 4.66 H20 6.377 4.267 0.871 -1.635 -3.619 -5.470 -7.866 RS91 0.87711 E+01-0.1 0186E+00 0.23918E-03-0.25784E-07-0.85294E-09 2.84000
berndtit + 1.0 H2 (aq) + 2.0 H+ = 1.0 Sn+2 + 2.0 H2S (aq) -7.674 -6.705 -5.095 -3.816 -2.788 -1.964 -1.326 -0.904 J092 -0.87729E+01 0.46875E-01-0.12175E-03 0.23312E-06-0.24107E-09 4.500
boehmite + 3.0 H+ = 1.0 Al+3 + 2.0 H20 9.596 7.996 5.530 3.723 2.302 1.952 -0.335 -2.873 RS91 0.11458E+02-0.80809E-01 0.25594E-03-0.42385E-06 0.1 0624E-09 3.071
bornHe + 0.5 H2 (aq) + 7.0 H+ = 5.0 Cu+ + 1.0 fe+2 + 4.0 .H2S (aq) -70.070 -63.931 -53.646 -45.358 -38.536 -32.904 -28.243 -24.453 J092 -0.76929E+02 0.29138E+00-0.69293E-03 0.11808E-05-0.10166E-08 5.089
brucite + 2.0 H+ = 1.0 Mg+2 + 2.0 H20 16.408 14.901 12.545 10.790 9.419 8.298 7.329 6.412 BM88 0.18148E+02-0.75419E-01 0.23503E-03-0.44798E-06 0.33844E-09 2.368
calcite + 1.0 H+ = 1.0 ca+2 + 1.0 HC03-2.113 1.721 0.998 0.323 -0.347 -1.055 -1.876 -3.046 BM88 0.24831 E+01-0.14863E-01-0.94761 E-05 0.12663E-06-0.30601 E-09 2.710
cassiter + 1.0 H2 (aq) + 2.0 H+ = 1.0 Sn+2 + 2.0 H20 0.099 0.136 0.126 0.048 -0.085 -0.276 -0.546 -0.982 J092
46C
0.20170E-01 0.40798E-02-0.41015E-04 0.12897E-06-0.19555E-09 7.000
cerussit + 1.0 H+ = 1.0 HC03- + 1.0 Pb+2 -3.074 -2.925 -2.796 -2.825 -2.984 -3.276 -3.750 -4.624 J092 -0.33258E+01 0.12061 E-01-0.92210E-04 0.29227E-06-0.44997E-09 6.583
chalcedony= 1.0 Si02 (aq) -3.700 -3.317 -2.827 -2.495 -2.235 -2.021 -1.845 -1.725 J092 -0.44039E+01 0.32381 E-01-0.23922E-03 0.88041 E-06-0.11472E-08 2.648
chalcoci + 2.0 H+ = 2.0 Cu+ + 1.0 H2S (aq) -27.714-25.193-21.004-17.724-15.046-12.816-10.938 -9.367 J092 -0 .30596E+02 0. 12306E+00-0 .32819 E-03 0 .61458E-06-0 .53236E-09 5. 791
chalcopy + 0.5 H2 (aq) + 3.0 H+ = 1.0 Cu+ + 1.0 Fe+2 + 2.0 H2S (aq) -14.241 -13.001 -10.869 -9.108 -7.646 -6.433 -5.451 -4.728 J092 -0.15619E+02 0.58133E-01-0.12544E-03 0.21410E-06-0.21778E-09 4.284
chrysoti + 6.0 H+ = 3.0 Mg+2 + 2.0 Si02 (aq) + 5.0 H20 31.586 28.548 23.582 19.824 16.887 14.475 12.340 10.174 BM88 0.35064E+02-0.14859E+00 0.39227E-03-0.55982E-06 0.20435E-09 2.554
claudeti + 3.0 H20 = 2.0 H3As03 (aq) -1.320 -0.940 -0.260 0.320 0.880 1.380 1.860 RS91 -0.17428E+01 0.17819E-01-0.39352E-04 0.10140E-06-0.11600E-09
clincl14 + 16.0 H+ = 5.0 Mg+2 + 2.0 Al+3 + 3.0 Si02 (aq) + 12.0 H20 58.564 51.166 39.162 29.987 22.662 16.483 10.875 5.174 BM88 0.67028E+02-0.36285E+00 0.99695E-03-0.16317E-05 0.86505E-09 2.6
chamosit + 16.0 H+ = 5.0 Fe+2 + 2.0 Al+3 + 3.0 Si02 (aq) + 12.0 H20 48.614 42.021 31.199 22.817 16.038 10.237 4.896 -0.632 SS93 0.56113E+02 0.32032E+00 0.83684E-03-0.12996E-05 0.57186E-09 3.343
clinozoi + 13.0 H+ = 2.0 ca+2 + 3.0 Al+3 + 3.0 Si02 (aq) + 7.0 H20 38.649 32.981 23.478 15.950 9.749 4.375 -0.599 -5.685 BM88 0.45044E+02-0.27148E+00 0.65033E-03-0.94548E-06 0.34415E-09 3.343
epid-ord + 12.0 H+ + 0.5 H2 (aq) = 1.0 Fe+2 + 2.0 Ca+2 + 2.0 Al+3 + 3.0 Si02 (aq) + 7.0 H20
46.311 40.669 31.215 23.741 17.613 12.338 7.497 2.552 J092 0.52668E+02-0 .26979E+00 0.64034E-03-0.89647E-06-0.2871 OE-09 3.471
coesite = 1.0 Si02 (aq) . -3.345 -2.982 -2.525 -2.217 -1.977 -1.778 -1.615 -1.504 BM88 -0.37800E+01 0.19944E-01-0.97861 E-04 0.27613E-06-0.30371 E-09 3.010
cord-hyd + 16.0 H+ = 2.0 Mg+2 + 4.0 Al+3 + 5.0 Si02 (aq) + 9.0 H20 47.339 39.442 26.136 15.618 7.016 -0.368 -7.121 -13.923 J092 0 .56260E+02-0 .37809E+00 0.88954E-03-0.12318E-05 0.39948E-09 2.500
cord-anh + 16.0 H+ = 2.0 Mg+2 + 4.0 Al+3 + 5.0 Si02 (aq) + 8.0 H20 45.054 37.243 24.056 13.611 5.053 -2.308 -9.056-15.870 BM88 0.53870E+02-0.37340E+00 0.86982E-03-0.11884E-05 0.35677E-09 2.508
copper+ 1.0 H+ = 1.0 Cu+ + 0.5 H2 (aq) -10.304 -9.344 -7.724 -6.405 -5.305 -4.372 -3.571 -2.879 J092 -0.11375E+02 0.45422E-01-0.10566E-03 0.18085E-06-0.14747E-09 8.933
corundum + 6.0 H+ = 2.0 Al+3 + 3.0 H20 16.857 13.638 8.423 4.333 0.953 -1.988 -4.697 -7.363 0.20521 E+02-0.15746E+00 0.44271 E-03-0.84553E-06 0.61644E-09 3.987
covellit + 0.5 H2 (aq) + 1.0 H+ = 1.0 cu+ + 1.0 H2S (aq) -11.536-10.342 -8.357 -6.768 -5.465 -4.378 -3.465 -2.718 -0.12883E+02 0.57418E-01-0.14605E-03 0.27017E-06-0.24148E-09 4.682
cristo-a = 1.0 Si02 (aq) -3.556 -3.192 -2.734 -2.426 -2.185 -1.986 -1.823 -1.712 -0.39921 E+01 0.19997E-01-0.98181 E-04 0.27711 E-06-0.30487E-09 2.334
cristo-b = 1.0 Si02 (aq) -3.446 -3.102 -2.674 -2.389 -2.167 -1.983 -1.832 -1.732 -0.38601 E+01 0.19035E-01-0.95239E-04 0.27120E-06-0.29968E-09 2.194
diaspore + 3.0 H+ = 1.0 Al+3 + 2.0 H20 6.459 5.101-2.928 1.229 -0.175 -1.405 -2.551 -3.700 0.80038E+01-0.66501E-01 0.19185E-03 0.37278E-06 0.27016E-09 3.378
diopside + 4.0 H+ = 1.0 Ca+2 + 1.0 Mg+2 + 2.0 Si02 (aq) + 2.0 H20 21.462 19.539 16.253 13.680 11.623 9.905 8.367 6.779 0.23626E+02-0.91 079E-01 0.19159E-03-0.16209E-06-0.99252E-10 3.277
hedenber + 4.0 H+ = 1.0 Fe+2 + 1.0 Ca+2 + 2.0 Si02 (aQ) + 2.0 H20 19.776 17.999 14.929 12.498 10.537 8.884 1.388 5.826 0.21764E+02-0.83330E-01 0.16254E-03-0.1 0343E-06-0.14986E-09 3.634
dolomite + 2.0 H+ = 1.0 Ca+2 + 1.0 Mg+2 + 2.0 HC03-2.513 1.659 0.094 -1.349 -2.774 -4.297 -6.101 -8.466 0.33934E+01-0.36112E-01 0.28908E-04 0.57180E-07-0.34726E-09 2.865
dolo-ord + 2.0 H+ = 1.0 Ca+2 + 1.0 Mg+2 + 2.0 HC03-3.41 0 2.481 0.826 -0.659 -2.085 -3.559 -5.243 -7.608 0.43285E+01-0.37610E-01 0.12274E-04 0.18570E-06-0.55265E-09 2.866
dolo-dis + 2.0 H+ = 1.0 Ca+2 + 1.0 Mg+2 + 2.0 HC03-3.410 2.481 0.826 -0.660 -2.088 -3.564 -5.250 -7.619 0.43274E+01-0.37556E-01 0.12185E-04 0.18759"E-06-0.55514E-09 2.864
enargV2 + 0.5 H2 (aq) + 1.5 H20 + 1.5 H+ = 1.5 cu+ 2.0 H2S (aq) + 0.5 H3As03 (aq) -26.823 -24.346 -20.293 -16.951 -14.252 -12.141 -10.706 -0.29591 E+02 0.11867E+00-0.31933E-03 0.74925E-06-0.10132E-08
enst-cli + 2.0 H+ = 1.0 Mg+2 + 1.0 Si02 (aq) + 1.0 H20 11.629 10.456 8.484 6.957 5.748 4.748 3.866 2.981 0.12958E+02-0.56283E-01 0.13064E-03-0.14934E-06 0.80556E-11 3.210
enst-ort + 2.0 H+ = 1.0 Mg+2 + 1.0 Si02 (aq) + 1.0 H20 11.703 10.524 8.544 7.010 5.795 4.790 3.902 3.012 0.13039E+02-0.56577E-01 0.13179E-03-0.15251 E-06 0.11346E-1 0 3.210
enst-pro + 2.0 H+ = 1.0 Mg+2 + 1.0 Si02 (aq) + 1.0 H20 11.921 10.720 8.705 7.144 5.907 4.885 3.983 3.081 0.13281 E+02-0.57631 E-01 0.13462E-03-0.15731 E-06 0.14991 E-1 0 3.210
feldsp-k + 4.0 H+ = 1.0 K+ + 1.0 Al+3 + 3,0 Si02 (aq) + 2.0 H20
461
BM88
J092
BM88
BM88
BM88
BM88
J092
J092
BM88
BM88
SR89/J092
BM88
BM88
BM88
46:' ...
-0.781 -1.098 -1.989 -2.825 -3.554 -4.225 -4.920 -5.798 BM88 -0.48316E+00-0.91571 E-02-0.96363E-04 0.45735E-06-0.66094E-09 2.557
kfsp-dis + 4.0 H+ = 1.0 K+ + 1.0 Al+3 + 3.0 Si02 (aq) + 2.0 H20 -0.781 -1.098 -1.991 -2.833 -3.571 -4.255 -4.967 -5.863 BM88 -0.48316E+00 0.91571 E-02-0.96363E-04 0.45735E-06-0.66094E-09 2.557
fluorite = 1.0 Ca+2 + 2.0 F--9.841 -9.740 -9.789-10.071 -10.552-11.251 -12.266-14.008 J092 -0.101 09E+02 0.13879E-01-0.14859E-03 0.50107E-06-0.80181 E-09 3.181
forsteri + 4.0 H+ = 2.0 Mg+2 + 1.0 Si02 (aq) + 2.0 H20 28.292 25.448 20.834 17.310 14.525 12.225 10.214 8.265 BM88 0.31541 E+02-0.13921 E+OO 0.37939E-03-0.61435E-06 0.35412E-09 3.213
galena+ 2.0 H+ = 1.0 H2S (aq) + 1.0 Pb+2 -7.816 -6.990 -5.608 -4.496 -3.589 -2.849 -2.257 -1.830 J092 -0.87456E+01 0.39555E-01-0.98108E-04 0.18267E-06-0.18275E-09 7.598
gehlenit + 10.0 H+ = 2.0 Ca+2 + 2.0 AJ+3 + 1.0 Si02 (aq) + 5.0 H20 56.646 50.187 40.042 32.479 26.525 21.418 ~6.185 7.813 RS91 0.64122E+02-0.32296E+00 0.97628E-03-0.16271E-05 0.61990E-09 3.039
gibbsite + 3.0 H+ = 1.0 Al+3 + 3.0 H20 6.797 5.558 3.587 2.065 0.809 -0.302 J092 0.82545E+01-0.63311 E-01 0.21234E-03-0.51242E-06 0.51373E-09 2.441
graphite + 3.0 H20 = 1.0 HC03- + 1.0 H+ + 2.0 H2 (aq) -28.109-25.943-22.438-19.745-17.633-15.959-14.651 -13.739 J092 -0.30602E+02 0.10718E+00-0.31 020E-03 0.60954E-06-0.52700E-09 2.267
greenali + 6.0 H+ = 3.0 fe+2 + 2.0 Si02 (aq) + 5.0 H20 27.341 24.759 20.916 18.358 16.602 15.242 13.742 10.432 RS91 0 .30406E+02-0 .13372E+00 0.45214E-03-0.64 769E-06 0.30688E-1 0 3.23300
gruneri* + 14.0 H+ = 7.0 fe+2 + 8.0 Si02 (aq) + 8.0 H20 1613.2801487.1121284.5741129.5851007.216 908.020 825.678 755.462 RS91 0.17577E+04-0.62131 E+01 0.17832E-01-0.32962E-04 0.26740E-07 3.902
halite = 1.0 Na+ + 1.0 Cl-1.630 1.653 1.613 1.493 1.304 1.032 0.630 -0.103 J092 0.15369E+01 0.49564E-02-0.60541 E-0~ 0.22357E-06-0.36926E-09 2.163
hematite + 4.0 H+ 1.0 H2 (aq) = 2.0 fe+2 + 3.0 H20 29.727 26.824 22.126 18.469 15.495 12.970 10.709 8.483 J092 0.33015E+02-0.14108E+00 0.38418E-03-0.66983E-06 0.43366E-09 5.275
herzenbe + 2.0 H+ = 1.0 Sn+2 + 1.0 H2S (aq) -8.551 -7.745 -6.388 -5.296 -4.407 -3.687 -3.120 -2.721 J092 -0.94569E+01 0.38463E-01-0.92650E-04 0.16614E-06-0.16657E-09 5.160
huntite + 4.0 H+ = 1.0 Ca+2 + 3.0 Mg+2 + 4.0 HC03-1 0.755 8.317 4.101 0.489 -2.885 -6.466 -11.179 -20.777 RS91 0 .13346E+02-0 .1 0769E+00 0.14077E-03 0.25005E-06-0.14364E-08 2.873
illite+ 8.0 H+ = 0.6 K+ + 2.3 Al+3 + 3.5 Si02 (aq) + 5.0 H20 + 0.25 Mg+2 9.802 7.474 3.764 1.024 -1.146 -3.158 -5.723-11.458 RS91 0.12443E+02-0.11265E+00 0.27650E-03-0.10255E-06-0.80048E-09 2.770
jadeite + 4.0 H+ = 1.0 Na+ + 1.0 Al+3 + 2.0 Si02 (aq) + 2.0 H20 8.721 7.548 5.678 4.311 3.253 2.305 1.131 -1.476 0.10055E+02-0.56876E-01 0.13981 E-03-0.50181 E-07-0.38125E-09 3.347
kalsilit + 4.0 H+ = 1.0 K+ + 1.0 Al+3 + 1.0 Si02 (aq) + 2.0 H20 11.257 9.826 7.577 5.920 4.621 3.465 2.131 -0.503 0.12905E+02-0.70931 E-01 0.20165E-03-0.24221 E-06-0.13609E-09 2.641
kaolin it + 6.0 H+ = 2.0 Al+3 + 2.0 Si02 (aq) + 5.0 H20 3.469 1.774 -1.195 -3.594 -5.602 -7.388 -9.112-10.971 0.73582E+01-0.96437E-01 0.30680E-03-0.82769E-06 0.95828E-09 2.594
kerolite + 6.0 H+ = 3.0 Mg+2 + 1.0 Si02 (aq) + 7.0 H20 23.680 21.612 18.290 15.900 14.170 12.850 11.650 0.26057E+02-0.1 0151 E+OO 0.26426E-03-0.23549E-06-0.17050E-09
kyanite + 6.0 H+ = 2.0 Al+3 + 1.0 Si02 (aq) + 3.0 H20 11.998 9.292 4.773 1.174 -1.821 -4.446 -6.894 -9.369 0.15055E+02-0 .13009E+00 0.32275E-03-0.52596E-06 0.27 459E-09 3.145
laumonti + 8.0 H+ = 1.0 Ca+2 + 2.0 Al+3 + 4.0 Si02 (aq) + 8.0 H20 14.145 11.604 7.577 4.645 2.384 0.355 -2.164 -7.776 0.17042E+02-0.12381 E+OO 0.31390E-03-0.14988E-06-0.77360E-09 2.267
lime + 2.0 H+ = 1.0 Ca+2 + 1.0 H20 32.600 29.975 25.820 22.692 20.239 18.224 16.419 14.321 0.35646E+02-0.13165E+00 0.40512E-03-0.77827E-06 0.59515E-09 3.345
loelling + 6.0 H20 + 2.0 H+ = 1.0 fe+2 + 4.0 H2 (aQ) + 2.0 H3As03 (aq) -30.918 -28.664 -24.684 -21.124 -18.004 -15.262 -12.832 -0.33294E+02 0.98857E-01-0.14215E-03 0.18256E-06-0.16456E-09
magnesit + 1.0 H+ = 1.0 Mg+2 + 1.0 HC03-2.033 1.430 0.393 -0.498 -1.320 -2.140 -3.047 -4.281 0.26557E+01-0.25954E-01 0.31363E-04 0.41746E-07-0.23199E-09 3.009
magnetit + 1.0 H2 (aq) + 6.0 H+ = 3.0 fe+2 + 4.0 H20 39.988 35.902 29.309 24.194 20.050 16.546 13.425 10.373 0 .44623E+02-0 .19903E+00 0.54854E-03-0.96554E-06 0.641 02E-09 5.199
margarit + 14.0 H+ = 1.0 ca+2 + 4.0 A!+3 + 2.0.Si02 (aq) + 8.0 H20 42.169 35.417 24.891 17.117 10.984 5.553 -0.528-11.837 0.49978E+02-0.33743E+00 0.10134E-02-0.15025E-05 0.11045E-10 3.077
merwinit + 8.0 H+ = 3.0 ca+2 + 1.0 Mg+2 + 2.0 Si02 (aq) + 4.0 H20 68.243 62.306 52.863 45.776 40.231 35.599 31.150 24.837 0.75103E+02-0.29544E+00 0.86651 E-03-0.14414E-05 0.69342E-09 3.149
micr-max + 4.0 H+ = 1.0 K+ + 1.0 Al+3 + 3.0 Si02 (aq) + 2.0 H20 -0.781 -1.098 -1.989 -2.825 -3.554 -4.225 -4.920 -5.798 -0.74986E+00-0.13491 E-01-0.33514E-04 0.14328E-06-0.16471 E-09 2.560
rnonticel + 4.0 H+ = 1.0 ca+2 + 1.0 Mg+2 + 1.0 Si02 (aq) + 2.0 H20 29.751 27.022 22.689 19.445 16.906 14.711 12.675 9.551 0.32900E+02-0.13561E+00 0.39548E-03-0.63413E-06 0.24553E-09 3.040
muscovit + 10.0 H+ = 1.0 K+ + 3.0 Al+3 + 3.0 Si02 (aq) + 6.0 H20
463
RS91
RS91
BM88
RS91
BM88
RS91
RS91
SR89/J092
BM88
J092
RS91
RS91
BM88
RS91
10.423 7.499 2.393 -1.746 -5.220 -8.307-11.267-14.427 0.13693E+02-0.13702E+00 0.26801 E-03-0.24882E-06-0.15524E-09 2.831
paragoni + 10.0 H+ = 1.0 Na+ + 3.0 Al+3 + 3.0 Si02 (aq) + 6.0 H20 12.653 9.451 3.932 -0.490 -4.163 -7.394-10.463-13.717 0.16252E+02-0.15142E+00 0.31912E-03-0.34696E-06-0.79122E-10 2.884
nesqueho + 1.0 H+ = 1.0 Mg+2 + 1.0 HC03- + 3.0 H20 5.135 6.580 9.006 10.829 12.179 13.083 13.401 12.236 0 .34537E+01 0. 71735E-O 1-0.19771 E-03 0.40041 E-06-0.56639E-Q9 1.850
orpiment + 6.0 H20 = 3.0 H2S (aq) + 2.0 H3As03 (aq) -26.415-23.674-19.145-15.551 -12.629-10.233 -8.401 -0.29562E+02 0.13491 E+00-0.38327E-03 0.85713E-06-0.98271 E-09
pargas/2 + 11 .0 H+ = 0.5 Na+ + 1.0 Ca+2 + 2.0 Mg+2 + 1.5 Al+3 + 3.0 Si02 (aq) + 6.0 H20
49.715 43.845 34.142 26.587 20.480 15.283 10.575 6.819 0.56629E+02:0.29667E+00 0.89431 E-03-0.19446E-05 0.18546E-08 3.056
par/2Fe* + 11.0 H+ = 0.5 Na+ + 1.0 Ca+2 + 2.0 Fe+2 + 1.5 AJ+3 + 3.0 Si02 (aq) + 6.0 H20
46.897 41.296 32.415 25.796 20.596 16.105 11.331 3.063 0.53350E+02-0.27752E+00 0.79133E-03-0.11075E-05-0.94932E-11 3.437
pearcV5 + 3.2 H+ + 1.2 H20 = 1.6 Cu+ + 0.4 Na+ + 2.2 H2S (aq) + 1.6 Ag+ + 0.4 H3As03 (aq)
-26.415-23.674-19.145 -15.551 -12.629 -10.233 -8.401 -0.29562E+02 0.13491 E+00-0.38327E-03 0.85713E-06-0.98271 E-09
periclase + 2.0 H+ = 1.0 Mg+2 + 1.0 H20 21.477 19.437 16.228 13.828 11.946 10.377 8.898 6.925 0 .23844E+02-0.1 0238E+00 0.31650E-03-0.58576E-06 0.38270E-09 3.584
phlogopi + 10.0 H+ = 1.0 K+ + 3.0 Mg+2 + 1.0 Ai+3 + 3.0 Si02 (aq) + 6.0 H20 39.439 35.003 27.634 21.935 17.377 13.544 10.080 6.540 0.44479E+02-0.21437E+00 0.53039E-03-0.72153E-06 0.20369E-09 2.788
phlogo-F + 8.0 H+ = 1.0 K+ + 3.0 Mg+2 + 1.0 Ai+3 + 3.0 Si02 (aq) + 4.0 H20 + 2.0 F-1076.164 990.790 853.840 748.917 665.853 598.235 541.727 492.879 0.11739E+04-0.42036E+01 0.12079E-01-0.22397E-04 0.18054E-07
prehnite + 10.0 H+ = 2.0 Ca+2 + 2.0 At+3 + 3.0 .Si02 (aq) + 6.0 H20 30.920 26.841 19.928 14.443 9.940 6.051 2.450 -1.280 0.35510E+02-0.19404E+00 0.43707E-03-0.54201 E-06 0.54950E-10 2.939
pyrite + 1.0 H2 (aq) + 2.0 H+ = 1.0 Fe+2 + 2.0 H2S (aq) 0.860 0.940 1.160 1.380 1.580 1.740 1.820 1.770 0.76851 E+OO 0.31192E-02 0.10742E-04-0.25811 E-07-0.19618E-10 5.012
pyrope + 12.0 H+ = 3.0 Mg+2 + 2.0 At+3 + 3.0 Si02 (aq) + 6.0 H20 55.570 48.468 36.756 27.642 20.283 14.060 ·8.470 2.954 0.63639E+02-0.34429E+00 0.88743E-03-0.13946E-05 0.72663E-09 3.580
pyrophyl + 6.0 H+ = 2.0 Al+3 + 4.0 Si02 (aq) + 4.0 H20 -3.036 -4.132 -6.420 -8.409-10.120-11.674-13.223-15.008 -0.18714E+01-0.45169E-01-0.35594E-04 0.42078E-06-0.73388E-09 2.846
46-::
BM88
BM88
RS91
SR89/J092
J092
RS91
SR89/J092
RS91
BM88
J092
BM88
J092
BM88
BM88
px.Ca-AI + 8.0 H+ = 1.0 Ca+2 + 2.0 Al+3 + 1.0 Si02 (aq) + 4.0 H20 31.519 27.121 19.905 14.243 9.600 5.605 1.963 -1.640 0.36508E+02-0.21338E+00 0.56456E-03-0.97184E-06 0.60288E-09 3.435
proust/2 + 1.5 H20 + 1.5 H+ = 0.5 fe+2 + 1.5 H2S (aq) + 1.5 Ag+ + 0.5 H3As03 (aq) -28.993-26.227-21.693-18.131 -15.260-12.952-11.151 -0.32158E+02 0.13576E+00-0.38212E-03 0.79808E-06-0.84918E-09
pyrrhoti + 2.0 H+ = 1.0 Fe+2 + 1.0 H2S (aQ) 3.290 2.886 2.308 1.909 1.587 1.316 1.053 0.746 0.37625E+01-0.20985E-01 0.80699E-04-0.17757E-06 0.13711 E-09 4.830
quartz = 1.0 Si02 (aq) -3.985-3.580-3.057-2.698 -2.417-2.186-1.995 -1.862 -0.44678E+01 0.2201 OE-01-0.1 0404E-03 0.28850E-06-0.31483E-09 2.648
quartz-beta = 1.0 Si02 (aq) -3.761 -3.385 -2.906 -2.582 -2.329 -2.120 -1.948 -1.830 -0.42116E+01 0.20611 E-01-0.99825E-04 0.27984E-06-0.30678E-09 2.648
realgar+ 12.0 H20 = 4.0 H2S (aq) + 2.0 H2 (aq) + 4.0 H3As03 (aq) -61.213 -55.383 -45.770 -37.707 -31.076 -25.679 -21.491 -0.67637E+02 0.27408E+00-0.67348E-03 0.14314E-05-0.17439E-08
sanidine + 4.0 H+ = 1.0 K+ + 1.0 Al+3 + 3.0 Si02 (aq) + 2.0 H20 0.378 -0.089 -1.220 -2.240 -3.113 -3.901 -4.693 -5.652 0.84792E+00-0.16567E-01-0.74784E-04 0.41669E-06-0.62705E-09 2.553
sepiolit + 8.0 H+ = 4.0 Mg+2 + 6.0 Si02 (aq) + 11.0 H20 31.002 28.445 24.374 21.487 19.368 17.580 15.425 10.478 0 .33928E+02-0 .12468E+00 0.30588E-03-0.54113E-07 -0.88476E-09 2.268
siderite + 1.0 H+ = 1.0 Fe+2 + 1.0 HC03--0.077 -0.549 -1.396 -2.159 -2.894 -3.654 -4.520 -5.730 0.38895E+00-0.19033E-01 0.49188E-05 0.97641E-07-0.28275E-09 3.944
amorphous silica= 1.0 Si02 (aq) -2.658 -2.420 -2.128 -1.927 -1.771 -1.649 -1.564 -1.536 -0.29391 E+01 0.12953E-01-0.64386E-04 0.18711 E-06-0.21772E-09 2.072
Silliman + 6.0 H+ = 2.0 Al+3 + 1.0 Si02 (aq) + 3.0 H20 12.742 9.923 5.225 1.490 -1.612 -4.322 -6.839 -9.371 0.15928E+02-0.13566E+00 0.33917E-03-0.55693E-06 0.30072E-09 3.145
silver+ 1.0 H+ = 0.5 H2 (aq) + 1.0 Ag+ -15.068 -13.650-11.313 -9.458 -7.943 -6.678 -5.602 -4.671 -0.16667E+02 0.68295E-01-0.17643E-03 0.31650E-06-0.25759E-0910.501
smithson + 1.0 H+ = 1.0 zn+2 + 1.0 HC03-0.582 0.137 -0.663 -1.386 -2.087 -2.818 -3.662 -4.852 0.10197E+01-0.17856E-01 0.33144E-05 0.98159E-07-0.28212E-09 4.434
sphaleri + 2.0 H+ = 1.0 zn+2 + 1.0 H2S (aq) -4.397 -4.213 -3.836 -3.480 -3.167 -2.909 -2.723 -2.643 -0.45849E+01 0.73865E-02 0.32895E-05-0.22839E-07-0.44273E-11 4.089
spinel + 8.0 H+ = 1.0 Mg+2 + 2.0 Al+3 + 4.0 H20 33.893 28.950 21.006 14.855 9.846 5.561 1.687 -2.074
46.1:\
BM88
SR89/J092
J092
BM88
BM88
SR89/J092
BM88
RS91
J092
J092
BM88
J092
J092
J092
BM88
0.39539E+02-0.24307E+00 0.69975E-03-0.13279E-05 0.97852E-09 3.583
sylvite = 1.0 K+ + 1.0 Cl-0.892 1.098 1.322 1.375 1.299 1.105 0.759 0.075 0.57933E+00 0.14645E-01-0.97338E-04 0.29544E-06-0.42457E-09 1.987
talc+ 6.0 H+ = 3.0 Mg+2 + 4.0 Si02 (aq) + 4.0 H20 22.423 20.168 16.177 13.052 10.589 8.554 6.716 4.732 0.24954E+02-0.1 0509E+00 0.17535E-03 0.44035E-07-0.45389E-09 2.784
minneso* + 6.0 H+ = 3.0 Fe+2 + 4.0 Si02 (aq) + 4.0 H20 798.663 736.378 636.391 559.887 499.505 450.586 410.018 375.489 0.86995E+03-0.30675E+01 0.88064E-02-0.16280E-04 0.13225E-07 3.205
tennan/5 + 0.2 H2 (aq) + 2.4 H20 + 2.4 H+ = 2.4 Cu+ + 0.8 K+ + 2.6 H2S (aq) + 0.8 H3As03 (aq)
-45.096 -41.042 -34.399 -28.976 -24.587 -21.109 -18.596 -0 .49644E+02 0.19485E+00-0.52324E-03 0.11692E-05-0.14677E-08
tin_native + 2.0 H+ = 1.0 Sn+2 + 1.0 H2 (aq) 1.781 1.618 1.433 1.357 1.331 1.296 1.214 1.104 0.20133E+01-0.10796E-01 0.65708E-04-0.17483E-06 0.15427E-09 7.300
topaz-F + 4.0 H+ = 2.0 Al+3 + 1.0 Si02 (aq) + 2.0 H20 + 2.0 F--20.634 -21.419 -23.031 -24.592 -26.135 -27.723 -29.437 -31.408 -0.19837E+02-0.31420E-01-0.14146E-04 0.12349E-06-0.27570E-09 3.484
tremolit + 14.0 H+ = 2.0 Ca+2 + 5.0 Mg+2 + 8.0 Si02 (aq) + 8.0 H20 63.879 57.974 48.248 41.193 36.059 32.164 28.897 25.420 0.70703E+02-0.28996E+00 0.72499E-03-0.64010E-06-0.34423E-09 2.977
actinol* + 14.0 H+ = 2.0 ca+2 + 5.0 Fe+2 + 8.0 Si02 (aq) + 8.0 H20 47.036 42.165 34.152 28.092 23.325 19.158 14.495 5.542 0.52512E+02-0.23170E+00 0.50612E-03-0.11180E-06-0.13627E-08 3.430
wairakit + 8.0 H+ = 1.0 ca+2 + 2.0 Al+3 + 4.0 Si02 (aq) + 6.0 H20 16.884 13.775 8.288 3.868 0.235 -2.896 -5.795 -8.821 0.20354E+02-0.14463E+00 0.25694E-03-0.12058E-06-0.32403E-09 2.328
wollasto + 2.0 H+ = 1.0 Ca+2 + 1.0 Si02 (aq) + 1.0 H20 13.617 12.552 10.733 9.299 8.147 7.182 6.323 5.449 0.14812E+02-0.50290E-01 0.1 0529E-0~-0.94479E-07-0.40518E-1 0 2.909
wurtzite + 2.0 H+ = 1.0 zn+2 + 1.0 H2S (aq) . -2.098 -2.092 -2.001 -1.865 -1.724 -1.606 -1.536 -1.553 -0.20819E+01-0.13850E-02 0.28427E-04-0.69370E-07 0.33744E-10 4.086
zoisite + 13.0 H+ = 2.0 Ca+2 + 3.0 Al+3 + 3.0 Si02 (aq) + 7.0 H20 39.057 33.315 23.694 16.076 9.804 4.371 -0.650 -5.776 0.45537E+02-0.27515E+00 0.66127E-03-0.96708E-06 0.36320E-09 3.343
46f
J092
BM88
J092
SR89/J092
J092
RS91
BM88
RS91
J092
BM88
J092
BM88
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y S
tage C
od
e
il34S ()180
FE
DE
RA
L·BA
SS
ET
T F
AU
LT
110977 5
03
07
(i) 504m
65500
1700 m
assive asp±w
olf with qtz vein (in brecciated hostrock-not sam
plec 0/S
R
110978 5
03
09
(i) 496m
66840
1760 qtz-po-asp m
ineralisation in vein I
0/S
-S
R, Fl
po qz
110979 5
03
09
(ii) 499.7m
66840
1760 qtz-po-asp breccia (asp late)
0/S
-S
R, F
l
110980 50309 (iii) 502m
66840
1760 replaem
ent by po-talc disseminations in brecciated dolom
ite s
R
110981 5
03
09
(iv) 504.5m
66840 1760
replacement by po-talc dissem
inated mineralisation in host sedim
er S
R
110982 5
03
10
(i) 807.5m
66390
1440 asp-cpy-qtz (w
olf?) mineralisation
0/S
-S
R,FI
po qz
110983 5
03
10
(ii) 808.2m
66390
1440 po-qtz-asp m
ineralisation s
R, Fl
110984 5
03
10
(iii) 810.5m
66390 1440
qtz-asp-cpy vein 0
/S
R, Fl
110985 5
03
10
(iv) 818.5m
66390 1440
asp with carb-asp-py vein
S-B
M
R
110986 50310 (v)
819.5m
66390 1440
asp-py-carb breccia B
M
R
po
110987 5
03
42
(i) 1052.5m
65780
1220 asp-chl-flu-cpy m
ineralisation s
R, Fl
po
,py,cp
y
110988 5
03
42
(ii) 1055.5m
•
65780 1220
asp-qtz-wolf breccia
0/S
R
110989 5
03
42
(iii) 1057m
65780
1220 sph-gal-py-carb m
ineralisation B
M
R
110990 5
03
42
(iv) 1051.5m
65780
1220 asp-qtz breccia w
ith main alteration
0/S
R
, Fl qz
110991 5
03
42
(v) 1062m
65780
1220 qtz-fels porphyry granite
Granite
R
110992 50342A
? (i) 1051.5m
65780
1220 qtz-asp-po vein w
ith meln thru silicified &
deformed hostrocks
s R
110993 50342A
? (ii) 1056.6m
65780
1220 asp-po-cpy breccia of hostrock w
ith meln
s R
110994 50342A
? (iii) 1061m
65780
1220 qtz-fels porphyry granite
Granite
R, F
l qz
110995 5
03
66
(i) 31m
66120
2280 dissem
po-hostrock mineralisation cut by py veins
s R
po
110996 5
03
66
(ii) 31.8m
66120
2280 asp-qz-po m
ineralisation cut by py veining 0
/S-S
R
po
110997 5
03
66
(iii) 38.2m
66120 2280
asp-qtz mineralisation cut by po-cpy
0/S
-S
R
110998 5
03
66
(iv) 41.2m
66120 2280
late stage carb-sph-gal-py vein B
M
R
110999 5
03
66
(v) 44.5m
66120
2280 dolom
ite cut by po-py-gal veins S
-BM
R
111000 50371 (i)
310.2m
67070 1810
po-py-qz vein s
R
po
,py
111001 50371 (ii)
310.7m
67070 1810
massive po cut by py-flu-carb vein
S-V
/C
R, Fl
111002 50371 (iii)
314m
67070 1810
hydrothermal sidlcarb w
ith po replaced by py s
R
111003 50381
(i) 387.2m
66780
1820 hostrock breccia w
ith qz-po-py s
R, Fl
po
111004 50381 (ii)
389.6m
66780 1820
qz vein cut po-qz-asp s
R, Fl
111005 50381 (iii) 399.3m
66780
1820 m
assive cass-po-py mineralisation in vein
s R
111006 50381 (iv) 400.5m
66780
1820 cass-po-trem
mineralisation
0/S
-S
R, Fl
111007 5
03
82
(i) 119.9m
66810
2090 late stage sph-carb-py vein in brecciated &
silicified host B
M
R
py
~
~
No
rthin
g
111008 S
03
85
(i) 809.5m
66940
111009 S
03
85
(ii) 813.0m
66940
111010 S
03
85
(iii) 813.2m
6
69
40
111011 S
0391 (i)
931.3m
65
58
0
111012 S
0391 (ii) 933m
65580
111013 S
0391 (iii) 942.3m
6
55
80
111014 S
0391 (iv) 946m
65580
111015 S
0391 (v) 948m
65580
111016 S
03
91
A (i)
935.5m
65580
111017 S
03
91
A (ii)
936.3m
65580
111018 S
07
63
(i) 892.5m
65800
111019 S
0763. (ii) 893.0m
6
58
00
111020 S
0763 (iii) 893. ?m
6
58
00
111021 S
07
63
(iv) 894.0m
65
80
0
111022 S
07
63
(v) 894.9m
6
58
00
111023 S
07
70
(i) 21.0m
6
55
60
111024 S
0781 (i) 35.6m
65700
111025 S
0781 (ii)
36. 7in
6
57
00
111026 S
0781 (iii) 39.0m
6
57
00
111027 S
0821 (i) 52.5m
6
59
80
111028 S
0821 (ii) 56.0m
6
59
80
111029 S
08
30
(i) 714m
6
65
60
111030 S
08
30
(ii) 719.0m
6
65
60
111031 S
08
30
(iii) 725.0m
6
65
60
111032 S
08
76
(i) 805. 7m
6
55
80
111033 S
08
76
(ii) 806.5m
6
55
80
111034 S
0876 (iii) 808.0m
6
55
80
111035 S
08
76
(iv) 809.0m
65
58
0
111036 S
08
76
(v) 814.0m
65580
111037 S
0876 (vi) 820.5m
65
58
0
111038 S
0876 (vii) 822.5m
65
58
0
111039 S
0896 (i) 863.0m
6
67
50
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
R.L.
Min
era
log
y S
tag
e
Co
de
1480 qz-po-asp veining w
ith p
y alteration 0
/S-S
R
1480 talc-po w
ith striations on fault surface s
R
1480 talc-po w
ith asp
-po
-cass vein
I 0
/S-S
R
1300 carb-asp w
ith late qz vein
BM
R
, Fl
1300 talc w
ith cass? + la
te qz-cpy-asp vein
0/S
R
1300 m
assive 7m zo
ne
flu-qz-trem w
ith late carb veins s
R, F
l
1300 flu-qz-chl-cpy
s R
, Fl
1300 asp-qz-w
olf cut by cp
y-chl vein la
ter cu
t by carb-qz vein 0
/S-B
M
R, F
l
1300 q
z-asp
-cass m
ineralisation with talc-cass-asp
0/S
R
1300 hornfels cu
t by late
stage carb-asp-sph-qz vein B
M?
R, F
l
1370 breccia w
ith ga
l-qz-ca
rb m
ineralisation B
M
R, Fl
1370 cass-qz-py re
pla
cem
en
t cut by rhod-qz vein 0
/S-B
M
R, F
l
1370 asp-qz-w
olf mineralisation w
ith po-cpy-meln overprint
0/S
-S
R, F
l
1370 asp-cpy-po m
ineralisation with m
eln vein s
R
1370 carb-asp vein w
ith meln overprint o
f po-flu S
-BM
R
, Fl
2230 po-asp-qz m
ineralisation with py alteration
s R
, Fl
2240 po-asp-qz-cpy m
ineralisation 0
/S-S
R
, Fl
22
40
asp-qz±
wolf m
ineralisation with po-cpy overprint
0/S
-S
R, F
l
22
40
po-qz co
nta
ct with qz-hornfels breccia w
ith assoc. py alteration s
R
22
40
po vein w
ith late asp
-carb
veining & p
y alteration S
-BM
R
22
40
sph-gal vein on m
arg
in o
f po-py breccia S
-BM
R
, Fl
1500 po-qz-asp-cpy m
ineralisation s
R, F
l
1500 sheared po-qz m
ineralsaition s
R
1500 qz-po-flu vein
S?
R, F
l
1440 po-flu m
ineralisation with carb-sph vein
s R
, Fl
1440 po-flu-asp-cpy m
ineralisation s
R, F
l
14
40
qz-cpy vein cut by late stage carb-gal vein
BM
R
1440 re
mn
an
t asp
-qz-w
olf po-cpy overpr. &
cut by carb-gal vein &
meln
0/S
-S-B
M R
, Fl
1440 asp-cass-qz-w
olf mineralisation cut by carb-qz vein
0/S
-V/C
R
, Fl
1440 qz-carb vein
VIC
R
, Fl
1440 trem
-po replacement &
qz vein s
R
1770 qz-asp-po m
ineralisation in brecciated dolostone host s
R
()34S
po
sph
py,cp
y
sph
ga
l
po
,cpy
py
po
po
py
po
,py
sph
po
,cpy
po
,sph
cpy
py
()18
0
qz
qz
qz
~
(J) '(
)
No
rthin
g
111040 S
0908 (i) 48.1 m
66220
111041 S
0918 (i) 687.5m
65360
111042 S
0918 (ii) 689.7m
65360
111043 S
0918 (iii) 698.8m
65360
111044 S
0918 (iv) 699.8m
65360
111045 S
0939 (i) 842.7m
66180
111046 S
0939 (ii) 842.5m
66180
111047 S
0939 (iii) 845.3m
66180
111048 S
0939 (iv) 847.5m
66180
111049 S
0952 (i) 746.0m
66720
111050 S
0952 (ii) 748.7m
66720
111051 S
0952A (i)
763.3m
66700
111052 S
0952A (ii)
769.3m
66700
111053 S
0952A (iii)
780. 7m .
66700
111054 S
12
n (i)
34.0m
66640
111055 S
1336 (i) 60.8m
65380
111056 S
1336 (ii) 64.0m
65380
111057 S
1400 (i) 117S
.7m
66800
111058 S
1400 (ii) 1174m
66800
111059 S
1400B (i)
1042.4m
66820
111060 S
1450A (i)
1068.5m
66670
111061 S
14
50
A (ii)
1085.7m
66670
111062 S
1450A (iii)
1086.8m
66670
111063 S
1450A (iv)
1096.0m
66670
111064 S
1450B (i)
1020.0m
66580
111065 S
14
50
B (ii)
1027.5m
66580
111066 S
1450B (iii)
1032.0m
66580
111067 S
1450C (i)
1037.2m
66700
111068 S
1450C (ii)
1039.8m
66700
111069 S
1450C (iii)
1044.0m
66700
111070 S
1454 (i) 1146.5m
67000
111071 S
14
54
A (i)
1063.0m
66970
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
R.L.
Min
era
log
y S
tag
e
2260 w
eathered gossanous silicified material
1480 asp-qz-w
olf mineralisation w
ith cpy-po overprint O
IS-S
1480 asp-qz breccia clasts in po-cpy m
ineralisation O
IS-S
1480 carb-qz vein cutting pyritised host
I V
IC
1480 lat stage sph-gal-carb-qz vein
BM
1400 qz-asp m
ineralisation cut by po-qz vein w
ith late cpy veinlets O
IS-S
1400 qz-asp-w
olf with po-cpy overprint
OIS
-S
1400 late stage carb-sph-gal vein w
ith py B
M
1400 py-po-qz m
ineralisation cut by la
te stage sph-gal-qz-carb vein
S-B
M
1550 qz-asp-w
olf with sheared m
assive po repl by po-qz-flu mineralisatio O
IS-S
1550 pyritised sedim
ent cut by late rhod vein V
IC
1480 po-qz co
nta
ct with talc-po replacem
ent s
1480 po-qz-asp w
ith flu-cpy mineralisation
s 1480
dolomite breccia w
ith flu-carb vein V
IC
2160 brecciated asp-py-qz m
ineralisation with late carb veins
s 2160
massive p
o w
ith qz veining s
2160 po-asp-qz breccia cut by late stage carb-sph m
in. & m
eln alteration S-B
M
1060 qz-asp-carb breccia
BM
1060 qz-po-asp-py vein
s 1220
massive po w
ith flow foliationtexture &
rotated clasts s
1160 po re
pla
cem
en
t of brecciated hostrock with asp-qz-py m
ineralisatio1S
1160 po-asp-py-qz vein
s 1160
po-qz-asp-flu-cpy mineralisation
s 1160
late stage qz-carb-gal-asp vein B
M
1280 replacem
ent front dol-sid-talc s
1280 replacem
ent front dol-sid-tremlpo
s 1280
hornfels with
po-qz & asp-qz-w
olf veins O
IS-S
1260 po-py replacem
ent of siliceous dolom
ite s
1260 po-qz cu
t by later qz-carb-po m
ineralisation &py alteration
s 1260
po-talc con
tact betw
een No.3 dolom
ite & R
RM
s
1120 po-cpy w
ith green flu-carb-qz veining S
-VIC
1250 po-qz repl. w
ith py altern & cut by carb-flu(green) vein
S-V
IC
Co
de
R
R, Fl
R, Fl
R,F
I
R, Fl
R, Fl
R, F
l
R,F
I
R, Fl
R, Fl
R, Fl
R, Fl
R, Fl
R, Fl
R
R. Fl R
R, Fl
R
R
R
R, Fl
R, Fl
R, Fl
R
R
R, Fl
R
R, Fl
R
R, Fl
R
()345
po
py
po
py,sp
h,cp
y
po
po
po
py, meln
po
po
,py
po
po
,py
po
,py,c
py
po
,py
()18
0
qz
qz*
qz
""' '.I -,
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y
111072 5
14
54
A (ii)
1063.5m
66970 1250
late stage colloform qz-carb vein &
py veining of sedim
ent
111073 5
14
54
8 (i)
1028.7m
66910 1320
sheared po-qz contact with dolom
ite
111074 5
14
54
C (i)
1001.5m
66910 1390
brecciated hostrock with po-qz-cpy m
ineralisation
111075 5
14
54
C (ii)
1002.0m
66910 1390
po-flu-qz with flow
foliation I
111076 5
14
55
8 (i)
790.9m
66800 1500
massive po-qz-cpy w
ith green flu-carb vein
111077 5
14
55
8 (ii)
791.?m
66800 1500
qz-asp-po-talc replacement
111078 5
14
64
(i) 672.3m
66960
1560 contact betw
een massive po-py and silicified dolom
ite
111079 5
14
64
(ii) 678.5m
66960
1560 replacem
ent front dol-po/host-po/talc
111080 5
14
64
(iii) 681.0m
66960 1560
massive po-qz m
ineralisation
111081 5
14
74
(i) 906.?m
66600
1340 po-talc-py m
ineralisation with qz-flu &
calc veins breccia
111082 U
0638 (i) 85.0m
65780
1920 m
assive po cut by carb-gal vein
111083 U
0638 (ii) 87.0m
65780
1920 m
assive po-asp cut by qz-carb vein w
ith py alteration.to meln
111084 U
0638 (iii) 89.0m
65780
1920 po-flu-carb m
ineralisation
111085 U
0638 (iv) 92.4m
65780 1920
massive po w
ith late carb-py-cpy vein
111086 U
0638 (v) 93.8m
65780
1920 carb-gal-sph vein w
ith colloform texture
111087 U
0638 (vi) 96.0m
65780 1920
gal-sph-cpy-carb vein
111088 U
0638 (vii) 97.9m
65780 1920
po-flu-cpy mineralisation
111089 U
0685 (i) 113.5m
66180
2060 po vein cutting dissem
asp-po
111090 U
0685 (ii) 125.8m
66180
2060 m
assive asp with py veining
111091 U
0741 (i) 49.7m
65640
1880 flu-po-carb vein
111092 U
0741 (ii) 57.0m
65640
1880 po-flu-qz m
ineralisation
111093 U
0741 (iii) n
.sm
65640
1880 py-po-cpy vein
111094 U
0741 (iv) 77.5m
65640 1880
po-cpy-flu vein
111095 U
0741 (v) 60.6m
65640
1880 cpy-sph-qz vein
111096 U
0748 (i) 23.8m
66460
1900 m
assive po(qz) mineralisation
111097 U
0748 (ii) 30.9m
66460
1900 po m
ineralisation with carb-asp veins &
py alteration
111098 U
0777 (i) 82.8m
66380
1920 po-qz replacem
ent of dolom
itic ho
st
111099 U
0777 (ii) 94.5m
66380
1920 silicified host w
ith po-cpy veinlets
111100 U
0777 (iii) 97.8m
66380
1920 po-qz m
ineralisation
1111 01 U
0777 (iv) 98.5m
66380 1920
po-cpy-py vein in silicified dolomitic breccia
111102 U
0777 (v) 105.0m
66380
1920 asp-cass-qz m
ineralisation
111103 U
0777 (vi) 106.0m
66380
1920 po-py m
ineralisation with qz-carb-cpy vein
Sta
ge
C
od
e
aa4s
V/C
R
, Fl
5 R
po
5 R
, Fl po
5 R
, Fl
5-V
/C
R, Fl
5 R
, Fl po
5 R
py
5 R
p
o
5 R
, Fl
5-V
/C
R
po
,py
5-8
M
R, Fl
po, sph, gal
5-8
M
R,P
T5
p
o,p
y,a
sp
5 R
, Fl po
5-8
M-V
/C R
, Fl
8M
R
, Fl gal
8M
R, Fl
5 R
, Fl
po
5 R
, PT
5
po
5 R
,PT
5
VIC
? R
, Fl
5 R
, PT
5
po
5 R
, PT
5
po, py
5 R
, Fl
8M
R,P
T5
5 R
,PT
5
5-8
M?
R
,PT
5
5 R
, Fl
5 R
,PT
5
5 R
, Fl po
5 R
, PT
5
py
0/5
R
, Fl asp
5-8
M
R, Fl
po
,py
()180
qz*
~
-..,J
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y S
tag
e
Co
de
()34S
()180
111104 U
0790 (i) 55.2m
6
65
40
1950
asp-qz-po mineralisation
0/S
A
,PT
S
po
111105 U
0790 (ii) 55.6m
6
65
40
1950
massive po w
ith replacement texture
s A
,PT
S
po
111106 U
0790 (iii) 47.2m
6
65
40
1950
trem-qz-po replacem
ent of dolomitic siltstone
I s
A,P
TS
111107 U
0797 (i) 114.2m
6
59
60
2100
massive po-py m
ineralisation with carb-sph veins
S-B
M
A, F
l p
o,sp
h
111108 U
0797 (ii) 116.0m
6
59
60
2100
qz with py-m
eln veining S
? A
,PT
S
111109 U
0797 (iii) 116.7m
6
59
60
2100
qz vein A
,PT
S
111110 U
0797 (iv) 119.2m
65
96
0
2100 py-bte-chl m
ineralisation s
A,P
TS
111111 U
0803 (i) 86.6m
6
63
20
2090
qz-po mineralisation w
ith late carb veinlets s
A,P
TS
111112 U
0803 (ii) 92.6m
6
63
20
2090
po-qz mineralisation
s A
, Fl p
o
111113 U
0803 (iii) 93.0m
6
63
20
2090
asp-po-py mineralisation w
ith late carb vein lets s
A, P
TS
po, asp
111114 U
0809 (i) 98.0m
6
59
60
2000
po-flu mineralisation w
ith py on fractures s
A, F
l po
111115 U
0809 (ii) 99.5m
6
59
60
2000
po-qz mineralisation w
ith py on fractures s
A, F
l po
111116 U
0809 (iii) 105.3m
6
59
60
2000
massive po-cpy w
ith late asp-carb veining S
-BM
A
, Fl po
111117 .
2010 po-flu m
ineralisation with late carb-qz-cpy vein
S-B
M
A, Fl
U0817 (i)
99.8m
65
73
0
po
111118 U
0817 (ii) 101.1m
6
57
30
2010
po-qz-asp-py mineralisation cut by carb-sph-qz vein
S-B
M
A, Fl
po
,py
111119 U
0817 (iii) 104.1m
6
57
30
2010
po-qz vein S
? A
, Fl
qz
111120 U
0817 (iv) 107.2m
6
57
30
2010
po-qz mineralisation w
ith qz-sph-carb veining S
-BM
A
, Fl
po
111121 U
0825 (i) 64.1m
6
56
90
1800
trem-po-py replacem
ent mineralisation
s A
,PT
S
111122 U
0825 (ii) 70.0m
6
56
90
1800
late stage qz-carb vein breccia in massive po-asp
VIC
A,P
TS
p
o,a
sp
111123 U
0825 (iii) 72.5m
6
56
90
1800
massive po(cpy-w
olf) mineralisation
s A
,PT
S
po
111124 U
0825 (iv) n.5
m
65
69
0
1800 qz-asp-po-cpy m
ineralisation 0
/S-S
A
,FI
po
111125 U
0825 (v) 79.5m
6
56
90
1800
asp-qz-po-cpy breccia mineralisation
0/S
-S
A, F
l
111126 U
0833 (i) 194.5m
6
63
60
1710
carb-mag m
ineralisation 0
/S
A,P
TS
111127 U
0833 (ii) 196.0m
6
63
60
1710
asp-cass-qz-py mineralisation
0/S
A
, PT
S
asp
111128 U
0833 (iii) 200.0m
6
63
60
1710
po-trem replacem
ent mineralisation
s A
,PT
S
111129 U
0844 (i) 211.8m
6
64
70
1680
asp-po-cpy-qz mineralisation
0/S
-S
A,P
TS
111130 U
0844 (ii) 215.3m
6
64
70
1680
po-qz mineralisation cu
t by qz vein s
A, Fl
po
111131 U
0844 (iii) 220.4m
6
64
70
1680
po-trem m
ineralisation s
A,P
TS
111132 U
0844 (iv) 233. 7m
66
47
0
1680 po-qz m
ineralisation with py deform
ation evident s
A,P
TS
111133 U
0844 (v) 235.0m
6
64
70
1680
po-qz-py mineralisation
s A
, Fl p
o,p
y
111134 U
0862 (i) 61.8m
6
61
00
1890
sheared asp-qz vein B
M?
A,P
TS
111135 U
0862 (ii) 65.0m
6
61
00
1890
asp-qz-po vein 0
/S-S
A
,FI
po
-"" -J
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y
111136 U
0862 (iii) 68.0m
66100
1890 po-py vein
111137 U
0862 (iv) 78.8m
66100 1890
massive po w
ith qz crystals
111138 U
0862 (v) 79.7m
66100
1890 m
assive trem-po m
inealisation
111139 U
0870 (i) 117.1m
65480
2020 m
assive po-trem replacem
ent I
111140 U
0870 (ii) 118.0m
65480
2020 m
assive po-qz crystals
111141 U
0892 (i) n.om
66500
2000 sheared po-py-qz
111142 U
0892 (ii) 84.3m
66500
2000 carb-sph-py m
ineralisation
111143 U
0936 (i) 12.0m
66180
1810 m
assive po-qz-flu veining in hostrock
111144 U
0936 (ii) 20.4m
66180
181 0 asp-py-carb m
ineralisation
111145 U
0936 (iii) 26.5m
66180
1810 po-py m
inealisation
111146 U
0936 (iv) 28.5m
66180 1810
py-asp mineralisation
111147 U
0936 (v) 33.0m
66180
1810 sheared py-asp-flu m
ineralisation with py-carb alteration
111148 U
0938 (i) 51.5m
66180
1870 po-py m
ineralisation in hostrock breccia
111149 U
0938 (ii) 66.2m
66180
1870 po-asp-py m
ineralisation with carb-flu veining
111150 U
0938 (iii) 68.2m
66180 1870
po-cpy mineralisation
111151 U
0938 (iv) 69.8m
66180 1870
trem-po replacem
ent mineralisation
111152 U
0938 (v) 81.0m
66180
1870 fibrous vein (trem
?)
111153 u
o9
43
(i) 44.5m
65350
2060 po-flu-py m
ineralisation in brecciated replacement hostrock
111154 U
0943 (ii) 53.2m
65350
2060 qz vein w
ith po-cpy veinlets
111155 U
0968 (i) 132.1m
66140
1680 qz-py m
ineralisation in sheared hostrock
111156 U
0968 (ii) 134.3m
66140
1680 asp-qz ±
po mineralisation
111157 U
0968 (iii) 145.0m
66140
1680 py-flu-po veinlets in hostrock
111158 U
0968 (iv) 145.3m
66140
1680 asp-po-flu-py veined breccia
111159 U
0968 (v) 155.0m
66140
1680 po-qz m
ineralisation
111160 U
0978 (i) 97.8m
65760
1710 m
assive cass with late qz-flu vein
111161 U
0978 (ii) 99.1 m
65760
1710 po-flu-py m
ineralisation with m
eln alteration & hem
111162 U
0978 (iii) 102.8m
65760
1710 flu-cpy-po m
ineralisation with py alteration
111163 U
0978 (iv) 106.8m
65760
1710 flu-po-cpy m
ineralisation with py alteration
111164 U
0978 (v) 113.0m
65760
1710 flu-po-cpy m
ineralisation
111165 U
1006 (i) 114.6m
66720
1980 carb-gal in brecciated host
111166 U
1006 (ii) 115.5m
66720
1980 po-py vein in silicified hostrock
111167 U
1006 (iii) 114.9m
66720
1980 po m
ineralisation with carb veinlets associate w
ith py alteration
Sta
ge
s s s s s s BM
s BM
s s s s S
-V/C
s s s s s S
?
0/S
s s s 0/S
s s s s BM
s s
Co
de
()3
45
A, PT
S
po, py
A, Fl po
A,P
TS
A,P
TS
po
A, Fl
po
A,P
TS
p
o,p
y
A, Fl py, sph
A, Fl
po
A, P
TS
asp
A, P
TS
po, py
A, P
TS
py
A, Fl
py
A,P
TS
po
A, P
TS
po
A, PT
S
po, py
A,P
TS
p
o,p
y
A,P
TS
A. Fl
po
A, P
TS
po
A,P
TS
A, Fl asp
A, Fl
py
A, Fl
po
A, Fl
po
A, F
l
A, Fl p
o,p
y
A, Fl
A, Fl
po
A, Fl po
A,P
TS
A,P
TS
A, P
TS
po
()18
0
qz
~
o...,J (,J
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y
111168 U
1012 (i) 103.0m
6
52
60
1
76
0
po-flu-cpy vein
111169 U
10
12
(ii) 108.0m
6
52
60
1
76
0
asp-qz-po-cpy-wolf m
ineralisation with
py alteration
111170 U
1012 (iii) 113.5m
6
52
60
1
76
0
gal-carb-qz-sph vein
111171 U
10
12
(iv) 114.0m
65
26
0
17
60
carb-sph-py-qz vein
111172 U
10
12
(v) 119.9m
6
52
60
1
76
0
tremolite alteration w
ith disseminated po
111173 U
10
23
(i) 40.0m
6
54
40
1
98
0
po-asp mineralisation w
ith carb-py-flu veining
111174 U
10
23
(ii) 40.8m
6
54
40
1
98
0
po-py-cpy mineralisation w
ith carb-flu-qz vein
111175 U
1023 (iii) 41.0m
6
54
40
1
98
0
asp-po-cpy mineralisation w
ith qz-ca
rb vein
111176 U
1023 (iv) 58.0m
65
44
0
19
80
po-asp-qz m
ineralisation with flu-carb vein
111177 U
10
28
(i) 55.6m
6
53
80
1
92
0
po-qz mineralisation w
ith late qz-carb vein
111178 U
1 02
8 (ii)
62.3m
65
38
0
19
20
asp-po m
ineralisation with carb veining &
py alteration
111179 U
10
28
(iii) 66.5m
6
53
80
1
92
0
cass-asp-po mineralisation
111180 U
10
36
(i) 29.5m
6
62
70
1
80
0
green flu-qz-carb mineralisation
111181 U
10
36
(ii) 36.1m
6
62
70
1
80
0
po-qz-cpy mineralisation
111182 U
10
36
(iii) 47.0m
6
62
70
1
80
0
po-qz-py mineralisation
111183 U
10
36
(iv) 47.8m
66
27
0
18
00
py-carb-qz vein
111184 U
10
45
(i) 52.6m
6
53
60
1
84
0
po-flu-qz-asp mineralisation
111185 u
1o
45
(ii) 61.om
6
53
60
1
84
0
po-py-qz mineralisation
111186 U
10
45
(iii) 65.5m
6
53
60
1
84
0
dissem po-talc replacem
ent mineralisation
111187 U
10
45
(iv) 68.2m
65
36
0
18
40
dissem
po-talc replacement m
ineralisation
111188 U
10
92
(i) 39.0m
6
63
60
1
80
0
brecciated an
d veined h
ostro
ck with green flu-py
111189 U
10
92
(ii) 43.5m
6
63
60
1
80
0
qz-asp mineralisation w
ith py altration
111190 U
10
92
(iii) 52.0m
6
63
60
1
80
0
massive p
o w
ith min
or carb-py vein
111191 U
11
07
(i) 29.6m
6
55
60
1
82
0
massive po-flu m
ineralisation
111192 U
11
07
(ii) 33.2m
6
55
60
1
82
0
po-asp-qz mineralisation
111193 U
1112 (i) 21.0m
6
60
60
1
70
0
po-asp-qz-wolf veining
111194 U
1112 (ii) 24.5m
6
60
60
1
70
0
vein containing qz w
ith radiating tou
r
111195 U
11
15
(i) 31.5m
6
60
60
1
73
0
po-asp-qz mineralisation w
ith py-carb-qz vein
111196 U
11
15
(ii) 32.5m
66060
17
30
asp-cass-qz vein , cut b
y late carb
-qz-p
y vein
111197 U
11
15
(iii) 38.7m
66060 1
73
0
po vein cut by carb-sph-qz vein w
ith py alteration
111198 U
11
15
(iv) 42.5m
66
06
0
17
30
asp-qz-w
olf vein cut by po-cpy-qz m
ineralisation
111199 U
11
18
(i) 32.0m
6
65
10
1
88
0
asp-cass-wolf-qz m
ineralisation
Sta
ge
s 0/S
-S
BM
I
BM
s S-V
/C
S-V
/C
S-V
/C
s S-V
/C
s 0/S
VIC
?
s s VIC
s s s s VIC
?
0/S
s s s 0/S
-S
0/S
?
S-V
/C
0/S
-V/C
S-B
M
0/S
-S
0/S
Co
de
o34S
A, F
l po
A, F
l a
sp,sp
h
A, F
l
A, F
l p
y,sph
A,P
TS
A, P
TS
po, py
A, F
l p
o,p
y
A, F
l p
o,a
sp
,cp
y
A, F
l
A, F
l po
A, P
TS
asp
A, F
l p
o,a
sp
A, F
l
A, F
l p
o
A, P
TS
p
o
A,P
TS
A, Fl
po
A, P
TS
po, py
A,P
TS
A,P
TS
A, F
l
A,P
TS
A, P
TS
po
A, F
l po x2
A, F
l
A, F
l p
o,sp
h
A,P
TS
A, F
l p
o,p
y
A, F
l p
o,p
y
A, P
TS
po, py
A, Fl
A,P
TS
a1so
~
-..J .fl.
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L
M
ine
ralo
gy
111200 U
1118 (ii) 37.0m
66510
1880 po-qz m
ineralisation
111201 U
1118 (iii) 42.0m
66510
1880 late py veinlets in siderite
111202 U
1160 (i) 40.0m
65780
1840 asp-cass-w
olf-qz mineralisation
111203 U
1160 (ii) 40.8m
65780
1840 po m
ineralisation cut by sph-qz-gal vein & py alteration
I 111204
U1
16
0(iii) 41.0m
65780
1840 po-qz m
ineralisation cut by flu-carb vein & py alteration
111205 U
1160 (iv) 43.0m
65780 1840
po-cpy-flu-qz-asp mineralisation
111206 U
1160 (v) 45.9m
65780
1840 po-qz-asp-cpy m
ineralisation
111207 U
1176 (i) 63.0m
65880
1720 cpy-carb-qz vein
111208 U
1176 (ii) 66.2m
65880
1720 contact po-asp-qz m
ineralisation with late stage carb-asp-qz vein
111209 U
1176 (iii) 71.0m
65880
1720 po-flu-py m
ineralisation
111210 U
1176 (iv) 71.6m
65880 1720
po-flu vein
111211 U
1186 (i) 103.5m
65790
1700 sph-carb-qz vein
111212 U
1186 (ii) 105.5m
65790
1700 flu-py-cpy-m
eln mineralisation
111213 U
1186 (iii) 107.4m
65790
1700 qz-carb-cpy-flu-asp vein w
ith meln alteration
111214 U
1186 (iv) 107.5m
65790
1700 flu-po-cpy m
ineralisation with carb vein
111215 U
1186 (v) 114.0m
65790
1700 po-flu-cpy-asp m
ineralisation
111216 U
1186 (vi) 117.0m
65790
1700 po-asp-flu-cpy m
ineralisation with sph-carb-qz veining
111217 U
1198 (i) 77.1m
65260
1940 brecciated hostrock w
ith po infill
111218 U
1214 (i) 102.0m
65640
1730 w
olf-asp-qz-cpy mineralisation
111219 U
1214 (ii) 102.1m
65640
1730 po-asp-cpy m
ineralisation
111220 U
1214 (iii) 102.5m
65640
1730 flu-po-asp-cpy m
ineralisation
111221 U
1214 (iv) 108.0m
65640
1730 po-flu-cpy-asp m
ineralisation
111222 U
12
14
(v) 113.5m
65640
1730 po-flu-qz-cpy m
ineralisation
111223 U
1214 (vi) 115.0m
65640
1730 po-flu-cpy m
ineralisation
111224 U
1214 (vii) 101.5m
65640 1730
qz minm
eralisation with po-cpy veinlets
111225 U
1226A (i)
74.7m
66240 1960
po vein cutting silicified po replacament zone
111226 U
1226A (ii)
77.1m
66240 1960
po-py-flu mineralisation w
ith flow foliation
111227 U
1226A (iii)
84.5m
66240 1960
po-talc with w
ell developed foliated replacement texture
111228 U
1240 (i) 35.5m
66590
1900 asp-po-cpy-qz m
ineralisation
111229 U
1240 (ii) 36.0m
66590
1900 qz-po-py m
ineralisation
111230 U
1240 (iii) 42.0m
66590
1900 py-carb-qz m
ineralisation
111231 U
1253 (i) 14.8m
65530
1870 qz-flu-rhod-gal vein
Sta
ge
C
od
e
Cl34S
s R
, Fl po
supergene R, P
TS
0/S
R
,PT
S
S-B
M
R, Fl
po
S-V
/C
R, Fl
s R
, Fl p
o,p
y
0/S
-S
R, P
TS
po
BM
R
, PT
S
cpy
S-B
M?
R, Fl
po
s R
, Fl
po
s R
, Fl
po
BM
R
, Fl sph
BM
R
, Fl cpy
BM
? R
, Fl
py
s R
, Fl
s R
, Fl
po
,cpy
S-B
M
R, Fl
po
,sph
s R
,PT
S
0/S
R
, Fl p
o,cp
y
s R
,PT
S
s R
, Fl
s R
, Fl
po
s R
, Fl
s R
, Fl po x2
0/S
-S?
R
, Fl
s R
, PT
S
po
s R
,PT
S
s R
,PT
S
0/S
-S
R, Fl
s R
, Fl po
VIC
R
, Fl po
BM
R
, Fl
()18
0
qz
~
'I
•n
AP
PE
ND
IX X
II-R
OC
K C
ATA
LOG
UE
No
rthin
g
R.L.
Min
era
log
y
111232 U
1253 (ii) 15.4m
6
55
30
1870
qz-po-py vein
111233 U
1253 (iii) 16.4m
65530
1870 sph-gal-qz vein w
ith rhod-py breccia vein
111234 U
1253 (iv) 24.8m
65530 1870
po-asp-talc replacement m
ineralisation
111235 U
1253 (v) 30.9m
65530
1870 gal-sph-carb colloform
vein with py
I 111236
U1267 (i)
56
.4m
6
66
10
1
94
0
asp-po bre
ccia w
ith carb veining
111237 U
12
67
(ii) 5
7.5
m
66
61
0
1940 po-qz-flu m
ineralisation
111238 U
12
67
(iii) 62.5m
6
66
10
1940
po-qz-siderite contact
111239 U
1267 (iv) 64.6m
66610 1940
disseminated po-dolom
ite con
tact
111240 U
1274 (i) 48.0m
6
65
70
1
87
0
dissem p
o re
pla
cem
en
t texture with carb-m
ag mineralisation
111241 U
1305 (i) 114.0m
6
59
40
1790
asp-po breccia in contact with hostrock
111242 U
1305 (ii) 123.5m
6
59
40
1790
dissem p
o-q
z replacement o
f tram-talc-asp m
ineralisation
111243 U
1343 (i) 102.7m
6
54
40
2110
dissem p
o replacem
ent of talc
111244 U
1361 (i) 106.1m
66020
2010 qz w
ith po
-asp
veinlets
111245 U
1361 (ii) 107.0m
. 66020
2010 asp-po w
ith py veinlets
111246 U
1361 (iii) 107.2m
66020
20
10
qz-asp m
ineralisation with p
o overprint
111247 U
13
77
(i) 70.0m
6
56
80
1820
gal-carb vein
111248 U
1377 (ii) 72.5m
6
56
80
1820
qz-a
sp-cp
y vein in po
111249 U
13
77
(iii) 7
7.5
in
65680 1820
wolf-qz-asp m
ineralisation in massive po-cpy-bism
ove
rprin
t
111250 U
13
77
(iv) 80
.2m
65680
1820 po-asp-cpy-flu m
ineralisation
111251 U
1390 (i) 69.0m
65490
1900 po-qz-asp m
ineralisation grading into dissem po-talc repl. texture
111252 U
1390 (ii) 6
9.9
m
65
49
0
19
00
flu-qz vein cutting dissem
po-talc replacement texture
111253 U
13
90
(iii) 78.0m
6
54
90
1900
dissem po-asp-talc-flu replacem
ent texture
111254 U
1408 (i) 63.8m
6
67
00
1930
po
-asp
brecciated by carb-py & late m
eln alteration
111255 U
1408 (ii) 67.0m
6
67
00
1930
po-py mineralisation replacing hostrock breccia
111256 U
1408 (iii) 76.0m
6
67
00
1930
po-sph-carb veinlet in silicified hostrock
111257 U
1414 (i) 206.2m
66650
1700 qz-po vein
111258 U
14
26
(i) 119.5m
66660
1800 qz vein cu
t by anastomosing po-py-cpy veinlets
111259 U
14
26
(ii) 120.4m
6
66
60
1
80
0
slate bre
ccia cu
t by carb-flu vein
111260 U
1522 (i) 8
8.0
m
66880 1840
dissem p
o-ta
lc replacement textures w
ith py vein
s
111261 U
1522 (ii) 89.5m
66880
1840 dissem
po
-asp
-qz m
ineralisation
111262 U
1522 (iii) 93.2m
6
68
80
1840
cass-talc-asp mineralisation
111263 U
1563 (i) 117.3m
66860
1920 R
BM
cut by carb-flu-sph vein
Sta
ge
s BM
s BM
s s s s 0/S
-S
0/S
s S.
0/S
s 0/S
-S
BM
0/S
-S
0/S
-S
s 0/S
-S
S·
0/S
-S
S-V
/C
s S-B
M
s s VIC
s s 0/S
BM
Co
de
d34S
R, F
l p
o
R, F
l sph, g
al
R,P
TS
R,P
TS
R,P
TS
R, F
l p
o
R,P
TS
R,P
TS
R,P
TS
R, P
TS
p
o
R,P
TS
R,P
TS
p
o
R, F
l p
o
R,P
TS
R, F
l p
o
R, F
l
R, F
l p
o,c
py
R, F
l p
o
R, F
l p
o
R, F
l p
o
R, F
l
R, F
l p
o
R,P
TS
p
ox2
R, F
l p
o
R, F
l p
o,sp
h
R,F
I p
o
R,P
TS
R,P
TS
R,P
TS
p
o x2, py
R, F
l
R, F
l
R,P
TS
d180
qz
qz
qz
""" '-.I n
Northing
111040 S0908 (i) 48.1 m 66220
111041 S0918 (i) 687.5m 65360
111042 S0918 (ii) 689.7m 65360
111043 S0918 (iii) 698.8m 65360
111044 S0918 (iv) 699.8m 65360
111045 S0939 (i) 842.7m 66180
111046 S0939 (ii) 842.5m 66180
111047 S0939 (iii) 845.3m 66180
111048 S0939 (iv) 847.5m 66180
111049 S0952 (i) 746.0m 66720
111050 S0952 (ii) 748.7m 66720
111051 S0952A (i) 763.3m 66700
111052 S0952A (ii) 769.3m 66700
111053 S0952A (iii) 780. 7m .
66700
111054 S12n (i) 34.0m 66640
111055 S1336 (i) 60.8m 65380
111056 S1336 (ii) 64.0m 65380
111057 S1400 (i) 117S.7m 66800
111058 S1400 (ii) 1174m 66800
111059 S1400B (i) 1042.4m 66820
111060 S1450A (i) 1068.5m 66670
111061 S1450A (ii) 1085.7m 66670
111062 S1450A (iii) 1086.8m 66670
111063 S1450A (iv) 1096.0m 66670
111064 S1450B (i) 1020.0m 66580
111065 S1450B (ii) 1027.5m 66580
111066 S1450B (iii) 1032.0m 66580
111067 S1450C (i) 1037.2m 66700
111068 S1450C (ii) 1039.8m 66700
111069 S1450C (iii) 1044.0m 66700
111070 S1454 (i) 1146.5m 67000
111071 S1454A (i) 1063.0m 66970
APPENDIX XII- ROCK CATALOGUE
R.L. Mineralogy Stage
2260 weathered gossanous silicified material
1480 asp-qz-wolf mineralisation with cpy-po overprint OIS-S
1480 asp-qz breccia clasts in po-cpy mineralisation OIS-S
1480 carb-qz vein cutting pyritised host I VIC
1480 lat stage sph-gal-carb-qz vein BM
1400 qz-asp mineralisation cut by po-qz vein with late cpy veinlets OIS-S
1400 qz-asp-wolf with po-cpy overprint OIS-S
1400 late stage carb-sph-gal vein with py BM
1400 py-po-qz mineralisation cut by late stage sph-gal-qz-carb vein S-BM
1550 qz-asp-wolf with sheared massive po repl by po-qz-flu mineralisatio OIS-S
1550 pyritised sediment cut by late rhod vein VIC
1480 po-qz contact with talc-po replacement s 1480 po-qz-asp with flu-cpy mineralisation s 1480 dolomite breccia with flu-carb vein VIC
2160 brecciated asp-py-qz mineralisation with late carb veins s 2160 massive po with qz veining s 2160 po-asp-qz breccia cut by late stage carb-sph min. & meln alteration S-BM
1060 qz-asp-carb breccia BM
1060 qz-po-asp-py vein s 1220 massive po with flow foliationtexture & rotated clasts s 1160 po replacement of brecciated hostrock with asp-qz-py mineralisatio1S
1160 po-asp-py-qz vein s 1160 po-qz-asp-flu-cpy mineralisation s 1160 late stage qz-carb-gal-asp vein BM
1280 replacement front dol-sid-talc s 1280 replacement front dol-sid-tremlpo s 1280 hornfels with po-qz & asp-qz-wolf veins OIS-S
1260 po-py replacement of siliceous dolomite s 1260 po-qz cut by later qz-carb-po mineralisation &py alteration s 1260 po-talc contact between No.3 dolomite & RRM s 1120 po-cpy with green flu-carb-qz veining S-VIC
1250 po-qz repl. with py altern & cut by carb-flu(green) vein S-VIC
Code
R
R, Fl
R, Fl
R,FI
R, Fl
R, Fl
R, Fl
R,FI
R, Fl
R, Fl
R, Fl
R, Fl
R, Fl
R, Fl
R
R. Fl
R
R, Fl
R
R
R
R, Fl
R, Fl
R, Fl
R
R
R, Fl
R
R, Fl
R
R, Fl
R
()345
po
py
po
py,sph,cpy
po
po
po
py, meln
po
po,py
po
po,py
po,py,cpy
po,py
()180
qz
qz*
qz
""' '.I -,
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy
111072 51454A (ii) 1063.5m 66970 1250 late stage colloform qz-carb vein & py veining of sediment
111073 514548 (i) 1028.7m 66910 1320 sheared po-qz contact with dolomite
111074 51454C (i) 1001.5m 66910 1390 brecciated hostrock with po-qz-cpy mineralisation
111075 51454C (ii) 1002.0m 66910 1390 po-flu-qz with flow foliation I 111076 514558 (i) 790.9m 66800 1500 massive po-qz-cpy with green flu-carb vein
111077 514558 (ii) 791.?m 66800 1500 qz-asp-po-talc replacement
111078 51464 (i) 672.3m 66960 1560 contact between massive po-py and silicified dolomite
111079 51464 (ii) 678.5m 66960 1560 replacement front dol-po/host-po/talc
111080 51464 (iii) 681.0m 66960 1560 massive po-qz mineralisation
111081 51474 (i) 906.?m 66600 1340 po-talc-py mineralisation with qz-flu & calc veins breccia
111082 U0638 (i) 85.0m 65780 1920 massive po cut by carb-gal vein
111083 U0638 (ii) 87.0m 65780 1920 massive po-asp cut by qz-carb vein with py alteration.to meln
111084 U0638 (iii) 89.0m 65780 1920 po-flu-carb mineralisation
111085 U0638 (iv) 92.4m 65780 1920 massive po with late carb-py-cpy vein
111086 U0638 (v) 93.8m 65780 1920 carb-gal-sph vein with colloform texture
111087 U0638 (vi) 96.0m 65780 1920 gal-sph-cpy-carb vein
111088 U0638 (vii) 97.9m 65780 1920 po-flu-cpy mineralisation
111089 U0685 (i) 113.5m 66180 2060 po vein cutting dissem asp-po
111090 U0685 (ii) 125.8m 66180 2060 massive asp with py veining
111091 U0741 (i) 49.7m 65640 1880 flu-po-carb vein
111092 U0741 (ii) 57.0m 65640 1880 po-flu-qz mineralisation
111093 U0741 (iii) n.sm 65640 1880 py-po-cpy vein
111094 U0741 (iv) 77.5m 65640 1880 po-cpy-flu vein
111095 U0741 (v) 60.6m 65640 1880 cpy-sph-qz vein
111096 U0748 (i) 23.8m 66460 1900 massive po(qz) mineralisation
111097 U0748 (ii) 30.9m 66460 1900 po mineralisation with carb-asp veins & py alteration
111098 U0777 (i) 82.8m 66380 1920 po-qz replacement of dolomitic host
111099 U0777 (ii) 94.5m 66380 1920 silicified host with po-cpy veinlets
111100 U0777 (iii) 97.8m 66380 1920 po-qz mineralisation
1111 01 U0777 (iv) 98.5m 66380 1920 po-cpy-py vein in silicified dolomitic breccia
111102 U0777 (v) 105.0m 66380 1920 asp-cass-qz mineralisation
111103 U0777 (vi) 106.0m 66380 1920 po-py mineralisation with qz-carb-cpy vein
Stage Code aa4s
V/C R, Fl
5 R po
5 R, Fl po
5 R, Fl
5-V/C R, Fl
5 R, Fl po
5 R py
5 R po
5 R, Fl
5-V/C R po,py
5-8M R, Fl po, sph, gal
5-8M R,PT5 po,py,asp
5 R, Fl po
5-8M-V/C R, Fl
8M R, Fl gal
8M R, Fl
5 R, Fl po
5 R, PT5 po
5 R,PT5
VIC? R, Fl
5 R, PT5 po
5 R, PT5 po, py
5 R, Fl
8M R,PT5
5 R,PT5
5-8M? R,PT5
5 R, Fl
5 R,PT5
5 R, Fl po
5 R, PT5 py
0/5 R, Fl asp
5-8M R, Fl po,py
()180
qz*
~ -..,J
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code ()34S ()180
111104 U0790 (i) 55.2m 66540 1950 asp-qz-po mineralisation 0/S A,PTS po
111105 U0790 (ii) 55.6m 66540 1950 massive po with replacement texture s A,PTS po
111106 U0790 (iii) 47.2m 66540 1950 trem-qz-po replacement of dolomitic siltstone I
s A,PTS
111107 U0797 (i) 114.2m 65960 2100 massive po-py mineralisation with carb-sph veins S-BM A, Fl po,sph
111108 U0797 (ii) 116.0m 65960 2100 qz with py-meln veining S? A,PTS
111109 U0797 (iii) 116.7m 65960 2100 qz vein A,PTS
111110 U0797 (iv) 119.2m 65960 2100 py-bte-chl mineralisation s A,PTS
111111 U0803 (i) 86.6m 66320 2090 qz-po mineralisation with late carb veinlets s A,PTS
111112 U0803 (ii) 92.6m 66320 2090 po-qz mineralisation s A, Fl po
111113 U0803 (iii) 93.0m 66320 2090 asp-po-py mineralisation with late carb vein lets s A, PTS po, asp
111114 U0809 (i) 98.0m 65960 2000 po-flu mineralisation with py on fractures s A, Fl po
111115 U0809 (ii) 99.5m 65960 2000 po-qz mineralisation with py on fractures s A, Fl po
111116 U0809 (iii) 105.3m 65960 2000 massive po-cpy with late asp-carb veining S-BM A, Fl po
111117 .
2010 po-flu mineralisation with late carb-qz-cpy vein S-BM A, Fl U0817 (i) 99.8m 65730 po
111118 U0817 (ii) 101.1m 65730 2010 po-qz-asp-py mineralisation cut by carb-sph-qz vein S-BM A, Fl po,py
111119 U0817 (iii) 104.1m 65730 2010 po-qz vein S? A, Fl qz
111120 U0817 (iv) 107.2m 65730 2010 po-qz mineralisation with qz-sph-carb veining S-BM A, Fl po
111121 U0825 (i) 64.1m 65690 1800 trem-po-py replacement mineralisation s A,PTS
111122 U0825 (ii) 70.0m 65690 1800 late stage qz-carb vein breccia in massive po-asp VIC A,PTS po,asp
111123 U0825 (iii) 72.5m 65690 1800 massive po(cpy-wolf) mineralisation s A,PTS po
111124 U0825 (iv) n.5m 65690 1800 qz-asp-po-cpy mineralisation 0/S-S A,FI po
111125 U0825 (v) 79.5m 65690 1800 asp-qz-po-cpy breccia mineralisation 0/S-S A, Fl
111126 U0833 (i) 194.5m 66360 1710 carb-mag mineralisation 0/S A,PTS
111127 U0833 (ii) 196.0m 66360 1710 asp-cass-qz-py mineralisation 0/S A, PTS asp
111128 U0833 (iii) 200.0m 66360 1710 po-trem replacement mineralisation s A,PTS
111129 U0844 (i) 211.8m 66470 1680 asp-po-cpy-qz mineralisation 0/S-S A,PTS
111130 U0844 (ii) 215.3m 66470 1680 po-qz mineralisation cut by qz vein s A, Fl po
111131 U0844 (iii) 220.4m 66470 1680 po-trem mineralisation s A,PTS
111132 U0844 (iv) 233. 7m 66470 1680 po-qz mineralisation with py deformation evident s A,PTS
111133 U0844 (v) 235.0m 66470 1680 po-qz-py mineralisation s A, Fl po,py
111134 U0862 (i) 61.8m 66100 1890 sheared asp-qz vein BM? A,PTS
111135 U0862 (ii) 65.0m 66100 1890 asp-qz-po vein 0/S-S A,FI po
-"" -J
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy
111136 U0862 (iii) 68.0m 66100 1890 po-py vein
111137 U0862 (iv) 78.8m 66100 1890 massive po with qz crystals
111138 U0862 (v) 79.7m 66100 1890 massive trem-po minealisation
111139 U0870 (i) 117.1m 65480 2020 massive po-trem replacement I 111140 U0870 (ii) 118.0m 65480 2020 massive po-qz crystals
111141 U0892 (i) n.om 66500 2000 sheared po-py-qz
111142 U0892 (ii) 84.3m 66500 2000 carb-sph-py mineralisation
111143 U0936 (i) 12.0m 66180 1810 massive po-qz-flu veining in hostrock
111144 U0936 (ii) 20.4m 66180 181 0 asp-py-carb mineralisation
111145 U0936 (iii) 26.5m 66180 1810 po-py minealisation
111146 U0936 (iv) 28.5m 66180 1810 py-asp mineralisation
111147 U0936 (v) 33.0m 66180 1810 sheared py-asp-flu mineralisation with py-carb alteration
111148 U0938 (i) 51.5m 66180 1870 po-py mineralisation in hostrock breccia
111149 U0938 (ii) 66.2m 66180 1870 po-asp-py mineralisation with carb-flu veining
111150 U0938 (iii) 68.2m 66180 1870 po-cpy mineralisation
111151 U0938 (iv) 69.8m 66180 1870 trem-po replacement mineralisation
111152 U0938 (v) 81.0m 66180 1870 fibrous vein (trem?)
111153 uo943 (i) 44.5m 65350 2060 po-flu-py mineralisation in brecciated replacement hostrock
111154 U0943 (ii) 53.2m 65350 2060 qz vein with po-cpy veinlets
111155 U0968 (i) 132.1m 66140 1680 qz-py mineralisation in sheared hostrock
111156 U0968 (ii) 134.3m 66140 1680 asp-qz ±po mineralisation
111157 U0968 (iii) 145.0m 66140 1680 py-flu-po veinlets in hostrock
111158 U0968 (iv) 145.3m 66140 1680 asp-po-flu-py veined breccia
111159 U0968 (v) 155.0m 66140 1680 po-qz mineralisation
111160 U0978 (i) 97.8m 65760 1710 massive cass with late qz-flu vein
111161 U0978 (ii) 99.1 m 65760 1710 po-flu-py mineralisation with meln alteration & hem
111162 U0978 (iii) 102.8m 65760 1710 flu-cpy-po mineralisation with py alteration
111163 U0978 (iv) 106.8m 65760 1710 flu-po-cpy mineralisation with py alteration
111164 U0978 (v) 113.0m 65760 1710 flu-po-cpy mineralisation
111165 U1006 (i) 114.6m 66720 1980 carb-gal in brecciated host
111166 U1006 (ii) 115.5m 66720 1980 po-py vein in silicified hostrock
111167 U1006 (iii) 114.9m 66720 1980 po mineralisation with carb veinlets associate with py alteration
Stage
s s s s s s BM s BM s s s s S-V/C s s s s s S?
0/S
s s s 0/S
s s s s BM s s
Code ()345
A, PTS po, py
A, Fl po
A,PTS
A,PTS po
A, Fl po
A,PTS po,py
A, Fl py, sph
A, Fl po
A, PTS asp
A, PTS po, py
A, PTS py
A, Fl py
A,PTS po
A, PTS po A, PTS po, py
A,PTS po,py
A,PTS
A. Fl po
A, PTS po
A,PTS
A, Fl asp
A, Fl py
A, Fl po
A, Fl po
A, Fl
A, Fl po,py
A, Fl
A, Fl po
A, Fl po
A,PTS
A,PTS
A, PTS po
()180
qz
~ o...,J (,J
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy
111168 U1012 (i) 103.0m 65260 1760 po-flu-cpy vein
111169 U1012 (ii) 108.0m 65260 1760 asp-qz-po-cpy-wolf mineralisation with py alteration
111170 U1012 (iii) 113.5m 65260 1760 gal-carb-qz-sph vein
111171 U1012(iv) 114.0m 65260 1760 carb-sph-py-qz vein
111172 U1012(v) 119.9m 65260 1760 tremolite alteration with disseminated po
111173 U1023 (i) 40.0m 65440 1980 po-asp mineralisation with carb-py-flu veining
111174 U1023 (ii) 40.8m 65440 1980 po-py-cpy mineralisation with carb-flu-qz vein
111175 U1023 (iii) 41.0m 65440 1980 asp-po-cpy mineralisation with qz-carb vein
111176 U1023 (iv) 58.0m 65440 1980 po-asp-qz mineralisation with flu-carb vein
111177 U1028 (i) 55.6m 65380 1920 po-qz mineralisation with late qz-carb vein
111178 U1 028 (ii) 62.3m 65380 1920 asp-po mineralisation with carb veining & py alteration
111179 U1028 (iii) 66.5m 65380 1920 cass-asp-po mineralisation
111180 U1036 (i) 29.5m 66270 1800 green flu-qz-carb mineralisation
111181 U1036 (ii) 36.1m 66270 1800 po-qz-cpy mineralisation
111182 U1036 (iii) 47.0m 66270 1800 po-qz-py mineralisation
111183 U1036 (iv) 47.8m 66270 1800 py-carb-qz vein
111184 U1045 (i) 52.6m 65360 1840 po-flu-qz-asp mineralisation
111185 u1o45 (ii) 61.om 65360 1840 po-py-qz mineralisation
111186 U1045 (iii) 65.5m 65360 1840 dissem po-talc replacement mineralisation
111187 U1045 (iv) 68.2m 65360 1840 dissem po-talc replacement mineralisation
111188 U1092 (i) 39.0m 66360 1800 brecciated and veined hostrock with green flu-py
111189 U1092 (ii) 43.5m 66360 1800 qz-asp mineralisation with py altration
111190 U1092 (iii) 52.0m 66360 1800 massive po with minor carb-py vein
111191 U1107 (i) 29.6m 65560 1820 massive po-flu mineralisation
111192 U1107 (ii) 33.2m 65560 1820 po-asp-qz mineralisation
111193 U1112 (i) 21.0m 66060 1700 po-asp-qz-wolf veining
111194 U1112 (ii) 24.5m 66060 1700 vein containing qz with radiating tour
111195 U1115(i) 31.5m 66060 1730 po-asp-qz mineralisation with py-carb-qz vein
111196 U1115 (ii) 32.5m 66060 1730 asp-cass-qz vein , cut by late carb-qz-py vein
111197 U1115(iii) 38.7m 66060 1730 po vein cut by carb-sph-qz vein with py alteration
111198 U1115 (iv) 42.5m 66060 1730 asp-qz-wolf vein cut by po-cpy-qz mineralisation
111199 U1118 (i) 32.0m 66510 1880 asp-cass-wolf-qz mineralisation
Stage
s 0/S-S
BM I BM
s S-V/C
S-V/C
S-V/C
s S-V/C
s 0/S
VIC?
s s VIC
s s s s VIC?
0/S
s s s 0/S-S
0/S?
S-V/C
0/S-V/C
S-BM
0/S-S
0/S
Code o34S
A, Fl po
A, Fl asp,sph
A, Fl
A, Fl py,sph
A,PTS
A, PTS po, py
A, Fl po,py
A, Fl po,asp,cpy
A, Fl
A, Fl po
A, PTS asp
A, Fl po,asp
A, Fl
A, Fl po
A, PTS po
A,PTS
A, Fl po
A, PTS po, py
A,PTS
A,PTS
A, Fl
A,PTS
A, PTS po
A, Fl po x2
A, Fl
A, Fl po,sph
A,PTS
A, Fl po,py
A, Fl po,py
A, PTS po, py
A, Fl
A,PTS
a1so
~ -..J .fl.
APPENDIX XII- ROCK CATALOGUE
Northing R.L Mineralogy
111200 U1118 (ii) 37.0m 66510 1880 po-qz mineralisation
111201 U1118 (iii) 42.0m 66510 1880 late py veinlets in siderite
111202 U1160 (i) 40.0m 65780 1840 asp-cass-wolf-qz mineralisation
111203 U1160 (ii) 40.8m 65780 1840 po mineralisation cut by sph-qz-gal vein & py alteration I 111204 U1160(iii) 41.0m 65780 1840 po-qz mineralisation cut by flu-carb vein & py alteration
111205 U1160 (iv) 43.0m 65780 1840 po-cpy-flu-qz-asp mineralisation
111206 U1160 (v) 45.9m 65780 1840 po-qz-asp-cpy mineralisation
111207 U1176 (i) 63.0m 65880 1720 cpy-carb-qz vein
111208 U1176 (ii) 66.2m 65880 1720 contact po-asp-qz mineralisation with late stage carb-asp-qz vein
111209 U1176 (iii) 71.0m 65880 1720 po-flu-py mineralisation
111210 U1176 (iv) 71.6m 65880 1720 po-flu vein
111211 U1186 (i) 103.5m 65790 1700 sph-carb-qz vein
111212 U1186 (ii) 105.5m 65790 1700 flu-py-cpy-meln mineralisation
111213 U1186 (iii) 107.4m 65790 1700 qz-carb-cpy-flu-asp vein with meln alteration
111214 U1186 (iv) 107.5m 65790 1700 flu-po-cpy mineralisation with carb vein
111215 U1186 (v) 114.0m 65790 1700 po-flu-cpy-asp mineralisation
111216 U1186 (vi) 117.0m 65790 1700 po-asp-flu-cpy mineralisation with sph-carb-qz veining
111217 U1198 (i) 77.1m 65260 1940 brecciated hostrock with po infill
111218 U1214 (i) 102.0m 65640 1730 wolf-asp-qz-cpy mineralisation
111219 U1214 (ii) 102.1m 65640 1730 po-asp-cpy mineralisation
111220 U1214 (iii) 102.5m 65640 1730 flu-po-asp-cpy mineralisation
111221 U1214 (iv) 108.0m 65640 1730 po-flu-cpy-asp mineralisation
111222 U1214(v) 113.5m 65640 1730 po-flu-qz-cpy mineralisation
111223 U1214 (vi) 115.0m 65640 1730 po-flu-cpy mineralisation
111224 U1214 (vii) 101.5m 65640 1730 qz minmeralisation with po-cpy veinlets
111225 U1226A (i) 74.7m 66240 1960 po vein cutting silicified po replacament zone
111226 U1226A (ii) 77.1m 66240 1960 po-py-flu mineralisation with flow foliation
111227 U1226A (iii) 84.5m 66240 1960 po-talc with well developed foliated replacement texture
111228 U1240 (i) 35.5m 66590 1900 asp-po-cpy-qz mineralisation
111229 U1240 (ii) 36.0m 66590 1900 qz-po-py mineralisation
111230 U1240 (iii) 42.0m 66590 1900 py-carb-qz mineralisation
111231 U1253 (i) 14.8m 65530 1870 qz-flu-rhod-gal vein
Stage Code Cl34S
s R, Fl po
supergene R, PTS
0/S R,PTS
S-BM R, Fl po
S-V/C R, Fl
s R, Fl po,py
0/S-S R, PTS po
BM R, PTS cpy
S-BM? R, Fl po
s R, Fl po
s R, Fl po
BM R, Fl sph
BM R, Fl cpy
BM? R, Fl py
s R, Fl
s R, Fl po,cpy
S-BM R, Fl po,sph
s R,PTS
0/S R, Fl po,cpy
s R,PTS
s R, Fl
s R, Fl po
s R, Fl
s R, Fl po x2
0/S-S? R, Fl
s R, PTS po
s R,PTS
s R,PTS
0/S-S R, Fl
s R, Fl po
VIC R, Fl po
BM R, Fl
()180
qz
~ 'I •n
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy
111232 U1253 (ii) 15.4m 65530 1870 qz-po-py vein
111233 U1253 (iii) 16.4m 65530 1870 sph-gal-qz vein with rhod-py breccia vein
111234 U1253 (iv) 24.8m 65530 1870 po-asp-talc replacement mineralisation
111235 U1253 (v) 30.9m 65530 1870 gal-sph-carb colloform vein with py I 111236 U1267 (i) 56.4m 66610 1940 asp-po breccia with carb veining
111237 U1267 (ii) 57.5m 66610 1940 po-qz-flu mineralisation
111238 U1267 (iii) 62.5m 66610 1940 po-qz-siderite contact
111239 U1267 (iv) 64.6m 66610 1940 disseminated po-dolomite contact
111240 U1274 (i) 48.0m 66570 1870 dissem po replacement texture with carb-mag mineralisation
111241 U1305 (i) 114.0m 65940 1790 asp-po breccia in contact with hostrock
111242 U1305 (ii) 123.5m 65940 1790 dissem po-qz replacement of tram-talc-asp mineralisation
111243 U1343 (i) 102.7m 65440 2110 dissem po replacement of talc
111244 U1361 (i) 106.1m 66020 2010 qz with po-asp veinlets
111245 U1361 (ii) 107.0m .
66020 2010 asp-po with py veinlets
111246 U1361 (iii) 107.2m 66020 2010 qz-asp mineralisation with po overprint
111247 U1377 (i) 70.0m 65680 1820 gal-carb vein
111248 U1377 (ii) 72.5m 65680 1820 qz-asp-cpy vein in po
111249 U1377 (iii) 77.5in 65680 1820 wolf-qz-asp mineralisation in massive po-cpy-bism overprint
111250 U1377 (iv) 80.2m 65680 1820 po-asp-cpy-flu mineralisation
111251 U1390 (i) 69.0m 65490 1900 po-qz-asp mineralisation grading into dissem po-talc repl. texture
111252 U1390 (ii) 69.9m 65490 1900 flu-qz vein cutting dissem po-talc replacement texture
111253 U1390 (iii) 78.0m 65490 1900 dissem po-asp-talc-flu replacement texture
111254 U1408 (i) 63.8m 66700 1930 po-asp brecciated by carb-py & late meln alteration
111255 U1408 (ii) 67.0m 66700 1930 po-py mineralisation replacing hostrock breccia
111256 U1408 (iii) 76.0m 66700 1930 po-sph-carb veinlet in silicified hostrock
111257 U1414 (i) 206.2m 66650 1700 qz-po vein
111258 U1426 (i) 119.5m 66660 1800 qz vein cut by anastomosing po-py-cpy veinlets
111259 U1426 (ii) 120.4m 66660 1800 slate breccia cut by carb-flu vein
111260 U1522 (i) 88.0m 66880 1840 dissem po-talc replacement textures with py veins
111261 U1522 (ii) 89.5m 66880 1840 dissem po-asp-qz mineralisation
111262 U1522 (iii) 93.2m 66880 1840 cass-talc-asp mineralisation
111263 U1563 (i) 117.3m 66860 1920 RBM cut by carb-flu-sph vein
Stage
s BM
s BM
s s s s 0/S-S
0/S
s S.
0/S
s 0/S-S
BM
0/S-S
0/S-S
s 0/S-S
S·
0/S-S
S-V/C
s S-BM
s s VIC
s s 0/S
BM
Code d34S
R, Fl po
R, Fl sph, gal
R,PTS
R,PTS
R,PTS
R, Fl po
R,PTS
R,PTS
R,PTS
R, PTS po
R,PTS
R,PTS po
R, Fl po
R,PTS
R, Fl po
R, Fl
R, Fl po,cpy
R, Fl po
R, Fl po
R, Fl po
R, Fl
R, Fl po
R,PTS pox2
R, Fl po
R, Fl po,sph
R,FI po
R,PTS
R,PTS
R,PTS po x2, py
R, Fl
R, Fl
R,PTS
d180
qz
qz
qz
""" '-.I n
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy
111264 U1563(ii) 119.7m 66860 1920 dissem po-talc replacement texture in No.2 dolomite
111265 U1563 (iii) 125.7m 66860 1920 sheared contact between po-py mineralisation & hostrock
111266 U1564 (i) 110.6m 66850 2000 po replacement of dolomite I .
111267 U1564 (ii) 115.0m 66850 2000 brecciated py-asp in ARM with sph-gal-carb vein
111268 U1586 (i) 91.1m 67050 1840 po-py mineralisation with sph-carb brecciation & veining
111269 U1586 (ii) 94.0m 67050 1840 po-talc replacement texture
111270 U1614 (i) 41.8m 66100 2000 brecciated hostrock with porepl. clasts & py contacts
111271 U1614 (ii) 47.1m 66100 2000 po-qz mineralisation with sph
111272 U1614 (iii) 57.0m 66100 2000 dissem po-qz repl. in contact with hostrock
111273 U1617 (i) 166.0m 65360 1600 brecciated hostrock with po disseminations
111274 U1617 (ii) 168.8m 65360 1600 asp-qz vein with late carb-py vein cross-cutting
111275 U1625 (i) 63.0m 65360 1720 dissem po-qz cut by carb-flu veinlet (Envelopes)
111276 U1625 (ii) 74.5m 65360 1720 qz-asp mineralisation cut by qz-carb vein & later py veinlets
111277 U1647 (i) 45.0m 65620 1640 cass-qz(sacch) mineralisation with carb-py-chl veining
111278 U1647 (ii) 45.8m 65620 1640 cass-qz(sacch) mineralisation with carb-py-chl veining
111279 U1647 (iii) 51.3m 65620 1640 cpy-flu brecciation with meln
111280 U1647 (iv) 54.0m 65620 1640 asp-qz mineralisation with late py-cpy- & meln along fractures
111281 U1647 (v) ss.5m 65620 1640 po-qz vein with py fractures
111282 U1647 (vi) 58.0m 65620 1640 po-Ilu mineralisation
111283 U1786 (i) 42.8m 66250 1850 po-qz intergrowth
111284 U1786 (ii) 44.0m 66250 1850 po-qz intergrowth with cpy replacement
111285 U1786 (iii) 44.2m 66250 1850 qz-asp-po mineralisation
111286 U1786 (iv) 45.7m 66250 1850 qz-po mineralisation with meln-carb overprint
111287 U1786 (v) 52.0m 66250 1850 hostrock breccia with py replacement
111288 U1853 (i) 42.0m 66440 2130 po replacement of brecciated hostrock dolomite
111289 U1853 (ii) 44.5m 66440 2130 po-qz-wolf mineralisation
111290 U1853 (iii) 47.5m 66440 2130 po-asp-qz mineralisation
111291 U1853 (iv) 51.0m 66440 2130 siderite with p~ veinlets
111292 U1892 (i) 38.2m 65740 2200 carb-flu-sph-gal veining
111293 U1892 (ii) 39.7m 65740 2200 po-qz-cass vein
111294 U1892 (iii) 58.2m 65740 2200 dissem po-talc replacement with late py vein
111295 U1897 (i) 28.4m 65720 2190 selective po replacement of hostrock
Stage Code ()34S
s R,PTS po
s R,PTS po
s R, PTS po
S-BM R, PTS py, sph
BM R, PTS py, sph
s R, PTS po
s R, PTS po, py
S-BM R, Fl po,sph
s R,PTS
s R,PTS
0/S R, Fl
S. R, Fl po
0/S-V/C R, Fl
0/S-V/C R, Fl sph
0/S-V/C R, Fl
VIC R, Fl py, meln
0/S R, Fl
s R, Fl
s R, Fl po
s R, Fl
s R, Fl
0/S-S R, Fl
S-superge R, Fl
s R,PTS po,py
s R,PTS
s R, Fl po,py
s R,PTS
s R,PTS
BM R,PTS
S(O/S) R, Fl po
s R,PTS
s R,PTS
()180
qz
qz
qz
~
"' -..j
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code ()345 ()180
111296 U1897 (ii) 29.0m 65720 2190 cass-qz mineralisation 0/S R, Fl
111297 U1897 (iii) 29.3m 65720 2190 po-qz mineralisation s R, Fl
111298 U1897 (iv) 29.6m 65720 2190 po-qz mineralisation with qz-carb-meln vein S-V/C R, Fl po,py
111299 U1897 (v) 40.0m 65720 2190 po-py-qz-asp mineralisation in hostrock with green flu-ca~-qz vein S-V/C R, Fl
111300 U1901 (i) 35.7m 65660 2170 dissem po-qz mineralisation s R,PTS
111301 U1901 (ii) 38.8m 65660 2170 dissem po with py blebs s R,PTS
111302 U1901 (iii) 40.1m 65660 2170 dissem po-py mineralisation s R,PTS
111303 U1901 (iv) 55.1m 65660 2170 dissem po with py blebs s R,PTS
111304 U1901 (v) 71.5m 65660 2170 py blebs in hostrock s R,PTS
111305 U1947 (i) 76.8m 66900 1900 po-qz intergrowths with sph exsolutions s R, Fl po,sph
111306 U1947 (ii) 83.6m 66900 1900 po contact with hostrock s R,PTS
111307 U1947 (iii) 86.5m 66900 1900 po-py mineralisation in brecciated hostrock s R, PTS .py
111308 U1985 (i) 62.0m 65680 1680 dol-talc repl mineralisation cut by po-cpy-flu vein s R, Fl
111309 U1985 (ii) 64.6m 65680 1680 asp-qz mineralisation with po-cpy-qz associations 0/S-S R, Fl po,cpy
111310 U1985 (iii) 67.4m 65680 1680 po-cpy-flu mineralisation s R, Fl
111311 U1985 (iv) 67.7m 65680 1680 asp-qz-wolf mineralisation with po-qz-bism-cpy intergrowths 0/S-S R, Fl
111312 U1992 (i) 162.4m 66940 1750 po mineralisation with qz-carb vein containing flu tension veins S-V/C R, Fl po
111313 U1992 (ii) 170.8m 66940 1750 po-asp mineralisation s R,PTS
111314 U2013 (i) 65.7m 66200 1700 po-qz intergrowths s R,PTS po
111315 U2013 (ii) 67.6m 66200 1700 po-asp veins in brecciatd hostrock s R,PTS
111316 U2064 (i) 106.0m 65760 1600 sph-carb-gal breccia BM R, Fl sph
111317 U2064 (ii) 107.7m 65760 1600 sheared hostrock R,PTS
111318 U2064 (iii) 116.8m 65760 1600 po-flu-qz mineralisation cut by chi-asp vein S-BM R, Fl
111319 U2064 (iv) 118.1m 65760 1600 po-flu(purple & clear) mineralisation s R, Fl po,py
111320 U2064 (v) 118.4m 65760 1600 po-flu-qz-cpy mineralisation s R, Fl
111321 U2064 (vi) 122.0m 65760 1600 po-flu-qz-cpy mineralisation cut by chl-asp-qz vein s R, Fl
111322 U2127 (i) 100.5m 65820 1640 cpy-flu mineralisation s R, Fl
111323 U2127 (ii) 102.4m 65820 1640 po mineralisation cut by qz-carb-cpy vein S-BM R, Fl po
111324 U2127 (iii) 107.2m 65820 1640 po-flu vein s R,PTS
111325 U2127 (iv) 108.5m 65820 1640 qz-carb vein cutting qz-asp-po-cpy 0/S-S R, Fl
111326 U2127 (v) 109.5m 65820 1640 po mineralisation cut by carb±qz-flu-sph-cpy veining S-BM R, Fl
111327 U2127 (vi) 110.2m 65820 1640 bladed po-carb-sph mineralisation S-BM R, Fl po,py, sph
.,. ~
Northing
111328 U2127 (vii) 111.5m 65820 111329 U2129 (i) 306.6m 66660 111330 U2129 (ii) 306.7m 66660
111331 U2194 (i) 113.9m 66400
111332 U2194(ii) 114.3m 66400
POLARIS
111333 50318 (i) 62.4m 66340 111334 50329 (i) 143.0m 66600 111335 50329 (ii) 147.5m 66600 111336 50329 (iii) 148.0m 66600 111337 50422 (i) 45.0m 66400
111338 50425 (i) 83.1m 66530 111339 50425 (ii) 83.5m 66530
111340 50430 (i) 123.8m 66490
111341 50433 (i) 39.5m 66360 111342 50433 (ii) 4o.5m 66360 111343 50437 (i) 129.5m 66440 111344 50437 (ii) 130.5m 66440
111345 50437 (iii) 132.5m 66440 111346 50439 (i) 71.0m 66490 111347 50477 (i) 180.1m 66500
111348 50477 (ii) 181.0m 66500 111349 50493 (i) 75.0m 66440
111350 50493 (ii) 78.5m 66440
111351 50977 (i) 116.5m 66330
111352 50977 (ii) 117.5m 66330
111353 50986 (i) 89.5m 66460 111354 50986 (ii) 90.0m 66460
111355 50986 (iii) 91.5m 66460
111356 50986 (iv) 92.0m 66460
APPENDIX XII- ROCK CATALOGUE
R.L. Mineralogy Stage Code a34S a1so
1640 carb-qz-flu-chl vein BM R, Fl
1600 asp-qz vein replaced by py±carb vein S-superge R, Fl
1600 late qz-carb mineralisation cut by calcite vein VIC R, Fl
1600 edge po-qz vein I s R, Fl
1600 po-asp-qz mineralisation on edg~ of massive po 0/S-S R, Fl po
2180 silicified host rock overprinted by py s R,PTS Py
2025 carbonate vein with carb xsts. VIC R,A
2025 po mineralisation overprinted by py-carb-sph vein S-BM R,A Py, Po
2025 po-py-fluor shear s R,A Po,Sph
2220 asp overprinted by py s R,PTS Asp, Py, Py(shear)
2130 carb-mag relic in po with py altreration + sph-qz 0/S-S R,PTS,FIPo,Py
2130 carb-mag with talc-po overprint mineralisation 0/S-S R,PTS Po
2100 po-asp-qtz-cass mineralisation s R,A
2230 RBM pebbly sandstone R,PTS
2230 py-po-trem replacement mineralisation s R,PTS Py, Po
2120 pyritised breccia s R,PTS
2120 po-qtz replacement texture with py overprint s R,A Po,Py
2120 carb-mag replaced by po and late vein carb 0/S-S-V/C R, PTS(*2)
2170 carb-mag with py-cpy overprint 0/S-S R 2060 carb-mag with overprinting talc-po skarn assemblage 0/S-S R
2060 sheared contact between carb-mag mineralisation & hostrock + po 0/S-S R 2140 pyritic black shale with py-qz vein s R
2140 massive po mineralisation with qz-asp-cass vein (carb-mag at 77.51 0/S-S R
2120 sheared carb-mag-po mineralisation 0/S R
2120 po replacement mineralisation with qz-chl vein s R
2120 po-py mineralisation in fractured & pyritised hostrock s R 2120 sheared py-po-hostrock s R
2120 silicified-py hostrock breccia s R
2120 pyritised hostrock breccia s R
~ '-J '0
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code i)34S ()180
111357 51100 (i) 67.6m 66480 2160 hostrock-carb breccia VIC R
111358 51100 (ii) 68.7m 66480 2160 carb-mag with po-qz overprint 0/5-5 R
111359 51100 (iii) 70.3m 66480 2160 sheared contact of carb-mag mineralisation with talc-po mlneralisat 0/5-5 R
111360 51102 (i) 54.0m 66440 2170 breccia with po-py-qz mineralisation 5 R
111361 51102 (ii) 60.0m 66440 2170 sheared margin to massive po-py mineralisation 5 R
111362 51102 (iii) 61.0m 66440 2170 mag-talc mineralisation 0/5 R
111363 51175 (i) 123.5m 66560 2100 sheared margin between carb-mag & massive po 5 R
111364 U1493 (i) 66.8m 66480 2080 brecciated contact between po-py and hostrock 5 R
111365 U1493 (ii) 68.7m 66480 2080 carb-mag with py overprint shear with hostrock 0/5-5 R
111366 U1497 (i) 67.9m 66510 2100 po-mag mineralisaton 0/5-5 R
111367 U1497 (ii) 68.3m 66510 2100 carb-mag-trem hostrock breccia 0/5-5 R
111368 U1497 (iii) 70.0m 66510. 2100 po with py vein replacement 5 R
111369 U1497 (iv) 70.1m 66510 2100 qz-cass with py overprint (30cm) 0/5-5 R
111370 U1497 (v) 70.2m 66510 2100 qz-py vein 5? R
111371 U1838 (i) 27.6m 66390 2140 py breccia in massive po 5 R
111372 U1838 (ii) 30.0m 66390 2140 hostrock breccia R
111373 U1838 (iii) 31.1m 66390 2140 late stage py-sph vein BM R
111374 U1838 (iv) 32.4m 66390 2140 qz-py vein 5 R
111375 U1856 (i) 37.2m 66540 2160 carb-mag-talc-py mineralisation 0/5 R
111376 U2016 (i) 18.8m 66400 2120 py-po veining of brecciated hostrock 5 R
111377 U2016 (ii) 22.0m 66400 2120 carb-mag contact with massive po 0/5-5 R
111378 U2016 (iii) 22.8m 66400 2120 massive po replacement of carb-mag 0/5-5 R
111379 U2016 (iv) 23.0m 66400 2120 massive po with sheared pyritised contact with hostrocks 5 R
111380 U2022 (i) 28.6m 66500 2120 pyritised hostrock breccia with cass? 5 R
111381 U2022 (ii) 28.2m 66500 2120 pyritised hostrock breccia 5 R
111382 U2022 (iii) 27.1m 66500 2120 pyritised breccia with late stage carb vein 5 R
SHEAR L
111383 50313 (i) 155.5m 66080 2160 carb-mag mineralisation with po-qtz mineralisation 5 R,FI Po
111384 50313 (ii) 159.5m 66080 2160 qtz-po mineralisation 5 R,PT5
111385 50320 (i) 25.5m 66140 2240 py rich sheared hostrock with po-qz mineralisation 5 R,PT5 Py
.~
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code aa4S a1so
111386 50391 (i) 975.8m 65600 1260 asp-qtz mineralisation cut by sph-gal-cab vein 0/5-BM R, Fl Asp
111387 50391A (i) 948.0m 65590 1290 asp-cpy-qtz-fluor mineralisation BM R, Fl Asp,Ccp,Py
111388 50391A (ii) 946.0m 65590 1290 qtz-carb-fluor-chl mineralisation BM R, Fl
111389 50391A (iii) 943.0m 65590 1290 qtz-sph-gal-chl mineralisation I BM R, Fl
111390 50526 (i) 42.8m 66300 2220 qtz-py breccia 5? R, Fl Py
111391 50703 (i) 34.0m 66300 2250 py-hostrock breccia 5 R, PT5 X Py, Po
111392 50876 (i) 886.8m 65600 1380 qtz-asp-cass mineralisation 0/5 R,PTS Asp qz
111393 S0987 (i) 719.4m 65760 1510 carb-fluor mineralisation with meln alteration VIC R,FI
111394 S1135 (i) 53.7m 65740 2240 po-asp-py-qtz mineralisation 0/S-5 R,PTS Po
111395 51136 (i) 145.0m 65790 2160 po-py-qtz mineralisation s R, Fl Po,Py
111396 S1141 (i) 84.7m 65850 2220 qtz-po mineralisation 5 R,FI Po qz
111397 51141 (ii) 85.5m 65850 2220 massive po replacement mineralisation 5 R,PTS . Po
111398 51186 (i) 177.8m 66170 1920 asp-mag-carb mineralisation 0/S R,PTS Asp
111399 51186 (ii) 179.6m 66170 1920 carb-mag mineralisation 0/5 R,FI
111400 S1188 (i) 152.9m 66100 2160 po-py-qtz mineralisation 5 R, PTS X Po, Py qz
111401 51285 (i) 162.0m 65970 2170 massive po(asp-cpy) mineralisation 5 R,PT5 Po, Asp
111402 51374 (i) 73.2m 65710 2250 po-py-sph mineralisation S-(BM?) R, Fl Po,Sph
111403 U0695 (i) 17.8m 65690 1950 po-qtz mineralisation 5 R,FI
111404 U0695 (ii) 20.0m 65690 1950 po-asp-qtz mineralisation 0/5-5 R, PTS, F Po, Asp
111405 U0717 (i) 36.0m 65550 2040 qtz-po mineralisation with sph-gal-cpy-carb vein 5-BM R,FI
111406 U0766 (i) 64.7m 66040 2010 qtz-po-tour vein s R, Fl qz
111407 U0802 (i) 14.0m 65780 1880 po-qtz replacement mineralisation 5 R,FI Po
111408 U0802 (ii) 18.5m 65780 1880 po-qtz vein with fluor at18. 7m 5 R, Fl Po qz
111409 U0839 (i) 31.0m 65590 2100 qtz-asp-cpy-po mineralisation 5 R,PTS. Asp, Po
111410 U0839 (ii) 31.5m 65590 2100 po replacement mineralisation 5 R,PTS Po
111411 U0897 (i) 51.0m 65720 1820 asp-po-qtz mineralisation 0/5-5 R,FI
111412 U0897 (ii) 61.5m 65720 1820 po-cass mineralisation 5 R,PTS Po
111413 U0950 (i) 56.0m 65690 1760 po-qtz(cpy-chl) vein 5 R,PTS Po
111414 U0952 (i) 71.0m 65730 1750 po-fluor-cpy-qtz-tour mineralisation s R, Fl Po
111415 U0952 (ii) 74.7m 65730 1750 po-asp-qz-cass mineralisation 0/5-S R, Fl Asp, Po
111416 U0969 (i) 5.5m 65560 2140 po-qtz mineralisation s R,FI
111417 U0969 (ii) 7.5m 65560 2140 po-silicified hostrock with replacement texture s R,PTS
!;)
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code a34S a1eo
111418 U1107 (i) 33.0m 65560 1820 qtz-py-hostrock breccia 5 R,PT5
111419 U1107 (ii) 36.5m 65560 1820 qtz-po-wolf? vein 0/5 R, Fl
111420 U1190 (i) 132.8m 65780 1640 qtz(zoned)-carb-chl mineralisation BM? R, Fl
111421 U1190 (ii) 133.0m 65780 1640 qtz-carb(bladed)-chl-sph mineralisation I BM? R, Fl
111422 U1190 (iii) 133.3m 65780 1640 asp-qtz-cass mineralisation 0/5 R,PTS Asp
111423 U1255 (i) 62.8m 65540 1900 po-qtz mineralisation 5 R,FI Po
111424 U1540 (i) 20.5m 65550 1880 po-asp-qtz mineralisation 5 R, Fl Asp, Po
111425 U1657 (i) 0.5m 65610 1640 po-py mineralisation cut by qz-carb vein 5-V/C R,PT5 Po,Py
111426 U1818 (i) 20.5m 65520 1940 carb-sph-gal mineralisation with colloform text BM R,FI Ga
111427 U1818 (ii) 23.5m 65520 1940 massive po-qtz-asp-cpy-cass mineralisation 5 R, Fl Po
111428 U1913 (i) 39.0m 65660 1900 sph-gal-carb-qtz-cpy-py mineralisation BM R,FI Sph
111429 U1913 (ii) 42.5m 65660 1900 asp-talc-cass mineralisation 0/5 R,PT5
111430 U1913 (iii) 43.5m 65660 1900 po-qtz-py mineralisation 5 R,FI
111431 U1941 (i) 20.5m 65580 1860 asp-py-qtz-carb vein BM? R,FI Asp
111432 U1941 (ii) 26.5m 65580 1860 po-qtz mineralisation 5 R,PT5 Po
111433 U1941 (iii) 30.5m 65580 1860 po-asp-qtz-cpy replacement mineralisation 5 R,PT5 Po
111434 U1954 (i) 23.0m 65520 1890 po-qtz-py repl. mineralisation with colloform sph-gal-cpy-carb vein 5-BM R,FI Po,Py,5ph
111435 u1954 (ii) 31.6m 65520 1890 py-asp-carb breccia BM? R,PT5
111436 U1959 (i) 5.0m 65560 1880 sph-gal-cpy-carb-qtz veining BM R, Fl Sph
111437 U1974 (i) 18.0m 65520 1840 po-qtz-cpy mineralisation 5 R,FI Po
111438 U1974 (ii) 20.0m 65520 1840 po-asp-qtz replacement mineralisation with qzcpy-carb vein 5-BM R, Fl Asp, Po
SHEAR P
111439 50537 (i) 14.0m 66270 2240 brown porous gossan material R
111440 51184 (i) 34.0m 66120 2250 carb-mag mineralisation with po veinlets 0/5-5 R,FI
111441 51221 (i) 35.5m 65960 2300 po-asp-py breccia 5 R,PTS Po,Py,Asp
111442 51248 (i) 139.0m 66080 2220 siliceous breccia with po disseminations 5 R,PTS
111443 51248 (ii) 139.5m 66080 2220 po-qtz replacement texture 5 R, Fl Po
111444 51259 (i) 74.5m 66010 2270 po-py contact with hostrock 5 R,PTS Po,Py
111445 51260 (i) 72.5m 65990 2270 asp-qtz mineralisation with po-py overprint 0/5-5 R, PTS, F Po, Py qz
111446 U0615 (i) 58.9m 65960 2000 po-qtz mineralisation 5 R, Fl Po
~ r)
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code ()345 ()180
111447 U0764 (i) 36.2m 66110 1970 po-talc-carb mineralisation 0/S R,PTS
111448 U0766 (i) 47.0m 66040 2000 po-asp-qtz mineralisation 0/S-S R, Fl
111449 U0797 (i) 36.7m 65980 2100 po-fluor-qz mineralisation with asp-carb overprint S-BM R,PTS,FPo
111450 U0836 (i) 55.0m 66060 2020 asp-cpy-qtz mineralisation I 0/S R,PTS Asp
111451 U0836 (ii) 55.2m 66060 2020 po-qtz mineralisation s R, Fl Po
111452 U0840 (i) 25.0m 66060 1850 po-trem? replacement mineralisation s R,PTS
111453 U0840 (ii) 31.5m 66060 1850 asp-qtz mineralisation with po vein lets 0/S-S R, Fl Asp
111454 U0938 (i) 19.0m 66180 1830 relict carb-mag replaced by gal-sph-carb-py vein 0/S-BM R,PTS
111455 U0938 (ii) 20.5m 66180 1830 po-py-qtz mineralisation s R,PTS
111456 U0941 (i) 153.5m 66170 1660 asp-qtz-chl? mineralisation 0/S R,FI Asp
111457 U0941 (ii) 166.8m 66170 1660 qtz-po-asp- mineralisation 0/S-S R, Fl
1:11458 U0945 (i) 104.5m 66170 1720 po-qz mineralisation s R, Fl Po
111459 U0945 (ii) 111.5m 66170 1720 asp-qtz mineralisation with py vein 0/S-S R,PTS Asp
111460 U0954 (i) .
66230 1720 qtz-py vein s R,PTS 125.5m 111461 U0954 (ii) 128.5m 66230 1720 po-qtz mineralisation s R,FI
111462 U0964 (i) 80.7m 66140 1740 po-asp-qtz mineralisation in sheared host rock 0/S-S R,PTS Po
111463 U0964 (ii) 82.0m 66140 1740 qtz(xsts) vein R,FI
111464 U0976 (i) 15.6m 66010 1950 asp-fluor-chl-carb vein BM? R, Fl Asp
111465 U0976 (ii) 18.0m 66010 1950 po-py-qz vein s R,PTS
111466 U0976 (iii) 23.0m 66010 1950 po overprinting qz vein s R,PTS Po qz
111467 U1114 (i) 26.2m 66060 1690 po-qtz mineralisation s R, Fl Po qz
111468 U1114 (ii) 28.8m 66060 1690 qtz-asp-po mineralisation 0/S-S R,FI
111469 U1117 (i) 74.5m 66020 1900 qtz-asp-po mineralisation 0/S-S R,PTS Po
111470 U1257 (i) 53.8m 65750 2050 po-qtz vein s R, Fl Po
111471 U1258 (i) 36.0m 66160 2195 po-qtz mineralisation with carb-qz vein S-V/C R,FI Po
111472 U1258 (ii) 48.0m 66160 2195 qtz-po mineralisation s R, Fl Po qz
111473 U1623 (i) 12.0m 66060 2000 qtz-asp vein with po-py mineralisation 0/S-S R,PTS Po
111474 U1623 (ii) 12.5m 66060 2000 massive po with minor qz + meln s R,FI Po
111475 U1716 (i) 39.5m 66260 1840 qtz-po mineralisation s A qz
111476 U1716 (ii) 41.5m 66260 1840 po-qtz replacement of silicified hostrock s R,FI Po
111477 U1787 (i) 16.0m 66250 1810 qtz-po replacement mineralisation s R,FI Po
111478 U1787 (ii) 20.5m 66250 1810 qtz-fluor-carb-hostrock breccia V/C R,FI
to IJ
APPENDIX XII- ROCK CATALOGUE
Northing R.L. Mineralogy Stage Code ()34S ()180
111479 U1787 (iii) 21.5m 66250 1810 po-fluor-py vein 5 R,FI Py 111480 U1794 (i) 60.2m 66169 1840 po-qtz-py vein in sheared hostrock 5 R,PT5 Po 111481 U1896 (i) 45.5m 65760 2180 silicified-tourmalinised hostrock containing po 5 R,PT5 Po
DUNDAS
111482 Wallaces Prospect late stage qz-jam-py veining R py,jam qz
111483 Colebrook Hill Opencut qz-ax-asp-py-act mineralisation R po,cpy qz
111484 Frazer Creek Hut py-sph-jam mineralisation R py,jam, sph
111485 Kapi Mine qz-gal-sph-carb mineralisation R sph, gal
111486 Fahl Mine qz-po-py mineralisation R po,py
111487 South Comet Mine late stage sph-gal-carb-qz vug R sph, gal qz
111488 Curtin Davis 5W Mine qz-asp-cpy-carb-sph-jam mineralisation R py, cpy, jam qz
111489 Evendon Prospect .
qz-carb-py mineralisation R gal qz
111490 Grand Prize Mine po-qz-py mineralisation R po qz
111491 Maestries-Comet Mine qz-carb mineralisation R qz
111492 FIIKM Mine qz-carb mineralisation with asp-jam-py R qz
111493 Karlson-Riley Mine qz-carb-lim gossan R qz
GRANITE
DDH No. Northing R.L. Mineralogy Stage Code o34S ()180
51400 (i) 1402m Granite dyke R,D,P
111495 51400 (ii) 1511m Granite dyke R,D,P
& !;.