solutions dr. ron rusay spring 2003. limestone caves: solubility of caco 3
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Solutions
Dr. Ron RusayDr. Ron Rusay
Spring 2003Spring 2003
Limestone Caves: Solubility of CaCO3
Solutions
Substances can mix together to form Substances can mix together to form homogeneous mixtures (homogeneous mixtures (solutionssolutions). The material ). The material present in the larger amount is the present in the larger amount is the solventsolvent and and the other(s) is (are) the the other(s) is (are) the solute(s).solute(s). Together they Together they form a solution. form a solution.
The most common solutions are liquids. The The most common solutions are liquids. The solute can be a solid, liquid or gas which is solute can be a solid, liquid or gas which is dissolved in a liquid solvent.dissolved in a liquid solvent.
The most common solvent is water.The most common solvent is water.
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DHMO, dihydromonoxide : “The Universal” Solvent
04_40
H
O2δ−
δ+
δ+
105 °
H
http://www.dhmo.org
Water as a Solvent
04_40
H
O2δ−
δ+
δ+
105 °
H
Generally, likes dissolve likes, i.e. polar-polar and nonpolar-nonpolar. If polar and nonpolar mix , eg. oil and water:
The oil (nonpolar) and water (polar) mixture don’t mix and are immiscible. If liquids form a homogeneous mixture, they are miscible.
Salt dissolving in a glass of water
Water dissolving an ionic solid
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Concentration and Temperature
Besides amount, the rate also increases. What are two other ways of increasing the solubility of a solid, eg. sugar in coffee?
Relative SolutionConcentrations:SaturatedUnsaturatedSupersaturated
Solution Types Solutions with less solute dissolved than is Solutions with less solute dissolved than is
physically possible are referred to as physically possible are referred to as ““unsaturatedunsaturated”. Those with a maximum ”. Those with a maximum amount of solute are “amount of solute are “saturatedsaturated”.”.
Occasionally there are extraordinary Occasionally there are extraordinary solutions that are “solutions that are “supersaturatedsupersaturated” with ” with more solute than normal.more solute than normal.
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Gas Solubility
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Solubility @ P2 = Solubility @ P1 x [P2 / P1 ]P is the partial pressure of the gas vapor.
Solubility units (Concentration) are usually: g / 100 ml
Preparation of Solutions
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Solution Concentration
A solution’s concentration is the measure of the A solution’s concentration is the measure of the amount of solute dissolved. amount of solute dissolved.
Concentration is expressed in several ways. One way Concentration is expressed in several ways. One way is mass percent.is mass percent.
Mass % = Mass solute / [Mass solute + Mass solvent ] Mass % = Mass solute / [Mass solute + Mass solvent ] x100x100
What is the mass % of 65.0 g of glucose dissolved in What is the mass % of 65.0 g of glucose dissolved in 135 g of water?135 g of water?
Mass % = Mass % = 65.0 g / [65.0 + 135]g x10065.0 g / [65.0 + 135]g x100
= 32.5 % = 32.5 %
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Solution Concentration Concentration is expressed more importantly as Concentration is expressed more importantly as
molarity molarity (M)(M)..
Molarity (M) = Moles solute / LiterMolarity (M) = Moles solute / LiterSolutionSolution
An important relationship is An important relationship is M x VM x Vsolutionsolution= mol= mol This relationship can be used directly in mass This relationship can be used directly in mass
calculations of chemical reactions.calculations of chemical reactions. What is the molarity of a solution of 1.00 g KCl in What is the molarity of a solution of 1.00 g KCl in
75.0 mL of solution?75.0 mL of solution?M =M = 1.00g 1.00g KClKCl x 1mol x 1mol KClKCl / 74.55 g / 74.55 g KCl KCl x 1/ 75mL x 1000mL / Lx 1/ 75mL x 1000mL / L
= 0.18 mol / L= 0.18 mol / L
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Acid-Base Titration
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Solution ApplicationsSolution ApplicationsNeutralization-TitrationNeutralization-Titration
15.5015.50 mL of vinegar, a solution of acetic acid (aa), mL of vinegar, a solution of acetic acid (aa), required required 20.0020.00 mL of a mL of a 0.30000.3000 M (mol/L) M (mol/L) solution of a sodium hydroxide solution to react solution of a sodium hydroxide solution to react completely. completely. MMaaaa = ? = ?
HCHC22HH33OO2 2 (aq)(aq) + NaOH + NaOH(aq)(aq) ? + ? ? + ?
HCHC22HH33OO2 2 (aq) + NaOH(aq) (aq) + NaOH(aq) 11 NaC NaC22HH33OO22 (aq) + (aq) + 11HH22O (l)O (l)
??MMaaaa = [MNaOHx VNaOH / VHC2H3O2HC2H3O2 ] [? ] [? molmolHC2H3O2HC2H3O2 / ? / ? molmolNaOHNaOH]]
0.3000 molNaOH x 0.02000 LNaOHNaOH x 11 molmolHC2H3O2HC2H3O2
LLNaOHNaOH x 0.01550 0.01550 LLHC2H3O2HC2H3O2 x 11 molmolNaOHNaOH
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??MMaaaa =
??MMaaaa = 0.3870 0.3870 molHC2H3O2HC2H3O2 / L/ LHC2H3O2HC2H3O2 = 0.3870 0.3870 MHC2H3O2HC2H3O2
Solution ApplicationsSolution Applicationshttp://ep.llnl.gov/msds/Chem106/vinegar.html
What is the weight percent of the acetic acid What is the weight percent of the acetic acid (aa)? (aa)?
((Density of vinegar = 1.006 g/mL; Molar Mass (aa) = MW (aa) in grams/ mole aa = 60.056g aa/mole aa)
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� (Molarity aa x Volume aa) x (60.056g aa /mole aa)(Molarity aa x Volume aa) x (60.056g aa /mole aa)� = mass aa= mass aa == 0.3600.360 g gaaaa
[(mass of Acetic Acid) / (mass of vinegar) ] * 100% = % [(mass of Acetic Acid) / (mass of vinegar) ] * 100% = % Acetic Acid Acetic Acid
� mass of vinegar = density x sample volume = mass of vinegar = density x sample volume = 15.59 15.59 gg
� % = % = 0.3600.360 g gaa aa / / 15.59 15.59 g g * 100 = * 100 = 2.3%2.3%
Solution Dilution
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