slaughterhousesrestaurants waste disposal units ( container parks) fogra meat and bonemeal recycled...

Slaughterhouses RestaurantsWaste disposal units

( container parks)

FOGRA

Meat and bonemealRecycled FA

± 80 T.Animal fat

± 50 T.

DEMETER (NL)

VERKEST19/4

20/4

FEEDMILL

COMPANIES

Second contamination Rendac (Rendering of animals)

Aveve

TRANSPORT COMPANY VILLE DE COURTRAI N.V.

Annex 1

WAYS OF CONTAMINATION

19/1/99 FOGRA DE BRABANDER28.680 kg GR.REC.(très contaminées)

20/1/99 VERKEST TANK 127.200 KG

HUYS VOEDERS NV

ChargementFOGRA : 28.040 kg GR.AN.

VERKEST : - 2/3 Tank 1B+ 2/3 Tank 1

21/1/99 ALIMEX (FRANCE)22/1/99 FOGRA VERKEST (GR.AN.)25/1/99 FOGRA VERKEST (GR.AN.)26/1/99 FOGRA HUYS (GR.AN +GR.REC.)

VERKEST (1+1B) DE

Annex 1

PCB Dioxins

(µg/g fat) (pg/g fat)

453,000 11163,000

6,600 120,450

3,000 61,630

6,500 165,980

6,100 111,430

5,630 108,390

10,300 214,130

336,000 4970,000

0,830 20,080

332,000 6141,000

15,000 301,370

11,00 266,18

3,40 72,97

220,00 5915,00 Log PCBs (µg/g fat)L

og

dio

xin

s (p

g/g

fat)

0 1 2 3-0.50

1

2

3

4

5

Results:r2 = 0.994p < 0.0001Log dioxins = 0.974 x Log PCB + 1.344n = 13

Dioxins and PCBs infeedstuff

Annex 2

PCB Dioxins


38,890 713,060

15,938 265,700

0,093 1,400

0,440 6,680

0,380 12,150

4,600 64,310

0,080 2,100

0,110 1,620

0,406 12,000

0,770 19,000

0,850 19,580

0,07 6,04

0,09 1,68

0,12 2,14

0,11 0,90

4,38 54,18

0,05 3,87

0,07 2,23

2,65 67,78

3,93 71,65

0,06 2,43

0,08 2,08

0,13 2,02

0,09 1,85

0,05 0,94

Log PCBs (µg/g fat)

Lo

g d

ioxi

ns

(pg

/g f

at)

-2 -1 0 1 2-1

0

1

2

3

4


Dioxins and PCBs ineggs

Annex 2

PCB Dioxins


44,146 775,110

51,059 2513,000

0,515 14,000

2,721 132,620

5,237 54,380

47,101 965,350

7,602 132,420

6,908 156,500

22,637 463,280

0,159 5,830

0,471 15,800

Log PCBs (µg/g fat)L

og

dio

xin

s (p

g/g

fat

)-1 0 1 2

0

1

2

3

4

Resultsr2 = 0.944p < 0.0001Log dioxins = 0.932 x Log PCB + 1.45n = 11

Dioxins and PCBs inchicken

Annex 2

PCB Dioxins


0,014 1,350

0,053 2,080

0,011 0,880

0,024 2,100

0,018 0,800

0,022 3,250

0,015 1,620

0,018 1,730

0,010 0,830

0,028 1,430

0,160 0,650

0,136 2,600

0,028 1,390

0,048 2,500

0,122 2,310

0,144 4,310

0,117 1,890

0,134 2,130

0,101 2,560

0,111 3,000

0,122 4,070

0,058 1,138

0,015 2,070

0,034 1,970

0,019 2,650

0,014 2,290

0,030 1,650

0,013 1,100

0,015 1,460

0,024 2,510

0,018 0,990

0,016 1,230

0,041 2,760

0,019 1,770

0,031 2,470

0,030 2,160

Log PCBs (µg/g fat)Lo

g di

oxi

ns

(pg/

g fa

t)

-2.5 -2.0 -1.5 -1.0 -0.5-0.5

0.0

0.5

1.0


Dioxins and PCBs inmilk

Annex 2

PCB Dioxins


0,225 5,300

1,024 9,500

0,597 13,200

0,598 8,000

Log PCBs (µg/g fat)L

og

dio

xin

s (p

g/g

fat

)-0.75 -0.50 -0.25 0.00 0.25

0.0

0.5

1.0

1.5

2.0

Results:r2 = 0.528p = 0.2733, not significantLog dioxins = 0.437x Log PCB + 1.05n = 4

Dioxins and PCBs inbeef

Annex 3

PCB Dioxins PCB Dioxins

(µg/g fat) (pg/g fat) (µg/g fat) (pg/g fat)

0,23 0,45 0,426 0,97

0,48 1,80 1,05 2,7

0,30 5,50 0,555 0,504

0,29 2,00 1,901 2,2

0,23 0,55 14 2,64

0,44 2,20 0,222 1,9

0,43 2,80 0,755 5,4

0,24 3,20 1,356 5,5

0,75 11,70 2,36 2,1

0,43 3,20 17,954 64

25,47 2,70 3,268 15

4,70 9,80 0,36 1,11

0,61 9,75 0,229 0,92

0,76 2,40 0,491 3,1

0,25 1,60 0,294 1,6

0,24 0,15 0,297 3,4

4,47 4,50 0,244 0,685

0,23 1,27 0,456 2,9

0,37 5,13 0,415 2,1

0,37 1,10 0,277 0,15

0,60 2,10 0,322 2,9

0,49 2,00 0,475 3,1

0,26 3,00 0,356 0,718

0,23 1,50 0,28 1,3

0,74 3,00 0,308 0,35

0,367 2,8

0,381 3

4,285 0,82

0,777 3,1

0,519 3,4

0,612 2,8

0,284 1,2

0,205 0,956

0,38 2,1

0,408 3,2

0,26 0,99

0,37 1,4

0,278 1,2

3,936 3,32

0,894 6,6

2,24 2,8

9,247 20,6

0,463 1,3

0,468 1,9

0,512 1,9

0,207 1,36

0,346 1

2,099 3

2,327 3,2

0,244 1,154

Log PCBs (µg/g fat)Lo

g di

oxin

s (p

g/g

fat)

-1.0 -0.5 0.0 0.5 1.0 1.5-1.5

-1.0

-0.5

0.0

0.5

1.0

1.5

2.0


Dioxins and PCBs inpigs

Annex 3

-5

0

5

10

15

20

25

30

35

40

28 52 101 118 138 153 180

Congeneres

%

73% 1260/ 27% 1254 µ (feedstuff, 3-9-99) µ+1,96*s µ-1,96*s

Annex 4

ALL RESULTS PCB (results in the central database until 20/10/1999)Type of sample % Negative % Positive number of results negative positive limit (µg/kg)

unknown 99 1 101 100 1 200waste 97 3 471 456 15 1000butter 0 0 54 54 0 200eggs 92 8 1154 1063 91 200foodstuff 98 2 6368 6244 124 200milk 99 1 962 950 12 100fat/other 100 0 121 121 0 200fat-pigs 89 11 16724 14856 1868 200fat-poultry 96 4 4296 4112 184 200fat-cattle 99 1 4108 4055 53 200fat-animal not known 100 0 3694 3684 10 200Total 38053 35695 2358

Type of sample > 200 µg/kg 200 - 500 µg/kg 500 - 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgunknown 1 0 0 1 0butter 0 0 0 0 0eggs 91 40 29 14 8foodstuff 124 60 30 30 4fat/other 0 0 0 0 0fat-pigs 1868 786 425 594 63fat-poultry 184 83 53 30 18fat-cattle 53 33 13 7 0fat-animal not known 10 5 0 5 0

Type of sample > 100 µg/kg 100 - 200 µg/kg > 200 µg/kgmilk 12 8 4

Type of sample > 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgwaste 15 11 4

Annex 5

ALL RESULTS PCB (results in the central database until 20/10/1999)

Type of sample % Negative % Positive number of results negative positive limit (µg/kg)feedstuff 98 2 1244 1213 31 1000ingredients feedstuff 100 0 539 538 1 1000fat for feedstuff 95 6 1177 1118 68 1000Total 2960 2869 100

Type of sample > 200 µg/kg 200 - 500 µg/kg 500-1000 µg/kgfeedstuff 59 37 22ingredients feedstuff 35 13 22fat for feedstuff 33 15 18

Annex 5

Number of negative results PCB (results in the central database until 20/10/1999)

0

2000

4000

6000

8000

10000

12000

14000

16000

Nu

mb

er

of

sa

mp

les

Negative samples 100 456 54 1063 6244 950 121 14856 4112 4055 3684

unknow n w aste butter eggs foodstuff milk fat/other fat-pigs fat-poultry fat-cattlefat-animal not

know n

Annex 5

Number of negative results PCB (results in the central database until 20/10/1999)

0

200

400

600

800

1000

1200

1400

Nu

mb

er

of

sa

mp

les

Negative samples 1213 538 1118

feedstuff ingredients feedstuff fat for feedstuff

Annex 5

Number of positive results PCB (results in the central database until 20/10/1999)

0

200

400

600

800

1000

1200

1400

1600

1800

Nu

mb

er o

f sa

mp

les

Positive samples 1 15 0 91 124 12 0 1868 184 53 10

unknow n w aste butter eggs foodstuff milk fat/other fat-pigs fat-poultry fat-cattlefat-animal not

know n

Annex 5

Number of positive results PCB (results in the central database until 20/10/1999)

0

10

20

30

40

50

60

70

Nu

mb

er o

f sa

mp

les

Positive samples 31 1 68


Annex 5

% Negative-Positive Results PCB related to exportDate of entry results:04/08/99 - 20/10/99

0

10

20

30

40

50

60

70

80

90

100

Nu

mb

er o

f sa

mp

les

%

Negative 99,1 99,3 97,9 99,1 100,0 99,6 100,0

Positive 0,9 0,7 2,1 0,9 0,0 0,4 0,0

Pigs Poultry Eggs Bovine Veal Animal fat Feedstuff

Annex 5

% Negative-Positive Results (results in the central database until 20/10/1999)

0

10

20

30

40

50

60

70

80

90

100

Nu

mb

er o

f sa

mp

les

%

Negative 98 100 95

Positive 2 0 6


Annex 5

ALL RESULTS PCB RELATED TO EXPORT (date of entry results: between 04/08/99 - 20/10/1999)

Type of sample % negative % positive number of results negative positive limit (µg/kg)Pigs 99,1 0,9 8550 8471 79 200Poultry 99,3 0,7 1314 1305 9 200Eggs 97,9 2,1 485 475 10 200Bovine 99,1 0,9 2882 2856 26 200Veal 100,0 0,0 286 286 0 200Animal fat 99,6 0,4 1394 1388 6 200Feedstuff 100,0 0,0 319 319 0 1000Total 15230 15100 130

Type of sample > 200 µg/kg 200 - 500 µg/kg 500 - 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgPigs 79 60 11 8 0Poultry 9 8 0 0 1Eggs 10 7 2 1 0Bovine 26 17 7 2 0Veal 0 0 0 0 0Animal fat 6 3 2 1 0

Type of sample > 1000 µg/kg 1000 - 5000 µg/kg > 5000 µg/kgFeedstuff 0 0 0

Annex 5

Number of negative results PCB related to export

0

1000

2000

3000

4000

5000

6000

7000

Nu

mb

er

of

sa

mp

les

negative samples 8471 1305 475 2856 286 1388 319


Annex 5

Number of positive results PCB related to export

0

10

20

30

40

50

60

70

Nu

mb

er o

f sa

mp

les

Positive samples 79 9 10 26 0 6 0


Annex 5

% Negative-Positive Results PCB related to export

0

10

20

30

40

50

60

70

80

90

100

Nu

mb

er o

f sa

mp

les

%

Negative 99,1 99,3 97,9 99,1 100,0 99,6 100,0

Positive 0,9 0,7 2,1 0,9 0,0 0,4 0,0


Annex 5

NEGATIVE RESULT POSITIVE RESULT"EXPORT"-samples 15100 130"SANITARY"-samples 13082 2135"CERTIFICATION"-samples 3737 29

0

2000

4000

6000

8000

10000

12000

14000

16000

NEGATIVE RESULT 15100 13082 3737

POSITIVE RESULT 130 2135 29

"EXPORT"-samples "SANITARY"-samples"CERTIFICATION"-

samples

Annex 5

Management of the Belgian Dioxin Crisis

Federal Government

Task Force Governmental CoordinationCrisis CentreGeneral Coordination

Agriculture & Public HealthCrisis cell

Laboratories - ResultsGeert De Poorter

Sanitary InquiriesAlbert Vandersanden (DG 4)Gilbert Houins (DG 4)L. Hallet (DG 5)

Validation CommissionRelease Commission

Noel Vanginderachter (DG 5)Jean-Pierre Vermeersch (DG 5)Guy Temmerman (AEWI)Roger Francaux (IVK)

Regional Government

Annex 6

Entity ChartGovernmental coordination Crisis

Centre

Governmental Coordination Crisis Centre

Civil ProtectionMinistry of Agriculture

Ministry of HealthRegional Authorities

Flanders, Wallonia, Brussels

Provincial Authorities

Private Companies(Rendac, Indaver)

Aminal, Ovam, GANEnvironmental Police

Annex 6

CoordinationGeert De Poorter

LaboratoriesHedwig Beernaert

Sampling distributionBruno Buts

AnalysisAnneke De Cock

InvoicesGeert De Poorter

Export-certificationPierre Joye

Sanitary analysisSabien De Mont

Herd certification analysisSabien De Mont

Pierre Joye

Entity chart

“Laboratories-Results”

Annex 6

Entity Chart “sanitary Inquiries”

Sanitary Inquiries

DG4Feedstuff(feedmill control)

DG5Dairy products,(breeding)eggs and live stock(Farm control, packing station,egg products companies)

Food Inspection ServiceFoodstuff (other thanMeat and Fish)(Food industry and Retail

Veterinary InspectionInstituteMeat and Fish(Slaughterhouses and cutting plants)

Certificates

Destruction of contaminatedanimals and products

Epidemiological inquiryand tracing

Annex 6

SubentityLABORATORIES

LABORATORIES

Formal recognition Accreditation Quality Assurance Normalisation

Federal Ministryof Agriculture

Federal Ministryof Health

PCB and dioxin Protocol Method ValidationInternal QualityControlEuropean Assessement

EU-154

Proficiency TestingReference Materials

Beltest

Annex 6

Subentity ANALYSIS

Analysis

Sanitary analysisExport cerification

analysisHerd certification

analysis

Negative results Positive results

Milk:100(PCB),5 (dioxin)Animal fat and eggs: 200 (PCB), 5(dioxin)

Feed: 1000(PCB), 20(dioxin)Sanitary Inquiries

Annex 6

LAB RESULTS POS. RES. NEG. RES. % POS % NEGENVIROTOX 3811 253 3558 6,6 93,4EURACETA 209 0 209 0,0 100,0ECCA 3392 122 3270 3,6 96,4RIC 2250 121 2129 5,4 94,6CHEMIPHAR 1507 27 1480 1,8 98,2COPIN GEMBLOUX 1046 67 979 6,4 93,6PROV.INST.HYG.ANTW. 1709 50 1659 2,9 97,1CER-MARLOIE 566 10 556 1,8 98,2CCL-NED 52 0 52 0,0 100,0CREPIN-ROUEN 90 2 88 2,2 97,8DEP.ZEEVISSERIJ 253 66 187 26,1 73,9DEP.KWAL.MELLE 264 22 242 8,3 91,7ERC 211 16 195 7,6 92,4HAASE-ASCHOFF-GE 11 0 11 0,0 100,0LAB.ANAL.ALIM.FAC.MED.VET 4 0 4 0,0 100,0LABO MUNIC ROUEN 47 0 47 0,0 100,0LABO VAN VOOREN 4243 127 4116 3,0 97,0LARECO 2253 40 2213 1,8 98,2LISEC 707 111 596 15,7 84,3LOVAP 5140 229 4911 4,5 95,5MASTERLAB 127 1 126 0,8 99,2PROV.CENT.MILIEUOND. 256 29 227 11,3 88,7RIKILT 59 16 43 27,1 72,9ROLT 2012 533 1479 26,5 73,5SERVACO 1981 248 1733 12,5 87,5SGS AGRILAB 4097 379 3718 9,3 90,7TNO-NED 58 0 58 0,0 100,0TOX.CENTR.UNIV.ANTW. 1680 116 1564 6,9 93,1VITO 757 118 639 15,6 84,4WIV-LOUIS PASTEUR 1348 104 1244 7,7 92,3ISSP 33 4 29 12,1 87,9VERWEY-NED 4 0 4 0,0 100,0INSTITUT KUHLMAN 10 0 10 0,0 100,0B.E.A.G.X.-GEMBLOUX 4 0 4 0,0 100,0CLO OOSTENDE 2 0 2 0,0 100,0LUFA-ITL 1 0 1 0,0 100,0MAGHUIN-ROGISTER 78 1 77 1,3 98,7RIVM-NED 1 0 1 0,0 100,0PIVH 22 0 22 0,0 100,0TOTAL 40295 2812 37483 7,0 93,0

Approximative PCB-capacity of the Belgian Labs dioxin-crisis 1999

0

1000

2000

3000

4000

5000

6000

June

4

June

6

June

9

June

23

end o

f July

Augus

t 23

Septe

mbe

r 27

Octobe

r

0

5

10

15

20

25

30

CAPACITY

LABORATORIES

Dioxine/PCB-gehalte Destructievet Rendac (Produktie week 5 t.e.m. 13)

0

500

1000

1500

2000

2500

3000

3500

5 6 7 8 9 10 11 12 13

week

µg

/kg

vet

0

5

10

15

20

25

30

35

40

45

50

pg

TE

Q/g

vet

PCB Dioxine

Dioxine geanalyseerd in SGS-AGRILABPCB geanalyseerd in CCL (Centraal Cooperatief Labo - Nederland)

Week Dioxine PCBpg TEQ/g vet µg/kg vet

5 8,3 5506 35,1 25407 45,1 30808 34 22809 37 245010 33 229011 16,7 111012 10,8 66013 11 680

DIOXINS ANALYSIS TIME OF THE LABORATORY VITO

0

10

20

30

40

50

60

70

80

90

100

3/06

/1999

4/06

/1999

9/06

/1999

14/06

/199

9

16/06

/199

9

16/06

/199

9

1/07

/1999

6/07

/1999

6/07

/1999

10/07

/199

9

13/07

/199

9

13/07

/199

9

13/07

/199

9

14/07

/199

9

14/07

/199

9

26/07

/199

9

9/08

/1999

9/08

/1999

10/08

/199

9

11/08

/199

9

11/08

/199

9

11/08

/199

9

23/08

/199

9

24/08

/199

9

26/08

/199

9

1/09

/1999

3/09

/1999

6/09

/1999

20/09

/199

9

DATE ON WHICH THE SAMPLES WERE RECEIVED BY VITO

AN

AL

YS

IS T

IME

(D

AY

S)

DAYS

MEAN

slaughterhousesrestaurants waste disposal units ( container parks) fogra meat and bonemeal recycled...

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