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School of Chemistry Annual Report 2015
Contents | 01
Contents
SECTION 102 From the Head of School
03 Head of School Report
04 Mission Statement:
05 School of Chemistry Committees – 2015
06 Academic Responsibilities
SECTION 209 Academic Staff
21 Academic Staff Awards
SECTION 322 Research
23 Director of Research Report
26 Research Highlights
28 School Seminars 2015 – Invited Speakers
SECTION 430 Teaching
31 Director of Teaching Report
32 First Year Chemsitry
33 Honours Program
34 Postgraduate Seminars
35 Postgraduate Research
36 Outreach Activities
38 Degrees Awarded 2015
40 Postgraduate Research Completions
41 UNSW Chemical Society
SECTION 542 Students
43 Undergraduate Student Prizes
46 Postgraduate Student Awards and Prizes
48 Student Conference Presentations 2015
51 Conference Posters 2015
54 Undergraduate and Postgraduate Enrolments
59 SOCS President’s Report
SECTION 660 School
61 Staff
64 Publications & Patents
72 Grants and Research Fellowships
77 Industry and Community Interaction
SECTION 779 School Visiting Committee 2015
SECTION 881 Obituaries
02 | School of Chemistry Annual Report
Mission StatementSchool CommitteesAcademic Responsibilities
From the Head of School
Head of School Report | 03
Head of School Report
Welcome to my first Head of School Report.
It is hard to believe that, as I write this, I have been in this role
for over 18 months now. Taking over from Barbara Messerle
has been a double-edged sword; she left the School in such
good shape (great), but it is significant personal challenge to
ensure that the trajectory continues (daunting). So, 2015 was
a learning year for me, and while I was learning, the School
just kept getting better and better.
The School continues to grow in most areas. Dr Vinh
Nguyen joined the academic staff as a Lecturer in 2015.
Dr Jason Harper was promoted to Associate Professor.
Amanda Troobnikoff and Shan Balachandran joined the
general staff team as finance officer and stores officer
respectively.
In 2015, there were 116 PhD and Masters students, and
37 post-doctoral researchers in the School. This increase
is impressive both in its scale (tripling over the past 10
years) and crucial to the School. HDR students and post-
docs are the engine that drives research productivity. This
engine produced 226 research publications in 2015, which
is the first time that the School topped 200 publications in
a calendar year (at least within the recorded data I have
going back a couple of decades).
Of course such growth does not happen by chance and
without the very hard work of a great team of academic
researcher colleagues. It takes a lot of funds to support
research and researchers in the School were successful in
attracting almost $6M in external funds from a wide variety
of sources, including ARC, NHMRC, and direct funding
from industry.
The constant growth of the School over the past decade
has put significant pressure on space. The building
that houses the School’s research labs was built for 90
researchers in 2006. Ten years later, the School houses
247 people. I spent a great deal of my time this year
lobbying the university for increased laboratory space. I
think the business case is compelling, but you will have to
wait for the 2016 Annual Report to see how I have fared!
Several members of the School were recognized for the
success during the year. The most notable was the award
of an ARC Laureate Fellowship to Professor Justin Gooding.
This is a very significant achievement and well-deserved by
Justin. Dr Alex Donald was awarded the inaugural Michael
Guilhaus award from the Australian and New Zealand
Society for Mass Spectrometry. The is a special award
for the School as Michael was a former academic staff
member of the School and there is something poignant
about a new member of the School winning this award at its
first outing. In addition, Tim Schmidt won the Broida Prize
at the International Free Radicals Conference, Joe Brophy
the RACI Archibald Olle Prize and Renxun Chen a Fulbright
Postdoctoral Fellowship. Several PhD students won prizes
at conferences.
2015 saw the inception of the Chemistry Education
group. This is an informal group of staff (academic and
general) with an interest in chemistry education. The group
managed four research projects through the year, the
biggest of which was the “Lab Skills Assessment” project,
where the lab assessment in First Year labs was changed
to a regime of real-time skills assessment instead of
assessment being based mostly on submitted pro forma
lab reports.
I want to record my congratulations to the whole School
for a very successful and exciting 2015 and my thanks for
making the transition to a new Head of School so smooth.
We have a great School and I appreciate the efforts of
everyone – my academic colleagues, the fantastic admin
and technical staff and also the researchers (post-doc,
PhD, Hons).
Professor Scott Henderson Kable
PROFESSOR SCOTT HENDERSON KABLE
04 | School of Chemistry Annual Report
Mission Statement:
In order to remain a leading School in the region in both research and teaching, the School aims to grow to a size of 30 academic staff over the next five years. The growth will be targeted to maintain a balance of the four research clusters
To increase our research funding and broaden the funding base of the research groups we will target international funding schemes and industry support. A key goal is to achieve high quality publications in leading international journals with continued growth in terms of volume
of output in publications and of higher impact. Postgraduate research students form the core of our research strength and we need to continue to grow the quality and number of our higher degree students, with particular focus on attracting the best UNSW students and high quality international students into postgraduate studies.
As a School we constantly seek to improve our already high quality of teaching. We will achieve this by ensuring that the latest research developments in chemistry are included in our curricula and that our
teaching materials both challenge our undergraduate students and nurture their love of chemistry. By engaging the students we aim to promote their life long learning of chemistry.
To lead debate, we plan to expand our influence in the broader community. Our community engagement program will continue to target high schools across NSW and we will develop a new approach to our marketing strategy for students. We will grow the level of interactions with our alumni and focus on the inclusion of our alumni in the life of the School today.
¡ The School of Chemistry aspires to continue as a leading chemistry school in the region.
¡ We aim to develop cutting edge knowledge to solve key challenges in the world today.
Our research is focused in four research clusters Nanoscience, Medicinal Chemistry,
Energy & Environment, and Catalysis. These research areas provide a base from
which we take our research from the fundamentals of chemistry through to practical
applications.
¡ We aim to excel in the education of our future scientific leaders and community members.
We will continue to expand our interactions with institutions across the world, and build
strong ties with our community, in particular industry and schools.
Goals:
School of Chemistry Committees – 2015 | 05
School of Chemistry Committees – 2015
School Executive Committee ¡ Prof. Scott Kable (Chair)
¡ Scientia Prof. Justin Gooding
¡ A/Prof. Pall Thordarson
¡ Dr Gavin Edwards
School Board ¡ Prof. Scott Kable (Chair)
¡ Prof. Naresh Kumar
¡ A/Prof. Jonathan Morris
¡ A/Prof. Shelli McAlpine
¡ A/Prof. Pall Thordarson
¡ A/Prof Marcus Cole
¡ Dr Gavin Edwards
¡ Dr Toby Jackson
¡ Mr Rick Chan
¡ Mr Sveto Videnovic
Postgraduate Committee ¡ Prof. Martina Stenzel (Chair)
Outreach Committee ¡ Prof. Naresh Kumar (Chair)
Building & Space ¡ Prof. Scott Kable (Chair)
Research Committee ¡ A/Prof. Pall Thordarson
(Chair)
¡ Prof. Scott Kable
¡ Scientia Prof. Justin Gooding
¡ Prof. Martina Stenzel
¡ A/Prof. Jonathan Morris
¡ Dr Neeraj Sharma
Teaching Committee ¡ Dr Gavin Edwards (Chair)
¡ Prof. Scott Kable
¡ A/Prof Steve Colbran
¡ A/Prof John Stride
¡ Dr Ron Haines
¡ Dr Jason Harper
¡ Dr Luke Hunter
¡ Dr Scott Sulway
Health & Safety Committee ¡ Dr Graham Ball (Chair)
Search Committee ¡ Prof. Scott Kable (Chair)
School of Chemistry Research Committee Scientia Professor Justin Gooding, Professor Scott Kable, Professor Martina Stenzel, A/Prof Pall Thordarson,
Dr. Neeraj Sharma (A/Prof Jonathan Morris – absent)
School of Chemistry Teaching Committee Dr. Scott Sulway, Dr JasonHarper, A/Prof John Stride, Professor Scott Kable, Dr. Luke Hunter, A/Prof Steve Colbran,
Dr. Ron Haines
06 | School of Chemistry Annual Report
Academic Responsibilities
Head of SchoolProfessor Scott Henderson Kable
Deputy Head of SchoolScientia Professor Justin Gooding
Director of ResearchA/Prof Pall Thordarson
Director of TeachingDr Gavin Edwards
Deputy Director of Teaching & Talented Students ProgramDr Jason Harper
Postgraduate Research CoordinatorProfessor Martina Stenzel
Postgraduate Coursework CoordinatorDr Graham Ball
Honors CoordinatorA/Prof. John Stride
Higher Year Coordinator (2-3rd year)A/Prof. Pall Thordarson
Higher Year Laboratory CoordinatorA/Prof. Steve Colbran
1st Year CoordinatorDr Luke Hunter
1st Year Laboratory CoordinatorDr Ron Haines
Degree Program CoordinatorsMedicinal Chemistry
Professor Naresh Kumar
Nanotechnology
A/Prof Chuan Zhao
Seminar CoordinatorDr Jon Beves
Outreach Professor Naresh Kumar
Health & SafetyDr Graham Ball
ITDr Ron Haines
School of Chemistry Academic Staff 2015
Academic Responsibilities | 07
08 | School of Chemistry Annual Report
Academic StaffAcademic Staff Awards
Academic Staff
Academic Staff | 09
Dr Leigh Aldous - DECRA FellowB.Sc (Hon), Leeds, Ph.D. Queen’s University Belfast
Research ¡ Biomass processing and thermoelectrochemical waste heat harvesting
Dr Graham Edwin BallBSc (Hons) PhD University of Sheffield, UK
Professional Activities: ¡ RACI Inorganic Division, NSW Representative
Research: ¡ Chemical and biological applications of NMR spectroscopy.
¡ Characterisation of chemical reactive intermediates, especially organometallics.
¡ Applications of computational chemistry.
¡ Investigations of drug-DNA interactions.
¡ Structure elucidation
Dr Jonathan BevesBSc (Hons I), MSc University of Sydney, PhD University of Basel
Professional Activities: ¡ Member of Royal Australian Chemical Institute, Royal Society of Chemistry, Swiss Chemical Society
¡ Seminar coordinator - School of Chemistry
¡ Member, School Post-graduate Committee
¡ Chair, Australasian Metallosupramolecular Symposium
¡ Organising Committee, 23rd IUPAC Conference on Physical Organic Chemistry
Research: ¡ Supramolecular chemistry
¡ Coordination chemistry
Dr Leigh Aldous Dr Graham Edwin Ball Dr Jonathan Beves
10 | School of Chemistry Annual Report
Professor David BlackBSc (Hons 1), MSc University of Sydney PhD, University of Cambridge
Professional Activities: ¡ Secretary General, ICSU (2011-2017)
¡ Member of National Committee for Chemistry
Research: ¡ Synthetic organic chemistry including methods of synthesis, heterocyclic chemistry (especially indole chemistry, photochemistry.
¡ Organic aspects of coordination chemistry including ligand design and synthesis, macrocycles, organometallic chemistry.
¡ Polymer chemistry - new polyamides, polyesters and modified peptides. Self-assembly studies involving hydrogen bonding.
¡ Development of mild and efficient new metal
Associate Lecturer Anna ChoyBSc (Hons) UNSW
Professional Activities: ¡ UNSW School of Chemistry Coordinator of:
ú Summer School
ú Chemistry Bridging Course
ú Teaching Fellowship Scheme
Research: ¡ Chemistry Education
A/Prof Stephen Boyd ColbranBSc (Hons), PhD, Otago
Professional Activities: ¡ Level 2/3 Student Advisor & Level 2/3 Teaching Laboratory Coordinator, School of Chemistry, UNSW
¡ Member of the American Chemical Society (ACS) and the Royal Australian Chemistry Institute (RACI)
¡ Referee for the journals: Journal of the American Chemical Society; Angewandte Chemie International Edition, Chemistry–A European Journal; Journal of Physical Chemistry B, Inorganic Chemistry; Organometallics; Dalton Transactions; European Journal of Inorganic Chemistry; Inorganica Chimica Acta; Chemical Reviews.
¡ Editorial board member for the International Journal of Inorganic Chemistry (IJIC) and for the Journal of Chemical Sciences (JChem)
Research: ¡ Transition metal chemistry and electrochemistry
¡ Transition metal-based catalysis and electrocatalysis
Professor David Black Associate Lecturer Anna Choy A/Prof Stephen Boyd Colbran
Academic Staff | 11
A/Prof Marcus Lawford ColeBSc (Hons I) (Medal) 1998, PhD 2001, Cardiff University
Professional Activities: ¡ Fellow of the RACI
Research: ¡ Low oxidation state and hydrido complexes of the p- and f-block elements.
¡ Catalytic applications of N-heterocyclic carbenes.
¡ Probes for the quantification of multidentate ligand stereoelectronics.
¡ Sterically hindered ligand design
Dr Willilam Alex DonaldBSc Seattle University PhD University of California, Berkeley
Professional Activities: ¡ Chair Elect, RACI NSW Analytical & Environmental Chemistry Division
¡ Chartered member, Royal Australian Chemical Society
¡ Member, Australian and New Zealand Society for Mass Spectrometry
¡ Member, American Society for Mass Spectrometry
Research: ¡ Developing methods to control the ionization and fragmentation of molecules to improve the analytical performance of many types of mass spectrometry analyses. This is being achieved by surface modification and by improving our fundamental understanding of electrospray ionization.
¡ Obtaining a molecular level understanding of complex reaction mechanisms using mass spectrometry, ion mobility, laser spectroscopy, and electronic structure calculations. Directly probing reaction intermediates that are involved in many chemical processes, such as in organic synthesis and heterogeneous and biological catalysis
Dr Gavin Leslie EdwardsBSc (Hons), PhD (Monash)
Professional Activities: ¡ Associate Dean – Academic Programs
Research: ¡ Synthesis of novel DNA binding agents: new bisintercalating threading molecules, and organometallic drugs
¡ Sulfones, sulfoxides and sulfoximines in organic synthesis
¡ Cyclometallated complexes as new catalysts
A/Prof Marcus Lawford Cole Dr Willilam Alex Donald Dr Gavin Leslie Edwards
12 | School of Chemistry Annual Report
Professor Leslie FieldPh.D, D.Sc University of Sydney
Professional Activities: ¡ Secretary for Science Policy, Australian Academy of Science
¡ Fellow of the Australian Academy of Science
¡ Fellow of the Royal Australian Chemical Institute
¡ Member of the American Chemical Society
¡ Fellow of the Royal Society for Chemistry
¡ Fellow of the Royal Society of NSW
¡ Member of the International Society for Magnetic Resonance
¡ Director and Chairman of UNSW Innovations Pty Ltd
¡ Director of Australian Technology Park Innovations Pty Ltd
¡ Director of the Victor Chang Cardiac Research Institute Pty Ltd
¡ National ICT Australia Ltd (NICTA) UNSW Member Representative
¡ Member ARC Centre for Functional Nanomaterials Advisory Board
¡ Member of the National Drug & Alcohol Research Centre (NDARC) Board of Management
Research: ¡ Organometallic chemistry of coordinated dinitrogen - nitrogen fixation.
¡ C-H Bond activation and functionalisation
¡ Organometallic chemistry of carbon dioxide
¡ Applications of NMR spectroscopy in organic & organometallic chemistry
¡ Transition metal catalysis in organic synthesis
¡ Transition metal acetylides, organometallic polymers and new materials
¡ Metallocene chemistry
Professor Leslie Field
Academic Staff | 13
Scientia Professor J. Justin GoodingB.Sc. Hons (Melb), D. Phil (Oxon)
Professional Activities: ¡ Founding Co-Director of the Australian Centre for NanoMedicine
¡ Inaugural Editor-in-Chief, ACS Sensors
¡ Vice President of The International Society of Electrochemistry
Research: ¡ Immunosensors for detection of protein analytes (with a US based biosensing company)
¡ Porous silicon photonic crystals for biological imaging and disease diagnosis (with Dr Peter Reece, Physics UNSW and Dr. Katharina Gaus, Medicine UNSW).
¡ Modified surfaces for controlling surface interactions with cells for biomaterials applications (with Dr. Katharina Gaus, Medicine UNSW).
¡ Nanoparticle based biosensors labelling and detection in for medical diagnostics (with Professor Richard Tilley, Chemistry, UNSW).
¡ Silicon quantum dots for biolabelling (with Professor Richard Tilley, Chemistry, UNSW).
¡ Detection of microRNA (with Prof. Maria Kavallaris, Australian Centre for NanoMedicine).
¡ The three dimensional printing of cells (with Australian Centre for NanoMedicine).
¡ The immobilisation of homogeneous catalyst on surfaces (led by Professor Barbara Messerle, Macquarie University)
Dr Ronald Stanley HainesB.Sc. in Pure and Applied Chemistry (UNSW 1978) Ph.D. (UNSW 1982)
Professional Activities: ¡ First Year Chemistry Laboratory Coordinator
¡ School of Chemistry IT Coordinator
¡ Member, School of Chemistry Teaching Committee
¡ Member, Faculty of Science IT Group
¡ Honours Thesis Reading Panel Chair
Research: ¡ Assessment and instruction in undergraduate Chemistry laboratories.
¡ Chemical education and the impact of mobile devices and web development technologies on content delivery to students.
¡ Chemical kinetics, in particular the influence on reaction mechanisms of ionic liquids as solvents
Scientia Professor J. Justin Gooding Dr Ronald Stanley Haines
14 | School of Chemistry Annual Report
Dr Jason Brian HarperB.Sc. 1995, University of Adelaide, B.Sc.(Hons), 1996, Ph.D., 2000, Australian National University
Professional Activities: ¡ Director, Faculty of Science Talented Students Programme
¡ Director of Teaching, School of Chemistry
¡ Co-Chair, 23rd IUPAC Conference on Physical Organic Chemistry (Sydney 2016)
¡ National Scientific Program and Organisational Committee, 8th International Conference on Green and Sustainable (Melbourne 2017)
¡ Chair, 1st NSW Ionic Liquid Group One Day Symposium
¡ National Accreditation Committee (University Chemistry Programmes), Royal Australian Chemical Institute
¡ Treasurer, Southern Highlands Conference on Heterocyclic Chemistry
¡ Member, Royal Australian Chemical Institute
¡ Member, American Chemical Society (ACS)
Research: ¡ Application of physical organic chemistry to understanding organic processes, including:
¡ The development of an understanding of ionic liquids as novel reaction media, and their application.
¡ The examination of the chemical and physical properties of N-heterocyclic carbenes
¡ The investigation of novel NMR spectroscopic methods for monitoring reaction kinetics
Dr Luke HunterBSc (Advanced) (Honours), PhD, The University of Sydney
Professional Activities: ¡ Treasurer, RACI NSW Branch
Research: ¡ Research in the Hunter group focuses mainly on synthetic organofluorine chemistry, and its application to the creation of bioactive molecules. We collaborate extensively (e.g. with School of Medical Sciences, UNSW; Children’s Cancer Institute, UNSW; University of Marseilles; The University of Sydney; Macquarie University; The University of Tasmania; Monash University) to probe the properties of the molecules that we create
Dr Jason Brian Harper Dr Luke Hunter
Academic Staff | 15
Professor Scott Henderson KableB.Sc. (Hons) (Griffith), Grad. Dip. Business Admin. (QUT) PhD (Griffith)
Professional Activities: ¡ Board Member, RACI
Research: ¡ Photochemistry
¡ Atmospheric Chemistry
¡ Reaction Mechanisms
Professor Naresh KumarBSc (Hons 1) Punjab Agricultural University, IndiaMSc Punjab Agricultural University, IndiaPhD University of Wollongong, Australia
Professional Activities: ¡ Academic in charge: B Med Chem (Honours) program
¡ Academic in charge: School of Chemistry Outreach program
¡ Member, Royal Australian Chemical Institute (RACI)
¡ Member, American Chemical Society
¡ Chair, RACI (NSW) Natural Products Chemistry Group
¡ Assessor for ARC Discovery, Linkage and LIEF projects
¡ Assessor for ARC Laureate Fellowship applications
Research: ¡ Design and synthesis of novel antimicrobial agents including quorum-sensing inhibitors and antimicrobial peptide mimics
¡ Development of synthetic methodologies for the preparation of biologically important natural products and their analogues
¡ Heterocyclic chemistry
¡ Novel antimicrobial biomaterials
Professor Scott Henderson Kable Professor Naresh Kumar
16 | School of Chemistry Annual Report
A/Prof Shelli Renee McAlpineBSc University of Illinois, PhD UCLA
Professional Activities: ¡ Editorial Advisory board: Journal of Medicinal Chemistry
¡ Chair of the American Chemical Society Australian chapter
¡ American Chemical Society: International committee board member
¡ NHMRC adhoc grant reviewer
¡ Conference Organizer for RACI Medicinal Chemistry Division
Research: ¡ Investigating Heat shock protein 90 inhibitors as potential chemotherapeutics
¡ Synthesis and Mechanistic evaluation of natural products
¡ Designing small molecules that target Heat shock protein 70 and Heat shock protein 27
A/Prof Jonathan Charles MorrisBSc (Hons) UWA, PhD ANU
Professional Activities: ¡ Treasurer, Organic Division, RACI
¡ Treasurer, Medicinal Chemistry and Chemical Biology, RACI
Research: ¡ Design of inhibitors for RNA Splicing Kinases
¡ Total synthesis of natural products
¡ Natural Product-Inspired Compound Libraries
¡ Design of Isoform Selective Ceramide Synthase Inhibitors
¡ New drugs to counteract the side effects and premature ageing caused by chemotherapy
Dr Vinh NguyenB.E (1st class Honours) UNSW, Ph.D ANU
Research: ¡ Organocatalytic chemistry
¡ Synthetic methodology development
¡ Green chemistry
¡ Natural product synthesis
A/Prof Shelli Renee McAlpine A/Prof Jonathan Charles Morris Dr Vinh Nguyen
Academic Staff | 17
Professor Timothy SchmidtBSc (Hons 1M) USYD, PhD Cambridge
Professional Activities: ¡ Associate Editor, Journal of Photonics for Energy
Research: ¡ Molecular photophysics
¡ Renewable energy
¡ Molecular spectroscopy
¡ Astrochemistry
¡ Atmospheric chemistry
Dr Neeraj SharmaPhD USYD
Professional Activities: ¡ RACI Materials Division Treasurer & Secretary
¡ Asian Crystallographic Association Regional Representative
¡ Program Advisory Committee, Powder Diffraction Beamline, Australian Synchrotron
¡ Organising committee for the 11th International Symposium on Ceramic Materials and Components for Energy and Environmental Applications – Advanced Batteries and Supercapacitors for Energy Storage Applications Component, Canada
Research: ¡ Tuning negative thermal expansion materials to zero thermal expansion materials using electrochemical cells
¡ New electrodes for sodium-ion batteries
¡ In operando studies of lithium- and sodium-ion batteries
¡ New solid state electrolytes
Professor Timothy Schmidt Dr Neeraj Sharma
18 | School of Chemistry Annual Report
Professor Martina Heide StenzelMSc, University of Bayreuth, Germany PhD University of Stuttgart, Germany
Professional Activities:
¡ Co-Director Centre for Advanced Macromolecular Design (CAMD)
¡ Scientific editor of the RSC journal Materials Horizon
¡ Associate editor: Beilstein Journal of Nanotechnology
¡ Member of the editorial board of the journals Macromolecular Bioscience, Macromolecular Rapid Communications, Biomacromolecules, Polymer Chemistry, Journal of Materials Chemistry B and Acta Biomaterialia
¡ Member:
ú Australian Research Council (ARC) College of Experts.
ú National Chemistry Committee of the Australian Academy of Science
ú Royal Australian Chemical Institute (RACI)
Research: ¡ New polymer materials for drug delivery
¡ Self-assembly of polymers into nano-objects such as cylindrical micelles, vesicles, spherical micelles and other structures
¡ Hollow nanoparticles for the delivery of proteins
¡ Nanoparticles with proteins or sugars to generate bioactive nanoparticles with high affinity for cancer cells
¡ Macromolecular ligands for metal complexes and their use in cancer therapy
¡ Polyion complex micelles for protein delivery
¡ Investigation into the interaction of nanoparticles with cancer cells in 2D and in 3D multicellular spheroids
A/Prof John Arron StrideBSc (Hons.) Ph.D. (Chemistry), University of East Anglia, UK
Professional Activities: ¡ UNSW AINSE Delegate
¡ ANSTO Neutron Program Advisory Committee
¡ Chair Australian Carbon Society
¡ School of Chemistry Honours Coordinator
Research: ¡ Molecular magnetism
¡ Nanostructured materials
¡ Molecular dynamics
¡ Photo-active devices
¡ Porous framework materials
Professor Martina Heide Stenzel A/Prof John Arron Stride
Academic Staff | 19
A/Prof Pall ThordarsonBSc. Chemistry, University of Iceland, PhD Chemistry USYD
Professional Activities: ¡ Co-chair 23rd IUPAC Conference on Physical Organic Chemistry (ICPOC23), Sydney 2016
¡ Editorial board member – Commissioning Editor, the Australian Journal of Chemistry.
¡ Chair, Scientific Advisory Board Member, Biomedical Imaging Facility, Mark Wainwright Analytical Centre, The University of New South Wales.
¡ Membership of the Royal Australian Chemical Institute, The American Chemical Society, The Royal Society of New South Wales, The Icelandic Chemical Society, Society of Porphyrins and Phthalocyanines (SPP), The Australian Microscopy and Microanalysis Society and the Marie Curie Fellowship Association
Research: ¡ Systems Chemistry
¡ Self-assembled gels for biomedical applications and electroactive displays.
¡ Biophysical chemistry and the supramolecular chemistry of proteins.
¡ Non-linear interactions in supramolecular chemistry
Professor Richard TilleyMChem Oxford, PhD Cambridge
Professional Activities: ¡ Member of the Advisory Board of the journal, Nature Publishing Group Asia Materials
¡ Member of the Advisory Board of the new Wiley journal, ChemPlusChem
Research: ¡ Electron microscopy and Nanoparticle synthesis and applications
A/Prof Pall Thordarson Professor Richard Tilley
20 | School of Chemistry Annual Report
A/Prof Chuan ZhaoPhD Northwest University
Professional Activities: ¡ Secretary and Chairman elected of Electrochemistry Division RACI
¡ Organizing committee member for 18th Australian Electrochemistry Conference (18AEC)
¡ Member Chartered Chemist of Royal Australian Chemistry Institute (RACI).
¡ Member of American Chemical Society (ACS).
¡ Member of International Electrochemistry Society
¡ Chairman of 4th Asia-Pacific Conference on Ionic Liquids and Green Processes and 6th Australasian Symposium on Ionic Liquids (APCIL-4/ASIL-6)
Research: ¡ Nanomaterials for electrochemical energy storage and conversion.
¡ Ionic liquid and applications for energy and sensors.
¡ Scanning electrochemical microscopy
¡ Sensors and bionics
A/Prof Chuan Zhao
Academic Staff Awards | 21
Academic Staff Awards
Dr William Alexander Donald
¡ Physical Chemistry Division Lectureship (RACI)
¡ Inaugural Michael Guilhaus Research Prize
(ANZSMS)
¡ Named “Emerging Investigator”, Analytical Methods
(Published by RSC)
¡ Named “Emerging Investigator”, Analyst (Published
by RSC)
Scientia Professor J. Justin Gooding
¡ Australian Research Council - Australian Laureate
Fellowship
¡ Listed in The Analytical Scientist magazine as one
of the top 100 most influential analytical scientists
worldwide for 2015
Dr Luke Hunter
¡ UNSW Vice-Chancellor’s Award for Excellence in
Teaching (Early Career Category)
¡ Tasmanian Alkaloids Lectureship, The University of
Tasmania
Professor Timothy Schmidt
¡ Broida Prize 2015
Associate Professor Chuan Zhao
¡ Australian Research Council - Australian Research
Fellow
22 | School of Chemistry Annual Report
Director’s ReportHighlightsInvited Seminar Speakers
Research
Director of Research Report | 23
Director of Research Report
The year 2015 will go down in the history of the School of Chemistry as possibly the best so far. This includes a record number of publications, outstanding performances in obtaining competitive external research grants plus a number of awards and recognition for the research achievement of our staff and students.
Grants:The School had its best ever year in the main ARC
grant round announced late last October with a total
of over $3.2M in new research grant founding to
the School! This included 7 ARC Discovery grants;
6 of them with the first named investigator (Beves,
Colbran, Donald, Kable, Stenzel and Zhao) coming
from our School as well as an ARC DECRA fellowship
to Dr. Neeraj Sharma. Consequently, the School was
ranked number two in the country and topped the
state of NSW in terms of new ARC Discovery funding
to begin in 2016. In addition, researchers from the
School were Chief Investigators on three ARC LIEF
grants worth $1,565,000 with Prof. Martina Stenzel
being a Chief Investigator on two of these. These
were not the only successes the School had within the
highly competitive ARC Schemes. Two ARC Linkage
grants totalling $743,470, awarded to Prof. Naresh
Kumar and Scientia Prof. Justin Gooding.
In June 2015, Scientia Prof. Gooding was also
awarded the highly prestigious ARC Laureate
Fellowship worth over $2.8 million over the next
5 years. This Fellowship is probably the single
largest grant the School has ever obtained and is
well-deserved recognition of Justin’s international
research leadership.
The School also broke new ground in NHMRC
funding. Scientia Prof. Gooding was one of four
applicants (with Professors Kavallaris, Davis and
Lock) on a successful NHMRC Program Grant
totalling $7,088,250. An estimated $1,500,000 will
come to the School from this Program grant over
the next 5 years. Dr. Adam Martin, a Post-doctoral
Fellow in the School, also obtained one of the newly
established NHMRC-ARC Dementia Fellowships
worth $594,644.
The School also did very well in internal research
grant schemes with 2 VC Fellowships; Dr. Chen
Sheng (mentor: A/Prof. Chuan Zhao) and Dr. Robert
Chapman (mentor: Prof. Martina Stenzel) and two
MREII grants to Dr. (William) Alex Donald and Prof.
Timothy Schmidt plus over $160k in UNSW Faculty of
Science CAPEX funding for a new FT-IR spectroscopy
facility.
Accolades to our staff:Externally, our staff also received a number of
accolades:
¡ Dr. William Alex Donald was the inaugural winner
of the Michael Guilhaus Research Award from
the Australian and New Zealand Society for Mass
Spectrometry (ANZMS).
¡ Prof. Timothy Schmidt won the Broida prize at the
33rd International Symposia on Free Radicals.
¡ Scientia Prof. Justin Gooding was appointed as the
inaugural Editor-in-Chief of the new journal ACS
Sensor, and to our best of our knowledge, Justin is
the first Australian to be appointed as an Editor-in-
Chief at an ACS journal.
¡ A/Prof. Pall Thordarson was appointed to the ARC
College of Experts for the next 3 years.
Associate Professor PALL THORDARSON
Director of Research
24 | School of Chemistry Annual Report
Director of Research Report | 25
Student prizes: ¡ Not to be outdone by our staff, our
students keep also winning prizes
with Christian Gunawan (Zhao group)
winning both a Poster Prize and a Prize
for best PhD Student Oral Presentation
at the 66th Annual Meeting of the
International Society of Electrochemistry
in Taipei, Taiwan. At the 36th Annual
One-Day Symposium of the Royal
Australian Chemical Institute, NSW
Organic Chemistry Group, Elysha Taylor
was awarded the Best Poster prize and
Joana Da Rocha was awarded the Best
Poster in Chemical Biology, capping off
an excellent year for our students.
Publications:The number of papers from the School
of Chemistry continued to rise in 2015
with a total of 225 publications, including
209 journal articles – representing more
than a 16% increase from the previous
record in 2014. What is more, we had
a healthy number of papers published
in prestigious journals such as the
Journal of the American Chemical
Society, Angewandte Chemie, Chemical
Science and two Nature Communications
publications; one from A/Prof. Chuan Zhao
and co-workers and one from Dr. Yuanhui
Zheng and Scientia Prof. Justin Gooding.
Outlook:The start of 2015 again saw record
breaking PhD numbers and with the
bumper-harvest of grants outlined above,
the School appears to be on a continuing
growth trajectory for the next couple
of years. This means that our biggest
challenge has become space as we are
really struggling to fit any more people into
our laboratories and offices. Thankfully
it appears that the University will assist
with our problems on this front fairly
soon. Following a visit to the School from
our new VC, Prof. Ian Jacobs, in March
2015 he had a firsthand opportunity to
see how vibrant our research is, but also
how our space situation is starting to
have a significant effect on any future
growth. Under the VC’s leadership,
UNSW formulated an ambitious 10-year
strategy – the 2025 strategy. Central to this
new strategy are new research facilities
and as 2015 came to an end, UNSW
approved the new $200 million Science
and Engineering Building (SEB), which will
be connected to the new Hilmer Building
(formerly known as the Material Science
and Engineering Building). Plans are not
finalised for the new SEB building, but it
is now all but certain that the School of
Chemistry will be allocated space in the
SEB which is scheduled to open in 2019.
26 | School of Chemistry Annual Report
Dr. Vinh NguyenDr. Vinh Nguyen started his study in industrial chemistry at University of New South Wales in 2002. He then moved to undertake his PhD in organic chemistry at the Australian National University, Canberra in 2006. After travelling to Germany and Perth (WA), he moved back to UNSW in June 2015 to establish his new research group. His current research interests are organocatalysis and synthesis of naturally occurring and bioactive compounds.
Research Highlights
DR. VINH NGUYEN
Organocatalytic chemistryThe Nguyen group focuses on the development of
novel organocatalytic methods. Organocatalysis,
chemical process catalyzed by small non-metallic
organic compounds, has been attracting a great
deal of attention from synthetic organic chemists for
the last fifteen years as one of the most promising
emerging fields in organic chemistry. It can be
employed in diverse synthetic cascade sequences
to quickly construct complex bonds, stereocenters
and polycyclic frameworks. Organocatalysts are less
expensive, more stable and exhibit superior solubility
in both organic and aqueous solutions compared
to organometallic/bioorganic counterparts. Most
importantly, organocatalysis generally gives rise to
outstanding stereoselectivity, which is significantly
valuable and useful at the structural engineering stage
of bioactive compounds and pharmaceutical agents.
Research Highlights | 27
Organocatalytic chemistry by N-Heterocyclic Olefins (NHOs)The Nguyen group is one of a few groups establishing this
very topical emerging research field. In recent decades,
N-heterocyclic carbenes have become established as a
prevalent family of organocatalysts. N-Heterocyclic olefins,
the alkylidene derivatives of N-heterocyclic carbenes,
have recently also emerged as efficient promoters for
organic reactions. Their extraordinarily strong Lewis/
Brønsted basicity suggests great potential as a new class of
organocatalysts for a broad range of reactions in synthetic
chemistry such as the transesterification reaction or the
phase-transfer alkylation reaction. The NHO-promoted
transesterification can potentially be the practical solution for
recycling PET plastic in a chemical pathway as opposed to
the currently used mechanical or physical processes.
Organocatalytic chemistry by aromatic cation activationThe Nguyen group is one of the first few groups utilizing non-benzenoid aromatic ions to promote organic reactions. A new method for the nucleophilic substitution of alcohols and carboxylic acids and other substrates using aromatic tropylium cation activation has been developed in our group recently. It demonstrates, for the first time, the synthetic potential of tropylium cations in promoting chemical transformations.
Tropylium salts can be further utilized for a much broader range of applications such as Lewis acid organocatalysts, anion sensing systems, clean and efficient oxidants or chromophores in organic dyes and luminescent compounds. On the latter, our group has been able to attach tropylium moiety on biologically active frameworks to create electron push-and-pull systems, which can interconvertibly absorb light in the visible or UV range. These systems are potentially capable of combining with active functional groups commonly found in living organisms to ‘stain’ them for bio-imaging applications.
More information on the Nguyen group can be found at: https://tvnguyengroup.wordpress.com/
28 | School of Chemistry Annual Report
School Seminars 2015 – Invited Speakers
Dr Ivana EvansDurham University
Prof. Juliet Gerrard - Jeffrey LectureUniversity of Auckland
Pat UnwinUniversity of Warwick
Prof. Alexandre Shvartsburg Wichita State University
Dr Chiara MilaneseUniversity of Pavia
Prof Andrew WellerUniversity of Oxford
Prof. Erkki Lahderanta - Lappeenranta University of Technology, Finland
A/Prof MaryKay Orgill - Mellor LectureUniversity of Nevada
Ernst Peter KundigUniversity of Geneva
A/Prof John McMurtrieQueensland University of Technology
Dr Patrick HowlettDeakin University
Dr Guohua JiaCurtin University
Peter MacLeodBayer Crop Science
Prof Alison ButlerUniversity of California, Santa Barbara
Dr Keith StubbsUniversity of Western Australia
Dr Fred PfefferDeakin University
Dr. Scott Cohen Children’s Medical Research Institute, University of Sydney
Dr Christopher RichardsonUniversity of Wollongong
Prof Marisa KozlowskiUniversity of Pennsylvania
Dr Chenghua SunMonash University
Prof. Brendan KennedyUniversity of Sydney
Dr Sally PlushUniversity of South Australia
Dr Huynh Thien Ngo National Institute for Materials Science, Japan
Dr Joanna WlochalAstraZeneca
Prof M. G. Finn - Howard LectureGeorgia Institute of Technology
A/Prof Christian DoonanUniversity of Adelaide
Prof Mark Ogden Curtin University
Prof Stephen BlanksbyQueensland University of Technology
Prof. John EvansDurham University
Dr Jason Price Australian Synchrotron
Dr. James D. CrowleyUniversity of Otago
A/Prof Adam TrevittUniversity of Wollongong
Dr Evan MooreUniversity of Queensland
Dr Bridget L. Stocker & Dr Mattie S. M. Timmer University of Wellington
Dr Gail Iles
ANSTO
Dr Masahiro FujitaSophia University, Japan
Dr Santosh RudrawarSydney University
Prof Helen Blackwell – Cavill LectureUniversity of Wisconsin-Madison
Prof Jonathan WhiteUniversity of Melbourne
Prof Guillaume LesseneThe Walter and Eliza Hall Institute
Prof Carl SchiesserUniversity of Melbourne
A/Prof Yu BaiPeking University
Prof. Ebbe NordlanderLund University
Stefania G. BaldurdottirCopenhagen University
Prof Christine McKenzieSyddansk University
School Seminars 2015 – Invited Speakers | 29
30 | School of Chemistry Annual Report
Director’s ReportFirst Year ChemistryHonours ProgramPostgraduate SeminarsPostgraduate ResearchOutreach ActivitiesDegrees Awarded Research Completions UNSW Chemical Society
Teaching
Director of Teaching Report | 31
Director of Teaching Report
The School’s recent growth has continued through 2015, with strong enrolments in first year and sustained numbers continuing on through our higher year courses, including the honours research year.
Our specialist programmes in Medicinal
Chemistry and Nanotechnology continue
to attract students though changes are
underway, particularly in the latter, in order
to increase these numbers further.
Of particular note in 2015 was the rollout
of skills based assessment across the
laboratory portion of our core first year
chemistry courses. Trialled in 2014
through funding of a UNSW Learning and
Teaching Grant (A/Prof. Steve Colbran,
Dr. Ron Haines, Dr. Luke Hunter and Prof.
Scott Kable), this new way to assess
students in the chemical laboratory
focuses, as the name suggests, on
developing a set of skills which can be
transferred between disciplines and
built on as students progress in their
degree. Everyone involved should
be congratulated on this significant
redevelopment, from those who proposed
the initial idea, through to those that had
to lay out the framework and develop
the infrastructure, and to all of the
staff and students responsible for its
implementation on the very large scale
that was needed. Into the future, there
is the potential to develop this concept
further and apply it to our higher year
teaching lab.
Any such changes will go hand in hand
with development of our curricula in
the courses targeted at students in the
second and third year of their degree
programmes. With changing demands
from students (both chemistry majors and
not), a change in the staffing profile of
the School and the continually developing
nature of chemistry, a continual challenge
for the School is keep our course offerings
fresh. 2015 saw significant developments
on this front, starting at the School
Teaching retreat and continuing with
significant amounts of work being done by
the Teaching Committee on evaluating our
higher year courses. It is anticipated that
this process will move forward in 2016,
with the aim of rolling out the first round of
modified courses in 2017.
As some things develop, some others
come to an end. The Chemical Analysis
and Laboratory Management (CALM)
postgraduate coursework programme was
run for the last time in 2015. For many
years this was a flagship programme
in the School, but changing demands
from students and changes in School
personnel led to it being discontinued.
Everyone involved over its very long
history should be rightly proud of CALMs
long-term contribution to the School.
Finally, as incoming Director of Teaching
I would like to thank my predecessor,
Dr Gavin Edwards, who also continues
on as Deputy Director of Teaching
(along with his role as Associate Dean
(Undergraduate Programmes) in the
Faculty of Science). Gavin has negotiated
the twists and turns of this position
over the last eight years - including
the burgeoning student numbers and
resultant effects on term planning! -
and has always done so with levels of
organisation and good humour I can only
hope to emulate.
DR. JASON B. HARPERDirector of Teaching
32 | School of Chemistry Annual Report
First Year Chemsitry
Enrolments in First Year Chemistry were substantially higher in 2015 across all courses compared to the year before (except for summer semester which remained steady).
DR. LUKE HUNTER1st Year Coordinator
Most importantly, we implemented a
completely new model of First Year
Laboratory assessment. The demonstrators
now assess students in real time on
their physical skills as well as on their
understanding of chemistry theory. Under
the new model, all students must acquire
a complete set of “core” skills in order to
pass the course. This will have a knock-on
benefit in higher year chemistry courses,
because all students will from now on
have a common, well-defined minimum
package of laboratory skills. This project
was enabled by a $200K UNSW Strategic
Educational Development Grant. The rollout
of this new assessment model has been
very successful, and we have some big
ideas about where to go next (e.g. skills
assessment in higher year courses; a similar
concept of “core” knowledge for the lecture
component of First Year Chemistry).
We also rolled out a new initiative in
online teaching. Students in the course
CHEM1831 were required to complete
an online “Lecture Prep” activity once
per week, before the week’s lectures
started. The idea was to bring all students
up to a common minimum standard of
assumed knowledge, so that they would
subsequently get more out of their
lectures. This project was enabled by
a $25K UNSW Learning and Teaching
Innovation Grant. The rollout was very
successful in terms of both student
engagement and student learning, and
the “Lecture Prep” activities are now being
deployed in other First Year Chemistry
courses.
In 2015 we also laid the groundwork
for two more teaching innovations. We
secured a $20K UNSW Learning and
Teaching Innovation Grant to create a
suite of new lecture demonstrations; and
we devised an ambitious new project to
implement a threshold/mastery model
of lecture assessment (analogous to the
laboratory core/non-core assessment).
As always, it’s a team effort. I’d like to say
a very big thank you to all of the staff who
contributed to the teaching innovations
mentioned above (especially Anna Choy,
Steve Colbran, Ron Haines, Samantha
Furfari, Scott Kable, Scott Sulway and
Steve Yannoulatos), plus the staff at Smart
Sparrow, plus the army of lecturers, tutors,
demonstrators, lab tech staff and admin
staff who keep everything humming in
First Year Chemistry.
As well as these big enrolment numbers, 2015 was a huge year for First Year Chemistry in terms of teaching innovations.
Session one
Session two
Session three
CHEM1001 81
CHEM1011 542
CHEM1031 520
CHEM1051 26
CHEM1151 30
CHEM1831 109
CHEM1011 379
CHEM1021 386
CHEM1041 224
CHEM1061 20
CHEM1829 110
CHEM1021 79
Honours Program | 33
Honours Program
The term ‘Honours Program’ in the School of Chemistry covers several UNSW undergraduate Programs.
Our Honours cohort includes students
enrolled in the (i) Bachelor of Science
majoring in Chemistry, (ii) the Bachelor
of Advanced Science majoring in
Chemistry, (iii) the Bachelor of Science in
Medicinal Chemistry, and (iv) the Bachelor
of Science in Nanoscience. Students from
several other degree programs, such as
the Bachelor of Environmental Science
majoring in Chemistry, may also enroll in
the Bachelor of Science program majoring
in Chemistry.
In the first two ‘chemistry’ focused
degrees, students undertake their entire
fourth year in the School of Chemistry.
This comprises a research project
in collaboration with a member of the
academic staff and contemporary
chemistry courses delivered by
formal lectures. In the ‘medicinal
chemistry’ focused degree, students
follow the above but also have a greater
interaction with academic staff in the
Pharmacology section of the School of
Medical Sciences, including collaborative
projects.
The BSc Nanoscience students undertake
a research project that represents
just over 80% of their final year. This is
carried out in the School of Chemistry,
the School of Physics and/or the School
of Materials Science and Engineering,
and is supplemented by a number of
undergraduate courses taught by these
three Schools.
In 2015, sixteen (16) students completed
Honours through the Bachelor of Science
and Advanced Science BSc Programs,
fourteen (14) completed Honours through
the Bachelor of Medicinal Chemistry,
with a further three beginning Honours in
July 2015. Three (3) students completed
their Bachelor of Science in Nanoscience
with research projects in the School of
Chemistry.
Ena Luis (BSc Adv. Sci.) received
a University Medal for outstanding
performance across her degree program.
Ena Luis was also awarded the Angyal
Prize for the best performance in a
Chemistry Honours thesis and Edward
Stephens received the CETEC Prize for the
best performance in a Chemistry Honours
thesis having an environmental impact.
Associate Professor JOHN STRIDE
Honours Coordinator
34 | School of Chemistry Annual Report
Postgraduate Seminars
The Postgraduate Seminar Programme continued to thrive and remained an integral part of the School monitoring and mentoring system.
The School has enjoyed seminar presentations from postgraduate
research students finishing the induction phase, mid-candidature
and completing stages of their programme. They are held
Tuesday lunchtimes and are well attended by all members of
the School. The range of topics covered in the seminars was
impressive and of a very high standard. A panel of academic
staff assessed each presentation and individual feedback was
given to each student.
Postgraduate Research | 35
Postgraduate Research
Postgraduate research (HDR) student enrolments continue to grow rapidly in 2015, with 40 new HDR students enrolled over both the sessions.
By the end of 2015, the School had 118
PhD, MSc and MPhil actively enrolled. In
addition, 10 students have submitted their
thesis waiting for their results.
We have seen a further increase in
completions with 38 students having been
awarded their degree in 2015. This is a
significant jump from the 13 students that
graduated in 2014. The school growth is
also reflected by the increasing number
of new students. In 2015, we saw 48 new
postgrad students enrolling in the school
of chemistry. The number of students
therefore increased steadily over the last
few years as depicted in the Figure below.
As of Nov. 2015, the school had only two
overtime (>4 years) enrolment thanks
to intensive student management and
guidance.
Overall, the growth of student numbers
and the high completion rate below 4
years in combination with the increasing
amount of high quality research papers
generated from our postgraduate students
highlight bright future for the school of
chemistry as a place for top postgraduate
education.
Post
grad
uate
stu
dent
s
Semester
10
5
10
15
20
25
30
35
2 3 4 5 6 7 8 9 10
Figure: Number of postgraduate students
vs the numbers of semesters enrolled.
36 | School of Chemistry Annual Report
Outreach Activities
The School of Chemistry outreach program was established in 2007 to foster stronger links with high schools and to stimulate an interest in science and technology in high school students. The School has been busy in organizing a variety of programs to foster stronger links with high schools and to market the School of Chemistry programs to prospective students.
School visitsThe School of Chemistry has been very
active in hosting visits from various high
schools near and far in the past year. The
School hosted visits from Orange High
School, St Aloysius’ College and Sydney
Boys High School Year 12 students. The
students thoroughly enjoyed the visit
and the feedback from the schools has
been extremely positive. In particular the
students enjoyed working in real chemistry
laboratories and undertaking experiments
relevant to the HSC syllabus. The School
also hosted visits from Year 10 students
form De La Salle Catholic School and
Year 9 students St Aloysius’ College.
Furthermore, Prof Martina Stenzel gave
a presentation at the North Sydney Girls
High School Careers Day.
Presentation at the Science Teachers’ Association of NSW (STANSW) Chemistry ConferenceThe School has continued to maintain
strong links with the Science Teachers’
Association of NSW (STANSW)
giving a presentation on “Chemistry
Demonstrations” at the STANSW
Chemistry Teachers Conference on 12
June 2015. Sixty high school teachers
attended the chemistry workshop and
the presentation covered chemistry
demonstrations to enhance teaching of
Stage 4 and 5 chemical concepts as
well as Stage 6 chemistry, and included
demonstrations of combustion, acid-base
and redox chemistry as well as chemical
equilibria.
Participation in the Australian Museum Science Festival and Aspire Building on Bridges to Higher EducationThe School took an active part in the
Australian Museum Science Festival,
which ran over two weeks from 11-20
August, and also participated in a two
day Building on Bridges conference for
Year 10 students. These events promote
science and encourage the high school
students in pursuit of higher education.
UNSW School of Chemistry’s visit to DubboOn 8th–9th October, Dr. Luke Hunter,
Yuvixza Salas, Jeanette McConnell and
Mehran Kashi were in Dubbo as part of
the Australian Museum’s Science Festival.
Over the two days they ran a series of
workshops and an expo booth, interacting
with hundreds of primary and secondary
school students from the Dubbo region.
The event was covered in the local press
(newspaper and TV), and it hopefully
inspired a new generation of chemists to
come and study at UNSW! The Chemistry
Road Show to Dubbo was a great
success.
RACI NSW National Titration CompetitionThe School hosted the NSW division of the
RACI National Titration Competition on 12
September. Teams of high school students
from 23 schools competed in the event.
This was a great opportunity to showcase
our teaching facilities to the students.
This competition is an important outreach
activity for the School, and an important
RACI activity. Although there were no
perfect scores on the day, there were 24
individual Gold scores, with the remainder
achieving Silver scores.
PROFESSOR NARESH KUMAROutreach Coordinator
Outreach Activities | 37
Participation in the outreach programs organised by the Faculty of Science
UNSW Science and Engineering Parent and Student NightThe School actively participated in
this highly successful event, and
answered a number of queries from
year 11 and year 12 students keen to
do science at the university level.
Nura Gili Winter Schools Program A number of indigenous high school
students took part in the Science
stream of this program, undertaking
some chemistry experiments and
taking a tour of the chemistry building.
The students thoroughly enjoyed the
day and found it highly educating.
Science High School Information DayThe objectives of the UNSW Science
Information Day is to entice potential
students to UNSW by showcasing
the range of different Science
experiences available through
lectures and hands-on activities in
laboratories. The School oranised
hand-on chemistry activities and
presented a short talk on options for
studying chemistry at UNSW for the
visiting students.
Republic Polytechnic VisitThe School hosted a visit from
Republic Polytechnic students
sharing with them the study
prospects and research opportunities
in our School.
UNSW Open Day 2015The School actively participated in
the UNSW Open Day 2015, with
academics stationed at the Scientia
Advisory Centre to answer questions
regarding the chemistry programs.
Two presentations on “Chemistry – A
Diverse and Expanding Science” were
delivered, and seminars on “Medicinal
Chemistry” and “Nanoscience”
attracted significant interest. An
army of our postgraduate students
ambushed passing high school
students at the chemistry marquee,
which hosted a variety of new and old
favourite demonstrations which had
our visitors captivated. Overall the
event was a resounding success and
there was a lot of interest in Chemistry,
Medicinal Chemistry and Nanoscience.
Hosting work experience studentsThis year the School of Chemistry
hosted 5 work experience students
from 23-27 November who
worked under the supervision of
postgraduate mentors, experiencing
first-hand the joys and thrills of
research. The feedback from the
students was really positive.
Top left: Honorary Associate Professor Roger Read (RACI NSW Branch President), Mr. Steve Yannoulatos (School of Chemistry), Professor Naresh Kumar (School of Chemistry).
Two of the winning student groups at the RACI NSW National Titration Competition
38 | School of Chemistry Annual Report
Degrees Awarded 2015
Graduate Certificate in Chemical Analysis and Laboratory Management (Program 7428 / 7429)
¡ Warda Kamal
¡ Pauline Michaels
¡ Kaixian Zhu
Master of Science and Technology in Chemical Analysis and Laboratory Management (MSc Tech, Program 8708)
¡ May Abu Muti
¡ Pankaj Barai
¡ Ahlam Alenazi
¡ Zhi Hao Chan
¡ Ibrahim Alnashari
¡ Jo-Anne Collins
¡ Hamoud Alnazzal
¡ Pragna Gaur
¡ Raaid Alosaimy
¡ Brendan Sellors
¡ Fahd Althebyani
¡ Gina Valentin Avellaneda
Master of Science by Research (Program MSc 2910 & MPhil 2475)
Candidate Research Area Supervisor
Lachlan Carter Nanoparticle-mediated electrochemical gating: application to electroanalysis Scientia Prof. Justin Gooding
Genevieve Duche Supramolecular chemistry & nanomaterials A/Prof. Pall Thordarson
Chao Shen Novel transition metal containing supramolecular assemblies Dr Jon Beves
Mengchen Ge Ionic Liquids-Based Gas Sensor Dr Chuan Zhao
Yuvixza Lizarme Salas Medicinal Chemistry: towards a treatment for stroke Dr Luke Hunter
Worawan Tantisantison Synthesis of Sanguinamide B derivatives: SAR and mechanism of action A/Prof. Shelli McAlpine
Ran Xu Photochemistry of Organic Reactive Intermediates Monitored with NMR Spectroscopy Dr Graham Ball
Hassan Abdullah Alzahrani
Thermoelectrochemical cells for waste heat harvesting Dr Leigh Aldous
Changlong XiaoNon-Precious Metal-Based Mesoporous Electrocatalysts for Enhanced Oxygen Evolution Reactions
A/Prof Chuan Zhao
Jonatan Wangsahardja Fluorinated amino acids Dr Luke Hunter
Degrees Awarded 2015 | 39
Doctor of Philosophy (Ph. D, Program 1870)
Candidate Research Area Supervisor
Md. Iqbal AhmedConformational fine-tuning of cyclic peptides: an approach for improving peptide cyclisation and biological
Dr Luke Hunter
Xin Chen Nanoparticles for sensing Scientia Prof. Justin Gooding
Xiaoyu (JET) CHENG Silicon luminescent nanoparticles Scientia Prof. Justin Gooding
Moinul Haque Choudoury Nanoparticle modified electrodes Scientia Prof. Justin Gooding
Kyloon Chuah Nanoparticle – nanopore sensors Scientia Prof. Justin Gooding
Michelle Dunn Carbenes in Ionic liquidsA/Prof. Marcus Cole & Dr Jason Harper
Mark Gatus Design of Multimetallic Complexes for C-X Bond Formation Prof. Barbara Messerle
Stephen George Ionic liquids Dr Jason Harper
Joshua Ginges Immuno-biosensors Scientia Prof. Justin Gooding
Seong Kim Synthesis of macrocyclic peptides A/Prof. Shelli McAlpine
Ethan HOWE Supramolecular chemistry and self-assemble A/Prof. Pall Thordarson
Md Amuiril Islam Exploring Bio-active Natural Products as Potential Therapeutics Leads A/Prof Shelli McAlpine
Xunyu (Rain) LU Nanomechanic and nanoparticle based sensors A/Prof Chuan Zhao
Elizabeth MURAGO Analytical chemistry of oils Scienta Prof Justin Gooding
Duc Thanh N-Glyoxylamides as versatile precursors for peptide mimics and heterocycles Prof Naresh Kumar
Hamish TOOPDevelopment of Synthetic Protocols for Application in the Syntheses of Biologically Interesting Molecules
A/Prof. Jonathan Morris
Roya TAVALLAIETowards the biomedical applications of gold coated magnetic nanoparticles: Detection of serum circulating MicroRNAs as cancer markers
Scientia Prof. Justin Gooding
Fatemeh MIRNAJAFI ZADEH Investigations into quantum dots A/Prof. John Stride
Camille HoltObservation of Cationic Transition Metal-Alkane Complexes with Moderate Stability in Hydrofluorocarbon Solution
Dr Graham Ball
Matthew GytonThe coordination chemistry of stericallly femanding amido ligands with the lanthanides
A/Prof Marcus Cole
Alasdair McKay The synthesis of kinetically stabilised heavy group 13 hydride complexes A/Prof Marcus Cole
Raju CheerlavanchaSynthesis of homologated amino acid derivatives containing three vicinal fluorine atoms placed stereospecifically along the backbone
Dr Luke Hunter
Ika-Wiani HidayatDefining protocols for the synthesis of 3-substituted -5-benzylideneimidazolidine-2,4,diones
A/Prof Roger Read
Marcin MielczarekIndoles as novel antibacterial agents and versatile precursors of complex heterocyclic structures
Prof David Black
Stephen Parker Single-Cell Isolation Using Light-Activated Electrochemically-Switchable Surfaces Prof Justin Gooding
Alexander Weremfo Electrochemically-roughened platinum electrode: Application for neural stimulation A/Prof Chuan Zhao
Christopher Gardiner Novel Retinoid Enhances for Anti-Cancer Therapies Prof Naresh Kumar
Jeanette McConnellSynthesis, characterisation, and biological evaluation of Hsp90 inhibitors as anticancer therapeutics
A/Prof Shelli McAlpine
40 | School of Chemistry Annual Report
Postgraduate Research Completions
These students have had their thesis examined and will graduate in 2016
Master of Science by Research (Program MSc 2910 & MPhil Program 2475)
Candidate Research Area Supervisor
YeeYee Khine Dual-Responsive pH and temperature sensitive micelles for triggered release of drugs Prof Martina Stenzel
Doctor of Philosophy (Ph. D, Program 1870)
Candidate Research Area Supervisor
Nripenda Biswas Novel Small Molecules for Modulation of Bacterial Signaling Pathways Prof Naresh Kumar
Veronica Tecchio Development of Heterocyclic Scaffolds as Inhibitors of Splicing Kinases A/Prof Jonathan Morris
Sandra ChoyBimetallic rhodium complexes for various catalysed C-X bond formation reactions: Synthesis, and investigation of structure and mechanism using experimental and computational methods
Prof Barbara Messerles
Asim KhanTuning the electrodes and electrolytes towards efficient oxygen reduction for applications in fuel cells and metal-air batteries
A/Prof Chuan Zhao
Ekaterina Nam Surface-bound Light-activated Redox Enzyme Cascades A/Prof Pall Thordarson
Bradley James Butler Solvent effects of ionic liquids on a reaction at a phosphorus centre Dr Jason Harper
Xun Lu Super-resolution Fluorescence microscopy for Surface Characterisation Prof Justin Gooding
Md Mokarrom Hossain Ionic Liquids and Electrochemical approaches to Lignocellulosic Biomass Processing Dr Leigh Aldous
Xinyang Wei
UNSW Chemical Society | 41
UNSW Chemical Society
The UNSW Chemical Society assists in the organisation of the School Seminar Series, a weekly program of talks from distinguished academics around Australia and the world. In addition the society organises a number of prestigious, endowed lectureships each year, and in 2015 it played host to the following Lecture series.
The Howard Lectures,
May 2015
The Jeffrey Lectures, July 2015
The Mellor Lecture,
August 2015
The Cavill Lecture,
November 2015
PROF. M. G. FINN Georgia Institute of Technology
Lecture 1: Reliable and Reversible Molecular Linkages forChemical Biology
Lecture 2: Chemistry Returns Home: Developmentand Applications to
Materials Science
PROF. JULIET GERRARD University of Auckland
Lecture 1: Quaternary structure of proteins: evolutionary happenstance or a higher level of structure-function relationships that opens new avenues in drug design?”
Lecture 2: Quaternary structure of proteins: Assembling protein building blocks for use in nanotechnology
Lecture 3: Protein nanotechnology: approaches to generating useful
nanomaterials using protein nanostructures
A/PROF MARYKAY ORGILL Univeristy of Nevada
Do they see what we see? Developing chemistry students‚ Äô representational
competence
PROF HELEN BLACKWELL University of Wisconsin-Madison
Synthetic ligands for the interception of bacterial communication
42 | School of Chemistry Annual Report
Undergraduate Student PrizesPostgraduate Student Awards and PrizesConference Presentations Conference PostersUndergraduate & Postgraduate EnrolmentsStudents of Chemistry Society - SOCS
Students
Undergraduate Student Prizes | 43
The Angyal PrizeBest performance in Honours Chemistry
Ena Thea Luis
The CETEC PrizeBest performance in Honours Thesis
Edward Richard Neason Stephens
The Du Pont PrizeBest performance in BSc 3 Year Degree in Chemistry
Overall “TOP” of Chemistry
Deng Lin
The Cowper Prize and School Medal for best performance in Level 3 Chemistry
Jack Wade Duncan
The Cavill PrizeBest performance in Level 3 Medicinal Chemistry
Jack Wade Duncan
The RACI Analytical Chemistry Group PrizeBest performance in Level 3 Analytical Chemistry
Eric Dylan Benjamin Foley
The Inglis Hudson and Jeffery BequestsBest performance in Level 3 Organic Chemistry
Tsz Tin Yu
The University of New South Wales Chemical Society Dwyer PrizeBest performance in Level 3 Inorganic Chemistry
Surabhi Naik
The Bosworth Prize and Medal for best performance in Level 3 Physical Chemistry
Amy Joyce Geddes
The University of New South Wales Chemical Society Parke-Pope PrizeMeritorious performance in Level 3 Chemistry Courses
Surabhi Naik
Undergraduate Student Prizes
Third Year Prize Winners
Honours Prize Winners
44 | School of Chemistry Annual Report
The School of Chemistry Prize and School Medal for best performance in Level 2 Chemistry
Eric Dylan Benjamin FoleyThe University of New South Wales Chemical Society George Wright PrizeMeritorious performance in Level 2 Chemistry Courses
Bryan Yuk-Wah Tang
The June Griffith Memorial Prize and School Medal for best performance in Level 1 Chemistry
Thomas Zhou
The University of New South Wales Chemical Society PrizeMeritorious performance in Level 1 Chemistry Courses
Ian Neville Powell
The School of Chemistry PrizeFor Excellence and Enthusiasm in Chemistry for Year 10 students
Jacqueline Lim
Don Craig Memorial PrizeFor excellence in research using X-ray crystallography
Hasti Iranmanesh
Paddon-Row Scholarship For the highest ranked commencing local PhD student
Janina Miriam Noy
Black Scholarship For the highest ranked commencing international PhD student
Sanjun Fan
Teaching Fellowship HoldersJeffrey Black, Laura Buckton, James Christian, Kelvin Lee, Anthony Leverett, James McPherson, Catherine Onie, Jonathon Ryan Kieran Rowell and Chin Min Wong
Postgraduate Prizes, Scholarships
and Fellowships
First Year Prize Winners
Year 10 Prize Winner
Second Year Prize Winners
Undergraduate Student Prizes | 45
Prize winners 2015
46 | School of Chemistry Annual Report
Postgraduate Student Awards and Prizes
1st NSW Ionic Liquid Group One Day Symposium
¡ Sinead Keaveney (Superviosrs, Drs
Jason Harper & Ron Haines), Best
presentation senior Ph.D. student, “Ionic
liquid effects on SN1 reactions: the
importance of charge delocalisation”
¡ Rebecca Hawker (Superviosrs, Drs
Jason Harper & Ron Haines), Best
presentation 1st year Ph.D. student
“Rational selection of the cation of
an ionic liquid solvent to control the
outcome of an SN2 reaction”
6th International Nanomedicine Conference
¡ Roya Tavallaie, (Supervisor, Scientia
Professor Justin Gooding), Poster
Presentation Prize “The impact of
surface chemistry on microRNA
recognition interfaces”
9th Australasian Organometallics Meeting
¡ Lida Ezzedinloo (Supervisor A/Prof.
Steve Colbran), Poster Presentation
Prize, Session 1 “Organo-transition
metal complexes for electrocatalytic
reduction of carbon dioxide”
¡ Matthew Mudge (Supervisor A/Prof.
Steve Colbran), Poster Presentation
Prize, Session 1 “A Dixanthene Scaffold
for Cooperative Catalysis”
¡ Kai N. Buys (Supervisor; A/Prof. Marcus
Cole), Poster Presentation Prize, “Using
Pincer Ligands to Study s- and p-Block
Halides and Hydrides”
25th ANZSMS Conference & 6th Asia Oceania Mass Spectrometry Conference
¡ Michael Leeming (Uni Melbourne) (Co-
Supervisor Dr William Alex Donald) Best
Student Talk “Non-targeted detection of
drug metabolites using high-resolution
twin-ion metabolite extraction mass
spectrometry: from small molecules to
protein conjugates
66th Annual Meeting of the International Society of Electrochemistry
¡ Christian Gunawan (Supervisor: A/Prof
Chuan Zhao) Poster Prize: “Scanning
Electrochemical Microscopy of
Switchable Redox Enzyme Cascade”
Association of Molecular Modellers of Australasia (AMMA)
¡ Keiran Rowell (Supervisor; Dr. Graham
Ball), Best undergraduate/Honours
Poster, “Computational Studies of the
Neighbour Exclusion effect in DNA
intercalators”
Australian X-ray Analytical Association Student Conference
¡ James Christian (Superviosr: Dr Neeraj
Sharma) Winner – Best PhD student
presentation.
Chinese Scholarship Council
¡ Xiaoyu Cheng, (Supervisor, Scientia
Professor Justin Gooding), 2015
National Award for Outstanding Self-
financed Chinese Students Study
Abroad.
Royal Australian Chemical Institute (RACI)
¡ Joana Da Rocha (Supervisor: A/
Prof Jonathan Morris), Best poster in
Chemical Biology – One-Day Organic
Chemistry Symposium.
¡ Elysha Taylor (Supervisor: A/Prof
Jonathan Morris), Best poster, One-Day
Organic Chemistry Symposium.
¡ Aditi Taunk (Supervisor; Professor
Naresh Kumar), Poster prize, RACI
Medicinal Chemistry and Chemical
Biology NSW Symposium
Royal Society of New South Wales
¡ Dr. Stephen Parker (Supervisor, Scientia
Professor Justin Gooding), 2015
Scholarship
AMMA Molecular Modelling Conference
¡ Gabriella Marcolin (Supervisor: Dr. Luke
Hunter), Winner of the 1-minute thesis
talk
Postgraduate Student Awards and Prizes | 47
School of Chemistry – Research Poster Prizes
The four School Poster Prizes were
awarded to:
¡ Catalysis Cluster (John Morris Prize):
Demelza Lyons (Supervisor, Dr. Vinh
Nguyen) “Tropylium Salts as Coupling
Reagents”
¡ Energy Cluster (Bruker Prize): Bryan
Suryanto (Supervisor: A/Prof Chuan
Zhao) “Nanostructured earth-abundant
electrocatalysts for water splitting”.
¡ Medicinal Chemistry Cluster (Sigma
Aldrich Prize): Catherine Au (Supervisor,
Dr. Luke Hunter) “Fluorination of
4-guanidinobutanoic acid: effects on
molecular conformation and bioactivity”
¡ Nanoscience Cluster (Bruker Prize):
Manish Sriram (Supervisor, Scientia
Professor Justin Gooding) “Towards
single particle plasmonic core-satellites
for digital biosensing”
Demelza Lyons Bryan Suryanto
Catherine Au Manish Sriram
48 | School of Chemistry Annual Report
Student Conference Presentations 2015
249th American Chemical Society National Meeting, Denver, Colorado, USA, 22nd – 26th March 2015
¡ Adrian Pietkiewicz
Structure activity relationship of SanB analogues on HCT-116: the importance
of stereochemistry
5th International Symposium of Surface and Interface of Biomaterials & 24th Annual Conference of the Australasian Society for Biomaterials and Tissue Engineering, Sydney, Australia, 7th – 10th April 2015
¡ Ho K, Chen R, Willcox M, Kumar N
Prevention of bacterial infections by surface immobilized dihydropyrrolone compounds
¡ Chen R, Ho K, Willcox M, Kumar N
Inhibition of in vivo microbial colonisation of peptide-coated biomaterials
¡ Taunk A, Ho K, Iskander G, Willcox M, Kumar N
Antibacterial biomaterials based on quorum sensing inhibitors
Gordon research Seminar: Photosynthesis, Bentley University, USA, 27th – 28th – June 2015
¡ Alistair Laos, Paul Curmi and Pall Thordarson
Tuneable Light Harvesting and Folding
of a Photosynthetic Antenna Protein:
Insights into Photoprotection
6th International Nanomedicine Conference, Sydney Australia 6th-8th July 2015.
¡ B. Gupta, D. Wakefield, N. Di Girolamo, K. Gaus, P.J. Reece, J.J. Gooding.
Porous Silicon Microsensors for the Detection of Protease Activity In Vivo.
¡ G. Duche, P. Thordarson
Protein release from epoxy resin for dental applications
¡ Md. Musfizur Hassan, A. Martin and P. Thordarson
Rational Design Of Dipeptide Hydrogelators For Controlled Drug Delivery
¡ S. G. Parker, S. Ciampi, Y. Yang, K. Gaus, J.J. Gooding.
Towards Capture and Release of Circulating Tumour Cells (CTCs) - Using Electrochemically-Switchable Surfaces.
¡ M. Parviz, K. Gaus, J.J. Gooding.
Development of a Cell-Based Biosensor
Using Fluorescence Microscopy and
Impedance Spectroscopy
¡ S. Taufik, A. Barfidokht, M. Alam, J.J. Gooding.
Amperometric Sensor for the Detection of Haemoglobin (Hb) in Human Blood.
¡ Chin Ken Wong, Alistair J. Laos, A.H. Soeriyadi, J. Gooding, M.H. Stenzel, P. Thordarson
Revealing the (co-)encapsulation of drug and protein payloads via FLIM-FRET in thermoresponsive fluorescent polymersomes prepared from protein-polymer bioconjugates
25th ANZSMS Conference & 6th Asia Oceanic Mass Spectrometry Conference, Brisbane, 19th – 22nd July 2015.
¡ Michael Leeming
Non-targeted detection of drug metabolites using high-resolution twin-ion metabolite extraction mass spectrometry: from small molecules to
protein conjugates
2nd Asia-Oceania Conference on Neuron Scattering, Sydney, Australia, 19th – 23rd July 2015.
¡ James Christian Pramudita
Using quasi-elastic neutron diffraction to study positive electrode for sodium-ion
batteries
American Chemical Society Annual Meeting and Exposition, Boston, MA, USA, 16th – 20th August 2015
¡ Laura Buckton
Design, synthesis and biological evaluation of novel C-terminal hsp90 inhibitors
¡ Yen Chin Koay
Synthesis of novel heat shock protein 90
inhibitors
2015 Southern Highland Conference on Heterocyclic Chemistry, Bowral, NSW, 30th August – 1st September 2015.
¡ Adrian Pietkiewicz
Structure activity relationship of SanB analogues on HCT-116: the importance of stereochemistry
¡ Yuqi Zhang
Synthetic strategies targeting potent anti-cancer agent: Marthiapeptide A
Student Conference Presentations 2015 | 49
RACI NSW Medicinal Chemistry and Chemical Biology Symposium, University of Sydney, September 2015.
¡ Yen Chin Koay
A novel class of hsp90 inhibitors that are designed to be soluble and
synthetically accessible
Australian X-ray Analytical Association Student Conference, Western Sydney University, 15th September 2015
¡ James Christian Pramudita
Materials for Next Generation of
Batteries
250th American Chemical Society National Meeting, Boston, MA, USA, 28th September 2015
¡ Yen Chin Koay
Synthesis of novel heat shock protein 90
inhibitors
RACI Medicinal Chemistry & Chemical Biology NSW Symposium, Sydney University, 28th September 2015
¡ Laura Buckton
De novo design of novel heat shock protein 90 inhibitors: targeting the C-terminus
¡ Yen Chin Koay
A novel class of hsp90 inhibitors that are designed to be soluble and synthetically accessible
¡ Nizalapur S, Black D, Kumar N
Design, synthesis, and evaluation of N-aryl-glyoxamide derivatives as structurally novel bacterial quorum sensing inhibitors
¡ Adrian Pietkiewicz
Structure activity relationship of SanB analogues on HCT-116: the importance of stereochemistry
¡ Yao Wang
C-terminal versus N-terminal heat shock protein 90 inhibitors: is one more
effective than the other
RACI natural Products Chemistry Group Annual One-Day Symposium, Western Sydney University, 2nd October 2015
¡ Hong, K, Ball, G, Kumar N
The mosaic of Rottlerin
66th Annual meeting of the International Society of Electrochemistry, Taipei, Taiwan, 4th – 9th October 2015
¡ Christian Gunawan
Salt on a chip – miniaturised ionic liquid
systems
Reactive Organometallics Symposium, Macquarie University, 6th November 2015
¡ Christopher D. Barnett
Understanding N-Heterocyclic Carbene Properties
¡ Peter Jurd
Coupling Reactivity of Carbon Dioxide and Acetylene Mediated by Iron Phosphine Complexes
¡ Anthony R. Leverett
Exploring Thallium Organometallic Coordination Chemistry Using NHCs
¡ Daniel Twycross
Developing the Chemistry of N-2-6-terphenyl Substituted N-Heterocyclic
Carbenes
NSW Medicinal Chemistry Drug Discovery Symposium, UNSW 18th November 2015.
¡ Laura Buckton
Design, synthesis and evaluation of heat shock protein 90 inhibitors that directly impact the C-terminus
¡ Jessica Kho
The forgotten heat shock protein, HSP27: The design and synthesis of molecules targeting HSP27 as chemotherapies
¡ Adrian Pietkiewicz
Structure activity relationship of SanB analogues on HCT-116: the importance of stereochemistry
¡ M. Parviz, P. Toshniwal, I.K. Swaminathan, K. Gaus, J.J. Gooding
Development of a Dual Screening Tool for Drug Discovery Applications.
¡ Yao Wang
C-terminal versus N-terminal heat shock protein 90 inhibitors: is one more effective than the other
¡ Yee MH, Vittorio O, Black D, Kumar N
Dextran-Catechin inhibits angiogenesis
by chelating copper in endothelial cells
UNSW Medicinal Chemistry Symposium, December 2015.
¡ Aggie Lawer
Stereoselective fluorination: A tool to control peptides’ conformation and
biological activity.
RACI NSW Organic Group 36th Annual One Day Symposium, Macquarie University, 2nd December 2015.
¡ Catherine Au
Fluorinated analogues of guanidine-containing natural products
¡ Christopher D. Barnett, Marcus L. Cole and Jason B. Harper
Understanding N-Heterocyclic Carbene Properties
¡ Marcus Blumel
Developments of Novel N-Heterocyclic Olefin Promoted Chemical Reactions
50 | School of Chemistry Annual Report
¡ Nicholas Konstandaras
Correlating structure and reactivity. Electronic and strain effects in a range of systems
¡ Demelza Lyons
Novel Coupling Reagents with Tropylium Ions
¡ Jack Reed
Diversity-Oriented Synthesis using the Diene-Regenerative Diels-Alder
Reaction
RACI R&D Topics, The University of Melbourne, 6th – 9th December 2015
¡ Morphy Dumlao
Solid-phase microextraction low temperature plasma mass spectrometry for the direct and rapid analysis of chemical warfare simulants in complex mixtures
¡ Muhammad Zenaidee
Formation of Protein “Super-acids” for
Mass Spectrometry
RACI NSW Medicinal Ionic Liquid Group 1st One Day Symposium, UNSW, 7th December 2015.
¡ Jeffrey Black
Thermoelectrochemistry of lithium glyme solvate ionic liquids
¡ William E. S. Hart, Jason B. Harper and L. Aldous.
Ionic liquids for the controllable cleavage of lignin into aromatic feedstock chemicals
¡ Rebecca R. Hawker, Ronald S. Haines and Jason B. Harper.
Rational selection of the cation of an ionic liquid solvent to control the outcome of an S
N2 reaction. [Prize
Winner]
¡ Benjamin Lau
Biomass processing with ‘salty water’
¡ Sinead T. Keaveney, Benjamin P. White, Ronald S. Haines and Jason B. Harper.
Ionic liquid effects on SN1 reactions: the
importance of charge delocalisation. [Prize Winner]
¡ Karin S. Schaffarczyk McHale and Jason B. Harper
Ionic liquid effects on nucleophilic substitution reactions: Variation of the
nucleophilic heteroatom
9th Australasian Organometallics Meeting, Sydney University, 8th - 11th December 2015.
¡ Christopher D. Barnett
Understanding N-Heterocyclic Carbene Properties
¡ Kai N. Buys
Using Pincer Ligands to Study s- and p-Block Halides and Hydrides
¡ Daniel Twycross
Developing the Chemistry of N-2-6-terphenyl Substituted N-Heterocyclic Carbenes
¡ Peter Jurd
Coupling Reactivity of Carbon Dioxide and Acetylene Mediated by Iron Phosphine Complexes
¡ Vera Diachenko
The Kinetic Stabilisation of Main Group and Transition Metal Complexes with a
Super Bulky Diiminopyridine
Pacifichem, Honolulu, Hawaii, USA 15th – 20th December 2015
¡ Jessica Kho
The forgotten heat shock protein, HSP27: The design and synthesis of molecules targeting HSP27 as chemotherapies
Conference Posters 2015 | 51
Conference Posters 2015
International Congress of Quantum Chemistry, Beijing, China, 8th – 13th June 2015.
¡ Yu Liu
Projections of tiles of correlated wavefunction: Viewing chemistry in a new way
The Chemical Bonds at the 21st Century, Xiamen China, 14th – 18th June 2015.
¡ Yu Liu
Projections of tiles of correlated wavefunction: Viewing chemistry in a new way
Tetrahedron Symposium, Berlin, Germany, 16th – 19th June 2015.
¡ Renecia Lowe
Optimising molecules with biomedical potential using selective fluorination
chemistry
Gordon Research Conference, Stress Proteins in Growth, Development & Disease, Barga, Italy, 5th – 10th July 2015.
¡ Yao Wang
Investigation of mono and combination cancer therapies targeting heat shock
proteins
6th International Nanomedicine Conference, Sydney, 6th – 8th July 2015.
¡ K. Zong, A.H. Soeriyadi, R. Utama, S.B. Lowe, V. Tan, F. Han, J.J. Gooding
pH and enzyme dual responsive “AND” gate polymeric micelle for anti-cancer drug delivery.
¡ L. Zarei, M.H. Choudhury, R. Tavallaie, V.R. Goncales, S. Ciampi, J.J. Gooding
Fabrication of high-density DNA microelectrode arrays using light activated electrochemistry.
¡ R. Tavallaie, N. Darwish, D.B. Hibbert, J.J. Gooding
The impact of surface chemistry on microRNA recognition interfaces.
¡ M. Sriram, S.R.C. Vivekchand, J.J. Gooding
Single particle plasmonic core-satellites for digital biosensors.
¡ R. Piya, A.H. Soeriyadi, B. Gupta, P.J. Reece, JJ. Gooding
Formation of Cell Microarrays on Porous Silicon Photonic Crystal: Towards Single Cell Detection.
¡ S.M. Silva, R. Tavallaie, M. Alam, J.J. Gooding
Electrochemical Characterization of Gold-Coated Magnetic Nanoparticles as ‘Dispersible Electrodes’.
¡ F. Han, A.H. Soeriyadi, Y.H. Zheng, S. R.C. Vivekchand, J.J. Gooding
Stimuli-responsive Plasmonic Core-Satellite Nanostructures.
¡ X.Y. Cheng, E. Hinde, D.M. Owen, S.B. Lowe, P.J. Reece, K. Gaus, J.J. Gooding
Using advanced optical microscopy to overcome the challenges of the blue colour of solution prepared silicon
quantum dots (SiQDs).
2nd Asia-Oceania Conference on Neuron Scattering, Sydney, Australia, 19th – 23rd July 2015.
¡ Othman Al Bahri
The Thermal Expansion of Li and Na Intercalated ZrW
2O
8
¡ Damian Goonetilleke
Doped Li7La
3Zr
2O
12 derivatives as
electrolytes for next generation solid
state batteries
2015 Southern Highland Conference on Heterocyclic Chemistry, Bowral, NSW, 30th August – 1st September 2015.
¡ Yuqi Zhang
Synthetic strategies targeting potent
anti-cancer agent: Marthiapeptide A
15th European Symposium on Physical Organic Chemistry, Kiel, Germany, 30th August – 4th September 2015.
¡ Rebecca R. Hawker, Ronald S. Haines and Jason B. Harper
Rational selection of the cation of an ionic liquid solvent to control the outcome of an S
N2 reaction
¡ Sinead T. Keaveney, Ronald S. Haines and Jason B. Harper
Stimuli-responsive Ionic liquids as solvents for organic reactions: the importance of microscopic interactions in predicting reaction outcome.
RACI NSW Medicinal Chemistry and Chemical Biology Symposium, University of Sydney, September 2015.
¡ Alexandra Daryl Ariawan
Amino-nitrile: versatile intermediate for iminosugar synthesis
¡ Catherine Au
Fluorination of 4-guanidinobutanoic acid: effects on molecular conformation and bioactivity
¡ Rasha Jwad
Sigma 1 receptor ligands in biology and medicine
¡ Aggie Lawer
Stereoselective fluorination: A tool to control peptides’ conformation and biological activity
52 | School of Chemistry Annual Report
¡ Yuvixza Lizarme
From magic mushrooms to a treatment
for stroke
ACOVS-11, Sydney University, 29th September – 2nd October 2015.
¡ O. Krechkivska, K. Nauta, Y. Liu, K. L. K. Lee, S. H. Kable, T. W. Schmidt
REMPI Spectroscopy of Toluene+H and Hydrogenation and Deuteration effects on Methyl Rotor
RACI NSW Natural Products Symposium, University of Western Sydney, 2nd October 2015.
¡ Yuvixza Lizarme
From magic mushrooms to a treatment for stroke
¡ Taunk A, Ho K, Iskander G, Willcox M, Kumar N
Developing antibacterial biomaterials based on quorum sensing inhibitors
Gordon Research Conference, 5th – 10th October 2015.
¡ Yao Wang
Investigation of mono and combination cancer therapies targeting heat shock proteins
66th Annual meeting of the International Society of Electrochemistry, Taipei, Taiwan, 4th – 9th October 2015
¡ Christian Gunawan
Scanning electrochemical microscopy of photoswitchable enzyme cascade
Atmospheric Composition & Chemistry Observations & Modelling Conference / Cape Grim Annual Science Meeting, Tasmania, 11th – 13th November 2015.
¡ Alireza Kharazmi, Kim Lapere, Miranda Shaw, Klaas Nauta, Meredith Jordan and Scott Kable
Phototautomerization: a new pathway to formation of organic acids
Atmospheric Composition and Chemistry Observations and Modelling Conference, Murramarang, NSW, 11th – 13th November 2015.
¡ Callan M. Wilcox, Olha Krechkivska, Klaas Nauta, Timothy W. Schmidt and Scott H. Kable
Understanding the Primary Oxidation of Terpenes
UNSW Medicinal Chemistry / Drug Discovery Symposium, 18th November 2015
¡ Biswas N, Black D, Kumar N.
Palladium catalysed coupling reactions of fimbrolides: Synthesis of new substituted furanones as bacterial quorum sensing inhibitors
¡ Jiang H, Black D, Kumar N
Synthesis and biological activity of some indole and benzimidazole inhibitors of bacterial transcription initiation complex formation
¡ Nizalapur S, Black D, Kumar N
Design, synthesis, and biological evaluation of phenylglyoxamide-based small molecular antimicrobial peptide mimics as novel antimicrobial agents and biofilm Inhibitors
¡ Su J, Byrne F, Hoehn K, Black D, Kumar N
A new chemical activator of glucose oxidation and its potential use as an anticancer agent
Asia-Oceania Forum on Synchrotron Radiation Research, Melbourne, Australia, 25th – 27th December 2015.
¡ Othman Al Bahri
The Thermal Expansion of Li and Na Intercalated ZrW
2O
8
AMMA Molecular Modelling Conference, UNSW, December 2015.
¡ Yu Liu
Projections of tiles of correlated wavefunction: Viewing chemistry in a new way
¡ Gabriella Marcolin
Predicting the effect of stereoselective fluorination on an inhibitor of a malarial protease
UNSW Medicinal Chemistry Symposium, December 2015.
¡ Alexandra Daryl Ariawan
Amino-nitrile: versatile intermediate for iminosugar synthesis
¡ Rasha Jwad
Functionalized fluorinated molecules with applications in biology
36th Annual One Day Symposium, RACI NSW Organic Group, Macquarie University, Sydney, Australia, 2nd December 2015.
¡ Alexandra Daryl Ariawan
The Cyclic Peptide Unguisin A is a Selective Anion Receptor
¡ Joana Da Rocha
Controlling abnormal blood vessel growth to cure blindness
¡ Timothy E. Elton and Jason B. Harper
Correlating NHC properties with their catalytic function: Towards tailoring carbenes for catalysis
¡ Max S. Guerry, Marcus L. Cole, and Jason B. Harper
Measuring nucleophilicity of N-heterocyclic carbenes with competition experiments
¡ William E. S. Hart, Jason B. Harper and L. Aldous
Ionic liquids for the controllable cleavage of lignin into aromatic feedstock chemicals
¡ Rebecca R. Hawker, Ronald S. Haines and Jason B. Harper
Rational selection of the cation of an ionic liquid solvent to control the outcome of an S
N2 reaction
¡ Tom Hawtrey
Development of Inhibitors of RNA Splicing Kinases
¡ Rasha Jwad
Functionalized fluorinated molecules with applications in biology
¡ Sinead T. Keaveney, Ronald S. Haines and Jason B. Harper
Ionic liquids as solvents for organic reactions: the importance of microscopic interactions in predicting reaction outcome
¡ Nicholas Konstandaras, Marcus L. Cole and Jason B. Harper
Correlating structure and reactivity. Electronic and strain effects in a range of systems
¡ Aggie Lawer
Stereoselective fluorination: A tool to control peptides’ conformation and biological activity
¡ Yuvixza Lizarme
From magic mushrooms to a treatment for stroke
Conference Posters 2015 | 53
¡ Jonathon Ryan
Development of a Synthetic Approach to Coproverdine
¡ Karin S. Schaffarczyk McHale and Jason B. Harper
Ionic liquid effects on nucleophilic substitution reactions: Variation of the nucleophilic heteroatom
¡ Elysha Taylor
Using the AAL(S) scaffold for the control of Protein Phosphatase 2A and Ceramide Synthase
¡ Stephen Wearmouth
The Association of Molecular Modellers of Australasia, Sydney, Australia, 2nd – 5th December 2015.
¡ Christopher Pracey
Solution Structure of the Mitoxantrone-DNA Complex: NMR and Molecular Modelling Studies
¡ Keiran Rowell
Computational Studies of the Neighbour Exclusion effect in DNA intercalators
9th Australasian Organometallics Meeting (OZOM IX) University of Sydney, 8th – 11th December 2015.
¡ Kai N. Buys
Using Pincer Ligands to Study s- and p-Block Halides and Hydrides
¡ Christopher D. Barnett, Marcus L. Cole and Jason B. Harper
Understanding N-Heterocyclic Carbene Properties
¡ Lida Ezzedinloo, G. Ball, M. Bhadbhade, S. Colbran,
Organo-transition metal complexes for electrocatalyic reduction of carbon dioxide
¡ James McPherson, A. McSkimming, M. Bhadbhade, S. Colbran
Dipyridylpyrrolato anion analogues of terpyridine metal complexes
¡ Matthew Mudge, A. Patel, M. Bhadbhade, S. Colbran
A dixanthene scaffold for cooperative catalysis
PACIFICHEM, Hawaii USA, 15th – 20th December 2015.
¡ Rasha Jwad
Functionalized fluorinated molecules with applications in biology
¡ Lee, KLKL, Nauta, K, Kable, SH
Acetone photodissociation: what the fragments tell us
54 | School of Chemistry Annual Report
Undergraduate and Postgraduate Enrolments
Enrolment statistics 20152009 2010 2011 2012 2013 2014 2015
ENROLMENTS in CORE CHEMISTRY COURSES
First Year 1521 1844 1966 1966 2445 2117 2176
Second Year 231 219 336 352 340 399 383
Third Year 182 137 102 187 215 219 233
Level III CHEM electives 75 63 80 99 128 137 116
ENROLMENTS in SERVICE COURSES
First Year 878 898 954 1024 1233 1022 764
Second Year 98 94 275 367 330 350 303
Third Year 54 13 75 67 60 65 48
Honours 25 18 15 29 35 38 36
Total POSTGRADUATE COURSEWORK STUDENTSe
Master of Science and Technology (Program 8708)
20 30 36 26 26 19 12
Graduate Diploma (Program 5648) 12 3 3 2 3 2 1
Graduate Certificate (Program 7428) 4 3 4 1 0 3 34
POSTGRADUATE RESEARCH STUDENTS
MSc (Research) Program 2910 4 4 6 8 11 8 3
PhD Program 1870 69 86 88 78 88 106 116
Undergraduate and Postgraduate Enrolments | 55
Honours EnrolmentsThe following Honours students were enrolled during all or part of the 2015 reporting period.
Student Supervisor
MEDICINAL CHEMISTRY HONOURS STUDENTS:
Michelle Cheung A/Prof. Shelli McAlpine
Jeremy Dobrowolski Prof. Naresh Kumar
Eric Du A/Prof. Pall Thordarson
Clara Fong A/Prof. Chuan Zhao
Christina Gonzalez Dr. Luke Hunter
Vanessa Hunt A/Prof. Shelli McAlpine
Hilary Hyunh A/Prof. Pall Thordarson
Jessica Kho A/Prof. Shelli McAlpine
Duyen Nguyen Scientia Professor Justin Gooding
Jacky Su Professor Naresh Kumar
Ling-Chia Wang Prof. Martina Stenzel
Yukai Wang Prof. Martina Stenzel
Joshua Wong Prof. Martina Stenzel
Stephen Xu (*) Dr. Leigh Aldous
NANOTECHNOLOGY HONOURS STUDENTS:
Othman Al Bahri Dr Neeraj Sharma
Damian Goonetilleke Dr Neeraj Sharma
Yehezkiel Henson A/Prof. Chuan Zhao
* Mid-year entry, July 2014-June 2015
$ Mid-year entry, July 2015-June 2016
Student Supervisor
CHEMISTRY HONOURS STUDENTS:
Patrick Brown Dr. Jonathon Beves
Stephen Butler A/Prof. Jonathan Morris
Ilya Dragutinovic A/Prof. Jonathan Morris
Timothy Elton A/Prof. Jason Harper
Thomas Frith A/Prof. Jason Harper
Mackenzie Hagan Dr. Neeraj Sharma
Paige Hawkins A/Prof. Jonathan Morris
Laura Jeffress Dr. William Alex Donald
Arien Kadribasic ($) Dr. Jonathon Beves
Ena Luis Dr. Jonathon Beves
Lucas Matto Dr. Luke Hunter
James McPherson (*) A/Prof. Stephen Colbran
Justin Tan ($) A/Prof. Marcus Cole
Thomas Peters Prof. Leslie Field
Karin Schaffarczyk-McHale A/Prof. Jason Harper
Edward Stephens (*) Dr. William Alex Donald
Grace Yong Dr. William Alex Donald
Hon Ching Yu ($) Prof. Scott Kable
Sharon Yu Prof. Naresh Kumar
56 | School of Chemistry Annual Report
Postgraduate Coursework Enrolments The following postgraduate coursework students were enrolled during all or part of the
reporting period for 2015
Master of Science and Technology in Chemical Analysis and Laboratory Management (Program 8708 - MScTech) ¡ May Abu Muti
¡ Pankaj Barai
¡ Ahlam Alenazi
¡ Zhi Hao Chan
¡ Ibrahim Alnashari
¡ Jo-Anne Collins
¡ Hamoud Alnazzal
¡ Pragna Gaur
¡ Raaid Alosaimy
¡ Brendan Sellors
¡ Fahd Althebyani
¡ Gina Valentin Avellaneda
Graduate Diploma in Chemical Analysis and Laboratory Management (Program 5648) ¡ Monica Hibberd
Graduate Certificate in Chemical Analysis and Laboratory Management (Program 7428 / 7429) ¡ Warda Kamal
¡ Pauline Michaels
¡ Kaixian Zhu
Undergraduate and Postgraduate Enrolments | 57
Postgraduate Research EnrolmentsThe following postgraduate research students were enrolled during all or part of the reporting period for 2015
Master of Science by Research (Program MSc2910 & MPhil 2475)
Candidate Research Area Supervisor
Chao SHEN Supramolecular chemistry Dr Jonathon Beves
Jonatan WANGSAHARDJA Fluorinated amino acids Dr Luke Hunter
Chang Long XIAO Electrochemical energy conversion & storage A/Prof. Chuan Zhao
Doctor of Philosophy, Chemistry (Program 1870)The following postgraduate research students were enrolled during all or part of the reporting period for 2015 and who have
not completed or submitted their thesis in 2015
Candidate Supervisor
Iqbal AHMED Dr Luke Hunter
Moshiul ALAM A/Prof. Marcus Cole
Hassan ALZAHRANI, Dr Leigh Aldous
Alexandra Daryl ARIAWAN Dr Luke Hunter
Majid ASNAVANDI A/Prof Chuan Zhao
Catherine AU Dr Luke Hunter
Christopher BARNETT A/Prof Marcus Cole
Muhammad Afiq Bin ZENAIDEE Dr William Donald
Jeffrey BLACK Dr Leigh Aldous
Laura Katherine BUCKTON A/Prof Shelli McAlpine
Kai BUYS A/Prof. Marcus Cole
Lachlan CARTER Scientia Prof. Justin Gooding
Fan CHEN Prof Martina Stenzel
James CHRISTIAN Dr Neeraj Sharma
Reece CROCKER Dr Vinh Nguyen
Joana DA ROCHA A/Prof Pall Thordarson
Andrew DANOS A/Prof Pall Thordarson
Abbas DARESTANI FARAHANI A/Prof Marcus Cole
Vera DIACHENKO A/Prof Stephen Colbran
Genevieve DUCHE A/Prof Pall Thordarson
Morphy DUMLAO A/Prof Chuan Zhao
Lida EZZEDINLOO A/Prof Stephen Colbran
Tim FANG A/Prof Chuan Zhao
Mengchen GE A/Prof Chuan Zhao
Lucy GLOAG Prof Richard Tilley
Richard GONDOSISWANTO Dr Jason Harper
Christian GUNAWAN A/Prof. Pall Thordarson
Fei HAN A/Prof Jonathan Morris
William HART Dr Graham Ball
Md Musfizur HASSAN Prof. Naresh Kumar
Rebecca HAWKER Dr Jason Harper
Tom Jordan HAWTREY A/Prof Jonathan Morris
Mushi HE Dr Graham Ball
Kam HONG Prof. Naresh Kumar
Hasti IRANMANESH Dr Jonathon Beves
Hao JIANG Prof. David Black, Prof. Naresh Kumar
Cheng JIANG Scientia Prof. Justin Gooding
Candidate Supervisor
Rasha JWAD Dr Luke Hunter
Modaddeseh KAHRAM Scientia Prof. Justin Gooding
Mehran Bolourian KASHI Scientia Prof. Justin Gooding
Sinead KEAVENEY Dr Jason Harper
Alireza KHARAZMI Prof Scott Kable
Parisa Sowti KHIABANI Scientia Prof. Justin Gooding
Nicholas KONSTANDARAS Dr Jason Harper
Haiwang LAI Prof Martina Stenzel
Alistair LAOS A/Prof. Pall Thordarson
Benjamin LAU Dr Leigh Aldous
Aggie LAWER Dr Luke Hunter
Kelvin LEE Prof Scott Kable
Hyun Eui LEE Dr William Donald
Yun (Jimmy) Leung Dr Luke Hunter
Anthony LEVERRTT A/Prof Marcus Cole
Devi LIANA Scientia Prof. Justin Gooding
Kang LIU Scientia Prof. Justin Gooding
Yu LIU Prof Tim Schmidt
Yuvixza LIZARME SALAS Dr Luke Hunter
Renecia LOWE Dr Luke Hunter
Mingxia LU Prof Martina Stenzel
Yong LU Scientia Prof. Justin Gooding
Demelza LYONS Dr Vinh Nguyen
Neil MALLO Dr Jonathon Beves
Russul MAMDOOH Prof Martina Stenzel
Flora MANSOUR Dr Luke Hunter
Gabriella Mary MARCOLIN Dr Luke Hunter
Alexander MASON A/Prof. Pall Thordarson
James McPherson A/Prof Stephen Colbran
Benjamin McVey A/Prof Stephen Colbran
Toby MILLS Dr William Donald
Saimon MORAES SILVA Scientia Prof. Justin Gooding
Matthew MUDGE A/Prof Stephen Colbran
Shashidhar NIZALAPUR Prof Naresh Kumar
Janina NOY Prof Martina Stenzel
Catherine Jessica ONIE A/Prof John Stride
Raheleh PARDEHKHORRAM Scientia Prof. Justin Gooding
58 | School of Chemistry Annual Report
Candidate Supervisor
Matthew PETERSON Scientia Prof. Justin Gooding
Maryam PARIZ Scientia Prof. Justin Gooding
Adrian PIETKIEWICZ A/Prof Shelli McAlpine
Albert PILONI Prof Martina Stenzel
Ranjana PIYA Scientia Prof. Justin Gooding
Bijan POURYOUSEFI MARKHALI Scientia Prof. Justin Gooding
Christopher PRACEY Dr Graham Ball
Mitchell QUINN Prof Scott Kable
Marwa RAHIMI A/Prof Shelli McAlpine
Aravind RAMACHANDRAN Scientia Prof. Justin Gooding
John (Jack) REED A/Prof Jonathan Morris
Andrew ROBINSON A/Prof. Pall Thordarson
Jonathon RYAN A/Prof Jonathan Morris
Abu Sadat SAYEM RAHMAN Scientia Prof. Justin Gooding
Manish ramnath SRIRAM Scientia Prof. Justin Gooding
Jiaying SU Prof Martina Stenzel
Bryan SURYANTO A/Prof Chuan Zhao
Vincent TAN Scientia Prof. Justin Gooding
Safura TAUFIK Scientia Prof. Justin Gooding
Aditi TAUNK Prof. Naresh Kumar
Elysha TAYLOR A/Prof Jonathan Morris
Candidate Supervisor
Kristel Cahyadi TJANDRA A/Prof Pall Thordarson
Uyen TRAN Dr Vinh Nguyen
Daniel TWYCROSS A/Prof. Marcus Cole
Huixin WANG Dr William Donald
Yao WANG A/Prof. Shelli McAlpine
Steve WEARMOUTH A/Prof Jonathan Morris
Alexander WEREMFO A/Prof Chuan Zhao
Callan WILCOX Prof Scott Kable
Jonathan WOJCIECHOWSKI A/Prof Pall Thordarson
Chin Min WONG Prof. Barbara Messerle
Kenneth WONG A/Prof Pall Thordarson
Yanfang WU Scientia Prof. Justin Gooding
Ying YANG Scientia Prof. Justin Gooding
Vineeth YASAPARUNDI Prof. Tim Schmidt
Ming Han Eugene YEE Prof Naresh Kumar
Samantha ZAITER A/Prof Shelli McAlpine
Leila ZAREI Scientia Prof. Justin Gooding
Xiao ZHANG Scientia Prof. Justin Gooding
Yuqi ZHANG A/Prof Shelli McAlpine
Manchen ZHAO Scientia Prof. Justin Gooding
Kelly ZONG Scientia Prof. Justin Gooding
SOCS President’s Report | 59
SOCS President’s Report
It was another busy year for the Students of Chemistry Society as we hosted a number of exciting events and continued to play an important role in the smooth running of faculty events.
With a New Year came a new executive team, and the committee was keen to get started!
2015 began with the team representing the School during O-week,
setting up a stall showing off experiments for the incoming students,
whilst handing out a range of goodies for the eager 1st years. SOCS
took a more community-1``focused approach this year in coordination
with the new Head of School, Professor Scott Kable, which saw the first
year BBQ integrated with the School’s moving day/sports day to great
success.
The annual SOCS trivia night followed with Dr. Jason Harper and
Stephen George contributing wit, charm, sass, and the occasional
bit of trivia. Of special note, 2015 saw Jason reach his “aluminium
jubilee”, marking his 10th appearance as Quiz Master. To thank Jason
for his service to SOCS, the executive committee saw it fit to present
him with a roll of Homebrand Al-Foil. Fierce competition ensued, as
each team made their bid to take the coveted title of chemistry trivia
champions! Prizes were awarded for a range of achievements and non-
achievements throughout the night.
To round out the social calendar for 2015, SOCS held its 13th annual
Chem Ball to great success. Falling during the Vivid festival, the
committee saw the opportunity to secure a venue overlooking the
stunningly lit Darling Harbour. With such a perfectly set stage, and a
classy theme of “Flowers and Bowties”, SOCS quickly sold out all tickets
for the event, hitting capacity for the 120 seat venue, within the first day
of sales, the largest event in SOCS history! Staff and students enjoyed
a three-course meal, and danced the night away, enjoying the chance to
wind down after a busy semester.
Finally, a huge thank you must go to the other members of the executive
as well as all of the students who played a part in SOCS over the course
of the year. The society saw the building of a stronger community in the
school, which is hoped, will continue through 2016. A massive thank
you goes to Professor Scott Kable for his support in 2015, providing
guidance and encouragement throughout the year. To the admin staff,
Lucy, Steve, and Jodee, thank you for helping us with paperwork and
giving gentle nudges when needed. We couldn’t have made it through
the year without your help.
Tom Frith el Presidente, SOCS 2015
President Tom Frith
Treasurer Peter Lee
Secretary Daniel Moctezuma-Baker
Social Coordinator Matthew Mudge
Publicity Officer Catherine Tat
Merchandise Stephen Butler
Arc Representative William Li
Undergrad. Chem. Rep. Stephen Butler
Med. Chem. Rep. Jessica Kho
Above and below: Staff and students enjoying the Chem Ball
60 | School of Chemistry Annual Report
StaffPublications and PatentsGrants and Research FellowshipsIndustry & Community Interaction
School
Staff | 61
Staff
AdministrationHead of School
Professor Scott Henderson Kable, BSc (Hons 1), PhD, Griffith
Deputy Head of School
Scientia Professor John Justin Gooding,BSc Melb. DPhil Oxon
Director of Research
Associate Professor Pall Thordarson, BSc Iceland, PhD Syd
Director of Teaching
Dr. Gavin Leslie Edwards, BSc PhD Monash, CChem, MRACI
Deputy Director of Teaching & Talented Students Program
Dr. Jason Brian Harper, BSc Adelaide, BSc, PhD ANU
Post Graduate Research Coordinator
Professor Martina Heide Stenzel, MSc Bayreuth, PhD Stuttgart
Graduate Studies Coordinator
Dr Graham Edwin Ball, BSc PhD Sheffield, MRACI
Honours Coordinatoor
Associate Professor John Arron Stride, BSc (Hons.) PhD E.Anglia
Higher Year (2nd – 4th year) Coordinator
Associate Professor Stephen Boyd Colbran, BSc PhD Otago
First Year Coordinator
Dr. Luke Hunter, BSc (Adv)(Hons), PhD USYD
Laboratory Coordinator
Associate Professor Stephen Boyd Colbran, BSc PhD Otago
IT Coordinator
Dr. Ronald Stanley Haines, BSc PhD UNSW
Seminar Coordinator
Dr. Jonathan Beves,
Outreach Coordinator
Professor Naresh Kumar, MSc Punj., PhD W’gong., CChem, MRACI
Administrative Officer
Rick Sai Kin Chan, BBus Curtin
Administrative Officer
Jodee Anning, BA UNSW
Professors
David St Clair Black, MSc Syd., PhD Camb., AMusA, CChem, FRACI
John Justin Gooding, BSc Melb., DPhil Oxon
Scott Henderson Kable, BSc (Hons 1), PhD, Griffith
Naresh Kumar, MSc Punj., PhD W’gong., CChem, MRACI
Timothy Schmidt, BSc USyd, PhD Cambridge
Martina Heide Stenzel, MSc Bayreuth, PhD Stuttgart
Associate Professors
Stephen Boyd Colbran, BSc PhD Otago
Marcus Lawford Cole, BSc (Hons) PhD Cardiff
Shelli Renee McAlpine, BSc Ill, PhD UCLA
Jonathan Charles Morris, BSc UWA, PhD ANU
John Arron Stride, BSc (Hons.) PhD E.Anglia
Pall Thordarson, BSc Iceland, PhD Syd
Chuan Zhao, BSc Shaanxi, MSc PhD Northwest UT
Senior Lecturers
Graham Edwin Ball, BSc PhD Sheffield, MRACI
Gavin Leslie Edwards, BSc PhD Monash, CChem, MRACI
Jason Brian Harper, BSc Adelaide, BSc ANU PhD ANU
Lecturers
Leigh Aldous, BSc (Hon) Leeds, PhD Queen’s
Jonathon BevesBSc, MSc USyd, PhD Basel
William Alexander Donald, BSc Seattle, PhD UCA Berkley
Ronald Stanley Haines, BSc PhD UNSW
Luke Hunter, BSc (Adv)(Hons), PhD USYD
Neeraj Sharma, BSc (Hons) PhD USYD
Associate Lecturer
Anna Choy, BSc (Hons), UNSW
DECRA Fellows
Dr Hongxu Lu, BSc MSc Ocean University of China, PhD Tsukuba University, Japan
Dr Pu Xiao, BSc PhD Wuhan University, China
NHMRC Fellows
Dr Alex Soeriyadi, BEng (Hons 1), PhD Industrial Chemistry, UNSW
VC Postdoctoral Fellows
Dr. Robert Chapman, BEng (Hons 1) Industrial Chemistry, PhD USyd
Teaching Staff
62 | School of Chemistry Annual Report
Dr. Sheng Chen, BSc, MSc, PhD Nanjing University of Science & Technolgy
Dr Vivek Ramalinga Chandra Seluka, BSc American College, Madurai, MSc PhD Jawaharlal Nehru Centre for Advanced Scientific Research - Bangalore
Dr. Yuhua Xue, Ph.D. Zhejiang University, China
Dr Yuanhui Zheng, PhD Monash
Welcome Trust-India Fellow
Dr. Padmavarthy, Ph.D. Anna University, India
Casual 1st Year Teaching Staff
Dr Kakali Chowdhury, PhD, Uni New Dehli, India
Joan P. Ross, BSc Syd.
School Technical Staff: Back Row: Steve Yannoulatos, Dr. Toby Jackson, Rick Chan, Anne Ayres, Lucy Stride, Amanda Troobnikoff, Sveto Videnovic, Hitenda Gopel Front Row: Ian Aldred, Dr. Ruth Thomas, Dr. Nancy Scoleri, Jodee Anning
Research StaffProfessor Leslie D. Field (Deputy Vice Chancellor – Research)
Research AssociatesDr. Manohari Abeysinghe, BSc, PhD Wales
Dr. Shahrul Ahmad, PhD Sheffield, UK
Dr. Muhammad Alam, PhD Tokyo Institute of Technology, Japan
Dr Krzysztof Babiuch: MSc: PhD: University of Jena, Germany
Dr. Abbas Barfidokht, PhD UNSW
Dr. Renxun Chen, BSc (Hons), PhD UNSW
Dr. Xiaoyu (Jet) Cheng, PhD UNSW
Dr. Soshan Cheong PhD Victoria University of Wellington
Dr. Moinul Choudhury, PhD UNSW
Dr. Kyloon Chuah, PhD UNSW
Dr Andrew Dolan, PhD, Imperial College London
Dr. Miroslav Dvorak, MS, PhD, Czech Technical University
Dr. Samantha Furfari, B.Sc.(Hons), PhD UNSW
Dr. Vinicus Goncales, PhD, USP, Brazil
Dr. Bakul Gupta, PhD UNSW
Dr. Aaron Harrison, PhD UWA
Dr. Kitty Ho, BSc (Hons), PhD, UNSW
Dr. Xiang-Guo Hu, PhD Institute of Chemistry, Chinese Academy of Sciences
Dr. Celine Hue, PhD Lille University of Science and Technology
Dr. George Iskander, BSc MSc PhD Khartoum, FRSC, MRSC, RACI
Dr. Scott Jamieson, PhD UNSW
Dr. Fehmida Kanodarwala, BSc MSc Wilson College – Mumbai India, PhD UNSW
Dr. Olha Krechkivska, BSc & MSc National University of Kyivmohyla, PhD U. Utah
Dr Samuel Kutty, BSc Hons UNSW, PhD UNSW
Dr. Kim Lapere, PhD Berkley
Dr. Hsiu Lin Li, BSc (Hons), PhD Monash
Dr Yibing Li, PhD Griffith University
Dr. Guillaume Longatte PhD P.A.S.T.E.U.R., Ecole Normale Supérieure, Paris
Dr. Rowan MacQueen, BSc, PhD USyd
Dr. Alison Magill, BSc (Hons), PhD UTas
Dr. Adam Martin, PhD UWA
Dr. Klaas Nauta, PhD UNC
Dr. Stephen Parker, PhD UNSW
Staff | 63
Dr. Alpesh Patel, MTech (Pharm) (NIPER: SAS Nagar, India), PhD Macquarie
Dr. Janjira Panchompoo, BSc, Chulalongkorn, DPhil, Oxford
Dr. Lydia Sandiford PhD Kings College London
Dr. Scott Sulway, MChem (Hons), PhD University of Manchester
Dr. Roya Tavallaie, PhD UNSW
Dr Trang To, PhD, Imperial College London
Dr. Hamish Toop, BSC (Hons) Adelaide, PhD UNSW
Dr. Robert Utama, PhD UNSW
Dr. James E.A. Webb, PhD, USYD
Dr. Fangtong Zhang, MASc UNSW, PhD USYD
Dr. YuanHui Zheng, PhD Monash
Visiting Fellows
Emeritus Scientia Professor
Michael Nicholas Paddon Row, BSc Lond, PhD ANU, CChem, FRSC, FRACI
Emeritus Professors
Roger Bishop, BSc St And., PhD Camb., CChem, FRSC, FRACI
David Brynn Hibbert, BSc PhD Lond., CChem, MRSC, FRACI
Conjoint Professors
Grainne Mary Moran, BSc PhD NUI, CChem, MRACI
Professorial Visiting Fellows
Alan Norman Buckley, BSc Syd., PhD Monash, MRACI
Margaret M. Harding Michael James, BSc Syd, PhD Cambridge, MRACI
Barbara Messerle, BSc PhD Syd
Ronald Postle PhD Leeds
Visiting Fellows
Dr Nicholas Armstrong, B.App.Sc (Hons 1st), PhD UTS
Dr Joseph John Brophy, BSc, PhD DSc UNSW, DipEd Monash, CChem, FRACI
Honorary Associate Professors
A/Prof. Roger Read, BSc PhD Syd., DIC Lond., CChem, FRACI
Adjunct Senior Lectuer
Dr. Alex Falber, Algae Enterprises Ltd, Victoria, Australia
Professional and Technical Staff
Administrative Support
Anne AyresKenneth Gerard McGuffin, BA Syd
Computer Officer
Ray Arnhold
Finance Officer
Amanda Troobnikoff, BSc (Hons) UTS
Laboratory Manager
Dr Toby Jackson, BSc (Hons) Exeter, PhD Aberdeen
Marketing
Lucy Stride
Student Services Manager
Steve Yannoulatos, BSc (Hons) UNSW
Technical Officers
Peta Di Bella, BSc (Hons) UQ
Dr Dominic Frances, PhD UNSW
Hitendra GopalBerta Litvak, BSc UTS, MEdAdmin UNSW
Michael McMahonDr Nancy Scoleri, BSc (Hon), PhD Adel.
Dr Ruth Thomas, BSc, PhD UNSW
Svetislav Videnovic,BChemEng, Sarajevo
School Store
Ian AldredShan Balachandran
64 | School of Chemistry Annual Report
Publications & Patents
DR LEIGH ALDOUS
Facile, room-temperature pre-treatment of rice husks with tetrabutylphosphonium hydroxide: Enhanced enzymatic and acid hydrolysis yields; BBY Lau, ET Luis, MM Hossain, WES Hart, B Cencia-Lay, JJ Black, TQ To, L. Aldous; Bioresource technology 2015, 197, 252-259
Combining thermogalvanic corrosion and thermogalvanic redox couples for improved electrochemical waste heat harvesting; HAH Alzahrani, JJ Black, D Goonetilleke, J Panchompoo, L Aldous; Electrochemistry Communications 2015, 58, 76-79
Pretreatment of macadamia nut shells with ionic liquids facilitates both mechanical cracking and enzymatic hydrolysis; WX Teh, MM Hossain, TQ To, L Aldous; ACS Sustainable Chemistry & Engineering 2015, 3 (5), 992-999
Phenazine virulence factor binding to extracellular DNA is important for Pseudomonas aeruginosa biofilm formation; T Das, SK Kutty, R Tavallaie, AI Ibugo, J Panchompoo, S Sehar, L Aldous, AWS Yeung, SR Thomas, N Kumar, JJ Gooding, M Manefield; Scientific reports 2015, 5, 8398
The effect of changing the components of an ionic liquid upon the solubility of lignin; WES Hart, JB Harper, L Aldous; Green Chemistry 2015, 17 (1), 214-218
Extraction and electrochemical detection of capsaicin and ascorbic acid from fresh chilli using ionic liquids; BBY Lau, J Panchompoo, L Aldous; New Journal of Chemistry 2015, 39 (2), 860-867 .
DR GRAHAM E. BALL
Howe, E. N. W.; Ball, G. E.; Thordarson, P. “Step-by-step DFT analysis of the cooperativity in the binding of cations and anions to a tetratopic ion-pairing host” Supramol. Chem. 2015, 27, 829-839.
Hong, K. K. C.; Ball, G. E.; Black, D. S.; Kumar, N. “The Mosaic of Rottlerin” J. Org. Chem., 2015, 80, 10668–10674.
Wang, F.; Jiang, Y.; Lawes, D. J.; Ball, G. E.; Zhou, C.; Liu, Z.; Amal, R. “Analysis of the Promoted Activity and Molecular Mechanism of Hydrogen Production over Fine Au–Pt Alloyed TiO2 Photocatalysts” ACS Catal., 2015, 5, 3924–3931.
McSkimming, A.; Chan, B.; Bhadbhade, M. M.; Ball, G. E.; Colbran, S. B. “Bio-Inspired Transition Metal-Organic Hydride Conjugates for Catalysis of Transfer Hydrogenation: Experiment and Theory” Chem. - Eur. J. 2015, 21, 2821..
DR JONATHON BEVES
H. Iranmanesh, M. Bhadbhade, M.; N. de Haas, E. T. Luis, H. Yan, J. Yang, J. E. Beves, Supramol. Chem. 2015, 854-864.
J.-F.Ayme, J. E. Beves, C. J. Campbell, G. Gil-Ramírez, D. A. Leigh, A. J. Stephens, J. Am. Chem. Soc. 2015, 137, 9812-9815.
J. E. Beves, J. J. Danon, D. A. Leigh, J.-F. Lemonnier, I. J. Vitorica-Yrezabal, Angew. Chem., Int. Ed. 2015, 54, 7555-7559.
J. Yang, M. Bhadbhade, W. A. Donald, H. Iranmanesh, E. G. Moore, H. Yan and J. E. Beves, Chem. Commun., 2015, 51, 4465 - 4468..
EMERITUS PROFESSOR ROGER BISHOP
Alshahateet SF, Bhadbhade MM, Bishop R, Scudder ML, Different solvents yield alternative crystal forms through aromatic, halogen bonding, and hydrogen bonding competition, CrystEngComm, 17, 877-888 (2015).
Alshahateet SF, Bhadbhade MM, Bishop R, Craig DC, Scudder ML, Halogen containing clusters N
2Br
2, N
2Br
4, S
2Br
4 and S
2Br
6 yield penannular
inclusion compounds, CrystEngComm, 17, 9111-9122 (2015).
Bishop R, Organic crystal engineering beyond the Pauling hydrogen bond, Invited Highlight article, CrystEngComm, 17, 7448-7460 (2015)..
PROFESSOR DAVID ST CLAIR BLACK
Biswas, N. N., Kutty, S. K., Barraud, N., Iskander, G. M., Griffith, R., Rice, S., Willcox, M., Black, D. StC. and Kumar, N., Indole-based novel small molecules for the modulation of bacterial signalling pathways, Org. Biomol. Chem., 13, 925-937 (2015).
Iskandar, G., Wood, K., Eiffe, E., Yee, E. M. H., Black, D. StC. and Kumar, N., Ritter reactions of isoflavonols: a facile route to 4-amidoisoflavans, Tetrahedron Letters, 56, 1941-1943 (2015)
Mielczarek, M., Thomas, R., Ma, C., Kandemir, H., Yang, X., Bhadbhade, M., Black, D. StC., Griffith, R., Lewis, P. J. and Kumar, N., Synthesis and biological activity of novel mono-indole and mono-benzofuran inhibitors of bacterial transcription initiation complex formation, Bioorganic and Medicinal Chemistry, 23, 1763-1775 (2015).
Kutty, S., Barraud, N., Ho, K. K. K., Iskander, G. M., Griffith, R., Rice, S. A., Bhadbhade, M., Willcox, M. D. P., Black, D. StC. and Kumar, N., Hybrids of acylated homoserine lactone and nitric oxide donors as inhibitors of quorum sensing and virulence factors in Pseudomonas aeruginosa, Org. Biomol. Chem., 13, 9850-9861 (2015).
Chen, Y., Cass, S. L., Kutty, S. K., Yee, E. M. H., Chan, D. S. H., Gardner, C. R., Vittorio, O., Pasquier, E., Black, D. StC. and Kumar, N., Synthesis, biological evaluation and structure-activity relationship studies of isoflavene based Mannich bases with potent anti-cancer activity, Bioorganic and Medicinal Chemistry, 25, 5377-5383 (2015).
Mielczarek, M., Bhadbhade, M., Chen, R., Kumar, N. and Black, D. StC., Bromination of 2,7′-bi-indolyls and quinazolin-7-ones, Tetrahedron, 71, 8925-8942 (2015).
Hong, K. K. C., Ball, G. E., Black, D. StC. and Kumar, N., The mosaic of rottlerin, J. Org. Chem., 80, 10668-10674 (2015).
DR JOSEPH J. BROPHY
Brophy, J.J., Clarkson, J.R., Deseo, M.A., Ford, A.F., Lawes, D.J., Leach, D.N. The leaf essential oil of Eugenia reinwardtiana (Blume) DC. (Myrtaceae) growing in Australia. Natural Products Commun., 10, 1611-1614 (2015).
PROFESSORIAL VISITING FELLOW, ALAN BUCKLEY
Buckley, A.N., Woods, R., Can sulfide minerals oxidize water to hydrogen peroxide during grinding in the absence of dissolved oxygen? Minerals & Metallurgical Processing, 2015, 32, 59-61..
Publications & Patents | 65
ASSOCIATE PROFESSOR STEPHEN BOYD COLBRAN
McSkimming, A; Chan, B; Bhadbhade, MM; Ball, GE; Colbran, SB: Bio-inspired transition metal–organic hydride conjugate for catalysis of transfer hydrogenation: Experiment and theory. Chemistry-a European Journal, 2015, 21, 2821-2834.
ASSOCIATE PROFESSOR MARCUS LAWFORD COLE
Cole, ML; Davies, AJ; Jones, C; Junk, PC;* McKay, AI; Stasch, A, Aluminium and Indium Complexes derived from Guanidines, Triazenes, and Amidines, Z. Anorg. Allg. Chem. 2015, 41, 2233-2244. Special Issue: Dedicated to Professor F. Ekkehardt Hahn on the Occasion of His 60th Birthday.
Furfari, SK; Gyton, MR; Twycross, D; Cole, ML, Air Stable NHCs, A Study of Stereoelectronics and Metallorganic Catalytic Activity, Chem. Commun. 2015, 51, 74-76.
Leverett, AR; McKay, AI; Cole, ML, The stabilization of gallane and indane by a ring expanded carbene,
Dalton Trans. 2015, 44, 498-500.
Cole, ML; Junk, PC, Synthesis and Structural Characterization of Some New Magnesium Formamidinates, Z. Anorg. Allg. Chem. 2015, 41, 2624-2629.
Bruce, MI; Cole, ML; Ellis, BG; Gaudio, M; Nicholson, BK; Parker, CR; Skelton, BW; White, AH, The series
of carbon-chain complexes {Ru(dppe)Cp*}2{μ-(C′C)x} (x = 4-8, 11): Synthesis, structures, properties and some reactions, Polyhedron 2015, 86, 43-56..
DR WILLIAM ALEX DONALD
Leeming, M. G.; Isaac, A. P.; Pope, B. J.; Cranswick, N.; Wright, C. E.; Ziogas, J.; O’Hair, R. A. J.; Donald, W. A. High-Resolution Twin-Ion Metabolite Extraction (HiTIME) Mass Spectrometry: Nontargeted Detection of Unknown Drug Metabolites by Isotope Labeling, Liquid Chromatography Mass Spectrometry, and Automated High-Performance Computing. Analytical Chemistry, 2015, 87, 4104.
Zenaidee, M. A.; Donald, W. A. Extremely supercharged proteins in mass spectrometry: profiling the pH of electrospray generated droplets, narrowing charge state distributions, and increasing ion fragmentation. Analyst, 2015, 140, 1894.
Zenaidee, M. A.; Donald, W. A. Electron capture dissociation of extremely supercharged protein ions formed by electrospray ionisation. Analytical Methods, 2015, 7, 7132.
Stephens, E. R.; Dumlao, M.; Xiao, D.; Zhang, D.; Donald, W. A. Benzylammonium Thermometer Ions: Internal Energies of Ions Formed by Low Temperature Plasma and Atmospheric Pressure Chemical Ionization. Journal of the American Society for Mass Spectrometry, 2015, 25, 2081.
Leeming, M. G.; Gamon, L. F.; Wille, U.; Donald, W. A.; O’Hair R. A. J. What Are the Potential Sites of Protein Arylation by N-Acetyl-p-benzoquinone Imine? Chemical Research in Toxicology, 2015, 28, 2224.
Yang, J.; Bhadbhade, M.; Donald, W. A.; Iranmanesh, H.; Moore, E. G.; Yan, H.; Beves, J. E. Self-assembled supramolecular cages containing ruthenium(II) polypyridyl complexes. Chemical Communications, 2015, 51, 4465.
PROFESSOR LESLIE D. FIELD
Leslie D. Field, Nilay Hazari, Hsiu L. Li, “Nitrogen Fixation Revisited on Iron(0) Dinitrogen Phosphine Complexes”, Inorg. Chem. 2015, 54, 4768-4776
Leslie D. Field, Hsiu L. Li, Alison M. Magill, Organic Structures from 2D NMR Spectra, John Wiley & Sons: Chichester, 2015. ISBN: 978-1-118-86894-2.
Leslie D. Field, Hsiu L. Li, Alison M. Magill, Instructor’s Guide and Solutions Manual to Organic Structures from 2D NMR Spectra, John Wiley & Sons: Chichester, 2015. ISBN: 978-1-119-02725-6..
SCIENTIA PROFESSOR J. JUSTIN GOODING
S. Ciampi, M.H. Choudhury, S.A.B.A. Ahmad, N. Darwish, A. Le Brun, J.J. Gooding, The impact of surface coverage on the kinetics of electron transfer through redox monolayers on a silicon electrode surface, Electrochim. Acta 186 216-222 (2015).
Choudhury, S. Ciampi, Y. Yang, R. Tavallaie, Y. Zhu, L. Zarei, V.R. Goncales, J.J. Gooding, Connecting electrodes with light: one wire, many electrodes, Chem. Sci. 6 6769-6776 (2015).
Y.H. Zheng, A. Soeriyadi, L. Rosa, S.H. Ng, U. Bach, J.J. Gooding, Reversible gating of smart plasmonic molecular traps using thermoresponsive polymers for single-molecule detection, Nature Comm. 6 Art. No. 8797 (2015).
L. Carter, K. Chuah, R. Tavallaie, A. Barfidokht, S.G. Parker, J.J. Gooding, Switching “on and off” faradaic electrochemistry at an otherwise passivated electrode using gold-coated magnetic nanoparticles, Electrochem. Comm. 61 93-96 (2015).
R. Tavallaie, N. Darwish, D.B. Hibbert, J.J. Gooding, Nucleic-acids recognition interfaces: How the greater conformational flexibility of RNA affects sensor performance, Chem. Comm. 51 16526-16529 (2015).
X. Cheng, E. Hinde, D.M. Owen, S.B. Lowe, P.J. Reece, K. Gaus, J.J. Gooding, Enhancing Quantum Dots for Bioimaging using Advanced Surface Chemistry and Advanced Optical Microscopy: Application to Silicon Quantum Dots (SiQDs), Adv. Mater. 27 6144-6150 (2015).
M. Sriram, K. Zong, S.R.C. Vivekchand, J.J. Gooding, Single nanoparticle plasmonic nanosensors, Sensors, 15 25774-25792 (2015) doi:10.3390/s151025774
B. Gupta, K. Mai, S.B. Lowe, D. Wakefield, N. Di Girolamo, K. Gaus, P.J. Reece, J.J. Gooding, Ultrasensitive and specific measurement of protease activity using functionalized photonic crystals, Anal. Chem. 87 9946-9953 (2015).
D. Liana, B. Raguse, J.J. Gooding, E. Chow, Toward Paper-Based Sensors: Turning Electrical Signals into an Optical Readout System, ACS Appl. Mater. Interfaces 7 19201-19209 (2015).
K. Guo, A.H. Soeriyadi, H. Feng, A. Prévoteau, S.A. Patil, J.J. Gooding, K. Rabaey, Heat-treated stainless steel felt: a scalable anodic material for bioelectrochemical systems, Bioresource Tech. 195 4650 (2015).
Y. Lu, J.R. Peterson, J.J. Gooding N.A. Lee, Development of a Competitive ELISA for the Detection of 4-tert-Octylphenol in Seafood, Food Anal. Meth. 8 1923-1932 (2015).
X. Zhang, Q. Li, X. Jin, C. Jiang, Y. Lu, R. Tavallaie, J.J. Gooding, Quantitative determination of target gene with electrical sensor, Scientific Reports 5 12539 (2015).
S.G. Parker, J.J. Gooding, Single-cell isolation devices: Understanding the behaviour of cells, Proc. Royal Soc. New S. Wales, 148 70-81 (2015)
R. Tavallaie, S. De Almeida, J.J. Gooding, Towards biosensors for the detection of circulating microRNA as a cancer biomarker: An overview of the challenges and successes, WIRES Nanomedicine & Nanobiotechnology 7 580-592 (2015).
Y.Y. Lee, S.G. Parker, A. Barfidokht, M.T. Alam, D.B. Walker, B.A. Messerle, J.J. Gooding, A Ruthenium Based Organometallic Complex For Biosensing that is both a Stable Redox Label and a Homobifunctional Linker, Electroanalysis 27 1078-1085 (2015)
K. Liu, Y.H. Zheng, X. Lu, T. Thai, N.A. Lee, U. Bach, J.J. Gooding, Biocompatible Gold Nanorods: One-Step Surface Functionalization, Highly Colloidal Stability, and Low Cytotoxicity, Langmuir 31 4973-4980 (2015).
Tregubov, D.B. Walker, K. Vuong, J.J. Gooding, B.A. Messerle, The advantages of covalently attaching organometallic catalysts to a carbon black support: Recyclable Rh(I) complexes that deliver enhanced conversion and product selectivity, Dalton Trans. 44 7917-7926 (2015).
C.K. Wong, A.J. Laos, A.H. Soeriyadi, J. Wiedenmann, P.M.G. Curmi, J.J. Gooding, C.P. Marquis, M.H. Stenzel, P. Thordarson, Polymersomes Prepared from Thermoresponsive Fluorescent Protein–Polymer Bioconjugates: Capture of and Report on Drug and Protein Payloads, Angew. Chem. Int. Ed. 54 5317-5322 (2015).
Jiang, M.T. Alam, S.G. Parker, J.J. Gooding, Zwitterionic Phenyl Phosphorylcholine on Indium Tin Oxide: A Low-Impedance Protein-Resistant Platform for Biosensing, Electroanalysis, 27 884-889 (2015).
T. Das, S. Kutty, R. Tavallaie, J. Panchompoo, S. Sehar, L. Aldous, A. Yeung, S. Thomas, N. Kumar, J.J. Gooding, M. Manefield, Phenazine virulence factor binding to extracellular DNA represents new target for bacterial infection control, Scientific Reports 5 8398 Art. No. (2015)
H. Qiao, A.H. Soeriyadi, B. Guan, P.J. Reece, J.J. Gooding, The Analytical Performance of a Porous Silicon Bloch Surface Wave Biosensors as Protease Biosensor, Sensors Actuators B 211 469-475 (2015).
M.T. Alam, J.J. Gooding, Modification of Carbon Electrode Surfaces in Electrochemistry of Carbon Electrodes Ed. R.C. Alkre, P.N. Bartlett, J. Lipkowski, Wiley-VCH Germany 16 211-240 (2015), ISBN 978-527-33732-3
66 | School of Chemistry Annual Report
DR RONALD STANLEY HAINES
Keaveney, S.T.; Francis, D. V.; Cao, W.; Haines, R. S.; Harper, J. B.*: “The effect of modifying the anion of an ionic liquid on the outcome of an S
N2 process”, Australian Journal of Chemistry,
2015, 68, 31-35.
Keaveney, S.T., Haines, R.S., Harper, J.B., Developing principles for predicting ionic liquid effects on reaction outcome. The importance of the anion in controlling microscopic interactions, Org. Biomol. Chem., 2015, 13 (12), 3771 - 3780
Keaveney, S.T., Haines, R.S., Harper, J.B., Ionic liquid effects on a multistep process. Increased product formation due to enhancement of all steps, Org. Biomol. Chem., 2015, 13, 8925 - 8936
DR JASON BRIAN HARPER
Francis, D. V.; Harper, J. B.; Read, R. W.*: “Fluorous 1,2,3-Triazol-4-ylmethyl Amines and Amine Derivatives for Novel Surfactant Applications”, Australian Journal of Chemistry, 2015, 68, 57-68.
Butler, B. J.; Harper, J. B.*: “The effect of an ionic liquid on the rate of reaction at a phosphorus centre”, New Journal of Chemistry, 2015, 39, 213-219.
Hart, W. E. S.; Harper, J. B.*; Aldous, L.*: “The effect of changing the components of an ionic liquid upon the solubility of lignin”, Green Chemistry, 2015, 17, 214-218.
Yau, H. M.; Haines, R. S.*; Harper, J. B.*: “A robust, ‘one-pot’ method for acquiring kinetic data for Hammett plots used to demonstrate transmission of substituent effects in reactions of aromatic ethyl esters”, Journal of Chemical Education, 2015, 92, 538-542.
Keaveney, S. T.; Harper, J. B.*; Croft, A. K.*: “Computational approaches to understanding reaction outcomes of organic processes in ionic liquids”, RSC Advances, 2015, 5, 35709-35729.
George, S. R. D.; Frith, T. D. H.; Thomas, D. S.; Harper, J. B.*: “Putting corannulene in its place. Reactivity studies comparing corannulene with other aromatic hydrocarbons”, Organic and Biomolecular Chemistry, 2015, 13, 9035-9041.
George, S. R. D.; Elton, T. E.; Harper, J. B.*: “Electronic effects on the substitution reactions of benzhydrols and fluorenyl alcohols. Determination of mechanism and effects of antiaromaticity”Organic and Biomolecular Chemistry, 2015, 13, 10745-10750.
George, S. R. D.; Elton, T. E.; Harper, J. B.*: “Electronic effects on the substitution reactions of benzhydrols and fluorenyl alcohols. Determination of mechanism and effects of antiaromaticity”, Organic and Biomolecular Chemistry, 2015, 13, 10745-10750.
EMERITUS PROFESSOR D. BRYNN HIBBERT
Hejazi, L.; Guilhaus, M.; Hibbert, D. B.; Ebrahimi, D., Gas chromatography with parallel hard and soft ionization mass spectrometry. Rapid Communications in Mass Spectrometry 2015, 29, 91–99, DOI: 10.1002/rcm.7091
Alexander Weremfo, Paul Carter, D. Brynn Hibbert, and Chuan Zhao, Investigating the Interfacial Properties of Electrochemically Roughened Platinum Electrodes for Neural Stimulation, Langmuir, (2015) 31(8): 2593 – 2599. DOI: 10.1021/la504876n
Tavallaie R, Darwish N, Hibbert DB, Gooding JJ. Nucleic-acid recognition interfaces: how the greater ability of RNA duplexes to bend towards the surface influences electrochemical sensor performance. Chemical Communications 2015:51 16526 - 16529.
Badiola, K. A.; Bird, C.; Brocklesby, W. S.; Casson, J.; Chapman, R. T.; Coles, S. J.; Cronshaw, J. R.; Fisher, A.; Frey, J. G.; Gloria, D.; Grossel, M. C.; Hibbert, D. B.; Knight, N.; Mapp, L. K.; Marazzi, L.; Matthews , B.; Milsted, A.; Minns, R. S.; Mueller, K. T.; Murphy, K.; Parkinson, T.; Quinnell, R.; Robinson, J. S.; Robertson, M. N.; Robins, M.; Springate, E.; Tizzard, G.; Todd, M. H.; Williamson, A. E.; Willoughby, C.; Yang, E.; Ylioj, P. M., Experiences with a researcher-centric ELN. Chemical Science 2015, 6 (3), 1614-1629
DR LUKE HUNTER
Yap, D. Q. J.; Cheerlavancha, R.; Lowe, R.; Wang, S.; Hunter, L. “Investigation of cis- and trans-4- fluoroprolines as enantioselective catalysts in a variety of organic transformations,” Australian Journal of Chemistry, 2015, 68, 44–49.
Absalom, N.; Yamamoto, I.; O’Hagan, D.; Hunter, L.; Chebib, M. “Probing the mode of neurotransmitter binding to GABA receptors using selectively fluorinated GABA analogues,” Australian Journal of Chemistry, 2015, 68, 23–30.
PROFESSOR SCOTT HENDERSON KABLE
Resonance-Enhanced 2-Photon Ionization Scheme for C
2 through a newly identified band system:
43Pg ← a3P
u O. Krechkivska, K. Nauta, T.D.
Kreuscher, S.H. Kable, T.W. Schmidt,* G.B. Bacskay T.P. Troy, J. Chem. Phys., 119, 12102-12108 (2015).
2. Development, Evaluation and Use of a Student Experience Survey in Undergraduate Science Laboratories: The ASELL Student Laboratory Learning Experience (ASLE) Survey, S.C. Barrie, R.B. Bucat, M.A. Buntine, K. Burke da Silva, G.T. Crisp, A.V. George, I.M. Jamie, S.H. Kable*, K.F. Lim, S.M. Pyke, J.R. Read, M.D. Sharma and A. Yeung, Int. J. Sci. Educ. 37, 1795-1814 (2015).
3. New Role of Curcumin: as Multicolor Photoinitiator for Polymer Fabrication under Household UV to Red LED Bulbs, J. Zhao , J. Lalevée, H. Lu, R. MacQueen, S.H. Kable, T. W.Schmidt, M. H. Stenzel,* and P. Xiao*, Polymer Chemistry, 6, 5053-5061 (2015).
4. H and D Attachment to Naphthalene: Spectra and Thermochemistry of Cold Gas-Phase 1-C10
H9 and 1-C
10H
8D Radicals and
Cations, O. Krechkivska, C.M. Wilcox, B. Chan, R. Jacob, Y. Liu, K. Nauta, S.H. Kable, L. Radom, and T.W. Schmidt*, J. Phys. Chem. A 119, 3225-3232 (2015).
5. Atmospheric oxidation intermediates: Laser spectroscopy of resonance-stabilized radicals from p-cymene, T.P. Troy, M.J.Y. Tayebjee, K. Nauta, S.H. Kable, T.W. Schmidt*, Chem. Phys. Lett. 620, 129-133 (2015).
PROFESSOR NARESH KUMAR
Ho K. K., Kutty, S., Chan, D., Chen, R., Willcox, M., Kumar, N., Development of Fimbrolides, Halogenated Furanones and their Analogues as Antimicrobial Agents, In E. Ivanova and R. Crawford (Eds): Antibacterial Surface Design, Springer International,149-170, (2015).
Goh, Wai-Kean, Gardner CR, Chandra Sekhar KVG, Biswas NN, Nizalapur S, Rice SA, Willcox M, Black DStC, Kumar N, Synthesis, quorum sensing inhibition and docking studies of 1,5-dihydropyrrol-2-ones, Bioorganic & Medicinal Chemistry, 23:7366-7377, (2015).
Biswas, N. N., Kutty, S. K., Barraud, N., Iskander, G. M., Griffith, R., Rice, S., Willcox, M., Black, D. StC. and Kumar, N., Indole-based novel small molecules for the modulation of bacterial signalling pathways, Org. Biomol. Chem., 13, 925-937 (2015)
Iskandar, G., Wood, K., Eiffe, E., Yee, E. M. H., Black, D. StC. and Kumar, N., Ritter reactions of isoflavonols: a facile route to 4-amidoisoflavans, Tetrahedron Letters, 56, 1941-1943 (2015).
Das, D., Kutty, S. K., Tavallaie, R., Panchompoo, J., Sehar, S., Aldous, L., Yeung, A., Thomas, S., Kumar, N., Gooding, J. J., Manfield, M., Bacterial pathogen secondary metabolite interaction with extracellular DNA and interruption with antioxidants, Nature Scientific Reports, 5 (8398), 1-9 (2015).
Mielczarek, M., Thomas, R., Ma, C., Kandemir, H., Yang, X., Bhadbhade, M., Black, D. StC., Griffith, R., Lewis, P. J. and Kumar, N., Synthesis and biological activity of novel mono-indole and mono-benzofuran inhibitors of bacterial transcription initiation complex formation, Bioorganic and Medicinal Chemistry, 23, 1763-1775 (2015).
Pandika, K., Koshy, P., Ho, K. K. K., Kumar, N., and Sorrell CC, Photocatalytic TiO2 Thin Films on Fluorinated Ethylene Propylene Copolymer (FEP) Substrates, J. Aust. Ceram. Soc., 51(2),160-170 (2015).
Kutty, S., Barraud, N., Ho, K. K. K., Iskander, G. M., Griffith, R., Rice, S. A., Bhadbhade, M., Willcox, M. D. P., Black, D. StC. and Kumar, N., Hybrids of acylated homoserine lactone and nitric oxide donors as inhibitors of quorum sensing and virulence factors in Pseudomonas aeruginosa, Org. Biomol. Chem., 13, 9850-9861 (2015)
Chen, Y., Cass, S. L., Kutty, S. K., Yee, E. M. H., Chan, D. S. H., Gardner, C. R., Vittorio, O., Pasquier, E., Black, D. StC. and Kumar, N., Synthesis, biological evaluation and structure-activity relationship studies of isoflavene based Mannich bases with potent anti-cancer activity, Bioorganic and Medicinal Chemistry, 25, 5377-5383 (2015).
Mielczarek, M., Bhadbhade, M., Chen, R., Kumar, N. and Black, D. StC., Bromination of 2,7′-bi-indolyls and quinazolin-7-ones, Tetrahedron, 71, 8925-8942 (2015).
Hong, K. K. C., Ball, G. E., Black, D. StC. and Kumar, N., The mosaic of rottlerin, J. Org. Chem., 80, 10668-10674 (2015).
Publications & Patents | 67
DR HONGXU LU
Lu, H.; Blunden, B. M.; Scarano, W.; Lu, M.; Stenzel, M. H., Anti-metastatic effects of RAPTA-C conjugated polymeric micelles on two-dimensional (2D) breast tumor cells and three-dimensional (3D) multicellular tumor spheroids. Acta Biomaterialia 2015, 32, 68-76.
Dag, A.; Lu, H.; Stenzel, M. H., Controlling the Morphology of Glyco-nanoparticles in Water using Block Copolymer Mixtures: effect on cellular uptake. Polym. Chem. 2015, 6, (45), 7812-7820.
Jiang, Y.; Lu, H.; Chen, F.; Callari, M.; Pourgholami, M.; Morris, D. L.; Stenzel, M. H., PEGylated Albumin based Polyion Complex Micelles for protein delivery. Biomacromolecules 2016, 17, (3), 808-817.
Dag, A.; Callari, M.; Lu, H.; Stenzel, M. H., Modulating the cellular uptake of platinum drugs with glycopolymers. Polym. Chem. 2016, 7, (5), 1031-1036.
Jiang, Y.; Lu, H.;Dag, A.; Hart-Smith, G.; Stenzel, M. H., Albumin-polymer conjugate nanoparticles and their interactions with prostate cancer cells in 2D and 3D culture: comparison between PMMA and PCL. Journal of Materials Chemistry B 2016, 4, (11), 2017-2027.
ASSOCIATE PROFESSOR SHELLI RENEE MCALPINE
Synthesis of the natural product Marthiapeptide A, Yuqi Zhang, Amirul Islam, and Shelli R. McAlpine*, Org. Lett. V17, p5149-5151
Blocking the heat shock response and depleting HSF-1 levels through heat shock protein 90 (hsp90) inhibition: A significant advance over current chemotherapies Yen Chin Koay, Jeanette R. McConnell, Yao Wang, and Shelli R. McAlpine* RSC Advances V5, 59003-59013 2015
Regulating the master regulator: controlling heat shock factor-1 as a chemotherapeutic Jeanette R. McConnell, Laura K Buckton, and Shelli R. McAlpine*
Bioorg. Med. Chem Lett. V25, 3409-3414 2015
Thioimidazoline based compounds reverse glucocorticoid resistance in acute lymphoblastic leukemia cells, Cara Toscan, Marwa Rahimi, Mohan Bhadbhade, Russell Pickford, Shelli R. McAlpine* and Richard Lock*, Org. Biomol. Chem. V13, 6299-6312 2015
Predicating the unpredictable: recent examples of biologically active heterocycle-containing macrocycles, Hendra Wahyudi and Shelli R. McAlpine*, Bioorganic Chem. V60, 74-97 2015
Activation of the Nuclear Factor kB inducing kinase inducing kinase as a mechanism of beta cell failure in obesityElisabeth K. Malle, Nathan W. Zammit, Stacey N. Walters, Yen Chin Koay, Jianmin, Wu, Bernice, M. Tan, Jeanette E. Villanueva, Robert Brink, Tom Loudovaris, James Cantley, Shelli R. McAlpine, Daniel Hesselson, Shane T. Grey*, J. Exp. Med. V212, 1239-1254 2015
Hsp47: The new heat shock protein therapeutic target George Sharbeen, Shelli R. McAlpine, Phoebe Phillips*In Press Springer Books: “Heat shock Proteins: Success Stories” DOI: 10.1007/7355_2015_89
Are some Hsp90 therapies more effective than others? Evaluating dual Hsp90 and Hsp70 inhibition as an anticancer therapy, Laura K Buckton, Yao Wang, Jeanette R. McConnell, and Shelli R. McAlpine*In Press Springer Books: “Heat shock Proteins: Success Stories” DOI: 10.1007/7355_2015_96.
Heat shock protein 27: structure, function, cellular Role and inhibitors Rashid Mehmood* and Shelli R. McAlpine*, In Press Springer Books: “Heat shock Proteins: Success Stories” DOI: 10.1007/7355_2015_94
Targeting the c-terminus of heat shock protein 90 as a cancer therapy Jeanette R McConnell, Yao Wang, Shelli R. McAlpine*, In Press Springer Books: “Heat shock Proteins: Success Stories” DOI: 10.1007/7355_2015_93
C-terminal heat shock protein 90 modulators produce desirable oncogenic properties Yao Wang and Shelli R. McAlpine*,Org. Biomol. Chem: V13, 4627-4631, 2015
Combining an Hsp70 inhibitor with either an N-terminal and C-terminal hsp90 inhibitor produces mechanistically distinct phenotypes Yao Wang and Shelli R. McAlpine*, Org. Biomol. Chem. V13, 3691-3698 2015
Heat shock protein 90 inhibitors: will they ever succeed as chemotherapeutics? Yao Wang, and Shelli R. McAlpine*, Future Med. Chem. V7, 2, 87-90 2015
Regulating the cytoprotective response in cancer cells using simultaneous inhibition of Hsp90 and Hsp70 Yao Wang, and Shelli R. McAlpine*, Org. Biomol. Chem. V13, 2108-2116 2015
Design, Synthesis and anticancer activity of linked azoles Amirul Islam, Yuqi Zhang, Yao Wang, and Shelli R. McAlpine* Med. Chem. Comm. V6, 300-305 2015
The fungal natural product (1S, 3S)-austrocortirubin induces DNA damage via a mechanism unique from other DNA damaging agents Yao Wang ∞,Md. Amirul Islam ∞, Rohan A. Davis, and Shelli R. McAlpine*, Bioorg. Med. Chem Lett. V25, 249-253 2015
N-terminal and C-terminal modulation of hsp90 produce dissimilar phenotypes Yao Wang and Shelli R. McAlpine*, Chem. Comm. V51, 1410-1413 2015, Chem. Comm. V51, 1410-1413 2015
ASSOCIATE PROFESSOR JONATHAN CHARLES MORRIS
Toop, H. D., Don, A. S., & Morris, J. C. (2015). Synthesis and biological evaluation of analogs of AAL(S) for use as ceramide synthase 1 inhibitors. Organic and Biomolecular Chemistry, 13(48), 11593-11596. doi:10.1039/c5ob01931a
Li, J. J.; Maltby, S.; Xiang, Y.; Eyers, F.; Hatchwell, L.; Toop, H. D.; Morris, J. C.; Nair, P.; Mattes, J.; Foster, P. S.; Yang, M. (2015). MicroRNA-9 regulates steroid-resistant airway hyperresponsiveness by reducing protein phosphatase 2A activity. Journal of Allergy and Clinical Immunology, 136(2), 462-473. doi:10.1016/j.jaci.2014.11.044
Rahman, M. M., Rumzhum, N. N., Morris, J. C., Clark, A. R., Verrills, N. M., & Ammit, A. J. (2015). Basal protein phosphatase 2A activity restrains cytokine expression: Role for MAPKs and tristetraprolin. Scientific Reports, 5. doi:10.1038/srep10063
DR VINH NGUYEN
Anh S. Hoang, Thi H. Tran, Hong N. Nguyen, Hong S. Vu, Thanh P. Vo, Chi M. Phan and Thanh V. Nguyen, Korean J. Chem. Eng. 2015, 32, 1598-1605: “Synthesis of Oxime from a Renewable Resource for Metal Extraction”.
Thanh V. Nguyen,* Demelza J. M. Lyons, Chem. Commun. 2015, 51, 3131-3134: “A Novel Aromatic Carbocation-based Coupling Reagent for Esterification and Amidation Reactions”.
Anh S. Hoang, Hong N. Nguyen, Nam Q. Bui, Hong S. Vu, Thanh P. Vo, Thanh V. Nguyen, Chi M. Phan, Miner. Eng. 2015, 79, 88-93: “Extraction of gallium from Bayer liquor using extractant produced from cashew nutshell liquid“.
Van C. Nguyen, Thanh V. Nguyen, Chi M. Phan, Colloids Surf., A 2015, 482, 365-370: “Dynamic Adsorption of a Gemini Surfactant at the Air/Water Interface“.
PROFESSORIAL VISITING FELLOW, RON POSTLE
W.Y. Wong, J.K.C. Lam, C.W.Kan and R.Postle. ‘In Vitro Assessment of Ultraviolet Protection of Coloured Cotton Knitted Fabrics with Different Structures under Stretched and Wet Conditions’. Radiation Protection Dosimetry, Vol 164, Number 3, pages 325-334, Oxford, Jan 2015 (online doi:10.1093/rpd/ncu276).
Ron Postle. ‘Fibrous Materials and Wearable Technologies in a Nonlinear Interactive World’. Keynote Paper, The 13th Asian Textile Conference, Nov 2015, Geelong, Australia.
Gehui Wang, Jing Dai, Jiajing Cai and Ron Postle. ‘Performance of UV Protection Finish with HTUV100 on Knitted Cotton Fabric for Summer Clothing’. 13th Asian Textile Conference, Nov 2015, Geelong, Australia.
Gehui Wang, Wenxia Yue and Ron Postle. ‘Clothing Pressure and Elongation Performance For Elastic Knitted Fabrics’. 13th Asian Textile Conference, Nov 2015, Geelong, Australia.
Ron Postle. ‘Wearable Technologies in a Nonlinear World’ Plenary Paper, Advances in Material Engineering, International Conference, Technical University, TUL, Liberec, Czech Republic, Dec, 2015.
Wai-yin Wong, Jimmy Kwok-cheong Lam, Chi-wai Kan and Ron Postle. ‘Influence of Reactive Dyes on Ultraviolet Protection of Cotton Knitted Knitted Fabrics with Different Fabric Constructions’. Textile Research J, online doi:10.1177/0040517515591776, June 2015.
HONORARY ASSOCIATE PROFESSOR ROGER W. READ
D. V. Francis, J. B. Harper, R. W. Read, (2015) Fluorous 1,2,3-Triazol-4-ylmethyl Amines and Amine Derivatives for Novel Surfactant Applications, Aust. J. Chem. 68, 57-68. http://dx.doi.org/10.1071/CH14458
I. –W. Hidayat, M. Bhadbhade, R. W. Read, (2015) A Study of the Microwave-Accelerated Condensation of Substituted Benzaldehydes with 3-Substituted Hydantoins and the Unexpected Interception of Alcohol Products, Procedia Chem. 17, 75-83. http://creativecommons.org/licenses/by-nc-nd/4.0/
68 | School of Chemistry Annual Report
R. Gohari, M. Mosaddegh, F. Naghibi, B. Eslami-Tehrani, A. Priani, M. Hamseloo-Moghadam, R. W. Read, (2015) Cytotoxic sesquiterpene lactones from the aerial parts of Inula aucheriana, Anais da Academia Brasileira de Ciências, 87, 777-785. http://dx.doi.org/10.1590/0001-3765201520140063
M. Keller, C. Tränkle, X. She, A. Pegoli, G. Bernhardt, A. Buschauer, R. W. Read, (2015) M
2
Receptor preferring dibenzodiazepinone-type muscarinic receptor ligands: homo-dimerization increases allosteric binding, Bioorg. Med. Chem. 23, 3970-3990. http://dx.doi.org/10.1016/j.bmc.2015.01.015
J. Matschullat,* L. H. Armbrecht, H. Bachor, K. Bremhorst, M. Christian, S. Kanjanabootra, P. Lennox, D. Lowe, W. A. Matthews, P. Medwell, P. Mulvaney, P. Nelson, I. Nicholls, R. Read, C. Rizos, L. Spiccia, Y. Zhang, (2015) An Interhemispheric Perspective on Environment and Energy, International Journal of Performability Engineering, 11, 521-536.
PROFESSOR TIMOTHY SCHMIDT
Andrew Nattestad, Catherine Simpson, Tracey Clarke, Rowan William MacQueen, Yuen Yap Cheng, Adam Trevitt, Attila Janos Mozer, Pawel Wagner, Timothy W Schmidt “An Intermediate Band Dye-sensitised Solar Cell Using Triplet-Triplet Annihilation,” Phys. Chem. Chem. Phys., 17, 24826-24830 (2015).
Olha Krechkivska, George B. Bacskay, Tyler P. Troy, Klaas Nauta, Thomas D. Kreuscher, Scott H. Kable, and Timothy W. Schmidt “A Resonance-Enhanced 2-Photon Ionization Scheme for C
2
Through a Newly Identified Band System: 43Pg -
a3Pu,” The Journal of Physical Chemistry A, 119,
12102–12108 (2015).
Andrew Danos, Rowan W. MacQueen, Yuen Yap Cheng, Miroslav Dvorak, Tamim A. Darwish, Dane Robert McCamey, and Timothy W Schmidt “Deuteration of Perylene Enhances Photochemical Upconversion Efficiency,” The Journal of Physical Chemistry Letters, 6, 3061–3066 (2015).
Jiacheng Zhao, Hongxu Lu, Jacques Lalevée, Rowan William MacQueen, Timothy W Schmidt, Martina Heide Stenzel, Scott Kable, Pu Xiao “New Role of Curcumin: as Multicolor Photoinitiator for Polymer Fabrication under Household UV to Red LED Bulbs,” Polymer Chemistry, 6, 5053-5061 (2015).
Yanying Li , Raphael Clady , Ann F Marshall, Junghyun Park , Shruti Vivek Thombare, Gerentt Chan, Timothy W Schmidt, Mark Brongersma, and Paul C McIntyre “Ultrafast Carrier Dynamics of a Photo-Excited Germanium Nanowire-Air Metamaterial,” ACS Photonics, 2, 1091–1098 (2015).
Murad J. Y. Tayebjee, Dane R. McCamey and T. W. Schmidt “Beyond Shockley-Queisser: Molecular Approaches to High Efficiency Photovoltaics,” Journal of Physical Chemistry Letters, 6(12), 2367–2378 (2015).
Gerard D. O’Connor, Gabrielle V. G. Woodhouse, Tyler P. Troy, Timothy W. Schmidt, “Double-resonance spectroscopy of radicals: higher electronic excited states of 1-and 2-naphthylmethyl, 1-phenylpropargyl and 9-anthracenylmethyl,” Molecular Physics, 113, 2138-2147 (2015).
Olha Krechkivska, Callan M. Wilcox, Bun Chan, Rebecca Jacob, Yu Liu, Klaas Nauta, Scott H. Kable, Leo Radom, Timothy W. Schmidt, “H and D Attachment to Naphthalene: Spectra and Thermochemistry of Cold Gas-Phase 1-C10H9 and 1-C10H8D Radicals and Cations,” The Journal of Physical Chemistry A 119(13), 3225-3232 (2015).
Tyler P. Troy, Murad J. Y. Tayebjee, Klaas Nauta, Scott H. Kable, and Timothy W. Schmidt, “Atmospheric oxidation intermediates: Laser spectroscopy of resonance-stabilized radicals from p-cymene,” Chemical Physics Letters 620 (0), 129-133 (2015).
Kabilan Sripathy, Rowan W. MacQueen, Joshua R. Peterson, Yuen Yap Cheng, Miroslav Dvorak, Dane R. McCamey, Neil D. Treat, Natalie Stingelin, and Timothy W. Schmidt, “Highly efficient photochemical upconversion in a quasi-solid organogel,” Journal of Materials Chemistry C 3 (3), 616-622 (2015).
Tim F. Schulze and Timothy W. Schmidt, “Photochemical upconversion: present status and prospects for its application to solar energy conversion,” Energy & Environmental Science 8 (1), 103-125 (2015).
DR NEERAJ SHARMA
“Rate dependent performance related to crystal structure evolution of Na
0.67Mn
0.8Mg
0.2O
2 in a
sodium-ion battery” N Sharma*, N Tapia-Ruiz, G Singh, AR Armstrong, JC Pramudita, HEA Brand, J Billaud, PG Bruce, T Rojo*, Chemistry of Materials, 27, 6976−6986 DOI: 10.1021/acs.chemmater.5b02142, IF: 8.354
“Structural evolution of mixed valent (V3+/V4+) and V4+ sodium vanadium fluorophosphates as cathodes in sodium-ion batteries: Comparisons, overcharging and mid-term cycling” V Palomares*, P Serras, HEA Brand, T Rojo, N Sharma*, Journal of Materials Chemistry A, 3, 23017-23027 DOI: 10.1039/c5ta03780h IF: 7.443
“Introducing a 0.2 V Sodium-ion Battery Anode: The Na
2Ti
3O
7 to Na
3-xTi
3O
7 Pathway” A Rudola,
N Sharma, P Balaya*, Electrochemistry Communications, 61, 10-13 DOI: 10.1016/j.elecom.2015.09.016 IF: 4.847
“Understanding structure-function relationship in hybrid Co
3O
4-Fe
2O
3/C lithium-ion battery
electrodes” I Sultana, MM Rahman, T Ramireddy, N Sharma, D Poddar, H Zhang, Y Chen, AM Glushenkov*, ACS Applied Materials & Interfaces, 7, 20736–20744 DOI: 10.1021/acsami.5b05658 IF: 6.723
“Ammonia-Storage in Lithium Intercalated Fullerides” D Pontiroli, D D’Alessio, M Gaboardi, G Magnani, C Milanese, S Duyker, VK Peterson, N Sharma, M Riccò*, Journal of Materials Chemistry A, 3, 21099–21105 DOI: 10.1039/c5ta05226b IF: 7.443
“A comprehensive picture of the current rate dependence on the structural evolution of P2-Na
2/3Fe
2/3Mn
1/3O
2” N Sharma*, MH Han, JC
Pramudita, E Gonzalo, HEA Brand, T Rojo*, Journal of Materials Chemistry A, 3, 21023–21038 DOI: 10.1039/c5ta04976h IF: 7.443
“In-situ Neutron Diffraction Study of a High Voltage Li(Ni
0.42Mn
0.42Co
0.16)O
2/Graphite Pouch Cell” J Li,
R Petibon, S Glazier, N Sharma, WK Pang, VK Peterson, JR Dahn*, Electrochimica Acta, 180, 234–240 DOI: 10.1016/j.electacta.2015.08.122 IF: 4.504
“In Situ Neutron Powder Diffraction of Li6C
60 for
Hydrogen Storage” M Gaboardi, S Duyker, C Milanese, G Magnani, VK Peterson, D Pontiroli, N Sharma, M Ricco*, Journal of Physical Chemistry C, 119, 19715–19721 DOI: 10.1021/acs.jpcc.5b06711. IF: 4.772
“In situ powder diffraction studies of electrode materials in rechargeable batteries” N Sharma*, WK Pang, Z Guo, VK Peterson, ChemSusChem, 8, 2826 – 2853 DOI: 10.1002/cssc.201500152 IF: 7.657
“The unique structural evolution of the O3-phase Na
2/3Fe
2/3Mn
1/3O
2 during high rate charge/
discharge: A sodium-centred perspective” N Sharma*, E Gonzalo, JC Pramudita, MH Han, HEA Brand, JN Hart, WK Pang, Z Guo, T Rojo*, Advanced Functional Materials, 25, 4994-5005 DOI: 10.1002/adfm.201501655 IF: 11.805
“The use of deuterated ethyl acetate in highly concentrated electrolyte as a low-cost solvent for in-situ neutron diffraction measurements of Li-ion battery electrodes” R Petibon, J Li, N Sharma, WK Pang, VK Peterson, JR Dahn*, Electrochimica Acta, 174, 417-423 DOI: 10.1016/j.electacta.2015.05.169 IF: 4.504
“Interplay between electrochemistry and phase evolution of the P2-type Na
x(Fe
1/2Mn
1/2)O
2
cathode for use in sodium-ion batteries” WK Pang, S Kalluri, VK Peterson*, N Sharma, J Kimpton, B Johannessen, HK Liu, SX Dou, ZP Guo*, Chemistry of Materials, 27, 3150–3158 DOI: 10.1021/acs.chemmater.5b00943, IF: 8.354
“In situ Neutron Diffraction Monitoring of Li
7La
3Zr
2O
12 formation: Towards a Rational
Synthesis of Garnet Solid Electrolytes” RP Rao, W Gu, N Sharma, VK Peterson, M Avdeev, S Adams*, Chemistry of Materials, 27, 2903–2910 DOI: 10.1021/acs.chemmater.5b00149, IF: 8.354
“Evaluation of undoped and M-doped TiO2,
where M = Sn, Fe, Ni/Nb, Zr, V, and Mn, for lithium-ion battery applications prepared by the molten-salt method” MV Reddy*, N Sharma*, S Adams*, RP Rao, VK Peterson, BVR Chowdari, RSC Advances, 5, 29535-29544 DOI: 10.1039/c5ra00206k, IF: 3.84
“Graphene and selected derivatives as negative electrodes in sodium and lithium-ion batteries” JC Pramudita, D Pontiroli, G Magnani, M Gaboardi, M Riccò, C Milanese, HEA Brand, N Sharma*, ChemElectroChem, 2, 600-610 DOI: 10.1002/celc.201402352
“Using in situ synchrotron X-ray diffraction to study lithium- and sodium-ion batteries: A case study with an unconventional battery electrode, Gd
2TiO
5” JC Pramudita, R Aughterson, WM
Dose, SW Donne, HEA Brand, N Sharma*, Journal of Materials Research, 30, 381-389 DOI: 10.1557/jmr.2014.311. IF: 1.647
“Structural evolution of electrodes in the NCR and CGR cathode-containing commercial lithium-ion batteries cycled between 3.0 and 4.5 V: An operando neutron powder-diffraction study” WK Pang, M Alam, VK Peterson, N Sharma*, Journal of Materials Research, 30, 373-380 DOI: 10.1557/jmr.2014.297. IF: 1.647.
PROFESSOR MARTINA STENZEL
C. K. Wong, A. J. Laos, A. H. Soeriyadi, J. Wiedenmann, P. M. G. Curmi, J. J. Gooding, C. P. Marquis, M. H. Stenzel, P. Thordarson, Polymersomes Prepared from Thermoresponsive Fluorescent Protein-Polymer
Publications & Patents | 69
Bioconjugates: Capture of and Report on Drug and Protein Payloads, Angew. Chem.-Inter. Ed. 2015, 54, 5317-5322.
J. Zhao, J. Lalevee, H. Lu, R. MacQueen, S. H. Kable, T. W. Schmidt, M. H. Stenzel, P. Xiao, A new role of curcumin: as a multicolor photoinitiator for polymer fabrication under household UV to red LED bulbs, Polym. Chem. 2015, 6, 5053-5061.
P. Xiao, J. Lalevee, J. Zhao, M. H. Stenzel, N-Vinylcarbazole as Versatile Photoinaddimer of Photopolymerization under Household UV LED Bulb (392 nm), Macromol. Rapid Commun. 2015, 36, 1675-1680.
R. H. Utama, Y. Jiang, P. B. Zetterlund, M. H. Stenzel, Biocompatible Glycopolymer Nanocapsules via Inverse Miniemulsion Periphery RAFT Polymerization for the Delivery of Gemcitabine, Biomacromolecules 2015, 16, 2144-2156.
K. W. Fan, J. J. Roberts, P. J. Martens, M. H. Stenzel, A. M. Granville, Copolymerization of an indazole ligand into the self-polymerization of dopamine for enhanced binding with metal ions, J. Mater. Chem. B 2015, 3, 7457-7465.
R. H. Utama, M. Dulle, S. Foerster, M. H. Stenzel, P. B. Zetterlund, SAXS Analysis of Shell Formation During Nanocapsule Synthesis via Inverse Miniemulsion Periphery RAFT Polymerization, Macromolecul. Rapid Commun. 2015, 36, 1267-1271.
W. Scarano, P. de Souza, M. H. Stenzel, Dual-drug delivery of curcumin and platinum drugs in polymeric micelles enhances the synergistic effects: a double act for the treatment of multidrug-resistant cancer, Biomater. Sci. 2015, 3, 163-174.
S. Pearson, D. Vitucci, Y. Y. Khine, A. Dag, H. Lu, M. Save, L. Billon, M. H. Stenzel, Light-responsive azobenzene-based glycopolymer micelles for targeted drug delivery to melanoma cells, Eur. Polym. J. 2015, 69, 616-627.
S. Pearson, H. Lu, M. H. Stenzel, Glycopolymer Self-Assemblies with Gold(I) Cornplexed to the Core as a Delivery System for Auranofin, Macromolecules 2015, 48, 1065-1076.
L. Noorani, M. Stenzel, R. Liang, M. H. Pourgholami, D. L. Morris, Albumin nanoparticles increase the anticancer efficacy of albendazole in ovarian cancer xenograft model, J. Nanobiotech. 2015, 13.
H. Lu, R. H. Utama, U. Kitiyotsawat, K. Babiuch, Y. Jiang, M. H. Stenzel, Enhanced transcellular penetration and drug delivery by crosslinked polymeric micelles into pancreatic multicellular tumor spheroids, Biomater. Sci. 2015, 3, 1085-1095.
Y. Y. Khine, Y. Jiang, A. Dag, H. Lu, M. H. Stenzel, Dual-Responsive pH and Temperature Sensitive Nanoparticles Based on Methacrylic Acid and Di(ethylene glycol) Methyl Ether Methacrylate for the Triggered Release of Drugs, Macromol. Bioscience 2015, 15, 1091-1104.
Y. Jiang, C. K. Wong, M. H. Stenzel, An Oligonucleotide Transfection Vector Based on HSA and PDMAEMA Conjugation: Effect of Polymer Molecular Weight on Cell Proliferation and on Multicellular Tumor Spheroids, Macromol. Bioscience 2015, 15, 965-978.
F. Ishizuka, R. H. Utama, S. Kim, M. H. Stenzel, P. B. Zetterlund, RAFT inverse miniemulsion periphery polymerization in binary solvent mixtures for synthesis of nanocapsules, Eur. Polym. J. 2015, 73, 324-334.
J. Eliezar, W. Scarano, N. R. B. Boase, K. J. Thurecht, M. H. Stenzel, In Vivo Evaluation of Folate Decorated Cross-Linked Micelles for the Delivery of Platinum Anticancer Drugs, Biomacromolecules 2015, 16, 515-523.
W. Du, H. Lu, M. H. Stenzel, Core-Cross-Linking Accelerates Antitumor Activities of Paclitaxel-Conjugate Micelles to Prostate Multicellular Tumor Spheroids: A Comparison of 2D and 3D Models, Biomacromolecules 2015, 16, 1470-1479.
Dag, J. Zhao, M. H. Stenzel, Origami with ABC Triblock Terpolymers Based on Glycopolymers: Creation of Virus-Like Morphologies, ACS Macro Letters 2015, 4, 579-583.
Dag, H. Lu, M. H. Stenzel, Controlling the morphology of glyco-nanoparticles in water using block copolymer mixtures: the effect on cellular uptake, Polym. Chem. 2015, 6, 7812-7820.
Dag, Y. Jiang, K. J. Abd Karim, G. Hart-Smith, W. Scarano, M. H. Stenzel, Polymer-Albumin Conjugate for the Facilitated Delivery of Macromolecular Platinum Drugs, Macromol Rapid Commun. 2015, 36, 890-897.
Y. Chen, M. S. Lord, A. Piloni, M. H. Stenzel, Correlation between Molecular Weight and Branch Structure of Glycopolymers Stars and Their Binding to Lectins, Macromolecules 2015, 48, 346-357.
M. Blunden, M. H. Stenzel, Incorporating ruthenium into advanced drug delivery carriers-an innovative generation of chemotherapeutics, J. Chem. Tech. Biotech. 2015, 90, 1177-1195.
K. Babiuch, A. Dag, J. Zhao, H. Lu, M. H. Stenzel, Carbohydrate-Specific Uptake of Fucosylated Polymeric Micelles by Different Cancer Cell Lines, Biomacromolecules 2015, 16, 1948-1957.
Book chapter:J. Zhao, M. H. Stenzel, “Worm-Like Micelles and
Vesicles: Adjusting the Morphology of Self-Assembled Fructose Based Block Copolymers by Fine-Tuning the Processing Parameters” in Controlled Radical Polymerization, Vol 2: Materials, Vol. 1188, Eds.: K. Matyjaszewski, B. S. Sumerlin, N. V. Tsarevsky, J. Chiefari, 2015, pages 91-105.
S. R. Ting, M. H. Stenzel, “Synthesis of Glycopolymers by Direct Polymerisation” in Synthesis of Glycopolymers and their Applications, Eds. R. Becer and L. Hartman, Royal Society of Chemistry RSC, 2015, pages 17-76.
ASSOCIATE PROFESSOR JOHN ARRON STRIDE
Phase transformations in CdSe quantum dots induced by reaction time; F.K. Kanodarwala and J.A. Stride, Mater. Lett., 2015, 141, 67-69.
Low temperature reduction of CCl4 to fullerenes
using metallic sodium; M. Choucair, M.R. Hill and J.A. Stride Mater. Chem. & Phys., 2015, 154, 38-43.
Understanding the packing in the 1:1 molecular complex 1,3,5-tricyanobenzene-hexamethylbenzene lattice modes; J.A. Stride, CrystEngComm., 2015, 17, 3787-3792.
Air-stable PbS quantum dots synthesized with slow reaction kinetics via a PbBr
2 precursor; L. Yuan,
R. Patterson, W. Cao, Z. Zhang, J.A. Stride, S. Huang, G. Conibeer, P. Reece, Z. Zhang, RSC Advances, 2015, 5, 68579-68586.
Effect of acid or alkaline catalyst and of different capping agents on the optical properties of CdS nanoparticles incorporated within a diureasil hybrid matrix; L. Goncalves, C.J. Silva, F.K. Kanodarwala, J.A. Stride, M.R. Pereira, Opt. Mater., 2015, 49, 171-181.
Kesterite Cu2ZnSnS
4 thin film solar cells by a facile
DMF-based solution coating process; F. Liu, S. Shen, F. Zhou, N. Song, X. Wen, J.A. Stride, K. Sun, C. Yan, X. Hao, J. Mater. Chem. C, 2015, 3, 10783-10792.
Effect of Halide Treatments to PbSe Quantum Dot Thin Films: Stability, Hot Carrier Lifetime and Application to Photovoltaics; Z. Zhang, J. Yang, X. Wen, L. Yuan, S. Shrestha, J.A. Stride, G. Conibeer, R. Patterson, S. Huang, J. Phys. Chem. C, 2015, 119, 24149-24155.
Exploring the Application of Quaternary Metastable Wurtzite Nanocrystals in Pure-sulfide Cu
2ZnSnS
4 Solar Cells by Forming Nearly
Micron-sized Large Grains; X. Liu, F. Zhou, N. Song, C. Yan, F. Liu, K. Sun, J.A. Stride, J. Chen, X. Hao, M.A. Green, J. Mater. Chem. A, 2015, 3, 23185-23193..
ASSOCIATE PROFESSOR PALL THORDARSON
Dong Sub Kim, Jinho Chang, Soojung Leem, Jung Su Park, Pall Thordarson, and Jonathan L. Sessler, Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics, Journal of the American Chemical Society, 2015, 137, 16038-16042.
Chin Ken Wong, Alistair J. Laos, Alexander H. Soeriyadi, Jörg Wiedenmann, Paul M. G. Curmi, J. Justin Gooding, Christopher P. Marquis, Martina H. Stenzel and Pall Thordarson, Polymersomes Prepared from Thermoresponsive Fluorescent Protein-Polymer Bioconjugates which can both Encapsulate and Reveal the Location of Drug and Protein Payloads, Angewandte Chemie International Edition, 2015, 54, 5317-5322 (Hot Paper as selected by the editors).
Adam D. Martin, Andrew B. Robinson, and Pall Thordarson, Biocompatible small peptide super-hydrogelators bearing carbazole functionalities, Journal of Materials Chemistry B., 2015, 3, 2277-2280.
Md. Musfizur Hassan, Adam D. Martin, and Pall Thordarson, Macromolecular crowding and hydrophobic effects on Fmocdiphenylalanine hydrogel formation in PEG:water mixtures, Journal of Materials Chemistry B., 2015, 3, 9269-9276.
Warren Ty Truong, Yingying Su, Danmar Gloria, Filip Braet and Pall Thordarson, Dissolution and degradation of Fmoc-diphenylalanine self-assembled gels results in necrosis at high concentrations in vitro, Biomaterials Science, 2015, 3, 298-307.
70 | School of Chemistry Annual Report
Ethan N. W. Howe, Graham E. Ball and Pall Thordarson, Step-by-step DFT analysis of the cooperativity in the binding of cations and anions to a tetratopic ion-pairing host, Supramolecular Chemistry, 2015, 27, 829-839.
Robert D. Healey, Shiva Prasad, Vijaya Rajendram and Pall Thordarson, Unravelling the interaction between a-cyclodextrin with the thaumatin protein and a peptide mimic, Supramolecular Chemistry, Supramolecular Chemistry, 2015, 27, 414-419.
Galen L. Eakins, Rishi Pandey, Jonathan P. Wojciechowski, Han Yue Zheng, James E. A. Webb, Céline Valéry, Pall Thordarson, Natalie O. V. Plank, Juliet A. Gerrard and Justin M. Hodgkiss, Functional Organic Semiconductors Assembled via Natural Aggregating Peptides, Advanced Functional Materials, 2015, 25, 5640-5649.
Galen L. Eakins, Jonathan P. Wojciechowski, Adam D. Martin, James E. A. Webb, Pall Thordarson and Justin M. Hodgkiss, Chiral Effects in Peptide-Substituted Perylene Imide Nanofibers, Supramolecular Chemistry, 2015, 27, 746-756.
Shofiur Rahman, Ahmed Zein, Lousise N. Dawe, Grigory Shamov, Pall Thordarson and Paris E. Georghiou, Supramolecular host-guest complexation of Lash’s calix[4]azulene with tetraalkylammonium halides and tetrafluoroborate salts: binding and DFT computational studies, RSC Advances, 2015, 5, 54848-54852.
Paul J. Thomassen, Shaji Varghese, Edward J. A. Bijsterveld, Pall Thordarson, Johannes A. A. W. Elemans, Alan E. Rowan and Roeland J. M. Nolte, A Double-Cavity-Containing Porphyrin Host as a Highly Stable Epoxidation Catalyst, European Journal of Organic Chemistry, 2015, 5246-5253.
Kamonchanok Thananukul, Pakkamon Jarruwale, Nuchada Suttenun, Pall Thordason and Patchara Punyamoonwongsa, Silk Semi-interpenetrating Network Hydrogels for Biomedical Applications, Macromolecular Symposia, 2015, 354, 251-257.
PROFESSOR RICHARD TILLEY
A. J. McGrath, Y-H. Chien, S. Cheong, D. A. J. Herman, J. Watt, A. M. Henning, L. O. Gloag, C-S. Yeh, R. D. Tilley, ‘Gold over Branched Palladium Nanostructures for Photothermal Cancer Therapy’ ACS Nano, 9,12283–1229, (2015). (IF = 12.881).
*6. B. F. P. McVey, J. Butkus, J. E. Halpert, J. M. Hodgkiss, R. D. Tilley, ‘Solution Synthesis and Optical Properties of Transition-Metal-Doped Silicon Nanocrystals’ Journal of Physical Chemistry Letters, 6, 1573-1576, (2015). (IF = 7.458)
2. D. A. J. Herman, S. Cheong, A. J. McGrath, B. F. P. McVey, M. Lein and R. D. Tilley, ‘How to choose a precursor for decomposition solution-phase synthesis: the case of iron nanoparticles’ Nanoscale, 7, 5951-5954, (2015). (IF = 7.394)
3. H. Barron, G. Opletal, R. D. Tilley and A. S. Barnard ‘Dynamic evolution of specific catalytic sites on Pt Nanoparticles’ Catalysis, Science & Technology, (2015). (IF = 5.426)
4. S. Papst, M. A Brimble, C. W Evans, D. J Verdon, V. Feisst, P. R. Dunbar, R. D. Tilley, D. E. Williams, ‘Cell-targeted platinum nanoparticles and nanoparticle clusters’ Organic & Biomolecular Chemistry, 13, 6567–6572, (2015). (IF = 3.562)
ASSOCIATE PROFESSOR CHUAN ZHAO
Xunyu Lu, Wai-Leung Yim, Bryan H.R. Suryanto and Chuan Zhao, Electrocatalytic oxygen evolution at surface-oxidized multiwall carbon nanotubes, J. Am. Chem. Soc., 2015, 137, 2901-2907.
C.Y. Chen,Bryan H.R. Suryanto and Chuan Zhao, Xuchuan Jiang and Aibin Yu, Direct hydrothermal synthesis of carbonaceous silver nanocables and nanotubes for electrocatalytic application, Small, 2015, 11, 3556.
Xunyu Lu and Chuan Zhao, Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities, Nat. Commun., 2015, 6, 6616.
Majid Asnavandi, Bryan Suryanto and Chuan Zhao, Controlled electrodeposition of nanostructured Pd thin films from protic ionic liquids for electrocatalytic oxygen reduction reactions, RSC Advances, 2015, 5, 74017-74023.
Zhanwu Lei, Long Chen, Wenliang Wang, Zenglin Wang, Chuan Zhao, Tetrazole derived levelers for filling electroplated Cu microvias: electrochemical behaviors and quantum calculations, Electrochimica Acta, 178 (2015) 546–554.
Xunyu Lu, Hubert M. Chan, C-L Sun, C-M Tseng and Chuan Zhao, Interconnected core–shell carbon nanotube–graphene nanoribbon scaffolds for anchoring cobalt oxides as bifunctional electrocatalysts for oxygen evolution and reduction, StartFragmentJ. Mater. Chem. A, 2015, 3, 13371-13376.EndFragment
Alexander Weremfo, Paul Carter, David Brynn Hibbert and Chuan Zhao, Investigating the interfacial properties of electrochemically-roughened platinum electrodes for neural stimulation. Langmuir, 2015, 31, 2593−2599.
Junlin Yan, Hairui Lei, Yang Kang, Chuan Zhao, Yu Fang, Ferrocene-containing thixotropic molecular gels: creation and a novel strategy for water purification, J. Colloid Interface Sci., 2015, 448, 374 - 379.
Stefania Piantavigna, Muhammad E. Abdelhamid, Chuan Zhao, Xiaohu Qu, George A. McCubbin, Bim Graham, Leone Spiccia, Anthony P. O’Mullane, and Lisandra L. Martin, Mechanistic details of the membrane perforation and passive translocation of TAT peptides, ChemPlusChem, 2015, 80, 83–90.
Richard Gondosiswanto, Xunyu Lu and Chuan Zhao, Preparation of metal-free nitrogen-doped graphene via direct electrochemical exfoliation of graphite in ammonium nitrate, Aust. J. Chem., 2015, 68(5) 830-835.
Publications & Patents | 71
72 | School of Chemistry Annual Report
Grants and Research Fellowships
AUSTRALIAN RESESARCH COUNCIL
Discovery Projects
Investigator(s) $ Project
Prof. M. Stenzel 120,000Learning from nature: Creating synthetic viruses using self-assembled structures with branched or dendritic glycopolymers on their surfaces
A/Prof C. Zhao 110.000 Tuning the Electrolytes for High Efficiency Solar Splitting of Water
Prof Young Prof. D.B. Hibbert, Prof, Zhiang
50,000Heat-resisting iron-nickel base alloys in challenging new applications – oxygen permeabilities and resistance to internal oxidation
Dr J.B. Harper 120,000 Getting the reaction outcomes you want: towards solvent-controlled reactivity in ionic liquids
A/Prof P. Thordarson 110,000 How are self-assembled gels formed? From trial-and-error to rational molecular design
Prof. N. Kumar, Prof. D. Black, Prof. M. Willcox
130,000 Novel peptide mimics for the disruption of chemical communication in bacteria
Dr L. Hunter, Dr E. Pasquier 115,000Fine-tuning the conformations of cyclic peptides: a paradigm for optimising synthetic efficiency and biological activity
Prof. M. Stenzel, A/Prof. J.C. Morris, Prof. Pourgholami
130,000 Polyion complex micelles as smart nano-sized drug carriers for proteins.
A/Prof. S.B. Colbran, Prof L.D. Field, Dr G.E. Ball
110,000 A new metalloprotein-inspired methodology for energy-efficient chemical reduction
Prof. S.H. Kable, Prof. T. Schmidt 172,400 Reactive Intermediates in Atmospheric and Combustion Chemistry (New)
Dr J. Beves 82,249 Light-driven Supramolecular Reactors (New)
Prof J.J. Gooding, Prof Ciampi 170,000 Light Activated Electrochemistry: Microelectrode Arrays with just one wire (New)
A/Prof C. Zhao, Prof. D.B. Hibbert 129,000 Miniaturised Ionic liquid Systems: Design, Electrochemistry and Application (New)
ARC Laureate Fellowship
Investigator(s) $ Project
Prof J.J. Gooding 130,932 The first generation of single entity measurement tools for analysis
Grants and Research Fellowships | 73
Linkage Program
Investigator(s) $ Project
Prof. N. Kumar, M. Willcox, N. Cole 95,000 Antimicrobial contact lens cases
M. Willcox, Prof. N. Kumar, N. Cole, N. James
80,000 Novel antimicrobial surface coatings for biomedical applications
Prof J.J. Gooding, Prof T.P. Davis, Prof M. Kavallaris
175,000 The development of tuneable materials to allow the three-dimensional printing of cells
A/Prof. P. Thordarson, Dr J.M. Hodgkiss, Dr A. Falber
102,000 Controlling light-harvesting with complex perylene arrays
Prof. Suanning, A/Prof. C. Zhao, Emeritus Prof. D.B. Hibbert, et al
26,700 Chip-Scale Implantable Bionics for Next Generation Therapeutic Neural Prostheses arrays
Prof J.J. Gooding, Prof Williams (Agamatrix), Prof M. Kavallaris
100,000 A gold-coated magnetic nanoparticle biosensor for detecting microRNA (New)
LIEF: Linkage Infrastructure, Equipment and Facilities Funding
Investigator(s) $ Project
Prof. K. Gaus, Prof. J.J. Gooding, T. Boecking, et al
560,000 Single molecule imaging laboratory
Industrial Transformation Training Centre
Investigator(s) $ Project
Prof. J.J. Gooding et al 700,000 Training Centre for Advanced Technologies in Food Manufacture
DECRA: Discovery Early Career Researcher Award
Investigator(s) $ Project
Dr W.A. Donald 125,000Strike while the iron is hot – Structure and reactivity of Fe-oxo complexes that mimic C-H bond activating enzymes
Dr L. Aldous 94,544 Lignin in Ionic Liquids: Electrochemical approaches towards Delignification and Depolymerisation
Dr. H. Lu 125,000 Nanoparticle uptaking of cell culture grown on micropatterned surfaces
Dr. V. Nguyen 120,000 Organocatalysis: A new horizon for synthesis of organic structures
Dr. P. Xiao 129.937 Surface coated nanodiamonds as drug delivery carriers and simultaneous imaging
Future Fellowship
Investigator(s) $ Project
A/Prof. Thordarson, P. 205,714 Moving Supramolecular Assembly of Functional Systems into Water
Prof. T.W. Schmidt 217,873 Nanostructured upconvertors for advanced solar energy harvesting
Centre of Excellence
Investigator(s) $ Project
Prof. J.J. Gooding, A/Prof. P. Thordarson, et al
3,714,285 ARC Centre of Excellence in Convergent Bio-Nano Science and Technology
Industrial Transformation Training Centres
Investigator(s) $ Project
Arcot, Lee, Wills, Gooding, Fleet, et al 700,000 Advanced Technologies in Food Manufacture
74 | School of Chemistry Annual Report
NATIONAL HEALTH & MEDICAL RESEARCH COUNCILInvestigator(s) $ Project
A/Prof S.R. McAlpine 148,000 Developing novel molecules that target hormone receptors as an alternative cancer therapy
Dr Alexander H. Soeriyadi 77,359Peter Doherty Fellowship: Photonic Crystals for Probing Enzyme Activity: Single cells vs Bulk Measurement.
Prof. J.J. Gooding 189, 187 HbA1c biosensor
Prof. N. Kumar, Prof. M. Wilcox, Prof. F. Stapleton
196,724 Development of antimicrobial contact lenses
UNIVERSITY OF NEW SOUTH WALES GRANTS
Science Faculty Research Program
Investigator(s) $ Project
Dr G.E. Ball 10,000 Activating alkanes – a positively charged approach
A/Prof. M.L. Cole 20,000 New Routes to Heavy Main Group Hydride
Early Career Researcher
Investigator(s) $ Project
Dr W.A. Donald 10,000 High-throughput characterisation of ligand-protein binding
Dr. N. Sharma 5,000 A new method to realise zero thermal expansion materials
Dr. Y. Zheng 5,000 Multifunctional plasmonic architectures for anti-counterfeiting and security application
Dr. H. Lu 5,000 Drug delivery of HPMA-based micelles in breast tumour histoids mimicking tumour classification
Gold Star
Investigator(s) $ Project
A/Prof. J.C. Morris 40,000 Modulators of alternative splicing as novel therapeutics in prostate cancer
Silver Star
Investigator(s) $ Project
Prof. N. Kumar 35,000 Antimicrobial biomaterials to reduce implant-related bacterial infections
UNSW Learning & Teaching: Strategic Development Grant
Investigator(s) $ Project
Prof S Kable, Dr L Hunter, Dr R Haines, A/Prof S Colbran
137,000 A scientific portfolio approach to laboratory skills assessment
UNSW Faculty of Science Visiting Research Fellowship
Investigator(s) $ Project
A/Prof. S.B. Colbran 6,000 Prof. E. Norlander, Lund University
Grants and Research Fellowships | 75
AUSTRALIAN GRANTSInvestigator(s) $ Project Source
A/Prof. P. Thordarson 25,000 The supramolecular chemistry of natural sweeteners Neptune Bio-Innovations
Prof. S.H. Kable, et al 637,000Advancing Science and Engineering by Laboratory Learning in Schools
Australian Maths and Science Partnerships Program
Prof J.J. Gooding, Chaffey (Panorama Synergy)
177,310Development of a MEMS based Hydrogen Detector using LumiMEMS
Research Connections Grant
Prof. N. Kumar 36,000 Bone substitute Australian Industry
Dr. N. Sharma 100,000Developing improved materials for energy generation and storage
Australian Institute of Nuclear Science and Engineering
Dr. N. Sharma 5,400Using advanced techniques to understand and develop new materials for energy storage devices
Australian Academy of Science France-Australia Science Innovation Collaboration (FASIC)
A/Prof. J. Stride 82,948 Environmentally friendly surfactants Research Connections
INTERNATIONAL GRANTSInvestigator(s) $ Project Source
Dr W.A. Donald, Prof. JJ Gooding, M.Dumlao
26,500
Surface selective ionization mass spectrometry (SelectION-MS) for the detection of chemical warfare agent simulants and their degradation products in complex mixtures
The Organisation for the Prohibition of Chemical Weapons – International Cooperation Branch (The Hague, The Netherlands)
Dr J. Beves 18,000 Photo-active Metallosupramolecular AssembliesNational Natural Science Foundation of China (NSFC China)
A/Prof. J.C. Morris 79,000 Consulting services agreement EXONATE LTD (UK)
A/Prof. J.C. Morris 100,000 Tripartite research agreement EXONATE LTD (UK)
Dr. V. Nguyen, Prof D. Enders 5,300 Organocatalysis – A new tool for drug discovery Go8-DAAD seeding grant
76 | School of Chemistry Annual Report
Industry and Community Interaction | 77
Industry and Community Interaction
Listed below are the companies, government authorities, societies and educational institutions that academic staff interacted with in 2015.
¡ Aachen University, Germany
¡ Abo Akademi University, Finland
¡ AgaMatrix Inc
¡ Allegra Orthopeadics
¡ American Chemical Society Petroleum Research Fund
¡ ANSTO
¡ Arizona State University, USA
¡ Armstrong Legal, Bannisters Lawyers
¡ Auckland University, New Zealand
¡ Australian Government Analytical Laboratory
¡ Australian National University
¡ Australian Research Council (ARC)
¡ Australian Wool Innovation (AWI)
¡ Australian Wool Testing Authority (AWTA)
¡ Blue water Legal
¡ Broad Institute
¡ CDM Lawyers
¡ Centre for Marine Bio-Innovations
¡ CIC Energigune, Spain
¡ Cochlear Ltd
¡ CSIRO
¡ Curtin University
¡ Dalhousie University, Canada
¡ Deutschen Forschungsgemeinschaft (DFG), Germany
¡ Deakin University
¡ Donghua Univertsity, Shanghai, China
¡ Durham University, UK
¡ Elie Rahme Lawyers.
¡ Exonate Ltd.
¡ Fitzroy Legal
¡ Flawless Technologies
¡ Garvan Institute
¡ Greyhound Racing (VIC, TAS & NSW)
¡ Harness Racing NSW
¡ Harvard University
¡ Helmholtz Zentrum, Berlin
¡ Heriot-Watt University, UK
¡ Hunter Legal
¡ ICMCB, France
¡ Imperial College, London
¡ Institut National Des Sciences Appliquees, Toulouse
¡ Institute of Chemistry of Organometallic Compounds, Florence, Italy
¡ Institute of High Performance Computing, Singapore
¡ Intellectual Ventures
¡ Inventia Life Sciences
¡ Ionic Industries Pty. Ltd.
¡ Ixom (formerly Orica Chemicals)
¡ King and Wood Mallesons
¡ KK Lawyers
¡ Kohodo Sunshine Energy Ltd. China
¡ Legal Aid NSW
¡ Legal Aid Victoria
¡ Lowy Cancer Research Centre
¡ Mae Fah Luang University, Thailand
¡ Mark Wainwright Analytical Centre, UNSW
¡ Marsden Research Grants, NZ
¡ Memorial University of newfoundland, Canada
¡ Metrobiotech
¡ Minter Ellison
¡ Monash University
¡ Mutah University, Jordan.
¡ National Measurement Institute
¡ National Research Council, Florence, Italy
¡ National Taiwan University, Taiwan
¡ National University, Singapore
¡ Neptune Clean Australia
¡ New Zealand Racing
¡ O’Connor, Ruddy & garrett
¡ Oxford University, UK
¡ Paris University, France.
¡ Panorama Synergy
¡ PharmAxis Ltd.
¡ Princeton University, USA
¡ Qingdao University, China
¡ Racing NSW
¡ RMIT
¡ Shannxi Normal University, China.
¡ Tatung University, Taiwan
¡ The Scripps Research Institute, USA
¡ University of the Basque Country, Spain
¡ University of California, Davis, USA
¡ University of Malaya
¡ University of Melbourne
¡ University of Nancy and Ecole des Mines, Paris
¡ University of New Caledonia
¡ University of Newcastle
¡ University of Otago, NZ
¡ University of Parma, Italy
¡ University of Queensland
¡ University of South Australia
¡ University of Sydney
¡ University of Technology Sydney
¡ University of Texas, Austin USA
¡ University of Westerns Australia
¡ University of Wollongong
¡ UNSW - BABS
¡ UNSW Chemical Engineering
¡ UNSW Children’s Cancer Institute Australia
¡ UNSW Faculty of Medicine
¡ UNSW School of Mining Engineering
¡ UNSW School of Opthomology
¡ UNSW School of Physics
¡ Victoria University, Wellington
78 | School of Chemistry Annual Report
School Visiting Committee 2015 | 79
School Visiting Committee 2015
External Representatives from Industry, Government and Education
Prof. Bruce Sutton (Chair)Honorary Professor (Agronomy),
The University of Sydney
Prof. Brian YatesExecutive Director for Engineering,
Mathematics and Information Sciences - ARC
Dr. Christopher ArmstrongDirector, Office of the NSW Chief Scientist
and Engineer
Dr. Cathy Foley Chief, CSIRO Materials Science & Engineering
Dr. Paul Kelly Managing Director – OneVentures
Mr Leo Hyde DuPont
Mrs Roslynne Moxham Principal, Fort Street High School
Dr. Timothy Wright Headmaster, Shore Grammar
Ex Officio MembersProfessor Scott Henderson Head, School of Chemistry
Scientia Professor Justin Gooding Deputy Head, School of Chemistry
A/Prof. Pall Thordarson Director of Research, School of Chemistry
Dr. Jason Harper Director of Teaching, School of Chemistry
The Committee has representatives from our key stakeholder organisations – industry, government, schools and government research institutes. The terms of reference for the committee are as follows:
1. To appraise the School programs in light of the needs of the School stakeholders (industry, government, schools and research institutions).
2. To provide advice about the direction that the School should take to best enhance future interactions with our stakeholders.
3. To provide advice about the changing needs of industry, research and government organisations to best prepare the School’s graduates for future opportunities.
4. To receive and discuss the School of Chemistry’s Annual Report.
5. To aid the development of the School in any other way possible.
80 | School of Chemistry Annual Report
Obituaries | 81
Obituaries
PROFESSOR JAMES S. SHANNON 11 July 1926 – 15 May 2015Jim Shannon’s name is inextricably associated with mass spectrometry, as his scientific career
was devoted to its development and applications to organic, biological and coordination chemistry.
Jim was born in Adelaide on 11 July 1926 and studied at the University of Adelaide, graduating in
1949 with first class honours in Chemistry. After some further postgraduate work, he went in 1952
to Imperial College London for his PhD, as the recipient of a British Council Fellowship. He returned
to Australia in 1955 to a research position at CSIRO in what was to become the Division of Coal
Research in Sydney. Charged with elucidating the chemical structure of coal, Jim realised the
need for the latest analytical instrumentation, including mass spectrometry and nuclear magnetic
resonance. Consequently, a German Atlas CH4 mass spectrometer was installed in Sydney in
1961 and was the first in Australia that was devoted to the elucidation of the structures of organic
compounds. Jim was promoted to the level of Senior Principal Research Scientist in 1963. His
generous services to other chemists around the country were widely used and appreciated,
especially as he continued to develop and understand new and valuable applications.
In 1968 CSIRO transferred the Mass Spectrometry Unit to Canberra. Jim’s stay in Canberra
was rather short-lived, as he was appointed Professor of Chemistry at the University of New
South Wales in 1969 and stayed until his retirement in 1986. Jim’s role in the development
of the School of Chemistry at the University of New South Wales was immense, and
furthermore his wider contribution to the University cannot be overemphasised. Scientifically,
Jim established a strong group in chemical ionization mass spectrometry, and successfully
masterminded the transfer, from La Trobe University not only of Peter Derrick, but also Peter’s
grand-scale double-focussing mass spectrometer. The negotiations were significant because
they resulted in the conversion of substantial areas of teaching laboratories into state-of-the-
art mass spectrometry research laboratories. Jim’s scientific output was justly recognised by
the award of the H.G. Smith Medal for 1967 by the Royal Australian Chemical Institute. Also in
1967 the University of Adelaide awarded him the degree of Doctor of Science.
On the administrative side, Jim’s broad vision, unwavering integrity, sound judgment and
diplomatic skills were quickly recognised and highly valued. He served as Head of the School
of Chemistry in 1976-77 and again in 1980-84. He served on innumerable committees of the
Professorial Board of the University and chaired the Research and Higher Awards Committee,
and the Board of Studies in Science and Mathematics. He was elected to the University
Council where he represented the Faculty of Science.
There are many scientists who have benefited from Jim Shannon’s innovative science, wise
leadership and friendship, and they are deeply indebted to him.
Jim is survived by his devoted wife Vois, to whom he was married for 59 years.
PROFESSOR JAMES S. SHANNON
82 | School of Chemistry Annual Report
BRIAN RAYMOND CRAVEN 29th July 1929 – 22nd September 2015Dr. Craven was appointed as Lecturer at UNSW in August 1961 and his areas
of research included: diffusion studies in association coloids; humic materials
in natural waters; and adsorption of resins into fibres. He retired from UNSW
in November 1989 but continued to contribute to the School of Chemistry as a
Visiting Academic until December 2004.
He was instrumental in founding the Museum of the History of Science at the
School of Chemistry, UNSW in 1986, which collected and housed old scientific
apparatus, instruments and memorabilia.
He is survived by his wife of many years, Valerie.
BRIAN RAYMOND CRAVEN
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