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Jacek Chowdhary 1 Brian Cairns 1,3 Remote sensing of atmosphere-ocean systems in the UV: How can polarimetry help distinguish reflectance variations caused by absorbing aerosols from variations caused by CDOM? 1 Columbia University, New York, USA NASA Ocean Color Research Team meeting 2 NASA/Goddard Institute for Space Studies, New York, USA

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Page 1: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Jacek Chowdhary1 Brian Cairns1,3

Remote sensing of atmosphere-ocean systems in the UV:

How can polarimetry help distinguish reflectance variations

caused by absorbing aerosols from variations caused by CDOM?

1 Columbia University, New York, USA

NASA Ocean Color Research Team meeting

2 NASA/Goddard Institute for Space Studies, New York, USA

Page 2: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

PACE Mission

In autumn of 2011 NASA selected a science definition team (SDT) to provide (within 3 years) thescience justification and measurement, as well as mission requirements, for the PACE mission

In autumn of 2014 NASA selected a science team (ST) to pursue studies on inherent opticalproperties (IOPs) and Atmospheric Correction (AC)

Responding to the Challenge of Climate

and Env ironmental Change

National Aeronautics and Space Administration

The Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) mission

will make essential global ocean color measurements, essentialfor understanding the carbon cycle and how it both affects and

is affected by climate change, along with polarimetry

measurements to provide extended data records on clouds and

aerosols.

Pre-Aerosol, Clouds, and ocean Ecosystem (PACE)

“The PACE mission will extend key climate data records whose future was in jeopardy

prior to the FY2011 budget request. Global ocean color measurements, essential forunderstanding the carbon cycle and how it affects and is affected by climate change, will

be made by a radiometer instrument on this mission. A polarimeter instrument will

extend data records on aerosols and clouds using this approach begun by the French

PARASOL mission and expanded upon by NASA’s Glory mission, as well as multi-spectral and multi-angle measurements made by NASA’s MODIS and MISR instruments

on NASA’s EOS platforms (MODIS on terra and Aqua, MISR on Aqua).”

NASA’s plan for a Climate-Centric Architecture for Earth Observations and Applications from Space

June 2010

• Primary mission: Ocean; Secondary mission: atmosphere

• Atmospheric Correction: polarization

Page 3: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

o hyperspectral between 800-900

nm, 1-2 nm subsamples (O2 A)

PACE Mission

o 3 SWIR bands

(1240, 1640, 2130 nm)

o spatial resolution = 1 km2

o improved global coverage (1 day)

o spatial resolution better than

500m × 500m

Threshold Ocean Questions SQ 1-7

Goal Terrestrial Questions TSQ 1-3

OCI †

OCI/OG OCI Questions (SQ 1-7, TSQ 1-3)

Goal Coastal Questions CSQ 1-4

o Hyperspectral imager with 5 nm

resolution between 350-800 nm

o 2 NIR bands

(incl. 865 nm)

o OCI instrument capabilities

Option Science Threshold and Goal Questions Brief Instrument Description

Oce

an

Scie

nce o 3 SWIR bands

(1240, 1640, 2130 nm)

o spatial resolution = 1 km2

Note: Threshold Questions define required

research, i.e. they must be addressed

† OCI = Ocean Color Imager ‡ improved atmospheric correction, data continuity for POLDER products§ data continuity for MISR products, albeit with coarser spatial resolution¶ 3M = Multi-directional, Multi-polarization, Multi-spectral

OCI+

OCI-3M ¶

OCI/A

OCI/A-3M

OCI Questions (SQ 1-7, TSQ 1-3)

“Threshold” Atmosphere Question ASQ 1

OCI Questions (SQ 1-7, TSQ 1-3)

Goal Atmosphere Questions ASQ 4,5

OCI+ Questions (SQ 1-7, TSQ 1-3, ASQ 1)

Goal Atmosphere Question ASQ 2

o OCI instrument capabilities

o 3 additional NIR and SWIR

bands (940, 1378, 2250 nm)

o OCI instrument capabilities

o a 3M imager ‡ §

o OCI+ instrument capabilities

o selected atmospheric bands at

spatial resolution 250m × 250m

OCI-3M & OCI/A Questions (SQ 1-7,

TSQ 1-3, ASQ 2,4,5)

Goal Atmosphere Question ASQ 3

o OCI/A instrument capabilities

o a 3M imager ‡ §

Atm

osp

he

re S

cie

nce

absorbingaerosols

CDOM

phytoplankton

pigments

functional groups

particle sizes

physiology

pigment

fluorescence

coastal biology

atmosphericcorrection

(clear ocean)

atmosphericcorrection

(coastal ocean)

SW

IRN

IRV

isib

leU

ltra

vio

let

5 n

m r

eso

luti

on

(3

50

-885

nm

)

26

re

qu

ire

d “m

ult

isp

ectr

al” b

an

ds

3 S

WIR

ba

nd

s

products

Page 4: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

PACE Mission

NO2

UV-A Visible NIR SWIR

aerosol absorption

dark ocean

aerosol scattering

black oceanocean science products

Atmospheric Scattering (AS) estimate

NIR & SWIR band ratios: select aerosol scattering model

UV-A radiance: detect (& constrain?) aerosol absorption

AS

~ρw (412)

10–110–2 100 101

10–2

10–1

100

101

Sa

telli

te

In Situ

Santa Barbara Channel, CA

٭ MODIS

+ SeaWiFS

absorbingaerosols

CDOM

phytoplankton

pigments

functional groups

particle sizes

physiology

pigment

fluorescence

coastal biology

atmosphericcorrection

(clear ocean)

atmosphericcorrection

(coastal ocean)

SW

IRN

IRV

isib

leU

ltra

vio

let

5 n

m r

eso

luti

on

(3

50

-885

nm

)

26

re

qu

ire

d “m

ult

isp

ectr

al” b

an

ds

3 S

WIR

ba

nd

s

products

Source: D. Siegel (pers. com.)

Page 5: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

PACE Mission

NO2

UV-A Visible NIR SWIR

aerosol absorption

dark ocean

aerosol scattering

black oceanocean science products

Atmospheric Scattering (AS) estimate

NIR & SWIR band ratios: select aerosol scattering model

UV-A radiance: detect (& constrain?) aerosol absorption

AS

~ρw (412)

10–110–2 100 101

10–2

10–1

100

101

Sa

telli

te

In Situ

Santa Barbara Channel, CA

٭ MODIS

+ SeaWiFS

absorbingaerosols

CDOM

phytoplankton

pigments

functional groups

particle sizes

physiology

pigment

fluorescence

coastal biology

atmosphericcorrection

(clear ocean)

atmosphericcorrection

(coastal ocean)

SW

IRN

IRV

isib

leU

ltra

vio

let

5 n

m r

eso

luti

on

(3

50

-885

nm

)

26

re

qu

ire

d “m

ult

isp

ectr

al” b

an

ds

3 S

WIR

ba

nd

s

products

When is the ocean bright enoughto retrieve variations in CDOM?

When is the ocean dark enoughto retrieve variations in aerosolabsorption?

Source: D. Siegel (pers. com.)

Page 6: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

RT Comparison studies

Motivation

Results

1) Accuracy for Stokes parameters I, Q, Uemerging from various AOS is better than 10–6

2) Corresponding accuracy in degree of linear polarization better than 0.1%

Part I

RT comparison Studies

Page 7: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Motivation Polarization is an extremely useful tool to retrieve aerosol properties

Synthetic TOA data of I, Q, & U:

o Fine mode aerosol, τ = 0.2

(re = 0.4 μm; ve=0.2; m=1.45

o Rough ocean surface

(W = 7 m/s)

o Black water body

o μ0=0.8; μ=0.2, 0.4, 0.6, 0.8, 1.0

Δφ=60º & 120º

θ0 ≡ π – ϑ0

oce

an

atm

osp

her

e

x

y

zsun

k0

φ0 = 0º

view

k

ϑ

φ

AOS system

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

Source: Mishchenko and Travis, JQSRT 102:13,543-13,553 (1997)

Simulated aerosol retrieval from space-borne observation over ocean at 865 nm

Aerosol candidate models:

o Fine mode aerosol:

τ = 0.01 – 0.4, Δτ = 0.01

re = 0.01 – 0.8 μm, Δre = 0.01

m = 1.3 – 1.7, Δm = 0.01

ω = 0.78 – 1.00, Δω = 0.02

ve = 0.2

>350,000 aerosol candidate models

RT comparison Studies

Page 8: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Motivation

Aerosol candidate models:

o Fine mode aerosol:

τ = 0.01 – 0.4, Δτ = 0.01

re = 0.01 – 0.8 μm, Δre = 0.01

m = 1.3 – 1.7, Δm = 0.01

ω = 0.78 – 1.00, Δω = 0.02

ve = 0.2

>350,000 aerosol candidate models

Source: Mishchenko and Travis, JQSRT 102:13,543-13,553 (1997)

ω=1.00 ω=0.98

ω=0.94 ω=0.92

optic

al th

ickn

ess

optic

al th

ickn

ess

refractive index refractive index

o radiance I,

o 9 viewing angles

o ΔI = 4%

o polarization Q/I and U/I,

o 9 viewing angles

o ΔP = 0.2%

Simulated aerosol retrieval from space-borne observation over ocean at 865 nm

Polarization is an extremely useful tool to retrieve aerosol properties

RT comparison Studies

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

Page 9: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Motivation

o radiance I,

o 9 viewing angles

o ΔI = 6%

o polarization Q/I and U/I,

o 9 viewing angles

o ΔP = 0.8%

optic

al th

ickn

ess

optic

al th

ickn

ess

refractive index refractive index

ω=1.00 ω=0.98

ω=0.94 ω=0.92

Simulated aerosol retrieval from space-borne observation over ocean at 865 nm

Source: Mishchenko and Travis, JQSRT 102:13,543-13,553 (1997)

Polarization is an extremely useful tool to retrieve aerosol properties

Aerosol candidate models:

o Fine mode aerosol:

τ = 0.01 – 0.4, Δτ = 0.01

re = 0.01 – 0.8 μm, Δre = 0.01

m = 1.3 – 1.7, Δm = 0.01

ω = 0.78 – 1.00, Δω = 0.02

ve = 0.2

>350,000 aerosol candidate models

RT comparison Studies

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

Page 10: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Motivation

o radiance I,

o 9 viewing angles

o ΔI = 8%

o polarization Q/I and U/I,

o 9 viewing angles

o ΔP = 2.0%

optic

al th

ickn

ess

optic

al th

ickn

ess

refractive index refractive index

ω=1.00 ω=0.98

ω=0.94 ω=0.92

Simulated aerosol retrieval from space-borne observation over ocean at 865 nm

Source: Mishchenko and Travis, JQSRT 102:13,543-13,553 (1997)

Polarization is an extremely useful tool to retrieve aerosol properties

Aerosol candidate models:

o Fine mode aerosol:

τ = 0.01 – 0.4, Δτ = 0.01

re = 0.01 – 0.8 μm, Δre = 0.01

m = 1.3 – 1.7, Δm = 0.01

ω = 0.78 – 1.00, Δω = 0.02

ve = 0.2

>350,000 aerosol candidate models

RT comparison Studies

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

Page 11: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

2015:

~1e-4

~1e-4

~1e-4

absolute difference

I

Q

UAOS system: molecular atmosphere above ocean surface

view angle

0 20 40 60 80

view angle

0 20 40 60 80

Polarization is an extremely useful tool to retrieve aerosol properties

our forward RT computations need to match these high accuracies in DLP !

Motivation

RT comparison Studies

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

Page 12: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Results

θ0 ≡ π – ϑ0

oce

an

atm

osp

her

e

x

y

z

k0

φ0 = 0º

k

ϑ

φ

upper

lower

2 sun angles

13 viewing angles

4 azimuth angles

TOA

SRF

>100 scattering geometries x 2 altitudes

λ = 350 nm, 450 nm, 550 nm, 650 nm

Polarization is an extremely useful tool to retrieve aerosol properties

I, Q, U ΔP ≤ 0.1%

RT comparison Studies

models Ocean Body Ocean Surface Atmosphere

AOS-I

none

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-II pure water Pure Rayleigh scattering

rough Gaussian isotropic No foam or shadowing

none

AOS-III pure water Pure Rayleigh scattering

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-IV pure water & hydrosol Pure Rayleigh scattering Detritus-Plankton mix

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-V pure water & hydrosol Pure Rayleigh scattering Detritus-Plankton mix

rough Gaussian isotropic No foam or shadowing

molecular & aerosol Pure Rayleigh scattering Fine-mode aerosol

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

our forward RT computations need to match these high accuracies in DLP !

Page 13: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Results

10

–10

5

0

–5

–60–40–20 0 20 40 60

dI (x106) dQ (x106) dU (x106) dDLP (%)

SRF, θ0=60° SRF, θ0=60° SRF, θ0=60° SRF, θ0=60°10

–10

5

0

–5

–60–40–20 0 20 40 60

10

–10

5

0

–5

–60–40–20 0 20 40 60

0.2

–0.2

0.1

0.0

–0.1

–60–40–20 0 20 40 60

φ = 60° φ = 120°←║ φ = 60° φ = 120°←║ φ = 60° φ = 120°←║ φ = 60° φ = 120°←║

AOS-I (550 nm)

view angle view angle view angle view angle

Polarization is an extremely useful tool to retrieve aerosol properties

GSFCJPLNRL

UCSDUMBC

RT comparison Studies

models Ocean Body Ocean Surface Atmosphere

AOS-I

none

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-II pure water Pure Rayleigh scattering

rough Gaussian isotropic No foam or shadowing

none

AOS-III pure water Pure Rayleigh scattering

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-IV pure water & hydrosol Pure Rayleigh scattering Detritus-Plankton mix

rough Gaussian isotropic No foam or shadowing

molecular Pure Rayleigh scattering

AOS-V pure water & hydrosol Pure Rayleigh scattering Detritus-Plankton mix

rough Gaussian isotropic No foam or shadowing

molecular & aerosol Pure Rayleigh scattering Fine-mode aerosol

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

our forward RT computations need to match these high accuracies in DLP !

Page 14: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Results

10

–10

5

0

–5

–60–40–20 0 20 40 60

dI (x106) dQ (x106) dU (x106)

SRF, θ0=60° SRF, θ0=60° SRF, θ0=60° SRF, θ0=60°10

–10

5

0

–5

–60–40–20 0 20 40 60

10

–10

5

0

–5

–60–40–20 0 20 40 60

0.2

–0.2

0.1

0.0

–0.1

–60–40–20 0 20 40 60

φ = 60° φ = 120°←║ φ = 60° φ = 120°←║ φ = 60° φ = 120°←║ φ = 60° φ = 120°←║

AOS-I (550 nm)

view angle view angle view angle view angle

view angle

0 20 40 60 80

~1e-4

dI

~1e-4

dQ

view angle

0 20 40 60 80

~1e-4

dU

view angle

0 20 40 60 80

o Benchmarked >magnitude better

o Satisfies polarization accuracy

Polarization is an extremely useful tool to retrieve aerosol properties

GSFCJPLNRL

UCSDUMBC

RT comparison Studies

provided that the percent linear polarized light (“DLP”) is measured with high accuracies (0.2% - 0.5%)

our forward RT computations need to match these high accuracies in DLP !

dDLP (%)

Page 15: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV sensitivity Studies

Motivation

Results

1) TOA polarized reflectance is more sensitive to variations in aerosol properties than in ocean

2) This leads to changes in the TOA degree of polarization >>0.3% that have unique spectral and angular patterns for perturbations in CDOM

Part II

UV Sensitivity Studies

Page 16: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Motivation

UV Sensitivity Studies

Reflection r = p I

S0 cosq0

60° 40° 20°

60° 60°

120°120°

q =

Azimuth angle

View angle

Sideward scattering

Backward scattering

Specular reflection

Sunglint region

Anti-solar point for q0

(i.e. backscattering direction)

j−j0 = 0°

180°

UV polarized reflected light is nearly insensitive to variations in the ocean color

But is this light sensitive to the amount and variations in aerosols?

rS0

TOA

SRF

385 nm

4 km

Page 17: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

j−j0 = 180°

j−j0 = 0°

rocean (%) (385 nm)

3 3.5 4 4.5 5 7 12 5 13 13.56 ><

contribution of ocean to TOA reflectance: >13%

TOA

SRFrocean (%)

rocean, ,

P(%)

rocean ≡ rocean / r TOA (%)

Case I (open) ocean

Rayleigh scattering

Bodhaine et al. (1999)

Aerosol scattering

re = 0.15 μm, ve = 0.15, τ550 = 0.10

contribution of ocean to TOA polarized reflectance: <5%

average oligotrophic ocean

AOT(550) = 0.1, θ0 = 30°

Chow

dhary

et al. (2012)

4 km

RT results

385 nm

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

Page 18: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

j−j0 = 180°

j−j0 = 0°

ΔrTOA (%) (385 nm)

0.5 1 1.5 2 2.5 3.5 4 5 6 93 ><

TOA

SRF

4 km

DrTOA (%)

DrTOA, ,

P(%)

DrTOA ≡ DrTOA / r TOA (%)

Case I (open) ocean

Rayleigh scattering

Bodhaine et al. (1999)

Aerosol scattering

re = 0.15 μm, ve = 0.15, τ550 = 0.10

max CDOM variation

AOT(550) = 0.1, θ0 = 10°

TOA polarized reflectance change: <2%

380 nm

Mediterranean

South Pacif ic

Chl [mg/m3]

DKbio = 0.2433

bio-optical model

Kd

≡ K

w+

Kbio

[1/m

]

More

l et al. (2007)

DKd ≈ 1.04(md)−1 (Da + bb)

CDOM

RT results

TOA reflectance change: ~7%

385 nm

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

Page 19: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

j−j0 = 180°

j−j0 = 0°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

ΔrTOA (%) (385 nm)

0.5 1 1.5 2 2.5 3.5 4 5 6 73 ><

ΔrTOA (%) (385 nm)

0.5 1 1.5 2 2.5 3.5 4 5 6 73 ><

TOA

SRF

4 km

DrTOA (%)

DrTOA, ,

P(%)

DrTOA (%)

DrTOA, ,

P(%)

max CDOM variation

TOA polarized reflectance change: <2%

AOT(550) = 0.1, θ0 = 30°

RT results

TOA reflectance change: ~7%

385 nm

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

TOA polarized reflectance change: >7%

change aerosol zchange aerosol z

4 km

6 km

TOA

SRFDrTOA ≡ DrTOA / r TOA (%)

Page 20: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

j−j0 = 180°

j−j0 = 0°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

ΔrTOA (x1000) (385 nm)

1 1.5 2 2.5 3 4 12 13 14 153.5 ><

ΔrTOA (x1000) (385 nm)

1 1.5 2 2.5 3 4 12 13 14 153.5 ><

TOA

SRF

4 km

DrTOA (abs)

DrTOA, ,

P(abs)

DrTOA (abs)

DrTOA, ,

P(abs)

max CDOM variation

TOA polarized reflectance change: <0.0015

AOT(550) = 0.1, θ0 = 30°

RT results

TOA reflectance change: ~0.01

385 nm

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

TOA polarized reflectance change: >0.005

change aerosol zchange aerosol z

4 km

6 km

TOA

SRFDrTOA ≡ DrTOA (absolute)

Page 21: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

ΔrTOA (x1000) (385 nm)

1 1.5 2 2.5 3 4 12 13 14 153.5 ><

DrTOA (abs)

DrTOA, ,

P(abs)

RT results

TOA polarized reflectance change: >0.005

change aerosol zchange aerosol z

4 km

6 km

TOA

SRF

Δ DLP (%) (385 nm)

0.1 0.2.0.3 0.4 0.6 1.0 1.2 1.5 2.0 2.50.8 ><

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

D DLP ≡ D ( rTOA,P / rTOA )

“Polarization is an extremely useful tool to receive aerosol

properties provided that the percent linear polarized light

(DLP) is measured with high accuracies (0.2% - 0.5%)”

TOA DLP change: >1%

Page 22: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.5 0.9 1.2 1.6 2.0 2.50.7 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 445 nm

4 km

6 km

TOA

SRF

TOA

SRF

4 km

TOA DLP change: >1%

Page 23: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.5 0.9 1.2 1.6 2.0 2.50.7 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 412 nm

4 km

6 km

TOA

SRF

TOA

SRF

4 km

TOA DLP change: >1%

10 2 3 4 5 6

1

0

2

3

4

5

6

RSP: retrieved vs true height

Source: Wu et al. (In prep.)

Page 24: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.5 0.9 1.2 1.6 2.0 2.50.7 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 445 nm

TOA

SRF

4 km 4 km

TOA

SRF

Δ CDOM

TOA DLP change: >1%

Page 25: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ Intensity (%)

0.5 1.0 1.5 2.0 2.5 3.5 4.0 5.0 6.0 9.03.0 ><

λ = 370 nm λ = 385 nm λ = 400 nm λ = 415 nm

TOA

SRF

4 km 4 km

TOA

SRF

Δ CDOM

TOA intensity change: 3%

Δ ω ω = 0.9 darker

brighter

Page 26: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 0.2 0.3 0.4 0.6 0.7 0.8 0.9 1.00.5 ><

λ = 370 nm λ = 385 nm λ = 400 nm λ = 415 nm

TOA

SRF

4 km 4 km

TOA

SRF

Δ CDOM

TOA intensity change: 0.7%

Δ ω ω = 0.9 darker

brighter

Page 27: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 0.2 0.3 0.4 0.6 0.7 0.8 0.9 1.00.5 ><

λ = 370 nm λ = 385 nm λ = 400 nm

TOA

SRF

4 km 4 km

TOA

SRF

Δ CDOM

TOA intensity change: 0.7%

Δ ω ω = 0.9 darker

brighter

absorbingaerosols

CDOM

phytoplankton

pigments

functional groups

particle sizes

physiology

pigment

fluorescence

coastal biology

atmosphericcorrection

(clear ocean)

atmosphericcorrection

(coastal ocean)

SW

IRN

IRV

isib

leU

ltra

vio

let

5 n

m r

eso

luti

on

(3

50

-885

nm

)

26

re

qu

ire

d “m

ult

isp

ectr

al” b

an

ds

3 S

WIR

ba

nd

s

products

Page 28: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

RT results

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 0.2 0.3 0.4 0.6 0.7 0.8 0.9 1.00.5 ><

λ = 385 nm λ = 400 nm

TOA

SRF

4 km 4 km

TOA

SRF

Δ CDOM

TOA intensity change: 0.7%

Δ ω ω = 0.9 darker

brighter

absorbingaerosols

CDOM

phytoplankton

pigments

functional groups

particle sizes

physiology

pigment

fluorescence

coastal biology

atmosphericcorrection

(clear ocean)

atmosphericcorrection

(coastal ocean)

SW

IRN

IRV

isib

leU

ltra

vio

let

5 n

m r

eso

luti

on

(3

50

-885

nm

)

26

re

qu

ire

d “m

ult

isp

ectr

al” b

an

ds

3 S

WIR

ba

nd

s

products

SPEX:

• Swath: 60 deg• Angular range: ±60 deg• # view angles: 5• Spectral range: 375-850 nm• Polarimetric accuracy: 0.2%• Radiometric accuracy: 2%

Source: O. Hasekamp (pers. com.)

Page 29: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

RT Comparison studies 1) Accuracy for Stokes parameters I, Q, Uemerging from various AOS is better than 10–6

2) Corresponding accuracy in degree of linear polarization better than 0.1%

Conclusions

Part I

Part II

UV sensitivity Studies 1) TOA polarized reflectance is more sensitive to variations in aerosol properties than in ocean

2) This leads to changes in the TOA degree of polarization >>0.3% that have unique spectral and angular patterns for perturbations in CDOM

Page 30: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Backup Slides

RSP retrievals

Page 31: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

RSP retrievals

Aerosol Layer Height Retrieval from RSP (synthetic)

radiance + polarization

Polarimetry in near UV: elevated aerosol layer ‘shields’ partly molecular (Rayleigh) scattering polarization measurements

provide aerosol height information.

Polarization measurements in blue / near-UV are needed. (This is for a homogeneous aerosol layer; for plumes MISR has shown

that stereo retrievals form multi-angle radiometry work well)

(Wu et al, in preparation)

only radiance

Page 32: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Aerosol Layer Height Retrieval from RSP (real measurements)

radiance + polarization

• Comparison between RSP and the Cloud Physics Lidar from the ER-2.

• Given the very different measurement approaches and definition of aerosol layer height, the agreement is very encouraging.

• The importance of blue / near-UV polarization measurements is also confirmed for real measurements.

only radiance

(Wu et al, in preparation)

RSP retrievals

Page 33: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Backup Slides

D-P hydrosol model

Page 34: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Reference

“We previously developed a hydrosol model for use in underwater light scattering computations.

We apply this model to measurements of total and polarized reflectance that were acquired over open ocean during the

MILAGRO campaign by the airborne Research Scanning Polarimeter (RSP). Analyses show that our hydrosol model

faithfully reproduces the water-leaving contributions to RSP reflectance.”

DP: Detritus-Plankton mixtures (used for PACE). FF: Fournier-Forand. OTHG: one-term Henyey-Greenstein. Red error bars : RSP data at 62 m above surface.

Detritus-Plankton hydrosol mixtures

Page 35: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

Backup Slides

aerosol model variations

Page 36: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.4 0.6 0.7 0.8 0.9 1.00.5 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 445 nm

TOA

SRF

4 km

6 km

TOA

SRF

TOA DLP change: >0.3%

3 km

5 km

30°q0 =

Page 37: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.4 0.6 0.7 0.8 0.9 1.00.5 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 445 nm

TOA

SRF

4 km

6 km

TOA

SRF

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

TOA DLP change: >0.7%

3 km

5 km

50°q0 =

Page 38: Remote sensing of atmosphere-ocean systems in the UV · Pre-Aerosol, Clouds, and ocean Ecosystem (PACE) “The PACE mission will extend key climate data records whose future was in

UV Sensitivity Studies

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

60° 40° 20°

300° 60°

120°240°

q =

j−j0 = 0°

j−j0 = 180°

Δ DLP (%)

0.05 0.12 .0.2 0.3 0.5 0.9 1.2 1.6 2.0 2.50.7 ><

λ = 355 nm λ = 385 nm λ = 415 nm λ = 445 nm

TOA

SRF

4 km

Δ CDOM

4 km

6 km

TOA

SRF

TOA DLP change: >0.3%