A:

Orbitals fll in order o increasing energy : Aubau Principle

 This unctional group arises when a primary alcohol is oxidized by PCC (pyridinium

chlorochromate: Aldehyde

!:

Allotrope o carbon with the ormula   C 60 : !uc"minsterullerene

 This three#membered cationic intermediate orms when !r$ reacts with an al"ene: !romonium

ion

C:

An ob%ect that is not superimposable on its mirror image: Chiral

 This condensation reaction occurs when two esters combine to orm a beta#"etoester: Claisen

condensation: Claisen condensation

&:

 Term describing orbitals with e'ual energy: &egenerate

 This obel Prize#worthy cyclic reaction re'uires a diene and a dieneophile: &iels#Alder reaction

):

*pecies that can accept a pair o electrons to orm a new co+alent bond: )lectrophiles

 This is the technical term or a molecule or its non#superimposable mirror image: )nantiomer

,:

*andwich compound with the ormula ,e   (C 5  H 5)2 : ,errocene

 This reaction occurs when an acid chloride is combined with a benzene ring and AlCl-: ,riedel#

Crats acylation

.:

 Term or al"yl# or aryl# magnesium halides: .rignard/s 0eagent

1:

1ermitian operator that consists o "inetic energy and potential energy components: 1amiltonian

 The aromaticity o a cyclic compound is determined by this rule which re'uires 23n456 pi#

electrons: 17c"el rule

8:

A compound containing a carbon#nitrogen double bond9 Also "nown as a *chi base: 8mine

 ;:

umber relating the change in temperature o a gas to the change in pressure at constant

enthalpy: ;oule#Thomson Coe<cient

Any source o chromium (=8 ions and suluric acid orm this mixture used to oxidize alcohols:

 ;ones> reagent

?:

A compound containing a carbonyl group bonded to two carbons: ?etone

 

 This unctional group arises when a carbon is double bonded to both an oxygen and another

carbon: ?etene

@:

8ntermolecular orce resulting rom induced dipole#induced dipole interactions: @ondon

&ispersion ,orce

 This hydrogenation catalyst or al"ynes is made by >poisoning> palladium with lead acetate etc9:

@indlar/s catalyst

B:

&escribes the "inetics o enzyme catalyzed reactions: Bichaelis#Benten )'uation

 The term or an addition reaction which a+ors a group adding at the more substituted position:

Bar"o+ni"o+

:

A spectroscopic techni'ue that measures the energy associated with nuclear spin ips: uclear

Bagnetic 0esonance *pectroscopy

 This type o drawing shows the relati+e stereochemistry o two carbons along a bond: ewman

pro%ection

O:

&escribes the relati+e positions o the unctional groups in D 5# dimethylbenzene: Ortho

 This oxidati+e reaction with an allotrope o oxygen splits al"enes into two carbonyl compounds:

Ozonolysis

P:

A co+alent bond ormed by the o+erlap o parallel p#orbitals: Pi#!ond

 This alcohol with a p?a o about DE and used to be called carbolic acid: Phenol

F:

 The arrangement o polypeptide monomers into a nonco+alently bonded aggregate: Fuaternary

*tructure

 This heterocycle with a pyridine used to a benzene: Fuinoline

0:

A mixture o e'ual amounts o two enantiomers: 0acemic Bixture

 This reaction to ma"e G#membered rings is a condensation reaction ollowed by an aldol:

0obinson annulation

*:

A bimolecular nucleophilic substitution reaction: *5 0eaction

 This one#pot synthesis ma"es amino acids rom cyanide ammonium and a carbonyl: *trec"er

synthesis

 T:

 The unctional group 0#*1: Thiol

 This is a type o isomerization reaction where unctional groups intercon+ert li"e enol to "etone:

 Tautomerization

H:

 

 The repeating moti rom which a crystal could be constructed by simple translation operations:

Hnit cell

 This unctional group also called a carbamate is made o both an amide and an ester: Hrethane

=:

A group o intermolecular orces including dipole#dipole dipole#induced dipole and dispersion

orces: =an der Iaals ,orces

 This term rom the @atin or neighbour describes when two things are bound to neighbouring

carbons: =icinal

I:

 The minimum energy re'uired to remo+e an electron rom an atom: Ior" ,unction

 This reaction between an al"oxide and a primary al"yl halide will produce ethers: Iilliamson

)ther *ynthesis

J:

 The frst binary compound disco+ered containing a noble gas: Jenon Tetrauoride

 This is the common name o dimethyl benzene and mixtures o its isomers ma"e a good sol+ent:

Jylene

 K:

A neutral molecule with positi+e and negati+e charges on ad%acent atoms: Klide

L:

 The energy that remains in a 'uantum mechanical system e+en at absolute zero: Lero Point

)nergy

&uring elimination reactions this rule states that the more substituted al"ene should orm:

Laitse+>s rule

,urther 'uestions:

Ihat is the combination o temperature and pressure at which the solid li'uid and gas phases

can coexist at e'uilibrium called: Triple Point

Ammonium molybdate test is used to detect the presence o borate9 True or alse: ,alse

*b is the chemical symbol or which element: Antimony