process simulation and dynamic control for marine oily

1
RESEARCH POSTER PRESENTATION DESIGN © 2015 www.PosterPresentations.com INTRODUCTION OBJECTIVES MATERIALS AND METHODS RESULTS CONCLUSIONS This study examined the degradation kinetics of a typical PAH, namely naphthalene in seawater using UVC irradiation. Results show that fluence rate, temperature and the interaction between temperature and initial concentration are the most influential factors. An increase in fluence rate can linearly promote the photodegradation process. Salinity increasingly impedes the removal of naphthalene because of the existence of free-radical scavengers and photon competitors. A feed-forward back-propagation trained ANN was used to model this process. The proposed dynamic process control tool can well simulate and optimize nonlinear systems with good accuracy. Optimization results can be superior over traditional control strategies. This would help the application of advanced wastewater treatment technologies in terms of saving cost and time. The developed experimental-modeling approach and its concept/framework have high potential of applicability in other environmental fields where a treatment process is involved and experimentation and modeling are used for process simulation and control. REFERENCES Jing, L., Chen, B., Zhang, B.Y., Peng, H.X., 2012a. A review of ballast water management practices and challenges in harsh and Arctic environments. Environmental Reviews, 20, 83–108. Jing, L., Chen, B., Zhang, B.Y., Li, P., 2012b. A stochastic simulation- based hybrid interval fuzzy programming approach for optimizing the treatment of recovered oily water. Journal of Ocean Technology, 7(4), 59–72. Jing, L., Chen, B., Zhang, B.Y., Zheng, J.S., Liu, B., 2014a. Naphthalene degradation in seawater by UV irradiation: the effects of fluence rate, salinity, temperature and initial concentration. Marine Pollution Bulletin, 81, 149-156. Jing, L., Chen, B., Zhang, B.Y., 2014b. Modeling of UV-induced photodegradation of naphthalene in marine oily wastewater by artificial neural networks. Water, Air, & Soil Pollution, 225(4), 1-14. Jing, L., Chen, B., Zhang, B.Y., Li, P., 2015. Process Simulation and Dynamic Control for Marine Oily Wastewater Treatment using UV Irradiation. Water Research, 81, 101-112. ACKNOWLEDGEMENT Special thanks go to Natural Sciences and Engineering Research Council of Canada (NSERC), Canada Foundation for Innovation (CFI), Research & Development Corporation (RDC) of Newfoundland and Labrador, and Petroleum Research Newfoundland & Labrador (PRNL) for supporting this work. To investigate the removal of a typical PAH, Naphthalene, using UV irradiation in seawater (Jing et al., 2014a); To study and model the effects of photon flux, salinity and temperature using Artificial Neural Networks (ANN) (Jing et al., 2014b); To develop a simulation-based dynamic process control tool for marine oily wastewater treatment systems less cost, less time (Jing et al., 2015); To ensure a sound design and optimal operation in terms of cost, time and environmental standards. Department of Civil Engineering Faculty of Engineering and Applied Science, Memorial University, St. John’s, NL, Canada, A1B 3X5 Liang Jing, Bing Chen*, Baiyu Zhang and Pu Li Process Simulation and Dynamic Control for Marine Oily Wastewater Treatment using UV Irradiation Marine Oily Wastewater Produced Water, Ballast Water, Bildge Water (Jing et al., 2012a) 70% Marine Oil Pollution Polycyclic aromatic hydrocarbons (PAHs) are of great concerns due to toxicity and persistence (Jing et al., 2012b) Current gravity separation practices can not remove PAHs Needs Polishing Treatment UV Inner quartz jar & outer stainless steel chamber with UV lamps in between When UV lamps ↑ Average UV intensity ↑ Input Layer Hidden Layer Output Layer Photon Flux Salinity Temperature Time Naphthalene Removal Efficiency Initial generation count N g = 0 Set N p , N i , P r , P c , and P m Randomly generate initial string population (N p ) Run the ANN simulation model Evaluate objective function and fitness values of the strings Rank the strings and create a mating pool Generate offspring population by reproduction and crossover Perform mutation on the offspring population Update generation count N g = N g + 1 Is any convergence criterion met? No The top ranked string in the converged population Yes ANN Process Control Experimental Experimental and ANN modeling results at (a) 10 and 500 μg L -1 initial concentrations with 40 o C, 32.5 ppt and 8.27 mW cm -2 ; (b) 25, 32.5, and 40 ppt salinity with 20 o C, 10 μg L -1 and 2.88 mW cm -2 ; (c) 2.88 and 8.27 mW cm -2 fluence rate with 20 o C, 25 ppt and 10 μg L -1 ; and (d) 23 and 40 o C temperature with 40 ppt, 10 μg L -1 and 8.27 mW cm -2 Factorial Design: two (or four, six, eight) UV lights; Temperature (20 and 40 o C); Salinity (0, 25, and 40 ppt). Total reaction time: 240 min. Optimized treatment operation using the proposed dynamic process control – varying decision variables Optimized treatment operation using the traditional process control – fixed decision variables Minimization of treatment time and cost using both dynamic and traditional process control CONTACT This research water published in Water Research (IF = 5.528) in 2015. Contact: [email protected]; NRPOP Lab, Civil Engineering, Memorial

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RESEARCH POSTER PRESENTATION DESIGN © 2015

www.PosterPresentations.com

INTRODUCTION

OBJECTIVES

MATERIALS AND METHODS

RESULTS CONCLUSIONS

• This study examined the degradation kinetics of a typical PAH, namely naphthalene in seawater using UVC irradiation. Results show that fluence rate, temperature and the interaction between temperature and initial concentration are the most influential factors. An increase in fluence rate can linearly promote the photodegradation process. Salinity increasingly impedes the removal of naphthalene because of the existence of free-radical scavengers and photon competitors. A feed-forward back-propagation trained ANN was used to model this process.

• The proposed dynamic process control tool can well simulate and optimize nonlinear systems with good accuracy. Optimization results can be superior over traditional control strategies. This would help the application of advanced wastewater treatment technologies in terms of saving cost and time.

• The developed experimental-modeling approach and its concept/framework have high potential of applicability in other environmental fields where a treatment process is involved and experimentation and modeling are used for process simulation and control.

REFERENCES

• Jing, L., Chen, B., Zhang, B.Y., Peng, H.X., 2012a. A review of ballast water management practices and challenges in harsh and Arctic environments. Environmental Reviews, 20, 83–108.

• Jing, L., Chen, B., Zhang, B.Y., Li, P., 2012b. A stochastic simulation-based hybrid interval fuzzy programming approach for optimizing the treatment of recovered oily water. Journal of Ocean Technology, 7(4), 59–72.

• Jing, L., Chen, B., Zhang, B.Y., Zheng, J.S., Liu, B., 2014a. Naphthalene degradation in seawater by UV irradiation: the effects of fluence rate, salinity, temperature and initial concentration. Marine Pollution Bulletin, 81, 149-156.

• Jing, L., Chen, B., Zhang, B.Y., 2014b. Modeling of UV-induced photodegradation of naphthalene in marine oily wastewater by artificial neural networks. Water, Air, & Soil Pollution, 225(4), 1-14.

• Jing, L., Chen, B., Zhang, B.Y., Li, P., 2015. Process Simulation and Dynamic Control for Marine Oily Wastewater Treatment using UV Irradiation. Water Research, 81, 101-112.

ACKNOWLEDGEMENT Special thanks go to Natural Sciences and Engineering Research Council of Canada (NSERC), Canada Foundation for Innovation (CFI), Research & Development Corporation (RDC) of Newfoundland and Labrador, and Petroleum Research Newfoundland & Labrador (PRNL) for supporting this work.

• To investigate the removal of a typical PAH, Naphthalene, using UV irradiation in seawater (Jing et al., 2014a);

• To study and model the effects of photon flux, salinity and temperature using Artificial Neural Networks (ANN) (Jing et al., 2014b);

• To develop a simulation-based dynamic process control tool for marine oily wastewater treatment systems less cost, less time (Jing et al., 2015);

• To ensure a sound design and optimal operation in terms of cost, time and environmental standards.

Department of Civil Engineering Faculty of Engineering and Applied Science, Memorial University, St. John’s, NL, Canada, A1B 3X5 Liang Jing, Bing Chen*, Baiyu Zhang and Pu Li

Process Simulation and Dynamic Control for Marine Oily Wastewater Treatment using UV Irradiation

Marine Oily Wastewater Produced Water, Ballast Water, Bildge Water (Jing et al., 2012a)

70% Marine Oil Pollution

Polycyclic aromatic hydrocarbons (PAHs) are of

great concerns due to toxicity and persistence (Jing et al., 2012b)

Current gravity separation practices can not remove PAHs

Needs Polishing Treatment UV

Inner quartz jar & outer stainless steel chamber with UV lamps in between

When UV lamps ↑

Average UV intensity ↑

Input Layer

Hidden Layer

Output Layer

Photon Flux

Salinity

Temperature

Time

Naphthalene Removal Efficiency

Initial generation count Ng = 0Set Np, Ni, Pr, Pc, and Pm

Randomly generate initial string population (Np)

Run the ANN simulation model

Evaluate objective function and fitness values of the strings

Rank the strings and create a mating pool

Generate offspring population by reproduction and crossover

Perform mutation on the offspring population

Update generation countNg = Ng + 1

Is any convergence criterion met?

No

The top ranked string in the converged population

Yes

ANN

Process Control

Experimental

Experimental and ANN modeling results at (a) 10 and 500 μg L-1 initial concentrations with 40 oC, 32.5 ppt and 8.27 mW cm-2; (b) 25, 32.5, and 40 ppt

salinity with 20 oC, 10 μg L-1 and 2.88 mW cm-2; (c) 2.88 and 8.27 mW cm-2 fluence rate with 20 oC, 25 ppt and 10 μg L-1; and (d) 23 and 40 oC temperature with 40

ppt, 10 μg L-1 and 8.27 mW cm-2

• Factorial Design: two (or four, six, eight) UV lights; Temperature (20 and 40 oC); Salinity (0, 25, and 40 ppt). Total reaction time: 240 min.

Optimized treatment operation using the proposed dynamic process control – varying decision variables

Optimized treatment

operation using the traditional process

control – fixed decision variables

Minimization of treatment time and cost using both dynamic and

traditional process control CONTACT

This research water published in Water Research (IF = 5.528) in 2015. Contact: [email protected]; NRPOP Lab, Civil Engineering, Memorial