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    Predicting odour emissions from wastewater treatment 

    plants by means of odour emission factors

    Laura Capelli*, Selena Sironi, Renato Del Rosso, Paolo Cé ntola

    Politecnico di Milano, Department of Chemistry, Materials and Chemical Engineering ‘‘Giulio Natta’’, Olfactometric Laboratory,

    P.za Leonardo Da Vinci, 32 -20133 Milano, Italy

    a r t i c l e i n f o

    Article history:

    Received 18 August 2008

    Received in revised form

    21 January 2009

    Accepted 26 January 2009

    Published online 4 February 2009

    Keywords:

    Wastewater treatment

    Specific odour emission rate

    Odour emission factors

    Odour prediction

    a b s t r a c t

    In this study, the results of odour concentration measurements on different wastewater

    treatment plants are presented and used in order to estimate the odour emission factors

    relevant to single odour sources. An odour emission factor is a representative value that

    relates the quantity of odour released to the atmosphere to a specific activity index, which

    in this case was the plant treatment capacity, resulting in an odour emission factor

    expressed in odour units per cubic metre of treated sewage. The results show that the

    major odour source of a wastewater treatment plant is represented by the primary sedi-

    mentation (with an OEF equal to 1.9 105 ouE   m3). In general, the highest OEFs areobserved in correspondence of the first steps of the wastewater depuration cycle (OEF

    between 1.1 104 ouE   m3 and 1.9 105 ouE  m3) and tend to decrease along the depu-ration process (OEF between 7.4 103 ouE m3 and 4.3 104 ouE m3). In general, the OEFscalculated according to this approach represent a model for a rough prediction of odour

    emissions independently from the specific characteristics of the different plants.ª 2009 Elsevier Ltd. All rights reserved.

    1. Introduction

    Wastewater treatment plants (WWTPs) represent a common

    source of odour emissions that can be the cause of odour

    nuisance to the population living near, and problems con-

    nected to odour emissions often represent the limiting factor

    to the activity or construction of these kind of plants (Frechen,

    1988; Gostelow et al., 2001).

    Odours are emitted from waste water collection, treat-ment, and storage systems through volatilization of organic

    compounds at the liquid surface. Odours in wastewater

    treatment arise mainly from the biodegradation of sewage,

    especially anaerobic degradation (Burgess et al., 2001), and

    they are generated by a number of different wastewater

    components (Vincent and Hobson, 1998), the most significant

    being the sulphur compounds, hydrogen sulphide (H2S) and

    mercaptan. Domestic sewage contains 3–6 mg l1 organic

    sulphur, mainly arising from proteinaceous materials, plus

    z4 mg l1 from sulphonates contained in household deter-

    gents (Boon, 1995) and 30–60 mg l1 inorganic sulphur (as

    sulphates) (Gostelow and Parsons, 2000).

    Emissions can occur by diffusive or convective mecha-

    nisms, or both. Diffusion occurs when organic concentrations

    at the water surface are much higher than ambient concen-

    trations. The organics volatilize (Bianchi and Varney, 1997), or

    diffuse into the air, in an attempt to reach equilibriumbetween aqueous and vapour phases. Convection occurs

    when air flows over the water surface, sweeping organic

    vapours from the water surface into the air. The rate of vola-

    tilization relates directly to the speed of the air flow over the

    water surface (US EPA, 1995).

    A useful tool for odour impact assessment and prediction

    are odour emission factors (OEFs) (Sironi et al., 2005). OEFs are

    developed in analogy with the emission factors defined by the

    *   Corresponding author. Tel.: þ39 02 23993206; fax: þ39 02 23993291.E-mail address: [email protected] (L. Capelli).

    A v a i l a b l e a t w w w . s c i e n c e d i r e c t . c o m

    j o u r n a l h o m e p a g e :   w w w . e l s e v i er . c o m / l o c a t e / w a tr e s

    0043-1354/$ – see front matter  ª 2009 Elsevier Ltd. All rights reserved.

    doi:10.1016/j.watres.2009.01.022

    w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 1 9 7 7 – 1 9 8 5

    mailto:[email protected]://www.elsevier.com/locate/watreshttp://www.elsevier.com/locate/watresmailto:[email protected]

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    United States Environmental Protection Agency (1995) for

    other pollutants/chemical compounds, which relate the

    quantity of a pollutant released to the atmosphere to a given

    associated activity. In the estimation of OEFs for industrial

    plants, these values can be calculated as the product of the

    emitted odour concentration (ouE m3) by the emitted air flow

    (m3 s1), divided by a specific index, which may be for example

    the gross weight production, the site surface or a time unit.In general, OEFs can be used for odour impact assessment

    as input data for the application of specific odour dispersion

    models. OEFs also can have a predictive value: they allow to

    estimate the odour emission rate (OER) associated with an

    industrial plant even before its construction. Moreover, OEFs

    may be applied in order to predict how the odour impact of an

    industrial plant will be influenced by plant modifications, e.g.

    for the case of WWTPs, the change of the conferred waste-

    water quality or quantity, or the variation of the duration of 

    any treatment phase. In this case, OEFs can be useful in order

    to evaluate the feasibility of the planned technological or

    functional modifications (Sironi et al., 2006).

    Data regarding the chemical concentration of pollutants,resulting from measurement campaigns on representative

    sources, are generally available as a function of the processing 

    type and/or the fume depuration technology. On the other

    hand, data found in literature concerning odour concentra-

    tions and odour flow rates are few and with poor reliability.

    This fact represents a serious limit for the availability of 

    ‘‘bibliographical’’ OEFs and require that OEFs are created by

    from experimental laboratory data.

    This work describes the methods used for the calcula-

    tion of OEFs based on the results of olfactometric

    measurements that were carried out on a significant

    number of WWTPs, which differ in constructional features,

    in type of treated wastewater and in geographical locationsin Italy.

    2. Materials and methods

    2.1. Sampling

    The major odour sources of a typical WWTP are represented

    by the open-air wastewater treatment tanks, which can be

    classified as area sources without outward flow (or passive

    area sources) (Bockreis and Steinberg, 2005).

    The sampling on area sources without outward flow

    requires the use of specific hoods that have to be appropriatelydesigned in order to simulate the environmental conditions to

    which the emitting surface is usually subject. The design and

    the realization of a sampling system with such properties is

    not banal and it is still under study (Frechen et al., 2004;

    Hudson and Ayoko, 2008).

    The data presented in this paper were obtained by using 

    a wind tunnel (WT) system, which enables the simulation of 

    wind action on the sampled surface ( Jiang et al., 1995; Jiang 

    and Kaye, 1996). The WT consists of a polyethylenete-

    rephthalate (PET) hood that is positioned over the emitting 

    surface. A neutral air stream, either filtered through activated

    carbon or coming directly from a synthetic air bottle, is

    introduced at a known velocity inside the hood, simulating 

    the wind action on the liquid surface to be monitored. Air

    samples are then collected in the outlet duct by means of 

    a vacuum pump.

    Mass transfer from the monitored surface to the gaseous

    phase is guaranteed by the air stream velocity (convective

    mass transfer) (Bliss et al., 1995). This phenomenon can be

    described according to the Prandtl boundary layer theory, and

    the mass transfer coefficient calculated using the following expression:

    Kc ¼0:664D

    l  Re1=2Sc1=3

    where   Kc   is the mass transfer coefficient (m s1);   D   is the

    molecular diffusivity of the odorous compounds in the liquid

    phase;   l   is the length of the contact area between gaseous

    phase and liquid phase in the air flow direction, i.e. the length

    of the wind tunnel base; Re is the Reynolds number and  Sc the

    Schmidt number.

    The wind tunnel (Fig. 1) used during the experimentation

    has a circular section inlet and outlet duct, of 0.08 m diameter.

    The central body of the hood used was a 0.25 m wide, 0.08 mhigh and 0.50 m long rectangular section chamber. Inside the

    inlet duct there is a perforated stainless steel grid and inside

    the divergentthat connects this duct to the central body of the

    hood there are three flow deflection vanes. Both these devices

    have the function of making the air velocity profiles as

    homogeneous as possible.

    In total, 211 samples were collected in 17 different plants

    located all over Italy, treating mostly municipal wastewaters

    and an amount of industrial wastewaters comprised between

    10% and 25%, with a treatment capacity ranging from

    a minimum of 1000 m3 day1 and a maximum of 80,0000 m3

    day1.

    2.2. Analysis

    The olfactometric analyses were conducted in conformity

    with the European norm EN 13725 (2003) in the Olfactometric

    Laboratory of the Politecnico di Milano.

    Dynamic olfactometry is a sensorial technique that allows

    the determination of the odour concentration of an odorous

    air sample relating to the sensation caused by the sample

    directly on a panel of opportunely selected people. The odour

    concentration is expressed in European odour units per cubic

    metre (ouE  m3), and it represents the number of dilutions

    with neutral air that are necessary to bring the concentration

    of the sample to its odour perception threshold concentration.The analysis is carried out by presenting the sample to the

    panel at increasing concentrations by means of a particular

    dilution device called olfactometer, until the panel members

    start perceiving an odour that is different from the reference

    neutral air. The odour concentration is then calculated as the

    geometric mean of the odour threshold values of each pan-

    ellist, multiplied by a factor that depends on the olfactometer

    dilution step factor.

    An olfactometer ECOMA model TO7, based on the ‘‘yes/

    no’’ method, was used as a dilution device. This instrument

    with aluminium casing has 4 panellist places in separate

    open boxes. Each box is equipped with a stainless steel

    sniffing port and a push-button for ‘‘yes’’ (odour threshold).

    w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 1 9 7 7 – 1 9 8 51978

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    The measuring range of the TO7 olfactometer starts from

    a maximum dilution factor of 1:64,000, with a dilution step

    factor 2. All the measurements were conducted within 30 h

    after sampling, relying on a panel composed of 4 panellists.

    The odour concentration was calculated as the geometric

    mean of the odour threshold values of each panellist,

    multiplied by ffiffiffi

    2p 

      .

    2.3. Calculation of OEFs

    The OEF are developed with the aim of disposing of a simple

    method forestimating the overall odour emission rate (OER) of 

    an industrial site (Sironi et al., 2005).

    In WWTPs, odour emissions can be influenced by different

    factors, such as wastewater composition, treatment methods

    and treatment conditions (e.g. temperature, pH, retention

    time, etc.). Since emission factors in general should have

    a predictive and non-descriptive character (description of 

    plant emissions should be based on more specific data

    regarding the above mentioned aspects), enabling a quick and

    easyestimate of the overall emissions of a WWTP, theyshould

    be expressed as a function of one possible ‘‘rough’’ aspect of 

    the considered plant. It was decided, in analogy with the

    emission factors defined by the United States Environmental

    Protection Agency (1995) for other pollutants/chemical

    compounds, to refer the OEFs to a specific activity index,

    which should be representative of the examined plant and

    associated with the emitted odour quantity. In this study, the

    average yearly treatment capacity was assumed as activity

    index for WWTPs (Sironi et al., 2007). The appropriateness of 

    this choice is based on experimental evidence, which shows

    the existence of a correlation between conferred wastewater

    quantity and emitted odour quantity, and it is discussed in

    Section 3.4.

    The expression for the OEF calculation is therefore:

    OEF ¼ OERC

    where OEF is the odour emission factor in ouE m3, OER is the

    odour emission rate in ouE  year1 and  C  is the yearly treat-

    ment capacity in m3 year1. The OEF therefore represents the

    quantity of emitted odour related to the wastewater volume

    unit, i.e. it is expressed in odour units per cubic metre of 

    treated sewage.

    The OEF must be evaluated separately for each plant, and

    for each odour source, considering that each odour source is

    represented by the single treatment phases of the depuration

    cycle. The odour sources that were considered for this study

    are:

    Wastewater arrival (WW-arr); Pre-treatments (pre-tr); Primary sedimentation (I-sed); De-nitrification (denitr);

    Nitrification (nitr); Oxidation (oxi); Secondary sedimentation (II-sed); Chemical-physical treatments (ch-ph); Sludge thickening (sl-thi); Sludge storage (sl-st).

    Some considerations have to be made as far as the above

    mentioned odour sources are concerned. These sources are

    area sources without outward flow (passive area sources),

    whereliquid(orsolid)surfaceisexposedtoatmosphericagents

    and perturbations, and emissions occur directly to the atmo-

    sphere without any containment possibility. For these kind of 

    sources the evaluation of the OER requires the calculation of a parameter called specific odour emission rate (SOER), which

    is expressed in ouE s1 m2 and can be obtained by multiplying 

    the odour concentration measured at the outlet of the wind

    tunnel (ouE m3) with the flow rate of the inlet air (m3 s1) and

    dividing it bythe baseareaof the centralbodyof thehood (m2).

    The OER is then calculated as the product of the SOER and the

    emitting surface (m2) of the considered area source.

    Based on itsdefinition, the SOER is a function of theneutral

    air stream velocity that is introduced into the wind tunnel. As

    during field measurements samplings are not always con-

    ducted at the same conditions, the SOER values are evaluated

    for each sampling separately, considering the sampling 

    conditions, e.g. neutral air stream velocity, that were adoptedcase by case. The SOER values are then normalized to a refer-

    ence velocity of 0.3 m s1 (Bliss et al., 1995) using the following 

    equation, which is derived directly from the Prandtl boundary

    layer theory (Sohn et al., 2005):

    SOERv2 ¼ SOERv1

    v2v1

    1=2

    The emitting surface (e.g. dimensional characteristics of the

    wastewater treatment tanks) relevant to some of the consid-

    ered odour sources were not available. In these cases, the

    emitting surfaces had to be estimated according to the criteria

    forthe design of wastewater treatment plants (Tchobanoglous

    and Burton, 1991).

    Fig. 1 – Design of the wind tunnel.

    w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 1 9 7 7 – 1 9 8 5   1979

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    of the OEFs relevant to each of the odour sources that are

    present at the considered plant. As an example, if a WWTP

    is constituted by all the treatment phases that were

    considered as odour sources in this study, its overall

    OER could be determined according to the following 

    equation:

    OERTOT ¼ C

    OEFWW-arr þOEFpre-tr þOEFI-sed þOEFdenitrþOEFnitr þOEFoxi þOEFII-sed þOEFch-ph þOEFsl-thiþOEFsl-st

    where C is the plant treatment capacity (e.g. in m3 day1) and

    the OEF are expressed in ouE  m3

    . The index indicates theodour source which the OEFs refer to.

    The equation that allows the determination the overall

    OER, once the plant capacity is given, was obtained by

    substituting the OEFs values that were calculated in this

    study:

    OERTOT ¼C

    1:1 104 þ 1:0 105 þ 1:9 105 þ 9:2 103

    þ 7:4 103 þ 1:2 104 þ 1:3 104 þ 8:2 103

    þ 4:2 104 þ 8:3 103

    OERTOT ¼ C 4:07 105

    As an example, the overall OER relevant to a plant with an

    average treatment capacity of 50,000 m3 day1 may be calcu-

    lated according to the proposed model.

    In this specific case, the overall OER would be:

    OERTOT ¼50; 000

    1:1 104 þ 1:0 105 þ 1:9 105 þ 9:2 103þ 7:4 103 þ 1:2 104 þ 1:3 104 þ 8:2 103

    þ 4:2 104 þ 8:3 103

    OERTOT ¼ 50; 000 m3 day1 4:07 105 ouE   m3

    ¼ 2:04 1010 ouE   d1 ¼ 2:36 105 ouE   s1

    10

    100

    1000

    10000

    100000

    100   1000 10000 100000 1000000

    Treatment capacity C (m3 d-1)

       O   d  o  u  r  c  o  n  c  e  n   t  r  a   t   i  o  n  c  o   d   (  o  u   E  m  -   3   )

    Geometric mean = 845 ouE m

    -3

    Fig. 2 – Odour concentration values relevant to the sludge storage.

    Table 3 – Arithmetic mean, median and standarddeviation of the logarithms of the OEFs

    Arithmetic

    meanof log(OEF)

    Median of 

    log(OEF)

    Standard

    deviationof log(OEF)

    Wastewater arrival 4.036 3.488 1.405

    Pre-treatments 5.021 5.534 1.429

    Primary

    sedimentation

    5.280 5.072 0.854

    De-nitrification 3.962 3.797 0.631

    Nitrification 3.866 3.840 0.848

    Oxidation 4.082 4.236 0.790

    Secondary

    sedimentation

    4.118 4.120 0.524

    Chemical–physical

    treatments

    3.916 4.035 0.587

    Sludge thickening 4.629 4.698 0.894

    Sludge storage 3.917 4.009 0.701

    Table 4 – Average OEFs, median and percent deviation

    Geometricmeanof OEF

    Median of OEF %Deviation

    Wastew ater arrival 1.09Eþ04 3.09Eþ03 40Pre-treatments 1.05Eþ05 3.42Eþ05 26Primary sedimentation 1.90Eþ05 1.18Eþ05 17De-nitrification 9.15Eþ03 6.27Eþ03 17Nitrification 7.35Eþ03 6.91Eþ03 22Oxidation 1.21Eþ04 1.72Eþ04 19Secondary

    sedimentation

    1.31Eþ04 1.34Eþ04 13

    Chemical–physical

    treatments

    8.25Eþ03 1.09Eþ04 15

    Sludge thickening 4.25Eþ04 4.99Eþ04 19Sludge storage 8.26E

    þ03 1.02E

    þ04 17

    w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 1 9 7 7 – 1 9 8 5   1981

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    If any of the steps are carried out in closed sheds with an aircollection system that conveys the waste gases to an abate-

    mentsystem, the effective OER of the plant mustbe calculated

    taking account of the odour abatement efficiency of the

    adopted abatement system (Sironi et al., 2006).

    3.4. Influence of plant size on odour emissions

    In order to evaluate the influence of the size of a WWTP on its

    dour emissions, the data used for the OEF calculation were re-

    processed by dividing thembased on the plant size. The plants

    considered as ‘‘small’’ are the ones with a treatment capacity

    within 103 and 104 m3 day1, ‘‘medium’’ within 104 and 105 m3

    day1 and ‘‘large’’ within 105 and 106 m3 day1.Fig. 4   shows the average odour concentration values

    (geometric mean) for each examined odour source relevant to

    the three plant sizes. It can be observed that, if considering the

    same treatment phase, there are no significant differencesbetweenthe average odour concentration values measured on

    small, medium, or large size plants.

    This fact entails some interesting consequences for the

    correlation between the odour emission rates from the

    different treatment phases and the plant size.

    First, the SOER values relevant to each odour source, being 

    derived directly from the measured odour concentrations, are

    similar independently from the considered plant capacity.

    This means that SOER values could be used in order to

    calculate odour emissions from a proposed WWTP. None-

    theless, the direct use of SOER values for overall OER estima-

    tion entails the necessity to consider each treatment phase

    separately and to have precise information about each odoursource. Such information may not be available, especially in

    the case of a plant that does not already exist, moreover,

    calculations would be more difficult with respect to the

    1.09E+04

    1.05E+05

    1.90E+05

    9.15E+037.35E+03

    1.21E+04 1.31E+048.25E+03

    4.25E+04

    8.26E+03

    1.00E+03

    1.00E+04

    1.00E+05

    1.00E+06

       W  a  s

       t  e  w  a   t  e

      r   a  r  r   i  v

      a   l

       P  r  e -   t

      r  e  a   t  m

      e  n   t  s

       P  r   i  m

      a  r  y   s

      e  d   i  m

      e  n   t  a   t

       i  o  n

       D  e -  n   i   t  r   i   f

       i  c  a   t   i  o

      n

       N   i   t  r   i   f

       i  c  a   t   i  o

      n

      O  x   i  d  a

       t   i  o  n

      S  e  c  o

      n  d  a  r

      y   s  e  d

       i  m  e  n

       t  a   t   i  o  n

      C   h  e  m

       i  c  a   l -  p

       h  y  s   i  c

      a   l    t  r  e

      a   t  m  e  n

       t  s

      S   l  u  d

      g   e    t   h   i  c   k

      e  n   i  n  g 

      S   l  u  d  g 

      e   s   t  o  r

      a  g   e

       O   E   F   (  o  u   E  m  -   3   )

    Fig. 3 – Average OEFs for each considered odour source.

    1.00E+01

    1.00E+02

    1.00E+03

    1.00E+04

       W  a  s

       t  e  w  a   t  e

      r   a  r  r   i

      v  a   l

       P  r  e -   t

      r  e  a   t  m

      e  n   t  s

       P  r   i  m

      a  r  y   s  e

      d   i  m  e  n

       t  a   t   i  o  n

       D  e -  n   i

       t  r   i   f   i  c  a

       t   i  o  n

       N   i   t  r   i   f

       i  c  a   t   i  o

      n

      O  x   i  d  a

       t   i  o  n

      S  e  c  o

      n  d  a  r  y

       s  e  d   i  m

      e  n   t  a   t

       i  o  n

      C   h  e  m

       i  c  a   l -  p

       h  y  s   i  c

      a   l    t  r  e

      a   t  m  e  n

       t  s

      S   l  u  d  g 

      e    t   h   i  c

       k  e  n   i  n

      g 

      S   l  u  d

      g   e   s   t  o  r  a

      g   e

      c  o   d   (  o

      u   E  m  -   3   )

    Small

    Medium

    Large

    Fig. 4 – Average odour concentration relevant to each treatment phase for small, medium and large plants.

    w a t e r r e s e a r c h 4 3 ( 2 0 0 9 ) 1 9 7 7 – 1 9 8 51982

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    possibility of using of OEFs, which are useful in order to give

    a quick estimationin function of a single parameter (i.e. in this

    case the plant capacity).

    Finally, looking at Figs. 5 and 6, which illustrate the OER

    values and the OEFs in function of the plant size, respectively,

    the following considerations can be made.

    Some treatment phases, such as the primary sedimenta-

    tion, the oxidation and the secondary sedimentation, require

    an optimal residence time and tank deepness. These phases

    are therefore characterized by an emitting surface (i.e. the

    tank surface) that is proportional to the plant capacity andconsequently by odour emissions that increase proportionally

    to the plant size. On the other hand, for those treatment

    phases for which no direct relationship between the emitting 

    surface and the plant treatment capacity exists (such as the

    wastewater arrival, pre-treatments, de-nitrification, nitrifica-

    tion, sludge thickening and sludge storage), the odour emis-

    sion rates will be similar independently from the plant size

    (Fig. 5).

    The opposite consideration is valid if considering the OEFs.

    Given that the OEFs for WWTPs have been defined as the ratio

    between the OER values and the plant capacity, the OEFs

    related to the treatment phases whose emitting surface is

    proportional to the plant capacity will be similar indepen-

    dently from the plant size, whereas the OEFs relevant to odoursources whose emitting surface is independent from the plant

    capacity will decrease passing from small to larger plants

    (Fig. 6).

    1.00E+02

    1.00E+03

    1.00E+04

    1.00E+05

    1.00E+06

       W  a  s

       t  e  w  a   t  e

      r   a  r  r   i  v

      a   l

       P  r  e -   t

      r  e  a   t  m

      e  n   t  s

       P  r   i  m

      a  r  y   s  e

      d   i  m  e  n

       t  a   t   i  o  n

       D  e -  n   i

       t  r   i   f   i  c  a

       t   i  o  n

       N   i   t  r   i   f

       i  c  a   t   i  o

      n

      O  x   i  d  a

       t   i  o  n

      S  e  c  o

      n  d  a  r  y

       s  e  d   i  m

      e  n   t  a   t

       i  o  n

      C   h  e  m

       i  c  a   l -  p

       h  y  s   i  c

      a   l    t  r  e

      a   t  m  e  n

       t  s

      S   l  u  d  g 

      e    t   h   i  c

       k  e  n   i  n

      g 

      S   l  u  d  g 

      e   s   t  o  r

      a  g   e

       O   E   R

       (  o  u   E  s  -   1   )

    Small

    Medium

    Large

    Fig. 5 – Average odour emission rates relevant to each treatment phase for small, medium and large plants.

    1.00E+02

    1.00E+03

    1.00E+04

    1.00E+05

    1.00E+06

       W  a  s

       t  e  w  a   t  e

      r   a  r  r   i  v

      a   l

       P  r  e -

       t  r  e  a   t  m

      e  n   t  s

       P  r   i  m

      a  r  y   s

      e  d   i  m

      e  n   t  a   t

       i  o  n

       D  e -  n   i   t  r   i

       f   i  c  a   t   i

      o  n

       N   i   t  r   i   f

       i  c  a   t   i  o

      n

      O  x   i  d  a

       t   i  o  n

      S  e  c  o

      n  d  a  r

      y   s  e  d

       i  m  e  n

       t  a   t   i  o  n

      C   h  e  m

       i  c  a   l -  p

       h  y  s   i  c

      a   l    t  r  e

      a   t  m  e  n

       t  s

      S   l  u  d  g 

      e    t   h   i  c

       k  e  n   i  n

      g 

      S   l  u  d  g 

      e   s   t  o  r

      a  g   e

       O   E   F   (  o

      u   E  m  -   3   )

    Small

    Medium

    Large

    Fig. 6 – Average OEFs relevant to each treatment phase for small, medium and large plants.

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    4. Conclusions

    Based on the discussed results it is possible to list the

    following conclusions.

    - This paper discusses an approach for the creation of 

    a model for a rough and simple prediction of the odouremissions from a WWTP from experimental data, i.e.

    from the results of olfactometric analyses conducted on

    several Italian WWTPs.

    - Considering the same odour source, a similarity among 

    the odour concentration values measured on the different

    WWTPs is noticeable, independently from their size. This

    similarity has interesting consequences on the odour

    emission rates from the different phases, based on the

    whether the emitting surface of the considered phase is

    proportional to the plant size (i.e. treatment capacity) or

    not.

    - The obtained results show that the major odour source of 

    a WWTP is represented by the primary sedimentation,having an OEF of about 1.9 105 ouE m3. In general thehighest OEFs are observed in correspondence of the first

    steps of the wastewater depuration cycle: this demon-

    strates that the odour load of wastewater prior to biolog-

    ical treatment is rather high (OEF between 1.1 104 ouEm3 and 1.9 105 ouE m3), tending to decrease along thedepuration process (OEF between 7.4 103 ouE  m3 and4.3 104 ouE m3). This fact points out the importance of the sewer system, which influences the quality of the

    wastewater at the plant inlet and therefore its odour

    emission capacity (Frechen, 2008). For this reason, the

    operating conditions of the wastewater treatment plant

    itself generally have lower influence on odour emissionsfrom the first treatment steps than the correct manage-

    ment of the sewer system, which is often referred to as

    a subject that is different from the wastewater treatment

    plant management.

    - An indication of the margin of error introduced in the OEF

    calculation is given by the standard deviations of the

    odour concentration measurements of the different odour

    sources (Table 1). The effectiveness of the OEFs is not

    compromised by such errors, as OEFs must be useful for

    an estimation of a plant total odour impact.

    - The OEFs should be updated continuously, for example by

    adding more data from further olfactometric analyses.

    This procedure may be facilitated by creating an elec-tronic database for the insertion or variation of useful

    data for the OEF calculation.

    - The precision of the OEFs can be improved by first veri-

    fying the applicability of this model with accurate data-

    sets describing the actual conditions on site. The OEFs

    may be further refined and the margin of error associated

    with theuse of OEFs for the prediction of the odour impact

    caused by a WWTP may be reduced by evaluating their

    dependence from other parameters that were not

    considered in this study, such as for example BOD,

    temperature or humidity.

    - According to their definition, OEFs enable a simple and

    quick quantitative estimation of odour emissions,

    without taking into account odour quality, which

    nonetheless might represent an important aspect to

    be considered for odour impact and nuisance

    evaluation.

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