potential uses of south african coal fines: a review
TRANSCRIPT
Abstract—This short paper communicates various methods for
recovering energy value from fine coal discards generated by the
South African coal mining industry. The cost of dewatering or drying
these fines <150µm exceeds the fuel value of the fines. However the
quality of these fines is equivalent to that of run- of –mine coal.
These fines are normally disposed into the slurry dams. They have
negative environmental impact such as acid mine drainage, dust
release and spontaneous combustion. Various technologies for
treating and recovering the value out of these fines are discussed.
This paper, thus presents energy and material recovery from coal fine
coal discards. It also highlights the waste minimization and
utilization options for this abundantly available waste and resource.
Keywords—Energy, Environment, Fuel, Mining, Waste.
I. INTRODUCTION
LOBAL economic crisis reduced electricity and steel
production in many developed and developing countries.
The global coal production was about 6 billion metric
tonnes in 2009 with China producing about half of that [1].
Known coal reserves are spread over 100 countries. At the
production levels of 1999, world reserves were expected to
last over 100 years compared to oil and gas reserves at 45 and
65 years respectively [2]. However, in South Africa about 200
years – worth of supply is still available. In 2009, the total
world primary energy consumption by fuel was coal (26%),
gas (24%), oil (40%), nuclear (7%) and renewables (3%) [2].
Coal provides around 30% of global primary energy needs,
generates 41% of the world's electricity and is used in the
production of 70% of the world's steel [3]. The coal mining
industry was the largest component of the South African
mining sector by sales volume (R65.3 billion) with a coal
production of about 250.5 million tonnes in 2009 [1]. The
South African coal mining industry is currently disposing over
10 million tons of ultra-fine coal (<150µm) per year which is
approximately 4% of the annual coal production [4]. Coal
fines are an unavoidable by-product of the production of coal.
These fines have an average calorific value of 22.83MJ/kg
with average size fraction of 150µm. Dewatering of the high
quality fines is advantageous for several reasons including
reducing transport cost. Flotation is the only effective method
Edison Muzenda is a full professor in the Department of Chemical
Engineering Technology at the University of Johannesburg, Doornfontein,
South Africa e-mail: [email protected]
of beneficiating ultra-coal fines, and many coal producers in
the world commonly use these flotation plants. In terms of
dewatering, there are several kinds of equipment suitable for
the purpose, including screen-bowl-centrifuge, horizontal
vacuum belt filters and thermal drying. A recent study
concluded that thermal drying to 1% of the surface moisture is
the most economical method of dewatering the ultra fines. The
beneficiated and dewatered ultra-fines can be blended with
coarser coal for export market.
Un-beneficiated fines are low quality ultra-fines and
generally sold to local power stations as a feed stock. The
ultra-fines have ash content of 45%, particle size of 150
microns with nett calorific values ranging between 2-14.6
MJ/kg [5]. Thermal drying of these fines is not economically
feasible owing to the low value of coal. Waste Energy
Recovery and Management (WERM), has patented a process
of drying and recovering ultra-fines from slimes dams using
solar energy. Every 2-3 days the top of 300mm layer of the
dam is ploughed and stockpiled. The ultra-fines are dried
between to 12-18% because they become difficult to handle
outside this range [4]. Once the coal is dried, its not easy to re-
wet if it is stockpiled. This enables drying to occur during the
rainy seasons, although 30-40% decrease in yield may be
experienced.
The dried ultra-fine material is blended with re-washed
coarse waste rock. The purpose of blending the fines with
waste rock is to lower the overall moisture content. This
process converts the ultra-fines to a valuable product because
WERM operates until the slimes dam is empty. The dried
material is transported to site as a feed stock to power station.
The material is further dried by waste heat energy in the form
of flue gases from the power stations.
The fine coal plant consists of drying plant, dust separation
plant and medium phase pneumatic conveying. Drying of coal
fines is done through fluidized bed dryers using hot flue gas.
As the flue gas is inert, the drying process is safe from coal-
dust explosion [6].
II. TECHNOLOGY DISCUSSIONS
A. Ultra-fines into a low smoke fuel
This method entails converting the ultra-fine coal to a low
smoke fuel (LSF).These fuels release low levels of smoke
when burnt. These fuels are ideal for domestic usage,
particularly in the townships. Thus, this helps to reduce the
energy poverty for these disadvantaged communities by
Potential uses of South African Coal Fines:
A Review
Edison Muzenda
G
3rd International Conference on Mechanical, Electronics and Mechatronics Engineering (ICMEME'2014) March 19-20, 2014 Abu Dhabi (UAE)
37
providing them with affordable green energy. In order to
convert the ultra-fine coal into Low smoke fuels, the coal
should be agglomerated to make it easier to handle. Various
methods of agglomeration are available, including palletizing,
extrusion, binder and binder- less briquetting. Coal briquetting
can be achieved by means of pressure and / or chemical
bonding. Coal briquetting has drawbacks which have to be
addressed for this resource to be economically exploited. The
application of untreated fines and super fines cause process
difficulties as these fines can agglomerate and clog up process
equipment initially designed to use large coal particles. The
transportation and storage of fine coal pose environmental and
logistical problems. For example these fines may collect water
during transportation and become unusable. South Africa
produces millions tonnes of coal annually, hence the
production and storage of these fines is an increasing
environmental disaster that needs to be eliminated. Briquetting
offers a potential solution to these challenges. However for
briquetting to be successful, the following conditions have to
be met (i) The particles must be in the same size range (ii)
Briquettes must be water resistant for possible outside storage
(iii) Briquettes must be strong enough not to disintegrate
during transportation and handling (iv) Briquettes should have
similar properties such as heat value, fixed carbon, sulphur
content and ash content to the original coal. Laboratory tests
have been conducted at Kleinkopje by Coaltech 2020 to
establish the technical feasibility of the production of LSF
from ultra-fines in South Africa. The tests confirmed that the
process is technically feasible in South Africa [5].
B. Methane and Polymers Production
Methane gas and polymers may be produced from coal fines
through a process of solubilisation. Coal solubilisation is the
process through which coal is converted by micro organisms
and enzymes into a solution of macromolecules. These in turn
can be converted into various products, such as methane or
polymers. Low rank coals such as lignite are more susceptible
to solubilization because of their higher moisture content,
softness and low abrasion index. However certain micro-
organisms can solubilize high rank coals as well. This
technology is not commercially available in South Africa,
however research is currently being undertaken at local
universities to optimize and commercialise this process [7].
The research is driven by Coal Tech 2020, a collaborative
research programme which was formed by major coal
companies, Universities, Council for Scientific and Industrial
Research (CSIR), National Union of Mine Workers (NUM)
and the State to address the specific needs of the coal mining
industry in South Africa using local and international
knowledge and skills. The vision of Coal Tech 2020 is “The
development of technology and the application of research
findings to enable the South Africa coal industry to remain
competitive, sustainable and safe well into the Twentyfirst
Century”
C. Ultra-fines to Coal Water Fuel
Coal water fuels (CWF) are concentrated suspensions of
highly beneficiated ultra fines in water. They contain 60-70%
solids with ash content of not more than 4%.The CWF can be
produced from ultra fine slurries by undergoing extensive
grinding and crushing to improve liberation of high grade coal
so that the low ash requirement can be met. This fuel is
normally piped directly to a power station where it is burnt as
heavy oil, rather than being added to the coarse coal [8]. CWF
have several advantages over traditional dry coal, the problems
of spontaneous combustion and dust generation during
transportation and storage are eliminated. The cost of drying
and dewatering are significantly reduced and CWF are more
easily handled because, being liquid, they do not require large
scale transportation of handling facilities. There is currently no
power station in South Africa that can utilize CWF.
D. Fluidized Bed Technology
A fluidized bed reactor is a combustor in which coal
particles are suspended in a bed by updraft of gas that keeps
the coal fines in turbulent state. Research conducted by the
Council for Scientific and Industrial Research (CSIR), South
Africa has established that it is technically feasible to combust
ultra fines of 63% moisture in a fluidized bed reactor[5].A
conventional pulverized fuel boiler requires that the feed coal
contains at most 10% moisture. Therefore the cost of drying or
dewatering is greatly reduced in a fluidized bed reactor.
Although thermal efficiency of 67 is achieved, the cost of
obtaining this coal is reasonably low. The fines are unstable,
thus transport other than pipeline is not feasible. There are no
commercial fluidized bed combustion power stations in South
Africa that run on coal, although Eskom plans to install them
in the unspecified future.
E. Production of Solid Fuel
The following three fuel formulations were developed using
combinations of commonly available biomass, waste materials,
and recovered beneficiated coal fines to produce economical,
new solid fuels that reduce emissions from coal-fired boilers
[9].
Premium Fuel: Anthracite Fines & Waste Plastic
This formulation was developed for a premium fuel market,
specifically the stoker and home-heating market which
requires a very high-quality solid fuel, beneficiated anthracite
(90% by weight) is pelletized using waste mixed plastics as a
binder (10% by weight). The final pelletized low-moisture;
high-energy product is projected to have the following
qualities: 1.5% moisture, 9.0% ash, 0.56% total sulphur, and
30.27MJ/kg. The use of waste plastic as a binder reduces fuel
production costs. Fuel pellets have a high volatile content
(>90%), which can be adjusted to meet customer needs by
varying the amount of plastics in the formulation. Plastic also
has essentially no ash or sulphur and is high in heating value.
Low ash reduces particulate emissions, and the combination of
high heat content and low sulphur reduces SO2 emissions.
3rd International Conference on Mechanical, Electronics and Mechatronics Engineering (ICMEME'2014) March 19-20, 2014 Abu Dhabi (UAE)
38
Medium Quality: Coal Fines & Sewage Sludge.
This formulation was developed for a medium grade fuel
market, specifically the electric utility steam coal market.
Beneficiated coal fines (80% by weight, dry basis), such as the
type recovered from waste coal slurry impoundments, and
treated sewage sludge (20% by weight, dry basis) are mixed
and pelletized. The sewage sludge is typically received with
very high moisture content (80-85 percent), and a combination
of thermal drying and the pelletizer-dewatering would be used
to reduce the moisture content of the final product to 15
percent. The final pelletized product is projected to have the
following quality: 15.0% moisture, 10.0% ash, 1.4% total
sulphur, and 25.2MJ/kg.
Low Quality: Coal Fines & Sawdust
This formulation was developed for a low-grade fuel
market, specifically the electric utility steam coal market.
Beneficiated coal fines (90% by weight), such as the type
recovered from waste coal slurry impoundments, and sawdust
(10% by weight) are slurried during the coal preparation
process. An asphalt emulsion (at 2% dosage) is added to the
slurry prior to the mechanical dewatering step. This results in
an agglomerated product with improved dewatering
characteristics and flow ability properties, and reduces dust
generation during handling; it also improves the recovery of
fine-sized coal during the beneficiation process. This produce
is only considered to be "low quality" because of its finer size
and high moisture content as compared to typical steam-grade
bituminous coals. This agglomerated product is projected to
have the following quality: 19.0% moisture, 5.2% ash, 1.2%
total sulphur, and 23.3 MJ/kg
III. CONCLUSIONS
The current production of coal discards and slurry ponds are
35.5 and 3.26 million tonnes per year respectively. The coal
discards are generally compacted with soil and vegetated to
prevent further oxidation. These dumps are reclaimable and
can be used as feed stock to power stations. There are 29
active discards dumps (310Mt) and 17 active slurry ponds
(51Mt) available in South African coal mines. The utilization
of coal fines should aim to optimize the sometimes competing
economic, social and environmental objectives.
ACKNOWLEDGMENT
The author acknowledges Jefrey T Pilusa his PhD student
for collecting and reviewing the information as well as
assisting with drafting the manuscript. He is also indebted to
South African National Energy Development Institute
(SANEDI) through its Waste to Energy project at the
University of Johannesburg for partly funding conference
attendance. The University of Johannesburg’s Faculty of
Engineering and the Built Environment’s Research Committee
is also acknowledged for financial and technical support.
REFERENCES
[1] www.bullion.org.za/Publications/Facts and Figures 2009/ Accessed 18
February 2014
[2] BP Amoco Statistical Review of World Energy 1999 (1998 data)
[3] World Coal Association, www.worldcoal.org/resources/coal-statistics/
[4] J.F. Reddick, H. von Blottnitz, and B. Kothuis (2007). “A cleaner
production assessment of the ultra-fine coal waste generated in South
Africa” The Journal of The Southern African Institute of Mining and Metallurgy.
Vol 107, pp 55-60
[5] S.J. Mangena and G.J. de Korte (2004). “Development of a Process for
Producing Low-Smoke Fuels from Coal Discards”
[6] Horsfall, D.W. (1994). Low-smoke fuel from discards. DME Report No.
ES9017, 48 p.
[7] L.Wibberley (2011). “Coal base-load power using Micronised Refined
Coal (MRC)”, Energy Generation.
[8] B. G., Miller, D. K. Johnson, M. LaBarbera, B. A. Maben, J. L.
Morrison, R. S. Wasco, R. T. Wincek (2008). “Formulation, Production,
and Combustion Testing of a Coal-Water Mixture Prepared from Fine
Coal – Final Report,” Teck Cominco Metals Ltd.
[9] A. G. Shirey, D. J. Akers (2005). Production of New Biomass/Waste-
Containing Solid Fuels
Biography: Edison Muzenda is a Full Professor of Chemical Engineering,
the Research and Postgraduate Coordinator as well as Head of the
Environmental and Process Systems Engineering Research Group in the
Department of Chemical Engineering at the
University of Johannesburg. Professor
Muzenda holds a BSc Hons (ZIM, 1994)
and a PhD in Chemical Engineering
(Birmingham, 2000). He has more than 15
years’ experience in academia which he
gained at different Institutions: National
University of Science and Technology,
University of Birmingham, Bulawayo
Polytechnic, University of Witwatersrand,
University of South Africa and the
University of Johannesburg. Through his academic preparation and career,
Edison has held several management and leadership positions such as
member of the student representative council, research group leader,
university committees’ member, staff qualification coordinator as well as
research and postgraduate coordinator. Edison’s teaching interests and
experience are in unit operations, multi-stage separation processes,
environmental engineering, chemical engineering thermodynamics,
entrepreneurship skills, professional engineering skills, research methodology
as well as process economics, management and optimization. He is a recipient
of several awards and scholarships for academic excellence. His research
interests are in waste water treatment, gas scrubbing, environment, waste
minimization and utilization, green energy engineering as well as phase
equilibrium measurement and computation. He has published more than 180
international peer reviewed and refereed scientific articles in journals,
conferences and books. Edison has supervised 28 postgraduate students, 4
postdoctoral fellows as well as more than 140 Honours and BTech research
students. He serves as reviewer for a number of reputable international
conferences and journals. Edison is a member of the Faculty of Engineering
and Built Environment Research and Process, Energy and Environmental
Technology Committees. He has also chaired several sessions at
International Conferences. Edison is an associate member of the Institution of
Chemical Engineers (AMIChemE), member of the International Association
of Engineers (IAENG); associate member of Water Institute of Southern
Africa (WISA), Associate Editor for the South African Journal of Chemical
Engineering as well as a member of the Scientific Technical Committees and
Editorial Boards of several scientific organizations.
3rd International Conference on Mechanical, Electronics and Mechatronics Engineering (ICMEME'2014) March 19-20, 2014 Abu Dhabi (UAE)
39