pops monitoring in japan – fate and behavior of pops -
DESCRIPTION
POPs Monitoring in Japan – Fate and Behavior of POPs -. Takeshi NAKANO, (Hyogo Pref. Inst. of Pub. Health & Env. Sci.) [email protected] - PowerPoint PPT PresentationTRANSCRIPT
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POPs Monitoring in Japan Fate and Behavior of POPs -Takeshi NAKANO, (Hyogo Pref. Inst. of Pub. Health & Env. Sci.) [email protected] FUKUSHIMA (Osaka city Inst. of Pub. Health & Env. Sci.), Yasuyuki SHIBATA, Noriyuki SUZUKI, Yoshikatsu TAKAZAWA (National Inst. for Env. Studies), Yoshitoku YOSHIDA, Noriya NAKAJIMA, Yasunori ENOMOTO (Ministry of Environment), Shinsuke TANABE (Ehime University), Masatoshi MORITA (National Inst. for Env. Studies)
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Introduction POPs monitoring by Japanese Ministry of the Environment (former Environment Agency) had continued from 1978 in the biological samples and from 1986 in the water and sediment samples until 2001. To cope with the Stockholm Convention, changing pollution levels, and the technological innovations, the activity was reframed into "POPs pollution investigation (POPs monitoring survey)" in 2002 taking into consideration the data accumulation and continuity.
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Methods and MaterialsPOPs monitoring survey fiscal year 2002, -102 air samples from 34 sites, -114 water samples from 38 sites, -189 sediment samples from 63 sites, -118 biological samples from 24 sites were analyzed using HRGC/HRMS for PCBs, HCB, aldrin, endrin, DDTs, chlordanes, heptachlor, and HCHs.
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Acknowledgements This study was supported by POPs monitoring survey from the Ministry of Environment.
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Trend of PCB Use in JapanTotal 58,000tAmount of PCB use (t)
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PCB usage(t)PCB level (ng/m3)
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POPs levels (2002)AirSedimentWaterBiota0.01-1ng/m30.1-10ng/L0.05-800ng/g-dry0.1-800ng/g-wet
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AirWaterBirdFishShellfishSediment
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AirWaterBirdHuman bloodBreast milk
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2002airwaterbiotasediment-HCH-HCH
Graph3
5.2821300015000
4.573720063000
5.862820087000
3.883930039000
4.5120690033000
5.719079009000
5.325008400065000
5.4260019000029000
9.3250020000029000
223.62800049000
194.32600089000
213.63900015000
100825100014000
13068520005000
10076480004000
1065210001900
14901800015000
17543700018000
1801403100043000
1501404100068000
260190450008000
26011087005000
2201706900034000
18013012000200000
211103300016000
221204100051000
181206200099000
2327037000044000
20300150000028000
173202900008000
17140790092000
9.3220390040000
7.3120680042000
7.3200280068000
10220370063000
10120200019000
11140560009000
7.51505300028000
7.395490003000
101501400002000
1216014000018000
1012021000018000
12110180000042000
1112057000064000
101206200005000
1365450006000
1463570029000
11543600260000
9.638510017000
9.789820049000
1323027000110000
8.8206500041000
7.1192600034000
1319470008000
241707100120000
20180560069000
26240410032000
1222140066000
1823170062000
2028180028000
21309200013000
2433960002000
3227900003000
33170680002000
241406800016000
221603300017000
1081170045000
12100840011000
116962006000
1317500005000
13455400035000
174353000170000
1201405800011000
130745500084000
100905400089000
220517500023000
2906111000040000
2801108100011000
18150130000160000
151202700034000
157113000029000
15235200077000
141152000078000
1723660018000
1306202900014000
98540450004000
110470400002000
6777180003200
130825100017000
210807600016000
6126590045000
1104411000013000
98751200007000
182610000029000
201977000110000
19188000011000
222504100064000
232104300061000
242801700033000
516011000040000
16120300006000
1017013000120000
1202200021000
1401600043000
1303200055000
52032000065000
48035000019000
38028000016000
150960006700
160800003000
190680002000
543300013000
544300020000
585000049000
6300010000
310005000
3500029000
12000120000
14000
12000
21000
17000
18000
150000
170000
150000
35000
2600
26000
18000
42000
25000
95000
87000
66000
41000
9900
2600
62000
41000
44000
2000
1600
2100
6700
5100
14000
46000
120000
24000
2800
2400
3500
170000
89000
200000
160000
200000
190000
130000
110000
110000
130000
130000
180000
29000
16000
11000
540000
420000
530000
910000
1600000
1700000
50000
74000
140000
140000
85000
130000
190000
170000
110000
3600000
4700000
4400000
110000
110000
74000
-HCHpg/m, /L, /kg
-HCHpg/m, /L, /kg)
H14
1p,p'-DDTo,p'-DDT
2p,p'-DDEo,p'-DDE
3p,p'-DDDo,p'-DDD
4p,p'-DDTp,p'-DDE
5p,p'-DDTp,p'-DDD
6p,p'-DDEp,p'-DDD
7DDTsDDEs
8DDTsDDDs
9DDEsDDDs
10trans-Chlordanecis-Chlordane
11trans-Nonachlorcis-Nonachlor
12trans-ChlordaneOxychlordane
13trans-ChlordaneHeptachlor
14HeptachlorHeptachlor epoxide
15-HCH-HCH
16-HCH-HCH
17-HCH-HCH
18AldrinDieldrin
19AldrinEndrin
20DieldrinEndrin
21Toxaphene(Parlar #26)Toxaphene(Parlar #50)
22HCBDDTs
23HCBChlordanes
24HCBHeptachlor
25HCBDieldrin
26HCBEndrin
27HCBAldrin
28HCBToxaphenes
29MirexDDTs
30MirexChlordanes
31MirexHeptachlor
32MirexDieldrin
33MirexEndrin
34MirexAldrin
35MirexToxaphenes
36Total Non-ortho PCBsTeCB #81
37Total Non-ortho PCBsTeCB #77
38Total Non-ortho PCBsPeCB #126
39Total Non-ortho PCBsHxCB #169
40Total Mono-ortho PCBsPeCB #123
41Total Mono-ortho PCBsPeCB #118
42Total Mono-ortho PCBsPeCB #105
43Total Mono-ortho PCBsPeCB #114
44Total Mono-ortho PCBsHxCB #167
45Total Mono-ortho PCBsHxCB #156
46Total Mono-ortho PCBsHxCB #157
47Total Mono-ortho PCBsHpCB #189
48Total Di-ortho PCBsHpCB #170
49Total Di-ortho PCBsHpCB #180
50Total PCBsMCBs
51Total PCBsDiCBs
52Total PCBsTrCBs
53Total PCBsTeCBs
54Total PCBsPeCBs
55Total PCBsHxCBs
56Total PCBsHpCBs
57Total PCBsOCBs
58Total PCBsNCBs
59Total PCBsDeCB
1
1p,p'-DDTvso,p'-DDT
H140.810.82248.31700001900058000058000
0.550.55226.8120000063000130000010000
0.680.64206.83000004500012000021000
0.590.692205217000022000710000170000
0.50.572004631000045000540000120000
0.890.8842077420000400006800017000
0.250.424402921000035000310000320000
0.250.4119040270000460002000000350000
0.40.7841161800000360000670000180000
6.55.96.72.428000009400006800270000
4.25.99.64.6100000410001200000290000
4.84.29.42.81700005500028000081000
0.910.758.83.68200008800045000086000
1.41.23.62.66000008600012000042000
0.980.885.53.2110000096000420000130000
32.77.63.7200000150001600006000
6.84.46.23.31700001700010000060000
117.8126.71600001700030000083000
1.71.26031150000440001100000460000
1.50.96318.112000035000190000150000
2.81.8439.115000040000860000300000
3.11.8446.850004100093000
3.42651467000240004100027000
5.31.9391090003000430000140000
1.10.875.53.63100006800033000036000
1.81.43.82.431000086000510000
1.71.44.323600008000036000063000
8.97.1218.329000001600000480000110000
8.66.92414170000007300000400000140000
8.17.6237.8320000020000005300015000
2.9383.810000015000370000380000
1.11.2125.44500090001900000420000
0.640.758.53.77600014000880000210000
0.770.9661133200060007500310000
1.11491493000190001000000300000
0.961.2200411300001800036000085000
0.61297.7440000110000920000140000
0.611165.520000048000240000002300000
0.80.99286.923000061000450000130000
3.53.6124.36400008500011000009000
3.23.2134.65800008600015000081000
2.62.3164.671000012000027000075000
3.32.6206.631000003400001100000450000
53.9258.73000000280000220000150000
53.4268.85100000510000330000120000
0.660.969.94.7130000020000048000110000
1.30.91114.33400070005400031000
0.790.77103.2220003000470000150000
0.80.852.32.22500020007600010000
0.740.743.1980007000650000
1.51.14.82.9400000027000026000076000
0.761.220.799700000027000000780000190000
0.60.781.80.783900005800022000068000
0.590.771.70.66290000700005900015000
4.361812590009000500000530000
3.54.2115.562000100002200000520000
5.75.7126.2270005000620000150000
2.822.61.150007800320000
9.14.41.70.865000990000250000
7.13.81.80.936000680000140000
4.87.53.92120000015000032000061000
34.73.21.9100000025000014000039000
5.15.73.61.994000025000038000085000
3.74.525183200004900075000066000
3.12.935136200009300013000071000
2.72.755182900006000025000071000
0.961.72.82.9800020001200000450000
0.511.22.3220000400013000093000
0.851.71.61.7290004000360000130000
0.830.936.13.664000170004900083000
1.21.26.5487000230004200024000
1.823.8313000035000420000150000
1.224.23.52000004800020000020000
1.61.93.11.4130000310005100005000
11.52.51.91100002900014000033000
8.914431615000036000540000110000
20154919310000100000450000130000
2217145.5130000370005300018000
3.35132.8230000008600000440000480000
2.93.27.33.3720000026000001800000330000
2.62.75.32.1110000003200000830000170000
0.890.840.760.3581000160008400330000
1.61.30.250.194900001200001100000300000
2.920.510.2513000500030000087000
1.63.38.13.34900014000500000110000
1.92.2123.1540001700011000033000
2.62.87.83.2590001300032000076000
2.11.59.83.896000190001200007000
4.42.7113.82600005200011000063000
6.24.11243400007800026000073000
1.41.35.21.919000150001200000470000
1.42.27.74310000023000009600069000
1.83.193.71100000240000015000065000
2.915113.968000430003800022000
1.95.741144300039000550000190000
1.94.814048870002800020000015000
0.611.3126.257000012000005300007000
0.7626.63.521000085000011000031000
0.922.573.95100047000980000200000
3.18.295.226000016000028000099000
3.64084.5220000220005300016000
1.8179.55.94100015000450000450000
201120000043000920000190000
221281000240001100000270000
191088000350007900350000
983254000001000000960000230000
2004042000001300000470000110000
110292900000910000610000120000
206.796000022000011000041000
197.84500001300001200000270000
3213340000100000110000026000
144.9170000041000010000053000
7.32.362000017000029000075000
8.43.5120000340001100000480000
37000002700012000072000
1200003200019000079000
58000170004800031000
16000019000650000250000
19000038000
210000036000
260004000
24000015000
340007000
250000110000
2000000120000
53000086000
24000048000
120003000
16000036000
13000031000
16000013000
17000047000
18000044000
7900034000
34000092000
10000025000
260003000
110003000
7800010000
660007000
610007000
190003000
220002000
21000
210003000
11000
460007000
140000089000
23000000170000
1700000470000
6400012000
450005000
8300047000
39000062000
18000030000
31000054000
320000470000
48000003300000
630000310000
1300000190000
2500000560000
1400000260000
1900000610000
1200000520000
3400000540000
1600000140000
27000050000
26000044000
1500000480000
740000300000
860000270000
1400000300000
60000001500000
2200000460000
39000047000
180000094000
10000079000
720000350000
390000130000
510000350000
2000000710000
3100000850000
1100000340000
2500000460000
1800000290000
1900000330000
18000057000
19000046000
18000047000
H151816123.8350000100000380009300H151816123.8350000100000380009300
(1)3.43.374010010000008200004500012000(2)3.43.374010010000008200004500012000
3.83.8266.6200000680003800093003.83.8266.620000068000380009300
0.860.87113.345000018000066000160000.860.87113.34500001800006600016000
152.82.1390000550005400013000152.82.1390000550005400013000
0.330.966.51.5330000540003700001000000.330.966.51.533000054000370000100000
1.71.3132.9480000780005500001300001.71.3132.948000078000550000130000
0.970.596.33.26300001200005000001200000.970.596.33.2630000120000500000120000
4.23.68.85.132000002100006000001400004.23.68.85.13200000210000600000140000
1.918.13.73100001000005600001400001.918.13.7310000100000560000140000
3.93.1207.35100001500008100001100003.93.1207.3510000150000810000110000
2.51.7299.8200000510006300002100002.51.7299.820000051000630000210000
0.750.61198.643000083000690000.750.61198.643000083000185069000
6.65.1245.6380000110000200000560006.65.1245.638000011000020000056000
4.23.4296.631000078000150000390004.23.4296.63100007800015000039000
22139.12.823000019000580001700022139.12.8230000190005800017000
1.21236.31300001600058000180001.21236.3130000160005800018000
1113166.11200001700058000170001113166.1120000170005800017000
2.61.83212120000008100045000140002.61.8321212000000810004500014000
1.11.32.91.52400004900047000140001.11.32.91.5240000490004700014000
0.310.434827120000130002300001800000.310.43482712000013000230000180000
3.83.62012140000350002600002300003.83.6201214000035000260000230000
1.91.6135.8140000270002600002600001.91.6135.814000027000260000260000
4.34.37.13190000600004300004700004.34.37.1319000060000430000470000
0.781.14.22.8320010003000002900000.781.14.22.832001000300000290000
3.34.9271326006005000001000003.34.927132600600500000100000
0.640.955.97.12600600450000940000.640.955.97.1260060045000094000
8.57890005200001100008.57130089000520000110000
1.31.14.23.4580000900005300001100001.31.14.23.458000090000530000110000
136.62304634000065000510000120000136.62304634000065000510000120000
5.12.96.73.1250000057000019000005200005.12.96.73.125000005700001900000520000
108.643.31600000930000870000240000108.643.31600000930000870000240000
1.61.15.83.5190000082000011000003000001.61.15.83.519000008200001100000300000
12118.23.52200004100090000024000012118.23.522000041000900000240000
2.21.46.33.566000200008300002200002.21.46.33.56600020000830000220000
1.97.51406.722000370046002900001.97.51406.72200037004600290000
0.40.943.22.51300001700043003700000.40.943.22.5130000170004300370000
9.7101.912200004000049003900009.7101.91220000400004900390000
116.42.41.3280000310003700320000116.42.41.3280000310003700320000
9.461.90.91100002500053003800009.461.90.9110000250005300380000
1.41.2180000440007900002900001.41.218000044000790000290000
141321000051000480000170000141321000051000480000170000
1.51.375000120004800002000001.51.37500012000480000200000
18211900041004600001800001821190004100460000180000
8.25.9250000360004000001600008.25.925000036000400000160000
2.913260000460004300001200002.91326000046000430000120000
0.60.78110000095000350000870000.60.7811000009500035000087000
0.842.75600001200004400001200000.842.7560000120000440000120000
0.61.4940000190000330000870000.61.494000019000033000087000
8.37.713000002400005600001400008.37.71300000240000560000140000
1.71.612000002700007800002100001.71.61200000270000780000210000
20149900001900005400001800002014990000190000540000180000
31.7150000038000053000012000031.71500000380000530000120000
1810130000016000048000011000018101300000160000480000110000
5.22.62300000700000470000800005.22.6230000070000047000080000
138.31100000140000013000039000138.31100000140000013000039000
7.43.5420000140000110000400007.43.542000014000011000040000
5.36.31000000250000120000370005.36.3100000025000012000037000
1.51.2300000054000095000300001.51.230000005400009500030000
5.31199000019000078000240005.3119900001900007800024000
0.791.1150000220004700001800000.791.115000022000470000180000
243819000025000430000150000243819000025000430000150000
53.451000630056000017000053.4510006300560000170000
141626000036000370000100000141626000036000370000100000
3.53.2200000240004400001600003.53.220000024000440000160000
6.533350000440006700034006.53335000044000670003400
1.21.857000940018000029001.21.85700094001800002900
0.944.458000870041000067000.944.45800087004100006700
0.731.585000270008200042000.731.58500027000820004200
69001700400000210006900170040000021000
53001700320000310005300170032000031000
90002000990000480009000200099000048000
170000029000025000017000170000029000025000017000
82000014000024000085008200001400002400008500
150000023000018000015000150000023000018000015000
15000001200001400000260001500000120000140000026000
1000000190000680000830010000001900006800008300
130000170005500008500130000170005500008500
2000038009800001100020000380098000011000
220003800110000066000220003800110000066000
2700047001500005900027000470015000059000
13000039000140000520001300003900014000052000
10000030000160000640001000003000016000064000
960002400018000066000960002400018000066000
850002000017000063000850002000017000063000
82000190007800002900008200019000780000290000
68000160006100002300006800016000610000230000
1100002300072000026000011000023000720000260000
1100002900081000028000011000029000810000280000
1700004200040000014000017000042000400000140000
90000000310000001000001100009000000031000000100000110000
94000018000059000650009400001800005900065000
2000000510000570006300020000005100005700063000
64000014000050000550006400001400005000055000
53000011000049000540005300001100004900054000
45000010000018000004600004500001000001800000460000
4700011000110000028000047000110001100000280000
4600012000130000034000046000120001300000340000
55000120008300002100005500012000830000210000
68000150005100001300006800015000510000130000
280000680008000039000280000680008000039000
290000760008400038000290000760008400038000
130000200008400038000130000200008400038000
110000190008900041000110000190008900041000
180000320007500035000180000320007500035000
7800000150000110000048000078000001500001100000480000
2300000160000110000046000023000001600001100000460000
280000460001100000460000280000460001100000460000
950000270000970000420000950000270000970000420000
21000005600009700004100002100000560000970000410000
930000150000930000150000
2400007200024000072000
5700007300057000073000
17000004700001700000470000
2600005800026000058000
820000230000820000230000
61000013000006100001300000
17000001700001700000170000
730000370000730000370000
110000088000110000088000
2100003600021000036000
91000250009100025000
95000200009500020000
12000003000001200000300000
12000002900001200000290000
13000001100001300000110000
2100007300021000073000
61000300006100030000
1100003500011000035000
5100008800051000088000
96000160009600016000
81000140008100014000
70000160007000016000
1100002800011000028000
590000140000590000140000
32000008100003200000810000
6400000320000064000003200000
17000003900001700000390000
480000120000480000120000
3600007700036000077000
2400005700024000057000
2100006300021000063000
5500000140000055000001400000
1100003100011000031000
320007300320007300
420009200420009200
350007900350007900
48000140004800014000
53000002000005300000200000
44000110004400011000
77000130007700013000
1100001700011000017000
370007300370007300
290000073000290000073000
1400003000014000030000
240000030000240000030000
54000110005400011000
68000140006800014000
6000001100060000011000
500000100000500000100000
1800002900018000029000
64000110006400011000
21000006100002100000610000
110000003900000110000003900000
14000003100001400000310000
2200005400022000054000
2400005600024000056000
1800003700018000037000
1200002800012000028000
1400003200014000032000
1800004800018000048000
87009008700900
90000150009000015000
120001900120001900
320003800320003800
6300063000300
340004200340004200
300002800300002800
240006600240006600
1300300
450004400450004400
300003400300003400
600005700600005700
55000002400005500000240000
5000000039000050000000390000
27000005500002700000550000
&C&" ,"&12p,p'-DDT vs o,p'-DDT
1
p,p'-DDTpg/m, /L, /kg
o,p-DDTpg/m, /L, /kg)
H14
2
H14
H14
H14
H14
H15
H15
H15
H15
p,p'-DDTpg/m, /L, /kg
o,p'-DDTpg/m, /L, /kg
H14H15
3
p,p'-DDTpg/kg
o,p'-DDTpg/kg
H15
4
p,p'-DDTpg/m
o,p'-DDTpg/m
H15
5
p,p'-DDTpg/L
o,p'-DDTpg/L
H15
6
p,p'-DDTpg/kg
o,p'-DDTpg/kg
H15
7
p,p'-DDTpg/m, /L, /kg
o,p'-DDTpg/m, /L, /kg
H15
8
2p,p'-DDEvso,p'-DDE
H141.30.2491.6240000100001100000033000
0.830.11461.68800001800017000000049000
0.950.12391.232000010000100000018000
1.20.211103.51300006000220000034000
1.20.15862.83100007000270000048000
1.50.221503.9240000600068000014000
0.640.14763.62400008000840000110000
0.560.14382.323000080009800000013000000
1.10.29291.62400000970006100000790000
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5.21.524280000150007900000520000
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1.90.32142.22700000180000170000036000
30.4180.97900030006500004400
5.60.635.40.597000400041000024000
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110000056000
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&C&" ,"&12p,p'-DDEvso,p'-DDE
8
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0
0
0
0
0
0
0
0
p,p'-DDEpg/m, /L, /kg
o,p-DDEpg/m, /L, /kg)
H14
9
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
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0
0
0
H14
H14
H14
H14
H15
H15
H15
H15
p,p'-DDEpg/m, /L, /kg
o,p'-DDEpg/m, /L, /kg
H14H15
10
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
000
000
000
000
000
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0
0
0
0
0
0
0
0
0
0
0
0
0
p,p'-DDEpg/kg
o,p'-DDEpg/kg
H15
11
00
00
00
00
00
00
00
00
00
00
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00
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00
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00
00
00
00
00
00
00
00
00
00
00
00
p,p'-DDEpg/m
o,p'-DDEpg/m
H15
12
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
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p,p'-DDEpg/L
o,p'-DDEpg/L
H15
13
00
00
00
00
00
00
00
00
00
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
p,p'-DDEpg/kg
o,p'-DDEpg/kg
H15
14
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
p,p'-DDEpg/m, /L, /kg
o,p'-DDEpg/m, /L, /kg
H15
15
3p,p'-DDDvso,p'-DDD
H140.0610.0524.52.22000003400019000016000
0.02352.2100000086000390000023000
0.10.0784.12.2350000420009600014000
0.0225018460001000035000056000
47161300002200027000058000
0.0258722840001500019000021000
612133000065000510000180000
0.0244922350000790004900000850000
0.053371733000006400001700000460000
0.290.432.50.9320000077000098000074000
0.20.284.15600001700002700000850000
0.180.212.70.959000019000077000083000
0.0880.0862.14300000600000800000130000
0.150.145.61.7380000083000014000017000
0.10.116.31.9410000069000030000034000
0.10.13154.2310005000100000
0.210.2714437000500024000062000
0.260.3154.85000070001300000250000
0.090.1134102900006600029000002700000
0.0780.087298.2340000740002200016000
0.20.2317.5370000780001300000320000
0.110.1671936000600010000023000
0.110.127123510000770002000013000
0.120.11501964000100002000000660000
0.0650.0729.94.7110000019000017000021000
0.130.119.44.396000020000013000008000
0.0950.091134.3110000019000037000044000
0.270.43531710000000360000028000048000
0.360.65720340000001400000016000039000
0.420.6760239200000290000013000017000
0.210.245.12.213000018000550000210000
0.130.164.42.149000900047000001100000
0.0710.14299000230002500000970000
0.0960.1621311900080001100000100000
0.110.1527342800070002700000950000
0.160.189511022000600088000091000
0.0860.1660111000000380000890000130000
0.0740.1357131000000320000140000001100000
0.0590.081621375000017000045000042000
0.140.15205.31200000260000410000
0.20.19216.5120000032000024000067000
0.140.098246.814000002800001400000280000
0.140.19348.3490000093000030000002700000
0.240.32358.849000009500004600023000
0.220.27378.8510000013000001100000310000
0.0740.11102.3170000033000011000023000
0.0970.083122.8340000900001300010000
0.0459.32.581000210002200000680000
0.0660.0922.51.3440001700019000020000
0.0542.81.38300013000130000011000
0.0920.134.11.47000008600028000044000
0.10.144.11.119000000470000036000051000
0.0640.0833.81.188000039000017000039000
0.060.083.40.9997000064000015000018000
0.170.2539238100016000720000250000
0.140.227151700004700069000001100000
0.210.27241671000230001700000550000
0.140.154.51.62200110000093000
0.180.153.61.342002500000760000
0.170.183.81.391001400000160000
0.250.364.124500000740000680000120000
0.150.223.82.1340000049000023000029000
0.210.313.61.9320000056000026000033000
0.150.21592516000003700007100005000
0.130.187421140000018000022000065000
0.110.17611312000002200001200000250000
0.120.184.71.7430029000002900000
0.120.154.31.512000300011000039000
0.160.1941.5140004000690000180000
0.0850.14.71.51800003300015000027000
0.0960.0994.71.419000034000140009000
0.130.194.31.3190000340001300000420000
0.110.155.923200006100018000014000
0.110.146.3231000058000160000012000
0.0890.126.81.83600006700015000018000
0.480.67196.763000011000026000037000
0.680.77237.3720000130000440000100000
0.760.85176.266000013000014000019000
0.160.274.61.45100000012000000740000280000
0.20.351.323000006800003900000580000
0.150.225.91.42600000059000002500000590000
0.110.115.11.5370000700001200000110000
0.130.150.570.2117000004500002400000800000
0.230.266.11.83700010000890000110000
0.180.31206.118000035000930000160000
0.120.19237.32400006600017000021000
0.170.21226.72200004900022000032000
0.130.159.82.23000005400080000
0.30.219.82.374000013000021000056000
0.410.33102.28700001500001200000250000
0.140.213.41.21500005900032000002700000
0.190.343.21.1240000012000007300024000
0.310.424.91.625000001200000730000200000
0.260.418421750000270000110009000
0.140.22190274400001200001600000670000
0.130.23762240000010000014000017000
0.0740.11195.8520000360000190000012000
0.0950.17175.240000030000011000016000
0.120.19146.31300009100035000052000
0.190.253419200000050000019000048000
0.240.4930165000008000013000017000
0.10.18361921000059000640000240000
4834260000430002200000390000
4431220000460003000000780000
554125000036000110000089000
70100720000014000002000000770000
11010055000001300000980000110000
747741000009200001200000200000
2716130000017000011000015000
292386000016000069000099000
2922740000180000930000
421594000025000021000059000
3313310000740001400000270000
41152300006600031000002900000
12000002100007900028000
690000140000740000210000
5000001300001200010000
570000600002200000650000
770000140000
65000083000
15000037000
32000059000
16000038000
2200000620000
2100000600000
3500000830000
36000052000
270006000
27000048000
15000076000
7500034000
32000091000
1700000330000
990000600000
1800000440000
550000110000
11000012000
360008000
7300014000
5000010000
440009000
83002000
110002000
6400
140008000
110007000
5300019000
3000000640000
120000001400000
55000001700000
35000110000
300007000
5400012000
2000000450000
1400000320000
2000000440000
2000000740000
90000005900000
90000006000000
2200000650000
2900000600000
3200000620000
41000001700000
43000003000000
38000002500000
6600001300000
400000210000
270000150000
39000001400000
27000001100000
32000001100000
45000001300000
230000006000000
44000001200000
1000000380000
1300000720000
830000740000
1700000750000
1100000610000
1100000510000
53000001100000
64000001600000
3600000950000
110000002200000
73000001500000
73000001600000
2200000820000
2300000960000
1700000680000
H150.570.657.53770000120000430006500H150.570.657.53770000120000430006500
(1)0.180.21410672800000570000560008300(2)0.180.21410672800000570000560008300
0.10.176118390000650004700066000.10.17611839000065000470006600
0.0550.0776.51.72700006800083000110000.0550.0776.51.7270000680008300011000
0.0660.175.11.4170000390006900087000.0660.175.11.417000039000690008700
0.0370.065153.913000027000280000470000.0370.065153.91300002700028000047000
0.10.12144.2930000180000260000500000.10.12144.293000018000026000050000
0.0790.0963511950000200000330000600000.0790.096351195000020000033000060000
0.20.22255.12500000540000320000650000.20.22255.1250000054000032000065000
0.130.114511430000120000410000750000.130.11451143000012000041000075000
0.310.56119260000700004900001300000.310.5611926000070000490000130000
0.230.235924230000680005100001400000.230.23592423000068000510000140000
0.0630.059442790000001500000330000850000.0630.05944279000000150000033000085000
0.240.338.12.177000001600000260000590000.240.338.12.17700000160000026000059000
0.180.266.22889000001600000180000370000.180.266.2288900000160000018000037000
0.650.776512480006200240000400000.650.77651248000620024000040000
0.0910.11184.67800012000280000440000.0910.11184.6780001200028000044000
0.811256.6560007700290000490000.811256.656000770029000049000
0.230.28174.969000026000200000350000.230.28174.96900002600020000035000
0.0820.0953.51.16700015000200000370000.0820.0953.51.1670001500020000037000
0.0510.065443879000160003400001200000.0510.06544387900016000340000120000
0.130.161837430000990005100002500000.130.16183743000099000510000250000
0.120.134930440000980005800003200000.120.13493044000098000580000320000
0.20.2837124600001100007900004100000.20.283712460000110000790000410000
0.0480.0625.42.42600038005300002500000.0480.0625.42.4260003800530000250000
0.170.26369.416000310020000003600000.170.26369.41600031002000000360000
0.0650.0834.82.721000370020000004400000.0650.0834.82.72100037002000000440000
0.360.42103.8180000035000021000003500000.360.42103.818000003500002100000350000
0.0940.1192.7170000031000017000002900000.0940.1192.717000003100001700000290000
0.230.28170160100000019000018000003800000.230.2817016010000001900001800000380000
0.140.154.91.44100000150000037000009200000.140.154.91.4410000015000003700000920000
0.380.48113.914000000590000028000008700000.380.48113.91400000059000002800000870000
0.210.189.53.75700000200000032000008300000.210.189.53.7570000020000003200000830000
0.350.6112.473000014000030000007000000.350.6112.47300001400003000000700000
0.170.154.61.71500002700027000008800000.170.154.61.7150000270002700000880000
0.240.32391071000110009400001200000.240.3239107100011000940000120000
0.0840.14.51.737000760013000001500000.0840.14.51.73700076001300000150000
0.430.515.31.51200003900012000001400000.430.515.31.5120000390001200000140000
0.290.424.21.949000960011000001100000.290.424.21.94900096001100000110000
0.610.54.91.951000016000012000001800000.610.54.91.95100001600001200000180000
0.130.13110000037000019000005700000.130.1311000003700001900000570000
0.530.69110000038000012000003300000.530.6911000003800001200000330000
0.140.1458000014000011000003400000.140.145800001400001100000340000
0.590.56660001300010000002900000.590.5666000130001000000290000
0.380.3724000006000009000002600000.380.372400000600000900000260000
0.260.3315000003400009700001100000.260.331500000340000970000110000
0.110.122100000450000720000910000.110.12210000045000072000091000
0.0870.1329000006200007400001000000.0870.132900000620000740000100000
0.0910.1765000001800000760000970000.0910.176500000180000076000097000
0.490.764300000110000011000001500000.490.76430000011000001100000150000
0.10.124500000100000017000002900000.10.12450000010000001700000290000
0.40.4735000008000009300001700000.40.473500000800000930000170000
0.160.13370000085000011000001900000.160.1337000008500001100000190000
1.10.9823000005400009500001400001.10.982300000540000950000140000
0.250.2973000003300000930000950000.250.297300000330000093000095000
0.480.6649000004200000140000210000.480.664900000420000014000021000
0.520.3438000003200000100000170000.520.343800000320000010000017000
0.240.343000003300000110000160000.240.34300000330000011000016000
0.150.1345000003600000120000190000.150.134500000360000012000019000
0.360.314200000270000082000120000.360.31420000027000008200012000
0.0790.093500000120000490000720000.0790.09350000012000049000072000
1.41.237000080000390000520001.41.23700008000039000052000
0.280.311000024000550000730000.280.31100002400055000073000
0.710.8755000096000340000520000.710.875500009600034000052000
0.20.2526000038000600000880000.20.252600003800060000088000
1.31.3100000021000020000012001.31.310000002100002000001200
0.180.3100000290002400003800.180.310000029000240000380
0.0860.14120000320004300008300.0860.1412000032000430000830
0.130.156800020000650007300.130.15680002000065000730
370014003500002100370014003500002100
610020001100009500610020001100009500
88002300310000160008800230031000016000
5400000670000110000780054000006700001100007800
2900000380000120000500029000003800001200005000
5700000680000130000960057000006800001300009600
20000003900003900000320002000000390000390000032000
13000002300002900000160001300000230000290000016000
4800007500014000001200048000075000140000012000
120002800220000018000120002800220000018000
140002700260000036000140002700260000036000
1600034002900007100016000340029000071000
22000045000270000760002200004500027000076000
18000040000340000950001800004000034000095000
2300005100036000010000023000051000360000100000
29000072000330000920002900007200033000092000
34000077000170000019000003400007700017000001900000
33000079000140000015000003300007900014000001500000
6600001300001700000190000066000013000017000001900000
5600001300001700000190000056000013000017000001900000
580000130000930000990000580000130000930000990000
86000000240000002200001100008600000024000000220000110000
23000005600002500001300002300000560000250000130000
110000002900000250000120000110000002900000250000120000
63000006800002300001200006300000680000230000120000
34000004500002500001300003400000450000250000130000
3000000490000140000047000030000004900001400000470000
200000420001400000430000200000420001400000430000
220000460001300000390000220000460001300000390000
250000530001300000400000250000530001300000400000
280000490001100000320000280000490001100000320000
7400001300009500960074000013000095009600
7200001200009100740072000012000091007400
17000059000750065001700005900075006500
24000098000940094002400009800094009400
1900006600010000920019000066000100009200
250000088000026000001000000250000088000026000001000000
25000001000000260000011000002500000100000026000001100000
100000041000025000001000000100000041000025000001000000
280000010000002300000920000280000010000002300000920000
630000021000002200000900000630000021000002200000900000
22000009300002200000930000
18000005300001800000530000
17000004900001700000490000
4000000120000040000001200000
13000005400001300000540000
16000006900001600000690000
2000000110000020000001100000
2000000990000020000009900000
17000007600001700000760000
14000005800001400000580000
560000150000560000150000
460000110000460000110000
440000120000440000120000
7300000190000073000001900000
29000007900002900000790000
19000004600001900000460000
700000230000700000230000
200000120000200000120000
310000100000310000100000
55000008800005500000880000
3500007100035000071000
3100006500031000065000
1900003800019000038000
1600003300016000033000
2100004400021000044000
4600000120000046000001200000
140000004600000140000004600000
28000007000002800000700000
980000220000980000220000
890000210000890000210000
610000150000610000150000
3200007800032000078000
20000004000002000000400000
3300008600033000086000
13000002400001300000240000
3800008100038000081000
3900008700039000087000
4100008500041000085000
9700009600097000096000
4000008400040000084000
1700003900017000039000
3600006800036000068000
1500003700015000037000
320000008800000320000008800000
28000006800002800000680000
7000000170000070000001700000
3100005600031000056000
2900005300029000053000
1900003800019000038000
15000003000001500000300000
1200001800012000018000
2900004400029000044000
41000008800004100000880000
17000000100000001700000010000000
7600000160000076000001600000
19000003700001900000370000
20000003900002000000390000
19000003600001900000360000
15000002800001500000280000
15000002800001500000280000
13000002600001300000260000
9100170091001700
3400006600034000066000
440006900440006900
290005100290005100
580008800580008800
320006000320006000
6800100068001000
100001600100001600
1850500
420004500420004500
250004600250004600
210003800210003800
38000006700003800000670000
230000002600000230000002600000
5800000150000058000001500000
&C&" ,"&12p,p'-DDDvso,p'-DDD
15
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
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0000
0000
0000
0000
0000
0000
0000
0000
0000
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0000
0000
0000
0000
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0000
0000
0000
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0000
000
000
000
000
000
000
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000
000
000
000
00
00
00
00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
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0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
p,p'-DDDpg/m, /L, /kg
o,p-DDDpg/m, /L, /kg)
H14
16
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
00000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
0000000
000000
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0000
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0000
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000
000
000
000
00
00
00
00
00
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0
0
0
H14
H14
H14
H14
H15
H15
H15
H15
p,p'-DDDpg/m, /L, /kg
o,p'-DDDpg/m, /L, /kg
H14H15
17
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
p,p'-DDDpg/kg
o,p'-DDDpg/kg
H15
18
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
p,p'-DDDpg/m
o,p'-DDDpg/m
H15
19
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
p,p'-DDDpg/L
o,p'-DDDpg/L
H15
20
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
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00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
p,p'-DDDpg/kg
o,p'-DDDpg/kg
H15
21
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
000
000
000
000
000
000
000
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000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
00
00
00
00
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00
00
00
00
00
00
00
00
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00
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00
00
00
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00
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00
00
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00
00
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
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0
0
0
0
0
0
0
0
0
0
0
0
p,p'-DDDpg/m, /L, /kg
o,p'-DDDpg/m, /L, /kg
H15
22
4p,p'-DDTvsp,p'-DDE
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