General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights.

Users may download and print one copy of any publication from the public portal for the purpose of private study or research.

You may not further distribute the material or use it for any profit-making activity or commercial gain

You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim.

Downloaded from orbit.dtu.dk on: Jun 22, 2021

Phytoscreening of BTEX and chlorinated solvents by tree coring

Nielsen, Mette Algreen; Trapp, Stefan; Kalisz, Mariusz; Krupanek, Janusz; Stalder, Marcel; Martac,Eugeniu; Broholm, Mette Martina

Publication date:2014

Document VersionPublisher's PDF, also known as Version of record

Link back to DTU Orbit

Citation (APA):Nielsen, M. A., Trapp, S., Kalisz, M., Krupanek, J., Stalder, M., Martac, E., & Broholm, M. M. (2014).Phytoscreening of BTEX and chlorinated solvents by tree coring. Poster session presented at Ninth InternationalConference on Remediation of Chlorinated and Recalcitrant Compounds , Monterey, California, United States.

https://orbit.dtu.dk/en/publications/45cf3244-f2c8-47da-93ed-8e1c569dce53

fPh

tosc

reen

ing

ofB

TEX

and

chl

Phyt

oscr

eeni

ngof

BTE

Xan

dch

lPh

ytos

cree

ning

ofB

TEX

and

chl

Phyt

oscr

eeni

ng o

f BTE

X an

d ch

ly

gM

ette

Alg

reen

1(m

ann@

endt

dk)

Ste

fan

Trap

p1M

ari

sK

alis

2J

Met

teA

lgre

en1

(man

n@en

v.dt

u.dk

),S

tefa

nTr

app1

,M

ariu

szK

alis

z2,J

Met

te A

lgre

en(m

ann@

env.

dtu.

dk),

Ste

fan

Trap

p,

Mar

iusz

Kal

isz

, J

Ti

BT

lEt

hlb

Tree

corin

gB

enze

neTo

luen

eEt

hylb

enz

Tree

cor

ing

Ben

zene

, Tol

uene

, Eth

ylbe

nz

App

licat

ion:

Phy

tosc

reen

ing

bytr

eeco

ring

isa

low

-cos

tand

easy

met

hod

for

App

licat

ion:

Phy

tosc

reen

ing

by tr

ee c

orin

g is

a lo

w-c

ost a

nd e

asy

met

hod,

for

scre

enin

gof

shal

low

pollu

tion

over

larg

ear

eas

Itca

nbe

used

to

Purp

ose:

Test

met

hod

feas

ibili

tysc

reen

ing

of s

hallo

w p

ollu

tion

over

larg

e ar

eas.

It c

an b

e us

ed to

Pu

rpos

e: T

est m

etho

d fe

asib

ility

.fo

cus

othe

rmor

ead

vanc

edan

dco

st-in

tens

ive

scre

enin

gT

tit

FA

ib

iS

tfo

cus

othe

r mor

e ad

vanc

ed a

nd c

ost-i

nten

sive

scr

eeni

ng

Te

stsi

te:F

orm

erA

irba

sein

Szp

rota

wa

met

hods

tom

ake

site

char

acte

rizat

ion

mor

eef

ficie

ntTe

st s

ite: F

orm

er A

ir ba

se in

Szp

rota

wa

Pl

dm

etho

ds, t

o m

ake

site

cha

ract

eriz

atio

n m

ore

effic

ient

. P

olan

d.

Tr

eesp

ecie

s:P

ine

birc

hw

illow

and

asS

ubsu

rface

pollu

tant

sar

eta

ken

upby

the

root

syst

eman

d

Tree

spe

cies

: Pin

e, b

irch,

will

ow a

nd a

sS

ubsu

rface

pol

luta

nts

are

take

n up

by

the

root

sys

tem

and

tr

ansf

erre

dto

the

woo

dC

ores

from

the

stem

are

sam

pled

bya

C

onta

min

atio

nle

vel:

tran

sfer

red

to th

e w

ood.

Cor

es fr

om th

e st

em a

re s

ampl

ed b

y a

C

onta

min

atio

n le

vel:

hand

drill

and

anal

yzed

The

exte

ndan

dle

velo

fthe

-H

igh

risk

area

s:50

-70

mg

BTE

X/k

gha

nd d

rill a

nd a

naly

zed.

The

ext

end

and

leve

l of t

he

Hig

h ris

k ar

eas:

50

70 m

g B

TEX

/kg.

O

idhi

hi

k2

23

BTE

cont

amin

atio

nis

map

ped

The

met

hod

has

show

nto

bew

ell

-O

utsi

dehi

ghris

kar

eas:

2-2.

3m

gB

TEco

ntam

inat

ion

is m

appe

d. T

he m

etho

d ha

s sh

own

to b

e w

ell

id

fhl

id

lb

hli

iO

utsi

de h

igh

risk

area

s: 2

2.3

mg

BTE

suite

dfo

rchl

orin

ated

solv

ents

butt

hecu

rrent

appl

icat

ion

atC

ili

Sil

lsu

ited

for c

hlor

inat

ed s

olve

nts,

but

the

curre

nt a

pplic

atio

n at

B

TEX

ti

td

iti

liit

d

Com

paris

on s

ampl

ing:

Soi

l sam

ples

.B

TEX

cont

amin

ated

site

sis

limite

d.p

pg

pB

TEX

con

tam

inat

ed s

ites

is li

mite

d.

Out

com

e:Th

fthi

td

Out

com

e:Th

epu

rpos

eof

this

stud

yw

as:

The

purp

ose

of t

his

stud

y w

as:

Tt

tth

fib

ilitft

hth

dB

TEX

it

lB

TEX

can

bede

tect

edin

the

woo

d

Tote

stth

efe

asib

ility

ofth

em

etho

das

aB

TEX

scre

enin

gto

ol.

B

TEX

can

be

dete

cted

in th

e w

ood.

To te

st th

e fe

asib

ility

of t

he m

etho

d as

a B

TEX

scr

eeni

ng to

ol.

Tt

ii

itil

ith

dith

il

Toco

mpa

retre

eco

ring

asan

initi

alsc

reen

ing

met

hod

with

soil

Th

ehi

ghris

kar

eaw

aslo

cate

dho

wev

erTo

com

pare

tree

cor

ing

as a

n in

itial

scr

eeni

ng m

etho

d w

ith s

oil

li

The

high

risk

are

a w

as lo

cate

d, h

owev

erga

s sa

mpl

ing.

no

n-de

tect

ed)o

ccur

whe

nco

mpa

ring

wit

gp

gno

n-de

tect

ed) o

ccur

whe

n co

mpa

ring

wit

Th

em

etho

dde

pend

son

the

tree

spec

ies

The

met

hod

depe

nds

on th

e tre

e sp

ecie

si

bf

lft

lbi

hi

pine

may

be

usef

ul fo

r tol

uene

, birc

h is

np

y,

Sli

dSa

mpl

ing

proc

edur

eSa

mpl

ing

proc

edur

e

1)Th

eS

uunt

ubo

rer:

Cor

eex

tract

orbo

rera

ndha

ndle

1)Th

e S

uunt

ubo

rer:

Cor

e ex

tract

or, b

orer

and

han

dle.

) 2)

Scr

ewin

gin

the

bore

rto

the

stem

2) S

crew

ing

in th

e bo

rer t

o th

e st

em.

Cor

rect

sam

plin

gpo

int:

1m

heig

ht6

cmin

dept

hC

orre

ct s

ampl

ing

poin

t: 1

m h

eigh

t, 6

cm in

dep

th.

3)I

if

h3)

Inse

rtion

ofth

eco

reex

tract

or.

3)In

serti

on o

f the

cor

e ex

tract

or.

4)R

ift

lH

igh

risk

area

4)R

emov

ing

of tr

ee c

ore

sam

ple.

)g

p

5)Th

etre

eaf

ters

ampl

ing

5) T

he tr

ee a

fter s

ampl

ing.

Bas

edRe

sults

for

foi

l to

com

pariso

nBas

edRe

sults

for

foi

l to

com

pariso

n

1)2)

3)4)

5)1)

2

) 3)

4)

5)

Cl

iC

oncl

usio

n:C

oncl

usio

n:T

iill

db

itb

Tr

ee c

orin

g w

illow

and

asp

can

be

suita

bg

phi

ghris

kar

eas

forB

TEX

high

risk

are

as fo

r BTE

X.

g

M

ore

inve

stig

atio

nsar

ene

eded

M

ore

inve

stig

atio

ns a

re n

eede

d.

Priv

ate

phot

osP

rivat

e ph

otos

lorin

ated

sol

ents

btr

eeco

ring

lorin

ated

solv

ents

bytr

eeco

ring

lorin

ated

solv

ents

bytr

eeco

ring

lorin

ated

sol

vent

s by

tree

cor

ing

yg

Jan

sK

rpa

nek2

Mar

celS

tald

er3

Ege

niM

arta

c4M

ette

Bro

holm

1Ja

nusz

Kru

pane

k2,M

arce

lSta

lder

3 ,E

ugen

iuM

arta

c4,M

ette

Bro

holm

1 .Ja

nusz

Kru

pane

k, M

arce

l Sta

lder

, Eug

eniu

Mar

tac

, Met

te B

roho

lm.

dX

l(B

TEX)

Chl

it

dl

t(PC

E)ze

nean

dXy

lene

s(B

TEX)

Chl

orin

ated

solv

ent(

PCE)

zene

and

Xyl

enes

(BTE

X)C

hlor

inat

ed s

olve

nt (P

CE)

App

licat

ion:

App

licat

ion:

Test

site

Pu

rpos

e:M

etho

dco

mpa

rison

oftre

eco

ring

Test

site

Pu

rpos

e: M

etho

d co

mpa

rison

of t

ree

corin

g Te

st

itan

sso

ilga

ssa

mpl

ing

a,si

tean

sso

il ga

s sa

mpl

ing.

a,

T

tit

Fi

dti

ld

tii

Te

stsi

te:F

orm

erin

dust

rialp

rodu

ctio

nin

Test

site

: For

mer

indu

stria

l pro

duct

ion

in

Jtl

dD

ksp

Jutla

nd D

enm

ark.

sp.

Pic

ture

mod

ified

from

Tree

spec

ies:

Bee

choa

kpi

nean

dot

hers

Goo

gle

Ear

th

Tree

spe

cies

: Bee

ch, o

ak, p

ine

and

othe

rs.

C

onta

min

atio

nle

vel:

5-32

10μg

PCE/m

3

EX

/k

Con

tam

inat

ion

leve

l: 5-

3210

μg PC

E/m

.E

X/k

g.E

X/k

g.

C

ompa

rison

sam

plin

g:S

oilg

assa

mpl

ing

Com

paris

on s

ampl

ing:

Soi

l gas

sam

plin

g.A

n ae

ropl

ane

shed

in th

e ha

ngar

g

area

(med

ium

pol

lute

d).

Pi

th

tP

rivat

e ph

oto.

P

ictu

res

from

a C

OW

I rep

ort

Visi

ble

cont

amin

atio

n in

the

high

risk

area

Out

com

e:in

the

high

risk

are

a.

Priv

ate

phot

o.O

utco

me:

Priv

ate

phot

o.

C

hlor

inat

edso

lven

tsca

nbe

dete

cted

inth

ew

ood

and

high

risk

area

C

hlor

inat

ed s

olve

nts

can

be d

etec

ted

in th

e w

ood

and

high

risk

are

a g

wer

elo

cate

drs

ome

disc

repa

ncie

s(in

clud

ing

wer

e lo

cate

d.r s

ome

disc

repa

ncie

s (in

clud

ing

thso

ilsa

mpl

es

Eva

luat

ion

ofda

taan

dco

mpa

rison

with

othe

rmet

hods

shou

ldbe

base

dth

soi

l sam

ples

.E

valu

atio

n of

dat

a an

d co

mpa

rison

with

oth

er m

etho

ds s

houl

d be

bas

ed

onra

nked

data

.s;

will

owan

das

par

epr

efer

red,

on ra

nked

dat

a.s;

will

ow a

nd a

sp a

re p

refe

rred

, t

dd

Aiti

td

ib

db

tk

dil

dt

ino

t rec

omm

ende

d.

A

posi

tive

trend

is o

bser

ved

betw

een

rank

ed s

oil g

as a

nd tr

ee c

orin

g p

gg

resu

ltsre

sults

.

2035

0012

020 g

Dat

a ab

ove

DL

and

QL

Tree

cor

e18 ring

Bel

owQ

L30

0010

0

cor

Bel

ow Q

L30

0010

0

3]

L]

Soi

l gas

16 ee c

Bel

ow D

L25

00

/m3

μg/L

14 y tre

2500

80

[μg/

s [μ

14 by

80

ns [

ons

12 ned

2000

ion

atio

ain

60

rat

ntra

10 obta

1500

60

ent

cen

8

ts o

1500

nce

con

8

sult

40

co

re c

6

res

1000

as

cor

4

of

il g

ee c

4

nk

500

20

Soi

Tre

2

Ra

500

S

2

00

00

0

DDDDDDDDDDDDDDDDDDDD

d on

10

data

sets

wer

e bo

th w

illow

and

asp

wer

e sa

mpl

ed0

24

68

1012

1416

1820

01-2.06-2.6b-2.6c-2.6d-1.

7-1.7c-2.d-2.

97-1.6-1.b-1.7i-2.

02-1.7e-1.g-2.

7k-2.h-1.7j-1.8-1.

6e-1.

d on

10

data

sets

wer

e bo

th w

illow

and

asp

wer

e sa

mpl

edR

ank

ofre

sults

obta

ined

byso

ilga

sm

easu

rem

ents

1010

316316316

31317317

931

31731720

31731731731731731

316

Ran

k of

resu

lts o

btai

ned

by s

oil g

as m

easu

rem

ents

Sam

plin

gpo

int

Sam

plin

g po

int

Cl

iC

oncl

usio

n:C

oncl

usio

n:bl

iiti

lli

tlt

lt

Ti

ill

itd

it

lf

lti

fPC

E(

dTC

E)

ble

as in

itial

ly s

cree

ning

tool

to lo

cate

Tree

corin

gis

wel

lsui

ted

scre

enin

gto

olfo

rloc

atin

gof

PC

E(a

ndTC

E)

yg

Tree

cor

ing

is w

ell s

uite

d sc

reen

ing

tool

for

loca

ting

of P

CE

(and

TC

E)

ti

tii

thh

llb

fd

til

lt

idtif

/hi

hco

ntam

inat

ion

in th

e sh

allo

w s

ubsu

rface

and

par

ticul

arly

to id

entif

y so

urce

/hig

h p

yy

gris

kar

eas

risk

area

s.

G

ood

supp

lem

entt

oso

ilga

ssa

mpl

ing

G

ood

supp

lem

ent t

o so

il ga

s sa

mpl

ing.

Q

L Q

tifi

ti li

it D

L D

tti

liit

QL:

Qua

ntifi

catio

ns li

mit,

DL:

Det

ectio

n lim

it

1A

ffilia

tion:

1 Tec

hnic

al U

nive

rsity

of D

enm

ark,

Kgs

. Lyn

gby,

Den

mar

k,

y,

gy

gy,

,2 In

stitu

tefo

rEco

logy

ofIn

dust

rialA

reas

Kat

owic

eP

olan

dIn

stitu

te fo

r Eco

logy

of I

ndus

trial

Are

as, K

atow

ice,

Pol

and,

3 S

lGA

GS

lth

Sit

ld

3 Sol

Geo

AG

, Sol

othu

rn, S

witz

erla

nd,

4 Fug

roC

onsu

ltG

mbH

Mös

sing

enG

erm

any

Fugr

o C

onsu

lt G

mbH

, Mös

sing

en, G

erm

any.

Lite

ratu

re:h

ttp://

ww

w.ti

mbr

e-pr

ojec

t.eu/

Lite

ratu

re: h

ttp://

ww

w.ti

mbr

epr

ojec

t.eu/

A

dditi

onal

sam

plin

ggu

idel

ine

and

inve

stig

atio

nsre

port

will

beav

aila

ble

atth

eho

mep

age

sum

mer

2014

Add

ition

al s

ampl

ing

guid

elin

e an

d in

vest

igat

ions

repo

rt w

ill b

e av

aila

ble

at th

e ho

mep

age

sum

mer

201

4.

Ack

now

ledg

emen

t:Fi

nanc

ials

uppo

rtby

the

Eur

opea

nC

omm

unity

'sS

even

thFr

amew

ork

Pro

gram

me

FP7

proj

ectT

IMB

RE

Ack

now

ledg

emen

t: Fi

nanc

ial s

uppo

rt by

the

Eur

opea

n C

omm

unity

s S

even

th F

ram

ewor

k P

rogr

amm

e FP

7, p

roje

ct T

IMB

RE

.

/ColorImageDict > /JPEG2000ColorACSImageDict > /JPEG2000ColorImageDict > /AntiAliasGrayImages false /CropGrayImages true /GrayImageMinResolution 300 /GrayImageMinResolutionPolicy /OK /DownsampleGrayImages true /GrayImageDownsampleType /Bicubic /GrayImageResolution 300 /GrayImageDepth -1 /GrayImageMinDownsampleDepth 2 /GrayImageDownsampleThreshold 1.50000 /EncodeGrayImages true /GrayImageFilter /DCTEncode /AutoFilterGrayImages true /GrayImageAutoFilterStrategy /JPEG /GrayACSImageDict > /GrayImageDict > /JPEG2000GrayACSImageDict > /JPEG2000GrayImageDict > /AntiAliasMonoImages false /CropMonoImages true /MonoImageMinResolution 1200 /MonoImageMinResolutionPolicy /OK /DownsampleMonoImages true /MonoImageDownsampleType /Bicubic /MonoImageResolution 1200 /MonoImageDepth -1 /MonoImageDownsampleThreshold 1.50000 /EncodeMonoImages true /MonoImageFilter /CCITTFaxEncode /MonoImageDict > /AllowPSXObjects false /CheckCompliance [ /None ] /PDFX1aCheck false /PDFX3Check false /PDFXCompliantPDFOnly false /PDFXNoTrimBoxError true /PDFXTrimBoxToMediaBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXSetBleedBoxToMediaBox true /PDFXBleedBoxToTrimBoxOffset [ 0.00000 0.00000 0.00000 0.00000 ] /PDFXOutputIntentProfile () /PDFXOutputConditionIdentifier () /PDFXOutputCondition () /PDFXRegistryName () /PDFXTrapped /False

/CreateJDFFile false /Description > /Namespace [ (Adobe) (Common) (1.0) ] /OtherNamespaces [ > /FormElements false /GenerateStructure false /IncludeBookmarks false /IncludeHyperlinks false /IncludeInteractive false /IncludeLayers false /IncludeProfiles false /MultimediaHandling /UseObjectSettings /Namespace [ (Adobe) (CreativeSuite) (2.0) ] /PDFXOutputIntentProfileSelector /DocumentCMYK /PreserveEditing true /UntaggedCMYKHandling /LeaveUntagged /UntaggedRGBHandling /UseDocumentProfile /UseDocumentBleed false >> ]>> setdistillerparams> setpagedevice