phenosafranin in photography

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JL:ly, I921.1 CURRENT TOPICS. I43 Phenosafranin in Photography.--Great interest has been awakened by the discovery of the strong densitizing powers of the dyestuff known commercially as phenosafranin in Europe and supplied by an American manufacturer under the title Safranin A. extra. Dr.. Liippo-Cramer, Technical Director of Kranseder & Co.. Munich, whose fame in photographic research is interna- tional, called attention to the peculiar property that dilute solu- tions of this color have in diminishing the sensibility of exposed plates without appreciably affecting the latent image. As might be expected, many other substances have similar properties, but none so far examined equals phenosafranin. Solutions of not over one part of the color to 2ooo of water are efficient, and such solu- tion keeps. Lfippo-Cramer has further found that the dye mark- edly accelerates the action of hydroquinone, and that it also acts as preservative of developers. A solution of the material has re- cently been put on the market by an English firm under the title " Desensitol." This is a very concentrated solution, and is directed to be diluted to abont fifty times for use. A. and L. Lmniere and Sevewitz have recently presented a communication "~o the French Pfmtographic Society, detailing the results of many experiments to determine what other substances are densitizers. The paper has appeared in very full abstract in a recent issue of La l~c~'z~e Fr~znfaise dc Photographic. Lfil~p~-Cramer has published a small book giving an account of his researches in the field, and discussing some of the theories of the action. H.L. Note on the Possibility of Separating Mercury into Its Iso- topic Forms by Centrifuging. J. H. J. POOLE. (Phil. Mag., May, I92I.)--According to Aston's results mercury is a mixture of six isotopes having atomic weights of ~97, 198, I99, 200, 202 and 2o 4. To simplify the problem of finding on theoretical grounds whether it be possible to separate the liquid into its isotopes by centrifuging several assumptions are made. Only two isotopes are considered at present, and these have a difference in atomic weight of 4 units. They are in approximately equal amounts and are supposed to differ only in mass ; all other constants being the same for both. Mercury is regarded as incompressible. The conditions of equilibrium for such a mixture in a rotating tube placed in a centrifugal field of force are examined, and it is found that the difference of density between the two ends of the rotating tube would be only one part in 3o,ooo for 9ooo revolutions per minute. So minute a difference could hardly be detected. It is suggested that a centrifuge could be made to run at 6o,ooo revolu- tions per minute, and that with this apparatus the difference of density would reach z~ parts per thousand, which could be de- tected. After~attaining this conclusion the author puts a curb on anticit~ati0n by saying: " The results obtained would apparently

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JL:ly, I921.1 CURRENT TOPICS. I43

Phenosafranin in P h o t o g r a p h y . - - G r e a t interest has been awakened by the discovery of the s t rong densit izing powers of the dyestuff known commercial ly as phenosafranin in Europe and supplied by an American manufac turer under the title Safranin A. extra. Dr.. Liippo-Cramer, Technical Director of Kranseder & Co.. Munich, whose fame in photographic research is interna- tional, called a t tent ion to the peculiar p roper ty that dilute solu- tions of this color have in diminishing the sensibility of exposed plates wi thout appreciably affecting the latent image. As might be expected, many other substances have similar properties, but none so far examined equals phenosafranin. Solutions of not over one part of the color to 2ooo of water are efficient, and such solu- tion keeps. Lf ippo-Cramer has fur ther found that the dye mark- edly accelerates the action of hydroquinone, and that it also acts as preservat ive of developers. A solution of the material has re- cently been put on the market by an English firm under the title " Desensitol ." This is a very concentra ted solution, and is directed to be diluted to abont fifty times for use. A. and L. Lmniere and Sevewitz have recently presented a communicat ion "~o the French Pfmtographic Society, detail ing the results of many exper iments to determine what other substances are densitizers. The paper has appeared in very full abst ract in a recent issue of La l~c~'z~e Fr~znfaise dc Photographic. Lfil~p~-Cramer has published a small book giving an account of his researches in the field, and discussing some of the theories of the action.

H . L .

Note on the Possibility of Separating Mercury into Its Iso- topic Forms by Centrifuging. J. H. J. POOLE. (Phil. Mag., May, I 92 I . ) - - Ac c o r d ing to Aston's results mercury is a mixture of six isotopes having atomic weights of ~97, 198, I99, 200, 202 and 2o 4. To simplify the problem of finding on theoretical grounds whether it be possible to separate the liquid into its isotopes by centrifuging several assumptions are m a d e . Only two isotopes are considered at present, and these have a difference in atomic weight of 4 units. T h e y are in approximate ly equal amounts and are supposed to differ only in mass ; all other constants being the same for both. Mercury is regarded as incompressible.

T h e conditions of equil ibrium for such a mixture in a rota t ing tube placed in a centr ifugal field of force are examined, and it is found that the difference of density between the two ends of the ro ta t ing tube would be only one part in 3o,ooo for 9ooo revolut ions per minute. So minute a difference could hardly be detected. It is suggested that a centr i fuge could be made to run at 6o,ooo revolu- tions per minute, and that with this appara tus the difference of density would reach z ~ parts per thousand, which could be de- t e c t e d . Af te r~a t ta in ing this conclusion the author puts a curb on anticit~ati0n by saying: " The results obtained would apparent ly